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Microorganisms Resistant to White Phosphorus 抗白磷的微生物
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8035
A. Mindubaev, A. Voloshina, E. Babynin, S. Minzanova, G. L., Mironova, K. Saparmyradov, E. Badeeva, Yaw Abayie Akosah
We present preliminary results on the successful culturing of different microbial taxonomic groups on media containing white phosphorus (P4) as the sole source of phosphorus. The increase in culture resistance resulting from targeted selection was demonstrated. The highest concentration of P4 used in the study exceeds the threshold limit concentration of P4 in wastewater mud by 5000 times. Putative metabolites of P4 were also investigated. Keywords: biodegradation; white phosphorus; Aspergillus niger; Streptomyces sp. A8
我们介绍了在含白磷(P4)作为磷的唯一来源的培养基上成功培养不同微生物分类群的初步结果。有针对性的选择导致了培养抗性的增加。研究中使用的P4最高浓度超过了污水泥中P4阈值限制浓度的5000倍。还研究了P4的推定代谢物。关键词:生物降解;白色磷;黑曲霉;链霉菌属
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引用次数: 0
Use of Drill Cuttings for Road Building 钻屑在筑路中的应用
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8044
Anton Sergeevich Vlasov, Konstantin Georgievich Pugin
The negative impact on the environment from drill cuttings resulting from drilling wells for oil production is assessed in this article. Environmental hazards are contaminants such as petroleum products, drilling fluid reagents, and chemical compounds of heavy metals that make up drill cuttings. To assess the negative impact, the heavy metal content indicators and chemical analysis parameters of drill cuttings were determined. It has been established that there are no excesses in the standards for the content of heavy metals in drill cuttings. The results of chemical analysis showed that there are excesses in values: MPC (Maximum Permissible Concentrations), COD (Chemical Oxygen Demand), oil content, solids, hardness, magnesium and calcium ions, chlorides. Two directions of utilization of drill cuttings were selected: the use of drill cuttings in the construction of the foundation of the road, and obtaining material based on drill cuttings to strengthen slopes. A technoground was obtained in the form of a lumpy material for placement in a barn and further excavation for filling embankments and strengthening soil. In preliminary studies, it was found that theb technoground sample with the following component composition has the most stable strength characteristics: cement - 20%; drill cuttings - 80%; liquid glass - 2% over 100% of the mixture. Keywords: drill cuttings, negative impact, environment, utilization, technoground
本文对钻井采油过程中产生的钻屑对环境的负面影响进行了评价。环境危害是污染物,如石油产品、钻井液试剂和构成钻屑的重金属化合物。为了评估负面影响,确定了钻屑重金属含量指标和化学分析参数。经确认,钻屑中重金属含量标准不存在超标现象。化学分析结果显示:MPC(最大允许浓度)、COD(化学需氧量)、含油量、固体、硬度、镁离子和钙离子、氯化物等值超标。选择了钻屑利用的两个方向:在道路基础施工中使用钻屑,以及以钻屑为基础获取材料加固边坡。技术场地以块状材料的形式获得,用于放置在谷仓中,并进一步挖掘以填充堤防和加强土壤。在初步研究中发现,采用以下组分组成的工艺磨样具有最稳定的强度特性:水泥- 20%;钻屑- 80%;液体玻璃-百分之百混合物的百分之二。关键词:钻屑;负面影响;环境
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引用次数: 0
The Influence of the Direction of the Channels of the Gas Swirlers on the Properties of the Flow of the Plasma Jet under Implementation Theoretical Basis and Technical Solutions for Recycling Technogenic Waste 气体旋流器通道方向对等离子体射流特性的影响及其实现技术废物回收的理论基础和技术解决方案
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8048
Roman Aleksandrovich Okulov, Konstantin Ivanovich Sarsadskikh, Sergey Anatolievich Ilinykh, Mikhail Nikolayevich Zakharov
A variant of the use of plasmatrons for the disposal of industrial waste and the organization of non-waste production is proposed in this article, which presents the design for the functioning equipment. A computer experiment was carried out to determine the parameters of the flow of the plasma jet. The results of a computer experiment are confirmed by a full-scale experiment. Conclusions and results are of practical benefit to developers and consumers of technological equipment. Keywords: plasmatron, flow, plasma, jet, temperature, velocity
本文提出了利用等离子体处理工业废物和组织非废物生产的一种变体,并介绍了功能设备的设计。通过计算机实验确定了等离子体射流的流动参数。计算机实验的结果得到了全尺寸实验的证实。结论和结果对技术装备的开发商和消费者具有实际意义。关键词:等离子体,流动,等离子体,射流,温度,速度
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引用次数: 0
Suitability Evaluation of Ash-And-Slag Waste from Coal Power Plants as Soil Components 燃煤电厂灰渣废弃物作为土壤组分的适宜性评价
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8106
D. Volkov, O. Rogova, I. Levin, Proskurnin
The chemical and fractional composition of ash-and-slag waste and fly ash materials of three large combined heat and power plants in Central Russia was compared in this study to assess their influence on the germination of oats as an indicator of the phytotoxic effect of these materials as soil components. It was found that these materials have an acceptable chemical composition from the viewpoint of their release into the environment, but there are factors such as fractional composition that significantly affect the growth and the development of plants when using these materials as soil components during soil reclamation. Keywords: Ash-And-Slag waste, coal fly ash, Chemical and fractional composition
本研究比较了俄罗斯中部三个大型热电联产电厂的灰渣废物和粉煤灰材料的化学成分和分数组成,以评估它们对燕麦发芽的影响,作为这些材料作为土壤成分的植物毒性作用的指标。从释放到环境中的角度来看,这些材料具有可接受的化学成分,但在土壤复垦过程中,这些材料作为土壤组分使用时,存在组分分数等因素对植物的生长发育有显著影响。关键词:灰渣废物,粉煤灰,化学与分级组成
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引用次数: 0
Complex Processing of Copper Smelting Slags with Obtaining of Cast Iron Grinding Media and Proppants 炼铜渣的复合处理及铸铁磨矿介质和支撑剂的获得
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8126
V. E. Roshchin, G. Adilov, A. Povolotckii, Y. Kapelyushin
The Ural region has a large number of metallurgical companies. The extraction of metals from ore is always accompanied by the accumulation of wastes. Currently, most of the wastes are stored in dumps and storage facilities forming technogenic deposits. One such that occupies huge areas is copper slag from the copper-smelting production. According to current estimations, about 2.2 tons of slag is formed for each ton of copper produced and about 24 million tons are produced annually [1]. In general, a copper slag contains about 35-45% iron and 0.4-0.5 copper, which indicates that this is a valuable secondary resource for recycling and utilization [33]. However, more than 80% of copper slag is not utilized, which makes it possible to consider this waste not only as a valuable material, but also as a potential hazard for the environment; it contaminates the soil and water with heavy elements [8]. Currently, only small amounts of the waste are recycled. In addition, technologies do not allow the complete extraction of valuable elements. This offers potential for the development of new highly efficient technologies for processing copper smelting wastes with extraction of valuable elements such as iron (Fe). Improvement of Fe quality requires a decrease in non-ferrous metal content, especially Cu. In recent years, extensive research was directed at the extraction of valuable materials from copper slags by high-temperature firing of copper conglomerates with subsequent magnetic separation or leaching of non-ferrous metals. However, these studies do not allow the complete processing of copper smelting slags. This work studies the production of iron-containing briquettes from copper-smelting slags, and their subsequent processing to obtain valuable products for metallurgical and oil companies. Keywords: briquette, reduction, cast iron, proppants
乌拉尔地区有大量的冶金公司。从矿石中提取金属总是伴随着废物的积累。目前,大多数废物被储存在垃圾场和储存设施中,形成技术沉积物。其中占地面积较大的是铜冶炼生产产生的铜渣。根据目前的估计,每生产1吨铜产生约2.2吨渣,每年生产约2400万吨铜。一般情况下,铜渣中铁含量约为35-45%,铜含量约为0.4-0.5,是一种有价值的可回收利用的二次资源[33]。然而,超过80%的铜渣没有得到利用,这使得这种废物不仅可以被视为有价值的材料,而且可以被视为对环境的潜在危害;它用重元素污染土壤和水。目前,只有一小部分垃圾被回收利用。此外,技术不允许完全提取有价值的元素。这为开发新的高效技术处理铜冶炼废料并提取铁(Fe)等有价值元素提供了潜力。提高铁的质量需要降低有色金属的含量,特别是Cu的含量。近年来,广泛的研究方向是通过高温烧成铜砾岩,然后磁分离或浸出有色金属,从铜渣中提取有价物质。然而,这些研究并不能完全处理铜冶炼渣。本文研究了从炼铜渣中生产含铁型煤,并对其进行后续处理,以获得冶金和石油公司有价值的产品。关键词:型煤,还原,铸铁,支撑剂
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引用次数: 0
The Development of Plasma Incineration Technologies for Utilization and Neutralization of Waste Hazardous Class 等离子体焚烧有害废物利用中和技术的发展
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8043
Sergey Vadimovich Anakhov, Yuriy Anatolievich Pyckin, Anatoliy Vladimirovich Matushkin, Galina Valerianovna Kharina, Boris Nickolaevich Guzanov
In this study, the results of studies for plasma incineration processes in technologies of waste disposal and disposal are presented. Due to the high temperatures of the plasma jet (up to 10 thousand K), the speed of the process, the small influence of atmospheric oxygen, the necessary conditions for the neutralization of almost any toxic gases arise. It is noted that the evaluation of the efficiency of toxic gases neutralization with the use of plasma torches is a multiparameter problem, since in addition to the constructive ones, the gas-dynamic and heat-power parameters should be taken into account. The gas-dynamic parameters of the air-plasma flow in the plasma torch mixing chamber for environmental technologies are determined by methods of mathematical modeling. The characteristic temperatures, velocities and heating times of the utilized gas in different areas of the mixing chamber are calculated. Different configurations of mixing chambers with varying confusability are considered. The directions of further research and development necessary to create a technology of plasma incineration with maximum efficiency of disinfection are indicated. The issues of plasma incineration introduction at certain stages of high-temperature waste disposal technologies are also considered. The main advantages of technologies based on high-temperature plasma impact on materials, as well as the main directions of their application in waste management strategies are noted. Keywords: ecological safety, waste recycling, waste treatment, decontamination, incineration, plasma torch
本文介绍了等离子体焚烧工艺在垃圾处理和处置技术中的研究结果。由于等离子体射流的高温(高达10,000 K),过程的速度,大气中氧气的影响小,几乎任何有毒气体的中和的必要条件出现。需要指出的是,评价使用等离子体火炬中和有毒气体的效率是一个多参数问题,因为除了建设性的参数外,还应考虑气体动力学和热功率参数。采用数学建模的方法确定了环境技术用等离子炬混合室中空气-等离子体流动的气动力参数。计算了混合室不同区域内利用气体的特征温度、速度和加热时间。考虑了具有不同混淆度的混合室的不同配置。指出了进一步研究和开发等离子体焚烧技术所需的方向,以达到最高的消毒效率。讨论了高温垃圾处理技术在某些阶段引入等离子体焚烧的问题。指出了基于高温等离子体对材料冲击的技术的主要优势,以及它们在废物管理策略中的主要应用方向。关键词:生态安全,垃圾回收,垃圾处理,去污,焚烧,等离子炬
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引用次数: 0
The Waste of the Ferroalloy Production in Russia 俄罗斯铁合金生产的浪费
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8125
V. Zhuchkov, L. Leontiev, A. Sychev, V. Y. Dashevsky, O. Zayakin
Ferroalloys are used to change the composition and properties of ferrous and non- ferrous metals. Therefore, the volume of ferroalloy smelting corresponds to the amount of steel and other alloys produced. Currently world steel production is approximately 1630 million tons, and about 40 million tons of various ferroalloys are produced (2.5%). The structure of ferroalloy production in different countries mainly depends not on the needs of industrial enterprises, but on ore reserves. Excessive amounts of ferroalloys produced are exported, and the missing alloys are imported. In Russia silicon alloys that have no restrictions in the raw material base (44%) are the most produced, then manganese (25%) and chromium (23%) ferroalloys. The remaining ferroalloys account for 8% of production. About half of the manganese ferroalloys needed for consumption are bought abroad, and half are produced in the Russian Federation from foreign raw materials (Kazakhstan, South Africa, Gabon). The Russian Federation provides itself with chromium ferroalloys completely, and sells ∼ 80%, and for their production mainly imported raw materials (∼ 65%) from Kazakhstan are used. Keywords: ferroalloy, ferrochrome, slags, production of ferroalloy
铁合金用于改变铁金属和有色金属的成分和性能。因此,铁合金的熔炼量与钢和其他合金的产量相对应。目前世界钢铁产量约为1630亿吨,各种铁合金产量约为4000万吨(2.5%)。各国铁合金生产结构主要不是取决于工业企业的需求,而是取决于矿石储量。过量生产的铁合金出口,而缺少的合金则进口。在俄罗斯,不受原料基础限制的硅合金(44%)产量最大,其次是锰(25%)和铬(23%)铁合金。剩下的铁合金占产量的8%。消费所需的锰铁合金约有一半是在国外购买的,一半是在俄罗斯联邦用外国原料生产的(哈萨克斯坦、南非、加蓬)。俄罗斯联邦完全提供自己的铬铁合金,并销售约80%,其生产主要使用从哈萨克斯坦进口的原材料(约65%)。关键词:铁合金,铬铁,炉渣,铁合金生产
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引用次数: 1
Processing of Sb-Pb-Sn-Containing Materials 含sb - pb - sn材料的加工
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8070
Konstantin L. Timofeev, Alexey A. Korolev, Gennady I. Maltsev
During the processing of lead containing products and polymetallic alloys the recovery of tin and antimony from technology of lead production is carried out by oxidation refining of decopperized lead with rich oxides (Sn, Sb ≥ 20%).Tin oxides are melted in a short-drum furnaces to lead bullion (> 96% Pb) and tin-rich (> 20% Sn) slag. The slag is melted in an ore-smelting furnace to obtain a Sn-Pb alloy of next composition, %: 56.1 Sn, 18.2 Pb, 14.6 Sb, 6.9 As, which is refined by vacuum distillation with production of rough tin (Sn ≥ 90%). The additional profit of rough tin obtainment (∼310 tons/year), compared with sales of tin slag, is about ∼1.3 million $/year. Keywords: lead, tin, antimony, melting, vacuum distillation
在含铅产品和多金属合金加工过程中,采用富氧化物(Sn、Sb≥20%)对脱铜铅进行氧化精炼的方法回收铅生产工艺中的锡和锑。将氧化锡在短鼓炉中熔炼成铅锭(Pb > 96%)和富锡(Sn > 20%)渣。将炉渣在熔炼炉中熔化,得到以下成分的Sn-Pb合金:%:56.1 Sn, 18.2 Pb, 14.6 Sb, 6.9 As,经真空蒸馏提纯,得到Sn≥90%的粗锡。与锡渣的销售额相比,粗锡(~ 310吨/年)的额外利润约为~ 130万美元/年。关键词:铅、锡、锑、熔融、真空蒸馏
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引用次数: 0
The Use of Reftinskaya State District Power Plant Fly Ash in the Production of Building Materials and Products 利夫廷斯卡亚州地区电厂粉煤灰在建筑材料及制品生产中的应用
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8058
F. Kapustin, V. Ufimtsev, A. Vishnevsky, I. Fomina, A. Kapustin, K. Zemlyanoy
The system of dry ash–slag removal at the Reftinskaya state district power plant which provides capture, storage and shipment of fly ash to the consumers is considered in this study. The results of determination of chemical and phase composition, physical properties, melting temperature and activity of natural radionuclides of ash which is form during burning of stone coal of Ekibastuz basin are presented. Ash is acidic, superfine and refractory one with a low content of combustible substance. As to composition and properties it satisfies the requirements of Russian Standard no. 25818 and ships to consumers under Technical Conditions 5717–004–79935691–2009. The results of laboratory tests and industrial production of building materials and products on the basis of ash of Reftinskaya state district power plant are presented. It is shown that ash is used in the production of Portland cement, heavy and cellular autoclave concrete, dry mixes and can also be used as part of fly ash non-fired and agloporite gravel, ceramic bricks. The features of their production, basic physical and mechanical properties of building materials and products are described. It is shown that the introduction of a new system of dry ash removal at the state district power plant contributes to the expansion of directions and increase in the volume of ash recycling. Keywords: Reftinskaya state district power plant, dry ash removal, fly ash, composition, properties, use, construction materials and products
本文研究了雷夫京斯卡亚州地区电厂的干式除灰系统,该系统提供了飞灰的捕获、储存和运输给消费者。本文介绍了Ekibastuz盆地石煤燃烧产生的灰分的化学组成、物相组成、物理性质、熔融温度和天然放射性核素活度的测定结果。灰分为酸性超细耐火灰分,可燃物含量低。在成分和性能方面,它满足俄罗斯标准的要求。根据技术条件5717-004-79935691-2009,25818和船舶到消费者。介绍了以雷夫廷斯卡亚州地区电厂灰分为原料进行的室内试验和建筑材料及制品工业生产的结果。研究表明,粉煤灰可用于生产波特兰水泥、重质和蜂窝蒸压混凝土、干混料,也可作为粉煤灰的一部分,用于未烧制和辉绿石砾石、陶瓷砖。介绍了它们的生产特点、建筑材料和产品的基本物理力学性能。结果表明,国家区电厂引进干法除灰新系统,有利于扩大灰的回收方向和增加灰的回收量。关键词:雷夫廷斯卡亚州地区电厂,干式除灰,粉煤灰,成分,性质,用途,建筑材料和产品
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引用次数: 1
Development of Technology for Processing Oil Sludge with Application of Super High Frequency Electromagnetic Fields 超高频电磁场处理油泥技术的发展
Pub Date : 2020-12-31 DOI: 10.18502/kms.v6i1.8145
J. Harisova, R. Saitov, R. Abdeev
This article considers the problem of processing and disposing of oil sludge of various origins. Large oil companies are concerned about the problem of incomplete processing of oil sludge. The most hazardous from an environmental point of view include oil sludge formed at all stages of oil production, transportation and refining. In recent years, oil-producing enterprises have introduced various technological solutions aimed at waste management into production, but there is no single method for processing oil sludge for the purpose of neutralization and disposal. All known oil sludge processing technologies by processing methods can be divided into the following groups: thermal - burning in open barns, furnaces of various types, obtaining bitumen residues; physical - burial in special cemeteries, separation in a centrifugal field, vacuum filtration and filtration under pressure; physical and chemical - the use of specially selected reagents that change the physical and chemical properties, followed by processing on special equipment; and biological - microbiological decomposition in the soil directly in storage, biothermal decomposition. Each of them, while having certain advantages, also has its drawbacks. For over 50 years, microwave heating technology has been used in industry. To present the advantages of this method, one needs to turn to the theory of microwave heating. Keywords: oil sludge, oil waste, influence of electromagnetic fields, water-in-oil emulsions
本文讨论了各种来源的油泥的处理和处置问题。大型石油公司都很关注油泥处理不完全的问题。从环境的角度来看,最危险的是在石油生产、运输和提炼的各个阶段形成的油泥。近年来,石油生产企业在生产中引入了各种针对废物管理的技术解决方案,但目前还没有一种处理油泥以达到中和和处置目的的方法。所有已知的油泥处理技术按处理方法可分为以下几类:在露天仓、各种类型的炉中热燃烧,获得沥青残渣;物理——特殊墓地埋葬,离心场分离,真空过滤和压力过滤;物理和化学-使用特殊选择的试剂,改变物理和化学性质,然后在专用设备上进行加工;并在土壤中直接进行生物-微生物分解,在贮存中进行生物热分解。每一种方法,虽然有一定的优点,但也有其缺点。50多年来,微波加热技术一直应用于工业。为了说明这种方法的优点,我们需要求助于微波加热理论。关键词:油泥,废油,电磁场影响,油包水乳状液
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引用次数: 0
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