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Modeling the Influence of Mud Rheology on Drill Bit Behavior in Algerian Borehole: A Numerical Study Using CFD Approach 阿尔及利亚井眼泥浆流变性对钻头行为的影响建模:基于CFD方法的数值研究
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-13 DOI: 10.1111/jpg.70011
Abdellah Mekedeme, Samir Benammar, Haroun Ragueb, Belkacem Manser, Kong Fah Tee

The drill bit is a crucial device in oil companies, and it is quite expensive. Therefore, studying its mechanical behavior is essential for preserving this device and reducing its maintenance costs. The drilling mud is among the practical things that influence the bit's performance during the drilling operation. This article presents a numerical study of mud rheology in Algerian oil and gas wells using computational fluid dynamics (CFD) analysis. This study aims to optimize the rheological and dynamic properties around the polycrystalline diamond compact (PDC) drill bit of 244 mm diameter in the Algerian borehole. The drilling mud used is a mixture of water, 0.15% of hydroxyethyl cellulose (HEC), and an Algerian bentonite base. The Herschel–Bulkley model has been used to characterize the rheological behavior of this drilling mud because it is a non-Newtonian fluid. The three-dimensional (3D) model of the PDC drill bit was meticulously designed using SolidWorks (version 24, 2016). Additionally, the dynamic behavior of the PDC drill bit in the presence of drilling mud was modeled and simulated using ANSYS Fluent software (version 19.0, 2018). The results indicate that although mud density has minimal impact on annular velocity, it significantly affects the pressure drop across the drill bit. In contrast, the drill bit's rotational speed directly influences annular velocity, which plays a critical role in mitigating stick–slip phenomena. This mitigation is achieved through the enhancement of cuttings transport from the bottom hole to the surface, thereby preventing accumulation around the drill bit, a primary contributor to stick–slip vibrations. These findings support previous studies that have established the influence of mud density on pressure drop and the critical role of rotational speed in mitigating stick–slip phenomena. The numerical results for fluid parameters at the nozzle, obtained using ANSYS Fluent, were validated against established oilfield empirical correlations, demonstrating satisfactory agreement.

钻头是石油公司的关键设备,价格相当昂贵。因此,研究其力学行为对于保存该装置和降低其维护成本至关重要。在钻井作业中,泥浆是影响钻头性能的实际因素之一。本文采用计算流体动力学(CFD)方法对阿尔及利亚油气井的泥浆流变性进行了数值研究。该研究旨在优化阿尔及利亚井眼中直径为244mm的聚晶金刚石(PDC)钻头的流变和动态特性。所使用的钻井泥浆是水、0.15%的羟乙基纤维素(HEC)和阿尔及利亚膨润土基的混合物。Herschel-Bulkley模型被用来描述这种钻井液的流变特性,因为它是一种非牛顿流体。使用SolidWorks(2016年第24版)精心设计了PDC钻头的三维(3D)模型。此外,利用ANSYS Fluent软件(2018年19.0版)对PDC钻头在钻井液存在下的动态行为进行了建模和仿真。结果表明,尽管泥浆密度对环空速度的影响很小,但它对整个钻头的压降影响很大。相比之下,钻头转速直接影响环空速度,对减轻粘滑现象起关键作用。通过加强岩屑从井底到地面的运输,从而防止了钻头周围的堆积,这是造成粘滑振动的主要原因。这些发现支持了之前的研究,即泥浆密度对压降的影响以及转速在缓解粘滑现象方面的关键作用。利用ANSYS Fluent获得的喷嘴流体参数数值结果与建立的油田经验相关性进行了验证,结果令人满意。
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引用次数: 0
Textural and Compositional Controls on Reservoir Quality of the Cretaceous Caballos Formation in the Putumayo Basin, Colombia 哥伦比亚普图马约盆地白垩系Caballos组储层物性的结构成分控制
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-08 DOI: 10.1111/jpg.70009
Edison Joan Duarte Gomez, Agustín Cardona Molina, Sergio Hernando Lopera Castro
<div> <p>The evaluation of geological attributes such as mineralogical composition, sedimentary texture, diagenetic processes, and petrophysical properties is crucial for understanding the storage, flow, and recovery potential in hydrocarbon reservoir rocks. This study focuses on the Cretaceous Caballos Formation in the Putumayo Basin, a foreland basin that borders the intramontane Upper Magdalena Valley basin to the west and the Llanos Orientales basin to the northeast. The main objective is to determine how compositional, textural, and diagenetic characteristics influence petrophysical properties, specifically porosity, permeability, and capillarity. Surface exposures of clastic rocks associated with this formation were analyzed at the asymmetric and faulted Santa Ana anticline, near the Costayaco field. Core samples were collected, and thin sections were prepared for detailed sedimentological analysis, focusing on mineral composition, grain size, sorting, roundness, and sphericity. Additional analyses investigated compaction processes, pseudomatrix formation, dissolution, and cementation by silica, carbonates, and iron oxides. Subsequently, petrophysical tests were performed on both the lower and upper segments of the formation. Variations in porosity and permeability were correlated with geological attributes through statistical analysis using the Pearson correlation coefficient, quantifying the relationships between textural characteristics (grain size, shape, and sorting) and petrophysical properties. The results indicated a significant positive correlation between porosity and permeability in both segments, at the individual sample level and within the regional context supported by well data. Additionally, a relationship between pore throat size and grain size significantly influencing permeability was observed. Diagenetic and compositional analysis revealed that the presence of clay matrix and pseudomatrix, resulting from sedimentary lithic deformation and glauconite alteration, negatively impacted pore space connectivity, thus reducing reservoir quality. Furthermore, a progressive quartz enrichment from the lower to upper segments was identified, suggesting greater compositional maturity attributed to tropical humid conditions during the Albian–Aptian. This enrichment facilitated the preservation of petrophysical properties in specific petrofacies, enhancing hydrocarbon storage and flow potential. Recognizing surface analogues, as addressed in the introduction, becomes essential due to the frequent lack of detailed subsurface information. Surface analog studies provide valuable insights into reservoir characteristics and diagenetic processes, thereby significantly improving the certainty and reliability of subsurface reservoir models used in hydrocarbon exploration and production. Ultimately, integrating surface analogues into geological modeling contributes substantially to reducing uncertainties and optimizing explor
地质属性的评价,如矿物组成、沉积结构、成岩作用和岩石物理性质,对于了解油气储层岩石的储存、流动和采收率潜力至关重要。本研究以普图马约盆地白垩系Caballos组为研究对象。普图马约盆地是一个前陆盆地,其西与上马格达莱纳山间盆地接壤,东北与东方岛盆地接壤。主要目的是确定成分、结构和成岩特征如何影响岩石物理性质,特别是孔隙度、渗透率和毛细作用。在Costayaco油田附近的不对称和断裂的Santa Ana背斜上分析了与该地层相关的碎屑岩的表面暴露。采集岩心样品,制备薄片进行详细的沉积学分析,重点研究矿物组成、粒度、分选、圆度和球形度。额外的分析研究了压实过程、假基质形成、溶解和二氧化硅、碳酸盐和氧化铁的胶结作用。随后,对地层下部和上部进行了岩石物理测试。通过使用Pearson相关系数进行统计分析,将孔隙度和渗透率的变化与地质属性关联起来,量化结构特征(粒度、形状和分选)与岩石物理性质之间的关系。结果表明,在单个样品水平和井数据支持的区域背景下,这两个段的孔隙度和渗透率之间存在显著的正相关关系。此外,还观察到孔喉尺寸与颗粒尺寸之间的关系对渗透率有显著影响。成岩和成分分析表明,沉积岩屑变形和海绿石蚀变导致的粘土基质和伪基质的存在对孔隙空间连通性产生不利影响,从而降低了储层质量。此外,石英由下向上段逐渐富集,表明在Albian-Aptian时期,较高的成分成熟度归因于热带湿润条件。这种富集有利于特定岩相岩石物性的保存,增强了油气的储存和流动潜力。由于经常缺乏详细的地下信息,如引言所述,识别地表类似物变得至关重要。地面模拟研究为储层特征和成岩过程提供了有价值的见解,从而显著提高了用于油气勘探和生产的地下储层模型的确定性和可靠性。最终,将地表类似物整合到地质建模中,有助于减少不确定性,优化勘探和生产策略。
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引用次数: 0
Palynofacies Analysis Illustrates the Source Rock Potential of the Menilite Beds, Polish Outer Carpathians 波兰外喀尔巴阡山脉Menilite床的孢粉相分析说明了烃源岩潜力
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-30 DOI: 10.1111/jpg.70005
Filipek Anna, Barski Marcin, Wysocka Anna, Jankowski Leszek

The deposition of the Menilite Beds began during the reorganization of the sea ways and the extensional stage of the Carpathian Basin evolution in the early Oligocene. The beginning of their sedimentation is considered to be isochronous throughout the entire marine basin, which formed a part of the Paratethys and was likely isolated from the global ocean due to tectonic movements. However, the changes in the Carpathian region were likely also influenced by processes associated with the Eocene–Oligocene Transition. The present study focuses on the investigation of the Menilite Beds from two Outer Carpathians (OC) main tectonic units: the Skole (Krościenko section) and Silesian (Korzenna section), using a coupled palynofacies, Rock-Eval pyrolysis, and sedimentological framework. This approach permitted the observation of lateral variations in lithology, sedimentary structures, and palynofacies, recording the changes that took place in the early Oligocene, during the deposition of the Menilite Beds, in regions that are currently separated by great distances. In both sections, the palynofacies of the Menilite Beds are predominantly composed of amorphous organic matter (AOM), suggesting that the Menilite Beds were deposited under strongly oxygen-depleted conditions. The presence of spherical bacteria and AOM with alveolar structures in the Korzenna section indicates that microbial mats were probably locally present at the sediment–water interface during the deposition of the Menilite Beds. Analyses of microplankton with organic walls indicate that brackish conditions were present during the deposition of the lower Menilite Beds. Identified microplankton notably included Botryococcus sp. (Krościenko, Korzenna), Campenia sp. (Krościenko, Korzenna), Leiosphaeridia sp. (Krościenko, Korzenna), Pterospermella sp. (Krościenko, Korzenna), and Cymatiosphaera sp. (Korzenna). These results indicate that some lower Menilite Beds, which are located directly above the Eocene deposits (Krościenko—Complex II, III, and IV; Korzenna—Complex I, II, IV, VI), contain horizons with palynological compositions favorable to hydrocarbon generation, including Botryococcus sp. and Leiosphaeridia sp., which are characterized by a high ability to synthesize and accumulate hydrocarbon. We demonstrate that the integration of sedimentological, palynofacies, and organic matter analyses under UV light supported by Rock-Eval pyrolysis can facilitate the identification of potential hydrocarbon horizons—characterized by elevated algal abundances—within the differentiated lithostratigraphic profile of the Menilite Beds. The formation of these deposits was influenced by a complex interplay of paleogeographical, paleoclimatic, and tectonic factors.

Menilite床的沉积开始于早渐新世喀尔巴阡盆地演化的海道重组和伸展阶段。它们的沉积开始被认为是在整个海相盆地中是等时的,形成了Paratethys的一部分,并且可能由于构造运动而与全球海洋隔离。然而,喀尔巴阡地区的变化也可能受到始新世-渐新世过渡过程的影响。本研究主要研究了两个外喀尔巴阡山脉(OC)主要构造单元:Skole (Krościenko剖面)和Silesian (Korzenna剖面)的Menilite层,采用了耦合的孢粉相、岩石热解和沉积学框架。这种方法可以观察到岩性、沉积结构和孢粉相的横向变化,记录了早渐新世,在Menilite床沉积期间,在目前相隔很远的地区发生的变化。在两个剖面中,孟尼尔岩床孢粉相主要由无定形有机质(AOM)组成,表明孟尼尔岩床是在强缺氧条件下沉积的。Korzenna剖面中球形细菌和具有肺泡结构的AOM的存在表明,微生物席可能在Menilite床沉积过程中局部存在于沉积物-水界面。对具有有机壁的微型浮游生物的分析表明,在较低的Menilite床沉积期间存在微咸环境。已鉴定的小型浮游生物主要包括Botryococcus sp. (Krościenko, Korzenna)、Campenia sp. (Krościenko, Korzenna)、Leiosphaeridia sp. (Krościenko, Korzenna)、Pterospermella sp. (Krościenko, Korzenna)和Cymatiosphaera sp. (Korzenna)。这些结果表明,在始新世沉积层(Krościenko-Complex II、III和IV; korzenna -复合体I、II、IV、VI)正上方的下部Menilite床中,含有Botryococcus sp.和Leiosphaeridia sp.等孢粉组成有利于生烃的层位,具有较高的合成和聚集油气的能力。我们证明,在岩石热解的支持下,在紫外光下对沉积学、孢粉相和有机质进行综合分析,有助于在Menilite层的分化岩石地层剖面中识别潜在的油气层位,其特征是藻类丰度升高。这些矿床的形成受古地理、古气候和构造因素复杂的相互作用影响。
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引用次数: 0
A Conceptual Model of Hydrocarbon Migration Conduits in the Outer Carpathian Fold-and-Thrust Belt in Poland: An Interplay Among Fractures, Faults and Rock Properties 波兰喀尔巴阡山脉外褶皱冲断带油气运移管道的概念模型:断裂、断裂与岩石性质的相互作用
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-27 DOI: 10.1111/jpg.70006
Barbara Rybak-Ostrowska, Małgorzata Kozłowska, Michał Wyglądała, Anna Haluch, Joanna Uroda, Mirosław Ludwiniak, Sara Wróblewska-Janc, Marcin Barski, Andrzej Konon

The hydrocarbon migration conduits in the Outer Carpathian fold-and-thrust belt (OCFTB) are related to the dynamic development of the structural framework combined with changes of rock properties during the deformation process. Application of an integrated methodology, including fieldwork coupled with analysis of cores and thin sections as well as geophysical and petrophysical data from eight wells, made it possible to describe the relationships between the structural framework and the porous sandy rocks of the Cretaceous-to-Oligocene succession during the evolution of the OCFTB. The results indicate that the folding and thrusting, along with the associated rock fracturing during sustained horizontal contraction, resulted in the complex structure of the Silesian Nappe (part of the OCFTB). Structural deformation of lithified rocks created a system of conduits for hydrocarbon migration. The presence of bitumen in the thrust fault zones, normal faults and longitudinal joints (L), parallel to the anticline axes, transversal joints (T) and shear joints (D1 and D2) indicates permanent hydrocarbon migration through complex conduits formed by the subsequent structural deformation of the Silesian Nappe. The assembled evidence points to the existence of an interconnected system of a structural framework combined with porous carrier beds contributing to the formation of conduits for hydrocarbon migration during the progressive deformation of the OCFTB.

外喀尔巴阡褶皱冲断带的油气运移通道与构造格架的动态发育以及变形过程中岩石性质的变化有关。综合方法的应用,包括现场工作、岩心和薄片分析以及来自8口井的地球物理和岩石物理数据,使得描述OCFTB演化过程中白垩纪至渐新世序列的结构框架与多孔砂质岩之间的关系成为可能。结果表明,西列西亚推覆体的褶皱和逆冲作用,以及持续水平收缩过程中伴生的岩石破裂作用,形成了西列西亚推覆体的复杂构造。岩化岩的构造变形形成了油气运移的管道系统。逆冲断裂带、正断层、平行于背斜轴的纵向节理(L)、横向节理(T)和剪切节理(D1和D2)中沥青的存在表明油气通过西里西亚推覆体后续构造变形形成的复杂管道进行永久性运移。综合证据表明,在OCFTB的渐进变形过程中,存在一个相互连接的结构框架系统,该系统与多孔载体床相结合,有助于形成烃类运移的管道。
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引用次数: 0
Petrophysical Implications From a Microtectonic Evaluation of Villeta Formation Cores in the Putumayo Basin (Colombia) 哥伦比亚普图马约盆地Villeta组岩心微构造评价的岩石物理意义
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-26 DOI: 10.1111/jpg.70008
Eduardo A. Rossello, Marcos E. Mozetic

The HC-producing Putumayo Basin is located in Southwestern Colombia, forming the northern part of the Ecuadorian Oriente Basin. Traditional reservoirs are sandstones of the Caballos Fm. (Aptian–Albian) and also the ‘U and M2 Sandstones’ of the Villeta Fm. (Late Albian–Maastrichtian). To provide a frame for our observations, a review of the main tectosedimentary aspects and petroleum systems considered in the literature was carried out. To evaluate the potential of the carbonate layers as reservoirs, in addition to the traditional ones, a microtectonic study was carried out on some available carbonate-bearing cores from wells drilled in the Villeta Fm. Although not properly oriented in space when acquired, when available, dipmeter logs have contributed to the approximate 3D positioning of these cores. The recognized microstructures belong to two main tectonic events progressively superimposed in time from Upper Cretaceous to Recent and in space from West to East: (i) early features due to vertical compaction by overburden following deposition that develop gently deformed stratification and lamination surfaces around more competent objects generated by differential compaction, steep-angle normal faulting in competent levels with slickensides, subhorizontal stylolites and subvertical calcite veins with cuneiform patterns; (ii) later features due to ENE–WSW subhorizontal convergence by the action of the post-Eocene Andean convergence producing dextral transpressional reactivations on the pre-existing N–S normal faulting. The early compaction is usually associated with the onset of HC maturation and subsequent migration towards contemporaneous potential traps. The carbonate veins confirm that dissolution and precipitation processes have decreased the primary porosity and permeability of the reservoirs by calcareous cementation, especially in the deeper parts of the basin. If the Villeta Fm. is to be considered a potential unconventional or tight reservoir, the more efficient direction for future drilling is subhorizontal NNW–SSE. These studies on available cores are only complementary to the usual, more thorough and expensive methodologies of petrophysical reservoir analysis and mainly aspire to extract additional information considering the high costs of obtaining them.

产hc的Putumayo盆地位于哥伦比亚西南部,形成了厄瓜多尔东方盆地的北部。传统的储层是Caballos Fm的砂岩。(Aptian-Albian)以及Villeta Fm的“U和M2砂岩”。(Albian-Maastrichtian末)。为了给我们的观察提供一个框架,我们对文献中考虑的主要构造沉积方面和含油气系统进行了回顾。为了评价碳酸盐岩储层的潜力,除了传统的碳酸盐岩储层外,还对Villeta组钻探的一些含碳酸盐岩岩心进行了微构造研究。虽然在获取时没有正确的空间定位,但在可用的情况下,倾角测井有助于这些岩心的大致3D定位。已识别的微观构造在时间上由上白垩世至新近,空间上由西向东,属于两个主要的构造事件,它们依次叠加;(1)沉积后覆盖层的垂直压实作用形成的早期特征,在差异压实作用形成的较强岩体周围发育轻度变形的层状和层状表面,具有滑脱岩体的陡角正断层,亚水平柱状岩和亚垂直方解石脉具有楔形图案;(ii)始新世后安第斯会聚作用下的ENE-WSW次水平辐合形成的后期特征,在原有的N-S正断层的基础上产生右旋跨向再活化。早期压实作用通常与烃源岩成熟的开始和随后向同生潜在圈闭的运移有关。碳酸盐脉体证实溶蚀和沉淀作用通过钙质胶结作用降低了储层的原生孔隙度和渗透率,特别是在盆地的深部。如果维拉塔Fm。为潜在的非常规或致密储层,未来更有效的钻探方向是NNW-SSE亚水平方向。这些对可用岩心的研究只是对通常的、更彻底和昂贵的岩石物理储层分析方法的补充,主要是为了提取额外的信息,因为获取这些信息的成本很高。
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引用次数: 0
New Insights Into the Geochemical Characteristics of Petroleum Source Rocks and Oils From Southern Nigerian Sedimentary Basins 尼日利亚南部沉积盆地烃源岩及原油地球化学特征新认识
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-24 DOI: 10.1111/jpg.70007
Abdulkareem Toyin, Falilat Omotolani Idris, N'Guessan Francois De Sales Konan, Olabisi Adekeye

The Anambra and the Niger Delta Basins are well-known hydrocarbon-producing sedimentary basins in Southern Nigeria. In the present research, bulk geochemical analysis, which includes total organic carbon (TOC) and rock pyrolysis, molecular markers, and bulk and compound-specific carbon isotopes (CSIAs), in addition to organic petrological analysis was carried out on source rocks of Cretaceous age from the Anambra Basin and oils (both Anambra and Niger Delta Basins) in order to provide information on why there was a sudden seizure in liquid hydrocarbon production in the ANAR oilfield of the Anambra Basin and also to shed more light on the unending debate on the source of Cretaceous Niger Delta oils. From the results, bulk geochemical data and maceral abundances revealed that Nkporo shales from well-x and outcrop Mamu shales are dominantly of Types II and III organic matters and are capable of producing oil and gas upon attaining appropriate thermal maturity, whereas outcrop Mamu coals are of Types II and II/III organic matter, with good potential for oil generation but with minor gas, especially in the deeper section of the basin. Organic matter richness as deduced from TOC revealed that the Mamu coals are the richest (average TOC: 50.74 wt%), whereas Mamu shales are richer (average TOC: 2.89 wt%) than Nkporo shales (average TOC: 1.66 wt%). The hydrocarbon generative potentials of the analyzed source rocks as obtained through the hydrogen index are highest in the Mamu coals (average: 329.25 mg HC/g TOC), and are followed by Mamu shales (average: 130.89 mg HC/g TOC), whereas the least was obtained in Nkporo shales (average: 69.73 mg HC/g TOC). The maximum temperature (Tmax) and the vitrinite/huminite reflectance values of the source rocks are 396–443°C, 417–430°C, and 417–421°C, and 0.38%–1.51%, 0.23%–0.42%, and 0.22%–0.46% in Nkporo shales, Mamu shales, and coals, respectively. The values revealed that Nkporo shales are in immature to early–late hydrocarbon generation stages, whereas Mamu shales and coals are dominantly thermally immature. Further, the analyzed source rocks were deposited under sub-oxic-to-oxic conditions based on molecular indices and petrographic evidence. In the Nkporo shales, there was dominant input from lacustrine organic matter, as evident from the high abundance of C28R sterane, higher C21TT, and n-alkane maxima at n-C20 and n-C23. In contrast, the Mamu shales and coals and crude oil from the Anambra Basin received major input from terrigenous organic matter (high C29 R sterane, C29/C27 ratios, wax index, terrigenous/aquatic ratio (TAR), C19 + 20TT, and n-alkane maxima at n-C27n-C29). The oils (crude oils and condensates) from the Niger Delta are dominated by C29 R steranes, whereas C27 and C

阿南布拉盆地和尼日尔三角洲盆地是尼日利亚南部著名的产油气沉积盆地。在目前的研究中,体积地球化学分析,包括总有机碳(TOC)和岩石热解,分子标记,体积和化合物特异性碳同位素(CSIAs),此外,还对阿南布拉盆地白垩系烃源岩和油气(包括阿南布拉盆地和尼日尔三角洲盆地)进行了有机岩石学分析,以提供阿南布拉盆地ANAR油田液态烃产量突然中断的原因,并为白垩系尼日尔三角洲油气来源的争论提供更多的线索。结果表明,x井的Nkporo页岩和露头的Mamu页岩以II型和III型有机质为主,达到适宜的热成熟度后具有产油能力,而露头的Mamu煤则以II型和II/III型有机质为主,具有良好的生油潜力,但含气较少,特别是在盆地深部。有机质丰度计算结果显示,马木页岩有机质丰度最高(平均TOC为50.74 wt%),而Nkporo页岩有机质丰度最高(平均TOC为2.89 wt%),平均TOC为1.66 wt%。氢指数分析结果表明,烃源岩的生烃潜力在马木煤中最高(平均为329.25 mg HC/g TOC),其次是马木页岩(平均为130.89 mg HC/g TOC),在恩波罗页岩中最低(平均为69.73 mg HC/g TOC)。Nkporo页岩、Mamu页岩和煤的烃源岩最高温度(Tmax)为396 ~ 443℃、417 ~ 430℃和417 ~ 421℃,镜质组/腐质组反射率分别为0.38% ~ 1.51%、0.23% ~ 0.42%和0.22% ~ 0.46%。结果表明,Nkporo页岩处于不成熟-早-晚生烃阶段,而Mamu页岩和煤则以热不成熟为主。此外,根据分子指标和岩石学证据,分析的烃源岩在亚氧-氧条件下沉积。Nkporo页岩中C28R甾烷丰度高,C21TT高,正构烷烃在n-C20和n-C23处最大,湖相有机质输入占主导地位。相比之下,阿南布拉盆地的Mamu页岩和煤、原油主要来自陆源有机质(高C29 R甾烷、C29/C27比值、蜡指数、陆源/水生比(TAR)、C19 + 20TT、正构烷烃最大值在n-C27-n-C29)。尼日尔三角洲原油(原油和凝析油)以C29 R甾烷为主,C27和C28 R甾烷比例不同。油源对比参数还表明,Anambra盆地原油产自Nkporo页岩x井和Mamu页岩及煤热成熟当量。此外,Mamu页岩和煤炭的成分和基因与尼日尔三角洲陆上和海上的石油相似。根据油源对比参数,除存在其他含油气系统要素外,认为阿南布拉盆地存在上白垩统(Mamu-Nkporo /Ajali)含油气系统。短句来源研究认为,ANAR油田Nkporo页岩缺乏丰富的脂质类产油组分和有机质的III型性质是导致该地区液态烃产量骤停的主要原因。同样,在尼日尔三角洲盆地中,深层的白垩纪烃源层对白垩纪石油有贡献。这项研究对未来尼日利亚南部沉积盆地的油气勘探具有重要意义,并将为西非和中非裂谷系统(WCARS)盆地和几内亚湾的现有知识做出贡献。
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引用次数: 0
A Paleotectonic Atlas of the African Plate: Permian to Recent 非洲板块的古构造地图集:二叠纪到近代
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-21 DOI: 10.1111/jpg.70000
Duncan S. Macgregor, Colin V. Reeves

The fragmentary release of petroleum data defining the deep structure and stratigraphy of African basins has been integrated with existing literature to compile 19 tectonic maps over key geological intervals from Permian to Recent times. African plate margins range in their age of opening from Late Triassic (off Lebanon), through Early/Middle Jurassic (Eastern Mediterranean, Central Atlantic, Somali Basin) and Cretaceous (West Africa) to ongoing (northern Red Sea). Their opening follows propagational trends, for example, from the eastern Mediterranean to Guinea and from the Somali Basin in a “smile” shape around southern Africa, eventually to Guinea. Just under half of African margins are rifted margins. North Africa margins are controlled initially by transforms, while volcanic rifted margins dominate in southern Africa. The most debated ocean, the eastern Mediterranean, is demonstrated through well and seismic interpretations to have commenced spreading in late Early to early Middle Jurassic times. Much of West African Cretaceous tectonics, including the generation of strike–slip fault systems, is related to the counter-rotation of Africa versus South America initiated through South Atlantic opening, partly driven by the Bouvet and Tristan Plumes. From the Aptian onward, Africa receives a series of transpressional shocks, largely derived from the Tethyan margin. The most pronounced such event occurs in the Santonian, which is a global-scale event, with? Turonian events in the Indian Ocean also affecting East Africa. Africa is segmented by many interior rifts, with these developed on all mapped intervals, though with peaks of activity in the Permian (South Africa), Late Triassic (North Africa), Early Cretaceous (Central Africa), and Neogene (East Africa). In the Early Cretaceous, a tensional regime is imposed which creates a series of NW-SE trending rifts across the plate: this switches gradually to a N-S rift trend in the Cenozoic. Passive rifts show a high degree of inheritance and can be orientated both perpendicular and parallel to associated strike–slip faults. This type of rift dominates in the Mesozoic, with active plume-related rifts becoming the principal type as mantle activity becomes a more dominant control in the Cenozoic. The Early Cretaceous Sirt Basin is viewed as an isolated plume-related rift, later evolving into a strike–slip associated rift. Analogue-driven hypotheses are proposed for the origin of the more poorly controlled African rifts, such as the Western Desert of Egypt. The formation of the various elements of petroleum systems are responses to these tectonics. For example, geographical trends in basin restriction and potential anoxia are observed to follow the propagational trends of continental breakup.

通过对非洲盆地深部构造和地层资料的零碎整理,结合现有文献,编制了从二叠纪到近代的19张重要地质区间的构造图。非洲板块边缘的开放年代从晚三叠世(黎巴嫩外),到早/中侏罗世(地中海东部、大西洋中部、索马里盆地)和白垩纪(西非)一直到现在(红海北部)。它们的开放遵循了传播趋势,例如,从地中海东部到几内亚,从索马里盆地以“微笑”形环绕非洲南部,最终到几内亚。非洲近一半的边缘是裂谷边缘。北非边缘最初受变形控制,而南部非洲以火山裂谷边缘为主。最具争议的海洋是东地中海,通过油井和地震解释证明,东地中海在早侏罗世晚期到中侏罗世早期开始扩张。西非白垩纪构造的大部分,包括走滑断层系统的产生,都与南大西洋开放引起的非洲与南美洲的反向旋转有关,部分是由布韦和特里斯坦羽流驱动的。从阿普提亚开始,非洲受到了一系列的跨地壳冲击,主要来自特提斯边缘。这类事件中最明显的发生在三东期,这是一个全球性的事件,有?印度洋的突厥事件也影响着东非。非洲被许多内部裂谷分割开来,这些裂谷在所有绘制的区间都发育,尽管在二叠纪(南非)、晚三叠世(北非)、早白垩世(中非)和新近纪(东非)有活动高峰。早白垩世,受拉张作用,形成一系列北西-东南走向的裂谷,并在新生代逐渐转变为北-南走向的裂谷。被动裂谷具有高度的继承性,可与伴生走滑断层垂直或平行定向。这类裂谷在中生代占主导地位,新生代地幔活动对裂谷的控制作用更大,活动的羽状柱相关裂谷成为主要裂谷类型。早白垩世锡尔特盆地被认为是一个孤立的羽状相关裂谷,后来演变为走滑相关裂谷。类似驱动的假说提出了控制较差的非洲裂谷的起源,如埃及的西部沙漠。各种含油气系统元素的形成是对这些构造的反应。例如,观察到盆地限制和潜在缺氧的地理趋势遵循大陆分裂的传播趋势。
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引用次数: 0
Magnetic Properties of Sandstones Within the Zone of Hydrocarbon Migration Near the Boundary of Dukla and Silesian Units (Western Carpathians, Poland) 波兰西喀尔巴阡山脉Dukla - Silesian单元边界附近油气运移带内砂岩磁性特征
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-19 DOI: 10.1111/jpg.70004
Maciej Łoziński, Kamil Kobyliński, Radosław Staniszewski, Anna Wysocka, Anna Filipek

This study represents the application of magnetic techniques in hydrocarbon prospection within the Outer Western Carpathian petroleum play, specifically focusing on the Eocene–Oligocene rocks of southeastern Poland. Magnetic minerals serve as a sensitive proxy for diagenetic processes, particularly concerning hydrocarbon generation, migration, and biodegradation. We investigated the magnetic characteristics of surface rock samples from Dukla and Silesian Units, which have been altered by hydrocarbons migrating through pore spaces and tectonic fissures. The magnetic mineralogy of 29 specimens was analyzed through thermal demagnetization (Lowrie's test), complemented by hysteresis loop and anhysteretic remanence susceptibility measurements to assess domain states and ultrafine grain size ranges. Scanning electron microscope analysis of mineral composition revealed that traces of bitumen and abundant pyrite were common in almost all samples. Ultrafine maghemite emerged as the predominant magnetic mineral within the host rock, with some samples exhibiting varying amounts of ultrafine magnetite, often associated with iron sulfides. Areas adjacent to calcite veins stained with hydrocarbons displayed enhanced magnetic properties, primarily due to increased magnetite content. Additionally, aggregates of barite were identified as accessory minerals within these veins. Our study indicates that detrital iron oxides underwent partial dissolution, leading to the formation of new authigenic minerals such as paramagnetic pyrite and, likely, ultrafine magnetite. These constituents were subsequently transformed partially or completely into maghemite during the oxidation stage of diagenesis. Importantly, the presence of hydrocarbon appears to facilitate the formation of ultrafine (<100 nm) magnetic particles, with magnetite being particularly characteristic of tectonic migration pathways.

本研究代表了磁技术在喀尔巴阡山脉外西油气勘探中的应用,特别是在波兰东南部的始新世-渐新世岩石中。磁性矿物是成岩过程的敏感代表,特别是在烃的生成、运移和生物降解方面。我们研究了Dukla和Silesian单元的地表岩石样品的磁性特征,这些岩石样品已经被碳氢化合物通过孔隙空间和构造裂缝迁移而改变。通过热退磁(Lowrie’s test)分析了29个样品的磁性矿物学,并辅以磁滞回线和非磁滞剩余物敏感性测量,以评估畴态和超细晶粒尺寸范围。扫描电镜分析表明,几乎所有样品均含有沥青和丰富的黄铁矿。超细磁铁矿作为主要的磁性矿物出现在寄主岩石中,一些样品显示不同数量的超细磁铁矿,通常与硫化铁有关。被碳氢化合物染色的方解石脉附近的区域显示出增强的磁性,主要是由于磁铁矿含量增加。此外,重晶石聚集体被确定为这些矿脉中的副矿物。我们的研究表明,碎屑氧化铁经历了部分溶解,导致形成新的自生矿物,如顺磁性黄铁矿,也可能是超细磁铁矿。这些成分随后在成岩作用氧化阶段部分或全部转化为磁赤铁矿。重要的是,碳氢化合物的存在似乎促进了超细(100 nm)磁性颗粒的形成,其中磁铁矿是构造迁移路径的特别特征。
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引用次数: 0
Evolution of Microporosity in Mature Mudstones of the Outer Carpathians, Poland 波兰外喀尔巴阡山脉成熟泥岩微孔隙演化
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-12 DOI: 10.1111/jpg.70003
Olga Odrzygóźdź, Grzegorz Machowski, Mario Borrelli, Marta Waliczek, Edoardo Perri, Marek Szczerba, Mirosław Słowakiewicz

The Polish Carpathian region has over 170 years of conventional hydrocarbon exploration history, with numerous discovered oil and gas fields. In recent years, increasing attention has been given to the potential for new, alternative hydrocarbon deposits. This study evaluates three types of mature mudstones from the Oligocene Menilite Beds, Krosno Beds and Grybów Beds, collected from boreholes in the Polish part of the Outer Carpathians, as potential unconventional source and reservoir rocks. X-ray diffraction (XRD), optical and scanning electron microscopy (SEM), N2 adsorption and mercury injection capillary pressure (MICP) techniques were used to evaluate the pore system, organic matter and mineral composition in each lithofacies. The findings reveal that the Menilite Beds mudstone is thermally mature, with Type II/III kerogen. In contrast, the mudstones of the Grybów and Krosno beds are highly thermally mature, corresponding to the dry gas window stage, with kerogen Types IV and mixed III/IV, respectively. All three formations display a fair total organic carbon (TOC) value (0.7%–1.1%) but have low hydrocarbon generation potential (hydrogen index [HI] < 85 mg HC/g TOC). Microscopic observations confirm the presence of both mineral and organic matter pores in all three mature mudstones. Samples are dominated by nanoporosity (average pore size <14 nm), with low effective porosity values across all samples, ranging from 1.51% to 3.59%. Permeability is very low (0.029–0.081 mD). Nitrogen adsorption isotherms are type IV for all mudstones, with H3/H4 hysteresis loops, indicating slit- and wedge-shaped pores. The SBET N2 values range from 1.352 to 7.277 m2/g, with the highest values for Krosno Beds samples. The mudstones and claystones of the Menilite, Krosno and Grybów beds are primarily affected by compaction, with only a minor influence from cementation and dissolution. The evaluated mudstones do not qualify as effective shale oil/gas source rock; despite good thermal maturity, their hydrocarbon generation potential at the analysed depths is very low. It could be hypothesised that, given the overall volume of nanopores and their interconnectivity, such a potential unconventional hydrocarbon system may occur at greater depths or in regions where hydrocarbon generation potential has been documented, even at shallower depths.

波兰喀尔巴阡山脉地区有170多年的常规油气勘探历史,发现了许多油气田。近年来,人们越来越关注潜在的新的替代碳氢化合物矿床。本研究对外喀尔巴阡山脉波兰部分钻孔中收集的渐新世Menilite床、Krosno床和Grybów床的三种成熟泥岩进行了评价,认为它们是潜在的非常规烃源岩和储层。采用x射线衍射(XRD)、光学和扫描电镜(SEM)、氮气吸附和注汞毛细管压力(MICP)等技术对各岩相孔隙系统、有机质和矿物组成进行了评价。研究结果表明,蒙利岩层泥岩热成熟,干酪根类型为II/III型。Grybów层和Krosno层泥岩热成熟程度较高,属于干气窗期,干酪根类型分别为IV型和III/IV型混合。三个地层的总有机碳(TOC)值均为0.7% ~ 1.1%,但生烃潜力较低(氢指数[HI] <; 85 mg HC/g TOC)。显微观察证实,三种成熟泥岩均存在矿物和有机质孔隙。样品以纳米孔隙度(平均孔径为14 nm)为主,有效孔隙度值较低,范围为1.51% ~ 3.59%。渗透率很低(0.029-0.081 mD)。所有泥岩的氮吸附等温线均为IV型,具有H3/H4型滞回线,表明孔隙呈缝状或楔状。SBET N2值为1.352 ~ 7.277 m2/g,以Krosno床层样品最高。Menilite、Krosno和Grybów层的泥岩和粘土岩主要受压实作用的影响,胶结作用和溶蚀作用影响较小。评价的泥岩不能作为有效的页岩油气源岩;尽管热成熟度良好,但在分析深度的生烃潜力很低。可以假设,考虑到纳米孔的总体体积和它们之间的连通性,这种潜在的非常规油气系统可能出现在更深的深度,或者在已记录有生烃潜力的区域,甚至在较浅的深度。
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引用次数: 0
A New Saturated and Aromatic Hydrocarbon-Based Scheme to Decipher the Origin of Extracted Organic Matter in the Outer Carpathians: From the Jurassic to the Miocene 以饱和烃和芳烃为基础的新方案来解释喀尔巴阡山脉外提取有机质的来源:从侏罗纪到中新世
IF 1.7 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-04 DOI: 10.1111/jpg.70001
Mirosław Słowakiewicz

In this review, published and new geochemical data characterising 17 potential source rocks for hydrocarbons in the Polish part of the Outer Carpathians have been used to establish a new scheme that can be useful for oil–source rock correlations. Rock and drill core samples, ranging in age from Jurassic to Miocene, were analysed using Rock-Eval pyrolysis. The results confirmed that the best source rock is shale from the Oligocene Menilite Beds, particularly the so-called deep shale, occurring at depths greater than 4000 m. The Palaeocene/Eocene mudstone interbeds in the Istebna Beds can serve as a source rock for natural gas, although only locally, due to their highly irregular geochemical parameters. Lower Cretaceous strata, specifically the fine-grained sediments of the Spas Shales, Lgota Beds and Veřovice Beds, appear to be significant for microbial generation of methane. Molecular analysis of extractable organic matter, combined with pyrolytic data, revealed a wide range of organic matter maturation stages, from immature to overmature. These analyses also identified rare zones of high maturity at shallow depths in source rocks, confirming the upwards displacement of once deeply buried strata in the Outer Carpathians. Additionally, the saturated and aromatic hydrocarbon-based compounds and their ratios revealed characteristic biomarkers and polycyclic aromatic hydrocarbons (PAHs) that differentiate various shale- (mudstone, claystone) or marl-rich formations within specific lithostratigraphic units. These chemical compounds serve as strong tools for deciphering the origin of oils in the Outer Carpathians, regardless of the organic matter's maturity level. This age-based molecular characterisation highlights the particular importance of higher plant-derived compounds, such as oleanane isomers, which are most abundant in the Oligocene samples but also present in Kimmeridgian shale. Aromatised terpenoid precursors, in turn, are abundant in shale from the Menilite Beds as well as in the Krosno and Istebna beds. Terrigenous organic matter is also accompanied by algal-derived components (e.g., dinosteroids) and bacterial contributions (e.g., hopanes). Finally, the analysed organic matter was deposited in sedimentary basins under varied redox conditions. Anoxic environments were confirmed by high bisnorhopane/C30 hopane ratios, whereas oxic to suboxic conditions were indicated by high pristane/phytane ratios, suggesting a mixed oxic–anoxic water column.

在这篇综述中,已经发表的和新的地球化学数据描述了外喀尔巴阡山脉波兰部分17个潜在烃源岩的特征,并建立了一个新的方案,可以用于油源岩对比。岩石和岩心样品,年龄范围从侏罗纪到中新世,分析了岩石- eval热解。结果表明,渐新世Menilite地层的页岩是最佳烃源岩,尤其是深度大于4000 m的深层页岩。古新统/始新统泥岩互层地球化学参数高度不规则,可作为天然气的局部源岩。下白垩统地层,特别是Spas页岩、Lgota地层和Veřovice地层的细粒沉积物,似乎对微生物生成甲烷具有重要意义。可提取有机质的分子分析结合热解数据,揭示了从未成熟到过成熟的有机质成熟阶段。这些分析还在烃源岩的浅层深处发现了罕见的高成熟度带,证实了外喀尔巴阡山脉曾经深埋的地层向上位移。此外,饱和烃和芳烃基化合物及其比值揭示了在特定岩性地层单元内区分不同页岩(泥岩、粘土岩)或富泥灰岩地层的特征生物标志物和多环芳烃(PAHs)。无论有机物质的成熟度如何,这些化合物都是破译外喀尔巴阡山脉石油来源的有力工具。这种基于年龄的分子特征强调了高等植物衍生化合物的特别重要性,例如齐墩烷异构体,它们在渐新世样品中最丰富,但也存在于基默里纪页岩中。芳香化萜类前体在Menilite地层以及Krosno和Istebna地层的页岩中含量丰富。陆源有机物也伴随着藻类衍生成分(如恐龙类固醇)和细菌贡献(如藿烷)。最后,分析的有机质沉积于不同氧化还原条件下的沉积盆地。缺氧环境由高的双去甲藿烷/C30藿烷比值证实,而高的蒽/植烷比值表明缺氧条件为缺氧-缺氧混合水柱。
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Journal of Petroleum Geology
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