Pub Date : 2025-11-06DOI: 10.1038/s41557-025-02020-6
Junyi Hu, Zhuoya Dong, Chaoyang Chu, Yanhang Ma
{"title":"Publisher Correction: Quantification of enantiomorphs in chiral crystalline powders through three-dimensional electron diffraction","authors":"Junyi Hu, Zhuoya Dong, Chaoyang Chu, Yanhang Ma","doi":"10.1038/s41557-025-02020-6","DOIUrl":"10.1038/s41557-025-02020-6","url":null,"abstract":"","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"18 1","pages":"208-208"},"PeriodicalIF":20.2,"publicationDate":"2025-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.comhttps://www.nature.com/articles/s41557-025-02020-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145459217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-04DOI: 10.1038/s41557-025-01985-8
Roham Dorakhan, Shreya Sarkar, Erfan Shirzadi, Hafiz Ghulam Abbas, Ali Shayesteh, Sungjin Park, Jianan Erick Huang, David Sinton, Edward H. Sargent
The conversion of CO2 and CO using electricity offers a promising, sustainable approach to achieve valuable products. Although CO electroreduction to C1 and C2 products has seen rapid progress in efficiency and production rate, C3 synthesis remains a major challenge. Here we show that C3 products lie along the ethylene pathway by using a probe reactant and isotope-labelled CO. We find that glyoxal addition promotes C3 formation while suppressing acetate/ethanol production, while itself scarcely being consumed. Spectroscopy reveals lower CO* coverage in the presence of glyoxal. Reaction-order experiments show higher coverages of CO* and of OH− species linked to suppressing ethylene in favour of C3. By combining both strategies to suppress ethylene formation with an abundance of OH− and blocking acetate/ethanol formation with glyoxal, we report a high selectivity for C3 products, including a 53% Faradaic efficiency. These insights aid the design of future catalysts for C3 production. Electrochemical CO/CO2 reduction to multicarbon species represents an exciting approach to synthesize valuable products, but controllably linking three or more carbons remains a challenge. Now the pathway towards C–C coupling beyond two carbons has been shown using a probe reactant strategy to afford a 53% the selectivity towards C3+ oxygenates.
{"title":"Co-electroreduction of CO and glyoxal promotes C3 products","authors":"Roham Dorakhan, Shreya Sarkar, Erfan Shirzadi, Hafiz Ghulam Abbas, Ali Shayesteh, Sungjin Park, Jianan Erick Huang, David Sinton, Edward H. Sargent","doi":"10.1038/s41557-025-01985-8","DOIUrl":"10.1038/s41557-025-01985-8","url":null,"abstract":"The conversion of CO2 and CO using electricity offers a promising, sustainable approach to achieve valuable products. Although CO electroreduction to C1 and C2 products has seen rapid progress in efficiency and production rate, C3 synthesis remains a major challenge. Here we show that C3 products lie along the ethylene pathway by using a probe reactant and isotope-labelled CO. We find that glyoxal addition promotes C3 formation while suppressing acetate/ethanol production, while itself scarcely being consumed. Spectroscopy reveals lower CO* coverage in the presence of glyoxal. Reaction-order experiments show higher coverages of CO* and of OH− species linked to suppressing ethylene in favour of C3. By combining both strategies to suppress ethylene formation with an abundance of OH− and blocking acetate/ethanol formation with glyoxal, we report a high selectivity for C3 products, including a 53% Faradaic efficiency. These insights aid the design of future catalysts for C3 production. Electrochemical CO/CO2 reduction to multicarbon species represents an exciting approach to synthesize valuable products, but controllably linking three or more carbons remains a challenge. Now the pathway towards C–C coupling beyond two carbons has been shown using a probe reactant strategy to afford a 53% the selectivity towards C3+ oxygenates.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"18 2","pages":"317-325"},"PeriodicalIF":20.2,"publicationDate":"2025-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145445469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lariat-shaped lipopeptides are important antimicrobial agents; however, their complex structures pose synthetic challenges that hamper efficient structural diversification. Here we report a new chemoenzymatic approach that facilitates access to lariat-shaped macrocycles. Unprotected, branched peptides bearing multiple nucleophiles, including a native amino terminus and a pseudo-amino terminus, were site-selectively cyclized using versatile non-ribosomal peptide cyclases, generating an array of lariat peptides with diverse sequences and ring sizes. The generality of this strategy was demonstrated using two penicillin-binding protein-type thioesterases, SurE and WolJ, as well as one type-I thioesterase, TycC thioesterase. Furthermore, the remaining nucleophile, which was not involved in the cyclization process, was exploited as a reactive handle for subsequent diversification via a site-selective acylation reaction (that is, Ser/Thr ligation). The tandem cyclization–acylation strategy enabled the one-pot, modular synthesis of lariat-shaped lipopeptides equipped with various acyl groups. Biological screening revealed that the site-selective acylation endowed the macrocyclic scaffolds with antimycobacterial activity and led to the identification of lipopeptides that inhibit 50% of growth at concentrations of 8–16 µg ml−1. Non-ribosomal peptide cyclases that catalyse head-to-tail macrocyclization are repurposed here to enable regioselective macrocyclization of branched peptides with multiple nucleophiles, affording lariat-shaped peptides with various sequences and ring sizes. Coupled with subsequent site-selective acylation chemistry, this chemoenzymatic approach facilitates modular access to structurally diverse lariat lipopeptides.
{"title":"Non-ribosomal peptide cyclase-directed chemoenzymatic synthesis of lariat lipopeptides","authors":"Masakazu Kobayashi, Kenichi Matsuda, Yuito Yamada, Rintaro Ichihara, Naho Onozawa, Hanako Fukano, Yoshihiko Hoshino, Aki Hirabayashi, Masato Suzuki, Akira Katsuyama, Satoshi Ichikawa, Toshiyuki Wakimoto","doi":"10.1038/s41557-025-01979-6","DOIUrl":"10.1038/s41557-025-01979-6","url":null,"abstract":"Lariat-shaped lipopeptides are important antimicrobial agents; however, their complex structures pose synthetic challenges that hamper efficient structural diversification. Here we report a new chemoenzymatic approach that facilitates access to lariat-shaped macrocycles. Unprotected, branched peptides bearing multiple nucleophiles, including a native amino terminus and a pseudo-amino terminus, were site-selectively cyclized using versatile non-ribosomal peptide cyclases, generating an array of lariat peptides with diverse sequences and ring sizes. The generality of this strategy was demonstrated using two penicillin-binding protein-type thioesterases, SurE and WolJ, as well as one type-I thioesterase, TycC thioesterase. Furthermore, the remaining nucleophile, which was not involved in the cyclization process, was exploited as a reactive handle for subsequent diversification via a site-selective acylation reaction (that is, Ser/Thr ligation). The tandem cyclization–acylation strategy enabled the one-pot, modular synthesis of lariat-shaped lipopeptides equipped with various acyl groups. Biological screening revealed that the site-selective acylation endowed the macrocyclic scaffolds with antimycobacterial activity and led to the identification of lipopeptides that inhibit 50% of growth at concentrations of 8–16 µg ml−1. Non-ribosomal peptide cyclases that catalyse head-to-tail macrocyclization are repurposed here to enable regioselective macrocyclization of branched peptides with multiple nucleophiles, affording lariat-shaped peptides with various sequences and ring sizes. Coupled with subsequent site-selective acylation chemistry, this chemoenzymatic approach facilitates modular access to structurally diverse lariat lipopeptides.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"18 1","pages":"180-188"},"PeriodicalIF":20.2,"publicationDate":"2025-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.comhttps://www.nature.com/articles/s41557-025-01979-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145445416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-03DOI: 10.1038/s41557-025-01988-5
Joan Serrano-Plana
Philippe Loubet and André Estévez-Torres, from Bordeaux INP and CNRS-University of Lille respectively, talk to Nature Chemistry about assessing the carbon footprint of chemistry laboratories, and approaches to reducing their environmental impact.
分别来自波尔多国家化学研究所和法国国家科学研究院-里尔大学的Philippe Loubet和andr est - torres在《自然化学》杂志上谈到了评估化学实验室的碳足迹，以及减少它们对环境影响的方法。
{"title":"Reducing the carbon footprint of chemistry labs","authors":"Joan Serrano-Plana","doi":"10.1038/s41557-025-01988-5","DOIUrl":"10.1038/s41557-025-01988-5","url":null,"abstract":"Philippe Loubet and André Estévez-Torres, from Bordeaux INP and CNRS-University of Lille respectively, talk to Nature Chemistry about assessing the carbon footprint of chemistry laboratories, and approaches to reducing their environmental impact.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"17 11","pages":"1624-1625"},"PeriodicalIF":20.2,"publicationDate":"2025-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-03DOI: 10.1038/s41557-025-01982-x
Tobias Pausch, Bernd M. Schmidt
Porous materials have long been a focus of research for gas separations. Now, flexible, highly fluorinated coordination polymers lacking permanently built-in cavities have been shown to adsorb CO2 through a dissolution-like uptake process. The presence of dynamic perfluoroalkyl regions within the crystals is key to enabling transient porosity and establishing strong interactions with CO2.
{"title":"CO2 sorption in fluorinated non-porous coordination polymers","authors":"Tobias Pausch, Bernd M. Schmidt","doi":"10.1038/s41557-025-01982-x","DOIUrl":"10.1038/s41557-025-01982-x","url":null,"abstract":"Porous materials have long been a focus of research for gas separations. Now, flexible, highly fluorinated coordination polymers lacking permanently built-in cavities have been shown to adsorb CO2 through a dissolution-like uptake process. The presence of dynamic perfluoroalkyl regions within the crystals is key to enabling transient porosity and establishing strong interactions with CO2.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"17 11","pages":"1626-1627"},"PeriodicalIF":20.2,"publicationDate":"2025-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-03DOI: 10.1038/s41557-025-01983-w
Bruce C. Gibb
The buffering capacity of the world’s oceans has helped offset the effects of CO2 emissions on climate; however, it is not without cost. Bruce Gibb discusses the causes, the chemistry and the consequences of ocean acidification.
{"title":"Extinguishing the saturation horizon","authors":"Bruce C. Gibb","doi":"10.1038/s41557-025-01983-w","DOIUrl":"10.1038/s41557-025-01983-w","url":null,"abstract":"The buffering capacity of the world’s oceans has helped offset the effects of CO2 emissions on climate; however, it is not without cost. Bruce Gibb discusses the causes, the chemistry and the consequences of ocean acidification.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"17 11","pages":"1619-1620"},"PeriodicalIF":20.2,"publicationDate":"2025-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-03DOI: 10.1038/s41557-025-01978-7
Benjamin N. Bhawal
Benjamin N. Bhawal examines the enigmatic history of ribose in chemistry, its multifaceted structure, and its role in the origin of life and the design of future therapeutics.
Benjamin N. Bhawal研究了核糖在化学中的神秘历史，它的多面结构，以及它在生命起源和未来治疗设计中的作用。
{"title":"Ribose at the heart of life","authors":"Benjamin N. Bhawal","doi":"10.1038/s41557-025-01978-7","DOIUrl":"10.1038/s41557-025-01978-7","url":null,"abstract":"Benjamin N. Bhawal examines the enigmatic history of ribose in chemistry, its multifaceted structure, and its role in the origin of life and the design of future therapeutics.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"17 11","pages":"1798-1798"},"PeriodicalIF":20.2,"publicationDate":"2025-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145429602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-31DOI: 10.1038/s41557-025-01974-x
Liang Zhang, Jiahui Du, Zikai Xie, Linjiang Chen, Wenlang Li, Weihang Geng, Yi Zhou, Xinwen Ou, Chengtao Gong, Yijun Gao, Shan He, Chunxing Yan, Chengbin Zhao, Yantian Jiao, Sheng-Yi Yang, Bing Huang, Jacky W. Y. Lam, Jun Qian, Jun Jiang, Ben Zhong Tang, Hexiang Deng
The development of porous crystalline materials with targeted properties remains challenging owing to the vast chemical design space and the high cost of experimental screening. Here we develop an artificial-intelligence-assisted interactive experiment–learning evolution approach to accelerate the discovery of highly fluorescent covalent organic frameworks (COFs). This approach integrates model recommendation, experimental validation and active learning in an iterative refinement cycle, allowing the artificial intelligence model to evolve along the process. Among the 520 possible combinations derived from a library of 20 amine and 26 aldehyde building blocks, we needed to experimentally evaluate only 11 COFs to identify one with a remarkable photoluminescence quantum yield of 41.3%. By embedding electronic configuration and quantum-level insights into the learning process, this approach transcends intuition based on statistical analysis intuition to enable material discovery driven by chemical knowledge, enhancing prediction reliability and interpretability. We also reveal the fluorescence mechanism of these COFs and outline the critical role of HOMO–LUMO alignment and excited-state charge distribution. Developing porous crystalline materials with tailored properties is challenging because of the vast design space and the high cost of screening. Now, highly fluorescent covalent organic frameworks have been identified through an AI-assisted iterative experiment–learning cycle workflow that integrates electronic configuration and quantum-level insights into the learning process.
{"title":"Discovery of highly fluorescent covalent organic frameworks through AI-assisted iterative experiment–learning cycles","authors":"Liang Zhang, Jiahui Du, Zikai Xie, Linjiang Chen, Wenlang Li, Weihang Geng, Yi Zhou, Xinwen Ou, Chengtao Gong, Yijun Gao, Shan He, Chunxing Yan, Chengbin Zhao, Yantian Jiao, Sheng-Yi Yang, Bing Huang, Jacky W. Y. Lam, Jun Qian, Jun Jiang, Ben Zhong Tang, Hexiang Deng","doi":"10.1038/s41557-025-01974-x","DOIUrl":"10.1038/s41557-025-01974-x","url":null,"abstract":"The development of porous crystalline materials with targeted properties remains challenging owing to the vast chemical design space and the high cost of experimental screening. Here we develop an artificial-intelligence-assisted interactive experiment–learning evolution approach to accelerate the discovery of highly fluorescent covalent organic frameworks (COFs). This approach integrates model recommendation, experimental validation and active learning in an iterative refinement cycle, allowing the artificial intelligence model to evolve along the process. Among the 520 possible combinations derived from a library of 20 amine and 26 aldehyde building blocks, we needed to experimentally evaluate only 11 COFs to identify one with a remarkable photoluminescence quantum yield of 41.3%. By embedding electronic configuration and quantum-level insights into the learning process, this approach transcends intuition based on statistical analysis intuition to enable material discovery driven by chemical knowledge, enhancing prediction reliability and interpretability. We also reveal the fluorescence mechanism of these COFs and outline the critical role of HOMO–LUMO alignment and excited-state charge distribution. Developing porous crystalline materials with tailored properties is challenging because of the vast design space and the high cost of screening. Now, highly fluorescent covalent organic frameworks have been identified through an AI-assisted iterative experiment–learning cycle workflow that integrates electronic configuration and quantum-level insights into the learning process.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"17 11","pages":"1645-1654"},"PeriodicalIF":20.2,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145411831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-30DOI: 10.1038/s41557-025-01902-z
Patrick R. A. Zanon, Fengchao Yu, Patricia Z. Musacchio, Lisa Lewald, Michael Zollo, Kristina Krauskopf, Dario Mrdović, Patrick Raunft, Thomas E. Maher, Marko Cigler, Christopher J. Chang, Kathrin Lang, F. Dean Toste, Alexey I. Nesvizhskii, Stephan M. Hacker
Covalent inhibitors that do not rely on hijacking enzymatic activity have mainly been limited to those targeting cysteine residues. The development of such cysteine-directed covalent inhibitors has greatly profited from the use of competitive residue-specific proteomics to determine their proteome-wide selectivity. Several probes have been developed to monitor other amino acids using this technology, and many more electrophiles exist to modify proteins. Nevertheless, there has been a lack of direct, proteome-wide comparisons of the selectivity of diverse electrophiles. Here we developed an unbiased workflow to analyse electrophile selectivity proteome-wide and used it to directly compare 56 alkyne probes containing diverse reactive groups. In this way, we verified and identified probes to monitor a total of nine different amino acids, as well as the protein amino terminus, across the proteome. Covalent inhibitors are powerful entities in drug discovery. Now the amino acid selectivity and reactivity of a diverse electrophile library have been assessed proteome-wide using an unbiased workflow. This comparative analysis and the probes described could help guide the discovery and design of covalent ligands targeting residues beyond cysteine.
{"title":"Profiling the proteome-wide selectivity of diverse electrophiles","authors":"Patrick R. A. Zanon, Fengchao Yu, Patricia Z. Musacchio, Lisa Lewald, Michael Zollo, Kristina Krauskopf, Dario Mrdović, Patrick Raunft, Thomas E. Maher, Marko Cigler, Christopher J. Chang, Kathrin Lang, F. Dean Toste, Alexey I. Nesvizhskii, Stephan M. Hacker","doi":"10.1038/s41557-025-01902-z","DOIUrl":"10.1038/s41557-025-01902-z","url":null,"abstract":"Covalent inhibitors that do not rely on hijacking enzymatic activity have mainly been limited to those targeting cysteine residues. The development of such cysteine-directed covalent inhibitors has greatly profited from the use of competitive residue-specific proteomics to determine their proteome-wide selectivity. Several probes have been developed to monitor other amino acids using this technology, and many more electrophiles exist to modify proteins. Nevertheless, there has been a lack of direct, proteome-wide comparisons of the selectivity of diverse electrophiles. Here we developed an unbiased workflow to analyse electrophile selectivity proteome-wide and used it to directly compare 56 alkyne probes containing diverse reactive groups. In this way, we verified and identified probes to monitor a total of nine different amino acids, as well as the protein amino terminus, across the proteome. Covalent inhibitors are powerful entities in drug discovery. Now the amino acid selectivity and reactivity of a diverse electrophile library have been assessed proteome-wide using an unbiased workflow. This comparative analysis and the probes described could help guide the discovery and design of covalent ligands targeting residues beyond cysteine.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"17 11","pages":"1712-1721"},"PeriodicalIF":20.2,"publicationDate":"2025-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.comhttps://www.nature.com/articles/s41557-025-01902-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145397316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-30DOI: 10.1038/s41557-025-01906-9
Jeyun Jo, Matthew Bogyo
In the growing field of chemical proteomics, there is a need for general methods to map the reactivity profiles of covalent probes in complex proteomes. Now, a completely unbiased proteomic workflow has been developed that enables global characterization of the amino acid residues, chemically labelled by reactive electrophilic probes.
{"title":"A pipeline for proteome-wide analysis of electrophile selectivity","authors":"Jeyun Jo, Matthew Bogyo","doi":"10.1038/s41557-025-01906-9","DOIUrl":"10.1038/s41557-025-01906-9","url":null,"abstract":"In the growing field of chemical proteomics, there is a need for general methods to map the reactivity profiles of covalent probes in complex proteomes. Now, a completely unbiased proteomic workflow has been developed that enables global characterization of the amino acid residues, chemically labelled by reactive electrophilic probes.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"17 11","pages":"1638-1640"},"PeriodicalIF":20.2,"publicationDate":"2025-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145397312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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