首页 > 最新文献

Materials Processing & Manufacturing eJournal最新文献

英文 中文
Deformed Microstructure Characteristics and Nano-Mechanical Properties of CuSn10P1 Alloy CuSn10P1合金的变形组织特征及纳米力学性能
Pub Date : 2020-01-01 DOI: 10.2139/ssrn.3680271
Quiping Wang, R. Zhou, Yongkun Li, Chunjian Wang
Enclosed cooling slope channel was adopted to prepare CuSn10P1 semi-solid sample. Compared with as-cast sample by conventional liquid forming, the brittle phases among intergranular microstructure reduced, which prevented the risk of thermal cracks. During hot deformation process, the formation and movement of dislocations results in slipping bands. The β' -Cu13.7Sn phase balanced the Young's modulus in the microstructure and improved the ability of coordinated deformation among grains. These findings provide a theoretical guidance for semi-solid CuSn10P1 deformation process.
采用封闭冷却坡道制备CuSn10P1半固态样品。与常规液态成形的铸态试样相比,晶间组织中的脆性相减少,避免了热裂纹的发生。在热变形过程中,位错的形成和移动导致滑动带的产生。β′-Cu13.7Sn相平衡了杨氏模量,提高了晶粒间协调变形的能力。这些发现为半固态CuSn10P1的变形过程提供了理论指导。
{"title":"Deformed Microstructure Characteristics and Nano-Mechanical Properties of CuSn10P1 Alloy","authors":"Quiping Wang, R. Zhou, Yongkun Li, Chunjian Wang","doi":"10.2139/ssrn.3680271","DOIUrl":"https://doi.org/10.2139/ssrn.3680271","url":null,"abstract":"Enclosed cooling slope channel was adopted to prepare CuSn10P1 semi-solid sample. Compared with as-cast sample by conventional liquid forming, the brittle phases among intergranular microstructure reduced, which prevented the risk of thermal cracks. During hot deformation process, the formation and movement of dislocations results in slipping bands. The β' -Cu13.7Sn phase balanced the Young's modulus in the microstructure and improved the ability of coordinated deformation among grains. These findings provide a theoretical guidance for semi-solid CuSn10P1 deformation process.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"28 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82334006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oxide Dispersoid Strengthened CoCrFeMnNi High-Entropy Alloy: The Effects of Y2O3 Addition and Y Alloying 氧化物分散体强化CoCrFeMnNi高熵合金:添加Y2O3和Y合金化的影响
Pub Date : 2020-01-01 DOI: 10.2139/ssrn.3680402
Seunghyeok Chung, Bin Lee, S. Lee, Changwoo Do, H. Ryu
Oxide dispersion strengthened CoCrFeMnNi high-entropy alloys (ODS-HEAs) were prepared using two different powder preparation methods classified by yttrium addition strategy to investigate the effects of in-situ and ex-situ oxide dispersoid formation on the microstructure and mechanical properties. Systematic microstructural analysis was carried out by X-ray diffraction (XRD), electron backscattered diffraction (EBSD), high-resolution transmission electron microscopy (HRTEM), atom probe tomography (APT), and small-angle neutron scattering (SANS). Cryo-milled powder analysis, grain structure evolution after spark plasma sintering, dispersoid characteristics, and matrix/dispersoid interface structure analysis of the in-situ and ex-situ dispersoids within the high-entropy alloy (HEA) matrix were performed. In-situ and ex-situ dispersoid formations were observed in the Y2O3-added ODS-HEA, whereas the in-situ dispersoid formation was dominantly observed in the Y-alloyed ODS-HEA through the construction of a coherent interface relationship with complex chemical compositions. In-situ oxide dispersoids enhance the construction of ultrafine-grained structures up to approximately 300 nm in diameter. This study shows that the pre-alloying method, in which yttrium is alloyed, is efficient in achieving fine coherent dispersoids with an ultrafine-grained structure, resulting in a significant enhancement of the tensile strength of the CoCrFeMnNi HEA.
采用不同的粉末制备方法制备CoCrFeMnNi高熵合金(ODS-HEAs),考察原位和非原位氧化分散体形成对合金显微组织和力学性能的影响。采用x射线衍射(XRD)、电子背散射衍射(EBSD)、高分辨率透射电子显微镜(HRTEM)、原子探针层析成像(APT)和小角中子散射(SANS)等方法进行了系统的微观结构分析。对高熵合金(HEA)基体内原位和非原位弥散体进行了低温粉末分析、火花等离子烧结后的晶粒结构演变、弥散体特征和基体/弥散界面结构分析。添加y2o3的ODS-HEA中存在原位弥散和非原位弥散,而y -合金ODS-HEA中主要存在原位弥散,这是通过构建具有复杂化学成分的相干界面关系实现的。原位氧化物分散体增强了直径约300 nm的超细颗粒结构的构建。本研究表明,预先合金化钇的方法可以有效地获得具有超细晶结构的细相干弥散体,从而显著提高CoCrFeMnNi HEA的抗拉强度。
{"title":"Oxide Dispersoid Strengthened CoCrFeMnNi High-Entropy Alloy: The Effects of Y2O3 Addition and Y Alloying","authors":"Seunghyeok Chung, Bin Lee, S. Lee, Changwoo Do, H. Ryu","doi":"10.2139/ssrn.3680402","DOIUrl":"https://doi.org/10.2139/ssrn.3680402","url":null,"abstract":"Oxide dispersion strengthened CoCrFeMnNi high-entropy alloys (ODS-HEAs) were prepared using two different powder preparation methods classified by yttrium addition strategy to investigate the effects of in-situ and ex-situ oxide dispersoid formation on the microstructure and mechanical properties. Systematic microstructural analysis was carried out by X-ray diffraction (XRD), electron backscattered diffraction (EBSD), high-resolution transmission electron microscopy (HRTEM), atom probe tomography (APT), and small-angle neutron scattering (SANS). Cryo-milled powder analysis, grain structure evolution after spark plasma sintering, dispersoid characteristics, and matrix/dispersoid interface structure analysis of the in-situ and ex-situ dispersoids within the high-entropy alloy (HEA) matrix were performed. In-situ and ex-situ dispersoid formations were observed in the Y2O3-added ODS-HEA, whereas the in-situ dispersoid formation was dominantly observed in the Y-alloyed ODS-HEA through the construction of a coherent interface relationship with complex chemical compositions. In-situ oxide dispersoids enhance the construction of ultrafine-grained structures up to approximately 300 nm in diameter. This study shows that the pre-alloying method, in which yttrium is alloyed, is efficient in achieving fine coherent dispersoids with an ultrafine-grained structure, resulting in a significant enhancement of the tensile strength of the CoCrFeMnNi HEA.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"330 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73130380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Highly Efficient Diffusion TbF 3 to Enhance the Coercivity of Sintered Nd-Fe-B Magnet by Cu Addition Cu的加入提高Nd-Fe-B烧结磁体矫顽力的高效扩散tbf3
Pub Date : 2020-01-01 DOI: 10.2139/ssrn.3708688
Shuwei Zhong, San-lian Luo, Liuyimei Yang, S. Rehman, Yue Wu, Yaojun Lu, Munan Yang, Bin Yang
In this paper, Cu element was added to the grain boundary of sintered Nd-Fe-B magnet to form a low melting point alloy phase in the grain boundary to promote the diffusion depth of Tb element. The intrinsic coercivity of the magnet with 0.2 % Cu addition increased significantly from 16.07 kOe for standard alloy without Cu to 24.38 kOe after the diffusion of TbF3 . The squareness of the demagnetization curves is maintained at 94 %, ensuring a good diffusion efficiency and uniformity. EPMA analysis showed that the distribution depth of (Nd, Tb) 2 Fe 14 B core-shell layer of the magnet was increased from 50 μm to 145 μm after the diffusion. The addition of Cu increased the ratio and average area of the grain boundary phases effectively, and formed a good diffusion channel. A larger amount of (Nd, Tb) 2 Fe 14 B shell layers formed in the magnet as a result of TbF 3 diffusion in Cu added magnets and which increased the intrinsic coercivity due to enhanced magnetocryalline anisotropy and favorable microstructure.In this paper, Cu element was added to the grain boundary of sintered Nd-Fe-B magnet to form a low melting point alloy phase in the grain boundary to promote the diffusion depth of Tb element. The intrinsic coercivity of the magnet with 0.2 % Cu addition increased significantly from 16.07 kOe for standard alloy without Cu to 24.38 kOe after the diffusion of TbF3 . The squareness of the demagnetization curves is maintained at 94%, ensuring a good diffusion efficiency and uniformity. EPMA analysis showed that the distribution depth of (Nd, Tb) 2 Fe 14 B core-shell layer of the magnet was increased from 50 μm to 145 μm after the diffusion. The addition of Cu increased the ratio and average area of the grain boundary phases effectively, and formed a good diffusion channel. A larger amount of (Nd,Tb)2Fe14B shell layers formed in the magnet as a result of TbF3 diffusion in Cu added magnets which increased the intrinsic coercivity due to enhanced magnetocryalline anisotropy and favorable microstructure.
本文在烧结Nd-Fe-B磁体的晶界中加入Cu元素,在晶界处形成低熔点合金相,促进Tb元素的扩散深度。当Cu含量为0.2%时,经TbF3扩散后,磁体的本征矫顽力由不含Cu的标准合金的16.07 kOe显著提高到24.38 kOe。消磁曲线的平整度保持在94%,保证了良好的扩散效率和均匀性。EPMA分析表明,扩散后磁体的(Nd, Tb) 2fe14b核壳层分布深度由50 μm增加到145 μm。Cu的加入有效地提高了晶界相的比例和平均面积,形成了良好的扩散通道。由于TbF - 3在Cu中扩散,磁体中形成了大量的(Nd, Tb) 2fe14b壳层,磁晶各向异性增强,微观结构有利,从而提高了磁体的本征矫顽力。本文在烧结Nd-Fe-B磁体的晶界中加入Cu元素,在晶界处形成低熔点合金相,促进Tb元素的扩散深度。当Cu含量为0.2%时,经TbF3扩散后,磁体的本征矫顽力由不含Cu的标准合金的16.07 kOe显著提高到24.38 kOe。退磁曲线的平方度保持在94%,保证了良好的扩散效率和均匀性。EPMA分析表明,扩散后磁体的(Nd, Tb) 2fe14b核壳层分布深度由50 μm增加到145 μm。Cu的加入有效地提高了晶界相的比例和平均面积,形成了良好的扩散通道。由于TbF3在Cu中扩散,磁体中形成了大量的(Nd,Tb)2Fe14B壳层,磁晶各向异性增强,微观结构有利,从而提高了磁体的固有矫顽力。
{"title":"Highly Efficient Diffusion TbF 3 to Enhance the Coercivity of Sintered Nd-Fe-B Magnet by Cu Addition","authors":"Shuwei Zhong, San-lian Luo, Liuyimei Yang, S. Rehman, Yue Wu, Yaojun Lu, Munan Yang, Bin Yang","doi":"10.2139/ssrn.3708688","DOIUrl":"https://doi.org/10.2139/ssrn.3708688","url":null,"abstract":"In this paper, Cu element was added to the grain boundary of sintered Nd-Fe-B magnet to form a low melting point alloy phase in the grain boundary to promote the diffusion depth of Tb element. The intrinsic coercivity of the magnet with 0.2 % Cu addition increased significantly from 16.07 kOe for standard alloy without Cu to 24.38 kOe after the diffusion of TbF3 . The squareness of the demagnetization curves is maintained at 94 %, ensuring a good diffusion efficiency and uniformity. EPMA analysis showed that the distribution depth of (Nd, Tb) 2 Fe 14 B core-shell layer of the magnet was increased from 50 μm to 145 μm after the diffusion. The addition of Cu increased the ratio and average area of the grain boundary phases effectively, and formed a good diffusion channel. A larger amount of (Nd, Tb) 2 Fe 14 B shell layers formed in the magnet as a result of TbF 3 diffusion in Cu added magnets and which increased the intrinsic coercivity due to enhanced magnetocryalline anisotropy and favorable microstructure.In this paper, Cu element was added to the grain boundary of sintered Nd-Fe-B magnet to form a low melting point alloy phase in the grain boundary to promote the diffusion depth of Tb element. The intrinsic coercivity of the magnet with 0.2 % Cu addition increased significantly from 16.07 kOe for standard alloy without Cu to 24.38 kOe after the diffusion of TbF3 . The squareness of the demagnetization curves is maintained at 94%, ensuring a good diffusion efficiency and uniformity. EPMA analysis showed that the distribution depth of (Nd, Tb) 2 Fe 14 B core-shell layer of the magnet was increased from 50 μm to 145 μm after the diffusion. The addition of Cu increased the ratio and average area of the grain boundary phases effectively, and formed a good diffusion channel. A larger amount of (Nd,Tb)2Fe14B shell layers formed in the magnet as a result of TbF3 diffusion in Cu added magnets which increased the intrinsic coercivity due to enhanced magnetocryalline anisotropy and favorable microstructure.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"28 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83594820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure, Microhardness and Machining Characteristics of Al6063-SiC Composites Al6063-SiC复合材料的显微组织、显微硬度及加工特性
Pub Date : 2019-12-20 DOI: 10.2139/ssrn.3671806
R. Lam, Yogesh Venkatesan, S. Irullappasamy, T. K. Mahanta, R. Dumpala, R. B.
Machining of materials is an important operation in the manufacturing industry to develop different structures. Compared with metals and alloys, metal matrix composites (MMCs) respond differently during machining due to the presence of different phases possessing different physical and mechanical properties. In the present study, machining behavior of Al6063-SiC composites has been investigated to assess the role of dispersing phase on machining characteristics. Composites with varying SiC content (4% and 8% by Wt.) were produced by stir casting. From the micro structural studies, decreased grain size was observed with increased SiC dispersion. Higher hardness was measured for the composite with 4% SiC. From the machining studies during turning experiments, the variations within the cutting forces was found to be higher for the composites compared with the base material. Cutting forces were also measured as increased with the increase of SiC dispersion. From the results, it can be understood that the presence of SiC significantly influence the machining behavior of Al6063-SiC composites which is a valid factor must be considered while performing turning operations.
材料的加工是制造工业中发展不同结构的一项重要操作。与金属和合金相比,金属基复合材料在加工过程中的反应是不同的,因为不同相的存在具有不同的物理力学性能。在本研究中,研究了Al6063-SiC复合材料的加工行为,以评估分散相对加工特性的作用。采用搅拌铸造法制备了不同SiC含量(Wt = 4%和Wt = 8%)的复合材料。显微组织研究表明,SiC分散度增加,晶粒尺寸减小。含4% SiC的复合材料硬度较高。从车削试验的加工研究中,发现复合材料的切削力变化比母材大。切削力随SiC弥散度的增加而增大。结果表明,SiC的存在对Al6063-SiC复合材料的加工性能有显著影响,是车削加工时必须考虑的一个有效因素。
{"title":"Microstructure, Microhardness and Machining Characteristics of Al6063-SiC Composites","authors":"R. Lam, Yogesh Venkatesan, S. Irullappasamy, T. K. Mahanta, R. Dumpala, R. B.","doi":"10.2139/ssrn.3671806","DOIUrl":"https://doi.org/10.2139/ssrn.3671806","url":null,"abstract":"Machining of materials is an important operation in the manufacturing industry to develop different structures. Compared with metals and alloys, metal matrix composites (MMCs) respond differently during machining due to the presence of different phases possessing different physical and mechanical properties. In the present study, machining behavior of Al6063-SiC composites has been investigated to assess the role of dispersing phase on machining characteristics. Composites with varying SiC content (4% and 8% by Wt.) were produced by stir casting. From the micro structural studies, decreased grain size was observed with increased SiC dispersion. Higher hardness was measured for the composite with 4% SiC. From the machining studies during turning experiments, the variations within the cutting forces was found to be higher for the composites compared with the base material. Cutting forces were also measured as increased with the increase of SiC dispersion. From the results, it can be understood that the presence of SiC significantly influence the machining behavior of Al6063-SiC composites which is a valid factor must be considered while performing turning operations.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"44 3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90483573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Solidification and Melting Phase Change Behavior of Eutectic Gallium-Indium-Tin 共晶镓铟锡的凝固与熔化相变行为
Pub Date : 2019-12-01 DOI: 10.1016/j.mtla.2019.100512
Amanda S. Koh, Seth Chun, Wonseok Hwang, P. Zavalij, Geoffrey A. Slipher, R. Mrozek
{"title":"Solidification and Melting Phase Change Behavior of Eutectic Gallium-Indium-Tin","authors":"Amanda S. Koh, Seth Chun, Wonseok Hwang, P. Zavalij, Geoffrey A. Slipher, R. Mrozek","doi":"10.1016/j.mtla.2019.100512","DOIUrl":"https://doi.org/10.1016/j.mtla.2019.100512","url":null,"abstract":"","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"92 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85175408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 26
From Electricity to Fuels: Descriptors for C 1 Selectivity in Electrochemical CO 2 Reduction 从电力到燃料:电化学CO 2还原中c1选择性的描述符
Pub Date : 2019-11-02 DOI: 10.2139/ssrn.3479447
Michael T. Tang, Hongjie Peng, Philomena Schlexer Lamoureux, M. Bajdich, F. Abild-Pedersen
Electrochemical reduction of carbon dioxide (CO2)over transition metals follows a complex reaction network. Even for productswith a single carbon atom (C1 products), two bifurcated pathwaysexist: initially between carboxyl (COOH*) and formate (HCOO*) intermediates andthe COOH* intermediate is further bifurcated by pathways involving either formyl(CHO*) or COH*. In this study, we combine evidence from the experimentalliterature with a theoretical analysis of energetics to rationalize that notall steps in the reduction of CO2 are electrochemical. This insightenables us to create a selectivity map for two-electron products (carbonmonoxide (CO) and formate) on elemental metal surfaces using only the CO and OHbinding energies as descriptors. In the further reduction of CO*, wefind that CHO* is formed through a chemical step only whereas COH* follows froman electrochemical step. Notably on Cu(100), the COH pathway becomes dominantat an applied potential lower than −0.5V vs. RHE. For theelemental metals selective towards CO formation, the variation of the CObinding energy is sufficient to further subdivide the map into domains thatpredominantly form H2, CO, and ultimately more reduced products. Wefind Cu to be the only elemental metal capable of reducing CO2 toproducts beyond 2e− via the proposed COH pathway and we identify atomiccarbon as the key component leading to the production of methane. Our analysis alsorationalizes experimentally observed differences in products between thermaland electrochemical reduction of CO2 on Cu.
二氧化碳(CO2)在过渡金属上的电化学还原遵循复杂的反应网络。即使对于具有单碳原子的产物(C1产物),也存在两个分叉途径:最初在羧基(COOH*)和甲酸酯(HCOO*)中间体之间,而COOH*中间体则通过涉及甲酰(CHO*)或COH*的途径进一步分叉。在这项研究中,我们将实验文献的证据与能量学的理论分析相结合,以证明CO2减少的步骤并非都是电化学的。这使我们能够仅使用CO和oh结合能作为描述符,在元素金属表面上创建双电子产物(一氧化碳和甲酸)的选择性图。在CO*的进一步还原过程中,我们发现CHO*仅通过化学步骤形成,而COH*则通过电化学步骤形成。特别是在Cu(100)上,当外加电位低于- 0.5V时,COH途径占主导地位。对于选择性生成CO的元素金属,结合能的变化足以进一步将图谱细分为主要形成H2、CO和最终更多还原产物的结构域。我们发现Cu是唯一能够通过提出的COH途径将CO2还原为超过2e -的产物的元素金属,我们确定原子碳是导致甲烷生成的关键成分。我们的分析还解释了实验观察到的Cu上CO2热和电化学还原产物的差异。
{"title":"From Electricity to Fuels: Descriptors for C 1 Selectivity in Electrochemical CO 2 Reduction","authors":"Michael T. Tang, Hongjie Peng, Philomena Schlexer Lamoureux, M. Bajdich, F. Abild-Pedersen","doi":"10.2139/ssrn.3479447","DOIUrl":"https://doi.org/10.2139/ssrn.3479447","url":null,"abstract":"Electrochemical reduction of carbon dioxide (CO2)\u0000over transition metals follows a complex reaction network. Even for products\u0000with a single carbon atom (C1 products), two bifurcated pathways\u0000exist: initially between carboxyl (COOH*) and formate (HCOO*) intermediates and\u0000the COOH* intermediate is further bifurcated by pathways involving either formyl\u0000(CHO*) or COH*. In this study, we combine evidence from the experimental\u0000literature with a theoretical analysis of energetics to rationalize that not\u0000all steps in the reduction of CO2 are electrochemical. This insight\u0000enables us to create a selectivity map for two-electron products (carbon\u0000monoxide (CO) and formate) on elemental metal surfaces using only the CO and OH\u0000binding energies as descriptors. In the further reduction of CO*, we\u0000find that CHO* is formed through a chemical step only whereas COH* follows from\u0000an electrochemical step. Notably on Cu(100), the COH pathway becomes dominant\u0000at an applied potential lower than −0.5V vs. RHE. For the\u0000elemental metals selective towards CO formation, the variation of the CO\u0000binding energy is sufficient to further subdivide the map into domains that\u0000predominantly form H2, CO, and ultimately more reduced products. We\u0000find Cu to be the only elemental metal capable of reducing CO2 to\u0000products beyond 2e− via the proposed COH pathway and we identify atomic\u0000carbon as the key component leading to the production of methane. Our analysis also\u0000rationalizes experimentally observed differences in products between thermal\u0000and electrochemical reduction of CO2 on Cu.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"68 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72744460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 65
Catalyzing Zinc-Ion Intercalation in Hydrated Vanadates for Aqueous Zinc-Ion Batteries 催化锌离子在水合钒酸盐中嵌入水锌离子电池
Pub Date : 2019-10-24 DOI: 10.2139/ssrn.3474682
Chaofeng Liu, M. Tian, Mingshan Wang, Jiqi Zheng, Shuhua Wang, Mengyu Yan, Zhaojie Wang, Zhengmao Yin, Jihui Yang, G. Cao
The partially unfilled 3d orbitals in Cu(ii) can capture and transfer electrons in the redox reactions as expected from a catalytic function and promote the Zn-ion storage reaction kinetics in aqueous batteries.
Cu(ii)中部分未填充的三维轨道可以在氧化还原反应中捕获和转移电子,并从催化功能上促进了水电池中zn离子的储存反应动力学。
{"title":"Catalyzing Zinc-Ion Intercalation in Hydrated Vanadates for Aqueous Zinc-Ion Batteries","authors":"Chaofeng Liu, M. Tian, Mingshan Wang, Jiqi Zheng, Shuhua Wang, Mengyu Yan, Zhaojie Wang, Zhengmao Yin, Jihui Yang, G. Cao","doi":"10.2139/ssrn.3474682","DOIUrl":"https://doi.org/10.2139/ssrn.3474682","url":null,"abstract":"The partially unfilled 3d orbitals in Cu(ii) can capture and transfer electrons in the redox reactions as expected from a catalytic function and promote the Zn-ion storage reaction kinetics in aqueous batteries.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75430829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 49
Achieving Bi-Lamellar Microstructure with Both High Tensile Strength and Large Ductility in Ti-6Al-4V Alloy by Novel Thermomechanical Processing 采用新型热处理工艺制备Ti-6Al-4V合金,获得高抗拉强度和大塑性的双片层组织
Pub Date : 2019-08-13 DOI: 10.2139/ssrn.3436426
Yan Chong, T. Bhattacharjee, J. Yi, Shiteng Zhao, N. Tsuji
In this study, a novel through-β-transus processing followed by intercritical annealing was designed to obtain the bi-lamellar microstructure in Ti-6Al-4V alloy with refined colony sizes, by which both tensile strength and ductility were significantly improved. The colony size obtained in the through-β-transus processing was 60 μm, much smaller than the minimum colony size of 130 μm that can be achieved in the conventional β processing. The colony refinement was attributed to the decreased size of the grain boundary α phase with increased variety of crystallographic orientations, which acted as nucleation sites for subsequent colony structures. By intercritical annealing of the lamellar microstructures in α+β two-phase region followed by water quenching, bi-lamellar microstructures composed of primary α lamellae and transformed β regions composed of fine secondary α plates were obtained, maintaining the same colony size as the lamellar precursors. The total elongation of bi-lamellar microstructure significantly improved from 3.4% to 18.6% with decreasing the colony size, while the high yield and tensile strength was independent of the colony size. SEM-EBSD characterization of the bi-lamellar microstructures at interrupted tensile strains clarified that deformation behaviors of the bi-lamellar microstructures after yielding were mainly controlled by micro-shear bands across transformed β regions, which eventually evolved into micro-cracks at higher tensile strains. It was considered that the strain compatibility accommodated by the differently aligned micro-shear bands formed within different colonies was the main reason for delaying tensile fracture in the bi-lamellar microstructure with the smaller colony size.
在本研究中,设计了一种新的通过-β-跨晶处理和临界间退火的方法,使Ti-6Al-4V合金获得了具有细化集落尺寸的双片层组织,从而显著提高了抗拉强度和塑性。通过-β-横贯加工获得的菌落尺寸为60 μm,远小于常规β加工获得的最小菌落尺寸130 μm。集落细化是由于晶界α相的尺寸减小,晶体取向的多样性增加,这是后续集落结构的成核位点。通过对α+β两相区片层组织进行临界间退火并进行水淬处理,得到了由初级α片层组成的双片层组织和由细小次级α板组成的转变β区,并保持了与片层前体相同的集落大小。随着集落尺寸的减小,双片层组织的总伸长率从3.4%提高到18.6%,而高屈服和抗拉强度与集落尺寸无关。SEM-EBSD表征表明,屈服后双层组织的变形行为主要受转变β区的微剪切带控制,并最终在更高的拉伸应变下演变为微裂纹。认为不同菌落内形成的不同排列的微剪切带所适应的应变相容性是导致小菌落双层微观组织延迟拉伸断裂的主要原因。
{"title":"Achieving Bi-Lamellar Microstructure with Both High Tensile Strength and Large Ductility in Ti-6Al-4V Alloy by Novel Thermomechanical Processing","authors":"Yan Chong, T. Bhattacharjee, J. Yi, Shiteng Zhao, N. Tsuji","doi":"10.2139/ssrn.3436426","DOIUrl":"https://doi.org/10.2139/ssrn.3436426","url":null,"abstract":"In this study, a novel through-β-transus processing followed by intercritical annealing was designed to obtain the bi-lamellar microstructure in Ti-6Al-4V alloy with refined colony sizes, by which both tensile strength and ductility were significantly improved. The colony size obtained in the through-β-transus processing was 60 μm, much smaller than the minimum colony size of 130 μm that can be achieved in the conventional β processing. The colony refinement was attributed to the decreased size of the grain boundary α phase with increased variety of crystallographic orientations, which acted as nucleation sites for subsequent colony structures. By intercritical annealing of the lamellar microstructures in α+β two-phase region followed by water quenching, bi-lamellar microstructures composed of primary α lamellae and transformed β regions composed of fine secondary α plates were obtained, maintaining the same colony size as the lamellar precursors. The total elongation of bi-lamellar microstructure significantly improved from 3.4% to 18.6% with decreasing the colony size, while the high yield and tensile strength was independent of the colony size. SEM-EBSD characterization of the bi-lamellar microstructures at interrupted tensile strains clarified that deformation behaviors of the bi-lamellar microstructures after yielding were mainly controlled by micro-shear bands across transformed β regions, which eventually evolved into micro-cracks at higher tensile strains. It was considered that the strain compatibility accommodated by the differently aligned micro-shear bands formed within different colonies was the main reason for delaying tensile fracture in the bi-lamellar microstructure with the smaller colony size.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82524796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental Investigation and Optimisation of Treatment Parameters in Plasma Arc Cutting of D3 Tool Steel by Response Surface Modification 响应面改性等离子弧切割D3工具钢工艺参数的实验研究与优化
Pub Date : 2019-08-01 DOI: 10.2139/ssrn.3430314
S. Venkatesan, P. Mohan, T. Ranjith Kumar, E. Artralarasan
Currently with the rise in competition in market and deliver the goods high accuracy is very extremely tough the non-conventional machining like PAC (plasma arc cutting) is become life line of any business. Plasma arc cutting (PAC) is wide used treatment for the cutting of various varieties of metals in many in operation operating conditions. PAC is taken into account a difficult technology compared to its main competitors: oxy-fuel and optical master cutting. Today, thanks to advances in instrumentation style and improvement in cut quality. This paper delivers the result and constant optimisationof method parameters for the treatment of plasma arc cutting (PAC) of d3 tool steel. Gas force per unit area, arc rent and speed these are the 3 parameters of this treatment. The fabric material removal rate (MRR) is take process response .for maximum MRR treatment parameters are optimised supported the RSM technique including analysis of variance. Analysis of variance (ANOVA) is perform and contribute every treatment parameters and its have an effect on the response.
目前,随着市场竞争的加剧和产品的高精度交付是非常困难的,像PAC(等离子弧切割)这样的非常规加工已成为任何企业的生命线。等离子弧切割(PAC)被广泛应用于多种操作条件下各种金属的切割。与其主要竞争对手:氧燃料和光学主切割相比,PAC被认为是一项困难的技术。今天,由于仪器风格的进步和切割质量的提高。本文给出了d3工具钢等离子弧切割(PAC)处理的结果和方法参数的不断优化。单位面积气体力,电弧电流和速度这是该处理的3个参数。织物材料去除率(MRR)是一个过程响应,为了获得最大的MRR,支持RSM技术优化处理参数,包括方差分析。方差分析(ANOVA)是执行和贡献每个治疗参数及其对反应的影响。
{"title":"Experimental Investigation and Optimisation of Treatment Parameters in Plasma Arc Cutting of D3 Tool Steel by Response Surface Modification","authors":"S. Venkatesan, P. Mohan, T. Ranjith Kumar, E. Artralarasan","doi":"10.2139/ssrn.3430314","DOIUrl":"https://doi.org/10.2139/ssrn.3430314","url":null,"abstract":"Currently with the rise in competition in market and deliver the goods high accuracy is very extremely tough the non-conventional machining like PAC (plasma arc cutting) is become life line of any business. Plasma arc cutting (PAC) is wide used treatment for the cutting of various varieties of metals in many in operation operating conditions. PAC is taken into account a difficult technology compared to its main competitors: oxy-fuel and optical master cutting. Today, thanks to advances in instrumentation style and improvement in cut quality. This paper delivers the result and constant optimisationof method parameters for the treatment of plasma arc cutting (PAC) of d3 tool steel. Gas force per unit area, arc rent and speed these are the 3 parameters of this treatment. The fabric material removal rate (MRR) is take process response .for maximum MRR treatment parameters are optimised supported the RSM technique including analysis of variance. Analysis of variance (ANOVA) is perform and contribute every treatment parameters and its have an effect on the response.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"22 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91161781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Design and Simulation of Dual Polarized Patch Antenna 双极化贴片天线的设计与仿真
Pub Date : 2019-07-30 DOI: 10.34218/ijaret.10.4.2019.002
B.M Sachin, Dr. Shushrutha K.S
A single layer dual-polarized.microstrip patch antenna with dual port is designed, simulated and analyzed. The two ports are provided with a 1800 phase shift and designed to operate in the C-band with a solution frequency at 4GHz. The edges of the patch are etched which helps to improve the polarization of the designed antenna. The inset feed is the feeding technique used for the design of the dual-polarized antenna which provides a gain of about 8.5dB. This paper describes the parameters of the dual-polarized patch antenna like VSWR, Radiation Pattern, Axial Ratio and Return Loss are simulated and results are recorded. The proposed antenna works for the single narrow band frequency having a return loss lesser than -10dB and finds its application in satellite communications and weather RADAR.
单层双极化。对双端口微带贴片天线进行了设计、仿真和分析。这两个端口具有1800相移,设计用于在c波段工作,解决频率为4GHz。该贴片的边缘被蚀刻,这有助于改善所设计天线的极化。插入馈电是用于双极化天线设计的馈电技术,提供约8.5dB的增益。本文对双极化贴片天线的驻波比、辐射方向图、轴比和回波损耗等参数进行了仿真,并记录了仿真结果。该天线工作于回波损耗小于-10dB的单窄带频率,适用于卫星通信和气象雷达。
{"title":"Design and Simulation of Dual Polarized Patch Antenna","authors":"B.M Sachin, Dr. Shushrutha K.S","doi":"10.34218/ijaret.10.4.2019.002","DOIUrl":"https://doi.org/10.34218/ijaret.10.4.2019.002","url":null,"abstract":"A single layer dual-polarized.microstrip patch antenna with dual port is designed, simulated and analyzed. The two ports are provided with a 1800 phase shift and designed to operate in the C-band with a solution frequency at 4GHz. The edges of the patch are etched which helps to improve the polarization of the designed antenna. The inset feed is the feeding technique used for the design of the dual-polarized antenna which provides a gain of about 8.5dB. This paper describes the parameters of the dual-polarized patch antenna like VSWR, Radiation Pattern, Axial Ratio and Return Loss are simulated and results are recorded. The proposed antenna works for the single narrow band frequency having a return loss lesser than -10dB and finds its application in satellite communications and weather RADAR.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"26 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75109493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
Materials Processing & Manufacturing eJournal
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1