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Solution processed Pb0.8Ba0.2ZrO3 (lead barium zirconate) dielectric for photo transistor fabrication 溶液处理Pb0.8Ba0.2ZrO3(锆酸铅钡)电介质,用于光晶体管的制造
Pub Date : 2021-09-13 DOI: 10.1063/5.0061324
Vishwas Acharya, A. Sharma, S. Jangu, Prakash Singh
We describe the fabrication and device characterization of PBZ/IZO/PBS heterojunction photo transistor by using dielectric properties of lead barium zirconate (PBZ) thin film through solution processed. PBZ thin film is fabricated by low cost sol-gel process on heavily doped Si-substrate (p++-Si). Solution processed IZO used as a channel semiconductor for bottom gate top contact geometry of TFT. The fabricated device require <5V operating voltage to saturate with high drain current which is very beneficial for low-power electronics. Metal oxide/quantum dot heterojunction phototransistor was fabricated by coating IZO TFT with colloidal lead sulphide (PbS) quantum dot that shows the responsivity and the response time of 3 × 10−4 A/W and 2 sec respectively.
利用锆酸铅钡(PBZ)薄膜的介电特性,对PBZ/IZO/PBS异质结光晶体管进行了制备和器件表征。采用低成本溶胶-凝胶法制备了高掺杂硅衬底(p++-Si)的PBZ薄膜。溶液处理的IZO用作TFT底部栅极顶部接触几何的通道半导体。该器件需要低于5V的工作电压才能饱和,并具有高漏极电流,这对低功耗电子器件非常有利。采用胶体硫化铅(PbS)量子点涂层IZO TFT制备了金属氧化物/量子点异质结光电晶体管,其响应率和响应时间分别为3 × 10−4 A/W和2 sec。
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引用次数: 0
Nanosecond nonlinear optical and optical limiting properties of Eu3+ activated borate glasses embedded with silver nanoparticles 嵌入纳米银的Eu3+活化硼酸盐玻璃的纳秒非线性光学及光学限制性能
Pub Date : 2021-09-13 DOI: 10.1063/5.0061497
Naseem Fatima, Y. Nadaf, P. Ramesh, A. Pramod, G. Jagannath
Nonlinear optical and optical limiting attributes are evaluated at 532 nm using nanosecond laser pulses. The nonlinear coefficients such as nonlinear absorption and nonlinear refractive index values are increased with increase in AgNO3 concertation while the optical limiting threshold values showed a reverse trend. The increase in nonlinear optical properties in studied glasses with the Ag nanoparticles number density attributed to the local field effect stimulated by surface plasmon resonance of Ag nanoparticles when glasses are exposed to high energy radiation. The increase in nonlinear absorption and decrease in optical limiting threshold coefficients with AgNO3 concertation suggest the glasses containing high concentration of Ag nanoparticles are useful for designing the power optical limiters for functioning at the visible region under nanosecond regime.
利用纳秒激光脉冲在532 nm处评估了非线性光学和光学极限属性。非线性系数如非线性吸收值和非线性折射率值随着AgNO3浓度的增加而增加,而光学极限阈值则呈相反趋势。研究的玻璃非线性光学性质随银纳米粒子数目密度的增加归因于银纳米粒子表面等离子体共振所激发的局域场效应。随着AgNO3浓度的增加,非线性吸收增加,光学限制阈值系数降低,这表明含有高浓度Ag纳米粒子的玻璃可用于设计在纳秒范围内在可见光区域工作的功率光学限制器。
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引用次数: 1
Process development for the removal of malachite Green dye from wastewater using sewage sludge (STP) as an adsorbent 以污泥为吸附剂去除废水中孔雀石绿染料的工艺研究
Pub Date : 2021-09-13 DOI: 10.1063/5.0061212
P. Shrivastava, M. Dwivedi, V. Malviya, P. Jain
In the present study, Sewage sludge (STP) was used to develop an effective adsorbent and investigations were carried out for removal of malachite green dye from wastewater. The developed adsorbent was characterized using various techniques such as XRF, FTIR and SEM. Batch studies were carried out for optimization of parameters like contact time, reaction temperature, pH, adsorbent dose and adsorbate concentration. Adsorption data were also correlated with Langmuir, Freundlich, Temkin and Dubinin isotherm models. The Pseudo-first-order, Pseudo-second-order, Intra-particle diffusion and Elovich models were used to describe the adsorption kinetics. The results of batch studies revealed that removal efficiency was 95.7% at optimum experimental conditions of pH 6.0, contact time 120 min, Malachite green dye concentration 10 mg/L and adsorbent dose 10g/L. The results also showed that adsorption increased with an increase in temperature thereby showing the process endothermic in nature. The Freundlich adsorption model and Pseudo-second order kinetics were found to have the highest regression value and hence the fitted well. The results indicated that the sewage sludge could be employed as a low-cost adsorbent for the removal of Malachite green dye from wastewater.
本研究以污水污泥(STP)为吸附剂,对废水中孔雀石绿染料的去除进行了研究。利用XRF、FTIR和SEM等多种技术对所制备的吸附剂进行了表征。对接触时间、反应温度、pH、吸附剂用量、吸附质浓度等参数进行了批量优化。吸附数据也与Langmuir、Freundlich、Temkin和Dubinin等温模型相关。采用拟一阶、拟二阶、颗粒内扩散和Elovich模型描述吸附动力学。批量实验结果表明,在pH 6.0、接触时间120 min、孔雀石绿染料浓度10 mg/L、吸附剂剂量10g/L的最佳实验条件下,孔雀石绿的去除率为95.7%。结果还表明,随着温度的升高,吸附量增加,表明该过程本质上是吸热的。Freundlich吸附模型和拟二级动力学模型回归值最高,拟合良好。结果表明,污泥可作为一种低成本的吸附剂用于去除废水中的孔雀石绿染料。
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引用次数: 0
Microwave-assisted synthesis, spectroscopic properties, thermal behaviour and antimicrobial activity of unsymmetrical Schiff base complexes of Ti(III), Cr(III), MoO2(VI) and WO2(VI) Ti(III)、Cr(III)、MoO2(VI)和WO2(VI)非对称席夫碱配合物的微波合成、光谱性质、热行为和抗菌活性
Pub Date : 2021-09-13 DOI: 10.1063/5.0061307
S. R. Yaul, A. A. Ramteke, J. T. Makode, N. Salunkhe, A. Yaul
Four unsymmetrical Schiff base metal complexes, [Ti(L)(Cl)(H2O)], [Cr(L)(Cl)(H2O)], [MoO2(L)].H2O and [WO2(L)].H2O (L=4-hydroxy-3-(1-(2-(1-(2-hydroxy-5-methylphenyl)ethylideneamino)cyclohexylimino)ethyl)-6-methyl-2H-pyran-2-one) have been synthesized and characterized by their elemental analyses, magnetic susceptibility, thermogravimetric analysis, molar conductance, infrared (IR) and electronic spectral measurements. The purity of the ligand and its metal complexes are confirmed by microanalysis, while the unsymmetrical nature of the ligand was confirmed on the basis of 1H-NMR & 13C-NMR spectroscopy. Comparison of the IR spectra of the Schiff base ligand and its metal complexes confirm that the Schiff base behaves as tetradentate and coordinated via N2O2 chromophore. The ligand and its metal complexes were screened for antimicrobial activities against E. coli MTCC 443, P. aeruginosa MTCC 424 and S. aureus MTCC 96 and fungal strains, C. albicans MTCC 227 and A. niger MTCC 282. The activity data show that the complexes are more potent antimicrobials than the parent ligand.
四种不对称希夫贱金属配合物,[Ti(L)(Cl)(H2O)], [Cr(L)(Cl)(H2O)], [MoO2(L)]。H2O和[WO2(L)]。合成了水(L=4-羟基-3-(1-(2-(2-羟基-5-甲基苯基)乙基氨基)环己基)乙基)-6-甲基- 2h -吡喃-2- 1),并通过元素分析、磁化率、热重分析、摩尔电导、红外(IR)和电子光谱测量对其进行了表征。微量分析证实了配体及其金属配合物的纯度,1H-NMR和13C-NMR谱分析证实了配体的不对称性质。希夫碱配体及其金属配合物的红外光谱比较证实了希夫碱具有四齿性,并通过N2O2发色团进行配位。筛选了该配体及其金属配合物对大肠杆菌MTCC 443、铜绿假单胞菌MTCC 424、金黄色葡萄球菌MTCC 96以及真菌菌株白色念珠菌MTCC 227和黑曲霉MTCC 282的抑菌活性。活性数据表明,该配合物比母体配体具有更强的抗菌素活性。
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引用次数: 0
X-ray diffraction analysis on copper-cobalt ferrites 铜钴铁氧体的x射线衍射分析
Pub Date : 2021-09-13 DOI: 10.1063/5.0061267
Harish Sharma, B. Mishra, P. Sharma
In the present paper the study on the Copper-Cobalt ferrites with the general formulae CuxCo(1-x)Fe2O4 (where x=0.45,0.50,0.55,0.60) has been carried out . Solid root method was used to prepare the samples. X-ray diffraction (XRD) technique is used to analyze the samples. X-ray diffraction measurements were carried out .XRD investigation of all the compositions confirm the formation of single phase and tetragonal structure of ferrites .The particle size was calculated with the help of Debye Scherer's formulae using characteristics peaks.
本文采用通式CuxCo(1-x)Fe2O4(其中x=0.45,0.50,0.55,0.60)对铜钴铁氧体进行了研究。采用固根法制备样品。采用x射线衍射(XRD)技术对样品进行了分析。x射线衍射测定了所有成分,xrd分析证实了铁氧体的单相和四方结构,并利用特征峰计算了颗粒尺寸。
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引用次数: 0
Post annealing effects of perovskite (CH3NH3PbI3) thin films for solar cell applications 太阳能电池用钙钛矿(CH3NH3PbI3)薄膜的后退火效应
Pub Date : 2021-09-13 DOI: 10.1063/5.0061270
I. Mohanty, S. Mangal, S. Jana, U. Singh
In this work, methyl ammonium lead iodide (CH3NH3PbI3) thin films were deposited using spin-coating method. The thin films were investigated as a function of different thermal annealing temperatures with time being constant and as a function of time with constant temperature. The compositional and structural analyses have been studied by EDXRF and XRD respectively. The optical and chemical properties were also studied using UV-Vis spectrophotometer and FTIR spectroscopy. The characterization result shows the change in its properties with increase in temperature and time. From the XRD data, it can be observed that with an increase in temperature, the CH3NH3PbI3 decomposes to PbI2, and with an increase in annealing time, the CH3NH3PbI3 peaks show degradation. A basic comparison has been made in order to study the effect of annealing on the CH3NH3PbI3 thin films.
采用旋涂法制备了碘化铅甲基铵(CH3NH3PbI3)薄膜。研究了不同退火温度下薄膜随时间的变化规律和温度不变时薄膜随时间的变化规律。采用EDXRF和XRD对其进行了成分分析和结构分析。并用紫外-可见分光光度计和红外光谱对其光学和化学性质进行了研究。表征结果显示其性能随温度和时间的增加而变化。从XRD数据可以观察到,随着温度的升高,CH3NH3PbI3分解为PbI2,随着退火时间的延长,CH3NH3PbI3峰出现降解。为了研究退火对CH3NH3PbI3薄膜的影响,进行了基本的比较。
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引用次数: 1
Hot spots, MPPT technology and the differential power processing (DPP) for wearable PV applications 热点:可穿戴光伏应用的MPPT技术和差分功率处理(DPP)
Pub Date : 2021-09-13 DOI: 10.1063/5.0061031
R. D. Shengule
The PV cell connected in series experience several addressable problems which reduce the efficiency of power output in the solar system. Some of the serious issues are mismatching, shading issues, generation of ‘hot spot’, dust, and obstacles over the panel, solar charge controller design. This problem of overall decreased output power could be improved by introducing the converter design technique of differential power processing. DPP architecture achieves high system efficiency by processing the fraction of total power. This report is mainly focused on the home rooftop solar panel requirements, irradiance obstacles on the solar panel, factors affecting the efficiency of the solar panel system, and converter design for wearable PV application. PV cells can be used for wearable PV applications where fluctuation in illumination is observed. With the help of DPP technique, the MPPT for each cell is traced and the cell operates around that point. The DPP converter design is controlled with the help of the DC-DC controller design which is discussed in the report.
光伏电池串联存在着降低太阳能系统输出效率的问题。一些严重的问题是不匹配、遮阳问题、“热点”的产生、灰尘、面板上的障碍物、太阳能充电控制器的设计。通过引入差分功率处理的变换器设计技术,可以改善输出功率总体下降的问题。DPP架构通过对总功率的部分进行处理,实现了较高的系统效率。本报告主要针对家用屋顶太阳能板的需求、太阳能板上的辐照度障碍、影响太阳能板系统效率的因素、可穿戴光伏应用的转换器设计等方面进行阐述。光伏电池可用于观察光照波动的可穿戴光伏应用。在DPP技术的帮助下,跟踪每个细胞的MPPT,并围绕该点操作细胞。DPP变换器的设计是借助报告中讨论的DC-DC控制器的设计来控制的。
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引用次数: 1
Dielectric studies of (0.75) Cu0.5Zn0.5Fe2O4 + (0.25) BaZr0.5Ti0.5O3 composite (0.75) Cu0.5Zn0.5Fe2O4 + (0.25) BaZr0.5Ti0.5O3复合材料介电性能研究
Pub Date : 2021-09-13 DOI: 10.1063/5.0061037
V. Tandon, M. Saleem, N. Kaurav, RC Dixit
The composite of the formula (0.75) Cu0.5Zn0.5Fe2O4 + (0.25) BaZr0.5Ti0.5O3 has been discussed in this report. The structural studies were carried out using via X-ray diffraction technique and temperature dependent dielectric properties were examined at a constant field value of 500Hz. The X-ray diffraction data analysis reveal the presence of both the constituent phases. The ferrite Cu0.5Zn0.5Fe2O4 phase has attained cubic structure having space group Fd-3m and BaZr0.5Ti0.5O3 has acquired hexagonal crystal structure with space group P 63/m m c. The morphological and compositional studies were carried out. The as synthesized composite sample was studied for dielectric nature as a function of temperature (120K-320K) at a field of 500Hz. The dielectric constant was observed to initially increasing slowly but as the temperature enhances, dielectric constant increases rapidly near room temperature. Dielectric loss follows same trend with two humps corresponding to the two phases of the composite. The ac conductivity was observed low in the low temperature range and become higher in the extended temperature values.
本文讨论了(0.75)Cu0.5Zn0.5Fe2O4 + (0.25) BaZr0.5Ti0.5O3的复合配方。使用x射线衍射技术进行了结构研究,并在恒定场值500Hz下检测了温度相关的介电特性。x射线衍射数据分析显示了两种组成相的存在。铁素体Cu0.5Zn0.5Fe2O4获得了空间群为Fd-3m的立方结构,BaZr0.5Ti0.5O3获得了空间群为p63 /m - m - c的六方晶体结构。在500Hz的电场下,研究了合成的复合材料的介电性质随温度(120K-320K)的变化规律。在室温附近,介电常数开始缓慢增加,但随着温度的升高,介电常数迅速增加。复合材料的两相对应的介质损耗呈两个峰状分布。在低温范围内观察到交流电导率较低,在扩展温度值时变高。
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引用次数: 0
On metals’ properties manifested under complex loading 金属在复杂载荷下的性能表现
Pub Date : 2021-09-13 DOI: 10.1063/5.0060895
R. Abirov
At present many plasticity problems do not have a reliable solution. It is connected to the fact that in the theoretical calculations, based on the classical plasticity theories, a complexity of the process of loading of body is not considered. Sometimes this leads to significant errors. For plasticity with scleronome constraints (metals, alloys, etc.) at isothermal processes the functionals that were described of loading process do not depend on time. However the functionals in constitutive relations in plasticity should be also dependent on loading history. At practice, they can be found for some classes of complex loading processes experimentally. Some fundamental properties of functionals via experimental investigations of materials are presented here.
目前许多塑性问题都没有可靠的解决方案。这与在基于经典塑性理论的理论计算中,没有考虑机体加载过程的复杂性有关。有时这会导致严重的错误。对于等温过程中具有硬体约束(金属,合金等)的塑性,所描述的加载过程的泛函不依赖于时间。然而塑性本构关系中的泛函也应依赖于加载历史。在实际应用中,对于某些类型的复杂加载过程,可以在实验中找到它们。通过对材料的实验研究,给出了函数的一些基本性质。
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引用次数: 0
A study of structural, optical and electrical studies of the composites of ZnFe2O4, BiFeO3 and GaFeO3 compounds ZnFe2O4、BiFeO3和GaFeO3复合材料的结构、光学和电学研究
Pub Date : 2021-09-13 DOI: 10.1063/5.0061846
Reval Singh Kharat, M. Saleem, N. Kaurav, H. Dagar
The composites of the form 0.5ZFO + 0.4BFO + 0.1GFO (S1) and 0.75ZFO + 0.2BFO + 0.05GFO (S2) and synthesized by solid state route are reported in this study. These composites were subjected to structural, energy bandgap and dielectric studies. The XRD spectral analysis confirms that all the three phases are present in the samples under study. The BiFeO3 phase has acquired orthorhombic (Pnma) crystal structure, ZnFe2O4 has crystallized into cubic (Fd-3m) structure where GaFeO3 exhibited trigonal (R3c) structure. Diffuse reflectance spectral study conveys the sample to possess wide energy bandgap ≈2eV. The dielectric studies reveals the samples are extremely good dielectric materials with average dielectric constant, low loss value and relatively low decreasing rate with respect to applied field for both features.
本研究报道了固态法合成的0.5ZFO + 0.4BFO + 0.1GFO (S1)和0.75ZFO + 0.2BFO + 0.05GFO (S2)复合材料。对这些复合材料进行了结构、能带和介电性能的研究。XRD谱分析证实了这三种相均存在于所研究的样品中。BiFeO3为正交晶型(Pnma), ZnFe2O4为立方晶型(Fd-3m), GaFeO3为三角晶型(R3c)。漫反射光谱研究表明样品具有宽能带≈2eV。电介质研究表明,样品具有平均介电常数、较低的损耗值和相对于应用领域较低的衰减率,是非常好的介电材料。
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引用次数: 3
期刊
NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM2020
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