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Biopolymer Geogrids for Geotechnics 岩土工程用生物聚合物土工格栅
Pub Date : 2022-08-10 DOI: 10.18502/kms.v7i1.11627
Gabriel Oliveira, I. Falorca
This study focused on the mechanical characterisation of 3D printed biopolymer geogrids for civil and geotechnical engineering applications. The polylactic acid specimens were designed based on first-order similitude conditions and were produced by fused deposition modelling techniques. An experimental programme was carried out to investigate the mechanical behaviour of 1:2 scale model geogrids undergoing tensile loading conditions, in order to explore their use in soil reinforcement and stabilisation of geomaterials. The secant stiffness at 2.0% of strain and the ultimate tensile strength were used for this purpose. The results showed an average tensile strength of 4.5 ± 0.5 kN/m, which is in good agreement with that of fossil oil-derived polymer prototypes, while presenting a significantly lower elongation at failure. The printing process appeared stable and replicable. The influence of degradation on the tensile properties of 3D printed polylactic acid geogrids over time still needs to be studied. Keywords: geogrid, additive manufacturing, biopolymer, tensile strength, geotechnics
本研究的重点是用于土木和岩土工程应用的3D打印生物聚合物土工格栅的力学特性。聚乳酸试件基于一阶相似条件设计,采用熔融沉积建模技术制作。为了探索1:2比例模型土工格栅在土壤加固和土工材料稳定中的应用,进行了一项实验计划,以研究在拉伸载荷条件下的1:2比例模型土工格栅的力学行为。采用2.0%应变时的割线刚度和极限抗拉强度。结果表明,该材料的平均抗拉强度为4.5±0.5 kN/m,与化石石油衍生聚合物样品的抗拉强度基本一致,但断裂伸长率明显较低。印刷过程似乎稳定且可复制。随着时间的推移,降解对3D打印聚乳酸土工格栅拉伸性能的影响仍有待研究。关键词:土工格栅,增材制造,生物聚合物,抗拉强度,土工技术
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引用次数: 0
Development of Sustainable Cellulose-Based Tissue Materials Using an Innovative Experimental and Computational Methodology 利用创新的实验和计算方法开发可持续纤维素基组织材料
Pub Date : 2022-08-10 DOI: 10.18502/kms.v7i1.11606
F. Morais, Ana M. M. S. Carta, M. Amaral, J. Curto
In recent years, the tissue industry has been exposed to several challenges related to the growing demand for high-quality materials and sustainability. An approach that combined experimental and computational planning was implemented and presented in this work. For this purpose, a simulator that established relationships between the key fibre properties, the process steps that modify them, and the functional properties, named the SimTissue, was developed and validated. Different scenarios and a summary of the SimTissue research strategy are presented. The experimental planning design consisted of examining the influence of refining, enzymatic treatment, and incorporation of additives such as micro / nanofibrillated cellulose and biopolymers. The correlations between these tissue process inputs, and the softness, strength and absorption properties were established using the SimTissue. Overall, the SimTissue predicted and optimized several case studies for the management and optimization of sustainability formulations. Keywords: 3D computational simulation, cellulose-based materials, furnish optimization, tissue materials
近年来,纸巾行业面临着一些挑战,这些挑战与对高质量材料和可持续性的需求不断增长有关。本文提出了一种结合实验和计算规划的方法。为此,开发并验证了一个模拟器,该模拟器建立了关键纤维特性、修改它们的工艺步骤和功能特性之间的关系,称为SimTissue。提出了不同的场景和SimTissue研究策略的总结。实验计划设计包括检查精炼、酶处理和添加添加剂(如微/纳米纤维化纤维素和生物聚合物)的影响。利用SimTissue建立了这些组织过程输入与柔软度、强度和吸收性能之间的相关性。总的来说,SimTissue预测并优化了几个案例研究,以管理和优化可持续性配方。关键词:三维计算模拟,纤维素基材料,配料优化,组织材料
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引用次数: 0
E. Globulus Vessel and Fibre Chemical Analysis E.球血管和纤维化学分析
Pub Date : 2022-08-10 DOI: 10.18502/kms.v7i1.11605
Á. Vaz, João Coelho, V. Costa, A. Marqués, T. Maloney, Phiri Josphat, P. Pinto, Ricardo V B Oliveira, R. Simões, A. Sousa
Hardwood species have a complex cellular structure consisting of fibres, vessel elements and parenchyma cells with different chemical compositions. However, the presence of vessels with significant dimensions in their structure is a recurrent problem in the operation of industrial UWF paper printing. Since the 1980s, vessel picking and ink refusal are problems that paper professionals have tried to solve, but solutions for these have not yet been fully found. If vessels are concentrated in a stream, they can be pre-treated (e.g., by mechanical refining) and reincorporated into the pulp. Other strategies aim at vessel enzymatic and/or chemical passivation and sheet surface chemical treatment, altering the vessel adhesion to the fibre network. This requires vessel concentration at laboratorial level for proper chemical studies, such as FE-SEM, μ-XPS, TOF-SIMS and μFTIR. The main objective of our experimental study was to examine bleached kraft pulp E. globulus vessel and fibre composition. For this we performed EDX and μ-FTIR analysis on both fibre and vessel elements, and obtained the carbohydrate composition, the total acids content, the hexenuronic acids content and the zeta potential. Keywords: E. globulus, vessel, EDX, μ-FTIR, sugar content, zeta potential
硬木种具有复杂的细胞结构,由纤维、导管分子和薄壁细胞组成,具有不同的化学成分。然而,在工业UWF纸张印刷操作中,存在具有显著尺寸的容器是一个反复出现的问题。自20世纪80年代以来,纸张专业人士一直试图解决挑船和拒绝墨水的问题,但这些问题的解决方案尚未完全找到。如果容器集中在一个流中,它们可以被预处理(例如,通过机械精炼)并重新融入纸浆中。其他策略旨在血管酶和/或化学钝化和薄片表面化学处理,改变血管与纤维网络的附着力。这需要实验室水平的容器浓度进行适当的化学研究,如FE-SEM, μ-XPS, TOF-SIMS和μFTIR。本实验研究的主要目的是研究漂白牛皮纸浆的血管和纤维组成。为此,我们对纤维和血管元素进行了EDX和μ-FTIR分析,得到了碳水化合物组成、总酸含量、己醛酸含量和zeta电位。关键词:球茎,血管,EDX, μ-FTIR,糖含量,zeta电位
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引用次数: 0
Development of Biodegradable, Cellulose-Based, Essential Oil and Chitosan Drug Delivery Systems for Cosmetic Mask Applications 可生物降解、纤维素基、精油和壳聚糖给药系统在化妆品面膜中的应用
Pub Date : 2022-08-10 DOI: 10.18502/kms.v7i1.11609
Joana Moreira, Catarina Lopes, M. L. Lis Arias, Lucinda F. Silva, J. Curto
The goal of this research was the development of cellulose-based biodegradable drug delivery systems solutions for cosmetic mask applications. Cellulose-based materials derived from natural renewable sources provide a sustainable alternative to nonwoven cosmetic masks derived from nondegradable fossil-based raw materials. An experimental design was executed to assemble the 3D cellulose fibres matrix and the water in oil emulsion comprising the active molecules from Mentha piperita L. Two types of biopolymeric additives were used, one derived from a nano/micro fibrillated cellulose pulp and another one including chitosan. A 3D computational simulation study was performed to enhance porosity and strength properties. The results indicated that the cosmetic face mask optimized prototypes, made from a biodegradable 3D matrix of cellulose fibres and active molecules, are suitable for dermic use. Keywords: biopolymers, dermic application, drug delivery systems (DDS), essential oil, Mentha piperita
本研究的目的是为化妆品面膜应用开发基于纤维素的可生物降解药物输送系统解决方案。来源于天然可再生资源的纤维素基材料为来源于不可降解的化石基原料的无纺布化妆品口罩提供了一种可持续的替代品。实验设计将三维纤维素纤维基质和含有薄荷油活性分子的油中水乳液组装在一起,使用了两种生物聚合物添加剂,一种来自纳米/微纤化纤维素浆,另一种来自壳聚糖。为了提高孔隙率和强度,进行了三维计算模拟研究。结果表明,由纤维素纤维和活性分子的可生物降解3D基质制成的化妆品面膜优化原型适合皮肤使用。关键词:生物聚合物,真皮应用,给药系统,精油,薄荷
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引用次数: 0
Treatment of Industrial Effluents by the Microalgae Selenastrum Sp. 硒微藻处理工业废水的研究。
Pub Date : 2022-08-10 DOI: 10.18502/kms.v7i1.11616
Bruno P. Escobar, A. Cunha, R. Simões
High consumption of clean water results in the generation of effluents that need to be treated and then safely discarded. Conventional methods for such treatment often do not offer an economical and sustainable result; therefore, new methods are needed, such as microalgae usage. Microalgae are unicellular beings capable of rapid adaptation, growth, and production of compounds of interest (pharmaceuticals, biofuels and others). This work aimed to study the effectiveness of the microalgae Selenastrum sp. in the treatment of effluents from the textile and pulp & paper industries, as well as the respective effects on its biomass development and accumulation of compounds. Four types of culture were carried out (for each type of effluent, a control, and a control with addition of glucose) lasting eight days, in duplicate, all with the addition of a standard culture medium and controlled abiotic factors. Analyses for compound removal (chemical oxygen demand and colour readings on the 200–800nm range) and biomass development (cell number, its dimensions, and weight) were performed four times during the process. At the end of the experiments, the average removal in effluents for COD and colour were 56.6% and 32.7% respectively, in addition to a biomass accumulation of 0.45 g/L. These results were comparable to those obtained for the control cultivation using glucose as a carbon source (70.0% COD removal and 0.51 g/L biomass accumulation). These results demonstrate the effectiveness of Selenastrum sp. in the treatment of industrial effluents, its resilience in stressful environments and the potential use of its accumulated compounds for biotechnological purposes. Keywords: microalgae, Selenastrum sp., industrial effluent, textile effluent, pulp effluent, effluent treatment
清洁水的大量消耗导致废水的产生,这些废水需要处理,然后安全地丢弃。这种治疗的传统方法往往不能提供经济和可持续的结果;因此,需要新的方法,如微藻的利用。微藻是一种单细胞生物,能够快速适应、生长和生产感兴趣的化合物(药物、生物燃料和其他)。本研究旨在研究硒酸微藻处理纺织和纸浆造纸工业废水的效果,以及各自对其生物量发育和化合物积累的影响。进行了四种类型的培养(每种类型的流出物,一种对照,一种添加葡萄糖的对照),持续8天,一式两份,都添加了标准培养基和受控的非生物因子。在此过程中进行了四次化合物去除(化学需氧量和200-800nm范围内的颜色读数)和生物质发展(细胞数,其尺寸和重量)的分析。实验结束时,出水中COD和颜色的平均去除率分别为56.6%和32.7%,生物量积累量为0.45 g/L。这些结果与葡萄糖作为碳源的对照培养的结果相当(COD去除率为70.0%,生物量积累为0.51 g/L)。这些结果证明了硒酸钠在处理工业废水方面的有效性,其在压力环境中的复原力以及其积累的化合物在生物技术目的方面的潜在用途。关键词:微藻,Selenastrum sp,工业废水,纺织废水,纸浆废水,废水处理
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引用次数: 0
Assessment of Autofocus Techniques for Isolated Cellulose Microfiber 3D Imaging by Digital Holography 分离纤维素微纤维三维数字全息成像的自动聚焦技术评价
Pub Date : 2022-08-10 DOI: 10.18502/kms.v7i1.11604
Francisca Silva, P. Fiadeiro, E. Fonseca
Studying the three-dimensional structure of paper fibrous networks is an important step towards understanding the relationship between manufacturing conditions and the resulting microstructural and mechanical properties. Digital holography is a promising three-dimensional imaging technique enabling quantitative phase evaluation of micro and nano-fibres. One of the advantages of this high-resolution method is the ability to perform numerical refocusing at several depths from a single shot acquisition. In this work, the suitability of 22 focusing functions to accurately identify the positions of cellulose microfibers, using digital holography, was inspected. The best performing metrics were identified and the trade-off between metric accuracy and robustness to variable conditions and their computational complexity were discussed. Keywords: digital holography, autofocus, cellulose microfibre, morphology, tomography
研究纸纤维网络的三维结构是理解制造条件与产生的微观组织和力学性能之间关系的重要一步。数字全息技术是一种很有前途的三维成像技术,可以对微纤维和纳米纤维进行定量相位评估。这种高分辨率方法的优点之一是能够在单次拍摄中在多个深度执行数值重新聚焦。在这项工作中,研究了22种聚焦功能在使用数字全息技术准确识别纤维素微纤维位置方面的适用性。确定了性能最好的度量,并讨论了度量精度和对可变条件的鲁棒性及其计算复杂度之间的权衡。关键词:数字全息,自动对焦,纤维素微纤维,形态学,断层扫描
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引用次数: 0
Photocatalytic Activity of LaTi1−xFexO3 Perovskite-Type Oxides Under UV and Visible Light 紫外光和可见光下LaTi1−xFexO3钙钛矿型氧化物的光催化活性
Pub Date : 2022-08-10 DOI: 10.18502/kms.v7i1.11614
M. João Nunes, A. Rodrigues, P. Fiadeiro, A. Lopes, Maria José Pacheco, L. Ciríaco
LaTi1−xFexO3 (x = 0, 0.2, 0.4, 0.6, 0.8 and 1) perovskite-type oxide samples were synthesized by the solid state reaction method and characterized, and their photocatalytic activity was tested in the degradation of Acid Orange 7 under ultraviolet and visible light. The oxides were successfully synthesized and the XRD results showed a phase change from monoclinic to orthorhombic, with an increase in Fe content (x), with LaTi0.8Fe0.2O3 and LaTi0.6Fe0.4O3 samples presenting both phases. All samples presented low photocatalytic activity under visible light radiation, with a maximum Abs484nm removal of 2.9% for LaFeO3 after one hour. The best results were obtained under ultraviolet radiation, for all samples, with the best photocatalytic activity exhibited by the La2Ti2O7 perovskite, with 44.6% Abs484nm removal after one hour. Keywords: perovskites, LaTi1−xFexO3, photocatalysis, Acid Orange 7
采用固相反应法合成了LaTi1−xFexO3 (x = 0、0.2、0.4、0.6、0.8和1)钙钛矿型氧化物样品并对其进行了表征,并在紫外和可见光下测试了其降解酸性橙7的光催化活性。XRD结果表明,随着铁含量(x)的增加,样品由单斜晶向正交晶转变,其中LaTi0.8Fe0.2O3和LaTi0.6Fe0.4O3样品呈现两相。所有样品在可见光下都表现出较低的光催化活性,1小时后LaFeO3在ab484nm处的去除率最高为2.9%。所有样品在紫外辐射下的光催化效果最好,其中La2Ti2O7钙钛矿表现出最好的光催化活性,1小时后脱除ab484nm为44.6%。关键词:钙钛矿,LaTi1−xFexO3,光催化,酸橙
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引用次数: 1
Chemical and Mineralogical Characterization of Biomass Ashes for Soil Reinforcement and Liner Material 用于土壤加固和衬砌材料的生物质灰的化学和矿物学特性
Pub Date : 2022-08-10 DOI: 10.18502/kms.v7i1.11625
André Studart, L. Marchiori, Maria Vitoria Morais, A. Albuquerque, Pedro Gabriel Almeida, V. Cavaleiro
Mineralogical and chemical evaluations are necessary to investigate the background and origins of materials. In terms of residues commonly produced around the world, ashes biomass stands out for its high calorific capacity and use for energy production at thermoelectrical facilities. Given current sustainability issues and new demands from society, ashes and soil from pine biomass in the Castelo Branco region were investigated to research possible anthropogenic contaminations, heavy metals among their composition, and their physic-chemical characteristics. These properties can be used to define possible valorisation methods through residue introduction into the soil for its reinforcement and liner application. The results indicated that ashes biomass could help achieve these objectives and could be introduced into the soil, due to its enrichment with pozzolanic minerals and fine granulometry, while having a low-density, which could reduce final weight; however it was considerably different from the original biomass, and contained anthropogenic contaminations and high concentrations of heavy metals. Keywords: biomass ashes, chemical and mineralogical properties, residue valorisation, soil reinforcement, liner material
矿物学和化学评价是研究材料背景和来源的必要条件。就世界各地普遍产生的残留物而言,灰烬生物质因其高热容量和用于热电设施的能源生产而脱颖而出。考虑到当前的可持续发展问题和社会的新需求,对Castelo Branco地区松树生物量的灰烬和土壤进行了调查,以研究可能的人为污染、重金属成分及其物理化学特征。这些特性可以用来定义可能的增值方法,通过将残留物引入土壤进行加固和衬垫应用。结果表明,灰烬生物质可以帮助实现这些目标,并且由于其富含火山灰矿物和细粒度,可以引入土壤中,同时具有低密度,可以减轻最终重量;然而,它与原始生物量有很大不同,并且含有人为污染和高浓度的重金属。关键词:生物质灰烬,化学和矿物学性质,残留物增值,土壤加固,衬里材料
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引用次数: 0
Improving the Reliability of Rotary Furnace Drums By Stabilizing the Temperature Regime By Effect of Electromagnetic Fields 利用电磁场效应稳定炉筒温度,提高炉筒可靠性
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8142
Y. Mikhailov, A. A. Rukomoinikov, R. Abdeev, E. Abdeev
The unevenness of the heat flow generated in the furnaces of the drums of rotary kilns leads to damage to the drum casing, which can cause premature failure. The author suggests that by deflecting the flame by applying electromagnetic fields, it is possible to prevent direct contact between the flame and the furnace drum, extending the latter’s service life. In this way, it is possible to regulate the directions of movement of the heated combustion products to realize the uniform distribution of heat fluxes, as well as to regulate local temperature fields in real time. The study took into account 5 main factors of the influence of the electromagnetic field on the flame. Based on the studies, a description of a device partially integrated in the furnace is proposed. In this case, there is no significant constructive modernization of the furnace. This device is an analogue of a high-temperature fan, but has several advantages in comparison with it. Keywords: electromagnetic field, furnace, flame, heat exchange
回转窑转鼓炉内产生的热流不均匀,导致转鼓壳体损坏,导致过早失效。作者建议,通过施加电磁场使火焰偏转,可以防止火焰与炉筒直接接触,延长炉筒的使用寿命。这样,就可以调节被加热的燃烧产物的运动方向,实现热流的均匀分布,也可以实时调节局部温度场。研究考虑了电磁场对火焰影响的5个主要因素。在此基础上,提出了一种部分集成于炉内的装置。在这种情况下,没有显著的建设性的现代化的熔炉。这种装置类似于高温风机,但与之相比有几个优点。关键词:电磁场,炉膛,火焰,换热
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引用次数: 0
Development of a Repairable Heat Exchange for Disposal Considerations for Household and Municipal Waste 可修复热交换器的发展,以处理家庭和城市废物
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8093
M. A. Lobanov, Eldar Rinatovich, V. Chelnokov, R. Abdeev
Evolvent form can be applied in the new design of an air cooler and shell and tube heat exchanger used in the oil and gas industry. The air cooler is constructed as a vertically cylindrical multi-section with the evolvent-profile tube row in tube bundle. Tubes have a U-shape form for solving the problem of destruction from linear thermal expansion during maintenance. The dismountable shell-and-tube heat exchanger has an evolvent-profile tube bundle. The advantage of this heat exchanger is its dismountable construction, maintainability and energy efficiency. This is enhanced by the construction of the heat exchange element, which consists of stainless corrugated flexible tubes. Dismountable construction is achieved by a set of flanges and fittings. The energy efficiency of the heat exchanger is determined by thin wall of the corrugated tube, which is 0.3 mm, whereby a heat energy will be transferred faster from a hot stream to cold liquid. Also, energy efficiency is enhanced by tight packing of the tube bundle, which contributes to increase heat transfer area per unit volume. Such solutions contribute to the promotion of more efficient technological equipment and promising ideas for further development and improvement of technical and technological complexes. Keywords: tube, heat, corrugated, flexible, evolvent, construction
Evolvent形式可以应用于石油和天然气工业中空气冷却器和管壳式换热器的新设计。空气冷却器的结构是一个垂直的圆柱形多截面,在管束中有渐进式管排。管有一个u形的形式,以解决在维护过程中线性热膨胀的破坏问题。可拆卸式管壳式换热器具有演化型管束。该换热器的优点是可拆卸结构、可维护性和节能。这是加强了热交换元件的结构,它由不锈钢波纹柔性管组成。可拆卸结构是通过一组法兰和配件实现的。换热器的能量效率由波纹管的薄壁决定,波纹管的薄壁为0.3 mm,通过波纹管可以更快地将热能从热流体传递到冷液体。此外,能源效率提高了紧密的包装管束,这有助于增加单位体积的传热面积。这种解决办法有助于促进更有效的技术设备和有希望的想法,以进一步发展和改进技术和技术综合体。关键词:管,热,波纹,柔性,演变,构造
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引用次数: 0
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KnE Materials Science
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