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Improving anti-aging performance of terminal blend rubberized bitumen by using graft activated crumb rubber 用接枝活化胶粒提高终端共混橡胶沥青的抗老化性能
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-10-26 DOI: 10.1515/polyeng-2023-0073
Juan Xie, Xucheng Zhao, Wen He, Yongning Zhang, Yabing Xin
Abstract The appearance of terminal blend rubberized bitumen (TB) has improved a series of defects of traditional rubber bitumen, such as high viscosity, poor storage stability. Therefore, its wide application prospect is self-evident. However, different degrees of thermal-oxidative aging problem still exist in the process from production to use of TB, which seriously affects the service life of pavement. To improve the anti-aging performance of TB, grafting activated crumb rubber (GACR) was obtained by using acrylamide, and then compounded with TB. Firstly, TB was prepared in the self-developed nitrogen protection device. Secondly, GACR modified bitumen (GACR-MB), TB/CR composite modified bitumen (TB/CR) and TB/GACR composite modified bitumen (TB/GACR) were developed in the atmospheric environment. Finally, the performance of four kinds of crumb rubber modified bitumens before and after aging was compared and analyzed by testing high and low temperature rheological properties. The results show that GACR slowed down the formation rate and aggregation degree of asphaltenes and other macromolecular substances, and TB/GACR showed excellent aging resistance.
终端共混橡胶沥青(TB)的出现,改善了传统橡胶沥青粘度高、贮存稳定性差等一系列缺陷。因此,其广阔的应用前景不言而喻。但TB从生产到使用过程中仍然存在不同程度的热氧化老化问题,严重影响了路面的使用寿命。为提高TB的抗老化性能,以丙烯酰胺为原料制备了接枝活性颗粒橡胶(GACR),并与TB进行了复配。首先,在自行研制的氮气保护装置中制备TB。其次,在大气环境下研制了GACR改性沥青(GACR- mb)、TB/CR复合改性沥青(TB/CR)和TB/GACR复合改性沥青(TB/GACR)。最后,通过高低温流变性能测试,对四种颗粒橡胶改性沥青老化前后的性能进行了对比分析。结果表明,GACR减缓了沥青质等大分子物质的形成速度和聚集程度,TB/GACR表现出优异的耐老化性能。
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引用次数: 0
Development of a high-strength carrageenan fiber with a small amount of aluminum ions pre-crosslinked in spinning solution 在纺丝液中预交联少量铝离子的高强度卡拉胶纤维的研制
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-10-26 DOI: 10.1515/polyeng-2023-0151
Liting Jia, Xiao Han, Hongjie Zhai, Cuixia Qiao, Cunzhen Geng, Zhixin Xue, Yanzhi Xia
Abstract In this work, an improved wet spinning method was proposed to prepare high-tensile-strength carrageenan fibers by pre-crosslinking process. Pre-crosslinking was achieved by adding a small amount of Al 3+ ions into the spinning solution. The properties of the carrageenan spinning solution were analyzed by polarizing microscope, dynamic light scattering, and viscosity, the results showed that the modified spinning solution pre-crosslinked with Al 3+ ions was orderly and high-viscosity, and the average particle size of the spinning solution was increased. The properties of the carrageenan fibers were characterized using scanning electron microscope, Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy, X-ray photoelectron spectroscopy, and tensile tests. The results showed that the new carrageenan fibers were formed by coordination and ionic bonds between Al 3+ , –OH and sulfate groups. The tensile strength was up to 1.77 cN/dtex of Al-3.0/CAF (the best of newly prepared carrageenan fiber in this work), which is the highest strength carrageenan fiber prepared at present. Compared with the traditional process, this method reduced the concentration of Al 3+ ions in coagulation bath and stretch bath, thus saving the production cost and protecting the environment.
摘要本文提出了一种改进的湿法纺丝预交联制备高抗拉强度卡拉胶纤维的方法。预交联是通过在纺丝溶液中加入少量的Al - 3+离子来实现的。通过偏光显微镜、动态光散射和粘度分析了卡拉胶纺丝溶液的性质,结果表明,经Al 3+预交联的改性后的纺丝溶液有序,粘度高,纺丝溶液的平均粒径增大。采用扫描电子显微镜、傅里叶变换红外光谱、x射线衍射光谱、x射线光电子能谱和拉伸试验对卡拉胶纤维的性能进行了表征。结果表明,新的卡拉胶纤维是由Al - 3+、-OH和硫酸盐基团之间的配位和离子键形成的。Al-3.0/CAF的抗拉强度可达1.77 cN/dtex(本研究新制备的卡拉胶纤维中抗拉强度最高),是目前制备的强度最高的卡拉胶纤维。与传统工艺相比,该方法降低了混凝浴和拉伸浴中Al 3+离子的浓度,节约了生产成本,保护了环境。
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引用次数: 0
Development and characterization of new formulation of biodegradable emulsified film based on polysaccharides blend and microcrystalline wax 基于多糖共混物和微晶蜡的可生物降解乳化膜新配方的研制与表征
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-10-23 DOI: 10.1515/polyeng-2023-0048
Djalila Aoufi, Nabila Belloul, Aicha Serier
Abstract The aim of the present work is the development and characterization of new formulation of emulsified films based on soluble starch/sodium alginate blend and microcrystalline wax. The developed films were studied in order to use them as new formulations to produce food packaging. The obtained films were generally homogeneous, thin, and slightly flexible. These films appeared more opaque compared to the non-emulsified film. Incorporation of microcrystalline wax was caused modifications of mechanical properties of films; these modifications were principally due to the formation of amylose–lipid complex. It was found that microcrystalline significantly reduced film water vapor permeability (WVP) of emulsified films. Atomic force microscope (AFM) was used to evaluate surface topography and roughness of the films. The surface topography was significantly affected, in the other word high roughness values were obtained. Microemultion formation in which the microcrystalline wax particles are distributed homogeneously within the polymer matrix was investigated by scanning electron microscopy (SEM). Moreover, the polysaccharides blend/microcrystalline wax emulsified films can be useful as a biodegradable packaging material to maintain the quality of food products.
摘要本研究的目的是开发和表征基于可溶性淀粉/海藻酸钠共混物和微晶蜡的新型乳化膜配方。对显影后的薄膜进行了研究,以期将其作为新配方用于食品包装。得到的薄膜一般均匀、薄,并且有轻微的柔韧性。与非乳化膜相比,这些膜显得更不透明。微晶蜡的加入改变了薄膜的力学性能;这些修饰主要是由于直链淀粉-脂质复合物的形成。结果表明,微晶化显著降低了乳化膜的水蒸气渗透性。利用原子力显微镜(AFM)对膜的表面形貌和粗糙度进行了评价。表面形貌受到显著影响,即获得了较高的粗糙度值。采用扫描电子显微镜(SEM)研究了微晶蜡颗粒在聚合物基体内均匀分布的微乳化形成过程。此外,多糖混合物/微晶蜡乳化膜可作为生物可降解的包装材料,以保持食品的质量。
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引用次数: 0
Effect of super critical carbon dioxide and alkali treatment on oxygen barrier properties of thermoplastic starch/poly(vinyl alcohol) films 超临界二氧化碳和碱处理对热塑性淀粉/聚乙烯醇膜阻氧性能的影响
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-10-20 DOI: 10.1515/polyeng-2023-0157
Wei-xing Chen, Hong-juan Xu, Han-fang Mei, Ning Ma, Jen-taut Yeh
Abstract Sustainable oxygen barrier thermoplastic starch (TPS)/polyvinyl alcohol (PVA) blown films were successfully prepared by blending proper PVA loads during NaOH-treating and supercritical carbon dioxide (scCO 2 ) assisted processing. The NaOH-treated TPS or scCO 2 TPS films showed smaller free-volume-cavity characteristics (FVCC) and oxygen transmission rate (OTR) than those of TPS (or scCO 2 TPS) prepared without proper alkali-treatment. Smaller OTR and FVCC values were detected for NaOH-treated scCO 2 TPS films than those of NaOH-treated TPS films prepared without scCO 2 -assistance. All OTR and FVCC values detected for proper alkali-treated scCO 2 TPS y PVA z films diminished distinctly to a smallest value, when their PVA loads came near a solubility limit value of 27.5 wt%. An essential result is that the OTR of the optimal NaOH-treated scCO 2 TPS y PVA z film is merely 3.1 cm 3 /m 2 day atm, which meets the requirement of high oxygen barrier plastics. Dynamic molecular relaxations and WAXD patterns detected for proper NaOH-treated scCO 2 TPS y PVA z films disclosed that PVA was compatible with TPS, as PVA loads were ≤ the solubility limit value. The distinctly reduced OTR and FVCC detected for optimal NaOH-treated scCO 2 TPS y PVA z films are partially attributed to the reinforced molecular interactions between hydroxyl groups of TPS and PVA, as they were blended with proper PVA loads during their alkali-treating and scCO 2 -aid processing.
摘要通过naoh处理和超临界二氧化碳(scCO 2)辅助处理,混合适当的PVA负载,成功制备了可持续的氧屏障热塑性淀粉(TPS)/聚乙烯醇(PVA)吹膜。naoh处理的TPS或scCO 2 TPS膜的自由体积空腔特性(FVCC)和氧透过率(OTR)均小于未经适当碱处理的TPS或scCO 2 TPS膜。naoh处理的sco2 TPS膜的OTR和FVCC值比未经sco2辅助制备的naoh处理的TPS膜小。当PVA负载接近溶解度极限值27.5% wt%时,经适当碱处理的sco2 TPS的所有OTR和FVCC值都明显下降到最小值。一个重要的结果是,最佳的naoh处理的PVA - z膜的OTR仅为3.1 cm 3 /m 2 day atm,满足高氧屏障塑料的要求。PVA z膜对naoh处理的sco2 TPS的动态分子弛豫和WAXD模式检测表明,PVA与TPS是相容的,PVA负载≤溶解度极限值。在碱处理和scCO 2辅助处理过程中加入适当的PVA负荷,从而增强了TPS和PVA的羟基之间的分子相互作用,从而显著降低了经naoh处理的scCO 2 TPS的OTR和FVCC。
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引用次数: 0
Numerical simulation on the mixing behavior of double-wave screw under speed sinusoidal pulsating enhancement induced by differential drive 差动驱动速度正弦脉动增强下双波螺杆混流特性的数值模拟
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-10-20 DOI: 10.1515/polyeng-2022-0318
Tian-lei Liu, Yao-xue Du, Xian-yun He
Abstract A novel speed sinusoidal pulsating system is designed by applying differential drive, which is loaded on the plasticizing screw in an extruder or in an injection molding machine. With the CFD software ANSYS POLYFLOW 19.2, this paper builds simplified physical and mesh models for the double wave screw unit, carries out numerical simulation by using particle tracing manner, and finally analyses comparatively the mixing behavior of the wave screw mixing unit with and without sinusoidal pulsating field. It is found that the mixing screw unit with the superimposed excitation field takes on lower transportation efficiency and a descending melt pressure, while there are different reactions on the various pulsating amplitude and frequency for the max shear rate and mixing index. On the other hand, the introducing pulsating field can strengthen the shear field and gain a higher mixing efficiency. The results are of great importance and reference for improving the plasticizing performance and engineering application of the speed pulsating system.
摘要设计了一种新型的速度正弦脉动系统,该系统采用差动驱动加载在挤出机或注塑机的塑化螺杆上。利用CFD软件ANSYS POLYFLOW 19.2,对双波螺杆装置建立简化的物理模型和网格模型,采用粒子追踪的方式进行数值模拟,最后对比分析了有正弦脉动场和无正弦脉动场时波螺杆混合装置的混合行为。结果表明,叠加激励场的混合螺杆装置输送效率较低,熔体压力下降,但不同脉动幅值和频率对最大剪切速率和混合指数的影响不同。另一方面,引入脉动场可以增强剪切场,获得更高的混合效率。研究结果对提高转速脉动系统的塑化性能和工程应用具有重要的参考意义。
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引用次数: 0
Study on the volatilization behavior of monomer and oligomers in polyamide-6 melt by dynamic film–forming device 用动态成膜装置研究聚酰胺-6熔体中单体和低聚物的挥发行为
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-10-19 DOI: 10.1515/polyeng-2023-0142
Xia Zhu, Linzhong Tao, Liping Chen, Siwei Xiong, Feihua Yang, Yingbin Jia, Luoxin Wang, Hua Wang
Abstract In this study, a modified torque rheometer is used to investigate the volatilization behavior of monomer and oligomers in polyamide-6 (PA6) melt under dynamic film–forming conditions with negative pressure. The surface renewal model is employed to simulate the volatilization behavior. The effects of actual processing factors and simulation results on the volatilization behavior of monomer and oligomer are analyzed comparatively. It is found that the monomer and oligomers removal rate increase continuously with increasing temperature, residence time, and rotational speed. And, the cyclic dimer, which is extremely harmful to spinning, can be removed. It is found that the removal of monomer and oligomers continued to increase with increasing temperature, residence time, and spinning speed. Moreover, cyclic dimers, which are extremely harmful to spinning, are also removed. Additionally, it is discovered that the polycondensation reaction of PA6 results in an increase in the molecular weight and viscosity at lower temperatures (250 °C), while a higher temperature (270 °C) and shear rate (150 r/min) cause a reduction in viscosity and molecular weight.
摘要本研究采用改进的扭矩流变仪,研究了负压动态成膜条件下PA6熔体中单体和低聚物的挥发行为。采用表面更新模型对挥发行为进行了模拟。对比分析了实际工艺因素和模拟结果对单体和低聚物挥发行为的影响。随着温度、停留时间和转速的增加,单体和低聚物的去除率不断提高。并且,可以去除对纺丝极有害的环二聚体。随着温度、停留时间和纺丝速度的增加,单体和低聚物的去除率继续增加。此外,还去除了对纺丝有害的环二聚体。此外,还发现PA6的缩聚反应在较低温度(250℃)下导致分子量和分子量的增加,而在较高温度(270℃)和剪切速率(150 r/min)下导致粘度和分子量的降低。
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引用次数: 0
Preparation and properties of ABS/BNNS composites with high thermal conductivity for FDM FDM用高导热ABS/BNNS复合材料的制备及性能研究
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-10-17 DOI: 10.1515/polyeng-2023-0188
Caifeng Chen, Wuwen Zhong, Junhao Guo, Kai Liu, Andong Wang
Abstract Acrylonitrile-butadiene-styrene (ABS) resin is a widely used engineering plastic at present. Due to its excellent mechanical properties and high fluidity, it is utilized in fused deposition molding (FDM) technology. In this paper, boron nitride nanosheets (BNNS) were prepared by hydrothermal exfoliation and used as nano-fillers for ABS resin, and ABS/BNNS composite wires for FDM printing were prepared by melt blending method. The results showed that BNNS with fewer layers were obtained; the addition of BNNS to the ABS resin matrix could effectively enhance the thermal conductivity of the composites. When the addition amount of BNNS was 15 wt%, the thermal conductivity of the composite increased to 0.369 W/(m K), which was 120.06 % higher than that of pure ABS (0.174 W/(m K)). In addition, BNNS also improves the mechanical properties, thermal stability, and melt flow rate of the composites, thus making ABS composite wires more suitable for FDM printing.
丙烯腈-丁二烯-苯乙烯(ABS)树脂是目前应用广泛的工程塑料。由于其优异的力学性能和高流动性,它被用于熔融沉积成型(FDM)技术。本文采用水热剥离法制备了氮化硼纳米片(BNNS)作为ABS树脂的纳米填料,并采用熔融共混法制备了用于FDM打印的ABS/BNNS复合线材。结果表明:获得了层数较少的BNNS;在ABS树脂基体中加入BNNS可有效提高复合材料的导热性。当BNNS添加量为15 wt%时,复合材料的导热系数提高到0.369 W/(m K),比纯ABS (0.174 W/(m K))提高了120.06%。此外,BNNS还提高了复合材料的力学性能、热稳定性和熔体流动速率,从而使ABS复合线材更适合FDM打印。
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引用次数: 0
Frontmatter 头版头条
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-10-01 DOI: 10.1515/polyeng-2023-frontmatter9
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引用次数: 0
Effect of molecular weight distribution on the structure and properties of polypropylene cast film and stretched microporous membrane 分子量分布对聚丙烯铸膜和拉伸微孔膜结构和性能的影响
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-09-27 DOI: 10.1515/polyeng-2023-0118
Dahua Chen, Liangdong Yin, Zhixiang Su, Jiayi Xie, Ruijie Xu, Caihong Lei
Abstract Two isotactic polypropylene (iPP) resins with approximate weight-average molecular weight ( Mw ) and different molecular weight distribution ( MWD ) were chosen to prepare cast films by the melt-stretching method. The lamellar morphology and mechanical properties of the initial precursor films and stretched microporous membranes were characterized. It was found that PP1 resin with a broader MWD exhibits a higher relaxation time of around 5.5 s, a larger entanglement density of 24.7 mol/m 3 and fast crystalline ability. The lamellar lateral size, orientation degree and entanglement density of the corresponding cast film are significantly increasing, resulting in higher elastic recovery and more apparent strain-hardening behavior. The PP resin with broader MWD also benefits the pore formation, resulting in a larger pore size and better air permeability of the stretched microporous membrane.
摘要:选择两种分子量相近、分子量分布不同的等规聚丙烯(iPP)树脂,采用熔融拉伸法制备浇铸膜。对初始前驱体膜和拉伸微孔膜的片层形貌和力学性能进行了表征。结果表明,具有较宽MWD的PP1树脂具有较高的弛豫时间(约5.5 s)、较高的缠结密度(24.7 mol/m 3)和快速结晶能力。相应铸膜的片层横向尺寸、取向度和缠结密度显著增加,弹性回复率更高,应变硬化行为更明显。MWD更宽的PP树脂也有利于孔隙形成,拉伸后的微孔膜孔径更大,透气性更好。
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引用次数: 0
Multiobjective optimization of injection molding parameters based on the GEK-MPDE method 基于GEK-MPDE方法的注射成型参数多目标优化
4区 工程技术 Q4 POLYMER SCIENCE Pub Date : 2023-09-25 DOI: 10.1515/polyeng-2022-0236
Zhuocheng Wang, Jun Li, Zheng Sun, Cuimei Bo, Furong Gao
Abstract In plastic injection molding (PIM), the process parameters determine the quality and productivity of molded parts. The traditional injection molding process analysis method mainly relies on production experience. It is lack of advanced and rationality and seriously increases production costs. In this paper, a hybrid multiobjective optimization method is proposed to minimize the warpage, volumetric shrinkage and cycle time. The method integrates orthogonal experimental design, numerical simulation, and the metamodel method with multiobjective optimization. The orthogonal experiment chooses seven parameters as the design variables to generate sampling data and determines key factors that affect product quality by the numerical simulation. A gradient-enhanced Kriging (GEK) surrogate model strategy is introduced to construct the response predictors to calculate objective responses in the global design space. Multipopulation differential evolution (MPDE) is conducted to locate the Pareto-optimal solutions, where the response predictors are taken as the fitness functions. This study shows that the proposed GEK-MPDE method can reduce warpage, volumetric shrinkage and cycle time by 5.7 %, 4.7 %, and 18.1 %, respectively. It helps plastic industry to realize collaborative scheduling of multiple tasks between different production lines by providing a low-cost and effective dynamic control method.
在塑料注射成型(PIM)中,工艺参数决定了成型件的质量和生产率。传统的注塑工艺分析方法主要依靠生产经验。它缺乏先进性和合理性,严重增加了生产成本。本文提出了一种混合多目标优化方法,以最小化翘曲、体积收缩和循环时间。该方法将正交试验设计、数值模拟和多目标优化的元模型方法相结合。正交试验选取7个参数作为设计变量生成抽样数据,通过数值模拟确定影响产品质量的关键因素。引入梯度增强Kriging (GEK)代理模型策略构建响应预测因子,计算全局设计空间中的目标响应。采用多种群差分进化(MPDE)方法定位pareto最优解,将响应预测因子作为适应度函数。研究表明,GEK-MPDE方法可将翘曲量、体积收缩率和循环时间分别降低5.7%、4.7%和18.1%。它通过提供一种低成本、有效的动态控制方法,帮助塑料行业实现不同生产线之间多任务的协同调度。
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引用次数: 0
期刊
Journal of Polymer Engineering
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