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Spectrophotometric Study of Coloured Glasses (1) 有色玻璃的分光光度法研究(1)
Pub Date : 1958-01-01 DOI: 10.2109/JCERSJ1950.66.750_144
M. Ihara, Tokuji Yamamoto
A systematic study of the colour of glasses containing iron, and both iron and manganese was carried out using the spectrophotometric method.The base glass was a soda-lime-silica type, and the colouring agents added to the batch were rouge, copper slag, manganese dioxide, and manganese ore, all being the technical grade. Twenty four smaples containing different amount of colouring agents were subjected to the investigation. The transmission between 350 and 1100mμ were measured by a photo-electric spectrometer to represent the result by C. I. E. colour specification using mainly the chromaticy coordinates and the lightness which is familiar to glass technologists as luminous transmission.With increasing content of total iron oxide the colour of glasses added with rouge was observed to change from blue to green.If the partial pressure of oxygen is kept constant in the melting processes the relation[FeO]2/[Fe2O3]=k/[O2]1/2=α(constant)would hold, so that the ratio FeO/Fe2O3 is reduced with increasing amount of iron oxide. This means that the yellowish green tint of Fe2O3 would become stronger than the blue tint of FeO.FeO makes the glasses darker nine times as much as Fe2O3, so that a glass containing FeO which is equal to 1/9 of Fe2O3 gives the same luminous transmission.It was confirmed that the luminous transmission is linearly related withe FeO content of glass estimated by direct chemical analysis. This gives the possibility of estimating directly the value of FeO and Fe2O3 with fairly high accuracy by measuring the transmittance at a characteristic wave length. It was proved that this method may be applied to the iron contents of 0.5-2.5wt% Fe2O3.The colour of the glasses added with both iron and manganese changes mainly with the change of the ratio of mangenese to iron. The transmittance curves were classified into three groups, and the authors have advanced the three chemical equations which explain satisf actly the existence of the three types of the transmittance curves.MnO2+3Fe2O3_??_2Fe2O3+2FeO+MnO+O2 (for high iron ratio)2MnO2+2Fe2O3_??_2Fe2O3+2MnO+O2 (for medium iron ratio)3MnO2+Fe2O3_??_Fe2O3+Mn2O3+MnO+O2 (for low iron ratio)
用分光光度法对含铁、含铁、含锰玻璃的颜色进行了系统的研究。基料玻璃为钠-石灰-二氧化硅型,料中添加的着色剂为胭脂、铜渣、二氧化锰、锰矿石,均为技术级。二十四份含有不同数量着色剂的样本接受了调查。在350 ~ 1100μ之间的透射率用光电光谱仪测量,主要用色度坐标和玻璃技术人员所熟悉的亮度来表示c.i.e.颜色规格的结果。随着总氧化铁含量的增加,添加胭脂的玻璃的颜色由蓝色变为绿色。当熔炼过程中氧气分压保持一定时,[FeO]2/[Fe2O3]=k/[O2]1/2=α(常数),随着氧化铁用量的增加,FeO/Fe2O3的比值减小。这意味着Fe2O3的黄绿色调会比FeO的蓝色调更强。FeO使玻璃的颜色是Fe2O3的9倍,因此含有FeO的玻璃的透光率等于Fe2O3的1/9。通过直接化学分析,证实了玻璃的透光率与FeO含量呈线性相关。这就提供了通过测量特征波长的透射率直接估计FeO和Fe2O3的值的可能性,并且具有相当高的精度。结果表明,该方法适用于含铁量为0.5 ~ 2.5wt% Fe2O3的试样。同时加入铁和锰的玻璃的颜色主要随锰铁比的变化而变化。将透射曲线分为三类,并提出了三个化学方程,满意地解释了这三类透射曲线的存在性。_2Fe2O3+2FeO+MnO+O2(高铁比)2MnO2+2Fe2O3_??_2Fe2O3+2MnO+O2(中铁比)3MnO2+Fe2O3_??_Fe2O3+Mn2O3+MnO+O2(低铁比)
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引用次数: 0
On the Sintering of Porcelain Body and the Variation Hardness within it 瓷体的烧结及其内部硬度的变化
Pub Date : 1957-01-01 DOI: 10.2109/JCERSJ1950.65.743_281
C. Kawashima, Y. Murata
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引用次数: 0
An Improved Apparatus for Measuring Thermal Conductivity of Hard, High-Conductivity Ceramics 一种用于测量硬、高导电性陶瓷热导率的改进装置
Pub Date : 1956-07-01 DOI: 10.2109/JCERSJ1950.64.726_161
Hiroshige Suzuki, Norihiko Kuwayama, Toshiyoshi Yamauchi
An apparatus for determining thermal conductivity by an absolute (calorimetric) method of steady-state hea tflow through small cylindrical (20 or 30mmφ) or prismatic (22mm square) samples is described (Fig. 1). Some estimate of the accuracy and precision obtained is evidenced by comparing the values with that calculated from a comparative method experiment which the apparatus can also afford to perform with the aid of long silver rod beneath the sample. The results of the study are as follows;(1) It has been shown that if proper precautions are taken, linear heat flow and low heat loss can be so easily attained by the absolute method using a water flow calorimeter as to obtain reliable values on the high-conductivity materials.(2) An experimental results (Fig. 2) has shown that, unless the specimen is not soldered, interfacial temperature drop will grow so high that it can not be neglected in determining the thermal conductivity of these high-conductivity materials.(3) Measurements on electrolytic lead (>99.997%) have given data in good agreement with previous values reported for melting-point lead in literatures. Reproducibility obtained by using lead samples of various size and shape has also proved to be satisfactory (Table 1 and Fig. 4).(4) Two series of experiments were conducted in which the temperature of guard ring was made too high or too low relative to that of the sample, and the effect of these temperature gap on conductivity values obtained were examined. Examples obtained on lead are shown (Fig. 4).(5) It is very difficult to prepare accurate cylindrical samples of hard ceramic materials and to drill thermocouple holes. The difficulties were removed by preparing prismatic samples with narrow but deep groove on a vertical side face (Photo. 2 & 3). The holes for thermocouples were drilled into insulating material filled in the groove. The new method of sample preparation has been proved correct through the experiments made with lead (as well as with SiC brick) (Fig. 4, P).(5) The thermal conductivity of Carbofrax brick decreases from 0.052 at 100°C to 0.033 (cal. sec-1. cm-2. °C-1. cm.) at 750°C. The result is in good agreement with that of F. Holler for clay-bonded SiC bricks, but it is somewhat higher and has negative gradient to the contrary of the data given in the manufacturer's catalogue. The same is true on a domestic SiC brick (Fig. 5).
描述了一种通过小圆柱形(20或30mmφ)或棱镜形(22mm平方)样品的稳态热流的绝对(量热)方法来测定导热系数的装置(图1)。通过将值与比较方法实验的计算值进行比较,可以证明所获得的准确性和精密度的一些估计,该装置也可以在样品下方的长银棒的帮助下执行。研究结果如下:(1)研究表明,如果采取适当的预防措施,使用水流量热计的绝对法可以很容易地获得线性热流和低热损失,从而可以在高导电性材料上获得可靠的数值。(2)实验结果(图2)表明,除非试样没有焊接,(3)对电解铅(>99.997%)的测量结果与先前文献中报道的熔点铅的值吻合良好。使用不同尺寸和形状的铅样品所获得的再现性也被证明是令人满意的(表1和图4)。(4)进行了两个系列的实验,使保护环的温度相对于样品的温度过高或过低,并检查了这些温度间隙对所获得的电导率值的影响。在铅上获得的例子如图4所示。(5)制备硬陶瓷材料的精确圆柱形样品和钻热电偶孔是非常困难的。通过在垂直侧面制备具有窄而深凹槽的棱柱状样品(图2和3),消除了困难。热电偶的孔被钻入填充在凹槽中的绝缘材料中。用铅(以及SiC砖)进行的实验证明了这种制备样品的新方法是正确的(图4,P)。(5)Carbofrax砖的导热系数从100℃时的0.052降低到0.033 (cal. sec . 1)。cm-2。颈- 1°。厘米),750°C。该结果与F. Holler的黏结SiC砖的结果一致,但与制造商目录中给出的数据相反,它略高且具有负梯度。国产碳化硅砖也是如此(图5)。
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引用次数: 2
On Diffusion Layers formed around the Quartz Grains dissolving into Feldspathic Fusion 石英颗粒溶入长石熔合形成的扩散层
Pub Date : 1956-01-01 DOI: 10.2109/JCERSJ1950.64.729_217
K. Hamano
In his previous papers, the writer has shown the presence of diffusion layers around the quartz grains which were under the course of dissolution into the feldspathic fusion. In order to make clear the actual mater of the layers, microscopical measurements were made as reported in this paper. On the glass formed around the remaining quartz grain, as shown in Fig. 1, the refractive index, n, and distance from the quartz surface, t, were measured microscopically, as many as possible, and then these data were plotted.From the diagrams (Figs. 2 and 3) thus obtained, the following results are concluded.(1) Gradients of refractive index are found around the quartz grains. In the quartz-feldspar system, refractive indices of glasses formed are functions mostly of the amounts of quartz dissolved, i.e., the concentration of SiO2, so that the presence of refractive index gradient correspond to the presence of concentration gradient of SiO2, suggesting the formation of the diffusion layers around the quartz grains.(2) In the fusion of potash feldspar, the diffusion layers are continuous and of linear gradient, while in the fusion of soda feldspar, there appeared temporarily two layers s howing a discontinuity; but in the course of prolonged soaking time this discontinuity is gradually diminished, and they become one layer.(3) The higher the holding temperature is, the thiner the diffusion layer becomes.(4) In the stationary state, the thickness of diffusion layers formed in the potash feldspar fusion is of the same order with the one formed in the soda feldspar fusion, only the former being somewhate thicker.(5) The temporary formation of the double diffusion layers in the fusion of soda feldspar, as described in (2), may due to the singular fusion of the soda feldspar (plagioclase) used, by which the formation of melt is fast in earlier stage and then much slower down at a certain temperature range.(6) Furthermore, it is inferred that the dissolution velocity of quartz grains into the feldspathic fusion is determined by the diffusion velocity of SiO2 in the diffusion layers.
作者在以前的论文中已经证明,石英颗粒在溶蚀成长石熔融过程中,其周围存在扩散层。为了弄清这些层的实际物质,本文进行了显微测量。在剩余石英颗粒周围形成的玻璃上,如图1所示,显微镜下尽可能多地测量折射率n和到石英表面的距离t,然后绘制这些数据。从得到的图2和图3可以得出如下结论:(1)石英颗粒周围存在折射率梯度。在石英-长石体系中,形成的玻璃的折射率主要是石英溶解量即SiO2浓度的函数,因此折射率梯度的存在与SiO2浓度梯度的存在相对应,表明石英颗粒周围形成了扩散层。(2)钾长石熔融时,扩散层是连续的,呈线性梯度,而钠长石熔融时,扩散层呈线性梯度。暂时出现了两层,表现出不连续性;(3)保温温度越高,扩散层越薄。(4)在稳定状态下,钾长石熔合过程中形成的扩散层厚度与钠长石熔合过程中形成的扩散层厚度相同,只是前者略厚。(5)钠长石熔合过程中暂时形成双扩散层。如(2)所述,可能是由于使用的钠长石(斜长石)的奇异熔合,熔体的形成在早期较快,然后在一定温度范围内缓慢得多。(6)进一步推断石英颗粒在长石熔合中的溶解速度是由扩散层中SiO2的扩散速度决定的。
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引用次数: 0
X-ray Studies on Thermal Transformations in Sericite 绢云母热转变的x射线研究
Pub Date : 1955-01-01 DOI: 10.2109/JCERSJ1950.63.714_517
S. Udagawa
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引用次数: 1
磁器の諸牲質に及ぼす種々の形態の珪酸の影響 (第1報) 原料の特性と生素地の物理的性質 各种形式的硅酸对瓷器诸牲质的影响(第1报)原料特性和原料的物理性质
Pub Date : 1954-01-01 DOI: 10.2109/JCERSJ1950.62.24
Yoichi Shiraki
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引用次数: 0
Properties of Wanibuchi Chlorite Wanibuchi亚氯酸盐的性质
Pub Date : 1953-01-01 DOI: 10.2109/JCERSJ1950.61.688_485
Y. Shiraki
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引用次数: 0
Studies on the Mikawa Quartzite for Silica Refractories, (III) 三川石英岩中硅质耐火材料的研究(三)
Pub Date : 1953-01-01 DOI: 10.2109/JCERSJ1950.61.683_207
Schichiro Nagai, Z. Ota, Fumikazu Tanemura, Y. Arai
In continuing the previous reports (This Journal, 60 [677], 476 (1952); 61 [683] 207 (1953)), in the present paper were reported the results of studies on comparative tests of silica refractories by mixing the Mikawa quartzite with (1) other quartzites: Fujimaki Akashiro quartzite and Akaba quartzite used in the former reports, and (2) some mineralizers used in the previous trials: dolomite, hematite, basic slag and sea-water magnesia. The Mikawa quartzite and other quartzite raw materials above mentioned, were used to make test silica bricks as following: (1) the Mikawa quartzite mainly in the fine grain part, and (2) the Fujimaki Akashiro quartzite and Akaba quartzite in coarse grain part, the latter quartzites being easily heat inversible. To these mixtures were added some parts of mineralizers above mentioned and the cherty part of the Akaba quartzite above used.Many test samples of silica refractories were prepared by these two series of mixtures, and many comparative tests were carried out on variuos physical and thermal properties by discussing on the following points.(1) From the special formation of the Mikawa quartzite and the test results obtained heretofore in the comparative studies on the refractories by graining only the Mikawa quartzite, it cannot be obtained suitable silica brick for steel industry.(2) By using fine grains of the Mikawa quartzite to make matrix part, it can be succeeded to improve the refractoriness, resistance to slag corrosion, softening temperature under load, etc.(3) In this case, it is desirable to use the coarse grain parts of the so-called Akashiro or Aoshiro quartzite, and the Mikawa quartzite cannot be used for mixing over a certain limiting amount.
在继续以前的报告(本杂志,60 [677],476 (1952);(61[683] 207(1953))),本文报道了三川石英岩与(1)其他石英岩的对比试验研究结果:以前报告中使用的Fujimaki赤代石英岩和赤叶石英岩;(2)以前试验中使用的一些矿化剂:白云石、赤铁矿、碱性矿渣和海水镁砂。利用三川石英岩和上述石英岩原料制作试验硅砖:(1)三川石英岩主要为细粒石英岩,(2)藤木赤城石英岩和赤叶石英岩为粗粒石英岩,粗粒石英岩易热不可逆。在这些混合物中加入了上述矿化剂的一部分,并使用了上述阿卡巴石英岩的硅质部分。采用这两种混合方法制备了大量的硅质耐火材料试验样品,并对其各项物理和热性能进行了对比试验,讨论了以下几点:(1)从三川石英岩的特殊构造和迄今为止仅对三川石英岩进行粒化耐火材料对比研究的试验结果来看,(2)利用三川石英岩的细粒制作基体部分,可以成功地提高耐火度、抗渣腐蚀、载荷下软化温度等。(3)在这种情况下,最好使用所谓赤川石英岩或青石岩的粗粒部分,三川石英岩不能超过一定的限制量用于混合。
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引用次数: 0
Observation on Crack Forming in Cast Body 铸体裂纹形成的观察
Pub Date : 1952-01-01 DOI: 10.2109/JCERSJ1950.60.670_142
Y. Shiraki
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引用次数: 0
A Study on the Particle-distribution in a Concentra-type-mill 集中式磨机颗粒分布的研究
Pub Date : 1952-01-01 DOI: 10.2109/JCERSJ1950.60.669_99
Tatsuo Tanaka
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引用次数: 0
期刊
Journal of the Ceramic Association, Japan
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