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Preliminary Assessment of Several Heavy Metal Ions (Fe, Cu, Ni, Zn, Cr, Pb, and Cd) in Water, Sediment, Ceratophyllum demersum, and Potamogeton pectinatus Plants from Marsh Al-Hawizeh, Iraq 伊拉克Al-Hawizeh沼泽地区水、沉积物、长尾角藻和马铃薯植物中几种重金属离子(Fe、Cu、Ni、Zn、Cr、Pb和Cd)的初步评价
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/jwet.20-160
Al-thahaibawi B.m.h.
Seasonal samples of water, sediments, and two submerged plants, Ceratophyllum demersum and Potamogeton pectinatus , were collected from four sites within Al-Hawizeh marsh between December 2017 and November 2018 to assess several heavy metal concentrations (Fe, Cu, Ni, Cd, Pb, Cr, and Zn) and analyzed by using Flame Atomic Absorption Spectrophotometer. All concentrations were compared to permissible limits for aquatic life. The findings have clarified levels of metals so as the following: Sediments > plants > water. Concentrations of heavy metals in sediment decreased within the sequence Fe > Ni > Cd > Cu > Cr > Zn > Pb (mg/kg), plants as Fe > Zn > Cd > Cr > Ni > Pb > Cu (mg/kg dry weight), in water as Fe > Ni > Zn > Pb > Cr > Cd (mg/L). The concentrations of all metals in water didn’t exceed the permissible limit, thus Fe, Ni, and Pb showed a greater concentration in water samples than other metals. In sediments Fe, Ni, and Cd have exceeded the permissible limits except Cd wasn’t detected (ND) during the winter, whereas, Zn and Pb didn’t exceed the recommended limits. In-plant samples as C. demersum Fe, Cd, Zn, and Cr have exceeded the allowable limits, while Cu and Pb didn’t exceed the permissible limits, also in P. pectinatus Fe, Cd, and Zn have exceeded the permissible limits, whereas, Ni, Cu, Cr, and Pb didn’t exceed the permissible limits altogether seasons during this study. The correlation of Pearson was administered to detect the interrelationship between metal concentrations. A significant positive correlation ( p ≤ 0.05) was found in sediment rather than plants and water samples.
2017年12月至2018年11月,在Al-Hawizeh沼泽的4个地点收集了季节性的水、沉积物和两种淹没植物——长尾角藻(Ceratophyllum demersum)和马铃薯(Potamogeton pectinatus)样本,评估了几种重金属(Fe、Cu、Ni、Cd、Pb、Cr和Zn)的浓度,并使用火焰原子吸收分光光度计进行了分析。将所有浓度与水生生物的允许限值进行比较。这些发现澄清了金属的含量,如下所示:沉积物、植物、水。沉积物中重金属浓度递减顺序为Fe > Ni > Cd > Cu > Cr > Zn > Pb (mg/kg),植物为Fe > Zn > Cd > Cr > Ni > Pb > Cu (mg/kg干重),水中为Fe > Ni > Zn > Pb > Cr > Cd (mg/L)。所有金属在水中的浓度都没有超过允许的限度,其中Fe、Ni和Pb在水样中的浓度高于其他金属。沉积物中除冬季未检出Cd (ND)外,Fe、Ni、Cd均超过允许限量,Zn、Pb均未超过推荐限量。植物内样品中铁、镉、锌、铬超标,而铜、铅未超标,果木中铁、镉、锌超标,而Ni、Cu、Cr、Pb在本研究期间均未超标。采用Pearson相关法检测金属浓度之间的相互关系。植物与水样与沉积物呈显著正相关(p≤0.05)。
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引用次数: 2
Antioxidant Responses of a Brackish Water Clam to Sediment Composition and Water Quality: a Field Experiment 咸淡水蛤对沉积物组成和水质的抗氧化反应:野外试验
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/jwet.20-137
P. Pokhrel, Hiroki Machida, Shumona Akther, Jumpei Suzuki, M. Fujita
Field experiments were conducted at brackish-water sites (Lake Hinuma, Hinuma River, and Naka River) to investigate oxidative stress responses of a brackish-water clam, Corbicula japonica, to sediment composition and water quality. To ascertain the influence of the sediment composition, clams were subjected to three test sediments with different contents of clay/silt and organic matter from the same site. Sediment with ~33% of clay/silt content and ~10% of ignition loss exhibited decreased oxygen radical absorbance capacity (ORAC) within two weeks (p < 0.05). However, sediment with less than ~20% of clay/silt content and/or ~7% of ignition loss had no influence on ORAC (p > 0.05). To ascertain the influence of the water quality, clams were placed in baskets without sediment at four brackish-water sites. Significant differences in ORAC were observed in response to salinity and chlorophyll a (Chl a) (p < 0.05). Multiple regression analysis indicated that the levels of salinity and water temperature as well as variations in Chl a, dissolved oxygen, and turbidity for 1 d prior to the sampling date affected ORAC. We concluded that natural influencing factors need to be considered in ORAC assays for C. japonica, when anthropogenic impacts are assessed.
在半咸水点(Hinuma湖、Hinuma河和Naka河)进行了野外实验,研究了半咸水蛤蜊Corbicula japonica对沉积物组成和水质的氧化应激反应。为了确定沉积物组成的影响,在同一地点进行了三种不同粘土/粉砂和有机质含量的试验沉积物。粘土/粉土含量为~33%、燃失量为~10%的沉积物在2周内氧自由基吸收能力(ORAC)下降(p < 0.05)。而粘土/粉粒含量低于~20%和/或燃失量为~7%的沉积物对ORAC没有影响(p > 0.05)。为了确定水质的影响,在四个咸淡水地点将蛤蜊放在没有沉淀物的篮子里。ORAC对盐度和叶绿素a (Chl a)的响应差异有统计学意义(p < 0.05)。多元回归分析表明,采样前1 d的盐度、水温、Chl a、溶解氧和浊度变化影响ORAC。我们的结论是,当评估人为影响时,在粳稻的ORAC测定中需要考虑自然影响因素。
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引用次数: 1
Model-based Evaluation of the Effect of Temperature on Electric Power Generation in Microbial Fuel Cells 温度对微生物燃料电池发电影响的模型评价
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/JWET.20-142
Aiichiro Fujinaga, Y. Yamaguchi, N. Kishimoto, S. Taniguchi
To assess the effect of temperature on the electric power generation of a microbial fuel cell (MFC), a series of experiments was conducted across a 5–55°C temperature range. We found that the currents generated were not proportional to the temperature, with the currents at 15 and 45°C higher than those at other temperatures. In order to determine the reason for this, a mathematical model, using a diffusion layer in an MFC, was developed, and analysis of this model suggested that the MFC temperature characteristics were caused by aerobic and anaerobic reactions being lower at 15 and 45°C. Our calculations indicated that the consumption of organic compounds predominantly occurred at specific temperatures and that diffusion of the compounds affected the current. These calculations made it possible to estimate the influence of aerobic and anaerobic reactions on power generation in the MFC within a prescribed temperature range. This work suggests that, using this model, competi tive reactions in electrogenic bacteria could be controlled by setting the correct temperature.
为了评估温度对微生物燃料电池(MFC)发电的影响,在5-55°C的温度范围内进行了一系列实验。我们发现产生的电流与温度不成正比,在15°C和45°C时的电流比其他温度下的电流高。为了确定这一现象的原因,我们利用MFC中的扩散层建立了一个数学模型,对该模型的分析表明,MFC的温度特性是由15°C和45°C时的好氧和厌氧反应较低引起的。我们的计算表明,有机化合物的消耗主要发生在特定温度下,化合物的扩散影响电流。这些计算使得在规定的温度范围内估计好氧和厌氧反应对MFC发电的影响成为可能。这项工作表明,使用该模型,电致细菌中的竞争反应可以通过设置正确的温度来控制。
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引用次数: 1
Impact of Submerged Macrophytes on Behavior of Organic Carbon and Nutrients: An Experimental Study 沉水植物对有机碳和养分行为影响的实验研究
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/JWET.20-088
K. Wada, N. Kishimoto, I. Somiya, Toshihiko Sato, K. Ueno
The aim of this study was to survey the behavior of water quality and surface sediment during the growth period of submerged macrophytes. Their dynamics were investigated by a microcosm experiment. In midsummer, the nitrogen and phosphorus concentration of the column with vegetation (Column A) was kept low and the inorganic nitrogen loading in the first 15 days was about 3 times lower than that of the column without vegetation (Column B). The vegetated column prevented algal blooms in midsummer and was checked to see zooplankton and zoobenthos during the biological active period. The rate of change of masses of carbon and nutrients in the sediment before and after the column experiment were calculated on the basis of the contents of each and sediment thickness (0 to 5 cm). Masses of organic carbon in Column A and Column B in the sediment after 100 days were estimated to decrease by 14 and 23%, respectively. Masses of nitrogen in Column A and Column B in the sediment after 100 days were estimated to decrease by 11 and 26%, respectively. Thus, the mass reduction rate of the vegetated column was 10 to 16% less than that of the column without vegetation.
本研究的目的是调查沉水植物生长期间的水质和地表沉积物的变化。通过微观实验研究了它们的动力学。盛夏有植被柱(A柱)氮磷浓度较低,前15 d无机氮负荷约为无植被柱(B柱)的3倍。盛夏有植被柱防止了藻华,生物活化期检查浮游动物和底栖动物。根据各组分的含量和沉积物厚度(0 ~ 5 cm)计算柱实验前后沉积物中碳和营养物质的质量变化率。100 d后沉积物中A柱和B柱的有机碳质量分别减少了14%和23%。100 d后沉积物中A柱和B柱的氮质量分别下降了11%和26%。因此,植被柱的质量减少率比无植被柱的质量减少率低10 ~ 16%。
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引用次数: 0
Heavy Metals Distribution and Contamination in Groundwater of the South Eastern Coastal Area of Bangladesh 孟加拉东南沿海地区地下水重金属分布及污染
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/jwet.20-169
F. Deeba, Syed Hafizur Rahman, M. Z. Kabir, Nafisa Tamanaya Dina, S. Das, S. Sultana, F. T. Ahmed
Groundwater provides the largest source of usable water storage in Bangladesh. Groundwater samples have been analyzed for Fe, Mn, Zn, Ni, Cr, Cu, Cd, Pb, and Co using atomic absorption spectrophotometer to evaluate the heavy metal distribution and contamination level at the southeastern coastal area of Bangladesh. Heavy metals in water samples are in the range of Fe (490–4710 μg/L), Mn (13–1970 μg/L), Zn (70–550 μg/L), Ni (42–255 μg/L), Cr (25–133 μg/L), Cu (34–95 μg/L), Cd (7–26 μg/L), Pb (0–20 μg/L), and Co (43–141 μg/L). The mean concentration of Cr, Cd, Fe, Mn, and Ni exceeded the Bangladesh standards for drinking water. Application of Pearson correlation, principal component analysis (PCA), cluster analysis (CA) and hierarchical cluster analysis (HCA) indicate that groundwater of the study area are influenced by both geogenic and anthropogenic sources of the heavy metals. Heavy metal evaluation index (HEI), degree of contamination (Cd) and heavy metal pollution index (HPI) are employed to evaluate the overall pollution level of groundwater estimating 40, 27 and 60% of samples respectively and exhibit the medium degree of pollution.
地下水是孟加拉国最大的可用储水来源。利用原子吸收分光光度计对孟加拉国东南沿海地区的地下水样品进行了铁、锰、锌、镍、铬、铜、镉、铅和钴的分析,以评价重金属的分布和污染水平。水样中重金属含量为Fe (490 ~ 4710 μg/L)、Mn (13 ~ 1970 μg/L)、Zn (70 ~ 550 μg/L)、Ni (42 ~ 255 μg/L)、Cr (25 ~ 133 μg/L)、Cu (34 ~ 95 μg/L)、Cd (7 ~ 26 μg/L)、Pb (0 ~ 20 μg/L)、Co (43 ~ 141 μg/L)。铬、镉、铁、锰和镍的平均浓度超过了孟加拉国的饮用水标准。Pearson相关分析、主成分分析(PCA)、聚类分析(CA)和层次聚类分析(HCA)表明,研究区地下水重金属既有地质来源的影响,也有人为来源的影响。采用重金属评价指数(HEI)、污染程度(Cd)和重金属污染指数(HPI)分别评价了40%、27%和60%的样品的地下水总体污染水平,表现为中等污染程度。
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引用次数: 7
Fate Evaluation of CSO-derived PPCPs and Escherichia coli in Tokyo Coastal Area after Rainfall Events by a Three-dimensional Water Quality Model 基于三维水质模型的东京沿海地区降雨后cso衍生PPCPs和大肠杆菌的命运评估
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/jwet.20-139
Chomphunut Poopipattana, H. Furumai
This study developed a fate model of pharmaceuticals and personal care products (PPCPs), including acetaminophen, caffeine, and crotamiton, derived from combined sewer overflow (CSO) in the Tokyo coastal area. The target PPCPs were proposed as promising sewage markers having different persistency during treatment processes and in the environmental water. The PPCP model consists of hydrodynamic calculations and environmental kinetics by biodegradation and photodegradation. We considered inputs from pumping stations, sewage treatment plants, and urban rivers as CSO sources. We measured the PPCPs concentrations, Escherichia coli , and salinity in the collected surface water samples from several locations around Tokyo coastal area for consecutive days after rainfall events in October 2017 (113 mm), June 2018 (81 mm), and July 2018 (67 mm). We found high correspondence between simulation and monitoring results on E. coli and three PPCPs in the coastal locations for all events, suggesting that the model has the potential to quantitatively evaluate CSO-derived con taminants in the Odaiba Seaside Park and nearby locations. Simulation showed that acetaminophen concentration rapidly declined due to its susceptibility to sunlight and biodegradation. Caffeine and E. coli showed different attenuation rates, whereas crotamiton concentration did not change because of its comparable concentration level in CSO. limit of detection, limit of quantification, linearity, and recovery.
本研究建立了东京沿海地区联合下水道溢流(CSO)产生的药品和个人护理产品(PPCPs)的命运模型,包括对乙酰氨基酚、咖啡因和克罗米顿。目标PPCPs是一种很有前途的污水标记物,在处理过程和环境水中具有不同的持久性。PPCP模型由水动力学计算和生物降解和光降解的环境动力学组成。我们考虑了泵站、污水处理厂和城市河流的输入作为CSO来源。我们测量了2017年10月(113毫米)、2018年6月(81毫米)和2018年7月(67毫米)降雨后连续几天从东京沿海地区几个地点收集的地表水样本中的PPCPs浓度、大肠杆菌和盐度。我们发现,在所有事件中,沿海地区大肠杆菌和三种PPCPs的模拟结果与监测结果高度吻合,这表明该模型具有定量评估台场海滨公园和附近地区cso衍生污染物的潜力。模拟结果表明,对乙酰氨基酚对阳光和生物降解的敏感性使其浓度迅速下降。咖啡因和大肠杆菌表现出不同的衰减速率,而crotamiton浓度没有变化,因为其在CSO中的浓度水平相当。检出限、定量限、线性和回收率。
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引用次数: 0
Visualization and Quantification of the Impact of Humic Acid on Zinc Accumulation in Aquatic Plants Using a Low-Molecular-Weight Fluorescent Probe 利用低分子荧光探针可视化和量化腐植酸对水生植物锌积累的影响
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/JWET.20-110
T.A.O.K. Meetiyagoda, K. Fadilah, Masayori Hagimori, M. D. H. J. Senavirathna, T. Fujino
The main aims of this study were to investigate the impact of humic acid (HA) on zinc (Zn) accumulation in aquatic plants and to study a low-molecular-weight Zn2+-selective fluorescent probe to visualize and quantify the tissue-level Zn concentrations. Ceratophyllum demersum and Aldrovanda vesiculosa were exposed to solutions containing Zn (1 and 3 mg/L), HA (0.5 mg/L), and Zn with HA for nine days. The Zn accumulation (mg/g) in the plants was measured by ICP-OES and we applied a Zn2+-selective fluorescent probe with a low molecular weight to the analysis of Zn in C. demersum plant cells using fluorescence microscopy and ImageJ software. The application of HA reduced the Zn accumulation significantly (p < 0.05) and increased the chlorophyll concentration slightly less significantly (p > 0.05) in both plants. Results obtained from ImageJ revealed a strong positive correlation between fluorescence intensity and the Zn accumulation in C. demersum (r = 0.988). We showed that the application of HA reduced the Zn accumulation in both plants, and successfully visualized and quantified that a Zn2+-selective fluorescent probe with a low molecular weight can be applied to the diagnosis of Zn osmosis into a cell or tissue on the basis of fluorescence intensity.
本研究的主要目的是研究腐植酸(HA)对水生植物锌(Zn)积累的影响,并研究一种低分子量Zn2+选择性荧光探针,用于观察和量化组织水平的锌浓度。将长尾角藻(Ceratophyllum demersum)和小木犀草(Aldrovanda vesiculosa)分别暴露于含有Zn(1、3mg /L)、HA (0.5 mg/L)和Zn + HA的溶液中9 d。采用ICP-OES法测定锌在植物体内的积累量(mg/g),并采用低分子量Zn2+选择性荧光探针,利用荧光显微镜和ImageJ软件对金草植物细胞中锌的含量进行分析。施用透明质酸显著降低了两株植物Zn积累量(p < 0.05),提高叶绿素浓度(p < 0.05)。ImageJ分析结果显示,荧光强度与金貂草锌积累量呈正相关(r = 0.988)。我们发现,施用透明质酸降低了两种植物Zn的积累,并成功地可视化和量化了一种低分子量的Zn2+选择性荧光探针,可以根据荧光强度诊断Zn渗透到细胞或组织中。
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引用次数: 0
Mapping Changes of Water Quality Parameters Pattern in Anzali International Wetland Using Remote Sensing 安扎里国际湿地水质参数格局的遥感制图变化
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/JWET.20-114
A. P. Zefrehei, A. Hedayati, M. Fallah
In this study, the environmental monitoring of Anzali international wetland (based on water surface temperature (WST), chlorophyll - a (Chl-a) and transparency (secchi disk depth (SDD)) parameters) using Landsat images in the period 1985–2018 has been studied. Based on the results of zoning maps, in 2018 and 2013, WST fluctuations are higher, with the lowest water temperature observed in 2007. Based on Chl-a, the trend for this parameter is increasing from 1985 to 2018. Also, from 1985 to 2018, we saw a decrease in transparency (SDD), which could indicate an increase in opacity and concentration of suspended and organic particles in the wetland, which was consistent with the results of chlorophyll - a. Graph examination of wetland showed more changes belonged to the central and eastern parts of the wetland. The results of this study indicate that in the Anzali international wetland, comparing the values of the parameters studied, there are not good conditions for water quality and the need for a solution and management policies to improve the condition of this unique ecosystem is necessary more than ever.
利用1985-2018年Landsat影像对安扎里国际湿地进行了基于水面温度(WST)、叶绿素-a (Chl-a)和透明度(secchi disk depth (SDD))参数的环境监测。根据分区图的结果,2018年和2013年,WST波动较大,2007年的水温最低。基于Chl-a,该参数从1985年到2018年呈增加趋势。此外,从1985年到2018年,我们看到了透明度(SDD)的下降,这可能表明湿地中悬浮物和有机颗粒的不透明度和浓度增加,这与叶绿素- a的结果一致。湿地图检验显示,湿地的变化更多地属于湿地的中部和东部。本研究结果表明,在安扎里国际湿地,比较研究参数的值,水质条件不佳,比以往任何时候都更需要解决和管理政策来改善这一独特的生态系统状况。
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引用次数: 2
Potential for Enhanced Degradation and Removal of Various Bisphenols by Interaction between Common Reed (Phragmites australis) and Microorganisms 芦苇与微生物相互作用增强对多种双酚类物质降解和去除的潜力
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/JWET.20-117
R. Shrestha, M. Nakai, D. Inoue, M. Ike
The extensive global use of bisphenols (bisphenol A (BPA) and its analogs) is of serious concern to human health and aquatic ecosystems. Aquatic plants and rhizosphere microorganisms can largely affect the environmental fate of bisphenols. In this study, the association between common reed, which is distributed widely in the aquatic environment, and microorganisms existing in the surrounding area of its roots was studied to illustrate its capabilities and possible mechanisms for the removal of five different bisphenols (BPA, bisphenol F, bisphenol P, bisphenol S, and 4,4ʹ-thiodiphenol). Different experimental systems were prepared in the presence and absence of sterile common reeds and aquatic microorganisms. The effects of common reed and microorganisms on the removal of bisphenols differed across compounds. However, the removal of all the bisphenols tested was clearly accelerated in the co-presence of common reed and microorganisms, which indicated the importance of aquatic plant-microorganism association in enhancing bisphenol removal. The results of this study further revealed the major contribution of the distinct mechanism of removal of each bisphenol by the association between common reed and microorganisms.
双酚类物质(双酚A及其类似物)在全球范围内的广泛使用对人类健康和水生生态系统造成了严重影响。水生植物和根际微生物可以在很大程度上影响双酚的环境命运。本研究研究了广泛分布于水生环境中的芦苇及其根部周围微生物对5种不同双酚(BPA、双酚F、双酚P、双酚S和4,4 α -硫代二酚)的去除能力及其可能机制。在存在和不存在无菌芦苇和水生微生物的情况下制备了不同的实验系统。芦苇和微生物对双酚类化合物的去除效果不同。然而,在芦苇和微生物共同存在的情况下,所有被测试的双酚的去除都明显加快,这表明水生植物-微生物结合在增强双酚去除中的重要性。本研究的结果进一步揭示了芦苇和微生物之间的关系对每种双酚的去除机制的主要贡献。
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引用次数: 2
Microbial Communities and Nitrogen-Utilizing Bacteria of Rotating Biological Contactors and Activated Sludge Treating Public Sewage and Night Soil/Johkasou Sludge 旋转生物接触器和活性污泥处理公共污水和夜间土壤/Johkasou污泥的微生物群落和氮利用细菌
Q3 Environmental Science Pub Date : 2021-01-01 DOI: 10.2965/JWET.20-188
Tsukasa Ito, Y. Yamanashi, Naoki Noguchi, N. Miyazato, T. Aoi
The public sewage (PS) and night soil mixed with johkasou sludge (JO) have similar chemical compositions; however, the concentrations of organic matter and nitrogen compounds were different. We investigated the microbial community of the rotating biological contactor (RBC) units treating PS and JO, in which the RBC was submerged in the mixed liquor of activated sludge. Here, we observed that the microbial community compositions at the phylum and class levels were similar between the PSRBC and JO-RBC, whereas the relative abundances of several phyla (Euryarchaeota, Acidobacteria, Chloroflexi, Firmicutes, Patescibacteria, and Betaproteobacteria) significantly differed between them. The microbial community composition of RBC (an attached growth process) was similar to that of the activated sludge (a suspended growth process). The microbial community of activated sludge likely affected that of RBC. The relative abundance of total denitrifying bacteria in the PS-RBC was twice as much as that in JO-RBC, while nitrifying bacterial phylotypes had a similar relative abundance. The predominant denitrifying genera were different between the PS-RBC and JO-RBC, as well as in the cross-sectional layers of the PS-RBC, suggesting the functional diversity of denitrifying bacterial genera inhabiting the RBC.
公共污水(PS)和混合了污泥(JO)的夜土具有相似的化学成分;但有机质和氮化合物的浓度存在差异。研究了将旋转生物接触器(RBC)浸泡在活性污泥混合液中处理PS和JO的微生物群落。在这里,我们观察到PSRBC和JO-RBC在门和类水平上的微生物群落组成相似,而几个门(Euryarchaeota, Acidobacteria, Chloroflexi, Firmicutes, Patescibacteria和Betaproteobacteria)的相对丰度在它们之间存在显著差异。RBC(附着生长过程)的微生物群落组成与活性污泥(悬浮生长过程)相似。活性污泥的微生物群落可能影响红细胞的微生物群落。PS-RBC中总反硝化细菌的相对丰度是JO-RBC的两倍,而硝化细菌种类的相对丰度相似。在PS-RBC和JO-RBC之间,以及PS-RBC的横截面层中,优势的反硝化细菌属是不同的,这表明栖息在RBC中的反硝化细菌属的功能多样性。
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引用次数: 2
期刊
Journal of Water and Environment Technology
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