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Hierarchically heterogeneous microstructure and mechanical behavior of the multi-materials prepared by powder severe plastic deformation 粉末剧烈塑性变形制备的复合材料的层次非均相组织和力学行为
1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-19 DOI: 10.1080/21663831.2023.2258158
Sujung Son, Jungwan Lee, Peyman Asghari-Rad, Rae Eon Kim, Hyojin Park, Jae-il Jang, Wen Chen, Yoon-Uk Heo, Hyoung Seop Kim
A heterostructuring strategy is an effective approach for abiding problems referred to as the strength-ductility trade-off. However, tailoring the heterostructure is an arduous problem. This work synthesized hierarchically heterogeneity by combining the eutectic high-entropy alloy (EHEA) and medium-entropy alloy powders through novel powder metallurgy-based severe plastic deformation (P-SPD). EHEA forms nano-scaled heterogeneity composed of FCC and B2, and the mixture of powder types forms micro-scale heterogeneity with hard and soft domains. This hierarchically heterogeneous microstructure leads to strong hetero-deformation-induced strengthening, achieving a yield strength of ∼1.5 GPa. The present P-SPD represents the feasibility of heterostructuring, aiding the development of HEAs.
异质结构策略是解决强度-延性权衡问题的有效方法。然而,调整异质结构是一个艰巨的问题。本研究通过新型粉末冶金的严重塑性变形(P-SPD),将共晶高熵合金(EHEA)和中熵合金粉末结合,合成了分层非均质性。EHEA形成由FCC和B2组成的纳米尺度非均质性,粉末类型混合物形成具有硬域和软域的微观尺度非均质性。这种分层不均匀的微观结构导致了强烈的异质变形诱导强化,达到了1.5 GPa的屈服强度。该P-SPD代表了异质结构的可行性,有助于HEAs的发展。
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引用次数: 0
Revealing the mechanical behavior of homogeneous dislocation cell units in high-entropy alloy 揭示高熵合金中均相位错胞单元的力学行为
1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-19 DOI: 10.1080/21663831.2023.2256359
Liangxue Zhang, Qingsong Pan, Lei Lu
Gradient dislocation cell structured Al0.1CoCrFeNi high-entropy alloys exhibited exceptional strength and uniform ductility. HEA containing homogeneous dislocation cells, with the average size varying from 0.29 to 0.43 μm was observed to still exhibit a superior combination of high strength and good uniform elongation, distinct from traditional strong ultrafine-grained structures with limited ductility. This is because the initial dislocation cells tend to be progressively patterned into dense dislocation walls upon straining, associated with the massive dislocation motion and accumulation. The gradient-induced additional strain hardening behavior was clarified by directly comparing the mechanical behavior of the homogeneous and gradient samples.
梯度位错胞结构的Al0.1CoCrFeNi高熵合金表现出优异的强度和均匀的塑性。平均尺寸在0.29 ~ 0.43 μm之间的均匀位错胞,与传统的强超细晶组织相比,仍然具有优异的高强度和均匀伸长率。这是因为最初的位错细胞在拉伸时趋向于逐渐形成密集的位错壁,与大量的位错运动和积累有关。通过直接比较均匀和梯度试样的力学行为,明确了梯度诱导的附加应变硬化行为。
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引用次数: 0
High-temperature creep-induced site occupation evolution in the γ′ lattice in a Ru-bearing Ni-based superalloy 含ru镍基高温合金γ′晶格中高温蠕变诱导的占位演化
1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-13 DOI: 10.1080/21663831.2023.2254910
Yunsong Zhao, Na Li, Li Wang, Junyang He, Weihong Liu, Min Song
By using state-of-the-art characterisation techniques including atom probe tomography and atomic resolved elemental mapping, we successfully probed the site occupation evolution associated with composition change in γ′, during 1100°C creep of a fourth generation Ru-bearing Ni-based superalloy. It is quantified that, W and Ru maintain unchanged site preference after creep rupture, while interestingly, the rest elements especially Co, Ta and Re show a weakened preference at both α- and β-sites in the γ′ lattice. This indicates the overall reduced γ′ ordering degree and thus the possible decrease in planar fault energies, which further facilitates dislocation shearing in γ′.
通过使用最先进的表征技术,包括原子探针断层扫描和原子分辨元素映射,我们成功地探测了第四代含钌镍基高温合金在1100℃蠕变过程中与γ′成分变化相关的位点占据演变。结果表明,W和Ru在蠕变破裂后仍保持不变的位置偏好,而Co、Ta和Re等元素在γ′晶格中α-和β-位置的偏好减弱。这表明γ′有序度总体降低,从而可能导致平面断层能降低,进一步促进了γ′位错剪切。
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引用次数: 0
In-situ EBSD investigation of orientation induced mechanical anisotropy in selective laser melted Al-Mn-Sc alloy 选择性激光熔化Al-Mn-Sc合金取向诱导力学各向异性的原位EBSD研究
1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-13 DOI: 10.1080/21663831.2023.2255218
Wei Jiang, Yunlai Deng, Qingsong Dai, Xiaobin Guo
The mechanical anisotropy of selective laser melted (SLM) aluminum alloys resulting from heterogeneous grain structures is still not fully understood due to lacking study of grain orientation related mechanical response. Here, by introducing in-situ EBSD tensile method, the orientation induced anisotropy coefficient Ka related to the deformation-induced grain rotation was revealed by excluding effects of grain size and grain aspect ratio. Compared with traditional mechanical properties models by Taylor factor M, it was found that the orientation <001 > in as-built and <102 > in heat treatment contributed the most yield strength anisotropy, and introducing Ka predicts the mechanical anisotropy more accurately.
由于缺乏与晶粒取向相关的力学响应研究,选择性激光熔化(SLM)铝合金由非均质晶粒组织引起的力学各向异性仍未完全了解。本文通过引入原位EBSD拉伸方法,排除晶粒尺寸和晶粒长径比的影响,揭示了与变形诱导晶粒旋转相关的取向诱导各向异性系数Ka。通过Taylor因子M与传统力学性能模型的比较,发现原位取向和热处理取向对屈服强度各向异性的贡献最大,引入Ka能更准确地预测力学各向异性。
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引用次数: 0
In situ TEM study of the thermal stability of nanotwinned Ni-Mo-W alloys 纳米孪晶Ni-Mo-W合金热稳定性的原位透射电镜研究
1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-11 DOI: 10.1080/21663831.2023.2255321
Mo-Rigen He, Ruopeng Zhang, Rohan Dhall, Andrew M. Minor, Kevin J. Hemker
Microstructural evolution in nanotwinned Ni-Mo-W alloys under in situ heating experiments is investigated in a transmission electron microscope. Migration of twin boundaries and grain boundaries as well as formation of carbide precipitates are observed at various temperatures and characterized at atomic resolution. These transformations are found to occur at temperatures that are ∼200°C lower in Mo-rich (Ni85Mo13W2) specimens than in W-rich (Ni86Mo3W11) specimens, which highlights the different efficacy of Mo and W solutes in stabilizing the nanotwinned structure. Inspection of various mechanisms points to the importance of elastic modulus mismatch as a pathway for enhancing nanotwin stability by alloying. GRAPHICAL ABSTRACT IMPACT STATEMENT We present the first in situ and atomic-resolution study of the thermal stability of nanotwinned alloys. Comparison of Mo-rich and W-rich Ni-Mo-W alloys uncovers the nontrivial role of solute species.
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引用次数: 0
Role of microscopic degrees of freedom in mechanical response of bicrystal nanopillars 微观自由度在双晶纳米柱力学响应中的作用
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-06 DOI: 10.1080/21663831.2023.2252885
Avanish Mishra, K. Dang, Edward M. Kober, S. Fensin, Nithin Mathew
This study investigated the high-strain rate deformation of bicrystal Cu nanopillars, using atomistic simulations. Nanopillars with minimum grain boundary energy were deformed to investigate the role of macroscopic degrees of freedom, finding that geometric parameters (Schmid factor) influence the stress–strain response. The deformation of metastable grain boundaries (GBs) revealed that in addition to geometric parameters, the response was also governed by the local atomic arrangement at the boundary, dictating the dislocation-GB interactions. These findings shed light on the response of nanopillars as a function of GBs and show the importance of both macroscopic and microscopic degrees of freedom on the mechanical response. GRAPHICAL ABSTRACT IMPACT STATEMENT Metastable states, an often ignored aspect of GB structure, is shown to have a strong influence on dislocation-GB interactions; shedding new light on mechanical response of realistic GBs.
本研究采用原子模拟的方法研究了双晶铜纳米柱的高应变速率变形。对晶界能最小的纳米柱进行变形,研究宏观自由度对其应力应变响应的影响,发现几何参数(施密德因子)对其应力应变响应有影响。亚稳晶界(gb)的变形表明,除了几何参数外,响应还受边界上局部原子排列的控制,这决定了位错- gb相互作用。这些发现揭示了纳米柱作为GBs的函数的响应,并显示了宏观和微观自由度对力学响应的重要性。亚稳态,一个经常被忽略的GB结构方面,被证明对位错-GB相互作用有很强的影响;对真实gb的力学响应有了新的认识。
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引用次数: 0
Heterostructured titanium composites with superior strength-ductility synergy via controllable bimodal grains and dislocation activity 通过可控的双峰晶粒和位错活动具有优异强度-延展性协同作用的异质结构钛复合材料
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-05 DOI: 10.1080/21663831.2023.2252858
Jiajing Chen, Yuanfei Han, Zichao Wei, Shaopeng Li, Zhonggang Sun, Liang Zhang, Guangfa Huang, Jianwen Le, Di Zhang, Weijie Lu
Constructing heterostructures in particulate reinforced titanium matrix composites (PRTMCs) to evade the strength-ductility trade-off dilemma is much more difficult than in metals. Here, we proposed a novel and controllable strategy of simple powder assembly to fabricate bimodal-grained PRTMCs, this customized strategy makes coarse grains (CGs) surrounded by ultrafine-grained (UFG) matrices, conferring a superior strength-ductility combination not achievable by their traditional homogeneous counterparts. We found that such heterostructures appear to promote storage of mostly dislocations in CGs and accumulation near the CG/UFG boundaries. Moreover, hybrid reinforcements also activate multiple hardening mechanisms, inducing high ductility. GRAPHICAL ABSTRACT IMPACT STATEMENT We proposed a novel and controllable strategy of simple powder assembly to fabricate heterostructured metal matrix composites for breaking the strength-ductility trade-off dilemma and revealed the enhanced dislocation activity.
在颗粒增强钛基复合材料(PRTMCs)中构建异质结构以避免强度-延性权衡困境比金属材料要困难得多。在这里,我们提出了一种新的和可控的简单粉末组装策略来制造双模晶prtmc,这种定制的策略使粗晶粒(CGs)被超细晶粒(UFG)矩阵包围,赋予传统的均匀材料无法实现的优越的强度-延展性组合。我们发现这种异质结构似乎促进了大部分位错在CG中的储存和在CG/UFG边界附近的积累。此外,混杂增强材料还激活了多种硬化机制,从而产生了高延性。本文提出了一种新的、可控的简单粉末组装方法来制备异质结构金属基复合材料,打破了强度-塑性权衡的困境,并揭示了位错活性的增强。
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引用次数: 0
A method for increasing the supersolvus critical strain for recrystallization in single-crystal superalloys 提高单晶高温合金再结晶超溶质临界应变的方法
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-04 DOI: 10.1080/21663831.2023.2253267
Sicong Lin, Kai Chen, Qiang Zeng, U. Ramamurty
Recrystallization, possibly triggered during heat treatments by plastic strains of only 1–2%, is highly deleterious to Ni-based single-crystal superalloys. Herein, we successfully recover plastic deformation and enhance the supersolvus critical strain for recrystallization by ramping the annealing temperature slowly from 1100 °C to γ′-solvus point. This preempts recrystallization during the subsequent supersolvus solutionizing treatment. The proposed method is validated in single-crystals compressed to 5.9% plastic strain at room temperature. After supersolvus solutionizing, an almost dislocation-free single-crystal with uniformly distributed γ′-precipitates is obtained. The proposed method offers a practical means to bring down the overall expenses of single-crystal turbine blades. GRAPHICAL ABSTRACT IMPACT STATEMENT An optimized pre-solutionizing recovery heat treatment can elevate the critical plastic strain value for recrystallization in Ni-based superalloy single-crystals to 3 times higher than previously established.
再结晶对镍基单晶高温合金非常有害,可能在热处理过程中仅由1-2%的塑性应变触发。通过将退火温度从1100℃缓慢升高到γ′溶点,我们成功地恢复了塑性变形,并提高了再结晶的超溶剂临界应变。这可以防止在随后的超溶剂固溶处理过程中再结晶。该方法在单晶压缩至5.9%塑性应变的室温条件下得到了验证。经超溶剂固溶后,得到了几乎无位错的单晶,其γ′析出相分布均匀。该方法为降低单晶涡轮叶片的总体成本提供了一种实用的方法。优化后的预固溶恢复热处理可将ni基高温合金单晶再结晶的临界塑性应变值提高到原来的3倍。
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引用次数: 0
Understanding creep behaviors of additively manufactured 316L stainless steel via void characterization 通过孔隙表征了解添加制造316L不锈钢的蠕变行为
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-01 DOI: 10.1080/21663831.2023.2244969
Xuan Zhang, Christopher P. Carter, Yashas Satapathy, A. Tekawade, J. Park, P. Kenesei, Meimei Li
Additively manufactured (AM) 316L stainless steel (SS) has been reported to have low creep resistance compared to its conventionally made counterparts. Herein, we quantitatively characterized the voids in a creep-ruptured AM 316L SS specimen and those in a conventional specimen ruptured under the same testing condition. The AM 316L SS contained more small creep voids and fewer large ones. 3D reconstructions showed the spatial distribution of the small voids in AM 316L SS followed the melt pool tracks, which was attributed to the grain structure unique to the laser process. The observations explained the creep behaviors of the two specimens. GRAPHICAL ABSTRACT IMPACT STATEMENT This paper reports that the grain structure resulted from the laser printing process has critical effects on the creep void formation in AM 316L SS.
据报道,与传统制造的不锈钢相比,添加制造的(AM)316L不锈钢(SS)具有较低的抗蠕变性能。在此,我们对蠕变破裂的AM 316L SS试样和在相同测试条件下破裂的常规试样中的孔隙进行了定量表征。AM 316L SS包含更多的小蠕变孔隙,而较少的大蠕变孔隙。3D重建显示,AM 316L SS中的小空隙沿着熔池轨迹的空间分布,这归因于激光工艺特有的晶粒结构。观察结果解释了两个试样的蠕变行为。图形摘要影响声明本文报道了激光印刷工艺产生的晶粒结构对AM 316L SS中蠕变孔隙的形成具有关键影响。
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引用次数: 0
Mechanism analysis of grain growth dominated by alloy composition gradients during powder bed fusion 粉末床熔合过程中合金成分梯度主导晶粒长大的机理分析
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-09-01 DOI: 10.1080/21663831.2023.2250826
Liming Yao, Zhongmin Xiao, Zhiongsheng Hoo, Chao Tang, Jing Qiao, Yanmei Zhang
A multi-physics simulation model has been established to investigate the influence of Laser powder bed fusion parameters on the spatial composition distribution and grain growth mechanism of the single-track printed dissimilar alloys. Our study shows that alloy composition gradient isosurfaces can be used to visualize the spatial distribution of alloy composition for miscible dissimilar alloys. When the melt pool aspect ratio changes from large to small, the grain growth transitions from the temperature gradient mode to composition gradient mode and then to the mixed mode. Our experimental observations show that in extreme cases, the curved grain angle can reach 272°. GRAPHICAL ABSTRACT IMPACT STATEMENT The study found that the composition gradient of dissimilar alloys can dominate grain growth, which is entirely different from the conventional temperature gradient-dominated grain growth mechanism.
建立了一个多物理模拟模型,研究了激光粉末床聚变参数对单轨印刷异种合金空间成分分布和晶粒生长机制的影响。我们的研究表明,合金成分梯度等值面可以用于可视化可混溶的不同合金的合金成分的空间分布。当熔池长宽比由大变小时,晶粒生长从温度梯度模式转变为成分梯度模式,然后转变为混合模式。我们的实验观察表明,在极端情况下,弯曲晶粒的角度可以达到272°。图形摘要影响声明研究发现,不同合金的成分梯度可以主导晶粒生长,这与传统的温度梯度主导晶粒生长机制完全不同。
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引用次数: 1
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Materials Research Letters
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