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DEVELOPMENT OF FIBROUS CALCITE VEINS RELATED TO HYDROCARBON GENERATION AND OVERPRESSURING IN ORGANIC-RICH SHALE SOURCE ROCKS: THE VACA MUERTA FORMATION, NEUQUÉN BASIN, ARGENTINA 阿根廷neuquÉn盆地富有机质页岩烃源岩中与生烃和超压有关的纤维方解石脉发育
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-03-24 DOI: 10.1111/jpg.12814
J. B. Spacapan, M. Comerio, R. Ruiz, E. Rocha

Fibrous calcite bed-parallel veins (BPVs) are a typical feature of the Upper Jurassic – Lower Cretaceous Vaca Muerta Formation in the subsurface of the Neuquén Basin (Argentina). The formation is considered to be the main source rock in the basin as well as an important unconventional play. This study examines the growth of BPVs through an analysis of core from three wells located along a transect extending for some 150 km from the NE Platform near the basin margin in the east to the Agrio fold-and-thrust belt at the Andean deformation front in the west. The main objective is to integrate fluid inclusion data with the palaeothermal and palaeopresure evolution obtained from a regional-scale 2D basin and petroleum systems model to examine the timing of fracture development and its relationship with hydrocarbon generation in the Vaca Muerta Formation through time.

The apertures of BPVs were measured in more than 360 m of core from three wells (wells A, D and E). This data was combined with optical petrography to investigate the number of calcite cementation events, and the temperature of cement precipitation based on fluid inclusion data. The organic geochemical and mineralogical characteristics of the Vaca Muerta source rock were also analysed. The integrated results were incorporated into a poro-elastic basin model to investigate the impact of horizontal shortening due to Andean compression on pore pressure development and fracturing in the Vaca Muerta Formation. This framework allowed the timing of BPV formation to be determined together with possible mechanisms governing overpressure conditions through time.

Near the Andean deformation front in the west of the modelled section where the Vaca Muerta Formation is in the wet gas window (well D) and dry gas window (well A), BPVs are characterized by two or more generations of calcite fibres indicating multiple growth phases. Calcite which precipitated during cementation event 1 (E1) in the internal zones of BPVs consists of crystals oriented perpendicular to fracture walls, indicating perpendicular vein opening. Calcite precipitated during cementation event 2 (E2) in the outer zones of BPVs includes curved and oblique crystals. During this phase, shear occurred between the opening vein walls as a result of horizontal shortening. Cementation event 3 (E3) is characterized by an equant mosaic of calcite crystals which preserve intracrystalline porosity. E1cements formed between 110 and 90 Ma with trapping temperatures of ∼112 °C (upper Vaca Muerta, well A) and ∼125 °C (lower Vaca Muerta, well D). Fracturing resulted from disequilibrium compaction and from volumetric expansion due to primary cracking of kerogen within the oil window. E2 cements record a trapping temperature of ∼159 °C and formed between 70 and 55 Ma (lower Vaca Muerta, well D) during maximum burial of the Vaca Muerta Formation, synchronous with the secondary cracking of retained liquid hydrocarbons and the beginning of An

纤维状方解石床-平行脉是阿根廷neuqu盆地上侏罗统—下白垩统Vaca Muerta组地下的典型特征。该组被认为是盆地的主要烃源岩,也是重要的非常规油气藏。本研究通过对三口井的岩心进行分析,研究了bpv的生长情况。三口井位于一条横断面上,横断面从东部靠近盆地边缘的NE平台延伸到西部安第斯变形前沿的Agrio褶皱冲断带,全长约150公里。主要目的是将流体包裹体数据与区域尺度二维盆地和含油气系统模型获得的古热、古压演化相结合,研究Vaca Muerta组裂缝发育的时间及其与生烃的关系。在3口井(A、D和E井)超过360 m的岩心中测量了bpv的孔径,并将这些数据与光学岩石学相结合,研究方解石胶结事件的数量,以及基于流体包裹体数据的水泥沉淀温度。分析了瓦卡穆尔塔烃源岩的有机地球化学和矿物学特征。将综合结果整合到孔隙弹性盆地模型中,研究安第斯山脉压缩导致的水平缩短对Vaca Muerta组孔隙压力发育和压裂的影响。该框架允许确定BPV形成的时间以及随时间推移控制超压条件的可能机制。在模拟剖面西部的安第斯变形前缘附近,Vaca Muerta组处于湿气窗(D井)和干气窗(A井),BPVs的特征是两代或更多的方解石纤维,表明了多个生长阶段。胶结事件1 (E1)在bpv内部区域析出的方解石由垂直于裂缝壁取向的晶体组成,表明垂直的矿脉开口。胶结事件2 (E2)在bpv外区析出的方解石包括弯曲晶体和斜晶。在这一阶段,由于水平缩短,开放的脉壁之间发生了剪切。胶结事件3 (E3)的特征是方解石晶体的均匀镶嵌,保留了晶内孔隙度。胶结物形成于110 ~ 90 Ma之间,圈闭温度为~ 112°C (Vaca Muerta上部A井)和~ 125°C (Vaca Muerta下部D井)。压裂是由不平衡压实和油窗内干酪根初次裂解引起的体积膨胀造成的。E2胶结物记录的圈闭温度为~ 159℃,形成于70 ~ 55 Ma之间(Vaca Muerta下部D井),是Vaca Muerta组最大埋藏期,与残留液态烃的二次裂解和安第斯山脉压缩的开始同步。E3胶结物(Vaca Muerta上部A井)的圈闭温度为~ 162℃,形成于65 ~ 53 Ma之间,与热成因气的生成同步。相比之下,在neuqun盆地变形较小的前陆区东部,Vaca Muerta组处于早期油窗(E井),bpvv由单代方解石纤维(E1)组成,捕获温度为~ 118°C。E1胶结物的特征是方解石晶体垂直于裂缝壁取向,无剪切作用。根据模型模拟,胶结作用发生在最大埋藏期的64 ~ 53 Ma之间,与不平衡压实作用和干酪根初步转化成油的超压作用有关。研究结果表明,在Vaca Muerta组的某些层段,TOC含量的轻微增加伴随着脉体厚度的增加,胶结事件发生在研究区西部的安第斯形变前缘,而东部的前陆相对较多。
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引用次数: 2
TECTONOSTRATIGRAPHIC EVOLUTION AND HYDROCARBON PROSPECTIVITY SOUTH OF GWADAR BAY, MAKRAN ACCRETIONARY WEDGE, OFFSHORE SW PAKISTAN 巴基斯坦西南部近海makran增生楔瓜达尔湾南部构造地层演化及油气远景
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-03-24 DOI: 10.1111/jpg.12812
Conall Cromie, Nicola Scarselli, Jonathan Craig, Moin R. Khan, Abid Hussain

The Makran accretionary wedge developed as a result of subduction of the Arabian Plate beneath the southern margin of Eurasia since the Eocene. Interpretation of 2D seismic profiles calibrated to offshore well data in a study area to the south of Gwadar Bay (SW Pakistan) indicates a major period of accretion from the mid-Miocene, as evidenced by the occurrence of thick growth strata associated with large-scale imbricate thrusts. The thrust faults originate from a deep detachment within the mud-rich Oligocene interval, and well-developed piggy-back basin successions occur in thrust hanging walls. In the study area, the thrust structures are sealed by a thick, progradational Pliocene to Recent interval in which the presence of submarine canyons, up to 2.5 km across, indicate that sedimentary transport was from the north.

Fluid escape pipes and associated amplitude anomalies are observed in the seismic profiles studied and may be related to upward migration of thermogenic hydrocarbons from depth, as heavy hydrocarbon fractions <C3 have been reported from nearby wells. The hydrocarbons are believed to have been sourced from the Oligocene Hoshab Shale and to have then migrated up through a sedimentary succession in which permeability barriers are largely absent. Hanging wall anticlines mapped in the study area could provide structural traps, and turbidites in the Lower Miocene Panjgur Formation may represent a potential reservoir. Amplitude anomalies are also observed adjacent to shallow fluid escape pipes within the topsets of clinoforms in the Pleistocene Chatti and Omara Formations, and probably indicate the presence of biogenic hydrocarbons sourced from distal mudstones in bottomset strata.

马克兰增生楔是始新世以来阿拉伯板块向欧亚大陆南缘俯冲的结果。在瓜达尔湾南部(巴基斯坦西南部)的一个研究区域,根据海上油井数据校准的二维地震剖面解释表明,中新世中期开始出现了一个主要的增生时期,这一点可以从与大规模叠瓦状逆冲相关的厚生长地层中得到证明。逆冲断层起源于富泥渐新世段的深部拆离,逆冲上盘发育发育良好的背带盆地序列。在研究区,冲断构造被上新世至新近的厚层前积层封住,其中海底峡谷的存在,直径达2.5公里,表明沉积是从北方运来的。在研究的地震剖面中观察到流体逸出管和相关振幅异常,可能与深部热生烃向上运移有关,因为在附近的井中报告了重烃馏分<C3。据信,这些碳氢化合物来自渐新世Hoshab页岩,然后通过沉积演替向上运移,其中渗透率障碍基本上没有。研究区上盘背斜可提供构造圈闭,下中新统潘杰古尔组浊积岩可能是潜在储层。在更新世Chatti组和Omara组斜形顶部组中,在浅层流体逸出管附近也观察到振幅异常,这可能表明底部地层中存在来自远端泥岩的生物烃。
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引用次数: 0
NEOCOMIAN – BARREMIAN LACUSTRINE SHALES IN THE MAYO OULO-LERE BASIN, NORTH CAMEROON: DEPOSITIONAL ENVIRONMENT AND PETROLEUM POTENTIAL 喀麦隆北部梅奥奥勒盆地新新纪—巴雷米亚湖相页岩:沉积环境与油气潜力
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-03-24 DOI: 10.1111/jpg.12813
Bachirou Mfayakouo Chavom, François Baudin, Josiane F. Kwéa Nzouedjio, Johann Schnyder, Aicha Maloum, Serge Edouard Angoua Biouélé

The synrift Mayo Oulo-Léré Basin in Northern Cameroon is located in the transition zone between the West and Central African Rift Systems. Structural and stratigraphic elements of the basin resemble those of the Yola Basin in NE Nigeria, an extension of the Upper Benue Trough. The Lower Cretaceous lacustrine shales with source rock potential which occur in nearby rift basins are also present in the Mayo Oulo-Léré Basin. These shales were investigated at two outcrop locations (Badesi and Tchontchi), and samples collected (n = 60) were subjected to palynofacies and bulk geochemical analyses to evaluate their petroleum generation potential and to interpret their depositional environment. At the studied locations, shales were divided into two lithofacies: grey to black laminated shales containing algal-bacterial OM together with common woody (phytoclast) debris (“facies Fml”); and cm-bedded shales which had a higher content of algal-bacterial OM but a lower phytoclast content (“facies Fmlc”).

Palynological and bulk geochemical data indicate that the shales contain well-preserved organic matter (OM) and locally display good to excellent oil generation potential. Average TOC contents are 2.7% and 1.4% for samples of the Fmlc and Fml facies shales respectively. HI values (94-889 mg HC/g TOC and 131-638 mg HC/g TOC respectively) suggest that the shales contain Types I to III kerogen. Organic material in the Fmlc facies shales is dominated by amorphous organic matter (AOM: 90% on average) with a low phytoclast content (6% on average); whereas samples of the Fml facies shales contain less AOM (74% on average) and have a higher phytoclast content (23% on average). AOM in the Fmlc shales is highly fluorescent; these shales are interpreted to have been deposited in dysoxic to anoxic conditions. The AOM in the Fml shales is weakly fluorescent and the shales were deposited under more oxic conditions. The kerogen in the shales ranges from immature to early oil window mature. Average values of the pyrolysis S2 yield are 15.5 mg HC/g of rock and 7 mg HC/g of rock for samples from Fmlc and Fml facies shales respectively. The shales increase in thickness northwards towards the Logone Birni Basin where they may have reached the oil window, as in neighbouring basins. The results of this study of lacustrine shales from the Mayo Oulo-Léré Basin suggests that there may be potential for oil exploration in northern Cameroon.

喀麦隆北部的梅奥-奥罗-拉西姆盆地位于西非裂谷系和中非裂谷系之间的过渡地带。盆地的构造和地层元素类似于尼日利亚东北部的约拉盆地,是上贝努埃海槽的延伸。下白垩统湖相页岩存在于裂谷盆地附近,具有烃源岩潜力。研究人员在两个露头位置(Badesi和Tchontchi)对这些页岩进行了调查,并收集了60个样品,进行了孢粉相和整体地球化学分析,以评估其生油潜力并解释其沉积环境。在研究地点,页岩被划分为两个岩相:灰色至黑色层状页岩,含有藻-细菌OM和常见的木质(植物碎屑)碎屑(“相Fml”);cm层状页岩,藻-细菌有机质含量较高,而植物碎屑含量较低(“Fmlc相”)。孢粉学和整体地球化学数据表明,页岩中有机质保存较好,局部具有良好至极好的生油潜力。Fmlc和Fml相页岩样品TOC平均含量分别为2.7%和1.4%。HI值(94 ~ 889 mg HC/g TOC和131 ~ 638 mg HC/g TOC)表明页岩含ⅰ~ⅲ型干酪根。Fmlc相页岩有机质以无定形有机质为主(平均AOM为90%),植物碎屑含量较低(平均6%);而Fml相页岩样品的AOM含量较少(平均74%),植物碎屑含量较高(平均23%)。Fmlc页岩中的AOM具有高荧光性;这些页岩被解释为在缺氧或缺氧条件下沉积的。Fml页岩中的AOM具有弱荧光,且页岩沉积在较强的氧化条件下。页岩的干酪根处于未成熟-早期油窗成熟阶段。Fmlc和Fml相页岩的热解S2产率平均值分别为15.5 mg HC/g和7 mg HC/g。在Logone Birni盆地北部,页岩厚度增加,在那里它们可能到达了油窗,就像在邻近的盆地一样。这项对Mayo oulo - l 盆地湖相页岩的研究结果表明,喀麦隆北部可能存在石油勘探的潜力。
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引用次数: 0
A NEW OIL SEEPAGE IN THE OMAN MOUNTAINS AND ITS GEOLOGICAL, GEOCHEMICAL AND PETROLEUM SYSTEMS CONTEXT 阿曼山区一次新的石油渗流及其地质、地球化学和石油系统背景
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12805
M. Al Kindi, M. Al-Ghammari, A. Heward, P. Taylor, G. Siavalas
A minor natural oil seepage is described from an unlikely setting in the Oman Mountains. The host rocks are fractured pelagic limestones of the lower member of the Triassic – Lower Jurassic Matbat Formation of the Hamrat Duru Group in the lower part of the allochthonous Hawasina Complex. This paper summarises Oman's established oil families and documents previously recorded oil seepages as context for describing the new seepage, its geochemistry, and possible source rock. The seep oil is different to those known from Oman's oil fields and probably derived from a poor quality, Mesozoic clastic source rock containing a mix of terrigenous and marine organic matter. The most likely source appears to be the Toarcian turbiditic upper member of the Matbat Formation, equivalent to the clastic Mafraq Formation of the Arabian Platform. The occurrence of source rocks in the allochthonous sediments of the NeoTethyan Hawasina Basin has been suspected previously, though their commercial significance remains to be established.
阿曼山脉的一处不太可能的环境中出现了轻微的天然石油渗漏。寄主岩石为异地Hawasina杂岩下部Hamrat-Duru群三叠纪-下侏罗系Matbat组下部的破碎远洋石灰岩。本文总结了阿曼已建立的石油家族和先前记录的石油渗漏文件,作为描述新渗漏、其地球化学和可能的烃源岩的背景。渗油与阿曼油田的渗油不同,可能来源于质量较差的中生代碎屑烃源岩,其中含有陆源和海洋有机质的混合物。最可能的来源似乎是Matbat组的Toarcian浊积上段,相当于阿拉伯地台的碎屑Mafraq组。尽管其商业意义尚待确定,但先前曾怀疑新特提斯-哈瓦西纳盆地异地沉积物中存在烃源岩。
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引用次数: 2
Issue Information 问题信息
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12787
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引用次数: 0
BIOMARKER GEOCHEMISTRY OF PALEOGENE CRUDE OILS AND SOURCE ROCKS FROM THE RAOYANG SAG, BOHAI BAY BASIN, NE CHINA: AN OIL – SOURCE ROCK CORRELATION STUDY 渤海湾盆地饶阳凹陷古近系原油及烃源岩生物标志物地球化学油源岩对比研究
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12807
S.-H. Su, Youlu Jiang
This study presents a systematic geochemical analysis of Paleogene crude oils and source rocks from the Raoyang Sag in the Jizhong sub‐basin of the Bohai Bay Basin (NE China). The geochemical characteristics of fifty‐three oil samples from wells in four sub‐sags were analysed using gas chromatography (GC) and gas chromatography – mass spectrometry (GC‐MS). Twenty core samples of mudstones from Members 1 and 3 of the Eocene‐Oligocene Shahejie Formation were investigated for total organic carbon (TOC) content and by Rock‐Eval pyrolysis and GC‐MS to study their geochemistry and hydrocarbon generation potential. The oils were tentatively correlated to the source rocks.
本文对渤海湾盆地冀中盆地饶阳凹陷古近系原油和烃源岩进行了系统的地球化学分析。采用气相色谱(GC)和气相色谱-质谱(GC - MS)分析了4个亚凹陷井中53个油样的地球化学特征。摘要对始新统—渐新统沙河街组一段和三段20份泥岩岩心样品进行了总有机碳(TOC)含量测定,并通过岩石热解和气相色谱-质谱分析研究了泥岩的地球化学特征和生烃潜力。初步将油与烃源岩进行了对比。
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引用次数: 1
GEOCHEMICAL COMPOSITION OF ORDOVICIAN OILS FROM THE TUOPUTAI REGION, NORTHERN TARIM BASIN, NW CHINA: SOURCE ROCK CORRELATION 塔北托普台地区奥陶系原油地球化学组成及烃源岩对比
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12809
B. Cheng, Hua Liu, Xian Wu, Shen Wang, Zepeng Wu
Molecular and stable carbon isotope compositions of 46 Ordovician crude oil samples from wells in the Tuoputai region of the northern Tarim Basin were investigated using GC–MS, MRM GC–MS and IRMS to determine their genetic relationships and to identify possible source rocks. Thirty‐three source rock samples from outcrops and cores were also investigated. The oil samples varied from light to heavy crudes and showed very narrow δ13C value ranges for the whole oil, saturated and aromatic fractions. The majority of the oils displayed very similar molecular compositions with relatively high concentrations of n‐alkanes and isoprenoids and low concentrations of terpenoids and steroids. Comparison of the compositions of these crude oils strongly suggested their genetic affinity, while maturity parameters indicated maturity variations from the peak to the late oil generation stages. The samples also showed the characteristics of mixtures of biodegraded and fresh oil charges.
采用GC–MS、MRM GC–MS和IRMS方法,对塔北沱蒲台地区46口奥陶系原油样品的分子和稳定碳同位素组成进行了研究,确定了它们的成因关系,并确定了可能的烃源岩。还调查了来自露头和岩芯的三十三个源岩样本。油样从轻质原油到重质原油各不相同,全油、饱和馏分和芳香馏分的δ13C值范围非常窄。大多数油显示出非常相似的分子组成,具有相对高浓度的正烷烃和类异戊二烯,以及低浓度的萜类和类固醇。对这些原油成分的比较有力地表明了它们的遗传亲和力,而成熟度参数表明了从石油生成高峰期到晚期的成熟度变化。这些样品还显示了生物降解和新鲜油装药混合物的特征。
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引用次数: 0
STRATIGRAPHIC CORRELATION AND SOURCE ROCK CHARACTERISTICS OF THE BALUTI FORMATION FROM SELECTED WELLS IN THE ZAGROS FOLD BELT, KURDISTAN REGION, NORTHERN IRAQ 伊拉克北部库尔德斯坦地区扎格罗斯褶皱带选井巴鲁提组地层对比及烃源岩特征
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12806
I. Mohialdeen, Sardar S. Fatah, Rzger Abdula, M. Hakimi, W. Abdullah, P. Khanaqa, G. Lunn
The Upper Triassic Baluti Formation has been identified and mapped based on its log response in selected wells from the Zagros foldbelt in the Kurdistan Region of northern Iraq. A preliminary evaluation of the formation's source rock potential was made by Rock‐Eval screening analysis in four wells along a NW‐SE profile (Atrush‐1, Shaikan‐5B, Taq Taq‐22 and Miran‐2) with maturity determined from reflectance measurements in samples from well Taq Taq‐22. The Baluti Formation consists of thinly interbedded shales, carbonates and anhydrite ranging in thickness from 48 m in well Atrush‐1 to 118 m in well Miran‐2. The Rock‐Eval screening was conducted primarily on bulk cuttings samples plus selected picked cuttings. The TOC content is low to moderate (0.23 to 1.14 wt%). However, the shale content in many of the analysed bulk samples was relatively low, making assessment of the source potential problematic. The highest TOCs are recorded from the thickest analysed sections from wells Miran‐2 and Taq Taq‐22, where high‐gamma bituminous shales are present. Rock‐Eval Tmax values ranging from 295 to 438°C are not consistent with estimates of pre‐Zagros burial to depths of between 4600 m (Atrush‐1) and 6900 m (Miran‐2). The relatively low Tmax values suggest that the S2 response does not reflect kerogen pyrolysis in these samples and may be due to the presence of solid bitumen, which is observed in the Baluti Formation in at least three of the study wells (Taq Taq‐22, Miran‐2 and Shaikan‐5B). Little pyrolysable organic matter remains in the formation due to the interpreted deep pre‐Zagros burial and the consequent high maturity in Taq Taq‐22 (VR = 1.51%Ro) and Miran‐2 (estimated VR >2%Ro), and the poor source character in Atrush‐1 and Shaikan‐5B. Organic petrography suggests the presence of vestiges of Types I and II kerogen in Taq Taq‐22, with bitumen observed as stains in the matrix of the shales and also in the pores and fractures of interbedded dolostones. However, bitumen reflectance determinations for Taq Taq‐22 indicate an equivalent vitrinite reflectance maturity of no more than 0.93%Ro, which is significantly less than that of the indigenous vitrinite, implying the solid bitumen in this well is derived primarily from migrated hydrocarbons. Further detailed analysis is required, but the results suggest that the Baluti Formation may have sourced hydrocarbons in its depocentre which is identified in this study as covering a NW‐SE trending area between Bekhme and Sangaw.
根据伊拉克北部库尔德斯坦地区Zagros褶皱带选定井的测井响应,已确定并绘制了上三叠统Baluti组。通过沿NW‐SE剖面的四口井(Atrush‐1、Shaikan‐5B、Taq Taq‐22和Miran‐2)的岩石蒸发筛选分析,对地层的烃源岩潜力进行了初步评估,成熟度由Taq Taq-22井样品的反射率测量确定。Baluti组由薄互层页岩、碳酸盐和硬石膏组成,厚度从Atrush-1井的48 m到Miran-2井的118 m不等。岩石蒸发筛选主要针对大块岩屑样本和选定的岩屑。TOC含量为低至中等(0.23至1.14wt%)。然而,许多分析的散装样品中的页岩含量相对较低,这使得对来源潜力的评估存在问题。Miran‐2井和Taq Taq‐22井最厚的分析剖面记录了最高的TOC,其中存在高伽马沥青页岩。295至438°C范围内的岩石蒸发Tmax值与Zagros前埋深4600 m(Atrush-1)至6900 m(Miran-2)的估计值不一致。相对较低的Tmax值表明,S2响应并不反映这些样品中的干酪根热解,可能是由于存在固体沥青,在至少三口研究井(Taq Taq‐22、Miran‐2和Shaikan‐5B)的Baluti地层中观察到了固体沥青。由于解释的扎格罗斯前深埋藏以及Taq Taq‐22(VR=1.51%Ro)和Miran‐2(估计VR>2%Ro)的高成熟度,以及Atrush‐1和Shaikan‐5B的不良来源特征,地层中几乎没有可热解有机物残留。有机岩石学表明,Taq Taq‐22中存在I型和II型干酪根遗迹,在页岩基质以及夹层白云岩的孔隙和裂缝中观察到沥青作为污渍。然而,Taq Taq‐22的沥青反射率测定表明,等效镜质组反射率成熟度不超过0.93%Ro,明显低于原生镜质组的成熟度,这意味着该井中的固体沥青主要来源于迁移的碳氢化合物。需要进一步的详细分析,但结果表明,巴鲁提组的沉积中心可能有碳氢化合物来源,该沉积中心在本研究中被确定为覆盖Bekhme和Sangaw之间的西北-东南走向区域。
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引用次数: 2
SEVERE BIODEGRADATION OF CRUDE OILS FROM THE QUIRIQUIRE FIELD, EASTERN VENEZUELAN BASIN 委内瑞拉东部盆地quiriquire油田原油严重生物降解
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12808
Liliana López, Jesús A. Romero, Salvador Lo Mónaco
Five crude oil samples from the Quiriquire field (Maturin sub‐basin, Eastern Venezuelan Basin) were analysed to evaluate their levels of biodegradation. The oils were obtained from coarse sandstones and conglomerates of the Pliocene Quiriquire Formation at depths <1000 m. Analyses of the samples’ bulk physicochemical parameters indicate variations in API gravity and in the content of saturated hydrocarbons and NSO+asphaltenes, and also in the saturate/aromatic ratio which increases in more biodegraded oils. n‐Alkane distributions are characterized by a dominant unresolved complex mixture (UCM) or hump under an envelope of peaks which lack the acyclic isoprenoids pristane and phytane. The alteration of steranes and terpanes together with the presence of 25‐norhopanes and 17‐nor‐tricyclic terpanes, and the alteration of low molecular‐weight (C20‐C21) triaromatic steroids, phenanthrene, methyl‐phenanthrene, dibenzothiophene and methyl‐dibenzothiophene, indicate that the oils have undergone severe biodegradation.
对来自Quiriquire油田(委内瑞拉东部Maturin盆地)的5个原油样本进行了分析,以评估其生物降解水平。这些原油来自深度<1000 m的上新世基上组的粗砂岩和砾岩。样品的整体物理化学参数分析表明,API比重、饱和烃和NSO+沥青质的含量以及生物降解程度越高的饱和烃/芳烃比都发生了变化。正构烷烃分布的特征是一个主要的未解复杂混合物(UCM)或峰包络下的驼峰,缺乏无环类异戊二烯和植烷。甾烷和萜烷的变化,以及25 -去藿烷和17 -非三环萜烷的存在,以及低分子量(C20 - C21)三芳甾体、菲、甲基菲、二苯并噻吩和甲基二苯并噻吩的变化,表明油经历了严重的生物降解。
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引用次数: 0
SOURCE ROCK EVALUATION AND BASIN MODELLING IN THE GORGAN PLAIN, SE SOUTH CASPIAN BASIN, NORTHERN IRAN 伊朗北部CASPIAN盆地东南部GORGAN平原烃源岩评价与盆地建模
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-09-29 DOI: 10.1111/jpg.12802
A. Zeinalzadeh, M. Sharafi, M. Mirshahani, A. Shirzadi
Hydrocarbon exploration in the Gorgan Plain to the SE of the South Caspian Basin (northern Iran) has taken place since the 1960s but no economic resources of petroleum have yet been discovered in this area and few studies of potential source rocks have been carried out. In this study, the generation potential and thermal maturity of potential Cenozoic source rocks are investigated on the basis of Rock‐Eval analyses of core and cuttings samples and organic petrographic observations. Hydrocarbon generation, migration and entrapment are evaluated from 2D basin modelling along two seismically‐derived profiles, oriented east‐west and north‐south across the Gorgan Plain area. The models used input data from ten wells.
自20世纪60年代以来,在南里海盆地(伊朗北部)东南部的戈尔干平原进行了油气勘探,但尚未发现石油的经济资源,潜在烃源岩的研究也很少。在岩心、岩屑样品岩石评价分析和有机岩相观察的基础上,研究了潜在新生代烃源岩的生烃潜力和热成熟度。通过沿两条地震衍生剖面的二维盆地建模,对Gorgan平原区的东西方向和南北方向的生烃、运移和圈闭进行了评价。这些模型使用了10口井的输入数据。
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引用次数: 3
期刊
Journal of Petroleum Geology
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