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Geochemical Characteristics of Oils from the Orenburg Field in the SE Volga-Ural Basin, Russia: Implications for the Molecular Structure of a Marine Type II Kerogen
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-01-31 DOI: 10.1111/jpg.12877
Mohammed Hail Hakimi, Muneer A. Suwaid, Shadi A. Saeed, Ameen A. Al-Muntaser, Mikhail A. Varfolomeev, Aliia N. Khamieva, Danis K. Nurgaliev, Mohammed A. Abdullah, Aref Lashin, Evgeniya V. Morozova, Bulat I. Gareev, Vitaly V. Andriyashin, Igor Ognev, Fatma Tahhan

Six oil samples from an Upper Devonian carbonate reservoir in the Orenburg field in the SE Volga-Ural Basin (Russia) were analyzed geochemically, together with extracts of five core samples of the Domanik Formation source rock (Frasnian-Tournaisian) from a well located in the south of the basin. Biomarker analyses of saturated and aromatic oil fractions were combined with new data on the molecular structure of asphaltene in order to investigate source rock organic matter input, depositional environment, and thermal maturity. The studied oil samples have high API values (31°–37°) and saturated hydrocarbon contents up to 66%, suggesting that they were generated by a thermally mature source rock and consistent with high contents of С6–С14 n-alkanes relative to C15+ of the oil-asphaltene fraction. The molecular structure of asphaltene derived from pyrolysis-gas chromatograpy-mass spectrometry (Py-GC-Ms) analyses also suggests that the oils were generated by a source rock containing marine Type II kerogen, consistent with the H/C atomic ratio up to 1.25. Bulk kinetic analyses of the asphaltene showed a relatively broad range of activation energies between 40 and 58 kcal/mol and a frequency factor (A) of 12E+14/1 s. The biomarker characteristics of aliphatic and aromatic fractions in the studied oils suggest that they were generated by carbonate-rich source rocks containing organic matter of marine algal origin deposited under anoxic conditions. Furthermore, maturity-sensitive biomarker parameters show that the oils were generated at peak oil window maturities. Oil-source rock correlations of biomarker proxies indicated that the analyzed oils from the Orenburg field were mainly generated by carbonate-rich shaley source rocks in the Domanik Formation.

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引用次数: 0
Bulk Organic Matter Characteristics and Hydrocarbon Generation–Expulsion Modeling of Middle Jurassic–Lower Cretaceous Source Rocks in the Abadan Plain, Southern Mesopotamian Basin, SW Iran
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-01-06 DOI: 10.1111/jpg.12878
Buyuk Ghorbani, Hossain Rahimpour-Bonab, Vahid Tavakoli, Navid Vahidimotlagh, Hojjat Kazemi

This study examines the bulk organic geochemical properties, the burial and thermal history reconstruction, and timing of hydrocarbon generation of Jurassic and Cretaceous source rocks in the Abadan Plain, within the western Zagros fold-and-thrust belt in SW Iran. Three source rock units were evaluated: the Middle Jurassic (Bajocian–Callovian) Sargelu Formation, the Lower Cretaceous (Neocomian) Garau Formation, and the Lower Cretaceous (Aptian–Albian) Kazhdumi Formation. Rock-Eval pyrolysis and organic petrography analyses revealed that the Sargelu Formation is overmature, with abundant solid bitumen and pyrobitumen, indicating depleted hydrocarbon generation potential. Total organic carbon (TOC) values range from 0.46 to 14.8 wt% with low hydrogen index (HI) values, suggesting no further liquid hydrocarbon generation is possible. The Garau Formation is highly mature with TOC values of 0.44–9.4 wt% and HI values below 400 mg HC/g TOC, confirming that hydrocarbon generation has occurred. While the advanced maturity of both formations prevents direct kerogen-type identification through Rock-Eval results, petrography indicates the Sargelu and Garau formations are indicative of Type II kerogen. The Kazhdumi Formation shows varied maturity levels, ranging from immature to marginally mature, with TOC values between 0.16 and 6.33 wt% and HI values from 72 to 626 mg HC/g TOC, reflecting a mix of Types II and III kerogen.

The one-/two-dimensional basin modeling conducted across the Azadegan, Yadavaran, Darquain, and Mahshahr fields reveals significant variations in burial depth, thermal history, and hydrocarbon generation potential. Thermal modeling indicates maximum burial temperatures were reached in the late Neogene, with the basal heat flow value of 45 mW/m2 for most fields, except in Darquain, where an elevated basal heat flow of 62 mW/m2, potentially linked to detachment thrusting within the Hormuz salt caused by the reactivation of basement faults, accelerated thermal maturation of the Sargelu and Garau source rocks. In Darquain, the Sargelu Formation has entered the wet gas window (VRo% ∼1.9), and the Garau Formation. has reached late oil to wet gas maturity (VRo% ∼1.5), while in Azadegan both remain in the late oil window. The Kazhdumi Formation remains immature to marginally mature across all fields. The calculated transformation ratio (TR) shows that the Sargelu and Garau Formation. Source rocks in Darquain have surpassed 90% TR, fully exhausting their liquid hydrocarbon generation potential. These findings offer critical insights into the petroleum system of the Abadan Plain, highlighting areas like Darquain, where hydrocarbons have already been expelled and zones such as Azadegan and Mahshahr, with further oil generation potential.

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引用次数: 0
Comparison between Core- and Well Log-Based Identification of Flow Units in the Mid-Cretaceous Bangestan Group Reservoir, Mansuri Field, SW Iran: Implications for Regional Characterization
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-01-02 DOI: 10.1111/jpg.12876
Mehdi Daraei, Saeed Afrazi, Mahdi Vasighi, Zohreh Masoumi

Core- and well log-based techniques of reservoir characterization were used to independently assess mid-Cretaceous (Albian–Santonian) flow units in the Bangestan Group reservoir of the Mansuri oilfield, located in the Dezful Embayment of SW Iran. The outcomes of the two techniques were compared to assess their utility in flow unit determination. Core-based reservoir classification using the “Flow Zone Indicator” and “Stratigraphic Modified Lorenz Plot” approaches defined 15 flow units in the Mansuri reservoir, including three speed zones. Well log-based (“K-means” and “linkage clustering”) methodologies provided broadly consistent results with 16 flow units defined in the same reservoir sequence. The log-based reservoir zonation gave a better vertical and laterally continuous representation of the reservoir geometry, while the core-based zonation provided more information about reservoir quality and ranking of the flow units identified. To assess its regional significance, a reservoir zonation combining both techniques was then compared with Bangestan Group reservoirs across SW Iran. The analysis highlighted the influence of regional unconformities and associated subaerial exposure upon reservoir quality and flow unit geometries within the Bangestan reservoir. These exposure surfaces had distinct well log signatures, which could be traced across the region and used to define the regional configuration of the Bangestan Group reservoir in the absence of core data.

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引用次数: 0
APPLICATION OF BENZOCARBAZOLE MOLECULAR MIGRATION MARKERS IN RECONSTRUCTING RESERVOIR FILLING AT THE SOLVEIG FIELD, NORWEGIAN NORTH SEA 苯并咔唑分子迁移标记在重建挪威北海索维格油田储层充填中的应用
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-23 DOI: 10.1111/jpg.12870
Thorsten Uwe Garlichs, Rolando di Primio, Lorenz Schwark

Benzocarbazole (BC) migration tracers were used to investigate the complex filling of reservoir segments at the Solveig field in the Norwegian North Sea. The study suggests that the benzocarbazole ratio [a]/([a]+[c]) of crude oils and extracts decreases with inferred increasing migration distance. The complex filling history of the Solveig field is evident from the observation of variable degrees of palaeo biodegradation associated with two palaeo oil-water contacts in residual oil zones below non- to moderately biodegraded live oil columns. Live oil properties also vary significantly across the field. Benzocarbazole ratios (BCRs) obtained from oils and reservoir core extracts appear not to be affected by biodegradation and indicate a migration and filling trend from NW to SE. The BCR values were set by the initial phase of filling and do not show any overprint effects as a result of later and more mature oil charges.

BCRs from both oils and extracts of reservoir cores, particularly those composed of clean sands, helped to reconstruct migration processes in the Solveig field. Migration is construed to have first filled reservoir segment D in the NW of the field and to have continued further east towards segment C, and then via segment B and finally into segment A. Migration then continued along the southern margin of the Haugaland High to a well location to the east of the Solveig field. A fractionation effect for benzocarbazoles derived from oils versus those from extracts was noted and was attributed to differential partitioning behavior. Nevertheless, spatial trends for oil- and extract-derived BCRs were congruent. This allowed the generation of spatially more highly-resolved benzocarbazole datasets for migration assessment by combining data from both samples types (oil and reservoir extracts) if partitioning is accounted for.

苯并咔唑(BC)迁移示踪剂用于研究挪威北海索尔维格油田储层段的复杂充填。研究表明,原油和提取物中的苯并咔唑比率[a]/([a]+[c])随着迁移距离的增加而降低。索尔维格油田的填充历史非常复杂,这一点从观察到的不同程度的古生物降解中可以看出,这与非生物降解至中度生物降解活油柱下方残余油区的两个古油水接触点有关。整个油田的活油属性也有很大差异。从石油和储层岩心提取物中获得的苯并咔唑比率(BCR)似乎不受生物降解的影响,并显示出从西北向东南的迁移和填充趋势。BCR 值是在充填初期确定的,并没有显示出因后期和更成熟的油层充填而产生的叠加效应。 石油和储层岩心提取物(尤其是由洁净砂组成的岩心提取物)的 BCR 值有助于重建索尔维格油田的迁移过程。据推测,迁移过程首先填充了油田西北部的储油层 D 区段,然后继续向东迁移至 C 区段,再经过 B 区段,最后进入 A 区段。从油类中提取的苯并咔唑与从萃取物中提取的苯并咔唑相比,存在分馏效应,这归因于不同的分配行为。尽管如此,从油类和萃取物中提取的苯并咔唑的空间趋势是一致的。如果考虑到分区因素,就可以通过结合两种样本类型(油和储层提取物)的数据,生成空间分辨率更高的苯并咔唑数据集,用于迁移评估。
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引用次数: 0
FACIES PARTITIONING AT REGIONAL AND FIELD SCALES IN THE BARREMIAN KHARAIB-2 CARBONATES, UAE 阿联酋巴里米亚海盆Kharaib-2碳酸盐岩在区域和实地尺度上的岩相分区
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-23 DOI: 10.1111/jpg.12869
Pierre Gatel, Jean Borgomano, Jeroen Kenter, Tarek Mecheri

Carbonates in the Lower Cretaceous (Barremian to early Aptian) Kharaib Formation are reservoir rocks at giant oil fields in the UAE and Qatar. The Barremian Kharaib-2 member (K60), the focus of this study, is in general composed of a regionally continuous succession of high-energy, shallow-water limestones bounded above and below by “dense” low-energy mud-rich strata. Despite several decades of research, conventional carbonate facies classification schemes and resulting facies groupings for the Kharaib-2 member have failed to show a statistically acceptable correlation with core- and log-derived petrophysical data. Moreover, sedimentary bodies potentially responsible for dynamic reservoir heterogeneities have not clearly been identified. This paper proposes a standardized facies classification scheme for the Kharaib-2 carbonates based on vertical facies proportion curves (VPCs) and variogram analyses of core data to construct stratigraphic correlations at both field and regional scales. Data came from 295 cored wells penetrating the Kharaib-2 member at ten fields in the on- and offshore UAE. Thin, dense intervals separating reservoir units were adopted as fourth-order transgressive units and were used for stratigraphic correlation. Field-scale probability maps were used to identify sedimentary bodies such as shallow-water rudistid shoals.

Regional stratigraphic correlations of the Kharaib-2 member carbonates based on the VPCs identified variations in depositional environments, especially for the lower part of the reservoir unit; depositional facies at fields in the SE of the UAE were interpreted to be more distal compared to those at offshore fields to the NW. At a field scale, the VPCs failed to identify significant lateral variations in the carbonates. However, variogram analyses of cored wells showed spatial concentrations of specific facies in the inner ramp domain which could be correlated with high-energy depositional bodies such as shoals dominated by rudist debris. The bodies were sinusoidal in plan view with lengths of up to 8 km and widths of ca. 1 km. Although similar-shaped bodies with these dimensions have been reported from other carbonate depositional systems, they have not previously been reported in the Kharaib Formation. At a regional (inter-field) scale, the stratigraphic correlation of standardized sedimentary facies remains problematic; however, mapping of facies associations and their relative proportions relative to their environments of deposition demonstrated new patterns for the stratigraphic architecture of the Kharaib-2 member in the UAE.

下白垩统(巴里米统至早安普统)Kharaib 组碳酸盐岩是阿联酋和卡塔尔巨型油田的储油层岩石。本研究的重点--巴里米亚系 Kharaib-2 组(K60),总体上由区域连续的高能浅水灰岩演替组成,其上下部以 "致密 "的低能富泥质地层为界。尽管经过数十年的研究,传统的碳酸盐岩岩相分类方案以及由此产生的 Kharaib-2 成员岩相分组与岩心和测井获得的岩石物理数据之间并没有显示出统计学上可接受的相关性。此外,可能造成储层动态异质性的沉积体也没有得到明确识别。本文根据岩心数据的垂直岩相比例曲线(VPCs)和变异图分析,提出了一套针对 Kharaib-2 碳酸盐岩的标准化岩相分类方案,以构建油田和区域尺度的地层相关性。数据来自阿联酋陆上和近海十个油田的 295 口穿透 Kharaib-2 碳酸盐岩的岩心井。将分隔储层单元的细密间隔作为四阶递变单元,用于地层关联。根据 VPCs 对 Kharaib-2 碳酸盐岩进行的区域地层关联确定了沉积环境的变化,尤其是储层单元下部;与西北部近海油田的沉积面相比,阿联酋东南部油田的沉积面被解释为更远。在油田范围内,VPCs 未能确定碳酸盐岩的显著横向变化。然而,对取心油井的变异图分析表明,在斜坡域内部存在特定岩相的空间集中,这些岩相可与高能沉积体(如以芦苇碎屑为主的浅滩)相关联。这些沉积体从平面上看呈正弦曲线,长度可达 8 千米,宽度约为 1 千米。虽然在其他碳酸盐沉积系统中也曾发现过类似形状的岩体,但在哈赖卜地层中还没有发现过。在区域(油田间)范围内,标准化沉积面的地层关联仍然存在问题;然而,绘制面的关联及其相对于沉积环境的相对比例,为阿联酋 Kharaib-2 成员的地层结构展示了新的模式。
{"title":"FACIES PARTITIONING AT REGIONAL AND FIELD SCALES IN THE BARREMIAN KHARAIB-2 CARBONATES, UAE","authors":"Pierre Gatel,&nbsp;Jean Borgomano,&nbsp;Jeroen Kenter,&nbsp;Tarek Mecheri","doi":"10.1111/jpg.12869","DOIUrl":"https://doi.org/10.1111/jpg.12869","url":null,"abstract":"<p>Carbonates in the Lower Cretaceous (Barremian to early Aptian) Kharaib Formation are reservoir rocks at giant oil fields in the UAE and Qatar. The Barremian Kharaib-2 member (K60), the focus of this study, is in general composed of a regionally continuous succession of high-energy, shallow-water limestones bounded above and below by “dense” low-energy mud-rich strata. Despite several decades of research, conventional carbonate facies classification schemes and resulting facies groupings for the Kharaib-2 member have failed to show a statistically acceptable correlation with core- and log-derived petrophysical data. Moreover, sedimentary bodies potentially responsible for dynamic reservoir heterogeneities have not clearly been identified. This paper proposes a standardized facies classification scheme for the Kharaib-2 carbonates based on vertical facies proportion curves (VPCs) and variogram analyses of core data to construct stratigraphic correlations at both field and regional scales. Data came from 295 cored wells penetrating the Kharaib-2 member at ten fields in the on- and offshore UAE. Thin, dense intervals separating reservoir units were adopted as fourth-order transgressive units and were used for stratigraphic correlation. Field-scale probability maps were used to identify sedimentary bodies such as shallow-water rudistid shoals.</p><p>Regional stratigraphic correlations of the Kharaib-2 member carbonates based on the VPCs identified variations in depositional environments, especially for the lower part of the reservoir unit; depositional facies at fields in the SE of the UAE were interpreted to be more distal compared to those at offshore fields to the NW. At a field scale, the VPCs failed to identify significant lateral variations in the carbonates. However, variogram analyses of cored wells showed spatial concentrations of specific facies in the inner ramp domain which could be correlated with high-energy depositional bodies such as shoals dominated by rudist debris. The bodies were sinusoidal in plan view with lengths of up to 8 km and widths of ca. 1 km. Although similar-shaped bodies with these dimensions have been reported from other carbonate depositional systems, they have not previously been reported in the Kharaib Formation. At a regional (inter-field) scale, the stratigraphic correlation of standardized sedimentary facies remains problematic; however, mapping of facies associations and their relative proportions relative to their environments of deposition demonstrated new patterns for the stratigraphic architecture of the Kharaib-2 member in the UAE.</p>","PeriodicalId":16748,"journal":{"name":"Journal of Petroleum Geology","volume":"47 4","pages":"347-372"},"PeriodicalIF":1.8,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
STRATIGRAPHY AND DIAGENESIS OF THE THAMAMA-B RESERVOIR ZONE AND ITS SURROUNDING DENSE ZONES IN ABU DHABI OILFIELDS AND EQUIVALENT OMAN OUTCROPS 阿布扎比油田萨玛玛-B 储层带及其周边致密带和阿曼等效露头的地层学和成岩作用
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-23 DOI: 10.1111/jpg.12871
S. N. Ehrenberg, J. E. Neilson, E. Gomez-Rivas, N. H. Oxtoby, I.S.A.J. Jayachandran, Q. Adlan, V. C. Vahrenkamp

We review published studies characterizing the Thamama-B reservoir zone in the upper Kharaib Formation (late Barremian) in Abu Dhabi oilfields and at outcrops in Oman. Available data for oxygen and carbon isotope compositions, fluid inclusion measurements, cement abundance and formation water composition are interpreted in terms of a paragenetic model for the Thamama-B in field F in Abu Dhabi where the interval is deeply buried. The present synthesis provides a useful basis for understanding and predicting reservoir quality in static models and undrilled prospects, as well as for planning promising directions for further research. The goals of this study were to summarize the geologic setting and petrology of the Thamama-B reservoir and its surrounding dense zones, and to examine how sedimentology, stratigraphy and diagenesis have interacted to control porosity and permeability. Results that may have useful applications for similar microporous limestone reservoirs in general include:

我们回顾了已发表的关于阿布扎比油田和阿曼露头的上哈赖卜地层(巴里米亚晚期)Thamama-B 储层区特征的研究。根据阿布扎比 F 油田 Thamama-B 储层(该区间埋藏较深)的准成因模型,对有关氧和碳同位素组成、流体包裹体测量、水泥丰度和地层水组成的现有数据进行了解释。本综述为了解和预测静态模型和未钻探前景的储层质量以及规划有前景的进一步研究方向提供了有用的依据。本研究的目标是总结 Thamama-B 储层及其周边致密带的地质环境和岩石学,并研究沉积学、地层学和成岩作用如何相互作用控制孔隙度和渗透率。研究结果可用于类似的微孔石灰岩储层,包括:
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引用次数: 0
GEOCHEMICAL ANALYSES OF EOCENE OILS IN DEEPLY BURIED SANDSTONE RESERVOIRS IN THE DONGYING DEPRESSION, BOHAI BAY BASIN, NE CHINA 中国东北渤海湾盆地东营凹陷深埋砂岩储层中始新世石油的地球化学分析
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-23 DOI: 10.1111/jpg.12872
Xiaoxiao Zhou, Xiaojun Li, Xu Song, Yuzhi Li, Xuejun Wang, Ke Han, Haiqing Yan

We report the results of organic geochemical analyses of 19 crude oil samples from reservoir sandstones in the 4th Member of the Eocene Shahejie Formation from wells in the Minfeng Sag, Dongying Depression, Bohai Bay Basin (NE China). In addition, 42 Shahejie Formation core samples of dark-coloured mudstones, including 28 extracts, were analysed. Geochemical data included Rock-Eval measurements, gas chromatography, GC-MS and diamondoid analyses.

Maceral analyses showed that mudstones in the 4th Member of the Shahejie Formation (“Es4”) contain Types I and II1 kerogen. The member can be divided into upper (Es4s) and lower (Es4x) intervals. Oil-prone Es4s rock samples have good to excellent hydrocarbon-generating potential based on calculated initial TOC values; Rock-Eval Tmax values indicate that they are sufficiently mature for hydrocarbon generation. Analytical results suggest that both Es4s and Es4x mudrocks are potential source rocks for oils produced at fields in the Minfeng Sag.

Analysed crude oils from the Minfeng Sag were classified into three genetic groups. Group I oils are mature to highly mature and have undergone a moderate degree of thermal cracking. They are characterized by a low β-carotane/nC25 ratio and C30 4-methylsterane index (4MI); high values of oleanane index (oleanane /C30-hopane), C27 diasterane/C27 regular sterane (C27Dia/C27), regular sterane/17α hopane and gammacerane/C30 hopane (G/H); and medium pristane/phytane ratios (Pr/Ph). This suggests that Group I oils are mostly derived from source rocks in the upper part of the Es4x unit which are interbedded with evaporites. Group II oils are mature and have high 4MI and Pr/Ph ratios, low oleanane index, regular sterane/17α hopane and C27Dia/C27 ratios, and mediumβ-carotane/nC25 and G/H. These features are similar to those of Es4s source rocks, indicating their genetic correlation. Group III oils show the lowest maturity and highβ-carotane/nC25 and regular sterane/17α hopane, and low oleanane index, Pr/Ph and 4MI. Previously-published data indicates that oils similar to those in Group III were mainly sourced by Es4s mudstones.

我们报告了对渤海湾盆地东营凹陷民丰下陷油井中始新世沙河街地层第四系储层砂岩中 19 个原油样品的有机地球化学分析结果。此外,还分析了 42 个沙河街地层深色泥岩岩心样品,包括 28 个提取物。地球化学数据包括岩石评价测量、气相色谱、气相色谱-质谱和钻石样分析。宏观分析表明,沙河街地层第四系("Es4")泥岩含有 I 类和 II1 类角质。该层可分为上层(Es4s)和下层(Es4x)。根据计算得出的初始总有机碳值,易生油的 Es4s 岩石样本具有良好至卓越的碳氢化合物生成潜力;岩石-评价 Tmax 值表明,它们已足够成熟,可以生成碳氢化合物。分析结果表明,Es4s 和 Es4x 泥岩都是民丰沙格油田生产石油的潜在源岩。第一组为成熟至高度成熟的石油,经历了中等程度的热裂解。它们的特点是:β-胡萝卜烷/nC25 比率和 C30 4-甲基甾烷指数(4MI)较低;齐墩果烷指数(齐墩果烷/C30-桧烷)、C27 二甾烷/C27 普通甾烷(C27Dia/C27)、普通甾烷/17α 桧烷和加玛烷/C30 桧烷(G/H)的值较高;壬烷/phytane 比率(Pr/Ph)中等。这表明,I 组油主要来自 Es4x 单元上部与蒸发岩互层的源岩。第二组油成熟,具有较高的 4MI 和 Pr/Ph 比值、较低的齐墩果烷指数、规则的甾烷/17α 藿烷和 C27Dia/C27 比值以及中等的β-胡萝卜素/nC25 和 G/H。这些特征与 Es4s 源岩相似,表明它们之间存在遗传相关性。第 III 组油类的成熟度最低,β-胡萝卜素/nC25 和常规甾烷/17α 藿烷比率较高,齐墩果烷指数、Pr/Ph 和 4MI 较低。以前发表的数据表明,与第三组类似的油类主要来自 Es4s 泥岩。
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引用次数: 0
Index of editorial contents, JPG vol. 47, 2024 编辑内容索引,JPG 第 47 卷,2024 年
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-23 DOI: 10.1111/jpg.12875
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引用次数: 0
GEOCHEMISTRY OF OILS AND GASES FROM THE VERKHNECHONSKOYE FIELD, EAST SIBERIAN BASIN: APPLICATION OF ANALYTICAL RESULTS TO RESERVOIR CHARACTERISATION 东西伯利亚盆地韦尔赫内孔斯科伊油田油气地球化学:分析结果在储层特征描述中的应用
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-24 DOI: 10.1111/jpg.12865
N. V. Oblasov, I. V. Goncharov, I. V. Eftor, G. W. van Graas, M. A. Veklich, A. T. Akhmadishin, D. A. Lokshin

A geochemical study was carried out on oil and gas samples from the Verkhnechonskoye field, located on the Nepa-Botuoba Anteclise in the central-southern part of the Siberian Platform. The goal of the study was to distinguish between fluids derived from the V10-13 and B12 reservoir units in the Vendian (Neoproterozoic) Katanga and Nepa Formations and to identify the producing reservoir using geochemical data. The results of analyses of 12 oil and 13 associated gas samples from the two reservoirs showed that all the fluids have similar geochemical properties including: low Pr/Ph ratios (0.78-1.00); a predominance of C29 over C27 and C28 steranes; a predominance of odd-numbered C21-C25 n-alkylbenzenes over their even-numbered homologues; the presence of 12- and 13-methylalkanes; and a high relative abundance of tricyclic terpanes (cheilantanes). All these properties are consistent with those of the properties of petroleum from other fields on the Siberian Platform. The molecular and stable carbon isotope compositions of the oils and gases suggest that they were derived from marine organic matter with a high algal input deposited under reducing conditions. To date, specific source rocks which generated the oil and gas present at fields on the Nepa-Botuaoba Anteclise have not conclusively been identified, but potential candidates include the Upper Riphean Iremeken and Ayan Formations and more probably the Vendian Zherbinskaya, Seralakh, Vanavara and Nepa Formations.

The second part of the study demonstrates the application to reservoir geochemistry of C3- and C4- alkylbenzene compounds together with more conventional biomarkers. Key parameters were selected using statistical processing and displayed in graphic profiles. These profiles allowed the oil and gas samples to be classified according to the reservoir from which they were derived based on their geochemical properties. Parameters based on C3- and C4- alkylbenzene compounds were most effective in discriminating between oils from the two reservoirs. In addition, a new parameter is proposed based on the contents of 1-methyl-3-isopropylbenzene, 1-methyl-2-isopropylbenzene and 1-methyl-2-propylbenzene; this parameter correlates closely with the pristane/phytane ratio and can be used as an additional indicator of the level of oxicity in the source rock depositional environment.

对位于西伯利亚地台中南部 Nepa-Botuoba Anteclise 的 Verkhnechonskoye 油田的石油和天然气样本进行了地球化学研究。这项研究的目的是区分来自文迪岩(新近纪)加丹加地层和尼泊尔地层中 V10-13 和 B12 储层单元的流体,并利用地球化学数据确定生产储层。对这两个储油层中的 12 个石油样本和 13 个伴生天然气样本的分析结果表明,所有流体都具有类似的地球化学性质,包括:低镨/铽比值(0.78-1.00);主要为 C29 而非 C27 和 C28 立体烷烃;主要为奇数 C21-C25 正烷基苯而非偶数同族体;存在 12 和 13-甲基烷烃;三环萜类(cheilantanes)的相对丰度较高。所有这些特性与西伯利亚地台其他油田的石油特性一致。这些石油和气体的分子和稳定碳同位素组成表明,它们来自在还原条件下沉积的海洋有机物,其中藻类含量较高。迄今为止,在 Nepa-Botuaoba Anteclise 油气田生成石油和天然气的具体源岩尚未最终确定,但潜在的候选岩层包括上里普安期的 Iremeken 和 Ayan 地层,更可能是文登期的 Zherbinskaya、Seralakh、Vanavara 和 Nepa 地层。关键参数通过统计处理选出,并以图形剖面显示。通过这些剖面图,可以根据石油和天然气样本的地球化学特性,将其按照所来自的储层进行分类。基于 C3- 和 C4- 烷基苯化合物的参数对区分来自两个储层的石油最为有效。此外,还提出了一个基于 1-甲基-3-异丙基苯、1-甲基-2-异丙基苯和 1-甲基-2-丙基苯含量的新参数;该参数与pristane/phytane 比率密切相关,可用作源岩沉积环境中氧化程度的额外指标。
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引用次数: 0
Stratigraphic framework for Zechstein Carbonates on the Utsira High, Norwegian North Sea 挪威北海乌策拉高地泽赫斯坦碳酸盐岩的地层框架
IF 1.8 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-24 DOI: 10.1111/jpg.12867
Lars Stemmerik, Kasper H. Blinkenberg, Ingrid P. Gianotten, Malcolm S.W. Hodgskiss, Aivo Lepland, Päärn Paiste, Israel Polonio, Nicholas M.W. Roberts, Niels Rameil
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引用次数: 0
期刊
Journal of Petroleum Geology
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