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Tribological Performance of a Plasma Electrolytic Oxidation-Coated Mg Alloy in Graphene-Incorporated Ethanol 等离子电解氧化涂层镁合金在石墨烯包裹的乙醇中的摩擦学性能
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-28 DOI: 10.3390/lubricants12010009
S. Bhowmick, F. Muhaffel, Shayan Shirzadian, Hüseyin Çimenoğlu, A. Alpas
This study investigated the friction and wear characteristics of a plasma electrolytic oxidation (PEO)-coated Mg–Al alloy (AZ31) in sliding contact against steel using graphene nanoplatelets (GNPs) containing ethanol as a lubricant. The results revealed that the typically high coefficient of friction (COF) of PEO-coated surfaces under dry sliding (0.74) was notably reduced to 0.18 during the sliding tests conducted in GNP-free ethanol. When the ethanol contained 5 × 10−4 wt.% GNPs, the COF of the uncoated AZ31 alloy further dropped to 0.17. The PEO-coated surfaces achieved a significantly lower COF of 0.07 and demonstrated a marked reduction in wear rate, attributed to the formation of a tribolayer incorporating graphene. These findings highlight the significant potential of GNP-incorporated ethanol to improve the tribological performance of PEO-coated AZ31, presenting a promising avenue for advancing lightweight, sustainable, and efficient automotive technologies.
本研究使用含乙醇的石墨烯纳米颗粒(GNPs)作为润滑剂,研究了等离子电解氧化(PEO)涂层镁铝合金(AZ31)在与钢滑动接触时的摩擦和磨损特性。结果表明,在不含 GNP 的乙醇中进行滑动测试时,PEO 涂层表面在干滑动条件下的摩擦系数(COF)通常很高(0.74),而在不含 GNP 的乙醇中进行滑动测试时,摩擦系数则明显降低到 0.18。当乙醇中含有 5 × 10-4 重量百分比的 GNP 时,未涂层 AZ31 合金的 COF 进一步降至 0.17。PEO 涂层表面的 COF 明显降低到 0.07,磨损率也明显降低,这归功于石墨烯摩擦层的形成。这些发现凸显了掺入 GNP 的乙醇在改善 PEO 涂层 AZ31 的摩擦学性能方面的巨大潜力,为推进轻质、可持续和高效的汽车技术提供了一条大有可为的途径。
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引用次数: 0
Tribological Application of Nanocomposite Additives in Industrial Oils 纳米复合添加剂在工业油中的摩擦学应用
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-24 DOI: 10.3390/lubricants12010006
Milan Bukvić, S. Gajević, A. Skulić, Slobodan Savić, A. Ašonja, Blaža Stojanović
The demand for an improvement in the tribological properties of lubricants used in various industrial plants, the automotive industry, and other power transmissions has resulted in the development of a whole family of improved lubricants based on nanotechnology. Especially important are nanotube additives, which significantly improve the tribological properties of lubricants, primarily by reducing the friction coefficient and wear of the coupled elements but also by reducing the temperature load and increasing the stability of the oil film between the lubricated surfaces. The properties of nanotube-based additives were further improved using elements such as metal oxides and compounds based on titanium, molybdenum, aluminum, etc. This paper presents the results obtained in the field of research and application of nanocomposite lubricant additives. It also gives a partial comparative analysis of the research conducted in this field. The primary goal of this paper is to analyze the research results in the field of the application of nanotubes in lubricants and to indicate the importance of their application, such as improving the tribological properties of machines and reducing power losses. Furthermore, this paper shows the negative impact of nanoparticles on the environment and human health and the costs of applying some types of nanoparticles.
由于各种工业设备、汽车工业和其他动力传动装置中使用的润滑油需要改善摩擦学特性,因此开发出了一整套基于纳米技术的改进型润滑油。其中尤为重要的是纳米管添加剂,它能显著改善润滑油的摩擦学特性,主要是通过降低摩擦系数和耦合元件的磨损,同时还能降低温度负荷并提高润滑表面之间油膜的稳定性。使用金属氧化物和基于钛、钼、铝等的化合物等元素可进一步提高纳米管添加剂的性能。本文介绍了在纳米复合润滑油添加剂研究和应用领域取得的成果。本文还对该领域的研究进行了部分比较分析。本文的主要目的是分析纳米管在润滑剂应用领域的研究成果,并指出其应用的重要性,如改善机器的摩擦学特性和降低功率损耗。此外,本文还说明了纳米粒子对环境和人类健康的负面影响,以及应用某些类型纳米粒子的成本。
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引用次数: 0
Effect of Nb Addition on the Corrosion and Wear Resistance of Laser Clad AlCr2FeCoNi High-Entropy Alloy Coatings 添加铌对激光熔覆 AlCr2FeCoNi 高熵合金涂层耐腐蚀性和耐磨损性的影响
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-24 DOI: 10.3390/lubricants12010005
Xiulin Ji, Kunpeng Guan, Y. Bao, Zhongfa Mao, Fengtao Wang, Houfu Dai
Laser clad AlCr2FeCoNiNbx (x = 0, 0.5, 1.0, 1.5, 2.0, with x values in molar ratio) high-entropy alloy (HEA) coatings were fabricated on Q345 carbon steel. This study delves into the impact of Nb incorporation on the reciprocating sliding wear resistance of these laser clad coatings against a Φ6 mm silicon nitride ball. The microstructure of the as-clad AlCr2FeCoNiNbx coatings transformed from a single Face-Centered Cubic (FCC) solid solution (when x = 0) to the hypoeutectic state (when x = 0.5) and progressed to the hypereutectic state (when x ≥ 1.0). This evolution was marked by an increase in the Laves phase and a decrease in FCC. Consequently, the HEA coatings exhibited a gradually increasing Vickers hardness, reaching a peak at HV 820. Despite a decline in corrosion resistance, there was a notable enhancement in wear resistance, and the friction of the HEA coating could be reduced by Nb addition. The phase evolution induced by Nb addition led to a shift in the predominant wear mechanism from delamination wear to abrasive wear. The wear rate of Nb0.5 was impressively low, at 6.2 × 10−6 mm N−1 m−1 when reciprocating sliding under 20 N in air. In comparison to Nb0, Nb0.5 showcased 3.6, 7.2, and 6.5 times higher wear resistance at 5 N, 10 N, and 20 N, respectively. Under all applied loads, Nb1.5 has the lowest wear rate among all HEA coatings. This substantiates that the subtle introduction of Laves phase-forming elements to modulate hardness and oxidation ability proves to be an effective strategy for improving the wear resistance of HEA coatings.
在 Q345 碳钢上制作了激光熔覆 AlCr2FeCoNiNbx(x = 0、0.5、1.0、1.5、2.0,x 值为摩尔比)高熵合金 (HEA) 涂层。本研究探讨了掺入 Nb 对这些激光熔覆涂层与 Φ6 mm 氮化硅球的往复滑动耐磨性的影响。包覆后的 AlCr2FeCoNiNbx 涂层的微观结构从单一的面心立方(FCC)固溶体(当 x = 0 时)转变为低共晶状态(当 x = 0.5 时),并发展到高共晶状态(当 x ≥ 1.0 时)。这种演变的特点是拉维斯相的增加和催化裂化相的减少。因此,HEA 涂层的维氏硬度逐渐增加,在 HV 820 时达到峰值。尽管耐腐蚀性有所下降,但耐磨性却明显增强,而且 HEA 涂层的摩擦力可以通过添加铌而降低。添加铌引起的相变导致主要磨损机制从分层磨损转变为磨料磨损。Nb0.5 的磨损率非常低,在空气中 20 N 条件下往复滑动时为 6.2 × 10-6 mm N-1 m-1。与 Nb0 相比,Nb0.5 在 5 N、10 N 和 20 N 条件下的耐磨性分别高出 3.6、7.2 和 6.5 倍。在所有应用载荷下,Nb1.5 的磨损率在所有 HEA 涂层中最低。这证明了巧妙地引入 Laves 相形成元素来调节硬度和氧化能力是提高 HEA 涂层耐磨性的有效策略。
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引用次数: 0
Effect of Composite Bionic Micro-Texture on Cutting Performance of Tools 复合仿生微观纹理对刀具切削性能的影响
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-22 DOI: 10.3390/lubricants12010004
Tiantian Xu, Chun-Yang Ma, Hu Shi, Kai Xiao, Jinpeng Liu, Qinghua Li
Dry cutting is an effective method to realize the concept of green cutting today. However, in the process of cutting bearing steel, the high temperatures and high pressures produced by the cutting tool and chip under dry friction seriously affect the machining performance of the tool. Therefore, a bionic microstructure tool based on bionics is proposed to improve the cutting performance and reduce friction by changing the size parameters of the microstructure. On the basis of finite element simulation and cutting tests, the cutting force, surface roughness, and chip shape are used to evaluate the cutting performance. It is found that composite bionic micro-textured tools have a significantly reduced cutting force compared with non-micro-textured tools; composite bionic micro-textured tools lead to a reduction in surface roughness of 10–25%; and composite bionic micro-textured tools are more prone to enhancing the curling and breaking of chips. In addition, with the increase in the microstructure area occupancy, the cutting performance of the tool was also significantly improved. Moreover, it was found that the cutting performance of the tool was improved when the area occupancy of the micro-texture on the front face of the tool was increased.
干切削是当今实现绿色切削理念的有效方法。然而,在切削轴承钢的过程中,干摩擦下刀具与切屑产生的高温高压严重影响了刀具的加工性能。因此,提出了一种基于仿生学的微结构刀具,通过改变微结构的尺寸参数来提高切削性能,降低摩擦。在有限元模拟和切削试验的基础上,利用切削力、表面粗糙度和切屑形状来评价切削性能。研究发现,与非微观纹理刀具相比,复合仿生微观纹理刀具的切削力明显降低;复合仿生微观纹理刀具的表面粗糙度降低了 10%-25%;复合仿生微观纹理刀具更容易增强切屑的卷曲和断裂。此外,随着微结构面积占有率的增加,刀具的切削性能也得到显著改善。此外,研究还发现,当刀具正面的微纹理面积占有率增加时,刀具的切削性能也会得到改善。
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引用次数: 0
Evaluation of Antioxidant Properties and Molecular Design of Lubricant Antioxidants Based on QSPR Model 基于 QSPR 模型的抗氧化剂性能评估和润滑油抗氧化剂的分子设计
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-22 DOI: 10.3390/lubricants12010003
Jianfang Liu, Yaoyun Zhang, Chenglingzi Yi, Rongrong Zhang, Sicheng Yang, Ting Liu, Dan Jia, Qing Yang, Shuai Peng
Two quantitative structure–property relationship (QSPR) models of hindered phenolic antioxidants in lubricating oils were established to help guide the molecular structure design of antioxidants. Firstly, stepwise regression (SWR) was used to filter out essential molecular descriptors without autocorrelation, including electronic, topological, spatial, and structural descriptors, and multiple linear regression (MLR) was used to construct QSPR models based on the screened variables. The two models are statistically sound, with R2 values of 0.942 and 0.941, respectively. The models’ reliability was verified by the frontier molecular orbital energy gaps of the antioxidants. A hindered phenolic additive was designed based on the models. Its antioxidant property is calculated to be 20.9% and 11.0% higher than that of typical commercial antioxidants methyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate and 2,2′-methylenebis(6-tert-butyl-4-methylphenol), respectively. The structure–property relationship of hindered phenolic antioxidants in lubricating oil obtained by computer-assisted analysis can not only predict the antioxidant properties of existing hindered phenolic additives but also provide theoretical basis and data support for the design or modification of lubricating oil additives with higher antioxidant properties.
建立了润滑油中受阻酚类抗氧化剂的两个定量结构-性能关系(QSPR)模型,以帮助指导抗氧化剂的分子结构设计。首先,采用逐步回归(SWR)方法筛选出不存在自相关性的基本分子描述符,包括电子、拓扑、空间和结构描述符,然后根据筛选出的变量采用多元线性回归(MLR)方法构建 QSPR 模型。这两个模型的 R2 值分别为 0.942 和 0.941,在统计学上是合理的。抗氧化剂的前沿分子轨道能隙验证了模型的可靠性。根据模型设计了一种受阻酚类添加剂。经计算,其抗氧化性能分别比典型的商业抗氧化剂 3-(3,5-二叔丁基-4-羟基苯基)丙酸甲酯和 2,2′-亚甲基双(6-叔丁基-4-甲基苯酚)高 20.9% 和 11.0%。通过计算机辅助分析获得的润滑油中受阻酚类抗氧化剂的结构-性能关系,不仅可以预测现有受阻酚类添加剂的抗氧化性能,还可以为设计或改性具有更高抗氧化性能的润滑油添加剂提供理论依据和数据支持。
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引用次数: 0
Estimation of Road Wetness from a Passenger Car 估算乘用车的路面湿度
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-20 DOI: 10.3390/lubricants12010002
Wiyao Edjeou, Ebrahim Riahi, Manuela Gennesseaux, V. Cerezo, Minh-Tan Do
This paper presents an evaluation of a system aiming at estimating water depths on a road surface. Using accelerometers, the system records the vibrations of a wheel arch liner due to impacts of water droplets. The system setup, including the location of the accelerometers on a wheel arch and the data acquisition, is described. Tests were performed with a passenger car on various road surfaces and at different vehicle speeds and water depths. Signals recorded by the accelerometers are filtered and processed. The link between the acceleration amplitude, the water depth, and the vehicle speed is consistent with results from previous studies. The effect of the surface texture is less obvious and needs further investigations. A mathematical model has been developed to relate the acceleration amplitude to the water depth. The potential application of the developed system to on-board evaluation of pavement wetness, and consequently the pavement skid resistance, is discussed. Perspectives for driver assistance, or more generally, for autonomous driving to improve traffic safety, are also highlighted.
本文介绍了对旨在估算路面水深的系统的评估。该系统使用加速度计记录水滴撞击轮拱衬垫时产生的振动。系统设置包括加速度计在轮拱上的位置和数据采集。在不同的路面、不同的车速和水深条件下,对一辆乘用车进行了测试。加速度计记录的信号经过过滤和处理。加速度振幅、水深和车速之间的联系与之前的研究结果一致。表面纹理的影响不太明显,需要进一步研究。我们建立了一个数学模型,将加速度振幅与水深联系起来。讨论了所开发系统在车载路面湿度评估中的潜在应用,以及由此产生的路面防滑性能。此外,还强调了驾驶员辅助系统,或更广泛意义上的自动驾驶系统在改善交通安全方面的前景。
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引用次数: 0
The Influence of Load and Speed on the Initial Breakdown of Rolling Bearings Exposed to Electrical Currents 载荷和速度对暴露于电流中的滚动轴承初始破坏的影响
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-19 DOI: 10.3390/lubricants12010001
S. Puchtler, Robert Maier, Martin Kuhn, Yves Burkhardt
The reason for the failure of electric vehicle drives is increasingly current-induced damage to rolling bearings. Studies show that rolling bearings are more susceptible to current pass-through after the first occurrence of unwanted bearing currents. To investigate this effect, a test plan is introduced with variations in axial and radial loads, as well as rotational speeds. A new bearing is mechanically run-in for each test point and then subjected to a realistic voltage signal of gradually increasing amplitude. After the initial breakdown, the different voltage amplitudes are applied again to investigate the behavior after the initial breakdown. During the whole test, the maximum current, the duration and the dissipated energy of each breakdown are measured. The results provide insights into the processes after the initial breakdown and the stochastic nature of the breakdown behavior.
电动汽车驱动装置故障的原因越来越多地在于电流对滚动轴承造成的损坏。研究表明,滚动轴承在首次出现不必要的轴承电流后更容易受到电流穿越的影响。为了研究这种影响,采用了一种测试计划,改变轴向和径向载荷以及旋转速度。在每个测试点都对一个新轴承进行机械磨合,然后对其施加振幅逐渐增大的实际电压信号。初始击穿后,再次施加不同的电压幅值,以研究初始击穿后的行为。在整个测试过程中,对每次击穿的最大电流、持续时间和耗散能量进行测量。测试结果有助于深入了解初始击穿后的过程以及击穿行为的随机性。
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引用次数: 0
Reconstruction and Intelligent Evaluation of Three-Dimensional Texture of Stone Matrix Asphalt-13 Pavement for Skid Resistance 石子基质沥青-13 路面抗滑性三维纹理重构与智能评估
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-18 DOI: 10.3390/lubricants11120535
Gang Dai, Zhiwei Luo, Mingkai Chen, You Zhan, Changfa Ai
To examine the three-dimensional texture structure of SMA-13 asphalt pavement and assess its anti-skid performance, a light gradient-boosting machine evaluation model was developed using non-contact three-dimensional laser-scanning technology. The study focused on collecting three-dimensional texture data from newly laid SMA-13 asphalt pavement. Subsequently, wavelet transform was employed to reconstruct the pavement’s three-dimensional texture, and discrete Fourier transform was utilized to separate macro- and microtextures, enabling the calculation of their characteristics. The macro- and micro-characteristics of the three-dimensional texture and friction coefficient were input into the model. A comparative analysis with linear regression and a random forest model revealed superior accuracy and efficiency in the model. The training set R2 is 0.948, and the testing set R2 is 0.842, effectively enabling the evaluation of pavement anti-skid performance. An analysis of parameter importance indicated that Rku and MPD are still effective indicators for evaluating skid resistance. Furthermore, diverse texture indexes exhibited varying effects on the anti-skid performance. The established asphalt pavement anti-skid evaluation model serves as a theoretical foundation for understanding the actual influence on pavement anti-skid performance.
为检测 SMA-13 沥青路面的三维纹理结构并评估其防滑性能,利用非接触式三维激光扫描技术开发了光梯度增强机评估模型。研究重点是收集新铺设的 SMA-13 沥青路面的三维纹理数据。随后,利用小波变换重建路面的三维纹理,并利用离散傅里叶变换分离宏观纹理和微观纹理,从而计算出它们的特征。将三维纹理的宏观和微观特征以及摩擦系数输入模型。与线性回归和随机森林模型的对比分析表明,该模型具有更高的准确性和效率。训练集 R2 为 0.948,测试集 R2 为 0.842,可有效评估路面防滑性能。参数重要性分析表明,Rku 和 MPD 仍是评价路面防滑性能的有效指标。此外,不同的纹理指标对抗滑性能的影响也不尽相同。所建立的沥青路面防滑评价模型为了解路面防滑性能的实际影响奠定了理论基础。
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引用次数: 0
Dual Network Co-Crosslinked HNBR Composites with Enhanced Tribological Properties under Water Lubrication 在水润滑条件下具有更佳摩擦学特性的双网共交联丁腈橡胶复合材料
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-18 DOI: 10.3390/lubricants11120534
Hao Yu, Wuxuan Zheng, Caixia Zhang, Shoubing Chen, Guangke Tian, Tingmei Wang
Water-lubricated bearings play a critical role in underwater propulsion systems but are often prone to failure due to mechanical wear and vibration, especially under high loads and prolonged friction. In response to this issue, our study introduces a novel approach: a dual network co-crosslinking strategy utilizing hydrogenated nitrile butadiene rubber (HNBR). This strategy connects the rubber network with the epoxy network through epoxidized Eucommia ulmoides gum. A comprehensive analysis was conducted to assess the resulting composite’s damping, tribological, and mechanical properties. The results show that the material has excellent mechanical, damping, and tribological properties relative to pure HNBR, with a 65.9% increase in the damping temperature domain, a 78.5% increase in tensile strength, a low coefficient of friction of 0.022, and a high resistance to abrasion of 3.87 × 10−6 mm3/Nm. The successful synthesis of HNBR-based composites via the dual network co-crosslinking strategy underscores their potential as a practical solution for improving the reliability and prolonging the service life of water-lubricated bearings.
水润滑轴承在水下推进系统中起着至关重要的作用,但往往容易因机械磨损和振动而失效,尤其是在高负荷和长时间摩擦的情况下。针对这一问题,我们的研究引入了一种新方法:利用氢化丁腈橡胶(HNBR)的双网络共交联策略。该策略通过环氧化杜仲胶将橡胶网络与环氧网络连接起来。我们进行了一项综合分析,以评估由此产生的复合材料的阻尼、摩擦学和机械性能。结果表明,与纯 HNBR 相比,该材料具有优异的机械、阻尼和摩擦学性能,阻尼温度域提高了 65.9%,拉伸强度提高了 78.5%,摩擦系数低至 0.022,耐磨性高达 3.87 × 10-6 mm3/Nm。通过双网络共交联策略成功合成的基于 HNBR 的复合材料凸显了其作为一种实用解决方案的潜力,可用于提高水润滑轴承的可靠性并延长其使用寿命。
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引用次数: 0
Tribological Synergism of Anodic Aluminum Oxide Surface Containing Micro-Holes and Nanopores under Lubricated Reciprocation 含微孔和纳米孔的阳极氧化铝表面在润滑往复运动中的摩擦学协同作用
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-12-15 DOI: 10.3390/lubricants11120533
Minhaeng Cho
Micro-drilled aluminum surfaces containing micro-holes were anodized to produce nanopores over the machined and lapped surfaces. The anodized nanopores had an approximate diameter of 30–40 nm and a depth distribution of 20–30 μm from the surface. The diameter and depth of the machined micro-holes were 125 μm and 300 μm, respectively. Anodization itself did not change the surface roughness because the nanopores were very small. Ball-on-disk reciprocating tests were performed under lubricated conditions for 2 h using a frequency of 2 Hz, a load of 2 N, and a travel distance of 5 mm. The results showed that both the micro-drilled and anodized surfaces greatly reduced the coefficient of friction compared with the lapped bare surface; however, the coefficient of friction of the hole-textured specimen was not maintained till the end. Contrary to expectations, the lubricant retention capability of the textured structure declined because of hole failure that occurred during oscillation. This gradually increased friction until the end of the reciprocating test. When the micro-drilled surface was anodized, the coefficient of friction decreased again, implying that non-anodized micro-holes alone were ineffective for reducing friction. The surface hardness of Al increased owing to anodization, and thus the micro-holes remained intact. Therefore, it is concluded in this study that a prerequisite for friction reduction in Al is to increase the hardness to minimize the failure of micro-holes, which can be achieved by anodization. The synergistic lubricant retention capability can be maintained by the presence of both nanopores and micro-holes.
对含有微孔的微钻孔铝表面进行阳极氧化处理,以便在加工和研磨表面产生纳米孔。阳极氧化后的纳米孔直径约为 30-40 nm,深度分布在距离表面 20-30 μm 处。机加工微孔的直径和深度分别为 125 μm 和 300 μm。由于纳米孔非常小,阳极氧化本身并没有改变表面粗糙度。在润滑条件下进行了 2 小时的盘上球往复测试,测试频率为 2 Hz,载荷为 2 N,移动距离为 5 mm。结果表明,与研磨过的裸表面相比,微钻表面和阳极氧化表面都大大降低了摩擦系数;然而,孔纹理试样的摩擦系数并没有保持到最后。与预期相反,纹理结构的润滑剂保持能力下降了,原因是在摆动过程中出现了孔失效。这使得摩擦力逐渐增大,直至往复试验结束。当对微孔表面进行阳极氧化处理时,摩擦系数再次下降,这意味着仅靠未阳极氧化处理的微孔无法有效减少摩擦。由于阳极氧化,铝的表面硬度增加,因此微孔保持完好。因此,本研究得出结论,要减少铝的摩擦,前提条件是提高硬度,尽量减少微孔的失效,而阳极氧化可以实现这一点。纳米孔和微孔的存在可以保持协同的润滑剂保持能力。
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引用次数: 0
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