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Investigating tribological performance in 3D-printed PETG/graphene composites of varying composition 研究不同成分的 3D 打印 PETG/ 石墨烯复合材料的摩擦学性能
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-16 DOI: 10.1177/07316844241274294
Surjeet Singh Bedi, Vasu Mallesha
This work examines the effects of several graphene compositions (0.02, 0.04, 0.06, 0.08, and 0.1 wt%) on 3D-printed polyethylene terephthalate glycol (PETG) composites on their sliding wear properties that were created using fused deposition modeling (FDM) following ASTM G99-05 guidelines and the filament of each composition with a diameter of 1.75 mm has been prepared by the compounding and blending process using twin-screw extruder. The sliding wear characteristics are systematically assessed using a pin-on-disc tribometer, with three parameters: a load of 10 N, a standardized wear track diameter of 70 mm, and a rotational speed of 300 r/min. This innovative study explores the impact of low graphene loading on the sliding wear and coefficient of friction of PETG composites, revealing how minimal graphene enhancements significantly decrease wear rates and friction levels. These insights facilitate the development of PETG-based materials with tailored tribological properties, ideal for high-wear applications in industries such as automotive and aerospace, where material longevity and performance are critically important. The investigation showed that the reinforcement of graphene in PETG reduced the coefficient of friction (CoF) and showed better results when graphene’s weight percentage increased from 0.06 wt% to 0.1 wt%. However, it did not help to minimize the specific wear rate (SWR) at the selected parameters for the sliding wear test. Out of all other concentrations of PETG/graphene composites, 0.04 wt% of graphene reinforcement showed a lower SWR but not less than pure PETG. Further, an investigation needs to be done for the discrepancies in the results.
这项工作研究了石墨烯在 3D 打印聚对苯二甲酸乙二酯(PETG)复合材料上的几种成分(0.02、0.04、0.06、0.08 和 0.1 wt%)对其滑动磨损特性的影响。这些复合材料是根据 ASTM G99-05 指南使用熔融沉积建模(FDM)制作的,每种成分的长丝直径为 1.75 mm,是通过双螺杆挤出机的共混和混合工艺制备的。使用针盘摩擦磨损测试仪对滑动磨损特性进行了系统评估,该测试仪有三个参数:载荷为 10 N,标准磨损轨迹直径为 70 mm,转速为 300 r/min。这项创新性研究探讨了低石墨烯负载对 PETG 复合材料滑动磨损和摩擦系数的影响,揭示了石墨烯的最小增强如何显著降低磨损率和摩擦水平。这些见解有助于开发具有定制摩擦学特性的 PETG 材料,非常适合汽车和航空航天等行业的高磨损应用,因为这些行业对材料的使用寿命和性能要求极高。调查显示,在 PETG 中增强石墨烯可降低摩擦系数(CoF),当石墨烯的重量百分比从 0.06 wt% 增加到 0.1 wt% 时,效果更好。然而,在滑动磨损试验的选定参数下,石墨烯无助于将特定磨损率(SWR)降到最低。在 PETG/石墨烯复合材料的所有其他浓度中,0.04 wt% 的石墨烯增强显示出较低的 SWR,但并不比纯 PETG 低。此外,还需要对结果中的差异进行调查。
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引用次数: 0
Compression behavior of sheet-network triply periodic minimal surface metamaterials as a function of density grading 片网三周期极小表面超材料的压缩行为与密度分级的关系
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-16 DOI: 10.1177/07316844241273090
Abdurrahim Temiz, Fatih Pehlivan, Fatih H. Öztürk, Sermet Demir
This study involved the fabrication and experimental testing of five distinct geometries of triply periodic minimal surface (TPMS) cellular structures characterized by uniform and relative density grading. The specific geometries examined were Schoen-Gyroid, Schwarz-Diamond, Schoen-I-WP, Schwarz-Primitive, and Fischer-Koch S. The experimental tests focused on subjecting these structures to compression loads. Samples were produced with a masked stereolithography (MSLA) printer. The samples had initial and end volume fractions (VFs) ranging from 20% to 60% in increments of 10%, with five varied relative densities. The Taguchi method is utilized to determine the optimal testing parameters, while the Analysis of Variance (ANOVA) test is employed to examine the data. The novelty of this paper is to comprehensively investigate the structural efficiency and versatility of TPMS for various applications by optimizing five different functionally graded TPMSs. The ANOVA findings highlighted the substantial impacts of Initial VF, Final VF, and TPMS type on the observed fluctuations in stress at the first peak. The Initial VF made a significant contribution, demonstrating 28.8% higher effectiveness than the Final VF. The TPMS type had a statistically significant effect on the amount of energy absorbed, revealing that different lattice types have abilities to absorb energy.
这项研究涉及五种不同几何形状的三重周期性最小表面(TPMS)蜂窝结构的制造和实验测试,这些蜂窝结构具有均匀和相对密度分级的特点。所研究的具体几何形状包括 Schoen-Gyroid、Schwarz-Diamond、Schoen-I-WP、Schwarz-Primitive 和 Fischer-Koch S。样品是用掩模立体光刻(MSLA)打印机制作的。样品的初始和最终体积分数(VF)范围为 20% 至 60%,增量为 10%,并具有五种不同的相对密度。田口方法用于确定最佳测试参数,方差分析(ANOVA)测试用于检验数据。本文的新颖之处在于通过优化五种不同功能分级的 TPMS,全面研究了 TPMS 在各种应用中的结构效率和多功能性。方差分析结果凸显了初始 VF、最终 VF 和 TPMS 类型对观察到的第一个峰值应力波动的重大影响。初始 VF 的效果显著,比最终 VF 高出 28.8%。TPMS 类型对吸收的能量有显著的统计学影响,揭示了不同晶格类型吸收能量的能力。
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引用次数: 0
Fire-safe composites made from bio-derived and difunctional benzoxazine hybridized matrix reinforced with Pistachio shell particles 用开心果壳颗粒增强的生物衍生和双官能团苯并恶嗪杂化基质制成的防火复合材料
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-16 DOI: 10.1177/07316844241273040
Athar Ali Khan Gorar, Guo Zhiyi, Zhicheng Wang, Chen Qiufei, Abbas Daham, Muhammad Nadeem Ashraf, Jun Wang, Wen-Bin Liu
An isothermal compression molding process was used to create composites reinforced with pistachio shell particles. The composites were made using Bisphenol A–aniline-based benzoxazine and bio-based benzoxazine (VB) monomers derived from vanillin and furfuryl amine. The benzoxazine composites were developed by following green chemistry principles and blending with different weight percentages of Alkali treated pistachio shell particles. Proton nuclear magnetic resonance and Fourier transform infrared spectroscopy confirmed the structure of the VB monomer. Differential scanning calorimetry study shows the curing behavior of monomers and their blends. Surface treatment significantly enhanced the filler’s thermal stability. Copolymerization improved mobility and helped to align the chain and activate reactive groups at lower temperatures, lowering the curing temperature to 229°C with the inclusion of particles. The mechanical properties of composites are significantly enhanced. Compared to the neat matrix, composites showed a maximum increase of 155% in bending strength and 104.5% in impact tests. The theoretical model and simulation results are in good agreement with the experiment data. Thermogravimetric analysis of composites showed that neat polymers and composites have excellent thermal stability ( T10% of 296; Y c 38.4%). The flammability test (UL-94) reveals that composites are rated as V-0 and can be categorized as flame-retardant materials.
采用等温压缩成型工艺制造出了用开心果壳颗粒增强的复合材料。复合材料是用双酚 A-苯胺基苯并恶嗪和从香兰素和糠胺中提取的生物基苯并恶嗪(VB)单体制成的。苯并恶嗪复合材料是按照绿色化学原理,与不同重量百分比的碱处理开心果壳颗粒混合制成的。质子核磁共振和傅立叶变换红外光谱证实了 VB 单体的结构。差示扫描量热法研究显示了单体及其混合物的固化行为。表面处理大大提高了填料的热稳定性。共聚提高了流动性,并有助于在较低温度下排列链和激活活性基团,使加入颗粒后的固化温度降低到 229°C。复合材料的机械性能显著提高。与纯基体相比,复合材料的抗弯强度最大提高了 155%,冲击试验的抗弯强度最大提高了 104.5%。理论模型和模拟结果与实验数据十分吻合。复合材料的热重分析表明,纯聚合物和复合材料都具有出色的热稳定性(T10% 为 296;Y c 为 38.4%)。可燃性测试(UL-94)表明,复合材料的阻燃等级为 V-0,可归类为阻燃材料。
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引用次数: 0
Response of seawater sea sand coral aggregate concrete columns reinforced with hybrid glass fiber reinforced polymer and stainless steel bars under axial compression 用混合玻璃纤维增强聚合物和不锈钢条加固的海水海砂珊瑚骨料混凝土柱在轴向压缩下的响应
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-16 DOI: 10.1177/07316844241272977
Qi Cao, Zongke Jia, Zhimin Wu, Zhongguo J Ma
The potential application prospects for concrete structure in island engineering and marine structures are increasing through the utilization of concrete composed of seawater, sea sand and coral aggregates (SSCC) combined with hybrid reinforcement. This innovative approach effectively addresses the diminishing availability of freshwater and river sand resources, as well as steel corrosion. This study explores the axial load carrying capacity and ductility of columns reinforced with combination of stainless steel bars and GFRP bars. The study conducted tests on 36 columns, varying in strengths (30 MPa, 40 MPa, 50 MPa), reinforcement types (GFRP bars (G group), stainless steel bars (S group), GFRP bars-stainless steel bars (GS group)), and reinforcement ratios (1.01%, 1.56%, 2.26%). The results exhibit positive correlation between the axial load carrying capacity of the column and both the strength grade and reinforcement ratio. In general, SSCC columns reinforced with stainless steel bars (S-SSCC) exhibit the highest axial load carrying capacity, followed by those reinforced with combination of GFRP bars and stainless steel bars (GS-SSCC), and SSCC columns reinforced with GFRP bars (G-SSCC) exhibit the lowest axial load carrying capacity. Furthermore, the axial load carrying capacity was determined utilizing ACI 440, CSA S806 and the finite element software ABAQUS. The results derived from the analytical model exhibited strong agreement with those obtained experimentally. Ductility analysis results suggest that columns with hybrid reinforcement can significantly improve ductility compared to those with only GFRP bars.
通过利用由海水、海砂和珊瑚骨料(SSCC)组成的混凝土与混合加固相结合,混凝土结构在岛屿工程和海洋结构中的潜在应用前景日益扩大。这种创新方法有效地解决了淡水和河沙资源日益减少以及钢筋锈蚀的问题。本研究探讨了使用不锈钢钢筋和 GFRP 钢筋组合加固的柱子的轴向承载能力和延展性。研究对 36 根支柱进行了测试,这些支柱的强度(30 兆帕、40 兆帕、50 兆帕)、加固类型(GFRP 棒(G 组)、不锈钢棒(S 组)、GFRP 棒-不锈钢棒(GS 组))和加固比例(1.01%、1.56%、2.26%)各不相同。结果表明,柱子的轴向承载能力与强度等级和配筋率呈正相关。一般来说,用不锈钢钢筋加固的 SSCC 柱(S-SSCC)的轴向承载能力最高,其次是用 GFRP 钢筋和不锈钢钢筋组合加固的 SSCC 柱(GS-SSCC),而用 GFRP 钢筋加固的 SSCC 柱(G-SSCC)的轴向承载能力最低。此外,轴向承载能力是利用 ACI 440、CSA S806 和有限元软件 ABAQUS 确定的。分析模型得出的结果与实验结果非常一致。延性分析结果表明,与仅使用 GFRP 钢筋的柱子相比,使用混合加固的柱子可显著提高延性。
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引用次数: 0
Experimental investigation of trans-scale displacement responses of wrinkle defects in fiber-reinforced composite laminates 纤维增强复合材料层压板皱褶缺陷跨尺度位移响应的实验研究
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-16 DOI: 10.1177/07316844241273056
Li Ma, Shoulong Wang, Changchen Liu, Ange Wen, Kaidi Ying, Jing Guo
Wrinkle defects were found widely existing in the field of industrial products, that is, wind turbine blades and filament-wound composite pressure vessels. The magnitude of wrinkle wavelength varies from several millimeters to over one hundred millimeters. The detection and quantificationally evaluation of these defects are critical for structural integrity assessments. This study introduces a meso-mechanical model using the homogenization method, which calculates the effective stiffness of graded wrinkle defects. Finite element analysis (FEA) predicts a trans-scale out-of-plane displacement response in wrinkled laminates, with the maximum displacement ranges from nanoscale to millimeter scale. To address this, we utilized shearography (Speckle Pattern Shearing Interferometry) for nanoscale displacements and fringe projection profilometry (FPP) method for larger displacements. In FPP method, a displacement extraction algorithm was presented to obtain the out-of-plane displacement. Comparative analysis indicates that shearography possesses higher sensitivity, capable of detecting load responses as low as 10 N, whereas FPP requires a load range from 200 N to 1000 N. The FEA-validated measurement errors for shearography and FPP are within 3.3%–7.1% and 2.8%–10.5%. The comparison of measurement sensitivity and accuracy between shearography and FPP provides a quantitative reference for industrial non-destructive tests.
皱纹缺陷广泛存在于工业产品领域,即风力涡轮机叶片和丝状缠绕复合材料压力容器。皱纹的波长从几毫米到一百多毫米不等。这些缺陷的检测和量化评估对于结构完整性评估至关重要。本研究采用均质化方法引入了一个介观力学模型,该模型可计算分级皱纹缺陷的有效刚度。有限元分析(FEA)预测了皱褶层压板的跨尺度平面外位移响应,最大位移范围从纳米级到毫米级。为了解决这个问题,我们利用剪切成像法(斑点模式剪切干涉测量法)测量纳米级位移,利用边缘投影轮廓测量法(FPP)测量较大位移。在 FPP 方法中,提出了一种位移提取算法来获取平面外位移。对比分析表明,剪切成像法具有更高的灵敏度,能够检测低至 10 N 的负载响应,而 FPP 法需要 200 N 至 1000 N 的负载范围。经有限元分析验证,剪切成像法和 FPP 法的测量误差分别在 3.3% 至 7.1% 和 2.8% 至 10.5% 之间。剪切成像法和 FPP 测量灵敏度和精确度的比较为工业无损检测提供了定量参考。
{"title":"Experimental investigation of trans-scale displacement responses of wrinkle defects in fiber-reinforced composite laminates","authors":"Li Ma, Shoulong Wang, Changchen Liu, Ange Wen, Kaidi Ying, Jing Guo","doi":"10.1177/07316844241273056","DOIUrl":"https://doi.org/10.1177/07316844241273056","url":null,"abstract":"Wrinkle defects were found widely existing in the field of industrial products, that is, wind turbine blades and filament-wound composite pressure vessels. The magnitude of wrinkle wavelength varies from several millimeters to over one hundred millimeters. The detection and quantificationally evaluation of these defects are critical for structural integrity assessments. This study introduces a meso-mechanical model using the homogenization method, which calculates the effective stiffness of graded wrinkle defects. Finite element analysis (FEA) predicts a trans-scale out-of-plane displacement response in wrinkled laminates, with the maximum displacement ranges from nanoscale to millimeter scale. To address this, we utilized shearography (Speckle Pattern Shearing Interferometry) for nanoscale displacements and fringe projection profilometry (FPP) method for larger displacements. In FPP method, a displacement extraction algorithm was presented to obtain the out-of-plane displacement. Comparative analysis indicates that shearography possesses higher sensitivity, capable of detecting load responses as low as 10 N, whereas FPP requires a load range from 200 N to 1000 N. The FEA-validated measurement errors for shearography and FPP are within 3.3%–7.1% and 2.8%–10.5%. The comparison of measurement sensitivity and accuracy between shearography and FPP provides a quantitative reference for industrial non-destructive tests.","PeriodicalId":16943,"journal":{"name":"Journal of Reinforced Plastics and Composites","volume":"2 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142176376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of Kevlar and Basalt fiber hybridization on vibrational characteristics of composite plates 研究凯夫拉纤维和玄武岩纤维杂化对复合材料板振动特性的影响
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-14 DOI: 10.1177/07316844241273041
Mohammad Salimiyan, Amir Hossein Kazemian, Hossein Moeinkhah, Hossein Rahmani
The study of vibrational characteristics of plates, specifically composite plates, has gained significant importance in contemporary and cutting-edge industries involved in industrial plate manufacturing. This paper investigates the vibrational behavior of composite plates made of Kevlar, basalt, and a hybrid combination of Kevlar and basalt fibers embedded in an epoxy matrix. The investigation was carried out through experimental methods utilizing the D3560 analyzer device. Furthermore, in order to ensure the reliability of the findings, the experimental data were simulated and compared with finite element modeling using the ABAQUS software. The results demonstrate that hybridizing the fibers in the first and second modes leads to an increase in the natural frequency compared to pure Kevlar, while the hybridization effect compared to pure basalt has a negative impact. However, in the third to fifth modes, the layered arrangement shows an increase in the natural frequency compared to pure Kevlar and pure basalt. The experimental results obtained and the simulated ones in the finite element software exhibit a consistent trend.
对板材(尤其是复合材料板材)振动特性的研究,在涉及工业板材制造的当代尖端行业中具有重要意义。本文研究了由凯夫拉纤维、玄武岩纤维以及嵌入环氧树脂基体中的凯夫拉纤维和玄武岩纤维的混合组合制成的复合板的振动行为。研究是通过使用 D3560 分析仪装置的实验方法进行的。此外,为了确保研究结果的可靠性,还使用 ABAQUS 软件对实验数据进行了模拟,并与有限元建模进行了比较。结果表明,与纯 Kevlar 相比,纤维在第一和第二模式下的杂化会导致固有频率的增加,而与纯玄武岩相比,杂化效应则会产生负面影响。然而,在第三至第五模态中,分层排列与纯 Kevlar 纤维和纯玄武岩相比会提高固有频率。实验结果和有限元软件的模拟结果呈现出一致的趋势。
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引用次数: 0
Multi-functional hybrid sandwich composite structures: Evaluating damage mechanics and tolerance using compression after impacts 多功能混合夹层复合结构:利用冲击后的压缩评估损伤力学和耐受性
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-14 DOI: 10.1177/07316844241272988
Zafar Iqbal, Malik Adeel Umer, Haris Ali Khan, Kamran Asim
Building upon previous researches that introduced an innovative foam core hybrid-sandwich composite structure for radome applications, showcasing promising performance under low-velocity impacts (LVIs), this paper delves into the assessment of damage tolerance and mechanics through Compression After Impact (CAI) testing. The primary objective is to analyze disparities in damage tolerance, damage mechanisms, displacements, deformations, energy absorption, and residual strengths resulting from LVIs followed by CAIs on dissimilar materials on opposite faces of the hybrid structure. The extent of damage is evaluated through Computed Tomography (CT) scans. During LVIs, impacts on the S glass face sheets side demonstrated different energy dispersion and absorption mechanisms, leading to variations in indent damage depths and widths across all impact energy levels, unlike the impact damages observed from the Kevlar side. During CAI testing, this difference becomes more evident, with Kevlar specimens (KS3 & KS5) showing greater indentation depths and narrower widths, and S glass specimens (SK3 & SK5) experiencing buckling. These effects are due to the unique damage absorption and dispersion properties of Kevlar and S glass. These variations prompted an in-depth investigation of the structure using CAI to comprehend damage tolerance and mechanisms under compressive loads. This study, unparalleled in existing literature, proposes hybrid sandwich structures with superior specific impact and residual strength compared to various composite sandwich structures documented in published literature, expanding their utility beyond radomes.
之前的研究介绍了一种用于雷达罩的创新型泡沫芯混合夹芯复合材料结构,该结构在低速撞击(LVI)下表现出良好的性能,在此基础上,本文深入研究了通过撞击后压缩(CAI)测试对损伤容限和力学的评估。主要目的是分析混合结构相对面上的异种材料在低速撞击(LVI)后进行 CAI 所产生的损伤容限、损伤机制、位移、变形、能量吸收和残余强度的差异。损伤程度通过计算机断层扫描(CT)进行评估。在 LVI 期间,S 玻璃面片一侧受到的撞击表现出不同的能量分散和吸收机制,导致在所有撞击能量水平上的压痕损伤深度和宽度都有所不同,这与从 Kevlar 一侧观察到的撞击损伤不同。在 CAI 测试中,这种差异变得更加明显,Kevlar 试样(KS3 和 KS5)显示出更大的压痕深度和更窄的宽度,而 S 玻璃试样(SK3 和 SK5)则出现屈曲。这些影响是由于 Kevlar 和 S 玻璃独特的损伤吸收和分散特性造成的。这些变化促使我们使用 CAI 对结构进行深入研究,以了解压缩载荷下的损伤容限和机制。这项研究在现有文献中是绝无仅有的,它提出的混合夹层结构与已发表文献中记载的各种复合夹层结构相比,具有更优异的特定冲击强度和残余强度,从而将其用途扩展到雷达天线罩之外。
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引用次数: 0
Tailoring the vibration characteristics of carbon fiber-reinforced polylactic acid in fused filament fabrication process 在熔融长丝制造工艺中定制碳纤维增强聚乳酸的振动特性
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-14 DOI: 10.1177/07316844241272992
N Vinoth Babu, N Venkateshwaran, S Panneer selvan
The Fused Filament Fabrication (FFF) process has gained significant attention for its ability to manufacture parts using advanced polymeric materials, such as carbon fiber-reinforced polylactic acid (CF-PLA). By adjusting the printing process parameters of the CF-PLA, the optimized mechanical properties can be achieved with less chances of flaws. Structural integrity of the components plays an important role in analyzing the durability of the product which can be analyzed using modal analysis. This research study focuses on analyzing the effect of process parameters on the vibration damping characteristics of CF-PLA components produced by the FFF process. The Taguchi method is used to model the relationship between process parameters and vibration performance metrics. Based on the vibration study, the optimal process parameters were determined as 60% infill density, 0.08 mm slice thickness, and hexagonal pattern. This study shows that the natural frequency and damping increases with increase in infill percent but decreases with increase in slice thickness. The closely aligned values between the predicted and experimental results suggest that the developed model is effective in predicting the vibration characteristics of CF-PLA composites. By accurately adjusting the process parameters, the study’s findings—such as frequencies and damping ratio—provide manufacturers with important and dependable CF-PLA Fused Deposition Modeling components.
熔融长丝制造(FFF)工艺因其使用碳纤维增强聚乳酸(CF-PLA)等先进聚合物材料制造零件的能力而备受关注。通过调整 CF-PLA 的打印工艺参数,可以获得最佳的机械性能,同时减少出现缺陷的几率。在分析产品的耐用性时,部件的结构完整性起着重要作用,可通过模态分析进行分析。本研究的重点是分析工艺参数对通过 FFF 工艺生产的 CF-PLA 部件振动阻尼特性的影响。采用田口方法建立工艺参数与振动性能指标之间的关系模型。根据振动研究结果,确定最佳工艺参数为填充密度 60%、切片厚度 0.08 mm 和六边形图案。研究表明,固有频率和阻尼随填充密度的增加而增加,但随切片厚度的增加而减少。预测值和实验结果之间的密切吻合表明,所开发的模型能有效预测 CF-PLA 复合材料的振动特性。通过精确调整工艺参数,研究结果(如频率和阻尼比)可为制造商提供重要而可靠的 CF-PLA 熔融沉积模型部件。
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引用次数: 0
Synthesis and characterization of novel organoclay-epoxy based flame retardant nanocomposites 新型有机土-环氧基阻燃纳米复合材料的合成与表征
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-13 DOI: 10.1177/07316844241272956
Muhammad Altaf, Muhammad Naeem Ahmed, Anila Iqbal, Arshad Ali Khan
In this study, cost-effective, widely spread, and nontoxic fillers were used to improve the flame retardancy of epoxy nanocomposites. A novel and environmentally benign cation exchange approach was used for the modification of bentonite nanoclay with positively charged L-serine, used to synthesize nanocomposites. Modification of clay was confirmed by using X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) spectroscopy. X-ray diffraction (XRD) technique proved increase of d-spacing from 12.82 Å to 14.42 Å as a result of cation exchange. Field emission scanning electron microscopy (FE-SEM) and energy-dispersive X-ray spectroscopy (EDS) were used to investigate microstructure of the nanocomposites. Reduction in weight loss, with 28.0 % to 34.0 % increase in char yield of epoxy nanocomposites was determined by the thermogravimetric analysis (TGA). Underwriters laboratories (UL-94) V-0 ratings of nanocomposites indicated improved flame retardancy. Nanofillers significantly reduced the loading of aluminum tri-hydroxide (ATH) and improved the flame retardancy through its synergistic effect.
在这项研究中,使用了成本效益高、应用广泛且无毒的填料来提高环氧纳米复合材料的阻燃性。该研究采用了一种新颖且对环境无害的阳离子交换方法,用带正电荷的 L-丝氨酸对膨润土纳米粘土进行改性,用于合成纳米复合材料。使用 X 射线光电子能谱(XPS)和傅立叶变换红外光谱(FT-IR)确认了粘土的改性。X 射线衍射(XRD)技术证明,由于阳离子交换,d-间距从 12.82 Å 增加到 14.42 Å。场发射扫描电子显微镜(FE-SEM)和能量色散 X 射线光谱(EDS)用于研究纳米复合材料的微观结构。通过热重分析(TGA)确定了环氧纳米复合材料的失重率降低,炭产量增加了 28.0% 至 34.0%。美国保险商实验室(UL-94)对纳米复合材料的 V-0 评级表明其阻燃性能有所提高。纳米填料大大降低了三氢氧化铝(ATH)的含量,并通过其协同效应提高了阻燃性。
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引用次数: 0
Study on the influence of sandwich glass structure on its impact resistance 夹层玻璃结构对其抗冲击性能影响的研究
IF 3.1 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-08-13 DOI: 10.1177/07316844241273050
Xiang Wang, Jingjing He, Jing Chen, Yunkuan Zhang, Jing Shi, Xiangrui Wei
In view of the impact resistance of PVB laminated glass, PVB laminated glass of 0.76 mm and 1.52 mm thickness was selected in this paper to form five different types of “2 + 1” and “3 + 2” sandwich glass, and hydrogen gun flying plate variable speed impact combined with CT scanning and three-dimensional reconstruction technology was adopted. The failure mode and crack expansion of glass specimens after impact are studied. The influence of different factors (sandwich thickness, sandwich number, and sandwich position) on the impact resistance of explosion-proof glass is analyzed comprehensively. The results show that increasing the number and thickness of sandwiches can reduce the widening and expansion of microcracks, decrease crack connectivity, and effectively resist plastic damage to glass specimens. The appropriate position of the sandwich helps to improve the load-bearing capacity of the glass specimens. Therefore, the thickness of the sandwich, the number of sandwiches, and the position of the sandwich all have an impact on the impact load capacity and crack development of laminated glass. In addition, the impact resistance of laminated glass is positively correlated with the thickness of the PVB sandwich but shows different damage sensitivity to different impact velocities, with the best impact resistance under its medium velocity condition. This paper provides a significant theoretical foundation for establishing selection criteria for explosion-proof glass by examining the factors that influence its impact resistance, thereby enhancing its safety performance.
针对 PVB 夹层玻璃的抗冲击性能,本文选取了厚度分别为 0.76 mm 和 1.52 mm 的 PVB 夹层玻璃,形成五种不同类型的 "2+1 "和 "3+2 "夹层玻璃,并采用氢枪飞板变速冲击结合 CT 扫描和三维重建技术。研究了冲击后玻璃试样的破坏模式和裂纹扩展情况。综合分析了不同因素(夹层厚度、夹层数量、夹层位置)对防爆玻璃抗冲击性能的影响。结果表明,增加夹层的数量和厚度可以减少微裂纹的扩大和扩展,降低裂纹的连通性,有效抵抗玻璃试样的塑性损伤。夹层的适当位置有助于提高玻璃试样的承载能力。因此,夹层厚度、夹层数量和夹层位置都会对夹层玻璃的冲击承载能力和裂纹发展产生影响。此外,夹层玻璃的抗冲击能力与 PVB 夹层的厚度呈正相关,但对不同冲击速度的破坏敏感性不同,其中中速条件下的抗冲击能力最好。本文通过研究影响防爆玻璃抗冲击性能的因素,为建立防爆玻璃的选择标准提供了重要的理论基础,从而提高了防爆玻璃的安全性能。
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Journal of Reinforced Plastics and Composites
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