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Pore volume and surface diffusion model to characterize batch adsorption of Cu(II) over chemically modified Cucurbita moschata biosorbent: simulation using gPROMS 表征化学修饰葫芦生物吸附剂批量吸附Cu(II)的孔隙体积和表面扩散模型:使用gPROMS模拟
Pub Date : 2022-12-01 DOI: 10.2166/aqua.2022.073
M. Danish, K. B. Ansari, M. Danish, S. Zaidi, M. J. Khalil, R. A. Aftab
This work describes the successful application of the pore volume and surface diffusion (PVSD) model characterizing the batch adsorption of Cu(II) on a chemically modified Cucurbita moschata biosorbent. The PVSD model captures the convective transport of Cu(II) from the bulk solution to the biosorbent surface, followed by its surface and pore diffusion inside the biosorbent. The adsorption of Cu(II) is mimicked using the Langmuir isotherm. The algebraic, ordinary, and partial differential equations, involved in the PVSD model, are solved using the general process modeling system (gPROMS). The model simulation results, depicted by the Cu(II) concentration decay curve, show an excellent match with experimental data. The external mass transfer coefficient (≈10−3 m/s) indicated no restriction on approaching Cu(II) toward the biosorbent surface. Within the biosorbent, surface diffusion was dominant over pore volume diffusion. The statistical analysis of the PVSD model results has been done by calculating R2, Chi-square value, normalized standard deviation, p-value, and root-mean-square error. The PVSD model approach presented in this work could be beneficial to other heavy metal–biosorbent systems.
本文描述了孔隙体积和表面扩散(PVSD)模型在化学改性南瓜生物吸附剂上的成功应用。PVSD模型捕获了Cu(II)从体溶液到生物吸附剂表面的对流传输,然后是其在生物吸附剂内部的表面和孔扩散。用Langmuir等温线模拟了Cu(II)的吸附。利用通用过程建模系统(gPROMS)求解了PVSD模型中涉及的代数方程、常微分方程和偏微分方程。模型模拟结果表明,Cu(II)浓度衰减曲线与实验数据吻合良好。外传质系数(≈10−3 m/s)表明Cu(II)接近生物吸附剂表面没有限制。在生物吸附剂中,表面扩散比孔体积扩散占优势。通过计算R2、卡方值、标准化标准差、p值和均方根误差对PVSD模型结果进行统计分析。本文提出的PVSD模型方法可用于其他重金属生物吸附系统。
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引用次数: 1
The role of chloramines in enhancing soluble manganese removal by manganese contactors by W.R. Knocke, A.M. Weber, P.H. Hargette and E. Odom 氯胺在促进锰接触器去除可溶性锰中的作用韦伯,P.H.哈格特和e.o Odom
Pub Date : 2022-12-01 DOI: 10.2166/aqua.2022.143
W. Knocke, Adrianna M. Weber, Paul H. Hargette, Eric Odom
Manganese (Mn) contactors have previously been shown to be quite effective in removing dissolved Mn from drinking water. To date, the contactor media have been regenerated by the application of free chlorine, either continuously in the contactor-applied water or via offline regeneration. This research study was the first to evaluate the potential role of chloramines for the online regeneration of MnOx(s)-coated contactor media. Testing initially at the bench scale and then subsequently over 6 months at the pilot scale demonstrated that chloramines were quite effective at promoting significant media regeneration. Pilot-scale data showed that the presence of chloramines addressed approximately 80% of the media regeneration requirements, allowing for the addition of free chlorine following media backwashing to address the remaining oxidant needs for media regeneration. Hydraulic loading rates of up to 39 m/hr (16 gpm/ft2) could be employed and still produce highly effective Mn removal. The means by which these research results can be applied to other water treatment situations are also discussed.
锰(Mn)接触器先前已被证明在去除饮用水中溶解的锰方面非常有效。迄今为止,接触器介质已经通过游离氯的应用进行再生,或者在接触器使用的水中连续使用,或者通过离线再生。这项研究首次评估了氯胺在MnOx涂层接触器介质在线再生中的潜在作用。最初在实验规模上进行测试,随后在中试规模上进行了6个多月的测试,结果表明氯胺在促进培养基再生方面非常有效。中试数据表明,氯胺的存在解决了大约80%的介质再生要求,允许在介质反洗后添加游离氯,以解决剩余的氧化剂对介质再生的需求。水力加载速率高达39米/小时(16 gpm/ft2),仍然可以产生高效的Mn去除效果。本文还讨论了将这些研究结果应用于其他水处理的方法。
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引用次数: 0
Orange peel activated carbon produced from waste orange peels for adsorption of methyl red 利用废桔皮制备桔皮活性炭吸附甲基红
Pub Date : 2022-11-26 DOI: 10.2166/aqua.2022.119
S. Deshmukh, Niraj S. Topare, S. Raut-Jadhav, P. Thorat, Shantini A. Bokil, Anish Khan
The existence of pollutants in the water is a very significant environmental problem that needs to be addressed. This work describes the development and testing of activated carbon made from orange peels, which is effective at removing methyl red (MR) from aqueous solutions, and thus provides a solution to this problem. Adsorbents made in the lab can be characterized by their bulk density, particle size, surface area, and proximate analysis. The surface area of the prepared adsorbent was 512.2 m2g−1. Standard procedures such as XRD, SEM, and FTIR analysis are also used to characterize prepared orange peel-activated carbon. Adsorbent dosage (0.25 to 1.25 g/L), MR concentration (100 to 400 mg/L), temperature (40 to 60 °C), contact time (10 to 60 minutes), and pH (3 to 11) were all examined in this experiment. At an amount of adsorbent of 1 g/L adsorbent, MR concentration of 100 mg/L, and a pH of 11, maximum adsorption has been observed. In order to analyze the results, adsorption models such as the Langmuir and Freundlich were applied. At 60 °C, the adsorption isotherm was found to fit the Langmuir model with 111.11 mg/g. The linear regression correlation coefficient, the R2 value is 0.999. Analytical results showed that MR could be effectively removed by using AC made from waste orange peels as an adsorbent.
水中污染物的存在是一个非常重要的环境问题,需要解决。这项工作描述了由橘子皮制成的活性炭的开发和测试,它可以有效地从水溶液中去除甲基红(MR),从而为这一问题提供了解决方案。在实验室制造的吸附剂可以用它们的体积密度、粒度、表面积和近似分析来表征。制备的吸附剂的表面积为512.2 m2g−1。标准程序,如XRD, SEM和FTIR分析也用于表征制备的橘子皮活性炭。考察吸附剂用量(0.25 ~ 1.25 g/L)、MR浓度(100 ~ 400 mg/L)、温度(40 ~ 60℃)、接触时间(10 ~ 60分钟)、pH(3 ~ 11)。吸附剂用量为1 g/L, MR浓度为100 mg/L, pH为11时,吸附量最大。为了分析结果,采用了Langmuir和Freundlich吸附模型。在60℃时,吸附等温线符合Langmuir模型,为111.11 mg/g。线性回归相关系数,R2值为0.999。分析结果表明,用废桔皮制成的AC作为吸附剂,可以有效地去除MR。
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引用次数: 2
Limnoperna fortunei as an invasive biofouling bivalve species in freshwater: a review of its occurrence, biological traits, risks, and control strategies 淡水中入侵生物污染双壳类动物——褐藻的发生、生物学特性、风险及控制策略
Pub Date : 2022-11-26 DOI: 10.2166/aqua.2022.238
Ruihua Zhang, Yunhui Zhang, Xiali Fei, Yingna Hou, Jun Shi, Enchao Li, W. Chu
Concerns have been raised about the significant biofouling and environmental problems caused by the large numbers of Limnoperna fortunei clinging to water intake facilities. This review first provides a summary of the occurrence of L. fortunei in typical regions including China, South America, and Japan. Furthermore, this article provides a comprehensive overview of the biological traits, risks, and control of L. fortunei. Importantly, the planktonic larval stage is a critical period for the expansion of L. fortunei. Its biofouling process mainly relies on the adhesion of byssus to substrates. Various physical and chemical methods have been proposed and used to control L. fortunei. Among these methods, sodium hypochlorite has been shown to be effective in preventing the adhesion of L. fortunei by dissolving its byssus at much lower concentrations. Overall, effective and environmental-friendly antifouling strategies are still rare, particularly in drinking water treatment systems, and are encouraged to develop in future studies. This review not only provides a comprehensive understanding of L. fortunei but also helps to guide the prevention and control of L. fortunei.
人们对大量的褐藻附着在取水设施上造成的严重的生物污染和环境问题表示担忧。本文首先对其在中国、南美、日本等典型地区的分布进行了综述。此外,本文还对该病害的生物学特性、危害及防治进行了综述。重要的是,浮游幼虫期是沙蚕扩张的关键时期。其生物污染过程主要依赖于足丝对基质的粘附。各种物理和化学方法已被提出和应用。在这些方法中,次氯酸钠已被证明是有效的防止粘连l.f fortunei溶解其足在低浓度。总的来说,有效和环境友好的防污策略仍然很少,特别是在饮用水处理系统中,鼓励在未来的研究中发展。这一综述不仅有助于全面了解褐飞虱,而且有助于指导褐飞虱的防治。
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引用次数: 0
A study on villages of the planning of water infrastructure planning: 25 villages in Shaanxi Province as an example 村庄水利基础设施规划研究——以陕西省25个村庄为例
Pub Date : 2022-11-18 DOI: 10.2166/aqua.2022.037
Jing Li, R. Yu
This thesis provides a water infrastructure planning strategy based on an analysis and evaluation of the present situation, which more effectively integrates the current scenario of rural development while adjusting to the trend of population development and resource allocation in rural China. In the north-central area of Shaanxi Province, 25 villages were chosen for field study in order to get a comprehensive grasp of the population and land-use conditions. The size and population of the area needing sewage and drainage infrastructure are estimated by the projection of rural population decline and the projection of rural building land scale and land-use adjustment. On this basis, sewage and drainage facilities are subsequently planned, including the contents of a three-compartment septic tank, sedimentation tank, sewage network, and ecological treatment tank. This type of water infrastructure design may not only enhance the living environment of the region but also efficiently address the issues of water collection and agricultural irrigation in the desert tablelands, enabling the efficient use of resources and sustainable growth of the community.
本文在分析和评价现状的基础上,提出了一种更有效地结合农村发展现状,同时适应中国农村人口发展和资源配置趋势的水利基础设施规划策略。选取陕西省中北部地区25个村庄进行实地调查,以全面掌握人口和土地利用状况。通过农村人口下降预测、农村建设用地规模预测和土地利用调整预测,估算出污水排水基础设施建设需要区域的规模和人口。在此基础上,随后规划污水和排水设施,包括三室化粪池、沉淀池、污水管网和生态处理池的内容。这种类型的水利基础设施设计不仅可以改善该地区的生活环境,还可以有效地解决沙漠高原的集水和农业灌溉问题,使资源的有效利用和社区的可持续发展成为可能。
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引用次数: 1
Review of hydraulic modelling approaches for intermittent water supply systems 间歇供水系统水力建模方法综述
Pub Date : 2022-11-16 DOI: 10.2166/aqua.2022.028
Dondu Sarisen, Vasilis Koukoravas, R. Farmani, Z. Kapelan, F. Memon
Intermittent water supply (IWS) is widely used around the world, and with the increase in population and predicted future water scarcity, IWS applications seem to continue. While most of the existing studies on water supply concentrate on continuous water supply (CWS), the research focused on the IWS is now becoming mainstream. Hydraulic modelling is an effective tool for the process of planning, design, rehabilitation, and operation of water distribution systems. It helps significantly in engineers’ decision-making process. The necessity of modelling IWS systems arises from the complexity and variety of problems caused by intermittency. This paper offers a review of the state-of-the-art IWS modelling and identifies the key strengths and limitations of the available approaches, and points at potential research directions. Currently, neither computer software nor a practically used approach is available for modelling IWS. For a rigorous simulation of IWS, system characteristics first need to be understood, i.e., the user behaviour under pressure-deficient conditions, water losses, and filling and emptying processes. Each of them requires further attention and improvement. Additionally, the necessity of real data from IWSs is stressed. Accurate modelling will lead to the development of improved measures for the problems caused by intermittency.
间歇性供水(IWS)在世界范围内得到了广泛的应用,随着人口的增加和对未来水资源短缺的预测,IWS的应用似乎还会继续。现有的供水研究大多集中在连续供水(CWS)上,而对连续供水(IWS)的研究正在成为主流。水力建模是给水系统规划、设计、修复和运行过程中的有效工具。它对工程师的决策过程有重要的帮助。对IWS系统进行建模的必要性源于间歇性引起的问题的复杂性和多样性。本文回顾了最先进的IWS建模,并确定了可用方法的主要优势和局限性,并指出了潜在的研究方向。目前,既没有计算机软件,也没有实际使用的方法来模拟IWS。对于IWS的严格模拟,首先需要了解系统特性,即在压力不足条件下的用户行为,水损失以及填充和排空过程。每一个都需要进一步的关注和改进。此外,还强调了来自IWSs的真实数据的必要性。准确的建模将导致改进措施的发展,以解决由间歇性引起的问题。
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引用次数: 5
Water quality assessment of open wells in Malappuram district, Kerala 喀拉拉邦马拉普兰地区露天水井水质评价
Pub Date : 2022-11-16 DOI: 10.2166/aqua.2022.095
A. K. Sajeesh, Ajmal Koya Pulikkal
Most of the open well water is of low pH and polluted by an excess of turbidity, acidity, and iron in the district of Malappuram, Kerala, India. In this work, water samples were collected in a random manner from 15 blocks of Malappuram in between the post- and pre-monsoon seasons and studied their quality using standard analytical procedures. Based on the experimental analysis, various physicochemical characteristics, namely turbidity, temperature, pH, total dissolved solids, total alkalinity, and iron have been evaluated. It is found that all samples under investigation were of low pH and some samples were contaminated by turbidity, acidity, and iron. However, total dissolved solids and total alkalinity are within the desirable limit in all samples. Samples having excess turbidity and iron show a reddish brown color and it can cause coloration and stain to sanitary fittings, clothes, etc. Excess iron also causes an unpalatable metallic taste to the drinking water.
在印度喀拉拉邦马拉普兰地区,大多数露天井水pH值低,被过量的浑浊、酸性和铁污染。在这项工作中,在季风季节前后,从马拉普兰的15个街区随机收集了水样,并使用标准分析程序研究了它们的质量。在实验分析的基础上,评估了各种理化特性,即浊度、温度、pH、总溶解固形物、总碱度和铁。调查发现,所有样品的pH值都很低,有些样品被浊度、酸性和铁污染。然而,所有样品的总溶解固形物和总碱度都在理想的限度内。含有过量浑浊和铁的样品呈红棕色,会使卫生用品、衣服等变色和染色。过量的铁还会给饮用水带来难闻的金属味。
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引用次数: 0
Research on pipe burst in water distribution systems: knowledge structure and emerging trends 配水系统爆管研究:知识结构与发展趋势
Pub Date : 2022-11-16 DOI: 10.2166/aqua.2022.150
Chenwan Wang, Qiang Xu, Yanchun Zhou, Z. Qiang
Pipe bursts in water distribution systems (WDSs) lead to large water losses, pollution risks, and public discontent, attracting widespread attention from researchers and water utilities around the world. This study provides insights into the knowledge structure and emerging trends of pipe burst research from a bibliometrics perspective. We used 845 original research and review articles on pipe bursts in the period of January 1991 − June 2022 that cited 16,813 references in the CiteSpace® software for reference co-citation analysis. The results indicate that the knowledge structure of pipe burst research is classified into four categories including pipe burst mechanism, pipe burst detection, pipe burst prediction, and use of sensors. The entire research on pipe bursts advances remarkably. First, pipe burst prediction is the core research category with continuous efforts to improve prediction performance. Second, pipe burst detection is likely to define new research focus to extend existing research focus on pipe burst prediction. Third, computer science and technology are widely and increasingly applied in burst process simulation and data pattern analysis to increase accuracy and effectiveness. This study grasps a full view of current achievements in pipe burst research and provides guidance for future research directions and technological development.
配水系统爆管事故造成了大量的水损失、污染风险和公众不满,引起了世界各地研究人员和水务公司的广泛关注。本研究从文献计量学的角度对管爆研究的知识结构和新兴趋势进行了深入的了解。我们使用了1991年1月至2022年6月期间的845篇关于管道爆裂的原创研究和评论文章,在CiteSpace®软件中引用了16,813篇参考文献进行文献共被引分析。结果表明,爆管研究的知识结构可分为爆管机理、爆管检测、爆管预测和传感器应用四大类。整个爆管研究取得了显著进展。首先,爆管预测是核心研究范畴,预测性能不断提高。其次,爆管检测有可能定义新的研究热点,扩展现有爆管预测的研究热点。第三,计算机科学技术在突发过程模拟和数据模式分析中的应用越来越广泛,以提高准确性和有效性。本研究全面把握了当前爆管研究成果,为今后的研究方向和技术发展提供了指导。
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引用次数: 1
Impact of intermittent supply on water meter accuracy 断续供水对水表精度的影响
Pub Date : 2022-11-02 DOI: 10.2166/aqua.2022.091
M. Ferrante, D. Rogers, J. Mugabi, Francesco Casinini
Supply interruptions are a common occurrence in water systems and are particularly prevalent in developing countries. During the system filling, the air that entered into the pipes when the supply was closed is expelled through any fissures including service pipes. When a meter is installed, the airflow can cause inaccuracies, over-reading, and reliability issues. This paper investigates experimentally the impact of the airflow on water meter performance during filling by means of a laboratory set-up, using pipes with diameters comparable to those of a real water system. The impact of the airflow on the accuracy and reliability of the water meters is discussed and the potential for over-reading is estimated.
供水中断是供水系统的常见现象,在发展中国家尤其普遍。在系统充注过程中,当供气关闭时进入管道的空气通过包括服务管道在内的任何裂缝排出。安装仪表时,气流可能会导致不准确、读数过高和可靠性问题。本文通过实验室装置,采用与实际供水系统直径相当的管道,实验研究了充注过程中气流对水表性能的影响。讨论了气流对水表精度和可靠性的影响,并估计了超读的可能性。
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引用次数: 4
Comparison of bankruptcy methods in the operation management of the Karkheh River Basin to allocate more water to the Hawr-Al-Azim Wetland Karkheh河流域向haur - al - azim湿地增水运行管理中的破产方法比较
Pub Date : 2022-10-25 DOI: 10.2166/aqua.2022.126
Nima Pournabi, S. Janatrostami, A. Ashrafzadeh, K. Mohammadi
Bankruptcy methods are straightforward practical methods to address the problem of allocating limited sources of water to different users in regions where claims exceed assets. In the present study, three levels of restoration for the Hawr-Al-Azim wetland (35, 50, and 100%) and two agricultural-related scenarios, maintaining the current cultivation area and decreasing the area under cultivation, were considered and assessed using classical bankruptcy methods. The results showed that, because of climatic conditions and agricultural demands, full wetland restoration was out of reach and led to minimum satisfaction levels for agricultural beneficiaries. The results also showed that the modified bankruptcy method led to the highest satisfaction levels for beneficiaries in the scenario of maintaining the current cultivation area. In addition, the percentage of the water supply was increased by applying the scenario of crop restriction in the conditions of the full restoration of the wetland; for example, in the Abbas Plain region, this increase was achieved by almost 10–15% in all methods. On the other hand, decreasing the area under cultivation shifted the allocation problem in the basin to a non-bankruptcy one.
破产法是一种直截了当的实用方法,用于解决在索取权超过资产的地区将有限的水源分配给不同用户的问题。本研究采用经典破产方法,对haur - al- azim湿地的3种恢复水平(35%、50%和100%)和2种与农业相关的情景(维持现有耕地面积和减少耕地面积)进行了考虑和评估。结果表明,由于气候条件和农业需求的原因,完全恢复湿地是遥不可及的,导致农业受益人的满意度最低。结果还显示,在维持现有种植面积的情况下,改良破产方式的受益人满意度最高。此外,在湿地全面恢复的条件下,采用作物限制情景,增加了供水量的百分比;例如,在阿巴斯平原地区,所有方法都实现了近10-15%的增长。另一方面,减少耕地面积使流域分配问题转向非破产问题。
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引用次数: 0
期刊
Journal of Water Supply: Research and Technology-Aqua
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