V. Lyalko, M. Popov, S. Stankevich, S. Shklyar, V. N. Podorvan, Nicolay I. Likholit, V. M. Tiagur, Catherina V. Dobrovolska
{"title":"Physical Simulator of Infrared Spectroradiometer with Spatial Resolution Enhancement Using Subpixel Image Registration and Processing","authors":"V. Lyalko, M. Popov, S. Stankevich, S. Shklyar, V. N. Podorvan, Nicolay I. Likholit, V. M. Tiagur, Catherina V. Dobrovolska","doi":"10.15407/SCIN11.06.016","DOIUrl":"https://doi.org/10.15407/SCIN11.06.016","url":null,"abstract":"","PeriodicalId":19061,"journal":{"name":"Nauka ta Innovacii","volume":"11 1","pages":"16-28"},"PeriodicalIF":0.0,"publicationDate":"2015-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66980410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"New Heterocyclic Systems for New Drugs","authors":"S. L. Bogza","doi":"10.15407/SCIN11.06.085","DOIUrl":"https://doi.org/10.15407/SCIN11.06.085","url":null,"abstract":"","PeriodicalId":19061,"journal":{"name":"Nauka ta Innovacii","volume":"11 1","pages":"85-93"},"PeriodicalIF":0.0,"publicationDate":"2015-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66980962","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Innovation Developments of Coal Chemistry Science in L.M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry of NAS of Ukraine","authors":"T. Shendrik","doi":"10.15407/SCIN11.06.075","DOIUrl":"https://doi.org/10.15407/SCIN11.06.075","url":null,"abstract":"","PeriodicalId":19061,"journal":{"name":"Nauka ta Innovacii","volume":"13 1","pages":"75-84"},"PeriodicalIF":0.0,"publicationDate":"2015-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66980830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Tasks, Achievements and Prospects of L.M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry of NAS of Ukraine","authors":"A. Popov","doi":"10.15407/scin11.06.043","DOIUrl":"https://doi.org/10.15407/scin11.06.043","url":null,"abstract":"","PeriodicalId":19061,"journal":{"name":"Nauka ta Innovacii","volume":"11 1","pages":"43-46"},"PeriodicalIF":0.0,"publicationDate":"2015-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66980269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Korotkikh, V. Saberov, G. Rayenko, N. V. Glinyanaya, А.V. Knishevitsky, Оles Shvaika
The fundamental researches in the chemistry of stable carbenes carried out by the L.M. Litvinenko Institute of Physical, Organic & Coal Chemistry of the NAS of Ukraine (IPOCC) over the last decade and applications in the field of «green» technologies based on the results of these researches have been described. Carbene versions of Claisen ester condensation with the formation of zwitterionic compounds, the Leuckart-Wallach reaction with the autoreduction of carbenoid azolium salts, the Hofmann cleavage of aminocarbene insertion products, induced tandem autotransformation of 1,2,4-triazol-5-ylidenes into 5-amidino-1,2,4-triazoles have been discovered. New carbene reactions of addition, deesterification, oxidation, and complex formation have been found. Effective methods for obtaining stable carbenes and carbenoids have been suggested. New types of carbenes, benzimidazolylidenes, superstable conjugated bis-carbenes, and carbenoids have been synthesized. The existence of hypernucleophilic carbenes has been theoretically predicted and experimentally confirmed. Prospects for the use of carbenes and their derivatives, in particular, carbene complexes of transition metals in the catalysis of organic reactions and the search of biologically active compounds have been outlined.
在过去的十年中，乌克兰国家科学院(IPOCC)的L.M.利特维年科物理、有机和煤炭化学研究所(l.m.l itvinenko Institute of Physical, Organic & Coal chemistry)对稳定碳烯的化学基础研究以及基于这些研究结果的“绿色”技术领域的应用进行了描述。卡宾型克拉森酯缩合生成两性离子化合物，类卡宾唑盐自还原的Leuckart-Wallach反应，氨基卡宾插入产物的Hofmann裂解，诱导1,2,4-三唑-5-酰基烯串联自转化为5-氨基-1,2,4-三唑。发现了加成、脱酯化、氧化和络合物的新反应。提出了制备稳定碳烯和类碳烯的有效方法。合成了新型卡宾、苯并咪唑聚醚、超稳定共轭双卡宾和类卡宾。超亲核碳烯的存在已被理论预测和实验证实。概述了碳烯及其衍生物，特别是过渡金属碳烯配合物在催化有机反应和寻找生物活性化合物方面的应用前景。
{"title":"Chemistry of Stable Carbenes and «Green» Technologies","authors":"N. Korotkikh, V. Saberov, G. Rayenko, N. V. Glinyanaya, А.V. Knishevitsky, Оles Shvaika","doi":"10.15407/SCIN11.06.057","DOIUrl":"https://doi.org/10.15407/SCIN11.06.057","url":null,"abstract":"The fundamental researches in the chemistry of stable carbenes carried out by the L.M. Litvinenko Institute of Physical, Organic & Coal Chemistry of the NAS of Ukraine (IPOCC) over the last decade and applications in the field of «green» technologies based on the results of these researches have been described. Carbene versions of Claisen ester condensation with the formation of zwitterionic compounds, the Leuckart-Wallach reaction with the autoreduction of carbenoid azolium salts, the Hofmann cleavage of aminocarbene insertion products, induced tandem autotransformation of 1,2,4-triazol-5-ylidenes into 5-amidino-1,2,4-triazoles have been discovered. New carbene reactions of addition, deesterification, oxidation, and complex formation have been found. Effective methods for obtaining stable carbenes and carbenoids have been suggested. New types of carbenes, benzimidazolylidenes, superstable conjugated bis-carbenes, and carbenoids have been synthesized. The existence of hypernucleophilic carbenes has been theoretically predicted and experimentally confirmed. Prospects for the use of carbenes and their derivatives, in particular, carbene complexes of transition metals in the catalysis of organic reactions and the search of biologically active compounds have been outlined.","PeriodicalId":19061,"journal":{"name":"Nauka ta Innovacii","volume":"11 1","pages":"57-67"},"PeriodicalIF":0.0,"publicationDate":"2015-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66980121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Determination of Royalty Rates in the International Technology Transfer Contracts","authors":"Y. Kapitsa","doi":"10.15407/SCIN11.02.055","DOIUrl":"https://doi.org/10.15407/SCIN11.02.055","url":null,"abstract":"","PeriodicalId":19061,"journal":{"name":"Nauka ta Innovacii","volume":"11 1","pages":"55-74"},"PeriodicalIF":0.0,"publicationDate":"2015-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66979835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Development and Testing of Complex Molecular Genetic Diagnosis of Neoplasms of the Genitourinary System","authors":"G. Telegeev","doi":"10.15407/SCIN11.02.037","DOIUrl":"https://doi.org/10.15407/SCIN11.02.037","url":null,"abstract":"","PeriodicalId":19061,"journal":{"name":"Nauka ta Innovacii","volume":"11 1","pages":"37-45"},"PeriodicalIF":0.0,"publicationDate":"2015-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66979755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Prospects for Creating a Specialized Innovation Bank in Ukraine","authors":"I. B. Filonova","doi":"10.15407/SCIN11.02.083","DOIUrl":"https://doi.org/10.15407/SCIN11.02.083","url":null,"abstract":"","PeriodicalId":19061,"journal":{"name":"Nauka ta Innovacii","volume":"11 1","pages":"83-93"},"PeriodicalIF":0.0,"publicationDate":"2015-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66979941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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