首页 > 最新文献

Journal of the Korean Society of Mineral and Energy Resources Engineers最新文献

英文 中文
Detection of Boundary between Pulp and Froth in Flotation Process Using the Measurement of Electrical Resistance 用电阻测量法检测浮选过程中矿浆与泡沫边界
Pub Date : 2022-04-30 DOI: 10.32390/ksmer.2022.59.2.182
Yun-Ho Seo, Kwanho Kim, Kwang-suk You
{"title":"Detection of Boundary between Pulp and Froth in Flotation Process Using the Measurement of Electrical Resistance","authors":"Yun-Ho Seo, Kwanho Kim, Kwang-suk You","doi":"10.32390/ksmer.2022.59.2.182","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.2.182","url":null,"abstract":"","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74691592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of 4D Seismic Monitoring Tool Considering Anisotropic Media based on Pseudo-acoustic Wave Equation 基于伪声波方程的考虑各向异性介质的四维地震监测工具研制
Pub Date : 2022-04-30 DOI: 10.32390/ksmer.2022.59.2.161
Seok-Han Kim, Hee-Chan Noh, Sea-Eun Park, Ju-Won Oh, D. Min
Seismic anisotropy can be an obstacle when we interpret the seismic data from the seismic survey and monitoring in the sedimentary basins. In this study, we discuss the inaccuracy of the conventional isotropic monitoring algorithm in strong VTI media in causing reflectivity point differences because it offsets differences without considering anisotropic media. To mitigate its shortcomings, we propose a reverse-time migration algorithm for the 4D seismic data regarding vertically transverse isotropic (VTI) media and confirm that this proposed anisotropic monitoring algorithm based on elliptical anisotropy can properly correct the monitoring results. Finally, we improve the accuracy of reflectivity point depth by adapting the anisotropic equation in the pseudo-acoustic wave equation and controlling the offset distance. We compare the efficiency between elliptical anisotropy and VTI of the proposed monitoring algorithm using the synthetic monitoring data from a complex 3D geological model.
地震各向异性是沉积盆地地震调查和监测资料解释的一个障碍。在本研究中,我们讨论了传统各向同性监测算法在强VTI介质中引起反射率点差异的不准确性,因为它在没有考虑各向异性介质的情况下抵消了差异。针对其不足,提出了一种垂直横向各向同性(VTI)介质下四维地震数据的逆时偏移算法,并验证了该基于椭圆各向异性的各向异性监测算法能较好地校正监测结果。最后,在拟声波方程中引入各向异性方程并控制偏移距离,提高了反射率点深度的精度。利用复杂三维地质模型的综合监测数据,比较了椭圆各向异性和VTI监测算法的效率。
{"title":"Development of 4D Seismic Monitoring Tool Considering Anisotropic Media based on Pseudo-acoustic Wave Equation","authors":"Seok-Han Kim, Hee-Chan Noh, Sea-Eun Park, Ju-Won Oh, D. Min","doi":"10.32390/ksmer.2022.59.2.161","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.2.161","url":null,"abstract":"Seismic anisotropy can be an obstacle when we interpret the seismic data from the seismic survey and monitoring in the sedimentary basins. In this study, we discuss the inaccuracy of the conventional isotropic monitoring algorithm in strong VTI media in causing reflectivity point differences because it offsets differences without considering anisotropic media. To mitigate its shortcomings, we propose a reverse-time migration algorithm for the 4D seismic data regarding vertically transverse isotropic (VTI) media and confirm that this proposed anisotropic monitoring algorithm based on elliptical anisotropy can properly correct the monitoring results. Finally, we improve the accuracy of reflectivity point depth by adapting the anisotropic equation in the pseudo-acoustic wave equation and controlling the offset distance. We compare the efficiency between elliptical anisotropy and VTI of the proposed monitoring algorithm using the synthetic monitoring data from a complex 3D geological model.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75621401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Current Status in the Mining Industry of Critical Minerals for Battery (Li, Ni, Co, and C) in the Energy Transition Era 能源转型时代电池关键矿产(锂、镍、钴、碳)采矿业现状
Pub Date : 2022-04-30 DOI: 10.32390/ksmer.2022.59.2.218
R. Kim, Jaewook Lee, Junhyeok Park, S. Shin, I. Park, K. Chung, Jeong‐Hyun Yoo, S. Kim, Seong-Jun Cho, Hoseok Jeon, Han-Chun Chang
As the energy transition era begins, securing minerals is becoming critical, and countries worldwide are highly interested in “critical minerals,” which have a supply risk associated with them. Major countries have newly prepared or updated the list of critical minerals, where battery minerals such as lithium, nickel, cobalt, and graphite typically find a place. The demand for these four critical minerals is expected to increase 3 to 42 folds by 2040 in comparison to 2020 owing to the increasing demand for eco-friendly vehicles and energy storage systems. Recently, the supply risk of the four minerals has increased significantly, as commercial products manufactured using these minerals are generally produced in a specific country; furthermore, the prices of the minerals are constantly increasing. In this study, the current status of the production, markets, and relevant technologies of the four critical minerals was investigated, and some recommendations for securing them were presented.
随着能源转型时代的开始,确保矿产安全变得至关重要,世界各国都对“关键矿产”非常感兴趣,因为这些矿产存在供应风险。主要国家最近编制或更新了关键矿物清单,锂、镍、钴和石墨等电池矿物通常在其中占有一席之地。由于对环保汽车和能源储存系统的需求增加,预计到2040年,这四种关键矿物的需求将比2020年增加3 ~ 42倍。最近,这四种矿物的供应风险大大增加,因为使用这些矿物制造的商业产品一般是在特定国家生产的;此外,矿物的价格也在不断上涨。本文对这四种关键矿物的生产、市场和相关技术现状进行了调查,并提出了保护这些矿物的建议。
{"title":"Current Status in the Mining Industry of Critical Minerals for Battery (Li, Ni, Co, and C) in the Energy Transition Era","authors":"R. Kim, Jaewook Lee, Junhyeok Park, S. Shin, I. Park, K. Chung, Jeong‐Hyun Yoo, S. Kim, Seong-Jun Cho, Hoseok Jeon, Han-Chun Chang","doi":"10.32390/ksmer.2022.59.2.218","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.2.218","url":null,"abstract":"As the energy transition era begins, securing minerals is becoming critical, and countries worldwide are highly interested in “critical minerals,” which have a supply risk associated with them. Major countries have newly prepared or updated the list of critical minerals, where battery minerals such as lithium, nickel, cobalt, and graphite typically find a place. The demand for these four critical minerals is expected to increase 3 to 42 folds by 2040 in comparison to 2020 owing to the increasing demand for eco-friendly vehicles and energy storage systems. Recently, the supply risk of the four minerals has increased significantly, as commercial products manufactured using these minerals are generally produced in a specific country; furthermore, the prices of the minerals are constantly increasing. In this study, the current status of the production, markets, and relevant technologies of the four critical minerals was investigated, and some recommendations for securing them were presented.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91549100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
A Study on Preparation of Nano Iron Oxides-Based Metal Biochar Using Co-Pyrolysis in a CO2 Environment and Adsorption of Cr(VI) CO2环境下共热解制备纳米氧化铁金属生物炭及吸附Cr(VI)的研究
Pub Date : 2022-04-30 DOI: 10.32390/ksmer.2022.59.2.127
Jeong-Yun Jang, Sun Joon Kim
This study explored the effects of blending nano iron (III) oxides (NIO) with coffee grounds (CG) in a pyrolytic process under a CO 2 environment on the generation of syngas (H 2 and CO) and biochar properties regarding the removal of Cr(VI) from aqueous solutions. CG and NIO were physically mixed; CG was mass maintained at 1 g while NIO was added. Based on the mass ratio, the resulting solution was named NICG1(NIO/CG ratio=1:1). Compared with the generation amounts of syngas (0.37 mole% H 2 & 0.28 mole% CO) at 650°C from single pyrolysis of CG, co-pyrolysis with NIO-based additives resulted in increased production of syngas, with the measured concentrations of H 2 and CO reaching 0.99 mole% and 0.86 mole% at the same temperature, respectively. During the pH effect experiments, NICG1 demonstrated the highest removal efficiency under acidic conditions with pH = 2. Adsorption kinetic experiments demonstrated that the pseudo-second-order rate model was suitable for assessing the removal of Cr(VI) by NICG1. Furthermore, the removal of Cr(VI) using NICG1 fitted well with the Freundlich isothernm adsorption model (R 2 = 0.9807). In conclusion, co-pyrolysis of blending nano iron(III) oxide and coffee grounds can be considered an efficient resource for simultaneously producing syngas (H 2 and CO) as a fuel (energy resource) and metal-biochar as an adsorbent.
本研究探讨了在CO 2环境下,将纳米氧化铁(NIO)与咖啡渣(CG)混合在热解过程中对合成气(h2和CO)的生成以及去除水溶液中Cr(VI)的生物炭性能的影响。CG和NIO物理混合;添加NIO时,CG质量保持在1g。根据质量比,将所得溶液命名为NICG1(NIO/CG比=1:1)。与CG单次热解650℃时的合成气产生量(h2 = 0.37 mol %, CO = 0.28 mol %)相比,添加nio基添加剂共热解使合成气产生量增加,在相同温度下,h2和CO的测量浓度分别达到0.99 mol %和0.86 mol %。在pH效应实验中,NICG1在pH = 2的酸性条件下的去除率最高。吸附动力学实验表明,拟二级速率模型适用于NICG1对Cr(VI)的去除。NICG1对Cr(VI)的去除符合Freundlich等温吸附模型(r2 = 0.9807)。综上所述,纳米氧化铁(III)与咖啡渣共热解可以被认为是同时产生合成气(h2和CO)作为燃料(能源)和金属生物炭作为吸附剂的有效资源。
{"title":"A Study on Preparation of Nano Iron Oxides-Based Metal Biochar Using Co-Pyrolysis in a CO2 Environment and Adsorption of Cr(VI)","authors":"Jeong-Yun Jang, Sun Joon Kim","doi":"10.32390/ksmer.2022.59.2.127","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.2.127","url":null,"abstract":"This study explored the effects of blending nano iron (III) oxides (NIO) with coffee grounds (CG) in a pyrolytic process under a CO 2 environment on the generation of syngas (H 2 and CO) and biochar properties regarding the removal of Cr(VI) from aqueous solutions. CG and NIO were physically mixed; CG was mass maintained at 1 g while NIO was added. Based on the mass ratio, the resulting solution was named NICG1(NIO/CG ratio=1:1). Compared with the generation amounts of syngas (0.37 mole% H 2 & 0.28 mole% CO) at 650°C from single pyrolysis of CG, co-pyrolysis with NIO-based additives resulted in increased production of syngas, with the measured concentrations of H 2 and CO reaching 0.99 mole% and 0.86 mole% at the same temperature, respectively. During the pH effect experiments, NICG1 demonstrated the highest removal efficiency under acidic conditions with pH = 2. Adsorption kinetic experiments demonstrated that the pseudo-second-order rate model was suitable for assessing the removal of Cr(VI) by NICG1. Furthermore, the removal of Cr(VI) using NICG1 fitted well with the Freundlich isothernm adsorption model (R 2 = 0.9807). In conclusion, co-pyrolysis of blending nano iron(III) oxide and coffee grounds can be considered an efficient resource for simultaneously producing syngas (H 2 and CO) as a fuel (energy resource) and metal-biochar as an adsorbent.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78607349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seismic Velocity Modeling Building Using Depthwise Separable Convolutional Neural Network 用深度可分卷积神经网络建立地震速度模型
Pub Date : 2022-04-30 DOI: 10.32390/ksmer.2022.59.2.148
J. Jo, W. Ha
The construction of an accurate velocity model is one of the most important tasks in seismic data processing for hydrocarbon exploration. Because deep neural networks have garnered significant attention in the field of geophysics recently, studies have been performed to predict velocity models using regular convolutional neural networks. Herein, we propose a neural network with depthwise separable convolutional layers and an encoder – decoder structure to construct a velocity model. This network is trained using a supervised learning approach, and we predict P-wave velocity models from time-domain wavefields. In this network structure, depthwise separable convolutions perform spatial-oriented convolutions independently for each input channel. These depthwise separable convolutions can improve network performance while significantly reducing the number of model parameters as compared with regular convolutions. Synthetic velocity models generated for training contain various geological features, including folds, faults, and salt-dome structures. We compare a network with depthwise separable convolutions and a network with regular convolutions based on the same training conditions and hyperparameters. Experiments demonstrate that the network with depthwise separable convolutions is more efficient than the network with regular convolutions for constructing a seismic velocity model.
建立准确的速度模型是油气勘探地震资料处理的重要任务之一。由于深度神经网络近年来在地球物理领域引起了极大的关注,人们开始研究使用正则卷积神经网络来预测速度模型。在此,我们提出了一个深度可分离卷积层的神经网络和一个编码器-解码器结构来构建速度模型。该网络使用监督学习方法进行训练,并从时域波场预测纵波速度模型。在这种网络结构中,深度可分离卷积对每个输入通道独立执行面向空间的卷积。与常规卷积相比,这些深度可分离卷积可以提高网络性能,同时显著减少模型参数的数量。为训练生成的合成速度模型包含各种地质特征,包括褶皱、断层和盐丘构造。我们比较了基于相同训练条件和超参数的深度可分离卷积网络和正则卷积网络。实验表明,深度可分卷积网络比规则卷积网络更有效地构建了地震速度模型。
{"title":"Seismic Velocity Modeling Building Using Depthwise Separable Convolutional Neural Network","authors":"J. Jo, W. Ha","doi":"10.32390/ksmer.2022.59.2.148","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.2.148","url":null,"abstract":"The construction of an accurate velocity model is one of the most important tasks in seismic data processing for hydrocarbon exploration. Because deep neural networks have garnered significant attention in the field of geophysics recently, studies have been performed to predict velocity models using regular convolutional neural networks. Herein, we propose a neural network with depthwise separable convolutional layers and an encoder – decoder structure to construct a velocity model. This network is trained using a supervised learning approach, and we predict P-wave velocity models from time-domain wavefields. In this network structure, depthwise separable convolutions perform spatial-oriented convolutions independently for each input channel. These depthwise separable convolutions can improve network performance while significantly reducing the number of model parameters as compared with regular convolutions. Synthetic velocity models generated for training contain various geological features, including folds, faults, and salt-dome structures. We compare a network with depthwise separable convolutions and a network with regular convolutions based on the same training conditions and hyperparameters. Experiments demonstrate that the network with depthwise separable convolutions is more efficient than the network with regular convolutions for constructing a seismic velocity model.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74307136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Seismic Interferometry: Research Trends and Technological Introduction 地震干涉测量:研究趋势与技术介绍
Pub Date : 2022-04-30 DOI: 10.32390/ksmer.2022.59.2.205
Inseok Joung, Ahyun Cho, Hanna Jang, Bitnarae Kim, C. Cho, M. Nam
In the seismic interferometry (SI) method, cross correlation of seismic recordings at two receivers is performed to retrieve an estimate of the seismic trace at one of the receivers while the other acts as a so-called “virtual source” to obtain subsurface information. In this article, basic SI theories are described, and past cases in which SI methods were used are analyzed. SI, which mainly uses cross correlation, can be performed using deconvolution or coherence, and each SI method can be applied to seismic reflection, refraction, and surface wave survey data. Because the virtual source can be positioned at all receiver locations and active sources are not necessary, SI is an extremely effective monitoring technique. SI has been applied to such fields as geological imaging, fault detection, and structural health.
在地震干涉测量(SI)方法中,对两个接收器的地震记录进行相互关联,以检索其中一个接收器的地震迹线估计,而另一个接收器充当所谓的“虚拟源”,以获取地下信息。在这篇文章中,描述了基本的科学探究理论,并分析了过去使用科学探究方法的案例。SI主要使用互相关,可以使用反褶积或相干,每种SI方法都可以应用于地震反射、折射和面波测量数据。由于虚拟震源可以定位在所有接收器位置,而不需要有源,因此SI是一种非常有效的监测技术。SI已应用于地质成像、断层检测和构造健康等领域。
{"title":"Seismic Interferometry: Research Trends and Technological Introduction","authors":"Inseok Joung, Ahyun Cho, Hanna Jang, Bitnarae Kim, C. Cho, M. Nam","doi":"10.32390/ksmer.2022.59.2.205","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.2.205","url":null,"abstract":"In the seismic interferometry (SI) method, cross correlation of seismic recordings at two receivers is performed to retrieve an estimate of the seismic trace at one of the receivers while the other acts as a so-called “virtual source” to obtain subsurface information. In this article, basic SI theories are described, and past cases in which SI methods were used are analyzed. SI, which mainly uses cross correlation, can be performed using deconvolution or coherence, and each SI method can be applied to seismic reflection, refraction, and surface wave survey data. Because the virtual source can be positioned at all receiver locations and active sources are not necessary, SI is an extremely effective monitoring technique. SI has been applied to such fields as geological imaging, fault detection, and structural health.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88948900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Dispersion Stability Test of Seawater-based Nano-Smart Fluids 海水基纳米智能流体的合成及分散稳定性试验
Pub Date : 2022-02-28 DOI: 10.32390/ksmer.2022.59.1.091
Jihwan Kim, Jong-Seop Lee
In this study, nano-smart fluids available in high-temperature and high-salinity reservoirs were synthesized with surface-modified nanoparticles and potential determining ion(PDI)-controlled seawater to maximize oil production in carbonate reservoirs. Phase behavior observation and particle size analysis were also carried out to evaluate the dispersion stability of synthesized nano-smart fluids. Seawater was prepared based on the seawater composition of the Persian Gulf region and PDIs(K+, Mg2+, and SO4 2–) were added to the seawater. In addition, 0.05-3 wt% of surface-modified SiO2 nanoparticles were dispersed in the smart water prepared as aforementioned. As a result of the dispersion stability test, it was confirmed that stable fluids without agglomeration and precipitation could be synthesized at the condition with room temperature of 25°C and high temperature of 80°C as well as in the salinity range of seawater when the nanoparticle concentration was 0.5 wt% or more.
在本研究中,采用表面改性纳米颗粒和电位决定离子(PDI)控制的海水合成了适用于高温高矿化度油藏的纳米智能流体,以最大限度地提高碳酸盐岩油藏的产油量。通过相行为观察和粒径分析来评价合成的纳米智能流体的分散稳定性。根据波斯湾地区的海水组成配制海水,在海水中加入PDIs(K+, Mg2+, SO4 2 -)。此外,在上述制备的智能水中分散了0.05-3 wt%的表面改性SiO2纳米颗粒。分散稳定性试验证实,在室温25℃和高温80℃条件下,在纳米颗粒浓度为0.5 wt%及以上的海水盐度范围内,均可合成无团聚、无沉淀的稳定流体。
{"title":"Synthesis and Dispersion Stability Test of Seawater-based Nano-Smart Fluids","authors":"Jihwan Kim, Jong-Seop Lee","doi":"10.32390/ksmer.2022.59.1.091","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.1.091","url":null,"abstract":"In this study, nano-smart fluids available in high-temperature and high-salinity reservoirs were synthesized with surface-modified nanoparticles and potential determining ion(PDI)-controlled seawater to maximize oil production in carbonate reservoirs. Phase behavior observation and particle size analysis were also carried out to evaluate the dispersion stability of synthesized nano-smart fluids. Seawater was prepared based on the seawater composition of the Persian Gulf region and PDIs(K+, Mg2+, and SO4 2–) were added to the seawater. In addition, 0.05-3 wt% of surface-modified SiO2 nanoparticles were dispersed in the smart water prepared as aforementioned. As a result of the dispersion stability test, it was confirmed that stable fluids without agglomeration and precipitation could be synthesized at the condition with room temperature of 25°C and high temperature of 80°C as well as in the salinity range of seawater when the nanoparticle concentration was 0.5 wt% or more.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78514609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Elucidation of the Effect of Functional Group Substitution of BN-cyclohexane for Renewable Energy Hydrogen Storage: Density Functional Theory Approach bn -环己烷官能团取代对可再生能源储氢效果的阐释:密度泛函理论方法
Pub Date : 2022-02-28 DOI: 10.32390/ksmer.2022.59.1.021
Govindaraja Senthamaraikannan Thillai, Dong-Hee Lim
Liquid organic hydrogen carrier (LOHC) has been attracting attention as a hydrogen storage technology. Among the LOHC materials, we explore fluorine (F) and amine (NH2) functional group substituted 1,2-BN cyclohexane-based hydrogen storage materials with improved reversibility of dehydrogenation-hydrogenation reaction. Density functional theory (DFT) calculations were conducted by using Gaussian 16 software to calculate dehydrogenation reaction enthalpy (∆) and reaction free energy (∆). F-BN-cyclohexane and NH2-BN-cyclohexane show ∆ of ‒4.10 and ‒5.38 kJ/mol, respectively, whereas 1,2-BN cyclohexane shows ∆ of ‒5.71 kJ/mol. Because the reversibility of dehydrogenation-hydrogenation reactions is excellent as the ∆ value is close to zero, the functional group substitution enhanced the reversibility of the dehydrogenation-hydrogenation reaction. This DFT study not only presents a systematic methodology to evaluate the dehydrogenation-hydrogenation reaction reversibility that can be improved by substituting F and NH2 functional groups in existing BN-cyclohexane, but also provides the fundamental mechanisms of dehydrogenation of Fand NH2-BN-cyclohexane.
液态有机氢载体(LOHC)作为一种储氢技术一直受到人们的关注。在LOHC材料中,我们探索了氟(F)和胺(NH2)官能团取代1,2- bn环己烷基储氢材料,提高了脱氢-加氢反应的可逆性。采用Gaussian 16软件进行密度泛函理论(DFT)计算,计算脱氢反应焓(∆hf)和反应自由能(∆hf)。f - bn -环己烷和nh2 - bn -环己烷的∆焦距分别为-4.10和-5.38 kJ/mol,而1,2- bn环己烷的∆焦距为-5.71 kJ/mol。由于脱氢-加氢反应的可逆性极好,∆实况值接近于零,官能团取代增强了脱氢-加氢反应的可逆性。本DFT研究不仅为评价现有bn -环己烷取代F和NH2官能团可提高脱氢-加氢反应的可逆性提供了系统的方法,而且提供了f6和NH2- bn -环己烷脱氢的基本机理。
{"title":"Elucidation of the Effect of Functional Group Substitution of BN-cyclohexane for Renewable Energy Hydrogen Storage: Density Functional Theory Approach","authors":"Govindaraja Senthamaraikannan Thillai, Dong-Hee Lim","doi":"10.32390/ksmer.2022.59.1.021","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.1.021","url":null,"abstract":"Liquid organic hydrogen carrier (LOHC) has been attracting attention as a hydrogen storage technology. Among the LOHC materials, we explore fluorine (F) and amine (NH2) functional group substituted 1,2-BN cyclohexane-based hydrogen storage materials with improved reversibility of dehydrogenation-hydrogenation reaction. Density functional theory (DFT) calculations were conducted by using Gaussian 16 software to calculate dehydrogenation reaction enthalpy (∆) and reaction free energy (∆). F-BN-cyclohexane and NH2-BN-cyclohexane show ∆ of ‒4.10 and ‒5.38 kJ/mol, respectively, whereas 1,2-BN cyclohexane shows ∆ of ‒5.71 kJ/mol. Because the reversibility of dehydrogenation-hydrogenation reactions is excellent as the ∆ value is close to zero, the functional group substitution enhanced the reversibility of the dehydrogenation-hydrogenation reaction. This DFT study not only presents a systematic methodology to evaluate the dehydrogenation-hydrogenation reaction reversibility that can be improved by substituting F and NH2 functional groups in existing BN-cyclohexane, but also provides the fundamental mechanisms of dehydrogenation of Fand NH2-BN-cyclohexane.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82251867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physical Separation of Heavy Metals in Contaminated Soil Simulant near Abandoned Metal Mines 废弃金属矿山污染土壤模拟物中重金属物理分离研究
Pub Date : 2022-02-28 DOI: 10.32390/ksmer.2022.59.1.001
D. Jeong, J. Cha
The purpose of this study was to treat heavy metals from contaminated soil simulant around abandoned mines by using physical separation techniques. As a result of magnetic separation, the average removal efficiency was shown as lead 53%, zinc 67%, arsenic 66%, and cadmium 71% and volume of highly contaminated soil was reduced by approximately 16% in the condition of more than 5,000 gauss. When the corona discharging electrostatic separation applied, the highest removal efficiency according to supplied voltages was observed as 38% for lead at –35 kV, 45% and 48% for zinc and cadmium at –30 kV, respectively and 38% for arsenic at –25 kV conditions. However, considering the cost and the volume of contaminated soil to be treated later, it was considered that the –10 kV condition was optimal.
采用物理分离技术对废弃矿山周围污染土壤模拟物中的重金属进行处理。在大于5000高斯的条件下,磁选的平均去除率为铅53%、锌67%、砷66%、镉71%,高污染土壤体积减少约16%。电冕放电静电分离对铅的去除率最高,在-35 kV条件下为38%,锌和镉在-30 kV条件下为45%和48%,砷在-25 kV条件下为38%。但是,考虑到成本和后期需要处理的污染土壤体积,我们认为-10 kV条件是最优的。
{"title":"Physical Separation of Heavy Metals in Contaminated Soil Simulant near Abandoned Metal Mines","authors":"D. Jeong, J. Cha","doi":"10.32390/ksmer.2022.59.1.001","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.1.001","url":null,"abstract":"The purpose of this study was to treat heavy metals from contaminated soil simulant around abandoned mines by using physical separation techniques. As a result of magnetic separation, the average removal efficiency was shown as lead 53%, zinc 67%, arsenic 66%, and cadmium 71% and volume of highly contaminated soil was reduced by approximately 16% in the condition of more than 5,000 gauss. When the corona discharging electrostatic separation applied, the highest removal efficiency according to supplied voltages was observed as 38% for lead at –35 kV, 45% and 48% for zinc and cadmium at –30 kV, respectively and 38% for arsenic at –25 kV conditions. However, considering the cost and the volume of contaminated soil to be treated later, it was considered that the –10 kV condition was optimal.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81526255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stability Analysis of Pillar in Underground Limestone Mine Using 3D Scanning Techniques 基于三维扫描技术的地下石灰岩矿柱稳定性分析
Pub Date : 2022-02-28 DOI: 10.32390/ksmer.2022.59.1.010
Donghui Kim, Gyoungman Kim, H. Baek
In this study, point-cloud data were obtained using a laser scanner for an underground limestone mine. A total of 581 discontinuities were extracted and statistically treated using the obtained point-cloud data, and a discrete fracture network was simulated and applied to the numerical analysis model. The stability was evaluated for two pillars located in large underground openings using the numerical analysis model. The evaluation results based on the safety factor and displacement showed that the safety factor tended to decrease as it progressed from the center of the pillar to the side wall. However, the pillars showed a minimum safety factor of 1.0 or higher. For the displacement, a maximum displacement of 9 mm occurred in a part of the pillar side wall. Nevertheless, the stability of the pillar was achieved, as it was insignificant compared to the size of the pillar.
在本研究中,使用激光扫描仪获得了地下石灰石矿山的点云数据。利用得到的点云数据,对581个不连续面进行了提取和统计处理,模拟了一个离散裂缝网络,并将其应用于数值分析模型。采用数值分析模型对位于地下大孔洞中的两根矿柱的稳定性进行了评价。基于安全系数和位移的评价结果表明,从矿柱中心向侧壁推进,安全系数有减小的趋势。然而,柱的最小安全系数为1.0或更高。对于位移,柱侧壁部分最大位移为9 mm。然而,柱子的稳定性得到了实现,因为它与柱子的大小相比是微不足道的。
{"title":"Stability Analysis of Pillar in Underground Limestone Mine Using 3D Scanning Techniques","authors":"Donghui Kim, Gyoungman Kim, H. Baek","doi":"10.32390/ksmer.2022.59.1.010","DOIUrl":"https://doi.org/10.32390/ksmer.2022.59.1.010","url":null,"abstract":"In this study, point-cloud data were obtained using a laser scanner for an underground limestone mine. A total of 581 discontinuities were extracted and statistically treated using the obtained point-cloud data, and a discrete fracture network was simulated and applied to the numerical analysis model. The stability was evaluated for two pillars located in large underground openings using the numerical analysis model. The evaluation results based on the safety factor and displacement showed that the safety factor tended to decrease as it progressed from the center of the pillar to the side wall. However, the pillars showed a minimum safety factor of 1.0 or higher. For the displacement, a maximum displacement of 9 mm occurred in a part of the pillar side wall. Nevertheless, the stability of the pillar was achieved, as it was insignificant compared to the size of the pillar.","PeriodicalId":17454,"journal":{"name":"Journal of the Korean Society of Mineral and Energy Resources Engineers","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81879153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of the Korean Society of Mineral and Energy Resources Engineers
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1