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Effect of fly ash chemical components on epoxy mortar composite material performance 粉煤灰化学成分对环氧砂浆复合材料性能的影响
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-19 DOI: 10.1177/07316844241281623
Pengfei Cao, Guoxing Liang, Ming Lv
This study focuses on the application of fly ash (FA)-filled epoxy mortar composite material (EMCM) as a bed material for precision machine tools, emphasizing the impact of fly ash’s primary chemical components (SiO2, Al2O3, Fe2O3, and CaO) as mono-component or two-component fillers on the mechanical properties of EMCM composite material. The research thoroughly analyzed the porosity, macroscopic mechanical properties, and microstructure of the EMCM. The results revealed that increasing the filler content up to 40% significantly enhances the elastic modulus and compressive strength of the EMCM specimens, despite an increase in porosity. Specific filler combinations, such as SiO2/CaO and CaO/Fe2O3, exhibit superior performance. Additionally, Fe2O3 helps prevent sedimentation, enhancing the material’s uniformity. A comprehensive performance evaluation using the Entropy Weighted Technique for Order Preference by Similarity to Ideal Solution (EW-TOPSIS) method showed that specimens containing CaO/Fe2O3 exhibited optimal performance, even when considering cost factors.
本研究重点关注粉煤灰(FA)填充环氧砂浆复合材料(EMCM)作为精密机床床身材料的应用,强调粉煤灰的主要化学成分(SiO2、Al2O3、Fe2O3 和 CaO)作为单组分或双组分填料对 EMCM 复合材料机械性能的影响。研究深入分析了 EMCM 的孔隙率、宏观力学性能和微观结构。结果表明,尽管孔隙率会增加,但将填料含量增加到 40% 会显著提高 EMCM 试样的弹性模量和抗压强度。特定的填料组合(如 SiO2/CaO 和 CaO/Fe2O3)表现出卓越的性能。此外,Fe2O3 还有助于防止沉积,提高材料的均匀性。使用熵权法(EW-TOPSIS)进行的综合性能评估表明,即使考虑到成本因素,含有 CaO/Fe2O3 的试样也能表现出最佳性能。
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引用次数: 0
Shear capacity of slender FRP-RC beams utilizing a hybrid ANN with the firefly optimizer 利用带萤火虫优化器的混合 ANN 对细长 FRP-RC 梁的抗剪能力进行分析
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-18 DOI: 10.1177/07316844241283517
Yasser Sharifi, Nematullah Zafarani
The popularity of fiber-reinforced polymer (FRP) bars as a structural element has soared due to their advantageous mechanical and physical properties. Despite an abundance of code requirements and heuristic equations, engineers specializing in structural retrofitting and analysis often struggle to utilize a suitable yet precise equation. This study introduces a novel approach by presenting a firefly optimization algorithm (FOA) combined with an artificial neural network (ANN)—termed as FOA-ANN—as an advanced hybrid machine learning model. The primary objective is to predict the shear capacity of slender FRP reinforced concrete (FRP-RC) beams without stirrup. An extensive experimental database of slender FRP-RC beams without stirrup was compiled. Leveraging this database and the proposed hybrid method, a simple yet accurate closed-form equation for determining the shear capacity of slender FRP-RC beams without stirrup was formulated. Additionally, a selection of pre-existing equations was provided for comparison of accuracy. Results indicate that the suggested FOA-ANN equation offers a more accurate alternative, outperforming equations derived from CSA S806-12 and AASHTO LRFD. The FOA-ANN hybrid technique proves to be highly effective in predicting the shear capacity of slender FRP-RC beams without stirrup.
由于纤维增强聚合物(FRP)条具有良好的机械和物理特性,因此作为结构元件的受欢迎程度急剧上升。尽管有大量的规范要求和启发式方程,但专门从事结构改造和分析的工程师往往难以使用合适而精确的方程。本研究引入了一种新方法,将萤火虫优化算法(FOA)与人工神经网络(ANN)相结合,称为 FOA-ANN,作为一种先进的混合机器学习模型。其主要目标是预测无箍筋的细长玻璃钢加固混凝土(FRP-RC)梁的抗剪承载力。我们编制了一个不带箍筋的细长 FRP-RC 梁的广泛实验数据库。利用该数据库和拟议的混合方法,制定了一个简单而准确的闭式方程,用于确定无箍筋细长 FRP-RC 梁的抗剪承载力。此外,还提供了一些先前存在的方程,以比较其准确性。结果表明,建议的 FOA-ANN 方程提供了更精确的替代方案,优于 CSA S806-12 和 AASHTO LRFD 得出的方程。事实证明,FOA-ANN 混合技术在预测无箍筋细长 FRP-RC 梁的抗剪能力方面非常有效。
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引用次数: 0
Analysis of curing deformation for resin matrix composite T-shaped stiffened panel 树脂基复合材料 T 型加劲板的固化变形分析
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-14 DOI: 10.1177/07316844241272959
Xiaodong Ding, Jianwei Fu, Fei Bao, Yongzheng Ye, Zongzhan Gao
In this work, a multi-field coupled finite element simulation method involving thermochemistry and mechanics was devised to predict the curing deformation (C-DE) of a T-shaped stiffened panel (T-SSPL), a typical aircraft structural component, during the autoclave forming process. A more comprehensive and detailed analysis of the factors affecting the C-DE of T-SSPL is also carried out. The methodology uses the Fortran language to write different user subroutines and establish corresponding mathematical models to simulate the different mechanical states of components, and ultimately simulate the entire molding process of the product in the autoclave. And investigates the effects of process parameters, including heating rate, cooling rate, curing pressure, and structural parameters, including the number of bars and height of stringer on the C-DE of T-SSPL, and obtains the following conclusions: the heating rate and curing pressure are positively correlated with the C-DE, and the cooling rate has little influence on the C-DE, and C-DE hardly changes with the change of cooling rate; C-DE increases with the ribs count; however, it decreases and then increases with the stringer height, and these conclusions provides a theoretical basis for the manufacturing of T-SSPL.
在这项工作中,设计了一种涉及热化学和力学的多场耦合有限元模拟方法,用于预测 T 型加劲板(T-SSPL)(一种典型的飞机结构部件)在高压釜成型过程中的固化变形(C-DE)。此外,还对影响 T-SSPL C-DE 的因素进行了更全面、更详细的分析。该方法使用 Fortran 语言编写不同的用户子程序,并建立相应的数学模型来模拟部件的不同机械状态,最终模拟产品在高压釜中的整个成型过程。该方法研究了加热速率、冷却速率、固化压力等工艺参数,以及筋条数量、筋条高度等结构参数对 T-SSPL C-DE 的影响,得出以下结论:加热速率和固化压力与 C-DE 呈正相关,冷却速率对 C-DE 影响不大,且 C-DE 几乎不随冷却速率的变化而变化;C-DE 随筋条数量的增加而增加,但随筋条高度的增加而先减小后增大,这些结论为 T-SSPL 的制造提供了理论依据。
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引用次数: 0
Deformation processes of polymer composites with stress concentrators under different reinforcement schemes 不同加固方案下带有应力集中器的聚合物复合材料的变形过程
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-14 DOI: 10.1177/07316844241281780
Elena Strungar, Dmitrii Lobanov, Artur Mugatarov, Ekaterina Chebotareva
This paper is dedicated to an experimental investigation of an effect of a stress concentrator orientation on a mechanical behavior of polymer composites with various reinforcement schemes. Composite specimens have been made of layered carbon fiber reinforced polymer (CFRP) with lay-up patterns of [±45]16 and [0/90]16. The stress concentrators have been cut in a form of a rectangle (with rounded corners) orientated at angles of 0°, 45°, and 90° to a loading axis. The novel data about the composite’s mechanical behavior has been obtained by the digital image correlation (DIC) method, the acoustic emission (AE) method and the optical microscopy. Quasistatic tests have been carried out taking into account recommendations of the ASTM D5766, ASTM D3039, ASTM D3518. The effect of the stress concentrator orientation on the composite’s strength has been evaluated. It has been found that the stress concentrator does not affect the strength of the composite with the [±45]16 lay-up pattern. This peculiarity has been explained by the absence of the layers preventing the fibers system turning in the direction of the load application. The DIC method has allowed to study the evolution of inhomogeneous strain fields on the specimens’ surfaces. Computational simulations have been carried out within the elasticity stage. The results have shown that the strain fields obtained by both the DIC method and the numerical simulation were similar for the composites with the [0/90]16 reinforcement pattern. However, significant differences have been found for the [±45]16 reinforcement pattern, which have been explained by the development of inelastic zones near the stress concentrator even if the elastic stage is realized at the macrolevel. The using of the AE method and the optical microscopy has allowed to reveal typical mechanisms of the structural damage and to study their occurrence during the tests. It has been concluded that the orientation of the stress concentrator significantly influences the deformation processes of the CFRP with various reinforcement patterns.
本文旨在通过实验研究应力集中器取向对各种增强方案的聚合物复合材料机械性能的影响。复合材料试样由层状碳纤维增强聚合物(CFRP)制成,其铺设模式为 [±45]16 和 [0/90]16。应力集中器被切割成与加载轴成 0°、45° 和 90°角的矩形(带圆角)。通过数字图像相关(DIC)法、声发射(AE)法和光学显微镜获得了有关复合材料机械行为的新数据。根据 ASTM D5766、ASTM D3039 和 ASTM D3518 的建议进行了准静态测试。评估了应力集中器方向对复合材料强度的影响。结果发现,应力集中器不会影响[±45]16铺层模式下复合材料的强度。这种特殊性的原因是没有阻止纤维系统在施加载荷的方向上转动的层。利用 DIC 方法可以研究试样表面不均匀应变场的演变。在弹性阶段进行了计算模拟。结果表明,对于[0/90]16 增强模式的复合材料,DIC 方法和数值模拟获得的应变场相似。然而,[±45]16 增强模式的复合材料却存在明显差异,这是因为即使在宏观层面上实现了弹性阶段,在应力集中器附近也会形成非弹性区。使用 AE 方法和光学显微镜可以揭示结构损伤的典型机制,并研究其在试验过程中的发生情况。研究得出的结论是,应力集中器的方向会显著影响具有各种增强模式的 CFRP 的变形过程。
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引用次数: 0
Cooperative effect of hybrid polyethylene-basalt fibers on crack width control and mechanical properties in ECC 杂化聚乙烯-钴纤维对 ECC 中裂纹宽度控制和机械性能的协同效应
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-14 DOI: 10.1177/07316844241281781
Xiaodan Teng, Huihuang Sun, Yonghong Li, Qiyao Yao, Chenyu Lu
Engineered cementitious composite (ECC) reinforced with polyethylene (PE) fiber has large crack width and high production cost, and these two shortcomings affect its application in practical projects. In this study, basalt fiber (BF) was hybrid with PE fiber to achieve cooperative effect, developing a PE/BF-hybrid fiber ECC (PE/BF-HyECC) with tighter crack width and more economic advantages. The impacts of different fiber content on the pore structure, mechanical, and cost performance of PE/BF-HyECC were investigated. The PE/BF-HyECC with positive cooperative effect of 1.5 vol.% PE and 1.0 vol.% BF had higher strength and tighter crack width compared to PE-ECC with 2.0 vol.% PE. Its cost performance ratio was 1.19 to 1.37 times that of PE-ECC with 2.0 vol.% PE. The better performance and higher cost performance of PE/BF-HyECC is expected to expand its practical application.
用聚乙烯(PE)纤维增强的工程水泥基复合材料(ECC)裂缝宽度大、生产成本高,这两个缺点影响了其在实际工程中的应用。本研究将玄武岩纤维(BF)与聚乙烯纤维(PE)进行混合,以达到协同增效的效果,开发出一种裂缝宽度更窄、更具经济优势的聚乙烯/BF-混合纤维 ECC(PE/BF-HyECC)。研究了不同纤维含量对 PE/BF-HyECC 的孔隙结构、机械性能和成本性能的影响。与含有 2.0 Vol.% PE 的 PE-ECC 相比,含有 1.5 Vol.% PE 和 1.0 Vol.% BF 的 PE/BF-HyECC 具有更高的强度和更紧密的裂缝宽度。其性价比是含 2.0 体积%聚乙烯的 PE-ECC 的 1.19 至 1.37 倍。PE/BF-HyECC 具有更好的性能和更高的性价比,有望扩大其实际应用范围。
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引用次数: 0
Acoustic emission-based delamination investigation in drilled GFRP under mixed tensile and bending cyclic loading 在混合拉伸和弯曲循环加载条件下,基于声发射的钻孔 GFRP 分层研究
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-14 DOI: 10.1177/07316844241279721
Amirhossein Beigi, Ali Bastani Lay, Mehdi Ahmadi Najafabadi
The drilling process can cause various defects in glass fiber-reinforced polymer (GFRP), such as delamination, which ultimately leads to damage progression, especially under fatigue loading. Therefore, the current study aims to investigate the progression of failure in drilled composites subjected to cyclic bending and tensile loads using acoustic emission (AE), image processing, and mechanical behavior monitoring. The results show tyhat the fatigue diagram consists of three stages associated with resistance of fibers and matrix against delamination propagation, stable delamination progression, and ultimate spread of failure which are accurately identified by AE and mechanical methods. Additionally, the pattern and procedure of all fatigue diagrams under all loading conditions were similar and independent of loading parameters. Results from this study provide a strategy for real-time structural health monitoring (SHM) of delamination propagation in GFRPs under multi-axial fatigue loading.
钻孔过程会在玻璃纤维增强聚合物(GFRP)中造成各种缺陷,如分层,最终导致破坏的发展,尤其是在疲劳载荷下。因此,本研究旨在利用声发射(AE)、图像处理和机械行为监测技术,研究承受循环弯曲和拉伸载荷的钻孔复合材料的破坏过程。结果表明,疲劳图由三个阶段组成,分别是纤维和基体抵抗分层扩展、分层稳定发展和最终破坏扩散,声发射和机械方法可准确识别这三个阶段。此外,在所有加载条件下,所有疲劳图的模式和程序都是相似的,且与加载参数无关。这项研究的结果为在多轴疲劳加载条件下对 GFRP 的分层扩展进行实时结构健康监测(SHM)提供了一种策略。
{"title":"Acoustic emission-based delamination investigation in drilled GFRP under mixed tensile and bending cyclic loading","authors":"Amirhossein Beigi, Ali Bastani Lay, Mehdi Ahmadi Najafabadi","doi":"10.1177/07316844241279721","DOIUrl":"https://doi.org/10.1177/07316844241279721","url":null,"abstract":"The drilling process can cause various defects in glass fiber-reinforced polymer (GFRP), such as delamination, which ultimately leads to damage progression, especially under fatigue loading. Therefore, the current study aims to investigate the progression of failure in drilled composites subjected to cyclic bending and tensile loads using acoustic emission (AE), image processing, and mechanical behavior monitoring. The results show tyhat the fatigue diagram consists of three stages associated with resistance of fibers and matrix against delamination propagation, stable delamination progression, and ultimate spread of failure which are accurately identified by AE and mechanical methods. Additionally, the pattern and procedure of all fatigue diagrams under all loading conditions were similar and independent of loading parameters. Results from this study provide a strategy for real-time structural health monitoring (SHM) of delamination propagation in GFRPs under multi-axial fatigue loading.","PeriodicalId":16943,"journal":{"name":"Journal of Reinforced Plastics and Composites","volume":"16 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142249927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Implementing low budget machine vision to improve fiber alignment in wet fiber placement 采用低成本机器视觉技术改善湿法纤维铺放中的纤维排列
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-10 DOI: 10.1177/07316844241278050
Peter A Arrabiyeh, Moritz Bobe, Miro Duhovic, Maximilian Eckrich, Anna M Dlugaj, David May
Machine vision is revolutionizing modern manufacturing, with new applications emerging regularly. The composites industry, relying on precision in aligning fibers, stands to benefit significantly from machine vision. Ensuring the exact fiber orientation is critical, as deviations can compromise product mechanical properties and lead to failure. Machine vision, particularly in wet fiber placement (WFP), offers a solution for monitoring and enhancing quality control in composite manufacturing. WFP involves pulling fiber bundles, impregnating them with resin, and precisely transporting them to mold tooling for layer-by-layer fabrication. The challenge lies in handling tacky, wet fiber bundles, making tactile sensors impractical. This makes WFP an ideal candidate for contactless process monitoring. The objective of this study is to employ a low budget machine vision in WFP, utilizing a webcam connected to a single-board computer. Artificial intelligence is trained using images of fiber bundles just before placement on the tooling mold. The module detects and measures the position and orientation of a roving in the starting position, enabling the initiation of the WFP process. The methods employed are thoroughly evaluated for reliability and feasibility. After completing only 50 training epochs, a roving detection accuracy of 91.3% could be achieved with almost no critical errors. With additional iterations per placement process, the system functions almost flawlessly at its current state.
机器视觉正在彻底改变现代制造业,新的应用层出不穷。复合材料行业依赖于精确的纤维排列,将从机器视觉中获益匪浅。确保精确的纤维定向至关重要,因为偏差可能会影响产品的机械性能并导致故障。机器视觉,特别是在湿法纤维铺放(WFP)方面,为复合材料生产中的质量监控和增强质量控制提供了解决方案。湿法纤维铺放包括拉纤维束、用树脂浸渍纤维束并将其精确地输送到模具中进行逐层制造。所面临的挑战在于如何处理粘湿的纤维束,这使得触觉传感器变得不切实际。这使得 WFP 成为非接触式过程监控的理想选择。本研究的目的是在 WFP 中采用低成本的机器视觉,利用连接到单板计算机的网络摄像头。人工智能利用纤维束在模具上放置前的图像进行训练。该模块可检测和测量粗纱在起始位置的位置和方向,从而启动 WFP 流程。对所采用的方法的可靠性和可行性进行了全面评估。仅在完成 50 次训练后,粗纱检测的准确率就达到了 91.3%,几乎没有临界误差。在每次放置过程中增加迭代次数后,系统在当前状态下的功能几乎完美无缺。
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引用次数: 0
A simplified approach for predicting last ply failure load of VO-notched laminated composite components 预测 VO 缺口层压复合材料部件最后一层破坏载荷的简化方法
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-10 DOI: 10.1177/07316844241279714
Mohammad Sadegh Amirinia, Mojtaba Haghighi-Yazdi, Majid Safarabadi
In this study, the last ply failure (LPF) load of composite laminates with VO-notches under pure mode I and mixed mode I/II was investigated experimentally, analytically, and numerically. The efficiency of the virtual isotropic material concept (VIMC) in combination with a new combined failure criterion was also evaluated. The J-integral and average strain energy density failure criteria were combined with VIMC. Using analytical expressions for the J-integral and the average strain energy density (ASED), the prediction of the fracture load of notched components was simplified and expedited. The experimental fracture loads of notched specimens were determined for quasi-isotropic and cross-ply laminates under mode I and mixed mode I/II. The fracture loads were predicted using analytical expressions for the J-integral and ASED, combined with VIMC. The VIMC-ASED and VIMC-J-integral failure criteria demonstrated good accuracy in predicting the LPF, with the highest accuracy for mode I, slightly reduced accuracy for mixed mode I/II. VIMC, in combination with energy-based failure criteria, effectively predicts the fracture load. The use of analytical expressions further simplified and expedited the prediction process without losing accuracy, making it a practical approach for engineering applications. Additionally, this approach significantly reduces the time and cost associated with extensive experimental testing.
本研究采用实验、分析和数值方法研究了带有 VO 缺口的复合材料层压板在纯模式 I 和混合模式 I/II 下的最后一层破坏(LPF)载荷。此外,还评估了虚拟各向同性材料概念(VIMC)与新的组合失效准则相结合的效率。J 积分和平均应变能量密度失效准则与 VIMC 相结合。利用 J 积分和平均应变能密度 (ASED) 的分析表达式,简化并加快了缺口部件断裂载荷的预测。在模式 I 和混合模式 I/II 下,确定了准各向同性层压板和交叉层压板的缺口试样的实验断裂载荷。采用 J 积分和 ASED 的分析表达式并结合 VIMC 预测了断裂载荷。VIMC-ASED 和 VIMC-J-integral 失效准则在预测 LPF 方面表现出良好的准确性,其中模式 I 的准确性最高,而混合模式 I/II 的准确性略低。VIMC 与基于能量的失效准则相结合,可有效预测断裂荷载。分析表达式的使用进一步简化并加快了预测过程,同时又不失准确性,使其成为工程应用中的一种实用方法。此外,这种方法还大大减少了大量实验测试所需的时间和成本。
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引用次数: 0
Prediction of elastic properties of woven polymer composites using micromechanical models and measured microstructural parameters 利用微机械模型和测得的微结构参数预测编织聚合物复合材料的弹性性能
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-10 DOI: 10.1177/07316844241273025
Francisco López-Santos, Adrián Hernández-Pérez, Elías Ledesma-Orozco, Francis Avilés
Prediction of elastic properties of plain weave composites using two well-known micromechanical models is addressed, along with a dedicated finite element model of the unit cell which includes details of the woven architecture. Predictions of micromechanical models are carried out using geometric input parameters statistically measured from micrographies of the unit cell of the plain weave composite and compared to finite element predictions and to measured elastic properties of an E-glass/vinyl ester plain weave composite. The micromechanical models predict that the width and thickness of the yarn in the fill and warp directions greatly influence the elastic properties and anisotropy of the plain weave composite. Good agreement between all approaches and the measured values is observed for the in-plane elastic properties, as long as the input geometric parameters of the unit cell required for the models are measured with statistical rigor. However, transverse shear moduli are not accurately predicted by the examined micromechanical models, only by the finite element method. Reasons for such discrepancies are discussed and supported by modeling findings and digital image correlation full field strain maps.
本研究采用两种著名的微机械模型,以及包含编织结构细节的单元格专用有限元模型,对平纹编织复合材料的弹性特性进行了预测。微观机械模型的预测使用了从平纹编织复合材料单元格显微照片中统计测量的几何输入参数,并与有限元预测和 E 玻璃/乙烯基酯平纹编织复合材料的实测弹性特性进行了比较。微机械模型预测,纱线在填充和经纱方向上的宽度和厚度对平纹复合材料的弹性特性和各向异性有很大影响。只要对模型所需的单元格输入几何参数进行严格的统计测量,就能观察到所有方法与平面内弹性特性测量值之间的良好一致性。然而,横向剪切模量并不能通过所研究的微观力学模型准确预测,只能通过有限元方法预测。我们讨论了造成这种差异的原因,并通过建模结果和数字图像相关全场应变图提供了支持。
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引用次数: 0
Mechanical property, oxidation resistance, and ceramization mechanism of MoSi2-SiB6 reinforced phenolic resin matrix composites MoSi2-SiB6 增强酚醛树脂基复合材料的力学性能、抗氧化性和陶瓷化机制
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-09 DOI: 10.1177/07316844241273028
Qiang Shen, Suohui Yang, Shiquan Zhang, Sheng Hu, Junguo Li, Jian Zhang
Ceramizable phenolic resin matrix composites have a significant potential for widespread applications in the field of aerospace ablation. However, due to the sharp decrease of mechanical properties at elevated temperatures, the composite fails to meet the requirements of thermal protection as well as load-bearing of aircraft in a wide temperature range. In this study, boron phenolic composites modified by MoSi2 and SiB6 with high strength in a wide temperature range are prepared. The flexural strength of composites after ablation within the temperature range of 800 °C to 1600 °C ranges from 48.07 to 82.49 MPa. In particular, a significant increase of 224.9% is obtained at 1400 °C with 6 wt% SiB6. The mass ablation rate and line ablation rate of the composites are increased to 0.054 g/s and 0.013 mm/s, respectively. The cooperation effect of oxygen consumption, carbon fixation, oxygen barrier, and liquid phase bonding produced by ceramization reactions involving SiB6, MoSi2, O2, and pyrolytic carbon at different temperatures, resulting in an improvement of the mechanical property and the oxidation resistance of the composite. These composites have a potential in long term thermal protection and load-bearing of new ablation materials.
可釉化酚醛树脂基复合材料在航空航天烧蚀领域具有广泛应用的巨大潜力。然而,由于在高温下力学性能急剧下降,该复合材料无法满足飞机在宽温度范围内的热防护和承重要求。本研究制备了在宽温度范围内具有高强度的 MoSi2 和 SiB6 改性硼酚醛复合材料。在 800 °C 至 1600 °C 的温度范围内,烧蚀后复合材料的抗弯强度在 48.07 至 82.49 MPa 之间。尤其是在 1400 ℃ 时,6 wt% SiB6 的强度显著提高了 224.9%。复合材料的质量烧蚀速率和线烧蚀速率分别提高到 0.054 g/s 和 0.013 mm/s。SiB6、MoSi2、O2 和热解碳在不同温度下的陶瓷化反应产生了耗氧、固碳、阻氧和液相结合的协同效应,从而改善了复合材料的机械性能和抗氧化性。这些复合材料在新型烧蚀材料的长期热保护和承重方面具有潜力。
{"title":"Mechanical property, oxidation resistance, and ceramization mechanism of MoSi2-SiB6 reinforced phenolic resin matrix composites","authors":"Qiang Shen, Suohui Yang, Shiquan Zhang, Sheng Hu, Junguo Li, Jian Zhang","doi":"10.1177/07316844241273028","DOIUrl":"https://doi.org/10.1177/07316844241273028","url":null,"abstract":"Ceramizable phenolic resin matrix composites have a significant potential for widespread applications in the field of aerospace ablation. However, due to the sharp decrease of mechanical properties at elevated temperatures, the composite fails to meet the requirements of thermal protection as well as load-bearing of aircraft in a wide temperature range. In this study, boron phenolic composites modified by MoSi<jats:sub>2</jats:sub> and SiB<jats:sub>6</jats:sub> with high strength in a wide temperature range are prepared. The flexural strength of composites after ablation within the temperature range of 800 °C to 1600 °C ranges from 48.07 to 82.49 MPa. In particular, a significant increase of 224.9% is obtained at 1400 °C with 6 wt% SiB<jats:sub>6</jats:sub>. The mass ablation rate and line ablation rate of the composites are increased to 0.054 g/s and 0.013 mm/s, respectively. The cooperation effect of oxygen consumption, carbon fixation, oxygen barrier, and liquid phase bonding produced by ceramization reactions involving SiB<jats:sub>6</jats:sub>, MoSi<jats:sub>2</jats:sub>, O<jats:sub>2</jats:sub>, and pyrolytic carbon at different temperatures, resulting in an improvement of the mechanical property and the oxidation resistance of the composite. These composites have a potential in long term thermal protection and load-bearing of new ablation materials.","PeriodicalId":16943,"journal":{"name":"Journal of Reinforced Plastics and Composites","volume":"9 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142176334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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