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Simple Deconvolution Models for Evaluating the True Microhardness of Thin Nanostructured Coatings Deposited via an Advanced Physical Vapor Deposition Technique 评估通过先进物理气相沉积技术沉积的纳米结构薄涂层真实显微硬度的简单去卷积模型
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-26 DOI: 10.3390/lubricants11120501
U. Kanders, K. Kanders, Ernests Jansons, Jānis Lungevičs, Raimonds Sirants, A. Leitans, Irina Boiko
This article discusses the micromechanical properties and true microhardness determination of nanostructured tribological coatings (NTCs) based on a multilayered alternating nitride/carbonitride bilayer substructure for transition metals. The constituent nitride/carbonitride bilayers in the superlattice structure of the NTC were alloyed with refractory metals, denoted as Me = Me1 or Me2= Cr, Hf, Nb, W, and Zr. The resulting NTC coatings were deposited onto 100Cr6 steel substrates using an advanced physical vapor deposition (PVD) technique, referred to here as high-power ion-plasma magnetron sputtering (HiPIPMS). The comprising crystalline nanometer-scale TiAlSiMe1-N/TiMe2-CN nanoparticles strengthened by Me additives significantly increased the NTC microhardness to over 3200 HV. The primary focus of this research was to determine the true microhardness of the NTC film samples. The apparent microhardness (Ha) of the film/substrate system for various NTC samples was measured during microindentation testing using the Vickers method. Nine NTC samples were tested, each generating a corresponding microindentation dataset containing between 430 and 640 imprints, depending on the specific NTC sample. These datasets were analyzed using three distinct empirical approaches: (i) the inverse power-law model (IPL-Model), (ii) the sigmoid-like decay model (SLD-Model), and (iii) the error function model (ERF-Model). The observed solid correlation between the proposed models and experiments suggests that the true microhardness estimates (Hf) obtained through the empirical mathematical modeling approach are reliable.
本文讨论了基于过渡金属多层交替氮化物/碳氮化物双层子结构的纳米结构摩擦涂层(NTC)的微机械性能和真实显微硬度测定。NTC 超晶格结构中的氮化物/氮化碳双层成分与难熔金属(用 Me = Me1 或 Me2= Cr、Hf、Nb、W 和 Zr 表示)进行了合金化。利用先进的物理气相沉积(PVD)技术(此处称为高功率离子等离子体磁控溅射(HiPIPMS)),将得到的 NTC 涂层沉积到 100Cr6 钢基底上。由结晶纳米级 TiAlSiMe1-N/TiMe2-CN 纳米粒子组成,并通过 Me 添加剂进行强化,显著提高了 NTC 显微硬度,使其超过 3200 HV。本研究的主要重点是确定 NTC 薄膜样品的真实显微硬度。在使用维氏方法进行显微压痕测试时,测量了各种 NTC 样品的薄膜/基底系统的表观显微硬度 (Ha)。测试了九种 NTC 样品,根据具体的 NTC 样品,每种样品都产生了相应的微压痕数据集,其中包含 430 到 640 个压痕。使用三种不同的经验方法对这些数据集进行了分析:(i) 反幂律模型(IPL 模型),(ii) 类西格玛衰减模型(SLD 模型),以及 (iii) 误差函数模型(ERF 模型)。所观察到的建议模型与实验之间的坚实相关性表明,通过经验数学建模方法获得的真实显微硬度估计值 (Hf) 是可靠的。
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引用次数: 0
Lubrication Performance of Misaligned Journal Bearings with Flexible Structure under Shock Load Conditions 冲击载荷条件下具有柔性结构的错位滑动轴承的润滑性能
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-25 DOI: 10.3390/lubricants11120500
Sung-Ho Hong, Woo-Ju Jeon
Bearings might be damaged due to shock loads caused by disturbances, in addition to static loads. In this study, a flexible structure was applied to enhance the lubrication characteristics of misaligned journal bearings subjected to impact loads. When an impact load is added to the bearing, a misaligned journal bearing has a high possibility of metal-to-metal contact. It might also lead to failure. Misalignment can occur at any time during bearing operation. A flexible structure is applied to the end of the bearing as a way to improve lubrication performance in a system where impact loads might be applied. The bearing’s lubrication performance was numerically assessed under unsteady-state conditions. An elastohydrodynamic lubrication analysis was conducted, taking into account elastic deformation. The lubrication characteristics of misaligned journal bearings were compared with the dimensionless minimum film thickness. The flexible structure and elastic modulus of the bearing were investigated so that it could support the load without contact according to the change in the maximum magnitude of the impact load. When subjected to oil film pressure, this flexible structure underwent elastic deformation, resulting in enlargement of the oil film. A misaligned journal bearing with a suitable flexible structure provided stable lubrication without metal-to-metal contact, even under shock load conditions. The flexible structure was incorporated into the high-load-bearing region of the journal bearing as a groove. Therefore, the application of a flexible structure in misaligned journal bearings can effectively enhance lubrication performance in misaligned conditions and under shock loads.
除静载荷外,轴承还可能因扰动引起的冲击载荷而损坏。本研究采用柔性结构来增强承受冲击载荷的错位轴颈轴承的润滑特性。当轴承受到冲击载荷时,错位轴颈轴承极有可能发生金属与金属之间的接触。这也可能导致失效。不对中可能发生在轴承运行的任何时候。在轴承的端部采用柔性结构,是在可能施加冲击载荷的系统中提高润滑性能的一种方法。在非稳态条件下,对轴承的润滑性能进行了数值评估。考虑到弹性变形,进行了弹性流体动力润滑分析。将错位轴颈轴承的润滑特性与无量纲最小油膜厚度进行了比较。研究了轴承的柔性结构和弹性模量,使其能够根据冲击载荷最大值的变化,在无接触的情况下支撑载荷。当受到油膜压力时,这种柔性结构发生弹性变形,导致油膜扩大。具有适当柔性结构的错位轴颈轴承即使在冲击载荷条件下也能提供无金属间接触的稳定润滑。柔性结构以沟槽的形式融入轴颈轴承的高承载区域。因此,在错位轴颈轴承中应用柔性结构可有效提高错位条件和冲击载荷下的润滑性能。
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引用次数: 0
On the Difference in the Action of Anti-Wear Additives in Hydrocarbon Oils and Vegetable Triglycerides 碳氢油和植物甘油三酯中抗磨添加剂作用的差异
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-24 DOI: 10.3390/lubricants11120499
I. Mukhortov, E. Zadorozhnaya, I. Levanov, Sergey Surovtcev
This paper examines the difference between the effects of anti-wear additives on vegetable and hydrocarbon-based oils. Knowledge of the specific influence of additives on the anti-wear properties of vegetable oils is necessary to increase the efficiency of the development of biodegradable lubricating oils. In addition, this is interesting from the point of view of clarifying the mechanism of action of AW/EP additives. The effect of non-toxic additives—adipic acid monoester and hexadecanol—on hydrocarbon hydrocracking oil and vegetable oil was compared. The comparison was carried out in rolling contact with sliding, sensitive to the separating ability of the oil. It was found that in hydrocarbon oil, the additive affects the parameters of the hydrodynamic friction regime. When adding an additive to vegetable oil, the hydrodynamic parameters do not change. The additive acts in the same way in both oils during mixed and transient modes. The obtained results are compared to available data, and an explanation of the difference is proposed based on the AW/EP mechanism of action. It is concluded that there is little chance of enhancing vegetable oil properties for hydrodynamic bearings. Search criteria for additives that effectively influence the antifriction and anti-wear properties of vegetable oils in mixed and boundary friction modes are proposed.
本文探讨了抗磨损添加剂对植物油和碳氢化合物基油的影响差异。要提高可生物降解润滑油的开发效率,就必须了解添加剂对植物油抗磨损性能的具体影响。此外,从阐明 AW/EP 添加剂的作用机理的角度来看,这也很有意义。我们比较了无毒添加剂--己二酸单酯和十六烷醇--对碳氢化合物加氢裂化油和植物油的影响。比较是在滚动与滑动接触中进行的,对油的分离能力很敏感。结果发现,在碳氢化合物油中,添加剂会影响流体动力摩擦机制的参数。在植物油中添加添加剂后,流体力学参数不会发生变化。在混合模式和瞬态模式下,添加剂在两种油中的作用相同。将获得的结果与现有数据进行了比较,并根据 AW/EP 的作用机理提出了差异的解释。结论是,在流体动力轴承中提高植物油性能的可能性很小。提出了在混合摩擦和边界摩擦模式下有效影响植物油抗摩擦和抗磨损性能的添加剂的搜索标准。
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引用次数: 0
Dynamic Instability of Rigid Shoe Modes in a Drum Brake System 鼓式制动器系统中刚性蹄模的动态不稳定性
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-22 DOI: 10.3390/lubricants11120496
Dongwoo Seo, Jaeyoung Kang
This study examined the dynamic instability of a drum brake induced by the rigid modes of the brake shoe. The brake shoe was modeled as a rigid curved plate subject to frictional contact with a rotating drum. In the presence of a negatively sloped friction curve, dynamic instability was numerically analyzed with respect to variation in the system parameters. The results showed that mode-coupling instability did not occur, but dynamic instability was induced by negative damping in a specific rigid mode, and its propensity varied with the operating conditions and geometric changes.
本研究探讨了由制动蹄的刚性模式引起的鼓式制动器的动态不稳定性。制动蹄被模拟为与旋转鼓发生摩擦接触的刚性弧形板。在存在负倾斜摩擦曲线的情况下,对系统参数变化的动态不稳定性进行了数值分析。结果表明,模式耦合不稳定性并未发生,但动态不稳定性是由特定刚性模式的负阻尼引起的,其倾向性随工作条件和几何变化而变化。
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引用次数: 0
Effect of Varying the Volume Fractions of Ledeburitic Cementite and Graphite on the Tribological Properties of Commercially Used Cast Irons 改变辉绿岩和石墨的体积分数对商用铸铁摩擦学特性的影响
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-22 DOI: 10.3390/lubricants11120498
Ł. Frocisz, Piotr Matusiewicz, Janusz Krawczyk
The types and volume fractions of the carbonaceous phases present in the microstructures of cast irons strongly influence their properties. In the case of materials used commercially for tools, an important parameter with regard to their use is the resistance to abrasion wear. Cementite is the main reinforcing phase in cast irons and is present in significant quantities. In addition, cast irons contain graphite precipitates, which also affect wear by interacting with the matrix of the alloys. In this study, abrasive wear tests were carried out on a group of cast irons with different chemical compositions and, consequently, different microstructural morphologies. Due to the wide scatter of the results and the commercial rather than laboratory nature of the alloys studied, it was decided to use analysis of variance (ANOVA) to determine whether there was a statistically significant difference between the volume fractions of the carbonaceous phases. The volume fractions of graphite and ledeburite were then related to the results of the tribological tests. Statistical analysis confirmed significant differences in the results obtained for the alloys tested. A continuous increase in the volume fractions of both graphite and ledeburitic cementite is unfavourable in terms of the wear resistance and friction coefficient values. Optimum results can be obtained by balancing the volume fractions of the two phases observed. In addition, the phase composition of the material matrix plays an important role in wear, as the differences in the matrix of the tested alloys modify the nature of the influence of cementite and graphite on the wear.
铸铁微结构中碳质相的类型和体积分数对其性能有很大影响。对于商业用途的工具材料,耐磨损性是其使用的一个重要参数。硬石膏是铸铁中的主要强化相,其含量很大。此外,铸铁中还含有石墨析出物,它们也会通过与合金基体相互作用而影响磨损。在这项研究中,我们对一组具有不同化学成分的铸铁进行了磨料磨损测试,这些铸铁的微观结构形态也随之不同。由于试验结果差异很大,而且所研究的合金属于商业性质而非实验室性质,因此决定采用方差分析(ANOVA)来确定碳质相的体积分数之间是否存在显著的统计学差异。然后将石墨和ledeburite 的体积分数与摩擦学测试结果联系起来。统计分析表明,所测试合金的结果存在明显差异。就耐磨性和摩擦系数值而言,石墨和ledeburitic cementite 体积分数的持续增加是不利的。平衡两种相的体积分数可获得最佳结果。此外,材料基体的相组成在磨损中起着重要作用,因为测试合金基体的差异会改变水泥土和石墨对磨损影响的性质。
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引用次数: 0
Machine Learning for Film Thickness Prediction in Elastohydrodynamic Lubricated Elliptical Contacts 用于弹流润滑椭圆形触头薄膜厚度预测的机器学习技术
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-22 DOI: 10.3390/lubricants11120497
Joe Issa, Alain El Hajj, Philippe Vergne, W. Habchi
This study extends the use of Machine Learning (ML) approaches for lubricant film thickness predictions to the general case of elliptical elastohydrodynamic (EHD) contacts, by considering wide and narrow contacts over a wide range of ellipticity and operating conditions. Finite element (FEM) simulations are used to generate substantial training and testing datasets that are used within the proposed ML framework. The complete dataset entails 915 samples; split into an 823-sample training dataset and a 92-sample testing dataset, corresponding to 90% and 10% of the combined dataset samples, respectively. The proposed ML model consists of a pre-processing stage in which conventional EHD dimensionless groups are used to minimize the number of inputs into the model, reducing them to only three. The core of the model is based on Gaussian Process Regression (GPR), a powerful ML regression tool, well-suited for small-sized datasets, producing output central and minimum film thicknesses, also in dimensionless form. The last stage is a post-processing one, in which the output film thicknesses are retrieved in dimensional from. The results reveal the capabilities and potential of the proposed ML framework, producing quasi-instantaneous predictions that are far more accurate than conventional film thickness analytical formulae. In fact, the produced central and minimum film thickness predictions are on average within 0.3% and 1.0% of the FEM results, respectively.
本研究将机器学习(ML)方法用于润滑油膜厚度预测的范围扩展到椭圆形弹性流体动力(EHD)接触的一般情况,考虑了宽椭圆度和工作条件范围内的宽接触和窄接触。有限元(FEM)模拟用于生成大量的训练和测试数据集,这些数据集可用于所提议的 ML 框架。完整的数据集包含 915 个样本;分为 823 个样本的训练数据集和 92 个样本的测试数据集,分别相当于综合数据集样本的 90% 和 10%。所提出的 ML 模型包括一个预处理阶段,在该阶段中使用传统的 EHD 无量纲组,以最大限度地减少模型输入的数量,将其减少到仅有三个。该模型的核心基于高斯过程回归 (GPR),这是一种功能强大的 ML 回归工具,非常适合小型数据集,可生成无量纲形式的输出中心膜厚和最小膜厚。最后一个阶段是后处理阶段,输出的薄膜厚度以无量纲形式进行检索。结果揭示了所提出的 ML 框架的能力和潜力,其产生的准瞬时预测结果比传统的薄膜厚度分析公式精确得多。事实上,所生成的中心和最小薄膜厚度预测值与有限元计算结果的平均误差分别在 0.3% 和 1.0% 以内。
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引用次数: 0
Modeling the Pumping Behavior of Macroscopic Lead Structures on Shaft Counterfaces of Rotary Shaft Seals 旋转轴密封轴台面宏观引线结构的泵送行为建模
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-20 DOI: 10.3390/lubricants11110495
Maximilian Engelfried, Georg Haffner, Matthias Baumann, F. Bauer
The leak tightness of the sealing system rotary shaft seal is based on the formation of an active back-pumping effect of the sealing ring. Here, the sealing ring pumps the fluid in the sealing gap back into the housing. However, this active sealing mechanism is disturbed by so-called “lead structures”. Lead structures include all types of directional structures on the sealing counterface which create rotation-dependent axial fluid pumping. Lead-affected sealing counterfaces can thus cause leakage or insufficient lubrication of the sealing contact. To ensure leak tightness, lead must be avoided or tolerated. This article investigates how different structural characteristics of lead affect the amount of fluid pumped by the shaft surface. For this purpose, 26 shafts are subjected to surface analyzing methods and an experimental pumping rate test. The interaction of various geometric features of the lead structures and their combined effect on the pumping capacity is modeled based on the measured data. Appropriated correlation models are discussed and relationships between shaft lead and its pumping effect are shown. The aim is to estimate shaft pumping rates based on surface measurements in future. The results contribute to the derivation of measurable tolerance values for lead and to the prevention of leakage.
密封系统旋转轴密封的泄漏密封性基于密封环形成的主动反泵效应。在这里,密封环将密封间隙中的流体泵回外壳中。然而,这种主动密封机制会受到所谓的 "引线结构 "的干扰。引线结构包括密封台面上的各种定向结构,这些结构会产生与旋转有关的轴向流体泵送。因此,受铅影响的密封面会导致密封接触面泄漏或润滑不足。为确保密封性,必须避免或容忍铅的存在。本文研究了铅的不同结构特征如何影响轴表面泵送的流体量。为此,对 26 个轴进行了表面分析方法和实验性泵送率测试。在测量数据的基础上,对铅结构的各种几何特征之间的相互作用及其对泵送能力的综合影响进行了建模。对适当的相关模型进行了讨论,并展示了竖井引水及其抽水效果之间的关系。目的是在未来根据表面测量结果估算竖井的抽水率。研究结果有助于推导出可测量的铅容许值和防止泄漏。
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引用次数: 0
Comparison of Machining Performance of Ti-6Al-4V under Dry and Cryogenic Techniques Based on Tool Wear, Surface Roughness, and Power Consumption 基于刀具磨损、表面粗糙度和功耗的干式和低温技术下 Ti-6Al-4V 加工性能比较
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-15 DOI: 10.3390/lubricants11110493
Dhvanil Chauhan, M. Makhesana, R. R. Rahman Rashid, Vivek Joshi, Navneet Khanna
The machining of Ti-6Al-4V alloys is challenging due to their high strength, poor thermal conductivity, and high chemical reactivity. When used in traditional machining, cryogenic coolants can reduce tool wear, thus extending tool life, improving surface finish, and requiring less power with reduced environmental effects. In this context, this study aimed to perform a machinability analysis of the surface roughness, power consumption, tool wear, and specific energy consumption of a Ti-6Al-4V titanium alloy and to comprehend the performance of dry and cryogenic machining in turning operations. A comprehensive analysis of tool wear and specific cutting energy (SCE) under dry and cryogenic machining was conducted. It was found that the machining time under a cryogenic environment was increased by 83% and 39% at 80 and 90 m/min compared to a cutting speed at 100 m/min. The higher cutting speed (100 m/min) in cryogenic environments produced an improved surface finish. Compared to dry machining, the cooling effect of liquid CO2 helped dissipate heat and reduce thermal damage, improving surface finish. The findings revealed that in dry conditions, approximately 5.55%, 26.45%, and 27.61% less power was consumed than in cryogenic conditions at 80, 90, and 100 m/min cutting speeds, respectively. Based on the outcomes of the work, the application of cryogenic cooling can be considered an alternative to dry and flood cooling for improving the machinability of Ti-6Al-4V alloys.
由于 Ti-6Al-4V 合金具有强度高、导热性差和化学反应性高等特点,因此对其进行加工是一项挑战。在传统加工中使用低温冷却剂时,可以减少刀具磨损,从而延长刀具寿命,提高表面光洁度,并减少对环境的影响。在此背景下,本研究旨在对 Ti-6Al-4V 钛合金的表面粗糙度、功率消耗、刀具磨损和比能量消耗进行可加工性分析,并了解车削操作中干式加工和低温加工的性能。对干式和低温加工下的刀具磨损和比切削能量(SCE)进行了综合分析。结果发现,与 100 米/分钟的切削速度相比,80 米/分钟和 90 米/分钟的低温环境下的加工时间分别增加了 83% 和 39%。在低温环境下,较高的切削速度(100 米/分钟)可提高表面光洁度。与干式加工相比,液态二氧化碳的冷却效果有助于散热和减少热损伤,从而提高表面光洁度。研究结果表明,在 80、90 和 100 米/分钟的切削速度下,干式条件下的功率消耗比低温条件下分别低约 5.55%、26.45% 和 27.61%。根据这项工作的结果,可以认为应用低温冷却可替代干冷和泛冷,以提高 Ti-6Al-4V 合金的加工性能。
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引用次数: 0
Olive Pomace Oil as a Chainsaw Lubricant: First Results of Tests on Performance and Safety Aspects 橄榄渣油作为电锯润滑油:性能和安全方面测试的初步结果
IF 3.5 3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-15 DOI: 10.3390/lubricants11110494
R. Fanigliulo, Paolo Bondioli, M. Biocca, R. Grilli, P. Gallo, L. Fornaciari, L. Folegatti, Stefano Benigni, Igor Calderari, Francesco Gallucci, D. Pochi
The total loss lubrication system that is typical of chainsaws is responsible for a massive dispersion in the agro-forestry environment of highly impactful pollutants, mostly of fossil origin, often well known as carcinogenic substances, which, in addition to presenting a risk to the environment, represent an important risk factor for human health, especially for chainsaw users. During its use, the chain lubricant is dispersed from the guide bar tip in the form of droplets and aerosol, or it is adsorbed on wood residues and sawdust. Then, it is subjected to drift, settles on the ground and vegetation, and can hit the operators, who, after prolonged exposures, can suffer both irritation of the respiratory tract and dermal absorption. Such a risk factor is often amplified by the widespread use of less-expensive, sometimes illegal alternatives, such as exhausted motor oils. To mitigate said negative effects, a process has been in progress for several years that is aimed at replacing conventional lubricants with synthetic or biobased oils with increasing biodegradability. As a contribution to this process, a study has been started on the possibility of using refined olive pomace oil (ROPO) as a base stock for the formulation of a totally biodegradable chainsaw lubricant. On purpose, to improve its properties of viscosity and adhesivity, such an oil was added with a biodegradable thickening agent, obtaining four formulations with different viscosity. After a lab test and a preliminary cutting test on firewood, the formulation with 2% of thickener resulted in being the best, and 3.0 g kg−1 of tert-butylhydroquinone (TBHQ), a food-grade antioxidant, was then added to form the final formulation (F2) to be compared, in the subsequent four test sessions, to a biodegradable commercial chain lubricant (SB). The tests were carried out without changing the chainsaw setting, on different wood species, both in forest and, with the aim of increasing the repeatability of tests conditions and comparability of results, at a fixed point. The fluids’ performances were mainly evaluated based both on the operators’ opinions and on the measurements of the chain–bar temperatures and of saw chain wear related to a predefined number of cuts. As to the destiny of the fluid dispersed during cutting, the overall dispersion was assessed by considering the average working time, the consumption of chain lubricant, and the forest area cut down daily. Eventually, the amounts of inhalable and respirable dust particles as vectors of oil residues were quantified by means of personal air samplers worn by the operators and analyzed to determine any differences in the concentration of metallic elements. The test results evidenced chain temperatures that were 0.5, 4.9, and 12.5 °C higher with F2 relating to SB, respectively, in the cutting of trunks of fresh Pinus, Eucalyptus, and dry Pinus. They were accompanied by chain weight losses of 89.5% and 35% higher with F2 relating to SB, respe
油锯典型的全损耗润滑系统在农林业环境中造成了大量具有高度影响的污染物的扩散,这些污染物大多来自化石,通常是众所周知的致癌物质,除了对环境造成危害外,还对人类健康,尤其是油锯使用者的健康造成了重大危害。在使用过程中,链条润滑剂会以液滴和气溶胶的形式从导杆顶端散出,或吸附在木材残渣和锯屑上。然后,润滑油会飘散到地面和植被上,并击中操作人员,长时间接触后,操作人员的呼吸道会受到刺激,皮肤也会吸收。这种风险因素往往因广泛使用价格较低、有时甚至是非法的替代品(如用完的机油)而放大。为了减轻上述负面影响,多年来一直在开展一项工作,旨在用生物降解性更强的合成油或生物基油取代传统润滑油。作为对这一进程的贡献,已开始研究使用精炼橄榄渣油 (ROPO) 作为基础油来配制完全可生物降解的链锯润滑油的可能性。为了提高这种油的粘度和粘附性,研究人员在其中添加了一种可生物降解的增稠剂,从而获得了四种粘度不同的配方。经过实验室测试和在木柴上的初步切割测试后,添加 2% 增稠剂的配方效果最佳,然后添加 3.0 g kg-1 的食品级抗氧化剂叔丁基对苯二酚 (TBHQ),形成最终配方 (F2),并在随后的四个测试环节中与可生物降解的商用链条润滑剂 (SB) 进行比较。测试是在不改变链锯设置的情况下进行的,测试对象既包括森林中的不同木种,也包括固定点上的不同木种,目的是提高测试条件的可重复性和结果的可比性。对润滑油性能的评估主要基于操作员的意见、对链条温度的测量以及与预定切割次数相关的锯链磨损情况。至于切割过程中流体的散布情况,则通过考虑平均工作时间、链条润滑剂的消耗量和每天砍伐的森林面积来评估整体散布情况。最后,通过操作员佩戴的个人空气采样器,对作为油残留物载体的可吸入和可吸入粉尘颗粒的数量进行了量化,并进行了分析,以确定金属元素浓度的任何差异。测试结果表明,在切割新鲜松树、桉树和干松树树干时,F2 与 SB 的链温度分别高出 0.5、4.9 和 12.5 °C。在土耳其栎和白杨的切割试验中,与 SB 有关的 F2 的链重量损失分别高出 89.5% 和 35%。不过,这种较大的磨损显然不会影响使用 F2 的锯链的切割效率,因为操作人员表示,在进行比较时,他们没有发现两种润滑油的性能有任何不同。至于磨损加剧对链条寿命的影响、对操作员安全的风险以及降低 F2 磨损水平的可能性,将在进一步的研究中进行探讨,例如通过对链锯润滑系统进行不同的设置。对空气中残留粉尘的采样分析结果表明,使用 F2 时,可吸入颗粒物和某些金属元素(Al、Mg 和 Ca)的浓度低于使用 SB 时。这种情况可能是由于锯屑与两种流体之间的相互作用不同造成的,这两种流体的化学物理特性不同(粘度、成分和添加剂不同)。不过,这是一个有利于使用基于 ROPO 的润滑剂的积极因素,其残留物的完全生物降解性(可能包含在操作员吸入的粉尘中)也强调了这一点。
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引用次数: 0
Tribological Property of Al3BC3 Ceramic: A Lightweight Material 轻质材料Al3BC3陶瓷的摩擦学性能
3区 工程技术 Q2 ENGINEERING, MECHANICAL Pub Date : 2023-11-14 DOI: 10.3390/lubricants11110492
Jinjun Lu, Rong Qu, Fuyan Liu, Tao Wang, Qinglun Che, Yanan Qiao, Ruiqing Yao
Lightweight materials with a density less than 3 g/cm3 as potential tribo-materials for tribological applications (e.g., space tribology) are always desired. Al3BC3 ceramic, a kind of ternary material, is one of the lightweight materials. In this study, dense Al3BC3 ceramic is prepared via a reactive hot-pressing process in a vacuum furnace. Its tribological properties are investigated in two unlubricated conditions (one is at elevated temperature up to 700 °C in air, and another is in a vacuum chamber of back pressures from 105 Pa to 10−2 Pa at room temperature) and lubricated conditions (i.e., water and ethanol as low-viscosity fluids). At 400 °C and lower temperatures in air, as well as in vacuum, the tribological property of Al3BC3 ceramic is poor due to the fracture of grains and formation of a mechanically mixed layer. The beneficial influence of adsorbed gas species on reducing friction is very limited. Due to the formation of lubricious tribo-oxide at 600 °C and 700 °C, the friction coefficient is reduced from ca. 0.9 at room temperature and 400 °C to ca. 0.4. In the presence of low-viscosity fluids, a high friction coefficient and wear but a polished surface are observed in water, while a low friction coefficient and wear occur in ethanol. A lubricious carbide-derived carbon (CDC) coating on top of Al3BC3 ceramic through high-temperature chlorination can be fabricated and the wear resistance of CDC can be improved by adjusting the chlorination parameters. The above results suggest that Al3BC3 ceramic is a potential lubricating material for some tribological applications.
密度小于3g /cm3的轻质材料是摩擦学应用(如空间摩擦学)的潜在摩擦学材料。Al3BC3陶瓷是一种三元材料,是轻质材料之一。本研究采用真空炉反应热压法制备致密Al3BC3陶瓷。在两种无润滑条件下(一种是在空气中高达700℃的高温下,另一种是在室温下背压从105 Pa到10 - 2 Pa的真空室中)和润滑条件下(即水和乙醇作为低粘度流体),研究了其摩擦学性能。在空气和真空中,在400℃及更低温度下,由于晶粒断裂和形成机械混合层,Al3BC3陶瓷的摩擦学性能较差。吸附气体种类对减少摩擦的有益影响是非常有限的。由于在600°C和700°C形成了有色氧化三氮,摩擦系数从室温和400°C时的约0.9降低到约0.4。当存在低粘度流体时,在水中观察到高摩擦系数和磨损,但表面光滑,而在乙醇中观察到低摩擦系数和磨损。通过高温氯化法制备了Al3BC3陶瓷表面的有色碳化物衍生碳(CDC)涂层,通过调整氯化工艺参数可以提高CDC的耐磨性。上述结果表明,Al3BC3陶瓷是一种潜在的摩擦学润滑材料。
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