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ON THE ESTIMATION OF ARSENIC ACID IN ARSENATES. 砷酸盐中砷酸的测定。
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1896.TB00104.X
A. Williamson
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引用次数: 0
The Progress of Research in the Jonamine Dyestuffs Jonamine染料的研究进展
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1924.TB01264.X
A. Green
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引用次数: 3
The Theory and Practice of Sodium Chlorite Bleaching 亚氯酸钠漂白的理论与实践
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1960.TB02389.X
J. Skelly
The decomposition of sodium chlorite during the bleaching of flax has been studied at different pH values and various temperatures. Bleaching with sodium chlorite should be accompanied by maximum formation of sodium chloride and minimum formation of sodium chlorate and chlorine dioxide. The oxidising power of the bleaching agent is discussed. Whilst there is a good margin of safety with sodium chlorite under normal bleaching conditions, extreme conditions must be avoided, in order to prevent chemical damage. The effect of sodium chlorite on the impurities present in cotton and flax is discussed. The use of hot, weakly acid oxidising solutions permits shortened bleaching processes. The main problems in practical sodium chlorite bleaching are (1) choice of a suitable method of activation of the bleaching agent, (2) selection of corrosion-resistant materials for construction of bleaching plant, and (3) design of the equipment to be used.
研究了亚氯酸钠在不同pH值和不同温度下对亚麻漂白过程的分解作用。用亚氯酸钠进行漂白时,氯化钠的生成量最大,氯酸钠和二氧化氯的生成量最小。讨论了漂白剂的氧化能力。虽然在正常漂白条件下,亚氯酸钠有很好的安全边际,但必须避免极端条件,以防止化学损害。讨论了亚氯酸钠对棉麻杂质的影响。使用热的弱酸性氧化溶液可以缩短漂白过程。在实际亚氯酸钠漂白中存在的主要问题是:(1)选择合适的漂白剂活化方法,(2)选择耐腐蚀材料建造漂白厂,(3)所使用设备的设计。
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引用次数: 7
The Reduction of Vat Dyes in Printing Pastes 印花浆料中还原染料的减少
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1953.TB02801.X
W. Marshall, R. H. Peters
The relation between the reduction properties of vat dyes measured under conditions akin to practice and their printing properties has been examined. Leuco potentials have been determined from electrometric titrations in aqueous solutions, and they have been found to govern the sensitivity of the dyes to the Formosul concentration. Complementary to these measurements are those in which the reducing strengths of the pastes have been determined from the potentials developed at a platinum electrode. These results have been related to the leuco potentials of the dyes, and it has been shown that the maximum potentials reached are adequate to reduce all the dyes. Their duration, however, is short for the low concentrations of Formosul and long for the high concentrations. This is due to decomposition of the reducing agent in the presence of gum, and some decomposition rates are given. The rates of reduction have been measured in print pastes using a model steamer. The times required for complete reduction cover a wide range, but for most dyes they are a substantial proportion of the time allowed for steaming, and must be considered when the printing efficiency of a dye is assessed. Finally, provided the dye is completely reduced, the maximum fixation is determined by its affinity; rates of diffusion in the fibre, solubility of the leuco dye in the paste, and acid leuco formation do not appear to be important.
考察了在类似实际条件下测定的还原染料的还原性能与其印刷性能之间的关系。用电滴定法测定了水溶液中的亮色电位,并发现它们决定了染料对福尔摩苏尔浓度的敏感性。与这些测量相辅相成的是,通过铂电极上的电位测定膏体的还原强度。这些结果与染料的白电势有关,并且已经表明所达到的最大电势足以还原所有染料。然而,它们的持续时间在低浓度的Formosul中很短,在高浓度的Formosul中很长。这是由于还原剂在有树胶的情况下分解,并给出了一些分解速率。用模型蒸笼测量了印刷浆料的还原率。完全还原所需的时间范围很广,但对大多数染料来说,它们占了蒸煮时间的很大一部分,在评估染料的印刷效率时必须考虑到这一点。最后,如果染料完全还原,则最大固着率由其亲和力决定;在纤维中的扩散速率、色浆中白色染料的溶解度和酸性白色的形成似乎并不重要。
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引用次数: 7
Reduction of Direct Dyes during the Dyeing of Viscose Rayon 粘胶人造丝染色过程中直接染料的减少
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1951.TB02728.X
W. Armfield
The cause of reduction of certain direct dyes during the dyeing of viscose rayon at temperatures near the boil is the presence of alkali, and some direot dyes contain sufficient alkali to cause reduction of other direct dyes although they themselves may not be affected. With increase in temperature reduction increases, and at the boil considerably more reduction takes place than at 90dc. Dyeing in enclosed machines favours reduction owing to the restricted air space, but the effect of this can be overoome by blowing air. over the surface, or through the dye liquor. Lowering the pH of the dye liquor decreases the tendency of dyes to reduce during dyeing. Addition of such a substance as ammonium sulphate or chloride prevents reduction altogether even when dyeing at temperatures near the boil, in all but exceptional cases. The pH values of a number of aqueous dye solutions are listed, and a simple method is described whereby the susceptibility of direct dyes to reduction can be determined. A number of dyes have been tested, and are classified into four groups, according to whether they show considerable, moderate, slight, or no reduction.
某些直接染料在接近沸点的温度下染色时还原的原因是碱的存在,有些直接染料含有足够的碱,导致其他直接染料还原,尽管它们本身可能不受影响。随着温度的升高,还原量增加,在沸腾时比在90dc时发生更多的还原。由于空气空间有限,在封闭机器中染色有利于减少,但这种影响可以通过吹气来克服。在表面上,或通过染料液。降低染液的pH值可以降低染料在染色过程中的还原倾向。添加硫酸铵或氯化物等物质,即使在接近沸点的温度下染色,除例外情况外,也能完全防止还原。列出了许多水染料溶液的pH值,并描述了一种简单的方法,由此可以确定直接染料对还原的敏感性。许多染料已经经过测试,并根据它们是否显示出相当大的、中等的、轻微的或没有减少,被分为四组。
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引用次数: 2
The Application of Mixed Surfactant Micelles in Wool Textile Finishing 混合表面活性剂胶束在毛织物整理中的应用
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1986.TB01074.X
J. Parra, J. G. Domínguez, A. Maza, J. S. Leal
Anti-shrinkage procedures based on the deposition of Hercosett on untreated wool fibres combined with either the use of an amphoteric surfactant or mixed micelles of amphoteric/anionic surfactants are described. Specific molar ratios of the surfactants were found to promote good stability of the bath, giving area felting shrinkage values of the treated fabrics less than 10%.
本文描述了在未经处理的羊毛纤维上沉积Hercosett的抗收缩过程,该过程结合使用两性表面活性剂或两性/阴离子表面活性剂的混合胶束。发现特定的表面活性剂的摩尔比促进了浴液的良好稳定性,使处理过的织物的面积毡收缩值小于10%。
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引用次数: 2
An Investigation of Wool Bleaching by Steaming at over 100°C with Hydrogen Peroxide or Sodium Bisulphite 用双氧水或亚硫酸氢钠在100℃以上蒸煮羊毛漂白的研究
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1975.TB03230.X
J. Cegarra, J. Gacén
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引用次数: 3
Light and Life 光与生命
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1927.TB01410.X
E. Baly
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引用次数: 0
Apparatus for Purifying Ferruginous Water. 含铁水净化装置。
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1895.TB00086.X
H. Münzing
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引用次数: 0
Dyeing of modified cotton fibres with disperse dyes from supercritical carbon dioxide 超临界二氧化碳分散染料对改性棉纤维的染色
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1998.TB01977.X
A. Özcan, A. A. Clifford, K. Bartle, P. Broadbent, D. Lewis
Cotton, previously modified by reaction with benzoyl chloride and sodium benzoylthioglycollate, was dyed with disperse dyes APAN and DY82 in supercritical carbon dioxide at 100 °C and 300 bar. This process is compared with the dyeing of polyester and unmodified cotton under the same conditions. The modification of the cotton fabric was confirmed using FTIR. The dyed fibre was also subjected to an ISO 2 wash fastness test. The colour yields were assessed by K/S measurements before and after washing. Microscopic cross-section analysis for both modified and dyed cotton and for polyester was also performed.
用分散染料APAN和DY82在超临界二氧化碳中,在100℃和300 bar的条件下,对先前用苯甲酰氯和苯甲酰巯基酸钠改性的棉花进行染色。并与相同条件下涤纶和未改性棉的染色工艺进行了比较。用红外光谱对棉织物进行了改性。染色纤维还进行了ISO 2洗涤牢度测试。通过洗涤前和洗涤后的K/S测量来评估显色率。对改性棉和染色棉以及涤纶进行了显微截面分析。
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引用次数: 28
期刊
Journal of The Society of Dyers and Colourists
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