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Coal Particle Devolatilization and Soot Formation in Pulverized Coal Combustion Fields 煤粉燃烧场中煤颗粒的脱挥发与煤烟的形成
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2021-01-10 DOI: 10.14356/kona.2021003
Nozomu Hashimoto, J. Hayashi
In this paper, recent developments of the devolatilization model and soot-formation model for the numerical simulations of pulverized-coal combustion fields, and the technology used to measure soot particles in pulverized-coal combustion fields are reviewed. For the development of new models, the validation of the developed models using measurement is necessary to check the accuracy of the models because new models without validation have a possibility to make large errors in simulations. We have developed the tabulated devolatilization process model (TDP model) that can take into account the effect of particle heating rate on the volatile matter amount and the devolatilization-rate parameters. The accuracy of the developed TDP model was validated by using the laser Doppler velocimetry data for the bench-scale coal combustion test furnace. The soot-formation model combined with TDP model for the large eddy simulation (LES) has been also developed. The spatial distributions of both the soot-volume fraction and the polycyclic aromatic hydrocarbons were measured by virtue of laser-induced incandescence (LII) and laser-induced chemiluminescence (PAHs-LIF). The accuracy of the developed soot-formation model was validated by using the measured data.
本文综述了用于煤粉燃烧场数值模拟的脱挥发模型和烟尘形成模型的研究进展,以及煤粉燃烧场烟尘颗粒测量技术的研究进展。对于新模型的开发,由于未经验证的新模型有可能在模拟中产生较大的误差,因此必须使用测量对已开发的模型进行验证,以检查模型的准确性。建立了考虑颗粒加热速率对挥发物量和脱挥发速率参数影响的表化脱挥发过程模型(TDP模型)。利用煤燃烧试验炉的激光多普勒测速数据,验证了所建立的TDP模型的准确性。提出了结合TDP模型的大涡模拟烟尘形成模型。利用激光诱导白炽灯(LII)和激光诱导化学发光(PAHs-LIF)测量了煤烟体积分数和多环芳烃的空间分布。利用实测数据验证了所建立的煤烟形成模型的准确性。
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引用次数: 3
Agglomeration and Dispersion Related to Particle Charging in Electric Fields 电场中粒子带电的凝聚与色散
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2021-01-10 DOI: 10.14356/kona.2021016
M. Shoyama, S. Matsusaka
Electrostatic forces cause spontaneous movement of charged particles; subsequently, electrostatic technology is attracting attention because of its application in powder handling processes, such as separation, classification, dispersion, and collection. Dielectric and conductive particles are charged by induction in a strong electric field and moved by Coulomb forces. The magnitude and polarity of the transferred charges are controlled by the strength and direction of the electric field. The dielectric particles are also polarized in the electric field, and dipole interactions occur between particles or in the particle layers, complicating the particle behavior. This review paper presents induction charging, agglomeration, levitation, and other behaviors resulting from particle layers in electric fields. A series of particle phenomena occur in parallel electrode systems, which consist of a lower plate electrode and an upper mesh electrode. Charged agglomerates are formed on the particle layers, levitated by the Coulomb forces, and disintegrated with rotation when approaching the mesh electrode. The mechanisms of agglomeration and disintegration have been elucidated in multiple studies, including microscopic observations and theoretical analyses of particle motion, based on numerical calculations of the electric field. Furthermore, a new system is proposed for continuous feeding of dispersed particles using electric fields and vibration.
静电力引起带电粒子的自发运动;随后,静电技术因其在分离、分类、分散、收集等粉体处理过程中的应用而备受关注。电介质和导电粒子在强电场中通过感应带电,并在库仑力的作用下运动。转移电荷的大小和极性由电场的强度和方向控制。电介质粒子在电场中也被极化,粒子之间或粒子层中发生偶极相互作用,使粒子行为复杂化。本文综述了电场中粒子层引起的感应充电、团聚、悬浮等行为。在由下平板电极和上网状电极组成的平行电极系统中,会发生一系列的粒子现象。带电团块在粒子层上形成,在库仑力作用下悬浮,并在接近网状电极时随旋转崩解。在电场数值计算的基础上,通过微观观察和粒子运动的理论分析,阐明了团聚和解体的机理。此外,提出了一种利用电场和振动对分散颗粒进行连续喂料的新系统。
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引用次数: 6
Screening of Ternary Intermetallic Catalysts Is Possible Using Metallurgical Synthesis: Demonstration on Heusler Alloys 利用冶金合成技术筛选三元金属间催化剂是可能的:以Heusler合金为例
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2021-01-10 DOI: 10.14356/kona.2021008
T. Kojima, S. Kameoka, A. Tsai
Intermetallic compounds are becoming hot materials as catalysts because they show unique catalytic properties that originate from a unique electronic structure and an atomic ordered surface. Ternary intermetallic catalysts have rarely been reported, which is likely due to the difficulty in synthesizing their supported nanoparticles, the typical form for catalysis research; however, there could be novel catalysts in ternary systems because they have much more elemental combinations than binary systems. They are expected to exhibit novel properties due to the synergy between three elements. Metallurgical methods, such as arc-melting, can easily synthesize intermetallic compounds even in ternary (or more) systems if they are thermodynamically stable. Thus, only metallurgical synthesis enables screening for ternary intermetallic catalysts. The catalyst screening of Heusler alloys, which are a group of ternary intermetallic compounds popular in other research fields, such as magnetics, has been conducted using metallurgical synthesis. The screening revealed fundamental catalytic properties of Heusler alloys for several reactions and identified good catalysts for the selective hydrogenation of alkynes. The systematic control of catalysis was also demonstrated by the substitution of fourth elements using a feature of Heusler alloys. This paper describes the importance of ternary intermetallic catalysts with practical examples of Heusler alloy catalysts and discusses future prospects.
金属间化合物由于其独特的电子结构和原子有序的表面表现出独特的催化性能,正成为热门的催化剂材料。三元金属间催化剂很少被报道,这可能是由于其载体纳米颗粒的合成困难,而纳米颗粒是催化研究的典型形式;然而,三元体系中可能会有新的催化剂,因为它们比二元体系有更多的元素组合。由于三种元素之间的协同作用,它们有望表现出新的特性。冶金方法,如电弧熔炼,可以很容易地合成金属间化合物,甚至在三元(或更多)体系中,如果它们是热力学稳定的。因此,只有冶金合成才能筛选三元金属间催化剂。Heusler合金是一类广泛应用于其他研究领域的三元金属间化合物,其催化剂筛选采用了冶金合成方法。通过筛选,揭示了Heusler合金对几种反应的基本催化性能,并确定了炔选择性加氢的良好催化剂。利用Heusler合金的特征取代第四元素也证明了催化的系统控制。本文结合Heusler合金催化剂的实例,阐述了三元金属间催化剂的重要性,并对其发展前景进行了展望。
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引用次数: 6
From Quasi-static to Intermediate Regimes in Shear Cell Devices: Theory and Characterisation 剪切细胞装置从准静态到中间状态:理论和表征
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2021-01-10 DOI: 10.14356/KONA.2021018
Victor Francia, L. A. A. Yahia, R. Ocone, A. Ozel
The design of new technology for processing and manufacturing particulate products requires understanding granular rheology over a broad range of conditions. Powders display a complex behaviour due to their ability to rearrange under stress, and as a result, granular flow is generally classified into three flow regimes, namely a quasi-static regime dominated by frictional contacts, an inertial regime dominated by collisional and kinematic stresses and an intermediate regime where the three sources of stress are important to establish a stress-strain rate relationship. Characterisation of the flowability is generally restricted to the flow initiation in quasi-static regime, even if, transition into inertial conditions is very common in practical applications involving the control of dense flows, such as powder handling, particle formation processes or additive manufacturing. This work presents a critical review of available techniques to characterise the departure from the quasi-static regime into an intermediate flow. We revise the application of shear cells and present different strategies to modify classic devices with external actuation, such as aeration, to operate at higher inertial numbers. We pay particular attention to innovative designs using aerated Couette flow configurations, highlight the complexity in the standardisation and the challenges in advancing towards a universal model.
设计用于加工和制造颗粒产品的新技术需要在广泛的条件下了解颗粒流变学。粉末由于其在应力下重新排列的能力而表现出复杂的行为,因此,颗粒流动通常分为三种流动状态,即由摩擦接触主导的准静态状态,由碰撞和运动应力主导的惯性状态,以及三种应力源对建立应力-应变率关系很重要的中间状态。流动性的特征通常局限于准静态状态下的流动起始,即使在涉及密集流动控制的实际应用中,例如粉末处理、颗粒形成过程或增材制造,过渡到惯性条件非常常见。这项工作提出了一个关键的审查现有的技术,以表征从准静态状态到中间流动的离开。我们修改了剪切单元的应用,并提出了不同的策略来修改具有外部驱动的经典装置,如曝气,以在更高的惯性数下运行。我们特别关注采用充气库埃特流配置的创新设计,强调标准化的复杂性和向通用模型推进的挑战。
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引用次数: 8
The Properties of Kaolin from Different Locations and Their Impact on Casting Rate 不同产地高岭土的性能及其对浇注率的影响
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2021-01-10 DOI: 10.14356/kona.2021002
Mervat Said Hassan Badr, S. Yuan, Jiaqi Dong, H. El-Shall, Yamile A. Bermudez, D. C. Ortega, Jorge E. Lopez-Rendon, B. Moudgil
It has been well known that mineral samples from different locations and origins can exhibit a significant shift in their properties and behavior. The present study of three samples of kaolin from a wide set of origin of deposits, composition, and ceramic properties, provided an important and perhaps a unique opportunity for investigating the interdependence of mineralogy, chemical composition, particle morphology, and surface property with their rheological behavior in ceramic applications such as casting rate. The X-ray diffraction patterns of kaolin samples #2 and #3 suggested low crystallinity with Hinckley Index (HI) ranging between 0.78 and 0.8. On the other hand, kaolin sample #1 was highly ordered with HI of about 1.21, and it had higher quartz content. This free quartz could enhance the permeability and hence increase the casting rate. The abundance of divalent ions (Ca 2+ and Mg 2+ ) in samples #2 & #3 could result in the collapse of the electrical double layer and reduction of zeta potential, consequently, coagulation of the particles leading to an increase of viscosity and dispersant demands. The morphology study suggested the platelet particles in samples #2 & #3 would lead to slower dewatering, thus, lower casting rate than that of the blocky (lower aspect ratio and narrower size distribution) particles in sample #1.
众所周知,来自不同地点和产地的矿物样品在其性质和行为上可以表现出显著的变化。目前对三种高岭土样品的研究,从沉积物的起源、组成和陶瓷性能等方面进行了广泛的研究,为研究矿物学、化学组成、颗粒形态和表面性能与其在陶瓷应用中的流变行为(如铸造速率)之间的相互关系提供了重要的,也许是独特的机会。高岭土样品#2和#3的x射线衍射图显示结晶度较低,欣克利指数(Hinckley Index, HI)在0.78 ~ 0.8之间。另一方面,高岭土1号样品有序度高,HI约为1.21,石英含量较高。游离石英可以提高透气性,从而提高浇注速度。样品#2和#3中丰富的二价离子(ca2 +和mg2 +)可能导致双电层坍塌和zeta电位降低,因此,颗粒的凝固导致粘度和分散剂需求的增加。形态学研究表明,样品#2和#3中的血小板颗粒会导致脱水较慢,因此铸造速率低于样品#1中的块状颗粒(宽高比较低,尺寸分布较窄)。
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引用次数: 2
Smart Powder Processing for Excellent Advanced Materials and Its Applications 优质先进材料的智能粉末加工及其应用
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2021-01-01 DOI: 10.14356/kona.2023001
M. Naito, T. Kozawa, A. Kondo, C.C. Huang
To create advanced materials with minimal energy consumption and environmental impacts, a green and sustainable powder processing technology is essential. The authors have developed this technique based on powder grinding technology. In this paper, the authors will explain the recent progress of the smart powder processing, and its applications. Firstly, particle bonding process, and novel one-pot processing methods to synthesize nanoparticles, to create nanostructured composite granules and to form nano-porous films on substrates in dry phase will be discussed. Their applications on the advanced material fabrications contributing to the sustainable economy will also be explained. Then, the use of grinding technology in wet processing to synthesize nanoparticles and control their morphology will be explained. Smart powder processing can be a foundation to move forward material development technologies and create many more high-quality advanced materials in the future.
为了以最小的能源消耗和环境影响创造先进的材料,绿色和可持续的粉末加工技术是必不可少的。作者在粉末研磨技术的基础上发展了该技术。本文将介绍智能粉体加工的最新进展及其应用。首先,将讨论颗粒键合工艺,以及在干相衬底上合成纳米颗粒、制备纳米结构复合颗粒和形成纳米多孔膜的新型一锅加工方法。它们在先进材料制造中的应用有助于可持续经济的发展。然后,将解释在湿法加工中使用研磨技术合成纳米颗粒并控制其形貌。智能粉末加工可以成为推动材料开发技术的基础,并在未来创造出更多高质量的先进材料。
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引用次数: 2
Influence of Anions and Cations on the Formation of Iron Oxide Nanoparticles in Aqueous Media 阴离子和阳离子对水介质中氧化铁纳米颗粒形成的影响
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2020-11-28 DOI: 10.14356/kona.2022003
Hidekazu Tanaka
Recently, various types of functionalized metal oxide nanoparticles have been used for many applications because of their unique chemical and physical properties. To synthesize metal oxide nanoparticles, liquid-phase synthesis techniques have been developed. The production process of metal oxide nanoparticles in aqueous media is extremely complex because the formation, crystal structure, crystallinity, chemical composition, and morphology of the particles are considerably dependent on the preparation conditions (e.g., anion and cation concentrations and species, additives, solution pH, and reaction temperature and time). Accordingly, clarifying these effects is fundamental to accurately understand the formation mechanism of metal oxide nanoparticles to further develop new functionalized nanoparticles. In this review, the influence of anions (Cl – , SO 42– , and NO 3– ) and cations (Ni 2+ , Cu 2+ , and Cr 3+ ) on the formation and structure of iron oxide nanoparticles in aqueous media is described.
近年来,各种功能化金属氧化物纳米颗粒由于其独特的化学和物理性质而得到了广泛的应用。为了合成金属氧化物纳米颗粒,液相合成技术得到了发展。水介质中金属氧化物纳米颗粒的生产过程极其复杂,因为颗粒的形成、晶体结构、结晶度、化学组成和形态在很大程度上取决于制备条件(例如阴离子和阳离子的浓度和种类、添加剂、溶液pH、反应温度和时间)。因此,阐明这些效应是准确理解金属氧化物纳米颗粒形成机制的基础,是进一步开发新型功能化纳米颗粒的基础。本文综述了阴离子(Cl -、so42 -和no3 -)和阳离子(ni2 +、cu2 +和cr3 +)对水介质中氧化铁纳米颗粒形成和结构的影响。
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引用次数: 1
Synthesis of Noble Metals and Their Alloy Nanoparticles by Laser-induced Nucleation in a Highly Intense Laser Field 高强度激光场激光诱导成核合成贵金属及其合金纳米颗粒
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2020-10-17 DOI: 10.14356/kona.2022002
Takahiro Nakamura, Yuki Yamazaki, S. Sato
The synthesis of noble metals and their alloy nanoparticles by laser-induced nucleation is described. Femtosecond laser pulses with an energy on the order of mJ were tightly focused to create an intensity of 10 14 W/cm 2 or more in an aqueous solution of noble metal ions. The intense laser field generated solvated electrons and hydrogen radicals that have a highly reducing ability, resulting in nucleation through the reduction of the noble metal ions and particle growth through ripening. This laser-induced nucleation method can be performed without any reducing agents. Excess irradiation of chloroauric acid solution led to the formation of a stable colloidal solution of gold nanoparticles without any surfactants. Additionally, the irradiation of a mixed solution of different noble metal ions formed solid–solution alloy nanoparticles, even though these metals were immiscible in the bulk. Moreover, the laser-induced nucleation made it possible to form quinary solid-solution alloy nanoparticles of noble metals. The mechanism of superior catalytic activity found for alloy nanoparticles by using Rh–Pd–Pt solid–solution nanoparticles is discussed in terms of elemental distributions inside the particles.
介绍了激光诱导成核法制备贵金属及其合金纳米颗粒的方法。能量在mJ量级的飞秒激光脉冲在贵金属离子水溶液中被紧密聚焦,产生了10 14 W/ cm2或更高的强度。强烈的激光场产生具有高度还原能力的溶剂化电子和氢自由基,使贵金属离子还原成核,使颗粒成熟生长。这种激光诱导成核方法无需任何还原剂即可进行。氯金酸溶液的过量辐照导致了金纳米颗粒在没有任何表面活性剂的情况下形成稳定的胶体溶液。此外,不同贵金属离子的混合溶液的辐照形成固溶合金纳米颗粒,即使这些金属在体中是不混溶的。此外,激光诱导成核使贵金属五元固溶合金纳米颗粒的形成成为可能。从元素分布的角度讨论了铑钯铂固溶体纳米颗粒对合金纳米颗粒具有优异催化活性的机理。
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引用次数: 3
Present Status of Air Filters and Exploration of Their New Applications 空气过滤器的现状及新应用的探索
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2020-01-10 DOI: 10.14356/KONA.2020001
Myong-Hwa Lee, Hyun Jin Choi, M. Kumita, Y. Otani
図 Abstract Air filters have been commonly used for the removal of airborne particles. Currently the major concerns of air filters are ( 1 ) improvement of collection performance - a filter with a low pressure drop and a high collection efficiency, ( 2 ) influence of dust load on filter performance - prediction of filter life and development of a filter with a longer life, and ( 3 ) collection efficiency of nanoparticles - thermal rebound of sub -10 nm particles on fiber surfaces. In addition to the conventional usages of air filters, they may also be used for the classification of aerosol particles by tuning the filter structure and filtration conditions. Inertial filter is a low - pass filter, which may be used for the sampling of atmospheric particles and continuous measurement of PM 2 . 5 or PM 0 . 1 . The bounce - off of particles on fiber surfaces may be utilized to achieve “sieving” of aerosol particles. Another topic of filter is the collection efficiency of air filter for PM 2 . 5 . Combination of centrifugal force with air filter may solve many problems which the conventional air filters are confronted with now.
摘要空气过滤器已被广泛用于去除空气中的颗粒。目前空气过滤器的主要关注点是(1)提高收集性能——低压降和高收集效率的过滤器;(2)粉尘负荷对过滤器性能的影响——过滤器寿命的预测和更长的过滤器的开发;(3)纳米颗粒的收集效率——亚-10纳米颗粒在纤维表面的热反弹。除了空气过滤器的常规用途外,它们还可以通过调整过滤器结构和过滤条件来对气溶胶颗粒进行分类。惯性滤波器是一种低通滤波器,可用于大气颗粒物的采样和pm2的连续测量。5点或下午6点。1 . 颗粒在纤维表面的反弹可以用来实现气溶胶颗粒的“筛分”。过滤器的另一个话题是空气过滤器对pm2的收集效率。5 . 离心力与空气滤清器的结合可以解决目前传统空气滤清器面临的许多问题。
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引用次数: 4
Analysis of Industry-Related Flows by Optical Coherence Tomography—A Review 基于光学相干层析成像的产业相关流分析综述
IF 4.1 4区 材料科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2020-01-10 DOI: 10.14356/KONA.2020003
Antti I. Koponen, Sanna Haavisto
Fig. 3 c) A closer look at the measurement optics. Here U is the real velocity, v is the component of velocity in the direction of the measurement beam, and nf is the refractive index of the medium. Angle α is obtained by calculating first angle δ by applying the Snell’s law of refraction to the two interfaces. On page 46 the paragraph related to Eq. (3) should be: Fig. 3b shows as an example a measurement setup of pipe flow. From Fig. 3c, we get the real axial velocity in the pipe to be
图3 c)近距离观察测量光学器件。这里U是实际速度,v是速度在测量光束方向上的分量,nf是介质的折射率。在两个界面上应用斯涅尔折射定律,通过计算第一个角δ得到角α。在第46页,与式(3)相关的段落应为:图3b给出了一个管道流量的测量设置示例。由图3c可知,管道内实际轴向速度为
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引用次数: 9
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KONA Powder and Particle Journal
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