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Spheroid-based optical cavities for tunable photon recycling and emitter temperature control in robust solar thermophotovoltaic systems 用于可调谐光子回收和鲁棒太阳能热光伏系统发射极温度控制的球形光学腔
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1117/1.JPE.13.018501
Nima Talebzadeh, P. O'Brien
Abstract. The theoretical efficiency of solar thermophotovoltaic (STPV) systems is much greater than their efficiencies achieved in practice. Optical cavities can improve the performance of STPV systems by increasing the emitter-to-PV cell view factor and by facilitating photon recycling, whereby photons are reflected back to the emitter. Photon recycling reduces losses and increases the temperature of the emitter, thereby increasing efficiency. Our study presents STPV systems comprising optical cavities in the form of oblate and prolate spheroids. The geometry of the optical cavity can be tuned to control the degree of photon recycling, emitter temperature, emission losses, and the emitter-to-PV cell effective view factor and separation distance without using complex nano- or microstructured materials or optical filters. Numerical analysis shows an optical cavity in the form of a prolate spheroid, prolate spheroid with a middle annular aperture specular reflector, and integrated oblate- and prolate-spheroid can be used to achieve efficiencies of 17.7%, 18.9%, and 22%, respectively, under solar irradiation at a concentration factor of 1500X. These robust spheroid-based optical cavities can be used to design improved STPV systems with increased durability and higher performance.
摘要太阳能热光伏(STPV)系统的理论效率远大于其在实践中实现的效率。光学腔可以通过增加发射器到光伏电池的视角因子和促进光子回收来提高STPV系统的性能,从而将光子反射回发射器。光子回收减少了损失并提高了发射器的温度,从而提高了效率。我们的研究提出了STPV系统,包括扁球体和长球体形式的光学腔。在不使用复杂的纳米或微结构材料或滤光器的情况下,可以调整光学腔的几何形状以控制光子回收的程度、发射器温度、发射损耗以及发射器到PV电池的有效视角因子和分离距离。数值分析表明,在1500X的太阳辐射下,采用椭球体、带中间环形孔径镜面反射器的椭球体以及集成扁椭球体和椭球体形式的光学腔可以分别获得17.7%、18.9%和22%的效率。这些坚固的基于球体的光学腔可用于设计具有更高耐用性和更高性能的改进型STPV系统。
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引用次数: 0
Multirod approach to enhance solar-to-laser conversion efficiency in the Odeillo solar furnace 多棒方法提高Odeillo太阳能炉的太阳能-激光转换效率
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-10-01 DOI: 10.1117/1.JPE.12.048001
H. Costa, J. Almeida, D. Liang, D. Garcia, M. Catela, B. Tibúrcio, C. Vistas
Abstract. A multirod solar laser station for the megawatt solar furnace (MWSF) in Odeillo, France, was conceptualized and numerically studied to improve the solar-to-laser power conversion efficiency. 18 heliostats from the 63-heliostat field were selected, and 347 kW of solar power was obtained at its focus. From there, a two-dimensional compound parabolic concentrator further concentrated and redistributed the solar rays toward 11 core-doped Nd:YAG rods, each fixed inside a fused silica flow tube. 11.40 kW of total multimode laser power was calculated, corresponding to a 3.29% solar-to-laser power conversion efficiency. This efficiency value represents an enhancement of 1.70 and 1.26 times over that attained from single-rod solar laser systems in side-pumping configuration tested in Odeillo, France, in which Nd:YAG rods were codoped with Cr3  +   and Ce3  +   ions, respectively. It was also 1.44 times higher than that obtained by a previously proposed side-pumping scheme with a solar flux homogenizer and 12 Nd:YAG rods for the same MWSF.
摘要为提高太阳能-激光功率转换效率,对法国奥代洛兆瓦太阳能炉(MWSF)的多棒太阳能激光站进行了概念化和数值研究。从63个定日镜场中选择了18个定日器,并在其焦点处获得347kW的太阳能。从那里,一个二维复合抛物面聚光器将太阳光线进一步集中并重新分布到11个核心掺杂Nd:YAG棒上,每个棒都固定在熔融石英流管内。计算出11.40kW的总多模激光功率,对应于3.29%的太阳能到激光功率转换效率。该效率值比在法国Odeillo测试的侧面泵浦配置中的单棒太阳能激光系统提高了1.70和1.26倍,其中Nd:YAG棒与Cr3共掺杂  +   和Ce3  +   离子。对于相同的MWSF,它也比之前提出的具有太阳能通量均化器和12根Nd:YAG棒的侧面泵浦方案高1.44倍。
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引用次数: 0
Ni2O3-modified SrTiO3 for enhanced visible-light photocatalytic CO2 reduction activity ni2o3修饰SrTiO3增强可见光光催化CO2还原活性
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-10-01 DOI: 10.1117/1.JPE.12.046501
Qi Zhang, Yuan Kong, Yang Ge, Yao Zhang, Junwei Liang, J. Chen, Hangxiang Wang, Quanhong Ma, Jiancheng Zhou
Abstract. Low-cost and effective cocatalyst Ni2O3 was loaded on SrTiO3 (STO) via a simple one-step hydrothermal method. The Ni2O3  /  SrTiO3  (  m  )   photocatalysts were systematically characterized and applied to visible-light-driven CO2 reduction to investigate their photocatalytic activity. The series of the Ni2O3-modified SrTiO3 photocatalysts presented an improved photocatalytic activity and stability. Here, the N5.4STO  (  m  )   catalyst showed the best photocatalytic activity, with CO and CH4 yielding up to 11.57 and 1.51  μmol  /  g, respectively, under visible-light irradiation of 3 h, which were 3.15 and 14.84 times higher than that of pure STO(m), respectively. Based on the characterization and experimental results, the enhanced photocatalytic activity might be attributed to the following reasons: (1) Ni2O3 well dispersed on SrTiO3 served as CO2 attachment sites; (2) the modification of Ni2O3 could red shift the absorption edge and broaden the visible-light response ability; and (3) Ni2O3 nanoparticles act as electron traps to capture photogenerated electrons, effectively blocking the recombination of electron–hole pairs. The work offers important insights into the design of non-noble metal oxide cocatalyst modified photocatalysts for electron capture and photoreduction.
摘要采用简单的一步水热法在SrTiO3 (STO)上负载了低成本、高效的助催化剂Ni2O3。对Ni2O3 / SrTiO3 (m)光催化剂进行了系统表征,并将其应用于可见光驱动的CO2还原中,考察了其光催化活性。ni2o3修饰的SrTiO3光催化剂具有较好的光催化活性和稳定性。其中,N5.4STO (m)催化剂表现出最好的光催化活性,在可见光照射3 h下,CO和CH4的产率分别达到11.57和1.51 μmol / g,分别是纯STO(m)的3.15和14.84倍。基于表征和实验结果,光催化活性的增强可能归因于以下原因:(1)Ni2O3在SrTiO3上分散良好,成为CO2的附着位点;(2) Ni2O3改性能使吸收边红移,可见光响应能力变宽;(3) Ni2O3纳米颗粒作为电子陷阱捕获光生电子,有效阻止电子-空穴对的复合。这项工作为设计用于电子捕获和光还原的非贵金属氧化物修饰光催化剂提供了重要的见解。
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引用次数: 0
Enhancing radiative cooling performance for bifacial photovoltaic module using two kinds of polycarbonate films 利用两种聚碳酸酯薄膜增强双面光伏组件的辐射冷却性能
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-10-01 DOI: 10.1117/1.JPE.12.045501
Yanfang Zhou, Tairan Xia, Xinwei Niu, Shouliang Sun, Li Xu, Yanzhen Jian, Han Wang
Abstract. Radiative cooling, as a cooling method that does not consume any energy during operation, has become a hot topic in recent years. Unlike passive daytime radiative cooling in buildings, radiative coolers used in photovoltaic modules must also have high light transmittance, which undoubtedly makes relevant research more difficult. Currently, bifacial photovoltaic modules are widely available on the market, if traditional cooling methods are employed in the back of them, including passive cooling such as heat sink and active cooling such as air cooling and water cooling, it will block the rear irradiance into the module. Hence, radiative cooling is an excellent solution. In this paper, polycarbonate (PC) film and one composed with a high reflective layer are proposed. The former has high emissivity in the atmospheric window and the latter has high reflectivity in the near-infrared band. Both achieve a good cooling effect without affecting the normal operation of the module. We also prepared the reflective film on PC by magnetron sputtering, and its optical characteristics were also measured and compared with simulation results. We innovatively use PC material and combine the reflective film with quite simple structure. Compared with other research results, they are simpler and stabler film structures and have the advantages of low cost, easy installation, good cooling effect, and can be directly pasted on the surface of the photovoltaic module. It turns out that the cooling effect can reach 6.02°C with R-PC film and photoelectric conversion efficiency can be improved by 0.27% with PC film when hc  =  20  W  ·  m  −  2  ·  K  −  1 and Ta  =  27  °  C. Given its excellent performance, they have a broad application prospect in the daytime passive radiative cooling of bifacial photovoltaic modules.
摘要辐射冷却作为一种在运行过程中不消耗任何能量的冷却方法,近年来已成为一个热门话题。与建筑中的被动式日间辐射冷却不同,光伏组件中使用的辐射冷却器也必须具有高透光率,这无疑增加了相关研究的难度。目前,双面光伏模块在市场上广泛可用,如果在其背面采用传统的冷却方法,包括散热器等被动冷却和空气冷却和水冷却等主动冷却,将阻挡模块的背面辐照度。因此,辐射冷却是一个很好的解决方案。本文提出了聚碳酸酯(PC)薄膜和一种由高反射层组成的薄膜。前者在大气窗口具有高发射率,而后者在近红外波段具有高反射率。两者都能在不影响模块正常运行的情况下实现良好的冷却效果。我们还通过磁控溅射在PC上制备了反射膜,并对其光学特性进行了测量,并与模拟结果进行了比较。我们创新性地使用PC材料,并结合了结构非常简单的反射膜。与其他研究结果相比,它们是更简单、更稳定的薄膜结构,具有成本低、安装方便、冷却效果好、可以直接粘贴在光伏组件表面等优点。结果表明,采用R-PC薄膜的冷却效果可达到6.02°C,采用PC薄膜的光电转换效率可提高0.27%  =  20  W  ·  m  −  2.  ·  K  −  1和Ta  =  27  °  C.由于其优异的性能,它们在双面光伏组件的日间被动辐射冷却方面具有广阔的应用前景。
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引用次数: 2
Influence of thermal population of lower laser levels on the performance of end-side-pumped Ce:Nd:YAG solar laser 低能级热密度对端侧泵浦Ce:Nd:YAG太阳能激光器性能的影响
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-10-01 DOI: 10.1117/1.JPE.12.044501
S. Payziyev, A. Sherniyozov
Abstract. We report the results of a theoretical study of the combined end-side pumped solar lasers to solve the problem associated with a recent experimental finding where the unexpected underperformance of the Ce doped Nd:YAG lasers in comparison to pure Nd:YAG lasers was observed. For this, we have developed a theoretical model based on space-dependent rate equations, which considers the effect of the thermal population of the laser levels on the laser output. It is shown that the main reason for the lower laser performance of recently experimentally realized Ce:Nd:YAG solar laser in the end-pumped regime and the fracture of the Ce:Nd:YAG rod at the process is the excessively high thermal load on the end of the laser rod. As a result of our study, we propose easily-feasible solutions based on optimal pumping and cooling configurations. The results of this study also demonstrate that under the necessary conditions, using Ce:Nd:YAG as an alternative to Nd:YAG in the combined end-side pumping configuration could increase the laser output by more than 1.5 times.
摘要我们报道了一项对组合端侧泵浦太阳能激光器的理论研究结果,以解决与最近的一项实验发现相关的问题,在该实验发现中,与纯Nd:YAG激光器相比,Ce掺杂的Nd:YAG激光表现不佳。为此,我们开发了一个基于空间相关速率方程的理论模型,该模型考虑了激光能级的热布居对激光输出的影响。结果表明,最近实验实现的Ce:Nd:YAG太阳激光器在端泵浦状态下激光性能较低以及在此过程中Ce:Nd:YAG棒断裂的主要原因是激光棒端部的热负荷过高。根据我们的研究结果,我们提出了基于最佳泵送和冷却配置的简单可行的解决方案。本研究的结果还表明,在必要的条件下,在端侧组合泵浦配置中使用Ce:Nd:YAG作为Nd:YAG的替代品,可以将激光输出提高1.5倍以上。
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引用次数: 2
Cylindrical transparent conductive oxide-free dye-sensitized solar cells with treated flat titanium sheet 圆柱形透明导电无氧化染料敏化太阳能电池,处理扁平钛片
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-10-01 DOI: 10.1117/1.JPE.12.045502
A. Hayat, A. Baranwal, Masaki Nakamura, Fujisawa Shigeki, S. Pandey, S. Hayase
Abstract. Conventional dye-sensitized solar cells (DSSCs) require two transparent conductive oxide (TCO) glasses as working and counter electrodes and are one of the most costly components posing an appreciable cost burden for production and commercialization. To circumvent this issue, we propose a TCO-free device structure utilizing titanium (Ti) sheets as a substitute for TCO. This back contact device structure not only allows the removal of the costly TCO component from the working electrode but also enhances the extent of photons absorbed by the photoanode. A flat titanium sheet with microholes (FTS-MH) was successfully applied to fabricate cylindrical TCO-free-DSSCs) with a titanium sheet as a back contact electrode. When the H2O2 surface-treated FTS-MH substrate generating dense anatase TiO2 nanosheets was used as a photoanode, there was a pronounced improvement in efficiency from 5.76% to 8.59%. This was mainly attributed to the lower interfacial resistance facilitated by improved electrical contact between the conducting FTS-MH substrate and mesoporous TiO2 layer since enhancement in the dye loading was only 8.6%.
摘要传统的染料敏化太阳能电池(DSSC)需要两种透明导电氧化物(TCO)玻璃作为工作电极和对电极,并且是对生产和商业化造成明显成本负担的最昂贵的部件之一。为了避免这个问题,我们提出了一种利用钛(Ti)片作为TCO替代品的无TCO器件结构。这种背接触器件结构不仅允许从工作电极去除昂贵的TCO成分,而且增强了光阳极吸收光子的程度。成功地将具有微孔的扁平钛片(FTS-MH)应用于以钛片作为背接触电极的圆柱形无TCO DSSC。当使用H2O2表面处理的产生致密锐钛矿TiO2纳米片的FTS-MH衬底作为光阳极时,效率从5.76%显著提高到8.59%。这主要归因于导电的FTS-MH基底和介孔TiO2层之间的电接触的改善促进了较低的界面电阻,因为染料负载的增强仅为8.6%。
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引用次数: 0
Shell-shaped active layers for omnidirectional organic photovoltaic cells 用于全向有机光伏电池的壳形有源层
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-10-01 DOI: 10.1117/1.JPE.12.048501
D. Hah
Abstract. For the employment of organic photovoltaic cells in wearable electronic systems, improvements in energy conversion efficiency and omnidirectionality (angular coverage) are highly appreciated. This study aims at those improvements by introducing shell-shaped active layers. The proposed device structures enhance light absorption and angular range through light coupling to guided modes in the active layer. Two shapes, i.e., a triangle and a semicircle, are examined for the shell cross-sections. Numerical simulation using finite-element analysis and finite-difference time-domain methods demonstrates that the devices with the triangular-shell-shaped active layers exhibit an average absorption enhancement of up to 63% for transverse electric (TE)-polarization and up to 32% for transverse magnetic (TM)-polarization when compared with the flat active layers of the same thicknesses. The average enhancements of the semicircular-shell-shaped active layers are found to be slightly lower than those values, with 60% for TE and 28% for TM. The examined structures also show good omnidirectionality with decent absorption up to an 81 deg incidence angle for the triangular-shell-shaped device and up to a 76 deg angle for the semicircular one when TM polarization is considered. These absorption enhancements and improved angular coverages make the proposed structures highly attractive for wearable electronic system applications.
摘要对于在可穿戴电子系统中使用有机光伏电池,能量转换效率和全方向性(角度覆盖)的改进受到高度赞赏。本研究旨在通过引入壳状活动层来改善这些问题。所提出的器件结构通过光耦合到有源层中的引导模式来增强光吸收和角度范围。两种形状,即三角形和半圆,对壳体截面进行了检查。利用有限元分析和时域有限差分方法进行的数值模拟表明,与相同厚度的扁平有源层相比,具有三角形壳型有源层的器件对横向电极化(TE)和横向磁极化(TM)的平均吸收增强可达63%和32%。半圆壳型活性层的平均增强值略低于这些值,TE为60%,TM为28%。考虑TM偏振时,三角形壳型器件的吸收角为81°,半圆形器件的吸收角为76°,具有良好的全方向性。这些吸收增强和改进的角度覆盖使所提出的结构对可穿戴电子系统应用具有很高的吸引力。
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引用次数: 0
Side-pumped efficient Ce:Nd:YAG solar laser in a multi-pass scheme 侧泵浦高效Ce:Nd:YAG太阳能激光器的多通方案
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-07-01 DOI: 10.1117/1.JPE.12.034501
A. Sherniyozov, S. Payziyev
Abstract. We studied possible techniques for increasing the power-to-power conversion efficiency of the Ce:Nd:YAG solar laser using a simulation model developed with the Monte-Carlo photon tracing method framework. It is suggested that the multi-passage of photons through a medium can enhance the absorption probability. The effectiveness of the multi-pass scheme is experimentally investigated. The application of the multi-pass pumping scheme for Ce:Nd:YAG solar lasers is demonstrated. It is shown that the pumping efficiency in the Ce:Nd:YAG solar laser with the multi-pass pumping cavity is increased by 20%, paving the way for higher power-to-power conversion efficiency.
摘要我们利用蒙特卡罗光子跟踪方法框架建立的仿真模型,研究了提高Ce:Nd:YAG太阳能激光器功率-功率转换效率的可能技术。结果表明,光子通过介质的多通道可以提高光子的吸收概率。实验验证了多通道方案的有效性。介绍了多通道泵浦方案在Ce:Nd:YAG太阳激光器中的应用。结果表明,采用多通道抽运腔的Ce:Nd:YAG太阳能激光器的抽运效率提高了20%,为提高功率-功率转换效率铺平了道路。
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引用次数: 1
Collection of photocarriers in intermediate band solar cells: experiments and equivalent circuit analysis 中间带太阳能电池中光载流子的收集:实验和等效电路分析
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-07-01 DOI: 10.1117/1.JPE.12.032210
N. Ahsan, N. Miyashita, K. Yu, W. Walukiewicz, Y. Okada
Abstract. The unique electronic features of highly mismatched alloys such as III-V GaNAs are suitable for the intermediate band solar cell (IBSC) application, in which an intermediate band (IB) acts as a stepping stone to generate additional photocarriers across the host semiconductor bandgap through sequential two-step below-bandgap photon absorption (TSPA). However, the collection of photocarriers in a realistic GaNAs IBSC is much lower and often accompanies S-shape kink features in the current–voltage (J–V) curves under illumination for which a coherent picture is lacking. Based on the solar cell characterization of GaNAs IBSC devices grown with and without barriers, with and without antimony, and with and without indium using molecular beam epitaxy, and also with the photocarrier collection analysis using equivalent circuit models, it was identified that the TSPA and the S-shape J–V of this system depend on two critical factors: (1) high carrier recombination currents (I0CI) across the GaNAs sub-gap between the conduction- and intermediate bands (EgCI) and (2) the counterdiode effect of the AlGaAs IB electron barrier. Dramatic improvements in the S-shape J–V feature of the solar cell characteristics were achieved when lattice-strain was compensated in GaInNAsSb epitaxial layers.
摘要高度不匹配合金(如III-V型gaas)的独特电子特性适用于中间带太阳能电池(IBSC)应用,其中中间带(IB)作为垫脚石,通过带隙下连续两步光子吸收(TSPA)在宿主半导体带隙中产生额外的光载流子。然而,在现实的gaas IBSC中,光载流子的收集量要低得多,并且在照明下的电流-电压(J-V)曲线中经常伴有s形扭结特征,这是缺乏相干图像的。基于利用分子束外延对加和不加阻挡、加和不加锑、加和不加铟的gaas IBSC器件的太阳能电池特性,以及利用等效电路模型对光载流子收集的分析,确定了该系统的TSPA和s形J-V取决于两个关键因素:(1)高载流子复合电流(I0CI)穿过导电带和中间带之间的gaas子隙(EgCI)和(2)AlGaAs IB电子势垒的反二极管效应。当晶格应变在GaInNAsSb外延层中进行补偿时,太阳能电池的s形J-V特性得到了显著改善。
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引用次数: 0
Evaporation performance of self-cleaning evaporator with one-dimensional water supply channel for solar evaporation 太阳能蒸发用一维给水通道自洁蒸发器的蒸发性能
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-07-01 DOI: 10.1117/1.JPE.12.038001
Huiling Duan, Yujie Yan, Tong Ling, Yiding Wang
Abstract. Cotton rope has good water transport performance and plasticity. An efficient three-dimensional evaporator for solar evaporation was prepared by winding the cotton rope into different shapes and covering its surface with carbon black (CB). The light absorption of the evaporator coated with CB was significantly improved, and the average absorptance was 95.8% over the solar spectrum. Using a one-dimensional channel for water supply, the evaporator and bulk water were separated, and thermal localization was realized without thermal insulation materials. The influence of the evaporator shape on evaporation performance was analyzed. Under the same conditions, the evaporation rate of funnel-shaped evaporator was the highest, reaching 1.3033  kg  /  m2 h. The multiple reflection of light in the funnel-shaped evaporator promoted the capture and absorption of incident light. For the evaporator with a reflector placed below, the evaporation rates of funnel-shaped, plane-shaped, and umbrella-shaped evaporators increased by 2.3%, 1.67%, and 0.814%, respectively. In addition, the evaporator has a self-cleaning function. The salt deposited on the surface can be redissolved and leaves the evaporator with water. An efficient solar evaporator was designed in a simple and economical way. Its self-cleaning function is especially suitable for seawater desalination.
摘要棉绳具有良好的输水性能和可塑性。通过将棉绳缠绕成不同形状并在其表面覆盖炭黑,制备了一种用于太阳能蒸发的高效三维蒸发器。涂有CB的蒸发器的光吸收率显著提高,在太阳光谱上的平均吸收率为95.8%。采用一维通道供水,将蒸发器和本体水分离,在没有隔热材料的情况下实现了热局部化。分析了蒸发器形状对蒸发性能的影响。在相同条件下,漏斗形蒸发器的蒸发率最高,达到1.3033  公斤  /  m2 h.光在漏斗形蒸发器中的多次反射促进了入射光的捕获和吸收。对于下面放置有反射器的蒸发器,漏斗形、平面形和伞形蒸发器的蒸发率分别增加了2.3%、1.67%和0.814%。此外,蒸发器还具有自清洁功能。沉积在表面上的盐可以再溶解,并与水一起离开蒸发器。以一种简单、经济的方式设计了一种高效的太阳能蒸发器。其自清洁功能特别适用于海水淡化。
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引用次数: 0
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Journal of Photonics for Energy
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