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Experimental study on rooftop flow field of building based on the operation of vertical-axis wind turbines 基于垂直轴风力涡轮机运行的建筑物屋顶流场实验研究
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0205549
Jiafeng Hu, Xiangjun Wang, Hua Yang, Bin Huang
Vertical-axis wind turbines (VAWTs) demonstrate good adaptability for harnessing wind energy on the building rooftops. However, knowledge gaps still exist in the understanding of the wind resources on the rooftop, the operation of VAWTs, and its effect on the wind field. To add new knowledge on this subject, the operation of wind turbines modeled by the NACA0018 airfoil on the rooftop of a building is experimentally studied via wind tunnel. The results indicate that flow above the rooftop of building shows an obvious speed reduction due to the blunt body effect of the turbines, and the turbulence intensities are dramatically enhanced. The different tip-speed ratios, wind directions, and installation locations of wind turbine have significant effect on flow field on the roof. Due to the flow characteristics above the rooftop, the power spectral density of the fluctuating wind speed exhibits high energy below the top position of the VAWT on the rooftop. Additionally, the wind profiles and probability distribution of the wake of VAWTs on the rooftop are analyzed and mathematically fitted for quantifying wind field characteristics rooftop turbines on the roof. For the VAWTs investigated in this study, the impacts of the operation of VAWTs on the wind field are non-negligible on the roof of building. The findings of this study will provide valuable insights for the optimal placement of VAWTs and utilization of wind energy on the rooftops.
垂直轴风力涡轮机(VAWT)在利用建筑屋顶风能方面表现出良好的适应性。然而,在了解屋顶风能资源、垂直轴风力涡轮机的运行及其对风场的影响方面仍存在知识空白。为了增加这方面的新知识,我们通过风洞对以 NACA0018 机翼为模型的风力涡轮机在建筑物屋顶上的运行情况进行了实验研究。结果表明,由于涡轮机的钝体效应,建筑物屋顶上方的气流速度明显下降,湍流强度显著增强。不同的风口速比、风向和风机安装位置对屋顶流场有显著影响。由于屋顶上方的流动特性,波动风速的功率谱密度在屋顶 VAWT 的顶部位置下方表现出较高的能量。此外,还对屋顶 VAWT 的风廓线和尾流概率分布进行了分析和数学拟合,以量化屋顶风机的风场特性。对于本研究调查的 VAWT,VAWT 运行对建筑物屋顶风场的影响是不可忽略的。本研究的结果将为屋顶 VAWT 的优化布置和风能利用提供有价值的见解。
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引用次数: 0
Aerodynamic performance and starting torque enhancement of small-scale Darrieus type straight-bladed vertical axis wind turbines with J-shaped airfoil 采用 J 型翼面的小型达里厄斯直叶垂直轴风力发电机的空气动力性能和启动扭矩改进
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0203557
Kabita Naik, Niranjan Sahoo
Wind energy is one of the most eminent renewable sources for the generation of power. The increasing enthusiasm toward the advancement of small-scale Darrieus type straight-bladed vertical axis wind turbines (SB-VAWTs) can offer a potential remedy for addressing power shortage and the unpredictability of climate conditions. These particular wind turbines provide distinct advantages over their counterparts due to their linear blade design and uncomplicated structure. However, enhancements are required in their aerodynamic efficiency and self-initiation capabilities. These challenges stem from using traditional straight blade configurations and symmetrical airfoils. By substituting these conventional elements with J-shaped straight blades and along with cambered airfoils, these issues can be effectively overcome. The current study aims to investigate the effect of J-shaped straight blades with a series of cambered airfoils to improve the aerodynamic performance and starting torque of small-scale Darrieus type SB-VAWTs. Therefore, experimental and numerical studies are conducted to analyze the J-shaped airfoil impact with various opening ratios systematically. The J-shaped blade profile is designed by eliminating some portion toward the trailing edge of a conventional airfoil. This analysis demonstrated that the J-shaped blade incorporating a cambered NACA 4418 airfoil outperforms its alternative cambered airfoil designs. The performance of SB-VAWT improves by about 25% by the J-shape of the cambered NACA 4418 airfoil with a 70% opening ratio. Moreover, the use of J-shaped airfoils enhances the self-starting torque of SB-VAWT compared to conventional airfoils.
风能是最重要的可再生能源之一。人们对小型达里厄斯型直叶垂直轴风力涡轮机(SB-VAWT)的热情日益高涨,这为解决电力短缺和气候条件的不可预测性提供了一种潜在的补救措施。这些特殊的风力涡轮机因其线性叶片设计和简单的结构,与同类产品相比具有明显的优势。然而,它们的空气动力效率和自启动能力仍有待提高。这些挑战源于使用传统的直叶片配置和对称翼面。用 J 形直叶片和外凸机翼取代这些传统元件,可以有效地克服这些问题。本研究旨在探讨 J 形直叶片与一系列外倾机翼对改善小型达里厄斯型 SB-VAWT 的气动性能和启动扭矩的影响。因此,我们进行了实验和数值研究,系统分析了不同开口率的 J 形翼面冲击。J 形叶片轮廓是通过去掉传统机翼后缘的部分而设计的。分析表明,结合了外凸 NACA 4418 翼面的 J 形叶片优于其他外凸翼面设计。由于采用了开口率为 70% 的 J 型凸面 NACA 4418 机翼,SB-VAWT 的性能提高了约 25%。此外,与传统机翼相比,使用 J 形机翼可提高 SB-VAWT 的自启动扭矩。
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引用次数: 0
From wreckage to resource: Advanced 3D printing materials from construction waste for energy infrastructure 从残骸到资源:从建筑垃圾中提取先进的 3D 打印材料,用于能源基础设施建设
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0201775
Zhiqiang Lai, Yuancai Chen
This study redefines resource efficiency in the renewable energy sector by repurposing construction waste into high-performance thixotropic soils for additive manufacturing. Our comprehensive analysis reveals that these engineered soils achieve compressive strengths up to 30 MPa—indicating a 50% increase over traditional substrates—and flexural strengths reaching 5 MPa. Rigorous life cycle assessments quantify a reduction in carbon emissions by 20% and a resource efficiency enhancement to 85%, surpassing conventional materials which average 500 kg CO2 eq/ton in carbon footprint and 60% in resource efficiency. Fine-tuned 3D printing parameters deliver unparalleled precision, achieving layer accuracy to ±0.1 mm and reducing material wastage by 30%, while accelerating construction timelines by 40%. Additionally, the materials exhibit thermal stability with only a 0.1% variation under elevated temperatures and a durability that sustains less than 0.5 MPa degradation over a 10-month period. These quantitatively robust results support the thixotropic soils' adoption, not just as a sustainable choice but as a superior alternative to conventional building materials, setting a new paradigm in the construction of environmentally resilient and economically viable renewable energy infrastructures.
这项研究通过将建筑废料重新利用为高性能触变性土壤,从而重新定义了可再生能源领域的资源效率。我们的综合分析表明,这些工程土的抗压强度高达 30 兆帕,比传统基质提高了 50%,抗折强度也达到了 5 兆帕。严格的生命周期评估表明,碳排放量减少了 20%,资源效率提高了 85%,超过了碳足迹平均为 500 千克二氧化碳当量/吨、资源效率平均为 60% 的传统材料。经过微调的三维打印参数提供了无与伦比的精度,可实现±0.1毫米的层精度,并将材料损耗降低30%,同时将施工时间缩短40%。此外,这些材料还具有热稳定性,在高温条件下仅有 0.1% 的变化,而且在 10 个月的时间里,其耐久性降解小于 0.5 兆帕。这些定量的可靠结果支持了触变性土的应用,它不仅是一种可持续发展的选择,而且是传统建筑材料的优越替代品,为建设具有环境弹性和经济可行性的可再生能源基础设施树立了新的典范。
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引用次数: 0
Evolutionary game and simulation analysis of three parties of electricity market regulation under government participation mechanism 政府参与机制下电力市场监管三方的演化博弈与仿真分析
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0192019
Menglin Hou, Zhumei Luo, Shan Qing, Xiaoxu Zhang
Promoting the widespread access and integration of new energy generation into existing power markets is a key strategy for China to achieve peak carbon and carbon neutrality. A joint regulatory mechanism composed of government regulators, power generation enterprises, and third-party testing organizations has become an effective way to ensure the stable operation of the power market and safeguard the economic interest of all parties. In order to analyze the key factors affecting the mechanism and improve the regulatory efficiency, this paper constructs a three-party evolutionary game model, explores the motivations of the participants under different strategy choices, and establishes a set of indicator systems for evaluating producers. The evolutionary game model is numerically simulated using the unified dynamics method, and the evolutionary stable strategy analysis is used to reveal how the key parameters affect the outcome of the game and its dynamic process, so as to find out the potential driving factors affecting the strategy choices. The results of the study show that in the early stage of market development, it is crucial to improve the profitability of firms, and the government needs to impose strict penalties and high incentives. As the market gradually matures and becomes more transparent, the government can gradually reduce the level of penalties. At the same time, ensuring accountability mechanisms from higher authorities to the government is key to ensure the effectiveness of regulation. This study provides an important theoretical basis and policy recommendations for constructing a new regulatory structure for the electricity market.
促进新能源发电广泛接入和融入现有电力市场,是中国实现碳峰值和碳中和的关键战略。由政府监管部门、发电企业、第三方检测机构组成的联合监管机制已成为保障电力市场稳定运行、维护各方经济利益的有效途径。为了分析影响该机制的关键因素,提高监管效率,本文构建了一个三方演化博弈模型,探讨了不同策略选择下参与者的动机,并建立了一套评价生产者的指标体系。利用统一动力学方法对演化博弈模型进行数值模拟,并通过演化稳定策略分析揭示关键参数如何影响博弈结果及其动态过程,从而找出影响策略选择的潜在驱动因素。研究结果表明,在市场发展初期,提高企业的盈利能力至关重要,政府需要实施严格的惩罚和高额的奖励。随着市场的逐步成熟和透明化,政府可以逐步降低惩罚力度。同时,确保上级部门对政府的问责机制是保证监管有效性的关键。本研究为构建新的电力市场监管结构提供了重要的理论依据和政策建议。
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引用次数: 0
A novel transfer learning strategy for wind power prediction based on TimesNet-GRU architecture 基于 TimesNet-GRU 架构的新型风能预测迁移学习策略
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0200518
Dan Li, Yue Hu, Baohua Yang, Zeren Fang, Yunyan Liang, Shuai He
Currently, data-driven deep learning models are widely applied in the field of wind power prediction. However, when historical data are insufficient, deep learning models struggle to exhibit satisfactory predictive performance. In order to overcome the issue of limited training data for new wind farms, this study proposes a novel transfer learning strategy to address the challenge of less-sample learning in short-term wind power prediction. The research is conducted in two stages. In the pre-training stage, the TimesNet-GRU prediction model is established using data from a source wind farm. Parallel TimesNet modules are employed to extract multi-period features from various input feature sequences, followed by the extraction of long- and short-term features from the time series through gate recurrent unit (GRU). In the transfer learning stage, an effective transfer strategy is designed to freeze and retrain certain parameters of the TimesNet-GRU, thereby constructing a prediction model for the target wind farm. To validate the effectiveness of this approach, the results from testing with actual data from five wind farms in northwest China demonstrate that the proposed method exhibits significant advantages over models without transfer learning as explored in this study.
目前,数据驱动的深度学习模型被广泛应用于风力发电预测领域。然而,当历史数据不足时,深度学习模型很难表现出令人满意的预测性能。为了克服新风场训练数据有限的问题,本研究提出了一种新颖的迁移学习策略,以应对短期风电预测中样本较少学习的挑战。研究分两个阶段进行。在预训练阶段,使用源风电场的数据建立 TimesNet-GRU 预测模型。采用并行 TimesNet 模块从各种输入特征序列中提取多周期特征,然后通过门递归单元(GRU)从时间序列中提取长期和短期特征。在迁移学习阶段,设计了一种有效的迁移策略来冻结和重新训练 TimesNet-GRU 的某些参数,从而为目标风场构建预测模型。为了验证这种方法的有效性,利用中国西北地区五个风电场的实际数据进行测试的结果表明,与本研究探索的没有转移学习的模型相比,所提出的方法具有显著优势。
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引用次数: 0
Research on the participation model of energy storage in electricity spot markets considering energy constraints and cost characteristics 考虑能源约束和成本特征的电力现货市场储能参与模式研究
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0194872
Mingyuan Chen, Le Qi, Peizheng Xuan, Yanjie Liang, Youhui Yang, Qi Zou, Lanfen Cheng, Chaoyi Peng, Huayuan Li
In the context of power systems with a high proportion of renewable energy, energy storage plays a significant role in facilitating the consumption of renewable energy and ensuring the operational safety of power systems. However, the current power spot market's predominant power bidding model does not fully consider the physical and cost-operational characteristics of energy storage, which is not conducive to further incentivizing investment and construction of energy storage, and may indirectly affect the flexibility of energy storage in peak shaving and valley filling. This paper summarizes the key issues that need to be addressed for energy storage to participate in the spot market from two aspects: the power bidding model does not meet the requirements of the physical and cost-operational characteristics of energy storage, and the real-time market under this model cannot achieve optimal allocation of energy storage. Considering the energy constraints and cost characteristics of energy storage, a charge and discharge bidding model is proposed, which is based on the stored energy value of energy storage and is in line with the physical and cost-operational characteristics and real-time optimization needs of energy storage. Subsequently, a market clearing model for energy storage participation in the spot market under the state of energy bidding method is constructed, and based on the IEEE 39-bus test case, a comparative analysis of the nodal electricity prices, energy storage revenue, and total system costs under the proposed market participation model and the traditional power bidding model is conducted. Simulation results show that the proposed energy storage participation model in the spot market can better utilize the value of energy storage in peak shaving and valley filling compared to the conventional power bidding model, reducing the extreme electricity prices by up to 10%, increasing single cycle revenue of energy storage by 46%, and reducing the total operating costs of the system in scenarios with significant deviations in system load in the day-ahead and real-time markets.
在可再生能源比例较高的电力系统中,储能在促进可再生能源消纳和保障电力系统运行安全方面发挥着重要作用。然而,目前电力现货市场占主导地位的电量竞价模式并未充分考虑储能的物理特性和成本运营特性,不利于进一步激励储能的投资和建设,并可能间接影响储能在削峰填谷中的灵活性。本文从两个方面总结了储能参与现货市场需要解决的关键问题:一是电量竞价模式不符合储能物理特性和成本运营特性的要求,二是该模式下的实时市场无法实现储能的优化配置。考虑到储能的能量约束和成本特性,提出了基于储能储能值的充放电竞价模型,该模型符合储能的物理特性、成本运营特性和实时优化需求。随后,构建了能量状态竞价方法下储能参与现货市场的市场出清模型,并基于 IEEE 39-bus 测试用例,对提出的市场参与模型和传统电力竞价模型下的节点电价、储能收益和系统总成本进行了对比分析。仿真结果表明,与传统电力竞价模式相比,提出的储能参与现货市场模式能更好地发挥储能在削峰填谷中的价值,在日前市场和实时市场系统负荷出现显著偏差的情况下,极端电价最高可降低 10%,储能单周期收益可提高 46%,系统总运营成本可降低。
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引用次数: 0
Wave-phase dependence of Reynolds shear stress in the wake of fixed-bottom offshore wind turbine via quadrant analysis 通过象限分析确定定底式海上风力涡轮机尾流中雷诺切应力的波相依赖性
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0191264
C. Mouchref, B. Viggiano, O. Ferčák, J. Bossuyt, N. Ali, C. Meneveau, D. Gayme, R. B. Cal
There has been an increase in recognition of the important role that the boundary layer turbulent flow structure has on wake recovery and concomitant wind farm efficiency. Most research thus far has focused on onshore wind farms, in which the ground surface is static. With the expected growth of offshore wind farms, there is increased interest in turbulent flow structures above wavy, moving surfaces and their effects on offshore wind farms. In this study, experiments are performed to analyze the turbulent structure above the waves in the wake of a fixed-bottom model wind farm, with special emphasis on the conditional averaged Reynolds stresses, using a quadrant analysis. Phase-averaged profiles show a correlation between the Reynolds shear stresses and the curvature of the waves. Using a quadrant analysis, Reynolds stress dependence on the wave phase is observed in the phase-dependent vertical position of the turbulence events. This trend is primarily seen in quadrants 1 and 3 (correlated outward and inward interactions). Quantification of the correlation between the Reynolds shear stress events and the surface waves provides insight into the turbulent flow mechanisms that influence wake recovery throughout the wake region and should be taken into consideration in wind turbine operation and placement.
人们越来越认识到边界层湍流结构对尾流恢复和风场效率的重要作用。迄今为止,大多数研究都集中在地面静止的陆上风电场。随着海上风电场的预期增长,人们对波浪形运动表面上的湍流结构及其对海上风电场的影响越来越感兴趣。本研究采用象限分析法,对固定底部模型风电场尾流波浪上方的湍流结构进行了实验分析,重点分析了条件平均雷诺应力。相位平均剖面图显示雷诺剪应力与波浪曲率之间存在相关性。通过象限分析,可以观察到雷诺应力与波浪相位的关系,即湍流事件的垂直位置与相位有关。这种趋势主要出现在第 1 和第 3 象限(相关的向外和向内相互作用)。对雷诺切应力事件和表面波之间的相关性进行量化,可以深入了解影响整个尾流区域尾流恢复的湍流机制,在风力涡轮机运行和布置时应加以考虑。
{"title":"Wave-phase dependence of Reynolds shear stress in the wake of fixed-bottom offshore wind turbine via quadrant analysis","authors":"C. Mouchref, B. Viggiano, O. Ferčák, J. Bossuyt, N. Ali, C. Meneveau, D. Gayme, R. B. Cal","doi":"10.1063/5.0191264","DOIUrl":"https://doi.org/10.1063/5.0191264","url":null,"abstract":"There has been an increase in recognition of the important role that the boundary layer turbulent flow structure has on wake recovery and concomitant wind farm efficiency. Most research thus far has focused on onshore wind farms, in which the ground surface is static. With the expected growth of offshore wind farms, there is increased interest in turbulent flow structures above wavy, moving surfaces and their effects on offshore wind farms. In this study, experiments are performed to analyze the turbulent structure above the waves in the wake of a fixed-bottom model wind farm, with special emphasis on the conditional averaged Reynolds stresses, using a quadrant analysis. Phase-averaged profiles show a correlation between the Reynolds shear stresses and the curvature of the waves. Using a quadrant analysis, Reynolds stress dependence on the wave phase is observed in the phase-dependent vertical position of the turbulence events. This trend is primarily seen in quadrants 1 and 3 (correlated outward and inward interactions). Quantification of the correlation between the Reynolds shear stress events and the surface waves provides insight into the turbulent flow mechanisms that influence wake recovery throughout the wake region and should be taken into consideration in wind turbine operation and placement.","PeriodicalId":16953,"journal":{"name":"Journal of Renewable and Sustainable Energy","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141032490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study on preheating and salt circulation performance of a single receiver tube based on induction heating 基于感应加热的单接收管预热和盐循环性能实验研究
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0205772
Hao Zhou, Ao Zhang, Yuhang Zuo, Yifan Zhu, Xue Xue, Mingrui Zhang
The design of a light source for a molten salt receiver experimental system has become challenging owing to the complex heating characteristics of the half-circumference surface during operation. Electromagnetic induction heating is an innovative technology that can replicate a half-circle heating scenario. However, its feasibility must be verified. In this study, we constructed a single receiver tube experimental system using induction heaters and developed a 3D numerical model coupling electromagnetic field to analyze the tube temperature distribution and molten salt temperature rise during preheating and salt circulation, considering various parameters. The results indicated that the numerical simulation agreed well with the experimental results, and the induction heater successfully reproduced the half circumference heating scenario. During preheating, a lower heat flux and higher wind speed result in a more uniform temperature distribution along the circumference of the tube wall, facilitating comprehensive preheating. During salt circulation, the heat flux and inlet salt mass flow significantly affected the temperature of the tube wall but had a relatively small effect on the back-side wall. Wind speed had the opposite effect, which was related to the arrangement of the experimental site. A higher heat flux, lower wind speed, and higher inlet salt mass flow led to a higher temperature increase in the molten salt.
由于半圆表面在运行过程中具有复杂的加热特性,为熔盐接收器实验系统设计光源已成为一项挑战。电磁感应加热是一种创新技术,可以复制半圆加热情景。然而,其可行性必须得到验证。在本研究中,我们利用感应加热器构建了单接收管实验系统,并开发了一个耦合电磁场的三维数值模型,在考虑各种参数的情况下,分析了预热和盐循环过程中的管温分布和熔盐温升。结果表明,数值模拟与实验结果吻合良好,感应加热器成功再现了半周加热情景。在预热过程中,较低的热通量和较高的风速会导致沿管壁圆周的温度分布更加均匀,从而有利于全面预热。在盐循环过程中,热通量和入口盐质量流对管壁温度的影响很大,但对背面管壁的影响相对较小。风速的影响则相反,这与实验场地的布置有关。较高的热通量、较低的风速和较高的入口盐质量流量会导致熔盐温度升高。
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引用次数: 0
Influence of the development of solar photovoltaic industry on the relationship between supply and demand of key minerals in China 太阳能光伏产业发展对中国主要矿产品供求关系的影响
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-05-01 DOI: 10.1063/5.0202427
Qing Guo, Kaiyi Wu
The importance of mineral resources cannot be ignored in the country's economic and social development and is of vital significance in securing China's continued economic and social prosperity. Against the backdrop of the country's active promotion of the clean energy industry, the booming development of the photovoltaic industry has triggered a growing demand for its key raw materials, especially important metallic minerals. Based on the system dynamics theory, the article uses Vensim to construct a photovoltaic cell-key metal mineral simulation model to analyze the development of China's photovoltaic industry in depth and focuses on its far-reaching impact on the supply and demand relationship of key minerals. The results of the study show that (1) China's photovoltaic cells show strong growth; (2) recycling and technology substitution can significantly reduce the risk of copper and aluminum supply and demand imbalance; and (3) technology substitution is more effective than recycling in reducing the supply and demand imbalance of copper and aluminum. Based on the above-mentioned findings, the article puts forward corresponding policy recommendations.
矿产资源在国家经济和社会发展中的重要性不容忽视,对于确保中国经济和社会的持续繁荣具有至关重要的意义。在国家积极推进清洁能源产业的背景下,光伏产业的蓬勃发展引发了对其关键原材料,尤其是重要金属矿产日益增长的需求。文章以系统动力学理论为基础,利用 Vensim 构建了光伏电池-关键金属矿产仿真模型,深入分析了我国光伏产业的发展情况,并重点探讨了其对关键矿产供需关系的深远影响。研究结果表明:(1)中国光伏电池呈现出强劲的增长势头;(2)回收利用和技术替代可以显著降低铜铝供需失衡的风险;(3)在降低铜铝供需失衡方面,技术替代比回收利用更有效。基于上述结论,文章提出了相应的政策建议。
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引用次数: 0
Methane catalytic cracking by solid materials and molten media for hydrogen production: A review 利用固体材料和熔融介质催化裂解甲烷制氢:综述
IF 2.5 4区 工程技术 Q2 Energy Pub Date : 2024-03-01 DOI: 10.1063/5.0188819
Lei Guo, Jinchi Tan, Junyue Ren, Zhancheng Guo
Excessive emission of carbon dioxide is the leading cause of global warming. Hydrogen has the advantages of high calorific value and zero carbon emissions. It is considered an ideal energy to solve the problem of global warming, so the demand for hydrogen is increasing yearly. Due to economic considerations, methane is the main raw material for hydrogen production. Currently, 48% of the world's hydrogen comes from steam methane reforming. However, this process needs to burn some methane for heating, generating carbon dioxide emissions simultaneously. In order to avoid carbon emissions from hydrogen production, there is an urgent need to develop new methods to produce hydrogen from methane. Because the carbon generated from direct methane cracking exists in solid form while not as carbon dioxide, the direct methane cracking process for hydrogen production has become a hot research topic in recent years. In this paper, a comprehensive review of the research related to catalytic methane cracking for hydrogen production is presented, especially the research on catalytic cracking of methane using solid materials or molten metal media as catalytic media is summarized in detail. Next, a brief overview of the mechanism of catalytic methane cracking for hydrogen production and the characteristics of the generated carbon as a by-product are presented. Finally, the catalytic cracking of methane in molten media or solid materials and the research trend were prospected.
二氧化碳的过度排放是全球变暖的主要原因。氢气具有高热值和零碳排放的优点。它被认为是解决全球变暖问题的理想能源,因此对氢的需求逐年增加。出于经济方面的考虑,甲烷是制氢的主要原料。目前,全球 48% 的氢气来自甲烷蒸汽转化。然而,这一过程需要燃烧部分甲烷进行加热,同时会产生二氧化碳排放。为了避免制氢过程中的碳排放,迫切需要开发新的甲烷制氢方法。由于直接甲烷裂解产生的碳是以固体形式存在,而不是以二氧化碳形式存在,因此直接甲烷裂解制氢工艺成为近年来的研究热点。本文全面综述了催化甲烷裂解制氢的相关研究,特别是详细总结了以固体材料或熔融金属介质为催化介质的甲烷催化裂解研究。接着,简要介绍了催化甲烷裂解制氢的机理以及副产品碳的特性。最后,展望了在熔融介质或固体材料中催化裂解甲烷及其研究趋势。
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引用次数: 0
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