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LIBS Monitoring and Analysis of Laser-Based Layered Controlled Paint Removal from Aircraft Skin 基于激光分层控制的飞机蒙皮脱漆LIBS监测与分析
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-09-30 DOI: 10.1155/2021/4614388
Wenfeng Yang, Ziran Qian, Yu Cao, Yongchao Wei, Chanyuan Fu, TianQuan Li, Dehui Lin, Shaolong Li
Reliability and controllability of selective removal of multiple paint layers from the surface of aircraft skin depend on effective online monitoring technology. An analysis was performed on the multi-pulse laser-induced breakdown spectroscopy (LIBS) on the surface of the aluminum alloy substrate, primer, and topcoat. Based on that, an exploration was conducted on the changes of the characteristic peaks corresponding to the characteristic elements that are contained in the topcoat, primer, and substrate with different layers of a laser action, in combination with analysis of microscopic morphology, composition, and depth of laser multi-pulse pits. The results show that the appearance and increase of the characteristic peak intensity of the Ca I at the wavelength of 422.7 nm can be regarded as the basis for the complete removal of the topcoat; the decrease or disappearance of the characteristic peak intensity can be regarded as the basis for the complete removal of the primer. Al I spectrum at the wavelength of 394.5 nm and 396.2 nm can be adopted to characterize the degree of damage to the aluminum alloy substrate. The feasibility and accuracy of the LIBS technology for the laser selective paint removal process and effect monitoring of aircraft skin were verified. Demonstrating that under the premise of not damaging the substrate, laser-based layered controlled paint removal (LLCPR) from aircraft skin can be achieved by monitoring the spectrum and composition change law of specified wavelength position corresponding tothe characteristic elements that are contained in the specific paint layer.
飞机蒙皮表面多层涂料选择性去除的可靠性和可控性取决于有效的在线监测技术。对铝合金基材、底漆和面漆表面进行了多脉冲激光诱导击穿光谱(LIBS)分析。在此基础上,结合对激光多脉冲坑的微观形貌、组成和深度的分析,探讨了激光作用不同层位的面漆、底漆和基材中所含特征元素对应的特征峰的变化。结果表明:Ca I在422.7 nm波长处的出现和特征峰强度的增加可以作为完全去除面漆的基础;特征峰强度的减小或消失可视为底漆完全去除的依据。可以采用394.5 nm和396.2 nm波长的Al I光谱来表征铝合金基体的损伤程度。验证了LIBS技术用于飞机蒙皮激光选择性除漆工艺及效果监测的可行性和准确性。证明了在不损坏基材的前提下,通过监测特定涂料层中所含特征元素对应的特定波长位置的光谱和成分变化规律,可以实现基于激光的飞机蒙皮分层控制除漆(LLCPR)。
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引用次数: 3
Soil Classification Based on Deep Learning Algorithm and Visible Near-Infrared Spectroscopy 基于深度学习算法和可见近红外光谱的土壤分类
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-09-03 DOI: 10.1155/2021/1508267
Xueying Li, Pingping Fan, Zongmin Li, Guangyuan Chen, Huimin Qiu, G. Hou
Changes in land cover will cause the changes in the climate and environmental characteristics, which has an important influence on the social economy and ecosystem. The main form of land cover is different types of soil. Compared with traditional methods, visible and near-infrared spectroscopy technology can classify different types of soil rapidly, effectively, and nondestructively. Based on the visible near-infrared spectroscopy technology, this paper takes the soil of six different land cover types in Qingdao, China orchards, woodlands, tea plantations, farmlands, bare lands, and grasslands as examples and establishes a convolutional neural network classification model. The classification results of different number of training samples are analyzed and compared with the support vector machine algorithm. Under the condition that Kennard–Stone algorithm divides the calibration set, the classification results of six different soil types and single six soil types by convolutional neural network are better than those by the support vector machine. Under the condition of randomly dividing the calibration set according to the proportion of 1/3 and 1/4, the classification results by convolutional neural network are also better. The aim of this study is to analyze the feasibility of land cover classification with small samples by convolutional neural network and, according to the deep learning algorithm, to explore new methods for rapid, nondestructive, and accurate classification of the land cover.
土地覆被的变化会引起气候环境特征的变化,对社会经济和生态系统产生重要影响。土地覆盖的主要形式是不同类型的土壤。与传统方法相比,可见光和近红外光谱技术可以快速、有效、无损地对不同类型的土壤进行分类。基于可见近红外光谱技术,以中国青岛市果园、林地、茶园、农田、裸地和草地6种不同土地覆被类型土壤为例,建立了卷积神经网络分类模型。分析了不同数量训练样本的分类结果,并与支持向量机算法进行了比较。在Kennard-Stone算法划分校准集的条件下,卷积神经网络对6种不同土壤类型和单一6种土壤类型的分类结果优于支持向量机。在按1/3和1/4的比例随机划分标定集的情况下,卷积神经网络的分类效果也更好。本研究旨在分析基于卷积神经网络的小样本土地覆盖分类的可行性,并根据深度学习算法,探索快速、无损、准确的土地覆盖分类新方法。
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引用次数: 11
Evaluation of the Effectiveness of Multiple Machine Learning Methods in Remote Sensing Quantitative Retrieval of Suspended Matter Concentrations: A Case Study of Nansi Lake in North China 多种机器学习方法在悬浮物浓度遥感定量检索中的有效性评价——以华北南四湖为例
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-08-13 DOI: 10.1155/2021/5957376
Xiuyu Liu, Zhen Zhang, Tao Jiang, Xuehua Li, Yanyi Li
Total suspended matter (TSM) is a core parameter in the quantitative retrieval of ocean color remote sensing and an important indicator for evaluating the quality of the aquatic environment. This study selects part of Nansi Lake in North China as the study area. Researchers used Hyperion remote sensing data and field-measured TSM concentration as data sources. Firstly, the characteristic variables with high correlation were selected based on spectral analysis. Then, seven methods such as linear regression, BP neural network (BP), KNN, random forest (RF), and random forest based on genetic algorithm optimization (GA_RF) are used to construct the inversion model of TSM concentration. The retrieval accuracy of each model shows that the machine learning models are much more accurate than the linear model. Among them, the GA_RF model retrieves the suspended solids concentration with the best performance and the highest prediction accuracy, with a determination coefficient R2 of 0.98, a root mean square error (RMSE) of 1.715 mg/L, and an average relative error (ARE) of 6.83%. Additionally, the spatial distribution of TSM concentration was inversed by Hyperion remote sensing image. The results showed that the concentration of TSM was lower in the northwest and higher in the southeast, and the concentration distribution was uneven, showing the characteristics of a typical shallow macrophytic lake. This study provides an effective method for monitoring TSM concentration and other water quality parameters in the shallow macrophytic lake and further proves the advantages of machine learning in ocean color inversion. All in all, this research provides some useful methods and suggestions for quantitative inversion of TSM concentration in shallow macrophytic lakes.
总悬浮物(TSM)是海洋颜色遥感定量检索中的核心参数,也是评价海洋环境质量的重要指标。本研究选取华北南四湖部分区域作为研究区域。研究人员使用Hyperion遥感数据和现场测量的TSM浓度作为数据源。首先,基于谱分析选择相关性较高的特征变量;然后,采用线性回归、BP神经网络(BP)、KNN、随机森林(RF)和基于遗传算法优化的随机森林(GA_RF)等7种方法构建TSM浓度的反演模型。每个模型的检索精度表明,机器学习模型比线性模型要准确得多。其中,GA_RF模型对悬浮物浓度的反演效果最好,预测精度最高,决定系数R2为0.98,均方根误差(RMSE)为1.715 mg/L,平均相对误差(ARE)为6.83%。此外,利用Hyperion遥感影像反演了TSM浓度的空间分布。结果表明:TSM浓度呈西北低东南高的趋势,且浓度分布不均匀,呈现出典型的浅层大型植物湖特征;本研究为监测浅层大型植物湖TSM浓度等水质参数提供了一种有效的方法,进一步证明了机器学习在海洋颜色反演中的优势。总之,本研究为浅植湖TSM浓度的定量反演提供了一些有用的方法和建议。
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引用次数: 4
Wood Species Recognition Based on Visible and Near-Infrared Spectral Analysis Using Fuzzy Reasoning and Decision-Level Fusion 基于模糊推理和决策级融合的可见光和近红外光谱分析的树种识别
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-07-22 DOI: 10.1155/2021/6088435
Peng Zhao, Zhen-Yu Li, Cheng-Kun Wang
A novel wood species spectral classification scheme is proposed based on a fuzzy rule classifier. The visible/near-infrared (VIS/NIR) spectral reflectance curve of a wood sample’s cross section was captured using a USB 2000-VIS-NIR spectrometer and a FLAME-NIR spectrometer. First, the wood spectral curve—with spectral bands of 376.64–779.84 nm and 950–1650 nm—was processed using the principal component analysis (PCA) dimension reduction algorithm. The wood spectral data were divided into two datasets, namely, training and testing sets. The training set was used to generate the membership functions and the initial fuzzy rule set, with the fuzzy rule being adjusted to supplement and refine the classification rules to form a perfect fuzzy rule set. Second, a fuzzy classifier was applied to the VIS and NIR bands. An improved decision-level fusion scheme based on the Dempster–Shafer (D-S) evidential theory was proposed to further improve the accuracy of wood species recognition. The test results using the testing set indicated that the overall recognition accuracy (ORA) of our scheme reached 94.76% for 50 wood species, which is superior to that of conventional classification algorithms and recent state-of-the-art wood species classification schemes. This method can rapidly achieve good recognition results, especially using small datasets, owing to its low computational time and space complexity.
提出了一种新的基于模糊规则分类器的树种光谱分类方案。采用USB 2000-VIS-NIR光谱仪和FLAME-NIR光谱仪采集木材样品横截面的可见/近红外(VIS/NIR)光谱反射率曲线。首先,采用主成分降维算法对光谱波段为376.64 ~ 779.84 nm和950 ~ 1650 nm的木材光谱曲线进行处理。木材光谱数据分为两个数据集,即训练集和测试集。利用训练集生成隶属函数和初始模糊规则集,对模糊规则进行调整,对分类规则进行补充和细化,形成一个完善的模糊规则集。其次,对可见光波段和近红外波段进行模糊分类。为了进一步提高树种识别的准确性,提出了一种改进的基于Dempster-Shafer (D-S)证据理论的决策级融合方案。使用测试集进行的测试结果表明,该方案对50种木材的总体识别准确率(ORA)达到94.76%,优于传统分类算法和目前最先进的木材种类分类方案。该方法具有较低的计算时间和空间复杂度,可以快速获得较好的识别效果,特别是在小数据集的情况下。
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引用次数: 5
Spectroscopic Analysis for Harnessing the Quality and Potential of Gemstones for Small and Medium-Sized Enterprises (SMEs) 为中小企业利用宝石质量和潜力的光谱分析
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-07-08 DOI: 10.1155/2021/6629640
Imtiaz Ahmad, S. H. Serbaya, A. Rizwan, M. Mehmood
Introduction of modern technologies and methods and quality analysis for the gemstone industry are the main strategic initiatives of the Small and Medium Development Authority (SMEDA) of Pakistan. In this regard, four natural gemstones Quartz, Pyrope-Almandine Garnet, Black tourmaline, and Amethyst brought from Hunza valley Pakistan were analyzed by state-of-the-art spectroscopic techniques including EDX, UV-VIS, and FTIR spectroscopy. EDX revealed the traces of Fe, Mg, and Ca in Pyrope-Almandine garnet, Mg and Fe in Black tourmaline, Au and Ca in Amethyst. UV-VIS data revealed the values of Urbach energies 520, 210, 460, and 430 meV, and the values of direct bandgap energies 5.14, 6.12, 5.54, 5.74 eV, respectively. The higher structural disorder due to the presence of Fe and other impurities in stones except Quartz was attributed to the higher values of Urbach energies and decrease in band gaps: FTIR data Fe-O and Si-O stretching vibration in Pyrope-Almandine garnet, Si-O bending vibrations and O-H stretching vibration in Quartz, Si-O-Si bending and stretching vibrations and C=O stretching vibrations in Black tourmaline, Ca-O stretching vibrations and Si-OH weak-vibrations in Amethyst. Photoluminescence results also showed useful information in investigating the properties of gemstones.
为宝石行业引进现代技术和方法以及质量分析是巴基斯坦中小发展局(SMEDA)的主要战略举措。在这方面,通过最先进的光谱技术,包括EDX, UV-VIS和FTIR光谱,分析了来自巴基斯坦罕萨山谷的四种天然宝石石英,Pyrope-Almandine石榴石,黑色电气石和紫水晶。EDX检测结果显示,红铝石榴石中有微量的Fe、Mg和Ca,黑电气石中有微量的Mg和Fe,紫水晶中有微量的Au和Ca。UV-VIS数据显示其Urbach能分别为520、210、460和430 meV,直接带隙能分别为5.14、6.12、5.54和5.74 eV。除石英外,由于Fe和其他杂质的存在导致了较高的结构无序性,其原因是Urbach能量值较高,带隙减小:FTIR数据显示,焦石铝石榴石中Fe-O和Si-O的拉伸振动,石英中Si-O的弯曲振动和O- h的拉伸振动,黑电气石中Si-O- si的弯曲振动和C=O的拉伸振动,紫水晶中Ca-O的拉伸振动和Si-OH的弱振动。光致发光结果也为研究宝石的性质提供了有用的信息。
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引用次数: 15
Research on Correction Method of Water Quality Ultraviolet-Visible Spectrum Data Based on Compressed Sensing 基于压缩感知的水质紫外可见光谱数据校正方法研究
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-07-02 DOI: 10.1155/2021/6650630
Fengxiao Li, Bin Tang, Mingfu Zhao, Xinyu Hu, Sheng-hui Shi, Mi Zhou
The turbidity interference caused by suspended particles in water seriously affects the accuracy of ultraviolet-visible spectroscopy in detecting water quality chemical oxygen demand. Based on this, the application of ultraviolet-visible spectroscopy to detect water quality chemical oxygen demand usually requires physical and mathematical methods to correct the spectral baseline interference caused by turbidity. Because of the slow response speed and unstable compensation effect of traditional correction methods, this paper proposes to use a compressed sensing algorithm to perform baseline correction and achieve good results. In the experiment, we selected formazin turbidity solution and sodium oxalate standard solution and carried out the research on the algorithm of turbidity correction for detecting chemical oxygen demand of water quality by ultraviolet-visible spectroscopy. The experiment obtains the absorption spectra of different concentrations of formazine turbidity solutions and the same concentration of sodium oxalate with different turbidity standard solutions at 210∼845 nm and analyzes the nonlinear effect of absorbance on turbidity. This article uses standard solution experiments to explore the compressed sensing theory for turbidity correction, and through the correction of the absorption spectrum of the actual water sample, it verifies the feasibility of the compression theory for turbidity correction. The method effectively corrects the baseline shift or drift of the water quality ultraviolet-visible absorption spectrum caused by suspended particles, while retaining the absorption characteristics of the ultraviolet spectrum, and it can effectively improve the accuracy and accuracy of the ultraviolet-visible spectroscopy water quality chemical oxygen demand detection.
水中悬浮粒子引起的浊度干扰严重影响了紫外可见光谱法检测水质化学需氧量的准确性。基于此,应用紫外可见光谱法检测水质化学需氧量通常需要物理和数学方法对浑浊度引起的光谱基线干扰进行校正。针对传统校正方法响应速度慢、补偿效果不稳定的问题,本文提出采用压缩感知算法进行基线校正,取得了较好的效果。在实验中,我们选取了甲肼浊度溶液和草酸钠标准溶液,对紫外可见光谱法检测水质化学需氧量的浊度校正算法进行了研究。实验获得了不同浓度的甲醛浊度溶液和相同浓度的草酸钠与不同浊度标准溶液在210 ~ 845 nm的吸收光谱,并分析了吸光度对浊度的非线性影响。本文采用标准溶液实验探索压缩感知理论用于浊度校正,并通过对实际水样的吸收光谱进行校正,验证了压缩感知理论用于浊度校正的可行性。该方法有效地纠正了悬浮颗粒引起的水质紫外可见吸收光谱的基线偏移或漂移,同时保留了紫外光谱的吸收特性,可以有效地提高紫外可见光谱水质化学需氧量检测的准确度和准确度。
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引用次数: 4
Nondestructive Detection of Moisture Content in Walnut Kernel by Near-Infrared Diffuse Reflectance Spectroscopy 近红外漫反射光谱法无损检测核桃仁水分含量
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-06-16 DOI: 10.1155/2021/9986940
Dan Peng, Yali Liu, Jiasheng Yang, Yanlan Bi, Jingnan Chen
The rapid and accurate detection of the moisture content is of great significance to the quality evaluation and oil extraction process of walnut kernel. Near-infrared (NIR) spectroscopy is an ideal method for measuring the moisture content in walnut kernel. In this study, a regression model for moisture content in walnut kernel was developed based on NIR diffuse reflectance spectroscopy using chemometric methods. The different spectral pretreatment methods were adopted to preprocess the original spectral data. The whole spectra band was divided into 5 subbands, 10 subbands, 15 subbands, and 20 subbands to screen specific wavelengths relevant to the walnut kernel moisture content. PLS (partial least square regression), MLR (multivariate linear regression), PCR (principle component regression), and SVR (support vector regression) were used to establish the relationship model between the spectral data and measurement values of the moisture content. In comparison, the optimized modeling conditions were determined as follows: detection wavelength 1349–1490 nm, SNV-FD (standard normal variate transformation and first derivative) preprocessing method, and PLS algorithm. Under these conditions, the square correlation coefficient (R2) and root mean square error of prediction (RMSEP) of the prediction model were 0.9865 and 0.0017, respectively. The results of this study provided a feasible method for the rapid detection of moisture content in walnut kernel. To improve the performance and applicability of the model, it is necessary to continuously expand the size of the sample set.
快速、准确地检测核桃仁的水分含量,对核桃仁的质量评价和油脂提取工艺具有重要意义。近红外光谱法是测量核桃仁水分含量的理想方法。本文采用化学计量学方法,建立了基于近红外漫反射光谱的核桃仁水分含量回归模型。采用不同的光谱预处理方法对原始光谱数据进行预处理。将整个光谱带划分为5个子带、10个子带、15个子带和20个子带,筛选与核桃仁含水量相关的特定波长。采用偏最小二乘回归(PLS)、多元线性回归(MLR)、主成分回归(PCR)、支持向量回归(SVR)等方法建立光谱数据与水分测量值之间的关系模型。通过比较,确定了优化的建模条件为:检测波长1349 ~ 1490 nm,采用标准正态变量变换和一阶导数(SNV-FD)预处理方法,采用PLS算法。在此条件下,预测模型的平方相关系数(R2)为0.9865,预测均方根误差(RMSEP)为0.0017。本研究结果为快速测定核桃仁水分含量提供了一种可行的方法。为了提高模型的性能和适用性,需要不断扩大样本集的规模。
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引用次数: 8
Depth Semantic Segmentation of Tobacco Planting Areas from Unmanned Aerial Vehicle Remote Sensing Images in Plateau Mountains 高原山区无人机遥感影像烟草种植区深度语义分割
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-03-01 DOI: 10.1155/2021/6687799
Liang Huang, Xuequn Wu, Qiuzhi Peng, Xueqin Yu
The tobacco in plateau mountains has the characteristics of fragmented planting, uneven growth, and mixed/interplanting of crops. It is difficult to extract effective features using an object-oriented image analysis method to accurately extract tobacco planting areas. To this end, the advantage of deep learning features self-learning is relied on in this paper. An accurate extraction method of tobacco planting areas based on a deep semantic segmentation model from the unmanned aerial vehicle (UAV) remote sensing images in plateau mountains is proposed in this paper. Firstly, the tobacco semantic segmentation dataset is established using Labelme. Four deep semantic segmentation models of DeeplabV3+, PSPNet, SegNet, and U-Net are used to train the sample data in the dataset. Among them, in order to reduce the model training time, the MobileNet series of lightweight networks are used to replace the original backbone networks of the four network models. Finally, the predictive images are semantically segmented by trained networks, and the mean Intersection over Union (mIoU) is used to evaluate the accuracy. The experimental results show that, using DeeplabV3+, PSPNet, SegNet, and U-Net to perform semantic segmentation on 71 scene prediction images, the mIoU obtained is 0.9436, 0.9118, 0.9392, and 0.9473, respectively, and the accuracy of semantic segmentation is high. The feasibility of the deep semantic segmentation method for extracting tobacco planting surface from UAV remote sensing images has been verified, and the research method can provide a reference for subsequent automatic extraction of tobacco planting areas.
高原山地烟叶具有散植、生长不均匀、混播/套种的特点。采用面向对象的图像分析方法准确提取烟草种植面积,难以提取有效特征。为此,本文依靠深度学习特征自学习的优势。提出了一种基于深度语义分割模型的高原山区无人机遥感影像烟草种植面积精确提取方法。首先,利用Labelme建立烟草语义分割数据集;采用DeeplabV3+、PSPNet、SegNet和U-Net四种深度语义分割模型对数据集中的样本数据进行训练。其中,为了减少模型训练时间,采用MobileNet系列轻量级网络替代原有四种网络模型的骨干网。最后,通过训练好的网络对预测图像进行语义分割,并使用平均交联(Intersection over Union, mIoU)来评估准确率。实验结果表明,使用DeeplabV3+、PSPNet、SegNet和U-Net对71幅场景预测图像进行语义分割,得到的mIoU分别为0.9436、0.9118、0.9392和0.9473,语义分割的准确率较高。验证了深度语义分割方法在无人机遥感影像中提取烟草种植地表的可行性,研究方法可为后续自动提取烟草种植面积提供参考。
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引用次数: 10
He-Plasma Jet Generation and Its Application for E. coli Sterilization he等离子体射流的产生及其在大肠杆菌灭菌中的应用
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-02-27 DOI: 10.1155/2021/6671531
Tiejian Liu, Yuxuan Zeng, Xin Xue, Yinyi Sui, Yingying Liang, Fushan Wang, Fada Feng
Atmospheric pressure plasma jet (APPJ) is a promising technique for the sterilization of pathogenic microorganisms in an ambient environment. In this work, a helium-APPJ was generated by double dielectric barrier discharge and applied to the sterilization of model microorganism in air and water. Discharge characteristics (including waveform and frequency of applied voltage), jet properties (such as feed gas flow rate, jet length, thermal effect, and optic emission spectra), and sterilization performance (in terms of clear/sterilized area, size of plaques, and sterilization efficiency) were investigated. Homogeneous helium plasma jet was generated in an energy-efficient way (18 kHz, 6 kV, 0.08 W) with a 19 mm jet and limited heating. The He-APPJ achieved good sterilization performances within very short treatment time (as short as 30 s). For surface sterilization, the area of clear zone and size of the plaque were 1809 mm2 and 48 mm, respectively, within 5 min treatment. For water sterilization, 99.8% sterilization efficiency was achieved within 5 min treatment. The optic emission spectra suggest that active species such as excited molecules, ions, and radicals were produced in the He-APPJ. The as-produced active species played important roles in the sterilization process.
常压等离子体射流(APPJ)是一种很有前途的环境微生物杀菌技术。本文采用双介质阻挡放电产生氦- appj,并将其应用于空气和水中模式微生物的灭菌。研究了放电特性(包括施加电压的波形和频率)、射流特性(如原料气流速、射流长度、热效应和光学发射光谱)和灭菌性能(在清除/灭菌面积、斑块大小和灭菌效率方面)。均匀的氦等离子体射流以一种节能的方式(18 kHz, 6 kV, 0.08 W)产生,射流为19 mm,加热有限。He-APPJ在极短的处理时间内(短至30 s)取得了良好的灭菌效果。表面灭菌处理5 min内,清除区面积为1809 mm2,菌斑大小为48 mm。对水的灭菌,处理5 min内灭菌率达到99.8%。光学发射光谱表明He-APPJ中产生了激发态分子、离子和自由基等活性物质。产生的活性菌种在杀菌过程中起着重要作用。
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引用次数: 3
Experimental Study on the Microstructure and Expansion Characteristics of Paleosol Based on Spectral Scanning 基于光谱扫描的古土壤微观结构与膨胀特性实验研究
IF 2 4区 化学 Q4 BIOCHEMICAL RESEARCH METHODS Pub Date : 2021-01-15 DOI: 10.1155/2021/6689073
W. Ye, Yiqian Chen, Chong Gao, T. Xie, Hongjun Jing, Yousheng Deng
To investigate the microstructure of paleosol and its expansion characteristics, the paleosol of the Zaosheng #3 tunnel of the Yinxi high-speed railway was studied. Based on X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), nuclear magnetic resonance (NMR), and scanning electron microscopy techniques (SEM), the microstructure of the paleosol was analyzed in terms of the mineral composition, formation elements, pore structure, and particle morphology. Five groups of undisturbed and remolded soils with different moisture contents were tested for the unloaded expansion rate and loaded expansion rate. The results show that the mineral components of the paleosol are mainly quartz, potash feldspar, calcite, and hematite, with the highest-content-component quartz accounting for 45.4% of the total content; the clay mineral composition of the paleosol has the highest content of montmorillonite at 12.3%. The elemental composition of the paleosol is dominated by Al, Si, Ca, and Fe, which form expansive mineral components such as quartz and montmorillonite, creating inherent conditions for expansibility of the paleosol. The T2 distribution curves of the undisturbed and remolded paleosol are composed of three peaks. The pore distribution of paleosol mainly includes medium pores, followed by large pores, and the contents of small pores and superlarge pores are very small. In terms of particle contact, the undisturbed soil is mostly in the form of “surface-surface” and “surface-edge” contact, and the remolded soil is mainly in the form of “point-surface” and “point-point” contact. The unloaded expansion rate of remolded soil is approximately twice that of undisturbed soil. The rate of loaded expansion of both soils decreases with increasing moisture content.
为探讨古土壤的微观结构及其膨胀特征,对银西高速铁路枣胜3号隧道古土壤进行了研究。利用x射线衍射(XRD)、能量色散x射线能谱(EDX)、核磁共振(NMR)和扫描电镜(SEM)技术,从矿物组成、地层元素、孔隙结构和颗粒形态等方面分析了古土壤的微观结构。试验了5组不同含水率的原状和重塑土的卸载膨胀率和加载膨胀率。结果表明:古土壤矿物成分主要为石英、钾长石、方解石和赤铁矿,其中石英含量最高,占总含量的45.4%;古土壤粘土矿物组成中蒙脱石含量最高,为12.3%。古土壤元素组成以Al、Si、Ca、Fe为主,形成石英、蒙脱石等膨胀性矿物成分,为古土壤的膨胀性创造了内在条件。原状古土壤和重塑古土壤的T2分布曲线由3个峰组成。古土壤孔隙分布以中孔为主,大孔次之,小孔和超大孔含量极少。在颗粒接触方面,原状土主要以“面-面”和“面-边”接触形式存在,重塑土主要以“点-面”和“点-点”接触形式存在。重塑土的卸载膨胀率约为原状土的两倍。两种土的加载膨胀率随含水率的增加而减小。
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引用次数: 3
期刊
Journal of Spectroscopy
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