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GEOCHEMISTRY AND CARBON ISOTOPE CHARACTERISTICS OF ASSOCIATED GASES FROM OILFIELDS IN THE NW GREATER CAUCASUS, RUSSIA 俄罗斯新大高加索地区油田伴生气的地球化学和碳同位素特征
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-06-23 DOI: 10.1111/jpg.12822
N. Oblasov, I. Goncharov, A. Derduga, I. Kunitsyna
The NW Greater Caucasus and surrounding areas have a long history of petroleum production dating back to the mid‐19th century. However the origin of the oil and gas is still a matter of debate. This paper focusses on a study area to the north of the western Greater Caucasus covering the West and East Kuban Basins and neighbouring structural highs where oil and natural gas occur in reservoir units of Neogene, Paleogene, Cretaceous and Jurassic ages. The study is based on the results of organic geochemical and stable carbon isotope analyses of 21 samples of associated gases from 16 oil fields. The gas samples' compositions were investigated together with the δ13C values of C1 to C5 alkanes. Twenty of the gas samples were of thermogenic origin and one was mixed (thermogenic and secondary microbial). δ13C values for CH4 for all the gas samples varied over a wide range from ‐62.3 to ‐30.0 ‰, indicating major variations in the thermal maturity of the respective source rocks.
大高加索西北部及其周边地区的石油生产历史悠久,可以追溯到19世纪中期。然而,石油和天然气的来源仍然存在争议。本文重点研究了大高加索西部以北的一个研究区,该研究区涵盖了库班盆地西部和东部以及邻近的构造高点,在这些构造高点中,石油和天然气分布在第三纪、古近纪、白垩纪和侏罗纪的储层单元中。该研究基于对16个油田21个伴生气样品的有机地球化学和稳定碳同位素分析结果。研究了气体样品的组成以及C1至C5烷烃的δ13C值。其中20个气体样品来源于产热性,1个混合(产热性和次生微生物)。所有天然气样品的CH4δ13C值在-62.3‰至30.0‰的大范围内变化,表明各烃源岩的热成熟度存在重大变化。
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引用次数: 2
COMPOSITION OF LIGHT HYDROCARBONS IN JURASSIC TIGHT OILS IN THE CENTRAL SICHUAN BASIN, CHINA: ORIGIN AND SOURCE ROCK CORRELATION 川中侏罗系致密油轻烃组成与烃源岩对比
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-03-24 DOI: 10.1111/jpg.12811
Xiaolin Lu, Meijun Li, Tengqiang Wei, Changjiang Wu, Youjun Tang, Xiaojuan Wang, Haitao Hong, Yuan Liu, Zichao Ran

Crude oil reserves in tight Middle and Lower Jurassic reservoirs are of increasing exploration interest in the central Sichuan Basin, SW China. However, the origin of these “tight oils” is poorly understood. In this study, sixteen samples of light oils/condensates from tight Middle and Lower Jurassic reservoir rocks were analysed using gas chromatography (GC) and isotope ratio mass spectrometry to investigate the oils’ origin and to classify them into genetic families. The tight oils can be divided into two families. Family I oils occur in the Gongshanmiao oilfield where reservoir units comprise the Da'anzhai Member of the Lower Jurassic Ziliujing Formation, the Lower Jurassic Lianggaoshan Formation, and the First Member of the Middle Jurassic Shaximiao Formation. Family I oils are characterized by relatively low values of the methylcyclohexane (MCH) and cyclohexane (CH) indexes, low values of Mango's parameter K2 for light hydrocarbon composition, and relatively negative δ13C values ranging from -30.8‰ to -28.9‰. Family I oils are inferred to be self-sourced by lacustrine shales in the Da'anzhai Member and the Lianggaoshan Formation in the study area, both of which are rich in sapropelic organic matter. These source rocks also charged reservoirs in the First Member of the Shaximiao Formation. By contrast, the newly discovered Family II oils, which occur at the Jinhua oilfield and the as-yet undeveloped Qiulin and Bajiaochang structures, are reservoired in the Second Member of Shaximiao Formation. Family II oils have higher values of the MCH index, CH index and Mango's K2 parameter, and δ13C values varying from -27.5‰ to -25.4‰. These oils have similar light hydrocarbon compositions and δ13C values to oils derived from source rocks in the Upper Triassic Xujiahe Formation which contain dominantly humic organic matter. Family II oils are therefore inferred to be derived from the coaly mudstones in the Xujiahe Formation.

The different compositions of the tight oils in the First and Second Members of the Shaximiao Formation appear to be controlled by the distribution and thickness of source rocks in the study area. Thus, the Gongshanmiao oilfield where Family I oils occur in the First Member is close to the depocentre of source rocks in the Da'anzhai Member and Lianggaoshan Formation. These source rocks are inferred to have charged the First Member reservoirs which may also be present in nearby oil- and gas-bearing structures such as Nanchong and Yingshan. By contrast, Family II oils occur in tight reservoirs in the Second Member in areas with thick successions of Upper Triassic Xujiahe Formation mudstone source rocks, such as the Jinhua oilfield. In areas where both source rocks are present such as the Zhongtaishan and Lianchi oilfields, Shaximiao Formation reservoirs appear to contain both Family I and Family II oils.

四川盆地中部中、下侏罗统致密储层原油储量日益成为勘探热点。然而,人们对这些“致密油”的起源知之甚少。本文利用气相色谱和同位素质谱技术对中下侏罗统致密储层中的16个轻质油/凝析油样品进行了分析,探讨了油类的成因,并对其进行了科系划分。致密油可分为两大类。公山庙油田产一族油,储层单元包括下侏罗统自流井组大安寨段、下侏罗统梁高山组和中侏罗统沙溪庙组一段。ⅰ族原油具有甲基环己烷(MCH)和环己烷(CH)指数较低、轻烃组成Mango参数K2值较低、δ13C值相对负(-30.8‰~ -28.9‰)的特征。研究区大安寨段和两高山组湖相页岩自源ⅰ族油,均富含腐泥有机质。这些烃源岩在沙溪庙组一段也充注了储层。金华油田和尚未开发的秋林构造、八角场构造中新发现的II族油则集中在沙溪庙组二段。ⅱ族油的MCH指数、CH指数和Mango K2参数值较高,δ13C值在-27.5‰~ -25.4‰之间。这些油的轻烃组成和δ13C值与以腐殖质有机质为主的上三叠统须家河组烃源岩油相似。据此推断,ⅱ族油来源于须家河组煤质泥岩。研究区沙溪庙组一段和二段致密油的不同组成似乎受烃源岩分布和厚度的控制。因此,产一组油的公山庙油田与大安寨段和两高山组烃源岩的沉积中心较为接近。这些烃源岩被推断为充注了一段储层,这些储层也可能存在于附近的南充、英山等含油气构造中。在上三叠统须家河组泥岩烃源岩层序较厚的地区,如金华油田,二段致密储层发育ⅱ族油。在中台山油田、莲池油田等两种烃源岩同时存在的地区,沙溪庙组储集层既含ⅰ族油,也含ⅱ族油。
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引用次数: 1
SEQUENCE STRATIGRAPHY, PALAEOGEOGRAPHY AND PETROLEUM PLAYS OF THE CENOMANIAN – TURONIAN SUCCESSION OF THE ARABIAN PLATE: AN UPDATED SYNTHESIS 阿拉伯板块塞诺曼尼亚-图尔尼世演替的层序地层学、古地理和含油气油气藏:更新综合
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-03-24 DOI: 10.1111/jpg.12810
A. D. Bromhead, F.S.P. van Buchem, M.D. Simmons, R.B. Davies
In order to facilitate the search for new play concepts and exploration opportunities, a sequence stratigraphic synthesis of the Cenomanian–Turonian interval of the Arabian Plate has been compiled. The synthesis is based on published datasets which have been analysed within a temporal framework constrained by biostratigraphy and isotope stratigraphy. The high stratigraphic resolution allows the palaeogeography of the study area to be mapped within 3rd order depositional sequences, and the relative influence of eustacy and tectonics on basin development to be evaluated. This significantly improves the prediction of stratigraphic architecture and depositional morphology at the scale of the entire tectonic plate.
为了寻找新的油气藏概念和勘探机会,编制了阿拉伯板块塞诺曼—土尔盆期层序地层综合资料。综合基于已发表的数据集,这些数据集在生物地层学和同位素地层学限制的时间框架内进行了分析。高地层学分辨率使得研究区古地理可以在三级沉积层序范围内作图,并可以评价海平面上升和构造对盆地发育的相对影响。这大大提高了在整个构造板块尺度上对地层构型和沉积形态的预测。根据露头和地下观测得到的概念模型已被应用于描述陆架内盆地在沉积环境中的发育特征,这些沉积环境要么与硅塑性分离(对称陆架内盆地模型),要么受硅塑性影响(不对称陆架内盆地模型)。层序地层模型在区域测井样条上的应用有助于理解地层结构,并对生成一套新的总沉积环境(GDE)图起到重要的控制作用。这些地图以前所未有的分辨率和尺度描绘了高相对海平面(最大洪水面和高水位系统域)和低相对海平面(低水位系统域)时期的古地理特征。这些地图由序列等径图补充,序列等径图揭示了随时间和空间的变化。这种方法有助于刻画油气系统要素的保存分布和地层构型。在Shilaif(阿联酋)、Natih(阿曼)和Sarvak(伊朗)陆架内盆地,富集的富有机质碳酸盐烃源岩是在受限缺氧条件下沉积的。这些盆地是由海侵体系域碳酸盐台地的差异沉积作用形成的。在高水位沉积过程中,沿陆架内盆地边缘发育粒状、富含粗砾岩-碎屑的碳酸盐岩储层。上覆层序中的粘土可能形成地层内封印,沉积于与海平面上升有关的海岸线退积过程中。相比之下,在Najaf陆架内盆地(伊拉克),有大量来自阿拉伯地盾的硅塑料成分。这一流入形成了盆地近西缘碳酸盐-硅屑混合斜坡沉积体系,而在盆地中央演替中明显缺乏富有机质层段。粒状碳酸盐岩储层局限于东缘,受下伏地层中较老的烃源岩充注。GDE图记录了Cenomanian-Turonian段内这些含油气系统元素的配置,并为储层筛选奠定了基础。Cenomanian-Turonian interval被主要的中turonian不整合所打断,这是一个具有重要地质和经济意义的构造地层边界。在阿拉伯板块的南部和东部,这种不整合具有不同的侵蚀剖面,有利于形成具有勘探潜力的亚作物。识别微妙的地层圈闭是具有挑战性的,但通过将GDE相与每个层序的绘制保存极限相结合,可以识别出具有潜在喀斯特增强作用的富含砾岩的储层相被区域性粘土岩封闭覆盖的区域,以及具有潜在亚层圈闭潜力的高品位区域。
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引用次数: 15
DEVELOPMENT OF FIBROUS CALCITE VEINS RELATED TO HYDROCARBON GENERATION AND OVERPRESSURING IN ORGANIC-RICH SHALE SOURCE ROCKS: THE VACA MUERTA FORMATION, NEUQUÉN BASIN, ARGENTINA 阿根廷neuquÉn盆地富有机质页岩烃源岩中与生烃和超压有关的纤维方解石脉发育
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-03-24 DOI: 10.1111/jpg.12814
J. B. Spacapan, M. Comerio, R. Ruiz, E. Rocha

Fibrous calcite bed-parallel veins (BPVs) are a typical feature of the Upper Jurassic – Lower Cretaceous Vaca Muerta Formation in the subsurface of the Neuquén Basin (Argentina). The formation is considered to be the main source rock in the basin as well as an important unconventional play. This study examines the growth of BPVs through an analysis of core from three wells located along a transect extending for some 150 km from the NE Platform near the basin margin in the east to the Agrio fold-and-thrust belt at the Andean deformation front in the west. The main objective is to integrate fluid inclusion data with the palaeothermal and palaeopresure evolution obtained from a regional-scale 2D basin and petroleum systems model to examine the timing of fracture development and its relationship with hydrocarbon generation in the Vaca Muerta Formation through time.

The apertures of BPVs were measured in more than 360 m of core from three wells (wells A, D and E). This data was combined with optical petrography to investigate the number of calcite cementation events, and the temperature of cement precipitation based on fluid inclusion data. The organic geochemical and mineralogical characteristics of the Vaca Muerta source rock were also analysed. The integrated results were incorporated into a poro-elastic basin model to investigate the impact of horizontal shortening due to Andean compression on pore pressure development and fracturing in the Vaca Muerta Formation. This framework allowed the timing of BPV formation to be determined together with possible mechanisms governing overpressure conditions through time.

Near the Andean deformation front in the west of the modelled section where the Vaca Muerta Formation is in the wet gas window (well D) and dry gas window (well A), BPVs are characterized by two or more generations of calcite fibres indicating multiple growth phases. Calcite which precipitated during cementation event 1 (E1) in the internal zones of BPVs consists of crystals oriented perpendicular to fracture walls, indicating perpendicular vein opening. Calcite precipitated during cementation event 2 (E2) in the outer zones of BPVs includes curved and oblique crystals. During this phase, shear occurred between the opening vein walls as a result of horizontal shortening. Cementation event 3 (E3) is characterized by an equant mosaic of calcite crystals which preserve intracrystalline porosity. E1cements formed between 110 and 90 Ma with trapping temperatures of ∼112 °C (upper Vaca Muerta, well A) and ∼125 °C (lower Vaca Muerta, well D). Fracturing resulted from disequilibrium compaction and from volumetric expansion due to primary cracking of kerogen within the oil window. E2 cements record a trapping temperature of ∼159 °C and formed between 70 and 55 Ma (lower Vaca Muerta, well D) during maximum burial of the Vaca Muerta Formation, synchronous with the secondary cracking of retained liquid hydrocarbons and the beginning of An

纤维状方解石床-平行脉是阿根廷neuqu盆地上侏罗统—下白垩统Vaca Muerta组地下的典型特征。该组被认为是盆地的主要烃源岩,也是重要的非常规油气藏。本研究通过对三口井的岩心进行分析,研究了bpv的生长情况。三口井位于一条横断面上,横断面从东部靠近盆地边缘的NE平台延伸到西部安第斯变形前沿的Agrio褶皱冲断带,全长约150公里。主要目的是将流体包裹体数据与区域尺度二维盆地和含油气系统模型获得的古热、古压演化相结合,研究Vaca Muerta组裂缝发育的时间及其与生烃的关系。在3口井(A、D和E井)超过360 m的岩心中测量了bpv的孔径,并将这些数据与光学岩石学相结合,研究方解石胶结事件的数量,以及基于流体包裹体数据的水泥沉淀温度。分析了瓦卡穆尔塔烃源岩的有机地球化学和矿物学特征。将综合结果整合到孔隙弹性盆地模型中,研究安第斯山脉压缩导致的水平缩短对Vaca Muerta组孔隙压力发育和压裂的影响。该框架允许确定BPV形成的时间以及随时间推移控制超压条件的可能机制。在模拟剖面西部的安第斯变形前缘附近,Vaca Muerta组处于湿气窗(D井)和干气窗(A井),BPVs的特征是两代或更多的方解石纤维,表明了多个生长阶段。胶结事件1 (E1)在bpv内部区域析出的方解石由垂直于裂缝壁取向的晶体组成,表明垂直的矿脉开口。胶结事件2 (E2)在bpv外区析出的方解石包括弯曲晶体和斜晶。在这一阶段,由于水平缩短,开放的脉壁之间发生了剪切。胶结事件3 (E3)的特征是方解石晶体的均匀镶嵌,保留了晶内孔隙度。胶结物形成于110 ~ 90 Ma之间,圈闭温度为~ 112°C (Vaca Muerta上部A井)和~ 125°C (Vaca Muerta下部D井)。压裂是由不平衡压实和油窗内干酪根初次裂解引起的体积膨胀造成的。E2胶结物记录的圈闭温度为~ 159℃,形成于70 ~ 55 Ma之间(Vaca Muerta下部D井),是Vaca Muerta组最大埋藏期,与残留液态烃的二次裂解和安第斯山脉压缩的开始同步。E3胶结物(Vaca Muerta上部A井)的圈闭温度为~ 162℃,形成于65 ~ 53 Ma之间,与热成因气的生成同步。相比之下,在neuqun盆地变形较小的前陆区东部,Vaca Muerta组处于早期油窗(E井),bpvv由单代方解石纤维(E1)组成,捕获温度为~ 118°C。E1胶结物的特征是方解石晶体垂直于裂缝壁取向,无剪切作用。根据模型模拟,胶结作用发生在最大埋藏期的64 ~ 53 Ma之间,与不平衡压实作用和干酪根初步转化成油的超压作用有关。研究结果表明,在Vaca Muerta组的某些层段,TOC含量的轻微增加伴随着脉体厚度的增加,胶结事件发生在研究区西部的安第斯形变前缘,而东部的前陆相对较多。
{"title":"DEVELOPMENT OF FIBROUS CALCITE VEINS RELATED TO HYDROCARBON GENERATION AND OVERPRESSURING IN ORGANIC-RICH SHALE SOURCE ROCKS: THE VACA MUERTA FORMATION, NEUQUÉN BASIN, ARGENTINA","authors":"J. B. Spacapan,&nbsp;M. Comerio,&nbsp;R. Ruiz,&nbsp;E. Rocha","doi":"10.1111/jpg.12814","DOIUrl":"10.1111/jpg.12814","url":null,"abstract":"<p>Fibrous calcite bed-parallel veins (BPVs) are a typical feature of the Upper Jurassic – Lower Cretaceous Vaca Muerta Formation in the subsurface of the Neuquén Basin (Argentina). The formation is considered to be the main source rock in the basin as well as an important unconventional play. This study examines the growth of BPVs through an analysis of core from three wells located along a transect extending for some 150 km from the NE Platform near the basin margin in the east to the Agrio fold-and-thrust belt at the Andean deformation front in the west. The main objective is to integrate fluid inclusion data with the palaeothermal and palaeopresure evolution obtained from a regional-scale 2D basin and petroleum systems model to examine the timing of fracture development and its relationship with hydrocarbon generation in the Vaca Muerta Formation through time.</p><p>The apertures of BPVs were measured in more than 360 m of core from three wells (wells A, D and E). This data was combined with optical petrography to investigate the number of calcite cementation events, and the temperature of cement precipitation based on fluid inclusion data. The organic geochemical and mineralogical characteristics of the Vaca Muerta source rock were also analysed. The integrated results were incorporated into a poro-elastic basin model to investigate the impact of horizontal shortening due to Andean compression on pore pressure development and fracturing in the Vaca Muerta Formation. This framework allowed the timing of BPV formation to be determined together with possible mechanisms governing overpressure conditions through time.</p><p>Near the Andean deformation front in the west of the modelled section where the Vaca Muerta Formation is in the wet gas window (well D) and dry gas window (well A), BPVs are characterized by two or more generations of calcite fibres indicating multiple growth phases. Calcite which precipitated during cementation event 1 (E1) in the internal zones of BPVs consists of crystals oriented perpendicular to fracture walls, indicating perpendicular vein opening. Calcite precipitated during cementation event 2 (E2) in the outer zones of BPVs includes curved and oblique crystals. During this phase, shear occurred between the opening vein walls as a result of horizontal shortening. Cementation event 3 (E3) is characterized by an equant mosaic of calcite crystals which preserve intracrystalline porosity. E1cements formed between 110 and 90 Ma with trapping temperatures of ∼112 °C (upper Vaca Muerta, well A) and ∼125 °C (lower Vaca Muerta, well D). Fracturing resulted from disequilibrium compaction and from volumetric expansion due to primary cracking of kerogen within the oil window. E2 cements record a trapping temperature of ∼159 °C and formed between 70 and 55 Ma (lower Vaca Muerta, well D) during maximum burial of the Vaca Muerta Formation, synchronous with the secondary cracking of retained liquid hydrocarbons and the beginning of An","PeriodicalId":16748,"journal":{"name":"Journal of Petroleum Geology","volume":"45 2","pages":"219-248"},"PeriodicalIF":1.8,"publicationDate":"2022-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45208360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
TECTONOSTRATIGRAPHIC EVOLUTION AND HYDROCARBON PROSPECTIVITY SOUTH OF GWADAR BAY, MAKRAN ACCRETIONARY WEDGE, OFFSHORE SW PAKISTAN 巴基斯坦西南部近海makran增生楔瓜达尔湾南部构造地层演化及油气远景
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-03-24 DOI: 10.1111/jpg.12812
Conall Cromie, Nicola Scarselli, Jonathan Craig, Moin R. Khan, Abid Hussain

The Makran accretionary wedge developed as a result of subduction of the Arabian Plate beneath the southern margin of Eurasia since the Eocene. Interpretation of 2D seismic profiles calibrated to offshore well data in a study area to the south of Gwadar Bay (SW Pakistan) indicates a major period of accretion from the mid-Miocene, as evidenced by the occurrence of thick growth strata associated with large-scale imbricate thrusts. The thrust faults originate from a deep detachment within the mud-rich Oligocene interval, and well-developed piggy-back basin successions occur in thrust hanging walls. In the study area, the thrust structures are sealed by a thick, progradational Pliocene to Recent interval in which the presence of submarine canyons, up to 2.5 km across, indicate that sedimentary transport was from the north.

Fluid escape pipes and associated amplitude anomalies are observed in the seismic profiles studied and may be related to upward migration of thermogenic hydrocarbons from depth, as heavy hydrocarbon fractions <C3 have been reported from nearby wells. The hydrocarbons are believed to have been sourced from the Oligocene Hoshab Shale and to have then migrated up through a sedimentary succession in which permeability barriers are largely absent. Hanging wall anticlines mapped in the study area could provide structural traps, and turbidites in the Lower Miocene Panjgur Formation may represent a potential reservoir. Amplitude anomalies are also observed adjacent to shallow fluid escape pipes within the topsets of clinoforms in the Pleistocene Chatti and Omara Formations, and probably indicate the presence of biogenic hydrocarbons sourced from distal mudstones in bottomset strata.

马克兰增生楔是始新世以来阿拉伯板块向欧亚大陆南缘俯冲的结果。在瓜达尔湾南部(巴基斯坦西南部)的一个研究区域,根据海上油井数据校准的二维地震剖面解释表明,中新世中期开始出现了一个主要的增生时期,这一点可以从与大规模叠瓦状逆冲相关的厚生长地层中得到证明。逆冲断层起源于富泥渐新世段的深部拆离,逆冲上盘发育发育良好的背带盆地序列。在研究区,冲断构造被上新世至新近的厚层前积层封住,其中海底峡谷的存在,直径达2.5公里,表明沉积是从北方运来的。在研究的地震剖面中观察到流体逸出管和相关振幅异常,可能与深部热生烃向上运移有关,因为在附近的井中报告了重烃馏分<C3。据信,这些碳氢化合物来自渐新世Hoshab页岩,然后通过沉积演替向上运移,其中渗透率障碍基本上没有。研究区上盘背斜可提供构造圈闭,下中新统潘杰古尔组浊积岩可能是潜在储层。在更新世Chatti组和Omara组斜形顶部组中,在浅层流体逸出管附近也观察到振幅异常,这可能表明底部地层中存在来自远端泥岩的生物烃。
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引用次数: 0
NEOCOMIAN – BARREMIAN LACUSTRINE SHALES IN THE MAYO OULO-LERE BASIN, NORTH CAMEROON: DEPOSITIONAL ENVIRONMENT AND PETROLEUM POTENTIAL 喀麦隆北部梅奥奥勒盆地新新纪—巴雷米亚湖相页岩:沉积环境与油气潜力
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2022-03-24 DOI: 10.1111/jpg.12813
Bachirou Mfayakouo Chavom, François Baudin, Josiane F. Kwéa Nzouedjio, Johann Schnyder, Aicha Maloum, Serge Edouard Angoua Biouélé

The synrift Mayo Oulo-Léré Basin in Northern Cameroon is located in the transition zone between the West and Central African Rift Systems. Structural and stratigraphic elements of the basin resemble those of the Yola Basin in NE Nigeria, an extension of the Upper Benue Trough. The Lower Cretaceous lacustrine shales with source rock potential which occur in nearby rift basins are also present in the Mayo Oulo-Léré Basin. These shales were investigated at two outcrop locations (Badesi and Tchontchi), and samples collected (n = 60) were subjected to palynofacies and bulk geochemical analyses to evaluate their petroleum generation potential and to interpret their depositional environment. At the studied locations, shales were divided into two lithofacies: grey to black laminated shales containing algal-bacterial OM together with common woody (phytoclast) debris (“facies Fml”); and cm-bedded shales which had a higher content of algal-bacterial OM but a lower phytoclast content (“facies Fmlc”).

Palynological and bulk geochemical data indicate that the shales contain well-preserved organic matter (OM) and locally display good to excellent oil generation potential. Average TOC contents are 2.7% and 1.4% for samples of the Fmlc and Fml facies shales respectively. HI values (94-889 mg HC/g TOC and 131-638 mg HC/g TOC respectively) suggest that the shales contain Types I to III kerogen. Organic material in the Fmlc facies shales is dominated by amorphous organic matter (AOM: 90% on average) with a low phytoclast content (6% on average); whereas samples of the Fml facies shales contain less AOM (74% on average) and have a higher phytoclast content (23% on average). AOM in the Fmlc shales is highly fluorescent; these shales are interpreted to have been deposited in dysoxic to anoxic conditions. The AOM in the Fml shales is weakly fluorescent and the shales were deposited under more oxic conditions. The kerogen in the shales ranges from immature to early oil window mature. Average values of the pyrolysis S2 yield are 15.5 mg HC/g of rock and 7 mg HC/g of rock for samples from Fmlc and Fml facies shales respectively. The shales increase in thickness northwards towards the Logone Birni Basin where they may have reached the oil window, as in neighbouring basins. The results of this study of lacustrine shales from the Mayo Oulo-Léré Basin suggests that there may be potential for oil exploration in northern Cameroon.

喀麦隆北部的梅奥-奥罗-拉西姆盆地位于西非裂谷系和中非裂谷系之间的过渡地带。盆地的构造和地层元素类似于尼日利亚东北部的约拉盆地,是上贝努埃海槽的延伸。下白垩统湖相页岩存在于裂谷盆地附近,具有烃源岩潜力。研究人员在两个露头位置(Badesi和Tchontchi)对这些页岩进行了调查,并收集了60个样品,进行了孢粉相和整体地球化学分析,以评估其生油潜力并解释其沉积环境。在研究地点,页岩被划分为两个岩相:灰色至黑色层状页岩,含有藻-细菌OM和常见的木质(植物碎屑)碎屑(“相Fml”);cm层状页岩,藻-细菌有机质含量较高,而植物碎屑含量较低(“Fmlc相”)。孢粉学和整体地球化学数据表明,页岩中有机质保存较好,局部具有良好至极好的生油潜力。Fmlc和Fml相页岩样品TOC平均含量分别为2.7%和1.4%。HI值(94 ~ 889 mg HC/g TOC和131 ~ 638 mg HC/g TOC)表明页岩含ⅰ~ⅲ型干酪根。Fmlc相页岩有机质以无定形有机质为主(平均AOM为90%),植物碎屑含量较低(平均6%);而Fml相页岩样品的AOM含量较少(平均74%),植物碎屑含量较高(平均23%)。Fmlc页岩中的AOM具有高荧光性;这些页岩被解释为在缺氧或缺氧条件下沉积的。Fml页岩中的AOM具有弱荧光,且页岩沉积在较强的氧化条件下。页岩的干酪根处于未成熟-早期油窗成熟阶段。Fmlc和Fml相页岩的热解S2产率平均值分别为15.5 mg HC/g和7 mg HC/g。在Logone Birni盆地北部,页岩厚度增加,在那里它们可能到达了油窗,就像在邻近的盆地一样。这项对Mayo oulo - l 盆地湖相页岩的研究结果表明,喀麦隆北部可能存在石油勘探的潜力。
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引用次数: 0
A NEW OIL SEEPAGE IN THE OMAN MOUNTAINS AND ITS GEOLOGICAL, GEOCHEMICAL AND PETROLEUM SYSTEMS CONTEXT 阿曼山区一次新的石油渗流及其地质、地球化学和石油系统背景
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12805
M. Al Kindi, M. Al-Ghammari, A. Heward, P. Taylor, G. Siavalas
A minor natural oil seepage is described from an unlikely setting in the Oman Mountains. The host rocks are fractured pelagic limestones of the lower member of the Triassic – Lower Jurassic Matbat Formation of the Hamrat Duru Group in the lower part of the allochthonous Hawasina Complex. This paper summarises Oman's established oil families and documents previously recorded oil seepages as context for describing the new seepage, its geochemistry, and possible source rock. The seep oil is different to those known from Oman's oil fields and probably derived from a poor quality, Mesozoic clastic source rock containing a mix of terrigenous and marine organic matter. The most likely source appears to be the Toarcian turbiditic upper member of the Matbat Formation, equivalent to the clastic Mafraq Formation of the Arabian Platform. The occurrence of source rocks in the allochthonous sediments of the NeoTethyan Hawasina Basin has been suspected previously, though their commercial significance remains to be established.
阿曼山脉的一处不太可能的环境中出现了轻微的天然石油渗漏。寄主岩石为异地Hawasina杂岩下部Hamrat-Duru群三叠纪-下侏罗系Matbat组下部的破碎远洋石灰岩。本文总结了阿曼已建立的石油家族和先前记录的石油渗漏文件,作为描述新渗漏、其地球化学和可能的烃源岩的背景。渗油与阿曼油田的渗油不同,可能来源于质量较差的中生代碎屑烃源岩,其中含有陆源和海洋有机质的混合物。最可能的来源似乎是Matbat组的Toarcian浊积上段,相当于阿拉伯地台的碎屑Mafraq组。尽管其商业意义尚待确定,但先前曾怀疑新特提斯-哈瓦西纳盆地异地沉积物中存在烃源岩。
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引用次数: 2
Issue Information 问题信息
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12787
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引用次数: 0
BIOMARKER GEOCHEMISTRY OF PALEOGENE CRUDE OILS AND SOURCE ROCKS FROM THE RAOYANG SAG, BOHAI BAY BASIN, NE CHINA: AN OIL – SOURCE ROCK CORRELATION STUDY 渤海湾盆地饶阳凹陷古近系原油及烃源岩生物标志物地球化学油源岩对比研究
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12807
S.-H. Su, Youlu Jiang
This study presents a systematic geochemical analysis of Paleogene crude oils and source rocks from the Raoyang Sag in the Jizhong sub‐basin of the Bohai Bay Basin (NE China). The geochemical characteristics of fifty‐three oil samples from wells in four sub‐sags were analysed using gas chromatography (GC) and gas chromatography – mass spectrometry (GC‐MS). Twenty core samples of mudstones from Members 1 and 3 of the Eocene‐Oligocene Shahejie Formation were investigated for total organic carbon (TOC) content and by Rock‐Eval pyrolysis and GC‐MS to study their geochemistry and hydrocarbon generation potential. The oils were tentatively correlated to the source rocks.
本文对渤海湾盆地冀中盆地饶阳凹陷古近系原油和烃源岩进行了系统的地球化学分析。采用气相色谱(GC)和气相色谱-质谱(GC - MS)分析了4个亚凹陷井中53个油样的地球化学特征。摘要对始新统—渐新统沙河街组一段和三段20份泥岩岩心样品进行了总有机碳(TOC)含量测定,并通过岩石热解和气相色谱-质谱分析研究了泥岩的地球化学特征和生烃潜力。初步将油与烃源岩进行了对比。
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引用次数: 1
GEOCHEMICAL COMPOSITION OF ORDOVICIAN OILS FROM THE TUOPUTAI REGION, NORTHERN TARIM BASIN, NW CHINA: SOURCE ROCK CORRELATION 塔北托普台地区奥陶系原油地球化学组成及烃源岩对比
IF 1.8 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2021-12-21 DOI: 10.1111/jpg.12809
B. Cheng, Hua Liu, Xian Wu, Shen Wang, Zepeng Wu
Molecular and stable carbon isotope compositions of 46 Ordovician crude oil samples from wells in the Tuoputai region of the northern Tarim Basin were investigated using GC–MS, MRM GC–MS and IRMS to determine their genetic relationships and to identify possible source rocks. Thirty‐three source rock samples from outcrops and cores were also investigated. The oil samples varied from light to heavy crudes and showed very narrow δ13C value ranges for the whole oil, saturated and aromatic fractions. The majority of the oils displayed very similar molecular compositions with relatively high concentrations of n‐alkanes and isoprenoids and low concentrations of terpenoids and steroids. Comparison of the compositions of these crude oils strongly suggested their genetic affinity, while maturity parameters indicated maturity variations from the peak to the late oil generation stages. The samples also showed the characteristics of mixtures of biodegraded and fresh oil charges.
采用GC–MS、MRM GC–MS和IRMS方法,对塔北沱蒲台地区46口奥陶系原油样品的分子和稳定碳同位素组成进行了研究,确定了它们的成因关系,并确定了可能的烃源岩。还调查了来自露头和岩芯的三十三个源岩样本。油样从轻质原油到重质原油各不相同,全油、饱和馏分和芳香馏分的δ13C值范围非常窄。大多数油显示出非常相似的分子组成,具有相对高浓度的正烷烃和类异戊二烯,以及低浓度的萜类和类固醇。对这些原油成分的比较有力地表明了它们的遗传亲和力,而成熟度参数表明了从石油生成高峰期到晚期的成熟度变化。这些样品还显示了生物降解和新鲜油装药混合物的特征。
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引用次数: 0
期刊
Journal of Petroleum Geology
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