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The implications of structural control on the miocene carbonate reservoirs of Bakr-Al Hamd oil fields, Gulf of Suez 结构控制对苏伊士湾 Bakr-Al Hamd 油田中新世碳酸盐岩储层的影响
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-03-19 DOI: 10.1007/s13202-024-01770-2
Mayada Sayed, Sadek Salim, Abdel Moneim El Araby, Mohamed Hammed

The present work aims to provide a tectonostratigraphic model of the Miocene carbonate reservoirs accumulated in Bakr-Al-Hamd ridge to help unlock an estimated statistical yet-to-find over 10 MMbbl of oil. The structural ridge is located in the western central Gulf of Suez and the hydrocarbon exploration within this NE-dipping structural high began in 1951. The model integrated several interpreted 3-D seismic volumes and their attributes, a complete set of well-log data, borehole images, and the resultant extensional structures from the natural and physical models. The structural model proposed the following: (1) a major gulf-parallel curved and faulted detachment between the two differentially strained sections of Miocene and Pre-Miocene sediments which were distinguished by seismic attributes and confirmed by borehole images, (2) the synthetic Gulf-parallel faults which represent footwall collapsing structural style of extensional faults, delineated Al Hamd Miocene Nullipore carbonate reservoir, (3) south-westward dislocation of the western gulf-parallel boundary fault of Al Hamd Nullipore facies and its allocation at the present-day shoreline, (4) three classification of the Miocene carbonate reef were interpreted; fringe reef in Bakr ridge, barrier reef in Al-Hamd, and patch reef in the intra-field. The achievements of the present study prompted exploration activity and two discoveries were announced in 2021 and 2022 in the vicinity of Bakr and Al-Hamd intra-fields. The recent discoveries penetrated more than 200 m of Miocene carbonate reef and dolomitic reservoirs accumulated on the detachment surface. The present study workflow could be used in similar petroliferous rift basins to maximize hydrocarbon resources, enhance production performance, and revive brownfields.

本研究旨在提供巴克尔-阿尔-哈姆德海脊中新世碳酸盐岩储层的构造地层模型,以帮助揭开据估计尚未发现的超过 1,000 亿桶石油的神秘面纱。该构造脊位于苏伊士湾中西部,1951 年开始在这一东北倾构造高地进行油气勘探。该模型整合了多个三维地震解释量及其属性、一整套井记录数据、井眼图像以及自然和物理模型得出的延伸结构。该结构模型提出了以下几点:(1) 在两个不同应变的中新世和前中新世沉积层段之间有一个主要的海湾平行弯曲断裂支离,该支离由地震属性区分,并由井眼图像确认;(2) 合成的海湾平行断层代表了延伸断层的底壁塌陷构造样式、(3) Al Hamd Nullipore 层的西部海湾平行边界断层向西南方向变位,并将其分配到今天的海岸线上,(4) 对中新世碳酸盐岩礁的三种分类进行了解释;(4) 解释了中新世碳酸盐岩礁的三种分类:巴克尔山脊的边缘礁、哈姆德的屏障礁和场内的斑块礁。本研究的成果促进了勘探活动,并于 2021 年和 2022 年在 Bakr 和 Al-Hamd 内油田附近宣布了两个发现。最近的发现穿透了 200 多米的中新世碳酸盐岩礁和白云质储层,这些储层积聚在剥离面上。本研究的工作流程可用于类似的含油裂谷盆地,以最大限度地开发碳氢化合物资源,提高生产性能,并振兴棕色油田。
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引用次数: 0
Machine learning classification approaches to optimize ROP and TOB using drilling and geomechanical parameters in a carbonate reservoir 在碳酸盐岩储层中利用钻井和地质力学参数优化 ROP 和 TOB 的机器学习分类方法
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-03-19 DOI: 10.1007/s13202-024-01769-9
Mohammad Reza Delavar, Ahmad Ramezanzadeh

Drilling optimization has been broadly developed in terms of influential parameters. The assessment time and the effects of both geomechanical and drilling parameters were vital challenges of investigations. Drilling factors are applied force or rotation of drilling agents such as weight on bit (WOB), and geomechanical features represent mechanical indexes of rocks including unconfined compressive strength (UCS). Optimization efforts have been demonstrated on complex prediction methods whereas the simplicity of classification can offer some optimal ranges utilizing machine learning classifications in an accelerated process. In this study, a novel procedure using the supervised and semi-supervised learning approaches was conducted to classify and optimize the rate of penetration (ROP) and torque on bit (TOB). Firstly, in the case well, user-defined classes were assigned based on geomechanical units (GMU) and the ranges of high ROP and low TOB, thus classes divided drilling factors as GMUs of the case. Secondly, the feature selection was carried out by neural pattern recognition with three multi-objective optimization methods for classification. The inputs of classifications were WOB, hook load, pump pressure, flow rate, UCS, and internal friction angle. Classification approaches were decision trees, support vector machine (SVM), and ensemble learning. Finally, the bagged trees permutation and Laplacian SVM (LapSVM) algorithm separately revealed the significance of parameters and predicted the optimal ROP and TOB regions. Findings showed (1) in supervised classification of the case well, the cubic SVM and bagged trees had the highest area under the curve (AUC) and accuracy, on average 0.97 and 0.96, respectively. (2) The average accuracy of the supervised classifications in a test well was 91% except for the fine SVM, which makes them reliable for the fields with the least information. (3) The permutation outcomes for significant features, flow rate and UCS, exposed influential parameters for ROP and TOB optimization. (4) The semi-supervised method, LapSVM, not only acquired both ROP and TOB labels with an accuracy of 88% but also presented their optimal ranges in 95% of the assessed zones. (5) LapSVM deals with a limited training section perfectly opposed to the supervised version, which is vital for drilling investigation. (6) Implementing machine learning classification approaches with rock properties is a key factor in achieving effective drilling parameters in less time. More importantly, the recommended drilling factors concerning geomechanical properties can ameliorate both drilling performance and perception of upcoming collapse.

钻井优化在影响参数方面得到了广泛的发展。地质力学参数和钻井参数的评估时间和影响是研究的重要挑战。钻井因素是指钻井剂的作用力或旋转,如钻头重量(WOB),而地质力学特征是指岩石的力学指标,包括非收缩抗压强度(UCS)。复杂预测方法的优化工作已得到证实,而分类的简易性可以在加速过程中利用机器学习分类提供一些最佳范围。在本研究中,使用监督和半监督学习方法对渗透率(ROP)和钻头扭矩(TOB)进行了分类和优化。首先,在案例井中,根据地质力学单元(GMU)以及高 ROP 和低 TOB 的范围分配用户定义的类别,从而将钻井因素划分为案例的 GMU。其次,通过神经模式识别进行特征选择,并采用三种多目标优化方法进行分类。分类输入为 WOB、钩载、泵压、流量、UCS 和内摩擦角。分类方法有决策树、支持向量机(SVM)和集合学习。最后,袋装树排列和拉普拉斯 SVM(LapSVM)算法分别揭示了参数的重要性,并预测了最佳 ROP 和 TOB 区域。研究结果表明:(1)在对病例进行监督分类时,立方体 SVM 和袋装树的曲线下面积(AUC)和准确率最高,平均分别为 0.97 和 0.96。(2)除精细 SVM 外,试验井中监督分类的平均准确率为 91%,这使得它们在信息最少的油田中也是可靠的。(3) 重要特征、流速和 UCS 的置换结果揭示了对 ROP 和 TOB 优化有影响的参数。(4) 半监督方法 LapSVM 不仅以 88% 的准确率获得了 ROP 和 TOB 标签,而且在 95% 的评估区域中显示了它们的最佳范围。(5) LapSVM 处理的是有限的训练部分,完全不同于监督版本,这对钻井调查至关重要。(6) 利用岩石特性实施机器学习分类方法是在更短时间内获得有效钻探参数的关键因素。更重要的是,与地质力学特性相关的建议钻探因素可以改善钻探性能和对即将发生的塌方的感知。
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引用次数: 0
Interactions between chloride-based salts (CaCl2 and MgCl2), ionic liquids, pH, and titanium oxide nanoparticles under low and high salinity conditions, and synthetic resinous crude oil: dorud oilfield 氯基盐(CaCl2 和 MgCl2)、离子液体、pH 值和纳米氧化钛在低盐度和高盐度条件下与合成树脂原油的相互作用:多鲁德油田
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-03-07 DOI: 10.1007/s13202-024-01759-x
Mehrdad Pazhoohan, Ali Zeinolabedini Hezave

Unfortunately, oil reservoirs are complex considering the fluids (e.g., crude oil composition) and rock properties making it hard to propose a simple enhanced oil recovery (EOR) method for higher oil production. Besides, most of the investigations had focused on crude oil which is a complex mixture of thousands of components making it hard to extract any reliable conclusions with respect to the crude oil type. So, the current study is focused on the application of ionic liquids from different families of pyridinium and imidazolium, titanium oxide nanoparticles, and salts (MgCl2 and CaCl2) in the presence of resinous synthetic oil for the first time. The obtained results using the central composite design (CCD) approach revealed the positive effect of resin fraction on the IFT reduction by 27% considering the initial value (34.9%). Using the CCD approach revealed that using pH = 7, MgCl2 concentration = 21,000 ppm, CaCl2 concentration = 21,000 ppm, resin fraction of 9wt%t and 500 ppm of [C12mim][Cl] concentration reduces the IFT to minimum value of 0.62 mN/m while the minimum IFT value for optimum conditions of solution includes [C12py][Cl] led to minimum IFT value of 2.2 mN/m. But, the contact angle measurements revealed better synergy between [C12py][Cl] and TiO2-NPs (0–200 ppm) for better wettability alteration toward water-wet condition (27.3°) than [C12mim][Cl] (33.2°). Moreover, the IFT measurements revealed that the presence of TiO2-NPs is effective in reducing the IFT of the optimum formulations to 0.55 and 0.84 mN/m for [C12mim][Cl], and [C12py][Cl], respectively. According to the results, it seems that the obtained optimum formulations for [C12mim][Cl], and [C12py][Cl] are applicable for EOR purposes as new hybrid solutions.

遗憾的是,考虑到流体(如原油成分)和岩石特性,油藏非常复杂,因此很难提出一种简单的提高石油产量的强化采油(EOR)方法。此外,大多数研究都侧重于原油,而原油是由数千种成分组成的复杂混合物,因此很难针对原油类型得出任何可靠的结论。因此,本研究首次将重点放在吡啶和咪唑等不同系列的离子液体、纳米氧化钛颗粒和盐(氯化镁和氯化钙)在树脂合成油中的应用上。采用中央复合设计(CCD)方法得出的结果表明,考虑到初始值(34.9%),树脂馏分对减少 IFT 有 27% 的积极影响。使用 CCD 方法显示,在 pH = 7、氯化镁浓度 = 21,000 ppm、氯化钙浓度 = 21,000 ppm、树脂组分为 9wt%t 和[C12mim][Cl]浓度为 500 ppm 的条件下,IFT 的最小值为 0.62 mN/m,而在溶液包括[C12py][Cl]的最佳条件下,IFT 的最小值为 2.2 mN/m。但是,接触角测量结果显示,[C12py][Cl] 和 TiO2-NPs(0-200 ppm)之间的协同作用比[C12mim][Cl](33.2°)更好,能更好地改变水湿条件下的润湿性(27.3°)。此外,IFT 测量显示,TiO2-NPs 的存在可有效地将[C12mim][Cl]和[C12py][Cl]的最佳配方的 IFT 分别降至 0.55 和 0.84 mN/m。结果表明,所获得的[C12mim][Cl]和[C12py][Cl]最佳配方可作为新的混合溶液用于 EOR 目的。
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引用次数: 0
Development and field application of a jetting and helical combination tool 喷射和螺旋组合工具的开发和现场应用
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-03-04 DOI: 10.1007/s13202-024-01757-z
L. I. U. Huanle, X. U. E. Shifeng, S. U. N. Zhiyang, Zhou Chao

Liquid loading occurs in gas wells after a period of production, and the vortex drainage gas recovery technology can alleviate this problem by removing liquid. To substantially enhance the efficiency of this technology, a novel tool combining jetting and helical mechanisms has been introduced. To validate its effectiveness, a laboratory system for detailed analysis of pressure drops by using various tools at multiple gas flow rates has been set up. The analysis approach encompasses both single-factor and orthogonal analyses of tool structure parameters to find out the optimal tool structural parameters under different operating conditions. Consequently, a correlation between the gas flow rates observed in controlled laboratory environments and those in actual gas wells has been established. The study indicates that the tool’s main structural parameters significantly impact pressure drops along the wellbore. Furthermore, it is evident that distinct well profiles require unique tool setups to minimize such pressure drop. Field tests of the optimized tool have shown notable enhancements: The average gas flow rate increased by 25.9%, reaching 5.39 × 104 m3/d (1.90 × 106 scf/d), while the average liquid flow rate increased by 20.1%, reaching 1.46 m3/d (9.18 bbl/d). These results highlight the superior drainage stimulation effect of the new jetting and helical combination tool, presenting novel insights and methodologies for enhancing gas recovery in liquid-loaded gas wells.

气井在生产一段时间后会出现液体负载,涡流排水采气技术可以通过清除液体来缓解这一问题。为了大幅提高这项技术的效率,我们引入了一种结合了喷射和螺旋机制的新型工具。为了验证其有效性,我们建立了一个实验室系统,用于详细分析在多种气体流速下使用各种工具产生的压降。分析方法包括工具结构参数的单因素分析和正交分析,以找出不同工作条件下的最佳工具结构参数。因此,在受控实验室环境中观察到的气体流速与实际气井中的气体流速之间建立了相关性。研究表明,工具的主要结构参数对沿井筒的压降有显著影响。此外,不同的气井剖面显然需要独特的工具设置,以最大限度地减少压降。对优化工具进行的现场测试表明,其性能明显提高:平均天然气流量增加了 25.9%,达到 5.39 × 104 立方米/天(1.90 × 106 立方英尺/天),平均液体流量增加了 20.1%,达到 1.46 立方米/天(9.18 桶/天)。这些结果凸显了新型喷射和螺旋组合工具卓越的排水刺激效果,为提高含液气井的天然气采收率提供了新的见解和方法。
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引用次数: 0
Further study on oil/water relative permeability ratio model and waterflooding performance prediction model for high water cut oilfields sustainable development 高含水油田可持续开发的油水相对渗透率模型和注水性能预测模型的进一步研究
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-03-04 DOI: 10.1007/s13202-024-01753-3
Renfeng Yang

The accuracy of predicting waterflooding performance is crucial in determining the scale of investment for oilfield development. However, existing common waterflooding prediction models often relies on assumptions that may not apply universally or lack theoretical derivation through statistical analysis. This has led to unsatisfactory prediction accuracy and multiple potential solutions. To address these limitations, it is proposed to incorporate the oil/water relative permeability ratio model into the derivation process of waterflooding prediction models. Initially, an evaluation of prevalent oil/water relative permeability ratio models is conducted, along with an analysis of their primary constraints. Additionally, the applicability of the analytical relative permeability model is thoroughly examined. Building upon the analytical relative permeability model and a modified Welge equation, a new waterflooding model is formulated, encompassing all pertinent physical coefficients. Notably, this model aligns seamlessly with the commonly used Arps’ decline curve, while extending its applicability to a broader range of conditions. Moreover, it can be simplified to generate typical water drive curves under suitable circumstances. The semi-log relationship between oil/water relative permeability ratio and water saturation is further simplified into a linear relationship or a multi-term formula. Compared with the traditional waterflooding model, the new model proposed in this research has a wider application range and can be applied to oilfield at high water cut. At the same time, the new model clarifies the coefficient of waterflooding curve A and the physical meaning of parameter 7.5 in Tong’s chart method for the first time. The new model proposed in this research further enriches the connotation of waterflooding theory and has certain application significance.

预测注水性能的准确性对于确定油田开发的投资规模至关重要。然而,现有的普通注水预测模型往往依赖于一些可能并不普遍适用的假设,或者缺乏通过统计分析得出的理论推导。这就导致了预测精度不尽人意,潜在的解决方案也多种多样。针对这些局限性,建议将油/水相对渗透率比模型纳入注水预测模型的推导过程。首先,对现有的油/水相对渗透率模型进行评估,并分析其主要限制因素。此外,还深入研究了分析相对渗透率模型的适用性。在分析相对渗透率模型和修改后的韦尔热方程的基础上,制定了一个新的注水模型,包含所有相关的物理系数。值得注意的是,该模型与常用的阿普斯递减曲线无缝衔接,同时适用于更广泛的条件。此外,在适当的情况下,还可以对其进行简化,生成典型的水驱曲线。油/水相对渗透率与水饱和度之间的半对数关系被进一步简化为线性关系或多项式。与传统的注水模型相比,本研究提出的新模型适用范围更广,可应用于高含水油田。同时,新模型首次明确了注水曲线 A 的系数和唐氏图表法中参数 7.5 的物理意义。该研究提出的新模型进一步丰富了注水理论的内涵,具有一定的应用意义。
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引用次数: 0
Mechanical and energetic properties of rock-like specimens under water-stress coupling environment 水应力耦合环境下类岩石试样的力学和能量特性
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-02-24 DOI: 10.1007/s13202-024-01766-y
Xiaoyang Cheng, Haitao Sun, Yang Pu, Junjie Guo, Wei Qiao

Soft rock has the properties of low strength, poor integrity, and difficulty in core extraction. In order to study the deformation and failure of soft rock, this study used fine river sand as aggregate, cement and gypsum as bonding materials, and borax as a retarder to produce cylindrical rock-like samples (RLS) with a sand cement ratio of 1:1. Uniaxial compression tests were conducted on RLS under DIT (different immersion times) (0, 4, 8, 12, 24, and 48 h) in the laboratory. The mechanical and energy properties of RLS under water-stress coupling were analyzed. The results showed that the longer the IT of the RLS, the higher their water content (WC). As the moisture time increases, the uniaxial compressive strength, elastic modulus (EM), and softening coefficient (SC) of the sample gradually decrease, while the rate of change of EM is the opposite. The fitted sample SC exhibits a good logarithmic function relationship with WC. During the loading process of the sample, more than 60% of the U (total energy absorbed) during the loading process of the sample is accumulated in the form of Ue (releasable elastic energy), while less than 40% of U is dissipated by the newly formed micro cracks during the compaction, sliding, and yield stages of the internal pores and cracks of the sample. The U before the peak and the Ue of the RLS decrease exponentially with the moisture content; the relationship curves of Ue/U (released elastic energy ratio) and Ud/U (dissipated energy ratio) of RLS during uniaxial compression with the σ1/σmax (axial stress ratio) can be divided into three stages of change, namely the stage of primary fissure compaction and closure (σ1/σmax < 0.25), continuously absorbing energy stage (0.25 < σ1/σmax < 0.8), and energy dissipation stage (σ1/σmax > 0.8); the D (damage variable) was defined by the ratio of Ud (dissipated energy) to the Udmax (maximum dissipated energy) at failure time of RLS, the fitting of the relationship between the damage variable and axial strain conforms to the logistic equation.

软岩具有强度低、完整性差、岩芯提取困难等特性。为了研究软岩的变形和破坏,本研究采用细河砂作为骨料,水泥和石膏作为粘结材料,硼砂作为缓凝剂,制作出砂土比为 1:1 的圆柱形类岩石样品(RLS)。在实验室中,在 DIT(不同浸泡时间)(0、4、8、12、24 和 48 小时)条件下对 RLS 进行了单轴压缩试验。分析了水-应力耦合下 RLS 的机械和能量特性。结果表明,RLS 的 IT 时间越长,含水量(WC)越高。随着水分时间的增加,样品的单轴抗压强度、弹性模量(EM)和软化系数(SC)逐渐降低,而 EM 的变化率则相反。拟合的样品 SC 与 WC 呈良好的对数函数关系。在试样的加载过程中,60% 以上的 U(吸收的总能量)以 Ue(可释放的弹性能量)的形式积累,而不到 40% 的 U 是由试样内部孔隙和裂缝在压实、滑动和屈服阶段新形成的微裂缝耗散的。峰值前的 U 和 RLS 的 Ue 随含水率呈指数下降;单轴压缩时 RLS 的 Ue/U(释放的弹性能量比)和 Ud/U(耗散的能量比)与 σ1/σmax(轴向应力比)的关系曲线可分为三个变化阶段,即初级裂隙压实和闭合阶段(σ1/σmax < 0.25)、持续吸收能量阶段(0.25 < σ1/σmax < 0.8)和能量耗散阶段(σ1/σmax >0.8);D(损伤变量)由RLS破坏时的Ud(耗散能量)与Udmax(最大耗散能量)之比定义,损伤变量与轴向应变的拟合关系符合Logistic方程。
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引用次数: 0
Simulation and performance prediction of partially naturally fractured reservoirs under solution gas drive primary recovery and gas injection processes 部分天然裂缝储层在溶液气驱一次采收和注气过程中的模拟和性能预测
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-02-24 DOI: 10.1007/s13202-024-01764-0
Fuad H. Qasem, Ibrahim Sami Nashawi

The study presented in this paper has multiple objectives. First, a simulation model for partially naturally fractured reservoirs under solution gas drive is developed. The model considers the major key parameters controlling fluid flow in the reservoir, including fracture intensity and distribution, instantaneous gas/oil segregation due to vertical capillary continuity, gas/oil gravity drainage, and reinfiltration of the drained oil to the lower matrix. Once the model is well-established, it is used to study the reservoir performance under two recovery processes: primary depletion and gas injection. A detailed investigation of the sensitivity of the ultimate oil recovery to the fracture intensity, oil production rates, and gas injection rates is performed. The findings of this study indicate that the ultimate oil recovery of low-fracture intensity reservoirs subjected to the depletion drive process is insensitive to production rates. However, for moderate- to high-fracture intensity reservoirs and low production rates, the recovery increases with increasing fracture intensity. Conversely, for moderate- to high-fracture intensity reservoirs and high production rates, the recovery is not significantly affected. For the gas injection mechanism, it is found that the ultimate oil recovery is a function of both the fracture intensity and gas injection rate. Furthermore, three fracture intensity ranges are identified: low, medium, and high. For the low- and high-fracture intensity ranges, the recovery increases with increasing gas injection rates and fracture intensity. However, for the medium fracture intensity ranges, the recovery behaves differently. It increases at low gas injection rates and decreases at high injection rates as the fracture intensity increases. New equations relating the cumulative oil production to the production rates, gas injection rates, and fracture intensity are also presented.

本文介绍的研究有多个目标。首先,建立了溶解气驱条件下部分天然裂缝储层的模拟模型。该模型考虑了控制储层流体流动的主要关键参数,包括裂缝强度和分布、垂直毛细管连续性导致的瞬时气/油分离、气/油重力泄油以及泄油对下部基质的再渗透。模型建立后,可用于研究两种采油过程下的储层性能:一次枯竭和注气。详细研究了最终采油量对裂缝强度、产油率和注气率的敏感性。研究结果表明,采用耗竭驱动工艺的低断裂强度储层的最终采油率对生产率不敏感。然而,对于中高裂缝强度和低生产率的油藏,采收率会随着裂缝强度的增加而增加。相反,对于中高裂缝强度和高生产率的储层,采收率不会受到明显影响。对于注气机制,研究发现最终采油率是裂缝强度和注气速率的函数。此外,还确定了三个压裂强度范围:低、中、高。在低和高断裂强度范围内,采收率随着注气速率和断裂强度的增加而增加。然而,在中等断裂强度范围内,采收率表现不同。随着断裂强度的增加,低注气率时采收率增加,高注气率时采收率降低。此外,还提出了将累积石油产量与生产率、注气率和断裂强度相关联的新方程。
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引用次数: 0
Hydrothermally synthetized WO3 coated stainless steel mesh for oil–water separation purposes 用于油水分离的水热合成 WO3 涂层不锈钢网
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-02-23 DOI: 10.1007/s13202-023-01741-z
Mohammad Nouri, Mohammad Taghi Sadeghi, AliMorad Rashidi, Reza Norouzbeigi

To separate oil–water mixtures especially in oil field operations, new energy-efficient methods are urgently required. Conventional separation techniques using demulsifiers for separation of oil–water mixtures or even use of membranes usually suffered from high cost and energy consumption, composition dependency of demulsifiers and fouling or inability of a single membrane to separate all types of oil–water mixtures. This research aimed to synthesize tungsten oxide-coated stainless steel mesh using the hydrothermal method, with a focus on evaluating its effectiveness in oil–water separation. The coating procedure was carried out using hydrothermal techniques, with an emphasis on investigating the impact of precursor concentration, pH levels, reaction temperature and duration, on the separation efficiency of the optimal coating solution. The hydrothermally coated stainless steel mesh was created within a polytetrafluoroethylene reaction vessel, submerged in a 150 ml aqueous solution containing 0.0094 mol of sodium tungstate di-hydrate at pH 3.0, achieved through the addition of hydrochloric acid. Additionally, 1 g of oxalic acid, acting as a chelating agent, was introduced. Subsequently, the mesh underwent a 4 h reaction at 220 °C and was subsequently annealed for 30 min in a 350 °C furnace. Remarkably, the resultant mesh exhibited an exceptional water separation flux of 9870 ± 15 L/hr/m2 when exposed to 1:1 v/v oil–water mixtures. This performance significantly outperformed previous filters designed for similar oil–water separation tasks. The mesh efficiently facilitated the passage of water through the oil–water mixture, achieving an efficiency rate exceeding 98 ± 1%. To gauge its wetting behavior, the hydrophilic/underwater oleophobic filter underwent static contact angle measurements. The filter's wetting mechanism was primarily attributed to its hierarchical surface structure, which enhanced surface hydrophilicity and roughness. Analytical techniques such as XRD, FTIR, and FE-SEM were employed to scrutinize the fabricated filter's composition. These analyses confirmed the successful creation of a nanostructured WO3 coating on both sides of the stainless steel mesh. Moreover, the utilization of commercially available chemicals and straightforward fabrication techniques underscores the promising potential of this approach for large-scale applications.

要分离油水混合物,特别是在油田作业中,迫切需要新的节能方法。传统的分离技术使用破乳剂分离油水混合物,甚至使用膜,通常都存在成本高、能耗大、破乳剂成分依赖性强、易堵塞或单一膜无法分离所有类型的油水混合物等问题。本研究旨在利用水热法合成氧化钨涂层不锈钢网,重点评估其在油水分离方面的效果。涂层程序采用水热技术进行,重点研究前驱体浓度、pH 值、反应温度和持续时间对最佳涂层溶液分离效率的影响。水热涂层不锈钢网是在聚四氟乙烯反应容器中制成的,容器浸没在 150 毫升的水溶液中,水溶液中含有 0.0094 摩尔的二水钨酸钠,pH 值为 3.0,这是通过添加盐酸实现的。此外,还加入了 1 克草酸作为螯合剂。随后,网状物在 220 °C 下进行了 4 小时的反应,然后在 350 °C 的炉中退火 30 分钟。值得注意的是,当暴露在 1:1 v/v 的油水混合物中时,生成的滤网显示出 9870 ± 15 升/小时/平方米的超高水分离通量。这一性能明显优于以前为类似油水分离任务而设计的过滤器。滤网有效地促进了水通过油水混合物,效率超过 98 ± 1%。为了评估其润湿行为,亲水/水下疏油过滤器进行了静态接触角测量。过滤器的润湿机制主要归功于其分层表面结构,这种结构增强了表面亲水性和粗糙度。研究人员采用 XRD、傅立叶变换红外光谱和 FE-SEM 等分析技术仔细研究了制备的过滤器的成分。这些分析证实,在不锈钢网的两面都成功地形成了纳米结构的 WO3 涂层。此外,利用市场上可买到的化学品和简单的制造技术,也凸显了这种方法在大规模应用方面的巨大潜力。
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引用次数: 0
Prediction of wellbore sand production potential from analysis of petrophysical data coupled with field stress: a case study from the Shah-Deniz gas field (Caspian Sea Basin) 通过分析岩石物理数据和油田应力预测井筒产砂潜力:沙赫-德尼兹气田(里海盆地)案例研究
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-01-06 DOI: 10.1007/s13202-023-01738-8
Ali Gholami Vijouyeh, Mohammad Hassanpour Sedghi, David A. Wood

Identifying the optimal azimuth and inclination for wellbore drilling in sandy formations can be considered a valuable aid in reducing sand production risks, lost time, and decreasing drilling costs in the petroleum industry. Therefore, a numerical systematic approach was provided to predict sand production in wellbore SDX-5, drilled in a deep-water sandstone reservoir in the Shah-Deniz gas field (South Caspian Basin), which has never been done previously. Additionally, this systematic approach uses geomechanical and geodynamical criteria, along with petrophysical information (density and sonic log) and tectonic characteristics of the study area, which are influenced by the active tectonic stresses of the Apsheron-Balkhan zone. The subsurface data sources employed are more eco-friendly, available, and continuous than experimental tests. The computations conducted achieved azimuth, inclination, polar, and depth profile plots for the Lower Balakhany Formation. The calculations reveal that the optimum azimuth for the wellbore drilling trajectories is parallel to SHmax and oblique drilling to near horizontal is the result of optimum inclination. Polar plots showed optimum azimuth, inclination, and effect of wellbore trajectory on critical collapse pressure and collapse drawdown pressure with pressure values simultaneously, which identify safer alternatives for achieving higher petroleum production rates without sanding. Depth profile plots provide a simultaneous overview of the values of critical collapse pressure, critical sanding pressure for instantaneous drawdown, and optimum wellbore production pressure during drilling and production operations. Moreover, optimum reservoir fluid production (maximum discharge) rates can be identified and imposed as upper limits to prevent sand production.

确定在砂质地层中钻井的最佳方位角和倾角,对石油工业降低产砂风险、损失时间和减少钻井成本有重要帮助。因此,我们提供了一种数值系统方法来预测在 Shah-Deniz 气田(南里海盆地)深水砂岩储层中钻探的 SDX-5 井筒的产砂量,这是以前从未做过的。此外,这种系统方法还使用了地质力学和地球动力学标准,以及岩石物理信息(密度和声波测井)和研究区域的构造特征,这些都受到阿普谢隆-巴尔干地区活跃构造应力的影响。与实验测试相比,所采用的地下数据源更加环保、可用和连续。计算得出了下巴拉汗地层的方位角、倾斜角、极坐标和深度剖面图。计算显示,井筒钻进轨迹的最佳方位角是平行于 SHmax,而斜向钻进接近水平则是最佳倾角的结果。极坐标图同时显示了最佳方位角、倾角以及井筒轨迹对临界坍塌压力和坍塌缩减压力与压力值的影响,从而确定了更安全的替代方案,以实现更高的石油生产率,而无需起砂。深度剖面图可同时显示临界坍塌压力、瞬时缩减的临界起砂压力以及钻井和生产作业期间的最佳井筒生产压力值。此外,还可以确定最佳储层流体生产率(最大排量),并将其作为防止产砂的上限。
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引用次数: 0
Research on key technology of packer rubber barrel for integrated fracturing and completion of gas well 气井综合压裂完井封隔器胶筒关键技术研究
IF 2.2 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-01-06 DOI: 10.1007/s13202-023-01737-9
Peng Wang, Meng Cai, Zhaoyi Liu, Wenhai Ma, Junliang Li

The staged and layered fracturing technology plays an important role in unconventional tight reservoirs. And the gas well fracturing and completion integration is the core component to realize the fracturing and completion integration process, which can realize the integration of acid fracturing and later drainage production so as to reduce the secondary pollution to the reservoir. The packer rubber barrel’s performance directly affects the long-term effective sealing reliability itself in high temperature and high pressure environment. In this paper, the constitutive model of rubber tested from high temperature and high pressure curing kettle to simulate the high-temperature and highly corrosive environment of the formation. On this basis, the structure of the packer’s shoulder and the protective ring of the rubber barrels are optimized through Abaqus to reduce its stress failure under high pressure, and its corrosion resistance is improved by improving the rubber material. The sealing performance of the packer rubber cylinder under the field underground requirements is tested through laboratory evaluation test and field test. The results show that the protective ring and rubber tube shoulder at 30° angle are a reasonable result of optimization, and the optimized packer can meet the requirements of 154 °C temperature resistance, 79 MPa pressure bearing and long-term effective sealing. The successful development of packer rubber and the integrated analysis process can lay a solid foundation for the realization of integrated fracturing and completion process for exploration and development of deep volcanic or carbonate reservoirs.

分段分层压裂技术在非常规致密油藏中发挥着重要作用。而气井压裂完井一体化是实现压裂完井一体化工艺的核心部件,可以实现酸性压裂和后期排水生产一体化,从而减少对储层的二次污染。封隔器胶筒的性能直接影响其本身在高温高压环境下的长期有效密封可靠性。本文通过高温高压硫化罐测试的橡胶构成模型来模拟地层的高温高腐蚀环境。在此基础上,通过Abaqus优化封隔器肩部和胶筒保护环的结构,降低其在高压下的应力失效,并通过改进橡胶材料提高其耐腐蚀性能。通过实验室评估试验和现场试验,测试了封隔器橡胶筒在井下现场要求下的密封性能。结果表明,保护环和橡胶管肩呈 30° 角是合理的优化结果,优化后的封隔器能满足耐 154 °C 温度、79 MPa 承压和长期有效密封的要求。封隔器橡胶及综合分析工艺的研制成功,可为深层火山岩或碳酸盐岩储层勘探开发实现压裂完井一体化工艺奠定坚实基础。
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引用次数: 0
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Journal of Petroleum Exploration and Production Technology
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