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Density and Optical Properties of {Ciprofloxacin Hydrochloride + Aqueous-Ethanol} Mixtures at 30°C {盐酸环丙沙星+水-乙醇}混合物在30℃下的密度和光学性质
Pub Date : 2016-01-18 DOI: 10.1155/2016/1575836
S. Deosarkar, S. Birajdar, R. Sawale, M. P. Pawar, A. Thakre
The paper deals with the calculation of molar refraction () and polarizability () of antibiotic drug ciprofloxacin hydrochloride ( = 0.001–0.029 mol·dm−3) solutions in ethanol-water mixtures of different compositions (30, 50, and 70% v/v) from measured density () and refractive index () at 30°C. The effect of drug concentration and composition of ethanol-water mixtures on density and optical properties of drug solutions has been described.
本文研究了抗生素药物盐酸环丙沙星(= 0.001-0.029 mol·dm−3)在不同成分(30、50和70% v/v)的乙醇-水混合物中的摩尔折光率()和极化率()在30°C下的测量密度()和折光率()。描述了药物浓度和乙醇-水混合物的组成对药物溶液的密度和光学性质的影响。
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引用次数: 4
Enhancement of Integrated Solar Collector with Spherical Capsules PCM Affected by Additive Aluminum Powder 添加铝粉对球形胶囊型PCM集成太阳能集热器性能的影响
Pub Date : 2016-01-17 DOI: 10.1155/2016/1604782
Fatah O. Al Ghuol, K. Sopian, S. Abdullah
This research aims to study, analyze, design, and construct a solar air heater combined with an appropriate phase-change material (PCM) unit. This solar air heater is analogous to a collector integrating a thermal storage unit and a solar thermal collector. In this study, such single-pass solar air heater in amalgamation with PCM was constructed, and several tests were conducted on this device. During the experiments for the solar collector with PCM (spherical capsules), the temperature varied between 30°C and 35°C, and the air mass flow rate ranged between 0.03 and 0.09 kg/s. Results confirmed the predicted experimental findings. With the use of paraffin wax-aluminum composite, the thermal storage efficiency of the constructed solar air heater reached a maximum value of 71% at 0.05 kg/s mass flow rate, its charging time decreased by almost 70%, and its cooling rate increased. The thermal storage efficiency of the compound composite was 76.8% at 0.07 kg/s mass flow rate. The results also indicated that the time of charging decreased by almost 60% with the use of paraffin wax-aluminum composite.
本研究旨在研究、分析、设计和建造一个结合适当相变材料(PCM)单元的太阳能空气加热器。这种太阳能空气加热器类似于集热存储单元和太阳能热收集器为一体的集热器。在本研究中,构建了这种与PCM混合的单道太阳能空气加热器,并对该装置进行了多次试验。在PCM(球形胶囊)太阳能集热器的实验中,温度在30℃~ 35℃之间变化,空气质量流量在0.03 ~ 0.09 kg/s之间变化。结果证实了预测的实验结果。采用石蜡-铝复合材料后,在0.05 kg/s质量流量下,所构建的太阳能空气加热器蓄热效率达到最大值71%,充装时间缩短近70%,冷却速率提高。当质量流量为0.07 kg/s时,复合材料的蓄热效率为76.8%。结果还表明,石蜡-铝复合材料的充电时间缩短了近60%。
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引用次数: 4
Elastodynamic Response of Thermal Laser Pulse in Micropolar Thermoelastic Mass Diffusion Medium 热激光脉冲在微极热弹性质量扩散介质中的弹动力学响应
Pub Date : 2016-01-04 DOI: 10.1155/2016/6163090
Rajneesh Kumar, Arvind Kumar
The present investigation deals with the deformation in micropolar thermoelastic diffusion medium due to inclined load subjected to thermal laser pulse. Normal mode analysis technique is used to solve the problem. The inclined load is assumed to be a linear combination of a normal load and a tangential load. The closed form expressions of normal stress, tangential stress, couple stress, temperature distribution, and mass concentration are obtained. A computer program has been developed to derive the physical quantities numerically. The variation of normal stress, tangential stress, coupled stress, temperature change, and mass concentration is depicted graphically to show the effect of relaxation times and mass concentration. Some particular cases of interest are deduced from the present investigation.
本文研究了热激光脉冲作用下微极热弹性扩散介质在倾斜载荷作用下的变形问题。采用正态分析技术解决了这一问题。斜荷载假定为法向荷载和切向荷载的线性组合。得到了法向应力、切向应力、偶向应力、温度分布和质量浓度的封闭表达式。已编制了一个计算机程序,用以数值推导物理量。法向应力、切向应力、耦合应力、温度变化和质量浓度的变化用图形表示,以显示松弛时间和质量浓度的影响。从目前的调查中推断出一些值得注意的特殊情况。
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引用次数: 8
The Role of Soya Oil Ester in Water-Based PCM for Low Temperature Cool Energy Storage 大豆油酯在低温冷储能水基PCM中的作用
Pub Date : 2016-01-01 DOI: 10.1155/2016/5384640
I. Rasta, I. Wardana, N. Hamidi, M. N. Sasongko
This study focuses on the preparation of the water-based phase change material (PCM) with very small soya oil solution for low temperature latent heat thermal energy storage (LHTES). Soya oil ester is soluble very well in water and acts as nucleating agent for a novel solid-liquid PCM candidate that is suitable for low temperature cool storage in the range between −9°C and −6°C. Thermal energy storage properties of the water with very small soya oil ester solution were measured by T-history method. The experimental results show that very small amount of soya oil ester in water can lower the freezing point and trigger ice nucleation for elimination of the supercooling degree. The phase transition temperatures of the water-based PCMs with soya oil as nucleate agent were lower than those of individual water. The thermal properties make it potential PCM for LHTES systems used in low temperature cool energy storage applications.
本文研究了用极少量大豆油溶液制备用于低温潜热蓄热的水基相变材料(PCM)。大豆油酯很好地溶于水,并作为一种新型固液PCM候选物的成核剂,适用于- 9°C至- 6°C的低温冷藏。用t -历史法测定了极少量大豆油酯溶液对水的蓄热性能。实验结果表明,在水中加入极少量的大豆油酯可以降低水的冰点,引发冰核,消除过冷度。以大豆油为成核剂的水基PCMs的相变温度低于单个水的相变温度。热性能使其成为低温冷储能应用中LHTES系统的潜在PCM。
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引用次数: 6
Thermal-Hydraulics Study of a 75 kWth Aqueous Homogeneous Reactor for 99Mo Production 75 kWth水相反应器生产99Mo的热水力学研究
Pub Date : 2015-12-28 DOI: 10.1155/2015/268034
D. M. Pérez, D. Lorenzo, L. P. R. Garcia, Manuel Cadavid Rodríguez, C. D. O. Lira, C. Hernández, Jesús Salomón Llanes
is a very useful radioisotope, which is used in nearly 80% of all nuclear medicine procedures. is produced from 99Mo decay. A potentially advantageous alternative to meeting current and future demand for 99Mo is the use of Aqueous Homogeneous Reactors (AHR). In this paper, a thermal-hydraulics study of the core of a 75 kWth AHR conceptual design based on the ARGUS reactor for 99Mo production is presented. As the ARGUS heat removal systems were designed for working at 20 kWth, the main objective of the thermal-hydraulics study was evaluating the heat removal systems in order to show that sufficient cooling capacity exists to prevent fuel solution overheating. The numerical simulations of an AHR model were carried out using the Computational Fluid Dynamic (CFD) code ANSYS CFX 14. Evaluation shows that the ARGUS heat removal systems working at 75 kWth are not able to provide sufficient cooling capacity to prevent fuel solution overheating. To solve this problem, the number of coiled cooling pipes inside the core was increased from one to five. The results of the CFD simulations with this modification in the design show that acceptable temperature distributions can be obtained.
是一种非常有用的放射性同位素,在近80%的核医学程序中使用。是由99Mo衰变产生的。为了满足当前和未来对99Mo的需求,一个潜在的有利选择是使用水均相反应器(AHR)。本文介绍了基于ARGUS反应器的75 kWth AHR概念设计堆芯的热工水力学研究。由于ARGUS排热系统的设计工作功率为20千瓦时,因此热工水力研究的主要目的是评估排热系统,以表明存在足够的冷却能力来防止燃料溶液过热。利用计算流体动力学(CFD)软件ANSYS CFX 14对AHR模型进行了数值模拟。评估表明,在75千瓦时工作的ARGUS散热系统无法提供足够的冷却能力来防止燃料溶液过热。为了解决这个问题,堆芯内的盘状冷却管的数量从1根增加到5根。CFD模拟结果表明,在设计中进行修改后,可以获得可接受的温度分布。
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引用次数: 4
Scaling Model of Low-Temperature Transport Properties for Molecular and Ionic Liquids 分子和离子液体低温输运性质的标度模型
Pub Date : 2015-12-06 DOI: 10.1155/2015/208486
V. Rogankov
The universal scaling concept is applied to the low-temperature range of any liquid states and substances located between the melting () and normal boiling () points far away from the critical region. The physical reason to develop such approach is the revealed collapse of all low-temperature isotherms onto the single universal one argued by the model of fluctuational thermodynamics (FT) proposed recently by author. The pressure reduced by the molecular parameters of the effective short-range Lennard-Jones (LJ) potential depends here only on the reduced density. To demonstrate the extraordinary predictive abilities of the developed low-temperature scaling model it has been applied to the prediction of equilibrium and transport (kinetic and dynamic viscosity, self-diffusion, and thermal conductivity) properties not only for molecular liquids but also for molten organic salts termed ionic liquids (ILs). The best argument in favor of the proposed methodology is the appropriate consistency with the scarce experiments prediction of transport coefficients for ILs on the base of universal scaling function constructed for the simplest LJ-like liquid argon. The only input data of any substance for prediction are the linear approximations of -dependent density and isobaric heat capacity taken from the standard measurements at atmospheric pressure.
通用结垢概念适用于位于熔点()和正常沸点()之间、远离临界区域的任何液态和物质的低温范围。发展这种方法的物理原因是作者最近提出的涨落热力学模型揭示了所有低温等温线向单一普遍等温线的坍缩。由有效短程Lennard-Jones (LJ)势的分子参数所减少的压力在这里只取决于减少的密度。为了证明所开发的低温缩尺模型的非凡预测能力,它已被应用于预测平衡和输运(动力学和动态粘度,自扩散和导热性)性质,不仅适用于分子液体,也适用于被称为离子液体(ILs)的熔融有机盐。该方法与基于最简单类lj液态氩的通用标度函数的il输运系数的稀缺实验预测相吻合,是支持该方法的最佳理由。用于预测的任何物质的唯一输入数据是在大气压下的标准测量得到的依赖密度和等压热容的线性近似值。
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引用次数: 2
Effect of Longitudinal-External-Fins on Fluid Flow Characteristics for Wing-Shaped Tubes Bundle in Crossflow 纵-外-翅片对横流翼形管束流体流动特性的影响
Pub Date : 2015-11-05 DOI: 10.1155/2015/542405
Sayed Ahmed, O. Mesalhy, Mohamed A. Abdelatief
A numerical study is conducted to clarify fluid-flow characteristics, pressure drop coefficient (), and the average skin friction coefficient () for wing-shaped-tubes bundle with longitudinal fins at downstream side of the tube using the commercial CFD FLUENT software package. The air-side ranges from 1800 to 9700. The tubes are employed with various fin heights () and fin thicknesses () such as 2 mm ≤ ≤ 12 mm and 1.5 mm ≤ ≤ 3.5 mm at the considered range. Results indicate that increases with for all . decreases with for all values for 1800 ≤ ≤ 4200 and then increases for 4200 ≤ ≤ 10000. Lowest values of , , and pumping power (PP) occurred at = 6 mm. Values of for = 6 mm are lower than those of NOF and = 2 mm by about 73 % and 32 %, respectively, at = 4000. decreases with . has negligible effect on . increases for 1.5 mm ≤ ≤ 2.5 mm while decreases with 2.5 mm < ≤ 3.5 mm for the considered range except for = 1850.
利用商用CFD FLUENT软件包,对管下游带纵翅的翼形管束的流体流动特性、压降系数()和平均摩阻系数()进行了数值研究。空气面在1800到9700之间。这些管采用不同的翅片高度()和翅片厚度(),例如在考虑的范围内2mm≤≤12mm和1.5 mm≤≤3.5 mm。结果表明,对所有人来说都是增加的。当1800≤≤4200时,所有值随减小,当4200≤≤10000时,随增大。和泵送功率(PP)在= 6 mm处出现最低值。在= 4000处,for = 6 mm的值比NOF和= 2 mm的值分别低约73%和32%。随着减小。对…的影响微乎其微。除= 1850外,当1.5 mm≤≤2.5 mm时增大,当2.5 mm <≤3.5 mm时减小。
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引用次数: 12
Thermodynamic Modeling of Surface Tension of Aqueous Electrolyte Solution by Competitive Adsorption Model 竞争吸附模型对电解质水溶液表面张力的热力学模拟
Pub Date : 2015-11-02 DOI: 10.1155/2015/319704
M. J. Kamali, Zakarya Kamali, G. Vatankhah
Thermodynamic modeling of surface tension of different electrolyte systems in presence of gas phase is studied. Using the solid-liquid equilibrium, Langmuir gas-solid adsorption and ENRTL activity coefficient model, the surface tension of electrolyte solutions are calculated. The new model has two adjustable parameters which could be determined by fitting the experimental surface tension of binary aqueous electrolyte solution in single temperature. Then the values of surface tension for other temperature in binary and ternary system of aqueous electrolyte solution are predicted. The average absolute deviations for calculation of surface tension of binary and mixed electrolyte systems by new model are 1.98 and 1.70%, respectively.
研究了气相存在时不同电解质体系表面张力的热力学模型。采用固液平衡、Langmuir气固吸附和ENRTL活度系数模型,计算了电解质溶液的表面张力。该模型具有两个可调参数,可通过拟合二元水溶液在单一温度下的实验表面张力来确定。然后预测了二元和三元水溶液中其他温度下的表面张力值。新模型计算二元和混合电解质体系表面张力的平均绝对偏差分别为1.98和1.70%。
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引用次数: 3
Thermoacoustic Instability in a Rijke Tube with a Distributed Heat Source 分布热源Rijke管的热声不稳定性
Pub Date : 2015-10-27 DOI: 10.1155/2015/949384
Xiaochuan Yang, A. Turan, S. Lei
A Rijke tube with a distributed heat source is investigated. Driven by the widely existing thermoacoustic instability in lean premixed gas turbine combustors, this work aims to explore the physicochemical underpinning and assist in the elucidation and analysis of this problem. The heat release model consists of a row of distributed heat sources with individual heat release rates. The integrated heat release rate is then coupled with the acoustic perturbation for thermoacoustic analysis. A continuation approach is employed to conduct the bifurcation analysis and capture the nonlinear behaviour inherent in the system. Unlike the conventional approach by the Galerkin method, the acoustic equations are originally discretized using the Method of Lines (MOL) to build up a dynamic system. The model is first validated and shown to yield good predictions with available experimental data. Influences of multiple heat sources, time delay, and heat release distribution are then studied to reveal the extensive nonlinear characteristics involved in the case of a distributed heat source. It is found that distributed heat source plays an important role in determining the stability of a thermoacoustic system.
研究了具有分布式热源的Rijke管。针对精益预混燃气轮机燃烧室热声不稳定性普遍存在的问题,本研究旨在探讨热声不稳定性的物理化学基础,并有助于对这一问题的解释和分析。热释放模型由一排具有单独热释放率的分布式热源组成。然后将综合热释放率与声扰动耦合进行热声分析。采用延拓方法进行分岔分析,捕捉系统固有的非线性行为。与传统的伽辽金方法不同,声学方程最初是用线法(MOL)离散的,以建立一个动态系统。该模型首先被验证,并显示出良好的预测与现有的实验数据。然后研究了多个热源、时间延迟和放热分布的影响,揭示了分布式热源情况下所涉及的广泛的非线性特征。研究发现,分布热源对热声系统的稳定性起着重要的决定作用。
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引用次数: 10
The Influence of the Punched Delta Wings on Flow Pattern and Heat Transfer Characteristic in a Fin-and-Oval-Tube Heat Exchanger 冲孔三角翼对翅片-椭圆管换热器流态和换热特性的影响
Pub Date : 2015-10-26 DOI: 10.1155/2015/368960
A. Boonloi
3D numerical investigations are performed to study the heat transfer, friction factor, and thermal performance of a fin-and-oval heat exchanger with punched delta wings for a range of 500 ≤ Re ≤ 2500 (based on the hydraulic diameter). The influences of the punched angles, 20°, 30°, and 45°, flow directions, wing tips pointing downstream and upstream, and pitch ratios, 2, 3, 4, 5, and 6, are investigated. The results show that the use of the punched delta wings in the fin-and-oval-tube heat exchanger leads to an enhancement in the heat transfer and friction loss as compared to the plain fin for all cases (/ and higher than 1). The enhancements of the heat transfer and friction factor are around 1.01–1.22 and 1.37–2.65 times higher than the base case, respectively. The punched delta wings create the vortex flows through the test section that helps enhance the strength of the impinging flow on the tube walls. The impingement of the fluid flow is an important key to augment the heat transfer rate and thermal performance in the heat exchanger.
在500≤Re≤2500(基于水力直径)范围内,对带穿孔三角翼的翅片椭圆形换热器的传热、摩擦系数和热性能进行了三维数值研究。研究了冲孔角度(20°、30°和45°)、气流方向、翼尖指向下游和上游以及节距比(2、3、4、5和6)的影响。结果表明,与普通翅片相比,在所有情况下(/和大于1),在翅片-卵圆管换热器中使用穿孔三角翼的传热系数和摩擦损失都有所增加,其传热系数和摩擦损失分别是基本情况下的1.01-1.22倍和1.37-2.65倍。冲孔三角翼在测试段产生涡流,有助于增强对管壁的冲击流的强度。流体流动的冲击是提高换热器换热率和热性能的重要关键。
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引用次数: 0
期刊
Journal of Thermodynamics
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