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Synthesis and Optimization of Visible-light-driven G-C3N4/CoMoO4 for the Removal of Tetracycline 可见光驱动G-C3N4/CoMoO4去除四环素的合成与优化
Q3 Environmental Science Pub Date : 2023-01-01 DOI: 10.2965/jwet.22-060
H. T. Nguyen, Ha Thi Viet Tran, P. M. Nguyen, I. Kasuga
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引用次数: 0
Concurrent Analysis of 84 Compounds among Emerging Contaminants Listed by the Ministry of the Environment, Japan, in Domestic Wastewater Treatment Plants Using Liquid Chromatography and High-resolution Mass Spectrometry (LC-HRMS) 液相色谱-高分辨率质谱法(LC-HRMS)同时分析日本环境省污水处理厂新污染物中的84种化合物
Q3 Environmental Science Pub Date : 2023-01-01 DOI: 10.2965/jwet.22-076
Aishwarya Pandey, I. Kasuga, H. Furumai, F. Kurisu
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引用次数: 0
Occurrence of Stenotrophomonas spp. in the Water Environment and Characteristics of Isolates 水环境中窄养单胞菌的发生及分离特征
Q3 Environmental Science Pub Date : 2023-01-01 DOI: 10.2965/jwet.22-153
T. Urase, Xiao Yang, Saki Goto
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引用次数: 0
Catalytic Hydrogenation of Methyl Orange and Acid Orange 7 Using NaBH<sub>4</sub> over Core-shell Multicomponent Alloys NaBH&lt;sub&gt;4&lt;/sub&gt;超过核壳多组分合金
Q3 Environmental Science Pub Date : 2023-01-01 DOI: 10.2965/jwet.23-030
Shota Yokoyama, Yasukazu Kobayashi, Ryo Shoji
Azo dyes are common aqueous environmental pollutants in developing countries. Hydrogenation is a highly effective method for decomposition of azo dyes; however, this method requires the use of noble metals as catalysts. In this study, we investigated the use of multi-component alloy catalysts. Eight multi-component alloys (CoFeNiTiCr(800), CoFeNiTiAl(800), CoFeNiTiV(800), Fe40Mn10Cr15Ni25Al5(800), Fe35Mn10Cr20Ni35(800), Fe50Mn27Cr13Ni10(800), Al0.2Co1.5CrFeNi1.5Ti0.5(600), and Al0.2Co1.5CrFeNi1.5Ti0.5(800)), where numbers in brackets represent calcine temperature (°C), were used for hydrogenation of methyl orange and Acid Orange 7 with NaBH4. These multicomponent alloys were prepared from oxide precursors using a nonelectrochemical molten salt synthesis method. The reaction rates increased in the order of Al0.2Co1.5CrFeNi1.5Ti0.5(800) < CoFeNiTiAl(800) < Al0.2Co1.5CrFeNi1.5Ti0.5(600) for hydrogenation of methyl orange. Al0.2Co1.5CrFeNi1.5Ti0.5(600) rapidly decreased the methyl orange concentration to almost zero within 10 min. The reaction rates increased in the order of CoFeNiTiCr(800) < Al0.2Co1.5CrFeNi1.5Ti0.5(600) < CoFeNiTiV(800) for hydrogenation of Acid Orange 7. CoFeNiTiV(800) rapidly decreased the Acid Orange 7 concentration to almost zero within 10 min. This difference in catalytic activity for each azo dye was thought to arise because Acid Orange 7 was insufficiently decomposed by the reducing agent NaBH4, and this affected its interaction with the catalyst.
偶氮染料是发展中国家常见的水环境污染物。氢化反应是分解偶氮染料的一种高效方法;然而,这种方法需要使用贵金属作为催化剂。在这项研究中,我们研究了多组分合金催化剂的使用。用八种多组分合金(CoFeNiTiCr(800)、CoFeNiTiAl(800)、CoFeNiTiV(800)、Fe40Mn10Cr15Ni25Al5(800)、Fe35Mn10Cr20Ni35(800)、Fe50Mn27Cr13Ni10(800)、Al0.2Co1.5CrFeNi1.5Ti0.5(600)和Al0.2Co1.5CrFeNi1.5Ti0.5(800),括号中的数字表示焙烧温度(℃))与NaBH4加氢甲基橙和酸橙7。采用非电化学熔盐合成方法从氧化物前驱体制备了这些多组分合金。甲基橙加氢反应速率依次为Al0.2Co1.5CrFeNi1.5Ti0.5(800) < CoFeNiTiAl(800) < Al0.2Co1.5CrFeNi1.5Ti0.5(600)。Al0.2Co1.5CrFeNi1.5Ti0.5(600)在10 min内迅速将甲基橙浓度降低到几乎为零。酸橙7的加氢反应速率依次为cofenitir (800) < Al0.2Co1.5CrFeNi1.5Ti0.5(600) < CoFeNiTiV(800)。CoFeNiTiV(800)在10分钟内迅速将酸橙7的浓度降低到几乎为零。每种偶氮染料的催化活性差异被认为是由于酸橙7没有被还原剂NaBH4充分分解,这影响了它与催化剂的相互作用。
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引用次数: 0
An Analytical Method for Simultaneous Measurement of Various Cyanotoxins Using Stable Isotope-Labeled Surrogates and a Microbial Flora Analysis to Assign Each Cyanotoxin to its Source 利用稳定同位素标记代物和微生物区系分析同时测定各种蓝藻毒素的分析方法以确定每种蓝藻毒素的来源
Q3 Environmental Science Pub Date : 2022-01-01 DOI: 10.2965/jwet.22-005
Masaya Matsuki, N. Shimizu, K. Tobiishi, Yoshito Tanaka, Haruyo Yamaguchi, T. Sano
Cyanotoxins produced by blue-green algae in lakes are among the most serious threats to water quality worldwide. As global warming rapidly extends the locations and timing of blue-green algae blooms, a simple and accessible method for the detection and quantification of cyanotoxins in fresh water is increasingly necessary. Here, a quick, simple and accessible simultaneous analytical method for five cyanotoxins (cylindrospermopsin, anatoxin-a, microcystin-RR, YR and LR) is reported. This method has three advantages. First, it does not require complicated operations, such as a concentra - tion operation. Second, it employs an HPLC column without high pressure. Third, the use of stable isotope-labeled surrogates enables correct identification and precise quantification of cyanotoxins. The method was applied to the lakes of Fukuoka Prefecture in Japan, and four of the five above-named cyanotoxins ( i.e. , all but cylindrospermopsin) were detected. The limits of quantification were 20–43 ng/L, which were considerably lower than the WHO guideline values. The recovery levels were 97–104%. Microbial flora analysis revealed that the sources of anatoxin-a were Pseudanabaena limnetica and Cuspidothrix issatschenkoi , and the source of microcystins was the group A1 of Microcystis aeruginosa . This study provides a quick, easy and accessible method for the worldwide monitoring of cyanotoxin levels.
湖泊中蓝藻产生的蓝藻毒素是世界范围内对水质最严重的威胁之一。由于全球变暖迅速延长了蓝藻繁殖的地点和时间,一种简单易行的方法来检测和定量淡水中的蓝藻毒素越来越有必要。本文报道了一种快速、简便、易获得的同时分析5种蓝藻毒素(圆柱精子素、anatoxin-a、微囊藻毒素- rr、YR和LR)的方法。这种方法有三个优点。首先,它不需要复杂的操作,如浓缩操作。二是采用无高压的高效液相色谱柱。第三,使用稳定同位素标记的替代物可以正确识别和精确定量蓝藻毒素。该方法应用于日本福冈县的湖泊,检测到上述五种蓝藻毒素中的四种(即除了圆柱形精子素外的所有毒素)。定量限为20 ~ 43 ng/L,远低于WHO指导值。回收率为97 ~ 104%。微生物区系分析表明,anatoxin-a的来源为Pseudanabaena limnetica和Cuspidothrix issatschenkoi,微囊藻毒素的来源为Microcystis aeruginosa的A1群。本研究为全球范围内的蓝藻毒素水平监测提供了一种快速、简便、易获取的方法。
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引用次数: 0
Examination and Evaluation of Oyster Shell Utilization with Rice Husk Biochar for Phosphorus Adsorption 稻壳生物炭利用牡蛎壳吸附磷的研究与评价
Q3 Environmental Science Pub Date : 2022-01-01 DOI: 10.2965/jwet.21-154
Masaki Ohno, Yuki Kobayashi, Risa Sohma, Mayumi Suzuki, T. Kose, Takashi Asada, K. Kawata
Calcium (Ca)-loaded biochar was produced from rice husks by loading the Ca source with subsequent carbonization and was examined from the evaluation of P adsorption capability about the loading method, the availability of oyster shells as the alternative, and the effect of carbonization temperature. Ca-loaded biochar prepared at 650°C had the CaCO3 form, and that at 400°C had unconverted Ca(OH)2 with less CO2 generation. Moreover, silicon in the rice husks might have existed as an amorphous structure of calcium silicate hydrate by reacting with Ca. As the loading method of the Ca source, the powder mixing method was as effective as the conventional impregnation method. It was clarified that oyster shells can be used by decarboxylation and hydration in the powder mixing method, and that the chemical form of the Ca source is important for improving P adsorption capability. Furthermore, the Ca-loaded biochar prepared at 400°C as the condition that could be performed at the paddy field location was higher P adsorption capability than that at 650°C, even though the pores were not developed. The formation of Ca(OH)2 by low-temperature carbonization of rice husks with Ca affected the improvement of P adsorption capability.
以稻壳为原料,通过加载Ca源并进行后续炭化制备了钙负载生物炭,并从加载方式、牡蛎壳的可选性和炭化温度的影响等方面考察了钙负载生物炭对磷的吸附能力。650℃制备的载钙生物炭具有CaCO3形态,400℃制备的载钙生物炭具有未转化的Ca(OH)2,产生的CO2较少。此外,稻壳中的硅可能通过与钙的反应以水合硅酸钙的无定形结构存在。作为钙源的加载方式,混粉法与常规浸渍法同样有效。阐明了牡蛎壳可以通过脱羧和水合作用进行混粉,说明了钙源的化学形态对提高磷吸附能力有重要意义。此外,在400°C条件下制备的载钙生物炭在水田位置上的吸附P能力高于650°C条件下的吸附P能力,尽管孔隙没有发育。稻壳经Ca低温碳化后生成Ca(OH)2,影响了稻壳对磷吸附能力的提高。
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引用次数: 0
The Toxicity of Copper to Pacific Oyster and Sea Squirt from Japan Using Regional Seawater as a Test Medium 以区域海水为试验介质研究铜对日本太平洋牡蛎和海鞘的毒性
Q3 Environmental Science Pub Date : 2022-01-01 DOI: 10.2965/jwet.22-046
R. Tai, Kenta Chiba, Y. Nishimura, Shuping Han, S. Masunaga, W. Naito
Copper (Cu) toxicity is an increasing concern in marine environments; however, its effects are spe cies- and area-specific. In this study, area-specific Cu toxicity test was conducted on the sensitive early life stages ( i.e. , embryonic and larval development) of two important fisheries species, namely, Pacific oyster ( Crassostrea gigas ) and sea squirt ( Halocynthia roretzi ) using natural sea waters collected from three sites in the coastal area of Miyagi Prefecture, Japan. Measured concentrations for C. gigas and nominal concentrations for H. roretzi were used to calculate effect concentrations for each species. The 10% effect concentration (EC10) for Cu were 12.8–17.0 and 15.0–22.0 µg L −1 , and 50% effect concentration (EC50) for Cu were 20.3–22.6 and 45.6–47.2 µg L −1 , respectively. Notably, this study is the first to determine the toxicity of Cu to H. roretzi, and our results can provide additional information to strengthen the Cu species sensitivity distribution of saltwater species, which can support bioavailability correction. Moreover, the results of this study can help policymakers to develop more realistic Cu water quality standard while considering the effects of Cu toxicity on important species and the water chemistry in specific regions. (c)
铜(Cu)毒性在海洋环境中日益受到关注;然而,它的影响是特定物种和地区的。本研究利用日本宫城县沿海3个地点采集的自然海水,对两种重要渔业物种太平洋牡蛎(Crassostrea gigas)和海鞘(Halocynthia roretzi)敏感的早期生命阶段(即胚胎和幼体发育)进行了区域特异性铜毒性试验。利用测量的巨线虫浓度和罗氏螺旋体的名义浓度来计算每种物种的效应浓度。铜的10%效应浓度(EC10)分别为12.8 ~ 17.0和15.0 ~ 22.0µg L−1,铜的50%效应浓度(EC50)分别为20.3 ~ 22.6和45.6 ~ 47.2µg L−1。值得注意的是,本研究首次确定了铜对H. roretzi的毒性,为加强咸水物种对铜的敏感性分布提供了额外的信息,为生物利用度校正提供了支持。此外,本研究结果可以帮助决策者在考虑Cu毒性对重要物种的影响和特定区域水化学的同时制定更现实的Cu水质标准。(c)
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引用次数: 0
Development and Validation of an Analytical Method for Simultaneous Determination of Perfluoroalkyl Acids in Drinking Water by Liquid Chromatography/Tandem Mass Spectrometry 液相色谱/串联质谱同时测定饮用水中全氟烷基酸的分析方法的建立与验证
Q3 Environmental Science Pub Date : 2022-01-01 DOI: 10.2965/jwet.22-058
Norihiro Kobayashi, S. Takagi, Teruaki Kinoshita, Osamu Sakata, Fumi Nakano, Naoto Watanabe, Azumi Nomura, Nobuyuki Kawai, Toshiya Hiraiwa, M. Okumura, K. Furukawa, T. Kasuya, Noritomo Iwama, J. Yonekubo, Reika Takahara, Seiya Tanaka, Yuko Tsuchiya, Y. Ikarashi
The environmental presence and drinking water contamination of per-and polyfluoroalkyl substances (PFAS) have been reported since the early 2000s. This study seeks to develop a liquid chromatography/ tandem mass spectrometry analytical method for the simultaneous determination of 21 perfluoroalkyl acids (PFAAs) in drinking water to support future regulations in Japan. Inter-laboratory tests were conducted in 16 laboratories using different instrument to verify the applicability of the developed method for a wide range of drinking water samples in Japan. Recovery tests of PFAA-fortified tap water samples obtained in each laboratory were conducted at set points of 1 and 10 ng/L. Calibra - tion curve linearity, trueness (recovery), repeatability (RSD r ), and reproducibility (RSD R ) at these analyte concentrations were calculated using data obtained from the recovery tests. The trueness, RSD r , and RSD R of most PFAA analytes were satisfactory when the recoveries were corrected by 13 C-PFAA extraction standards with similar recovery to the corresponding PFAS analytes. The developed analytical method is valid for the quantification of the target PFAAs in drinking water. However, satisfactory PFAA quantification requires recovery adjustment using surrogates with similar recovery characteristics to the PFAA analytes.
自2000年代初以来,就有关于全氟烷基和多氟烷基物质(PFAS)的环境存在和饮用水污染的报告。本研究旨在开发一种液相色谱/串联质谱分析方法,用于同时测定饮用水中的21种全氟烷基酸(PFAAs),以支持日本未来的法规。在16个实验室使用不同的仪器进行了实验室间测试,以验证所开发的方法对日本各种饮用水样品的适用性。在设定点为1和10纳克/升时,对每个实验室获得的加pfa的自来水样品进行回收试验。使用从回收率试验中获得的数据计算这些分析物浓度下的校准曲线线性度、准确度(回收率)、重复性(RSD r)和再现性(RSD r)。采用13种与PFAS样品回收率相近的C-PFAA提取标准进行校正,多数PFAA样品的正确度、RSD r和RSD r均令人满意。所建立的分析方法可用于饮用水中PFAAs的定量分析。然而,令人满意的PFAA定量需要使用与PFAA分析物具有相似回收率特征的替代物进行回收率调整。
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引用次数: 0
Inhibitory Effects of UV-LED Irradiation and Period in Darkness on Photoreactivation of Coliforms in Johkasou Treated Water UV-LED照射和黑暗时间对约卡苏处理水中大肠菌群光活化的抑制作用
Q3 Environmental Science Pub Date : 2022-01-01 DOI: 10.2965/jwet.22-045
Akihiro Kakiki, O. Nishimura, Hiroshi Yamazaki
With the recent development of ultraviolet light emitting diodes (UV-LEDs), it is now possible to apply UV disinfection, previously used only for medium-to-large sized sewage treatment plants, to Johkasou wastewater, a household wastewater treatment system. However, it is known that coliforms that have been inactivated by UV irradiation regain their activity after of sunlight irradiation, etc. Therefore, in small Johkasou, where discharge channels are often open, photorecovery may occur immediately after UV disinfection. However, no studies have been conducted to investigate photorecovery by sunlight after UV disinfection of wastewater from small Johkasou. In this study, the relationship between the photorecovery of coliforms and the dose of sunlight after UV-LED irradiation of effluent in Johkasou was investigated. As a result, we identified the amount of sunlight that will maximize photoreactivation effect. We also clarified the suppressing effect of an excessive amount of sunlight on the photoreactivation phenomenon. Additionally, since it was confirmed that the photore activation effect was suppressed by a certain period of darkness following UV-LED irradiation, it was considered that the photoreactivation effect can also be suppressed by allowing wastewater to reside in darkness for the currently estimated residence time in a disinfection tank.
随着紫外线发光二极管(UV- led)的最新发展,以前仅用于大中型污水处理厂的紫外线消毒现在可以应用于家庭污水处理系统Johkasou废水。然而,众所周知,被紫外线照射灭活的大肠菌群在阳光照射后会恢复活性等。因此,在排放通道经常开放的小约翰卡苏,紫外线消毒后可能立即发生光恢复。然而,目前还没有研究对小Johkasou废水进行紫外线消毒后的光回收。本文研究了UV-LED照射约卡苏污水后大肠菌群的光恢复与光照剂量的关系。因此,我们确定了将最大化光活化效果的阳光量。我们还阐明了过量的阳光对光活化现象的抑制作用。此外,由于已经证实UV-LED照射后一定时间的黑暗会抑制光活化效应,因此可以认为,让废水在消毒池中停留在黑暗中,达到目前估计的停留时间,也可以抑制光活化效应。
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引用次数: 0
Demarcation of Groundwater Quantum and Quality of Lower Indus Basin: A Case Study of Seri and Muhammad Khan Distributaries 下印度河流域地下水数量和水质的划分——以Seri和Muhammad Khan流域为例
Q3 Environmental Science Pub Date : 2022-01-01 DOI: 10.2965/jwet.21-110
A. Qureshi, S. M. Kori, Waqas Wasi Pathan, Abdul Rehman Kori, A. A. Mahessar
{"title":"Demarcation of Groundwater Quantum and Quality of Lower Indus Basin: A Case Study of Seri and Muhammad Khan Distributaries","authors":"A. Qureshi, S. M. Kori, Waqas Wasi Pathan, Abdul Rehman Kori, A. A. Mahessar","doi":"10.2965/jwet.21-110","DOIUrl":"https://doi.org/10.2965/jwet.21-110","url":null,"abstract":"","PeriodicalId":17480,"journal":{"name":"Journal of Water and Environment Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69270798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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Journal of Water and Environment Technology
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