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Analytical modeling and design optimization of a graphene/n-GaAs Schottky junction solar cell 石墨烯/n-GaAs肖特基结太阳能电池的分析建模与设计优化
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-04-01 DOI: 10.1117/1.JPE.12.025502
Md Azmot Ullah Khan, Naheem Olakunle Adesina, Jian Xu
Abstract. A physics-based analytical model is important to understand the working mechanism through process parameters of any innovative material heterostructure. We present an analytical model to calculate the power conversion efficiency of solar cells based on graphene and III-V direct bandgap semiconductors. The model is comprehensively developed by incorporating several current densities obtained from both the generation and recombination processes. Moreover, to obtain a highly efficient Schottky junction solar cell, we propose an optimized structure of graphene/GaAs with lattice-matched passivation and carrier selective layers. The structure has the advantage of surface passivation and photon recycling that reduces interface recombination and ensures more electron–hole pair generation, respectively. It exhibits a theoretical efficiency of >18  %   from the analytical model simulation which is later verified by numerical simulation using SCAPS 1D software. The analytical model will provide not only a better understanding of the solar cells’ operation but also a comparative study among them to achieve better efficiency in the future. In addition, the enhanced efficiency of the proposed structure will encourage further research in this field of study.
摘要一个基于物理的分析模型对于理解任何创新材料异质结构的工艺参数的工作机理都是非常重要的。我们提出了一个分析模型来计算基于石墨烯和III-V直接带隙半导体的太阳能电池的功率转换效率。该模型综合了从生成和重组过程中获得的几个电流密度。此外,为了获得高效的肖特基结太阳能电池,我们提出了一种具有晶格匹配钝化层和载流子选择层的石墨烯/砷化镓的优化结构。该结构具有表面钝化和光子循环的优点,分别减少了界面复合和确保了更多的电子-空穴对的产生。通过分析模型模拟,该方法的理论效率为18%,并利用SCAPS 1D软件进行了数值模拟。该分析模型不仅可以更好地了解太阳能电池的运行情况,还可以对它们进行比较研究,以便在未来实现更好的效率。此外,拟议结构效率的提高将鼓励这一研究领域的进一步研究。
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引用次数: 1
Pathways to hot carrier solar cells 热载体太阳能电池的途径
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-04-01 DOI: 10.1117/1.JPE.12.022204
D. Ferry, V. R. Whiteside, I. Sellers
Abstract. Hot carrier solar cells (HCSCs) were first proposed many decades ago. Over the intervening years, there has been a continuing quest to create these cells that hold promise to shatter the Shockley–Queisser efficiency limit on single-junction solar cells. While there have been many positive and suggestive results in recent years, there remains no true operational HCSC. There are perhaps many reasons for this state. Here, many of the requirements for achieving such an HCSC will be discussed and some approaches will be modernized in terms of their science. Valley photovoltaics, in which carriers are transferred to higher-lying valleys of the conduction band will be described and the recent progress is discussed.
摘要热载流子太阳能电池(HCSC)是几十年前首次提出的。在这中间的几年里,人们一直在寻求制造这些电池,这些电池有望打破单结太阳能电池的Shockley–Queisser效率限制。尽管近年来取得了许多积极和有启发性的成果,但仍然没有真正可行的HCSC。造成这种状况的原因可能有很多。在这里,将讨论实现这种HCSC的许多要求,并将在科学方面对一些方法进行现代化。将描述载流子转移到导带的较高谷的谷光伏,并讨论最近的进展。
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引用次数: 3
Lateral spectrum splitting system with perovskite photovoltaic cells 钙钛矿光伏电池横向分光系统
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-04-01 DOI: 10.1117/1.JPE.12.022206
Benjamin D. Chrysler, S. Shaheen, R. Kostuk
Abstract. We examine the potential of a multijunction spectrum-splitting photovoltaic (PV) solar energy system with perovskite PV cells. Spectrum splitting allows combinations of different energy band gap PV cells that are laterally separated and avoids the complications of fabricating tandem stack architectures. Volume holographic optical elements have been shown to be effective for the spectrum-splitting operation and can be incorporated into compact module packages. However, one of the remaining issues for spectrum splitting systems is the availability of low-cost wide band gap and intermediate band gap cells that are required for realizing high overall conversion efficiency. Perovskite PV cells have been fabricated with a wide range of band gap energies that potentially satisfy the requirements for multijunction spectrum-splitting systems. A spectrum-splitting system is evaluated for a combination of perovskite PV cells with energy band gaps of 2.30, 1.63, and 1.25 eV and with conversion efficiencies of 10.4%, 21.6%, and 20.4%, respectively, which have been demonstrated experimentally in the literature. First, the design of a cascaded volume holographic lens for spectral separation in three spectral bands is presented. Second, a rigorous coupled wave model is developed for computing the diffraction efficiency of a cascaded hologram. The model accounts for cross-coupling between higher diffraction orders in the upper and lower holograms, which previous models have not accounted for but is included here with the experimental verification. Lastly, the optical losses in the system are analyzed and the hypothetical power conversion efficiency is calculated to be 26.7%.
摘要我们研究了具有钙钛矿光伏电池的多结光谱分裂光伏(PV)太阳能系统的潜力。光谱分裂允许横向分离的不同能带隙PV电池的组合,并避免了制造串联堆叠结构的复杂性。体全息光学元件已被证明对光谱分裂操作是有效的,并且可以被结合到紧凑的模块封装中。然而,频谱分割系统的剩余问题之一是实现高整体转换效率所需的低成本宽带隙和中频隙单元的可用性。钙钛矿光伏电池已被制造成具有广泛的带隙能量,这些带隙能量可能满足多结光谱分裂系统的要求。对能带隙分别为2.30、1.63和1.25eV,转换效率分别为10.4%、21.6%和20.4%的钙钛矿光伏电池组合的光谱分裂系统进行了评估,这已在文献中得到实验证明。首先,设计了一种级联体全息透镜,用于三个光谱带的光谱分离。其次,建立了计算级联全息图衍射效率的严格耦合波模型。该模型考虑了上全息图和下全息图中较高衍射级之间的交叉耦合,以前的模型没有考虑到这一点,但在实验验证中也包括了这一点。最后,分析了系统中的光学损耗,计算出假设的功率转换效率为26.7%。
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引用次数: 2
Investigation of dependence of solar-pumped laser power on laser medium length 太阳能泵浦激光功率与激光介质长度相关性的研究
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-03-29 DOI: 10.1117/1.JPE.12.026501
Zitao Cai, Changming Zhao, Haiyang Zhang, Zilong Zhang, Xingyu Yao, Ziying Zhao
Abstract. The efficiency of solar-pumped lasers (SPLs) is limited when the length of the laser medium is unsuitable. This is because superfluous regions in the laser medium introduce losses and contribute slightly to the stimulation of radiation in the laser resonator. Before designing an SPL, an appropriate length of laser medium is critical. We present a method to calculate the optimal length of the gain medium in SPLs by exploring the relationship between the absorbed solar power and material loss for different laser medium lengths. Thus, the lengths of Nd:YAG crystals with diameters of 3 to 6 mm were optimized, and the output characteristics were calculated numerically. The maximum collection efficiency (CE) (40.1  W  /  m2) was obtained for the 5.5-mm diameter Nd:YAG crystal rod of length 21.1 mm, which was 1.7  W  /  m2 higher than the previous numerical record. The optimal length of the 6-mm diameter Nd:YAG crystal rod was found to be 21.9 mm. For a laser rod of this length, a CE of 36.3  W  /  m2 is expected. This value is 1.13 times greater than the existing experimental record for the Nd:YAG crystal of the same diameter, which highlights the importance of optimizing the length of the laser rod.
摘要当激光介质长度不合适时,太阳能泵浦激光器的效率受到限制。这是因为激光介质中的多余区域引入了损耗,并且对激光谐振腔中的辐射刺激有轻微的贡献。在设计声压级光源之前,选择合适的激光介质长度是至关重要的。通过研究不同激光介质长度下太阳能吸收功率与材料损耗之间的关系,提出了一种计算增益介质最佳长度的方法。为此,对直径为3 ~ 6 mm的Nd:YAG晶体长度进行了优化,并对其输出特性进行了数值计算。对于直径5.5 mm、长度21.1 mm的Nd:YAG晶体棒,获得了最大的收集效率(CE) (40.1 W / m2),比之前的数值记录提高了1.7 W / m2。发现直径为6 mm的Nd:YAG晶体棒的最佳长度为21.9 mm。对于这种长度的激光棒,期望CE为36.3 W / m2。这一数值是现有相同直径Nd:YAG晶体实验记录的1.13倍,突出了优化激光棒长度的重要性。
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引用次数: 0
Gamma distribution excess minority carrier concentration model for solar cell performance modeling 伽马分布过量少数载流子浓度模型用于太阳能电池性能建模
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-03-25 DOI: 10.1117/1.JPE.12.024501
John T. Avrett, S. Cain, J. Sattler
Abstract. Concentrated photovoltaic (PV) technology represents a growing market in the field of terrestrial solar energy production. As the demand for renewable energy technologies increases, further importance is placed on the modeling, design, and simulation of these systems. Given the cultural shift toward energy awareness and conservation, several concentrated PV systems have been installed across the world. This research presents a new model for carrier concentration within a solar cell. The goal of this innovation is to facilitate the determination of the steady-state operating temperature as a function of the concentration factor for the optical part of the concentrated PV system, to calculate the optimum concentration that maximizes power output and efficiency. This model will be shown to produce a more realistic estimate of the current through a solar cell, which will enable further research into dynamic thermal modeling.
摘要聚光光伏技术代表着陆地太阳能生产领域日益增长的市场。随着对可再生能源技术的需求增加,这些系统的建模、设计和仿真变得更加重要。鉴于文化向能源意识和节能的转变,世界各地已经安装了几个集中的光伏系统。这项研究提出了一个新的太阳能电池内载流子浓度模型。这一创新的目标是便于确定作为聚光光伏系统光学部分的浓度因子函数的稳态工作温度,以计算最大化功率输出和效率的最佳浓度。该模型将显示出对通过太阳能电池的电流的更真实的估计,这将使对动态热建模的进一步研究成为可能。
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引用次数: 0
Investigating the variation in the optical properties of TiO2 thin-film utilized in bifacial solar cells using machine learning algorithm 利用机器学习算法研究双面太阳能电池中TiO2薄膜光学性质的变化
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-02-12 DOI: 10.1117/1.JPE.12.022202
S. Abdellatif, Ahmad Fathi, Kareem Abdullah, M. M. Hassan, Ziad Khalifa
Abstract. Among various solar cell architectures, dye-sensitized solar cells (DSSCs) and perovskite solar cells have demonstrated the capability of being bifacial as both can be fabricated on conducting glass electrodes. In both cells, TiO2 plays a key role in the optoelectronic properties of the cell. Various studies have reported a range of recipes and deposition techniques for TiO2 thin films. Such variety introduces some uncertainties into the optical properties of the prepared films as well as in the process repeatability. Here, we utilized machine learning methods to correlate the film porosity to the film refractive index, making it capable of studying the impact of varying the fabrication and deposition techniques. Image postprocessing for scanning electron microscope measurements was utilized to estimate the film porosity, and the refractive index was calculated from the T–λ spectra. Four sets of samples with complete bifacial DSSCs were fabricated and characterized. They recorded a maximum current of 23.42 mA. They were fabricated using carboxymethyl cellulose-based suspension and deposited via the spin-coating sol-gel method. The fabricated cells showed an overall conversion efficiency of 7.9% under optical injection of the AM1.5G spectrum from the front side and LED indoor lighting from the counter electrode.
摘要在各种太阳能电池结构中,染料敏化太阳能电池(DSSCs)和钙钛矿太阳能电池已经证明了双面的能力,因为它们都可以在导电玻璃电极上制造。在这两种电池中,TiO2在电池的光电性能中起着关键作用。各种各样的研究已经报道了一系列的二氧化钛薄膜的配方和沉积技术。这种变化给所制备薄膜的光学性能和工艺的可重复性带来了一些不确定性。在这里,我们利用机器学习方法将薄膜孔隙率与薄膜折射率联系起来,使其能够研究不同制造和沉积技术的影响。利用扫描电镜测量的图像后处理来估计薄膜的孔隙率,并从T -λ光谱计算折射率。制备了四组具有完整双面DSSCs的样品并对其进行了表征。他们记录的最大电流为23.42 mA。它们以羧甲基纤维素为基础的悬浮液制备,并通过自旋涂覆溶胶-凝胶法沉积。在AM1.5G光谱的正面光注入和对电极的LED室内照明下,所制备的电池的总转换效率为7.9%。
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引用次数: 6
2021 List of Reviewers 2021年审稿人名单
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-01 DOI: 10.1117/1.jpe.12.010102
Thanks to the reviewers who served JPE in 2020.
感谢2020年为JPE服务的审稿人。
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引用次数: 0
Influence of the anode buffer layer materials and the light radiation power on the efficiency of a planar p-i-n perovskite solar cell: theory and simulation 阳极缓冲层材料和光辐射功率对平面p-i-n钙钛矿太阳能电池效率的影响:理论和模拟
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-01 DOI: 10.1117/1.JPE.12.015503
Bita Farhadi, F. Zabihi, M. Tebyetekerwa, Ishaq Lugoloobi, Aimin Liu
Abstract. Planar perovskite solar cell (PSC) measuring 900 nm total thickness is designed and simulated using Silvaco and SCAPS. Silvaco (Atlas 5.16.3.R) photovoltaic simulating system enables the formation of the stacking model and estimation of the physical properties of various functional materials, whereas SCAPS (version. 3.3.07) patterns the photovoltaic metrics including the fill factor (FF), power conversion efficiency (PCE), open-circuit voltage (Voc), short-circuit current density (Jsc), maximum voltage (Vm), maximum current (Im), absorption and reflection coefficients, and energy state diagram of the whole device. Alternation of illumination power and use of different buffer materials was utilized as the main tuning strategy. The champion layout was achieved by optimization of the stacking model, material system, and power of illumination, which demonstrated 26.32% PCE, 83.77% FF, Jsc of 26.27  mA  /  cm2, and the exceptional Voc of 1.19 V. This theoretical performance remains stable in 1000  W  /  m2 light radiation. The calculated efficiency and FF were very close to the previously reported experimental data, and this proved the high accuracy of this simulation work. These findings promise a feasible application of PSC in high-efficiency wearable electronics.
摘要使用Silvaco和SCAPS设计并模拟了总厚度为900nm的平面钙钛矿太阳能电池(PSC)。Silvaco(Atlas 5.16.3.R)光伏模拟系统能够形成堆叠模型并估计各种功能材料的物理特性,而SCAPS(版本3.3.07)则对光伏指标进行建模,包括填充因子(FF)、功率转换效率(PCE)、开路电压(Voc)、短路电流密度(Jsc)、最大电压(Vm),最大电流(Im)、吸收和反射系数以及整个器件的能量状态图。改变照明功率和使用不同的缓冲材料被用作主要的调谐策略。通过优化堆叠模型、材料系统和照明功率,获得了冠军布局,PCE为26.32%,FF为83.77%,Jsc为26.27  毫安  /  cm2和1.19V的异常Voc。该理论性能在1000内保持稳定  W  /  m2光辐射。计算的效率和FF与之前报道的实验数据非常接近,这证明了该模拟工作的高精度。这些发现预示着PSC在高效可穿戴电子产品中的可行应用。
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引用次数: 11
Forecasting annual energy yield enhancement from diffuse light collectors for III-V multijunction microconcentrator photovoltaics 预测III-V多结微聚光灯光伏散射光收集器的年能量产量提高
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-01 DOI: 10.1117/1.JPE.12.015501
James E. Moore, M. Lumb, K. Schmieder, Wolfgang Wagner
Abstract. Conventional concentrator photovoltaics (CPV) employing two-axis tracking are generally only economically competitive with cheaper, less efficient alternatives in locations with large amounts of direct sunlight. Adding a diffuse light collector to a CPV panel in the form of a silicon back panel can potentially improve the light collection under cloudy conditions and expand the range of climates in which CPV is useful. However, to understand the performance advantages available with diffuse collection, a realistic forecasting tool to predict performance in different locations is required. We introduce a model to evaluate the annual energy yield of a hybrid CPV and Si module and compare the results with several conventional stand-alone Si and CPV modules. The advantages of including a bifacial Si panel as the diffuse collector will also be investigated.
摘要采用双轴跟踪的传统集中器光伏(CPV)通常只有在阳光直射量大的地方与更便宜、效率更低的替代品具有经济竞争力。以硅背板的形式在CPV面板上添加漫射集光器可以潜在地改善多云条件下的光收集,并扩大CPV有用的气候范围。然而,为了了解扩散收集的性能优势,需要一个现实的预测工具来预测不同位置的性能。我们介绍了一个评估CPV和硅混合模块年发电量的模型,并将其结果与几种传统的独立硅和CPV模块进行了比较。还将研究包括双面硅面板作为扩散收集器的优点。
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引用次数: 0
Corncob-based evaporator for high-efficiency solar vapor generation 玉米基蒸发器,用于高效太阳能蒸汽产生
IF 1.7 4区 工程技术 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2022-01-01 DOI: 10.1117/1.JPE.12.018001
Huiling Duan, Tong Ling, Yujie Yan, Yiding Wang
Abstract. Corncob is an extremely cheap and easily available biomass with excellent hydrophilicity. Crisscross pores of corncob provide channels for efficient water transport. An efficient solar evaporator is prepared by coating carbon black (CB) film on corncob. The light absorption of corncob coated with CB film is significantly enhanced, and the absorptance is more than 94% in solar waveband. The evaporation rate of CB-coated corncob is 1.425  kg/m2h, 78.1% higher than that of uncoated corncob. The height of corncob above water has an important influence on evaporation performance. The maximum evaporation rate is 1.88  kg/m2h when the corncob is 2 cm above water. Compared with 0 cm above water, the evaporation rate of corncob with 1, 2, and 3 cm above water increases by 13.7%, 32%, and 24%, respectively. The effect of light intensity on evaporation performance is studied. Although increasing the light intensity can achieve a higher evaporation rate, it will increase the complexity and cost of the solar evaporation device. With the advantages of rich raw materials and low cost, the corncob-based interfacial evaporator can reuse the crop waste. More importantly, the preparation method is very simple, and the whole process does not need to use complex mechanical equipment. This study will boost the applications of biomass materials in the field of solar vapor generation.
摘要玉米芯是一种非常便宜和容易获得的生物质,具有优异的亲水性。玉米芯的纵横孔为水分的有效输送提供了通道。采用在玉米芯上涂覆炭黑膜的方法制备了高效太阳能蒸发器。玉米芯涂覆CB膜后,光波吸收率显著提高,在太阳波段吸收率达94%以上。包膜玉米芯的蒸发速率为1.425 kg/m2h,比未包膜玉米芯的蒸发速率高78.1%。玉米芯离水高度对蒸发性能有重要影响。当玉米芯离水2cm时,最大蒸发速率为1.88 kg/m2h。与0 cm处相比,1、2和3 cm处玉米芯蒸发速率分别提高了13.7%、32%和24%。研究了光照强度对蒸发性能的影响。虽然增加光强可以实现更高的蒸发速率,但会增加太阳能蒸发装置的复杂性和成本。玉米芯基界面蒸发器具有原料丰富、成本低等优点,可以对农作物废弃物进行资源化利用。更重要的是,制备方法非常简单,整个过程不需要使用复杂的机械设备。该研究将促进生物质材料在太阳能蒸汽产生领域的应用。
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引用次数: 1
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