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Influence of Exhaust Gas Recirculation, and Injection Timing on the Combustion, Performance and Emission Characteristics of a Cylinder Head Porous Medium Engine 废气再循环及喷射正时对气缸盖多孔介质发动机燃烧、性能及排放特性的影响
Pub Date : 2015-10-12 DOI: 10.1155/2015/927896
C. Kannan, T. Vijayakumar
Homogeneous combustion has the potential of achieving both near-zero emissions and low specific fuel consumption. However, the accomplishment of homogeneous combustion depends on the air flow structure inside the combustion chamber, fuel injection conditions, and turbulence as well as ignition conditions. Various methods and procedures are being adopted to establish the homogeneous combustion inside the engine cylinder. In this research work, a highly porous ceramic structure was introduced into the combustion chamber (underside of the cylinder head). The influence of operating parameters such as exhaust gas recirculation (EGR) and injection timing on the combustion, performance, and emission characteristics of such developed engine was investigated in this research work.
均匀燃烧具有实现接近零排放和低油耗的潜力。然而,均匀燃烧的实现取决于燃烧室内的气流结构、燃油喷射条件以及湍流和点火条件。人们正在采用各种方法和程序来建立发动机气缸内的均匀燃烧。在这项研究工作中,在燃烧室(气缸盖下方)引入了一个高多孔陶瓷结构。研究了废气再循环(EGR)和喷射正时等工作参数对该发动机燃烧、性能和排放特性的影响。
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引用次数: 1
Effect of Condenser Fouling on Performance of Vapor Compression Refrigeration System 冷凝器结垢对蒸汽压缩制冷系统性能的影响
Pub Date : 2015-10-05 DOI: 10.1155/2015/756452
Naveen Solanki, A. Arora, S. Kaushik
Effect of condenser fouling is evaluated on the performance of a vapour compression system with refrigerants HFO1234yf and HFO1234ze as an alternative to HFC134a. The condenser coolant temperature has been varied between 35 and 40°C to evaluate the effect of fouling at different condenser temperatures. A simulation model is developed in EES for computing the results. The results have been computed by varying condenser conductance. The same has been validated with literature available before calculating the results. It is observed that the condenser fouling has larger effect on compressor power (%) as it increases up to 9.12 for R1234yf and 7.41 for R1234ze, whereas for R134a its value increases up to 7.38. The cooling capacity (%) decreases up to 13.25 for R1234yf and 8.62 for R1234ze, whereas for R134a its value decreases up to 8.76. The maximum percentage of decrease in value of COP is up to 19.29 for R1234yf and 14.47 for R1234ze, whereas for R134a its value decreases up to 14.49. The second-law efficiency is also observed to decrease with decrease in the condenser conductance. The performance of HFO1234ze is found to be better under fouled conditions in comparison to R134a and R1234yf.
以HFO1234yf和HFO1234ze作为制冷剂替代HFC134a,评价了冷凝器结垢对蒸汽压缩系统性能的影响。冷凝器冷却液温度在35 ~ 40℃之间变化,以评价不同冷凝器温度下结垢的影响。在EES中建立了仿真模型来计算结果。结果是通过改变电容器电导计算出来的。在计算结果之前,已经用现有的文献进行了验证。观察到冷凝器结垢对压缩机功率(%)的影响较大,R1234yf和R1234ze分别增大到9.12和7.41,而R134a增大到7.38。R1234yf和R1234ze的冷却能力(%)分别下降了13.25和8.62,而R134a的冷却能力(%)下降了8.76。R1234yf和R1234ze的COP值最大降幅百分比分别为19.29和14.47,而R134a的COP值最大降幅百分比为14.49。第二定律效率也随电容器电导的减小而减小。与R134a和R1234yf相比,HFO1234ze在污染条件下的性能更好。
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引用次数: 3
Volumetric Behavior of Binary Mixtures of Alkoxyethanols and Some Selected Amines at 298.15 K 298.15 K时烷氧乙醇和某些选定胺二元混合物的体积行为
Pub Date : 2015-02-23 DOI: 10.1155/2015/782138
A. Kemeakegha, G. .. Cookey, W. L. Izonfuo
Densities of binary mixtures of 2-methoxyethanol (2-MeO-EtOH) and 2-ethoxyethanol (2-EtO-EtOH) with hexylamine (HLA), diethylamine (DEA), triethylamine (TEA), tert-butylamine (TBA), aniline (ANL), and benzylamine (BLA) have been determined at varying compositions of the alkoxyalkanols at 298.15 K. The excess molar volumes, VE, of the binary mixtures were calculated from the experimental density data of the mixtures and the component single solvents. The calculated excess molar volumes were fitted into the Redlich-Kister polynomial to obtain the fitting coefficients and standard deviations. The excess molar volumes of the binary mixtures of all the solvent systems investigated were negative over the entire range of the solvents composition. The negative values were attributed to stronger hydrogen bond formations between the unlike molecules of mixtures than those between the like molecules of the pure components. The magnitude of the excess molar volumes of the binary mixtures of 2-methoxyethanol and the aliphatic amines were in the order TBA > TEA > DEA > HEA. For the two aromatic amines, the magnitudes were in the order BLA > ANL. For binary mixtures of the amines and 2-ethoxyethanol, the magnitudes were in the order DEA > TEA > TBA > HEA at compositions where the mole fraction of 2-EtO-EtOH was ≤0.5 and TBA > TEA > DEA > HEA above 0.5 mole fraction of 2-EtO-EtOH.
2-甲氧基乙醇(2-MeO-EtOH)和2-乙氧基乙醇(2-EtO-EtOH)与己胺(HLA)、二乙胺(DEA)、三乙胺(TEA)、叔丁胺(TBA)、苯胺(ANL)和苄胺(BLA)二元混合物的密度在298.15 K下测定了不同组成的烷氧烷醇。根据二元混合物和组分单一溶剂的实验密度数据,计算二元混合物的过量摩尔体积VE。将计算得到的过量摩尔体积拟合到Redlich-Kister多项式中,得到拟合系数和标准差。所研究的所有溶剂体系的二元混合物的过量摩尔体积在溶剂组成的整个范围内都是负的。负值归因于混合物中不同分子之间的氢键形成比纯组分中相同分子之间的氢键形成更强。2-甲氧基乙醇与脂肪胺二元混合物的过量摩尔体积大小为TBA > TEA > DEA > HEA。两种芳香胺的数量级均为BLA > ANL。对于胺和2-乙氧基乙醇的二元混合物,在2-乙氧基乙醇的摩尔分数≤0.5时,其数量级为DEA > TEA > TBA > HEA,在2-乙氧基乙醇的摩尔分数大于0.5时,其数量级为TBA > TEA > DEA > HEA。
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引用次数: 10
Symmetry Properties of Reciprocity Relations and Conditions for Minimum Entropy Production Law (In)validity 互易关系的对称性及最小熵产生律有效的条件
Pub Date : 2015-02-23 DOI: 10.1155/2015/952343
M. Štrunc, M. Kheilová
Consequences of symmetry properties of the phenomenological kinetic coefficients in Onsager-Casimir reciprocity relations for the minimum entropy production law validity are studied. The usually accepted symmetry requirement of the all cross kinetic coefficients for the validity of this law is found to be too strict.
研究了Onsager-Casimir互易关系中现象动力学系数的对称性对最小熵产生律有效性的影响。通常所接受的所有交叉动力学系数的对称性要求对于该定律的有效性是过于严格的。
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引用次数: 1
Gibbs Thermodynamics of the Renninger-Wilemski Problem Renninger-Wilemski问题的Gibbs热力学
Pub Date : 2015-02-11 DOI: 10.1155/2015/639572
V. Kurasov
The Renninger-Wilemski problem in nucleation is analyzed. The Gibbs dividing surfaces method with external parameters is used to enrich the initial model. It is shown that both the traditional (Doyle) model and the Renninger-Wilemski model are not complete ones and, namely, the Gibbs dividing surface approach can solve this problem. It is shown that the application of the Gibbs approach also requires some model constructions. The simplified Gibbs model is proposed. It is shown that the simplified Gibbs model gives for the height of activation barrier the same numerical results as the Renninger-Wilemski model.
分析了成核中的Renninger-Wilemski问题。采用带外参数的Gibbs分曲面法丰富初始模型。结果表明,传统的(Doyle)模型和Renninger-Wilemski模型都不是完全模型,即Gibbs分曲面法可以解决这一问题。结果表明,吉布斯方法的应用还需要建立一些模型。提出了简化的吉布斯模型。结果表明,简化的Gibbs模型与Renninger-Wilemski模型对激活势垒高度的计算结果相同。
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引用次数: 3
Thermoacoustic, Volumetric, and Viscometric Investigations in Binary Liquid System of Cyclohexanone with Benzyl Benzoate at T = 308.15, 313.15, and 318.15 K 在T = 308.15、313.15和318.15 K条件下环己酮与苯甲酸苄酯二元液体体系的热声、体积和粘度研究
Pub Date : 2014-12-29 DOI: 10.1155/2014/487403
S. Nayeem, M. Kondaiah, K. Sreekanth, D. Rao
Ultrasonic velocities (), densities (), and viscosities () of binary liquid mixtures of cyclohexanone with benzyl benzoate, including pure liquids, over the entire composition range have been measured at 308.15 K, 313.15 K, and 318.15 K. Using the experimental results, parameters such as molar volume (), isentropic compressibility (), intermolecular free length (), acoustic impedance (), internal pressure (), enthalpy (), Gibbs free energy of activation of viscous flow (), and excess/deviation properties of these including partial molar volumes ( and ), excess partial molar volumes ( and ), partial molar volume of the components at infinite dilution (, ), and excess partial molar volume at infinite dilution (and ) have been computed. The observed negative values of , , , and and positive values of , , , , and for all the liquid mixtures studied clearly indicate the presence of strong dipole-dipole-type interactions, fitting of smaller molecules into bigger molecules. Further theoretical values of sound velocity and viscosity in the mixtures have been evaluated using various theories and have been compared with experimental values to verify the applicability of such theories to the systems studied.
在308.15 K、313.15 K和318.15 K下测量了环己酮与苯甲酸苄酯二元液体混合物(包括纯液体)在整个组成范围内的超声波速度()、密度()和粘度()。利用实验结果,得到了摩尔体积()、等熵压缩率()、分子间自由长度()、声阻抗()、内压()、焓()、黏性流动激活的吉布斯自由能()等参数,以及这些参数的偏摩尔体积(和)、偏摩尔体积(和)、组分在无限稀释时的偏摩尔体积(和)的超偏/偏偏特性,并计算了无限稀释时的过量偏摩尔体积。所研究的所有液体混合物中,观察到的、、、和的负值和,,,,的正值清楚地表明存在强的偶极子-偶极子型相互作用,使小分子与大分子相拟合。用各种理论进一步计算了混合物中声速和粘度的理论值,并与实验值进行了比较,以验证这些理论对所研究系统的适用性。
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引用次数: 25
Towards the Equation of State for Neutral (C2H4), Polar (H2O), and Ionic ([bmim][BF4], [bmim][PF6], [pmmim][Tf2N]) Liquids 中性(C2H4)、极性(H2O)和离子型([bmim][BF4]、[bmim][PF6]、[pmmim][Tf2N])液体的状态方程
Pub Date : 2014-12-16 DOI: 10.1155/2014/496835
V. Rogankov, V. Levchenko
Despite considerable effort of experimentalists no reliable vapor-liquid coexistence at very small pressures and liquid-solid coexistence at high pressures have been until now observed in the working range of temperature / for ionic liquids. The measurements of high-pressure properties in low-temperature stable liquid are relatively scarce while the strong influence of their consistency on the phase equilibrium prediction is obvious. In this work we discuss the applicability of fluctuational-thermodynamic methodology and respective equation of state to correlate the properties of any (neutral, polar, ionic) liquids since our ultimate goal is the simple reference predictive model to describe vapor-liquid, liquid-liquid, and liquid-solid equilibria of mixtures containing above components. It is shown that the inconsistencies among existing volumetric measurements and the strong dependence of the mechanical and, especially, caloric derived properties on the shape of the functions chosen to fit the experimental data can be resolved in the framework of fluctuational-thermodynamic equation of state. To illustrate its results the comparison with the known experimental data for [bmim][BF4] and [bmim][PF6] as well as with the lattice-fluid equation of state and the methodology of thermodynamic integration is represented. It corroborates the thermodynamic consistency of predictions and excellent correlation of derived properties over the wide range of pressures /.
在离子液体的工作温度范围内,尽管实验工作者付出了相当大的努力,但迄今为止还没有观察到非常小压力下气液共存和高压下液固共存的可靠现象。低温稳定液体中高压性质的测量相对较少,而它们的一致性对相平衡预测的强烈影响是显而易见的。在这项工作中,我们讨论了波动热力学方法和相应的状态方程的适用性,以关联任何(中性,极性,离子)液体的性质,因为我们的最终目标是简单的参考预测模型,以描述含有上述成分的混合物的汽-液,液-液和液-固平衡。结果表明,在波动-热力学状态方程的框架下,现有的体积测量结果之间的不一致性以及力学性质,特别是热衍生性质对所选择的拟合实验数据的函数的形状的强烈依赖可以得到解决。为了说明所得结果,并与已知的[bmim][BF4]和[bmim][PF6]的实验数据以及格流状态方程和热力学积分方法进行了比较。它证实了预测的热力学一致性和在广泛压力范围内推导性质的良好相关性。
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引用次数: 2
Entropy Growth Is the Manifestation of Spontaneity 熵增长是自发性的表现
Pub Date : 2014-12-07 DOI: 10.1155/2014/387698
Lin-shu Wang
Every student of thermodynamics grasps entropy growth in terms of dissipation of energy. The real nature of energy and entropy is subtle. This critical review of the evolution of thermodynamic thought uncovers the remarkable advance on our understanding of energy made by Kelvin with his dissipation of energy proposition. Maxwell and Planck, however, pointed out that dissipation of energy does not exhaust growth of entropy (i.e., the idea of spontaneity), and in fact, as it is shown here, Kelvin’s proposition of dissipation of energy (1852) is subsumed under the principle of the increase of entropy (Clausius, 1865). It is necessary, therefore, for thermodynamics to become a coherent conceptual system, to introduce spontaneity as an independent concept. Instead of the heat-work dyad framework, the introduction of spontaneity entails energy transformation to be viewed in terms of a triad framework of heat (from the reservoir)-work-spontaneity. Spontaneity is the new energy in the triad framework, and it is also clear that energy commodity (fungible energy or energy carriers) is only one kind of spontaneity, stock spontaneity; the other kind is ongoing spontaneity, the consideration of which is necessary for comprehending problems of homeostasis in both the organic and inorganic worlds.
每个学热力学的学生都是从能量耗散的角度来理解熵增长的。能量和熵的真正本质是微妙的。这种对热力学思想演变的批判性回顾揭示了开尔文的能量耗散命题在我们对能量的理解上取得的显著进步。然而,麦克斯韦和普朗克指出,能量的耗散并没有耗尽熵的增长(即自发性的思想),事实上,正如这里所示,开尔文的能量耗散命题(1852年)被纳入熵的增加原理(克劳修斯,1865年)。因此,热力学有必要成为一个连贯的概念系统,将自发性作为一个独立的概念引入。与热-功二元框架不同,引入自发性需要能量转换,以热(来自热源)-功-自发性的三元框架来看待。自发性是三位一体框架下的新能源,同时也明确能源商品(可替代能源或能源载体)只是自发性的一种,存量自发性;另一种是持续的自发性,对它的考虑对于理解有机和无机世界的内稳态问题是必要的。
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引用次数: 9
Separation of Methylene Blue Dye from Aqueous Solution Using Triton X-114 Surfactant Triton X-114表面活性剂对亚甲基蓝染料水溶液的分离
Pub Date : 2014-12-02 DOI: 10.1155/2014/670186
Arunagiri Appusamy, P. Purushothaman, K. Ponnusamy, A. Ramalingam
In this study, the interaction energy between Triton X-114 surfactant + methylene blue or water and methylene blue + water was investigated using Hartree-Fock (HF) theory with 6- basis set. The results of structures and interaction energies show that these complexes have good physical and chemical interactions at atom and molecular levels. However, the Triton X-114 surfactant + methylene blue complex shows stronger molecular interaction compared to other complexes systems. The order of the interaction energy is 4303.472023 (Triton X-114 surfactant + water) > 1222.962 (methylene blue + water) > 3573.28 (Triton X-114 surfactant + methylene blue) kJ·mole−1. Subsequently, the cloud point extraction was carried out for 15 ppm of methylene blue in a mixture at 313.15 and 323.15 K over the surfactant concentration range from 0.01 M to 0.1 M. From the measured data, the excess molar volume was calculated for both phases. The results show a positive deviation in the dilute phase and a negative deviation in the surfactant rich phase. It is confirmed that the interaction between Triton X-114 and methylene blue is stronger than other complex systems due to the presence of chemical and structural orientation. The concentration of dyes and surfactant in the feed mixture and temperature effect in both phases has been studied. In addition, the thermodynamics feasibility and efficiency of the process have also been investigated.
本研究采用Hartree-Fock (HF)理论研究了Triton X-114表面活性剂+亚甲基蓝或水与亚甲基蓝+水的相互作用能。结构和相互作用能的结果表明,这些配合物在原子和分子水平上具有良好的物理和化学相互作用。而Triton X-114表面活性剂+亚甲基蓝配合物则表现出较强的分子相互作用。相互作用能的顺序为:4303.472023 (Triton X-114表面活性剂+水)> 1222.962(亚甲基蓝+水)> 3573.28 (Triton X-114表面活性剂+亚甲基蓝)kJ·mol−1。随后,在表面活性剂浓度为0.01 M ~ 0.1 M的条件下,在313.15 K和323.15 K的混合物中,对15 ppm的亚甲基蓝进行云点萃取。根据实测数据,计算了两相的过量摩尔体积。结果表明,在稀相中存在正偏差,在富表面活性剂相中存在负偏差。证实了由于化学取向和结构取向的存在,Triton X-114与亚甲基蓝的相互作用比其他复杂体系强。研究了混合料中染料和表面活性剂的浓度以及两相的温度效应。此外,还考察了该工艺的热力学可行性和效率。
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引用次数: 7
Thermohydraulic Performance of a Series of In-Line Noncircular Ducts in a Parallel Plate Channel 平行板槽内串联非圆形管道的热水力性能
Pub Date : 2014-09-21 DOI: 10.1155/2014/670129
Siddharth D. Mhaske, Soby P. Sunny, S. L. Borse, Yash Parikh
Heat transfer and fluid flow characteristics for two-dimensional laminar flow at low Reynolds number for five in-line ducts of various nonconventional cross-sections in a parallel plate channel are studied in this paper. The governing equations were solved using finite-volume method. Commercial CFD software, ANSYS Fluent 14.5, was used to solve this problem. A total of three different nonconventional, noncircular cross-section ducts and their characteristics are compared with those of circular cross-section ducts. Shape-2 ducts offered minimum flow resistance and maximum heat transfer rate most of the time. Shape-3 ducts at Re   100 can be considered to give out the optimum results.
研究了平行平板通道内5个不同截面的直列管道低雷诺数二维层流的传热和流体流动特性。采用有限体积法求解控制方程。利用商用CFD软件ANSYS Fluent 14.5解决了这一问题。对三种不同的非常规、非圆形截面风管及其特性与圆形截面风管进行了比较。形状2管道提供最小的流动阻力和最大的传热率,大多数时间。在Re 100时,可以考虑采用形状为3的风管,以获得最佳效果。
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引用次数: 0
期刊
Journal of Thermodynamics
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