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A complete workflow applied on an oil reservoir analogue to evaluate the ability of 4D seismics to anticipate the success of a chemical enhanced oil recovery process 一个完整的工作流程应用于油藏模拟,以评估四维地震的能力,以预测化学提高采油过程的成功
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020011
N. Dubos‐Sallée, A. Fourno, Jeanneth Zarate-Rada, V. Gervais, P. Rasolofosaon, O. Lerat
In an Enhanced Oil Recovery (EOR) process, one of the main difficulties is to quickly evaluate if the injected chemical products actually improve oil recovery in the reservoir. The efficiency of the process can be monitored in the vicinity of wells, but it may take time to estimate it globally in the reservoir. The objective of this paper is to investigate the ability of 4D seismics to bridge this gap and to help predict the success or breakdown of a production strategy at reservoir scale. To that purpose, we consider a complete workflow for simulating realistic reservoir exploitation using chemical EOR and 4D seismic modeling. This workflow spans from geological description to seismic monitoring simulation and seismic attributes analysis, through geological and reservoir modeling. It is applied here on a realistic case study derived from an outcrop analog of turbiditic reservoirs, for which the efficiency of chemical EOR by polymer and surfactant injection is demonstrated. For this specific field monitoring application, the impact of both waterflooding and proposed EOR injection is visible on the computed seismics. However, EOR injection induces a more continuous water front that can be clearly visible on seismics. In this case, the EOR efficiency can thus be related to the continuity of the water front as seen on seismics. Nevertheless, in other cases, chemical EOR injections may have more moderate impacts, or the field properties may be less adapted to seismic monitoring. This points out the importance of the proposed workflow to check the relevance of seismic monitoring and to design the most adapted monitoring strategy. Numerous perspectives are proposed at the end of the paper. In particular, experts of the different disciplines involved in the proposed workflow can benefit from the availability of a complete set of well-controlled data of various types to test and improve their own tools. In contrast, the non-experts can easily and quickly benefit from “hands-on” experiments for understanding the involved phenomena. Furthermore, the proposed workflow can be directly applied to geological reservoirs all over the world.
在提高采收率(EOR)过程中,主要困难之一是快速评估注入的化学产品是否真的提高了油藏的采收率。该过程的效率可以在井附近进行监测,但在油藏中进行全球评估可能需要时间。本文的目的是研究四维地震的能力,以弥补这一差距,并帮助预测油藏规模生产策略的成功或失败。为此,我们考虑了一套完整的工作流程,利用化学提高采收率和四维地震建模来模拟真实的油藏开发。该工作流程从地质描述到地震监测模拟和地震属性分析,再到地质和储层建模。将该方法应用于浊积岩油藏露头模拟的实际应用实例,验证了聚合物和表面活性剂联合化学提高采收率的有效性。对于这种特定的现场监测应用,水驱和建议的EOR注入对计算地震的影响是可见的。然而,EOR注入会产生更连续的水前缘,在地震时可以清晰地看到。在这种情况下,提高采收率的效率因此可以与在地震中看到的前缘的连续性有关。然而,在其他情况下,化学提高采收率的影响可能更温和,或者油田性质可能不太适合地震监测。这指出了所提出的工作流程对于检查地震监测的相关性和设计最适合的监测策略的重要性。在文章的最后提出了许多观点。特别地,所建议的工作流中涉及的不同学科的专家可以从各种类型的完整的控制良好的数据集的可用性中受益,以测试和改进他们自己的工具。相比之下,非专家可以很容易和快速地从“动手”实验中受益,以理解所涉及的现象。此外,该工作流程可直接应用于世界各地的地质储层。
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引用次数: 2
Effect of a modified nano clay and nano graphene on rheology, stability of water-in-oil emulsion, and filtration control ability of oil-based drilling fluids: a comparative experimental approach 改性纳米粘土和纳米石墨烯对油基钻井液流变性、油包水乳状液稳定性和过滤控制能力的影响:对比实验方法
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020032
Vahid Nooripoor, A. Hashemi
During the past decade, researchers have used different Nano-Particles (NPs) due to their unique characteristics for improving formulation of Oil-Based Drilling Fluids (OBDFs). This study is the first research that investigates the effect of a Modified Nano Clay (MNC), namely CLOISITE 5 and non-functionalized Nano Graphene (NG) on rheology, electrical/emulsion stability, and filtration control ability, as the main properties of OBDFs. Initially, five concentrations of both NPs (0.25, 0.5, 1, 1.5, and 2 wt%) were added separately into an NP-free OBDF (the base fluid). Then, rheological properties and electrical stability of all prepared fluids were measured at three 90, 140, and 180 °F temperatures. Moreover, filtration test was carried out under 500 psi (3447 kPa) differential pressure and exposed to 300 °F temperature for all fluids. Since experimentally measured shear stresses followed well both Herschel Bulkley (shear-thinning) and Bingham Plastic models, effects of temperature and the NPs concentration on both model parameters are investigated more deeply in the paper. Activation energies calculated from Arrhenius model showed that MNC is more effective than NG on reducing the dependency of apparent and plastic viscosities of the base fluid on temperature. MNC, due to its amphiphilic structure, significantly stabilizes water-in-oil emulsion at all temperatures and concentrations, but NG with high electrical conductivity reduces the emulsion stability. The nanofluids containing 0.5 wt% MNC and 0.25 wt% NG which have respectively 32.6% and 43.5% fewer filtrate volumes than the base fluid, were considered as the optimal nanofluids from controlling filtration into formation aspect. Finally, MNC is applicable to enhance the formulation of the OBDF through supporting its commercial viscosifier, emulsifiers, and fluid loss control agent, but the negative effect of NG on emulsion stability limits its application.
在过去的十年中,由于纳米颗粒(NPs)的独特特性,研究人员使用了不同的纳米颗粒来改善油基钻井液(OBDFs)的配方。本研究首次研究了改性纳米粘土(MNC),即CLOISITE 5和非功能化纳米石墨烯(NG)对OBDFs的流变性、电/乳液稳定性和过滤控制能力的影响。最初,将五种浓度的NPs(0.25、0.5、1、1.5和2 wt%)分别加入到不含NPs的OBDF(基础液)中。然后,在90,140和180°F三种温度下测量所有制备的流体的流变性能和电稳定性。此外,所有流体的过滤测试均在500 psi (3447 kPa)压差和300°F的温度下进行。由于实验测量的剪切应力符合Herschel Bulkley(剪切-减薄)和Bingham塑性模型,因此本文更深入地研究了温度和NPs浓度对这两个模型参数的影响。根据Arrhenius模型计算的活化能表明,MNC比NG更有效地降低了基液表观粘度和塑性粘度对温度的依赖关系。MNC由于其两亲性结构,在任何温度和浓度下都能显著稳定油包水乳液,而导电性高的NG则会降低乳液的稳定性。含0.5 wt% MNC和0.25 wt% NG的纳米流体比基液的滤液体积分别减少32.6%和43.5%,从控制过滤到地层方面被认为是最佳的纳米流体。最后,MNC可以通过配合OBDF的商用增粘剂、乳化剂和降滤失剂来增强OBDF的配方,但NG对乳液稳定性的负面影响限制了它的应用。
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引用次数: 11
A proposed capillary number dependent model for prediction of relative permeability in gas condensate reservoirs: a robust non-linear regression analysis 一种预测凝析气藏相对渗透率的毛细管数依赖模型:鲁棒非线性回归分析
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020017
Mehdi Mahdaviara, A. Helalizadeh
Well deliverability reduction as a result of liquid (condensate) build up in near well regions is an important deal in the development of gas condensate reservoirs. The relative permeability is an imperative factor for characterization of the aforementioned problem. The dependence of relative permeability on the coupled effects of Interfacial Tension (IFT) and flow velocity (capillary number) together with phase saturation is well established in the literature. In gas condensate reservoirs, however, the influence of IFT and velocity on this parameter becomes more evident. The current paper aims to establish a new model for predicting the relative permeability of gas condensate reservoirs by employing the direct interpolation technique. To this end, the regression analysis was carried out using seven sets of literature published experimental data. The validity analysis was executed by utilizing statistical parameters integrated with graphical descriptions. Furthermore, a comparison was carried out between the proposed model and some literature published empirical models. The results of the examination demonstrated that the new model outperformed other correlations from the standpoints of accuracy and reliability.
在凝析气藏开发中,由于近井区液体(凝析油)积聚而导致的井产能下降是一个重要问题。相对渗透率是表征上述问题的一个重要因素。相对渗透率依赖于界面张力(IFT)、流速(毛细数)和相饱和度的耦合效应。而在凝析气藏中,IFT和速度对该参数的影响更为明显。本文旨在利用直接插值技术建立一种预测凝析气藏相对渗透率的新模型。为此,利用7组文献发表的实验数据进行回归分析。采用统计参数与图形描述相结合的方法进行效度分析。并将本文提出的模型与部分文献发表的实证模型进行了比较。检验结果表明,从准确性和可靠性的角度来看,新模型优于其他相关性。
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引用次数: 2
Well modelling methods in thermal reservoir simulation 热储模拟中的井建模方法
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020058
Hui Liu, Zhangxin Chen, L. Shen, X. Guo, Dongqi Ji
Reservoir simulation is of interdisciplinary research, including petroleum engineering, mathematics, and computer sciences. It studies multi-phase (water, oil and gas) flow in porous media and well modelling. The latter describes well behavior using physical and mathematical methods. In real world applications, there are many types of wells, such as injection wells, production wells and heaters, and their various operations, such as pressure control, rate control and energy control. This paper presents commonly used well types, well operations, and their mathematical models, such as bottom hole pressure, water rate, oil rate, liquid rate, subcool, and steam control. These are the most widely applied models in thermal reservoir simulations, and some of them can even be applied to the black oil and compositional models. The purpose of this paper is to review these well modelling methods and their mathematical models, which explain how the well operations are defined and computed. We believe a detailed introduction is important to other reseachers and simulator developers. They have been implemented in our in-house parallel thermal simulator. Numerical experiments have been carried out to validate the model implementations and demonstrate the scalability of the parallel thermal simulator.
油藏模拟是石油工程、数学、计算机科学等多学科交叉的研究领域。研究多孔介质中多相(水、油、气)流动和井模型。后者使用物理和数学方法描述井的动态。在实际应用中,有许多类型的井,如注水井、生产井和加热器,以及它们的各种操作,如压力控制、速率控制和能量控制。本文介绍了常用的井型、井作业及其数学模型,如井底压力、水量、油量、液量、过冷量和蒸汽控制。这些是热储层模拟中应用最广泛的模型,其中一些模型甚至可以应用于黑油和成分模型。本文的目的是回顾这些井建模方法及其数学模型,这些模型解释了如何定义和计算井作业。我们相信详细的介绍对其他研究人员和模拟器开发人员很重要。它们已经在我们内部的并行热模拟器中实现。通过数值实验验证了模型的实现,验证了并行热模拟器的可扩展性。
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引用次数: 6
Design and formulation of surfactant stabilized O/W emulsion for application in enhanced oil recovery: effect of pH, salinity and temperature 用于提高采收率的表面活性剂稳定油水乳状液的设计与配方:pH、盐度和温度的影响
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020066
Narendra Kumar, Saif Ali, Amit Kumar, A. Mandal
Mobilization of crude oil from the subsurface porous media by emulsion injection is one of the Chemical Enhanced Oil Recovery (C-EOR) techniques. However, deterioration of emulsion by phase separation under harsh reservoir conditions like high salinity, acidic or alkaline nature and high temperature pose a challenge for the emulsion to be a successful EOR agent. Present study aims at formulation of Oil-in-Water (O/W) emulsion stabilized by Sodium Dodecyl Sulfate (SDS) using the optimum values of independent variables – salinity, pH and temperature. The influence of above parameters on the physiochemical properties of the emulsion such as average droplet size, zeta (ζ) potential, conductivity and rheological properties were investigated to optimize the properties. The influence of complex interactions of independent variables on emulsion characteristics were premeditated by experimental model obtained by Taguchi Orthogonal Array (TOA) method. Accuracy and significance of the experimental model was verified using Analysis Of Variance (ANOVA). Results indicated that the experimental models were significantly (p < 0.05) fitted with main influence of salinity (making it a critical variable) followed by its interactions with pH and temperature for all the responses studied for the emulsion properties. No significant difference between the predicted and experimental response values of emulsion ensured the adequacy of the experimental model. Formulated optimized emulsion manifested good stability with 2417.73 nm droplet size, −72.52 mV ζ-potential and a stable rheological (viscosity and viscoelastic) behavior at extensive temperature range. Ultralow Interfacial Tension (IFT) value of 2.22E-05 mN/m was obtained at the interface of crude oil and the emulsion. A favorable wettability alteration of rock from intermediate-wet to water-wet was revealed by contact angle measurement and an enhanced emulsification behavior with crude oil by miscibility test. A tertiary recovery of 21.03% of Original Oil In Place (OOIP) was obtained on sandstone core by optimized emulsion injection. Therefore, performance assessment of optimized emulsion under reservoir conditions confirms its capability as an effective oil-displacing agent.
通过注入乳化液从地下多孔介质中动员原油是化学提高采收率(C-EOR)技术之一。然而,在高矿化度、酸性或碱性以及高温等恶劣的储层条件下,乳化液会因相分离而变质,这对乳化液能否成为一种成功的提高采收率剂构成了挑战。本文研究了十二烷基硫酸钠(SDS)稳定水包油(O/W)乳状液的配方,选取了矿化度、pH和温度为自变量的最佳值。考察了上述参数对乳液的平均粒径、ζ (ζ)电位、电导率和流变性能等理化性质的影响,以优化乳液的性能。利用田口正交阵列(TOA)法建立的实验模型,研究了自变量间复杂相互作用对乳化液特性的影响。采用方差分析(ANOVA)验证实验模型的准确性和显著性。结果表明,实验模型均显著(p < 0.05)拟合出盐度对乳化液性质的主要影响(使其成为关键变量),其次是与pH和温度的相互作用。乳化液的预测响应值与实验响应值无显著差异,保证了实验模型的充分性。优化后的乳液具有良好的稳定性,液滴尺寸为2417.73 nm, ζ-电位为- 72.52 mV,在较宽的温度范围内具有稳定的流变(粘度和粘弹性)性能。原油与乳化液界面的超低界面张力(IFT)值为2.22E-05 mN/m。接触角测试表明岩石的润湿性由中湿向水湿转变,混相试验表明岩石与原油的乳化行为增强。通过优化后的乳液注入,砂岩岩心三次采收率达到21.03%。因此,优化后的乳化液在油藏条件下的性能评价证实了其作为一种有效的驱油剂的能力。
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引用次数: 10
Experimental study ofin-situW/O emulsification during the injection of MgSO4and Na2CO3solutions in a glass micromodel 玻璃微模型中mgso4和na2co3溶液注入时w /O乳化的实验研究
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020072
S. Palizdan, H. Doryani, M. Riazi, M. Malayeri
In-situemulsification of injected brines of various types is gaining increased attention for the purpose of enhanced oil recovery. The present experimental study aims at evaluating the impact of injecting various solutions of Na2CO3and MgSO4 at different flow rates resembling those in the reservoir and near wellbore using a glass micromodel with different permeability regions. Emulsification process was visualized through the injection of deionized water and different brines at different flow rates. The experimental results showed that the extent of emulsions produced in the vicinity of the micromodel exit was profoundly higher than those at the entrance of the micromodel. The injection of Na2CO3brine after deionized water caused the impact of emulsification process more efficiently for attaining higher oil recovery than that for the MgSO4brine. For instance, the injection of MgSO4solution after water flooding increased oil recovery only up to 1%, while the equivalent figure for Na2CO3was 28%. It was also found that lower flow rate of injection would cause the displacement front to be broadened since the injected fluid had more time to interact with the oil phase. Finally, lower injection flow rate reduced the viscous force of the displacing fluid which led to lesser occurrence of viscous fingering phenomenon.
以提高采收率为目的,各种类型注入盐水的原位乳化越来越受到人们的关注。本实验研究旨在利用具有不同渗透率区域的玻璃微观模型,评估以不同流速注入不同na2co3和MgSO4溶液对油藏和近井的影响。以不同流速注入去离子水和不同盐水,观察乳化过程。实验结果表明,微模型出口附近的乳状物产生程度远高于微模型入口。去离子水后注入na2co3盐水比mgso4盐水更有效地影响乳化过程,获得更高的采收率。例如,水驱后注入mgso4溶液仅能提高1%的采收率,而na2co3的当量数据为28%。由于注入流体与油相有更多的相互作用时间,较低的注入流量会使驱替前缘变宽。最后,较低的注入流量降低了驱替液的粘性力,减少了粘指现象的发生。
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引用次数: 4
Optimization of development mode of asphalt profile control based on numerical simulation and study of its mechanism 基于数值模拟的沥青调剖发展模式优化及其机理研究
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020020
Fulin Wang, T. Yang, Yun-fei Zhao, Yanjun Fang, Fulin Wang, Gaojun Shan, Guangsheng Cao
Asphalt profile control is an effective method, which can further improve oil recovery of reservoir polymer flooded, it has a lot of advantages including high strength profile control, seal strata formation efficiency, low cost and no pollution, but there has not a perfect evaluation system for its development mode. The effect of different concentration, injection rate, radius of profile control, the timing of profile and segment combination way on the oil displacement effect of the asphalt profile control were researched using numerical simulation method on actual typical well area in Daqing oilfield, and the mechanism of asphalt profile control was studied in detail. According to the results of laboratory test, the largest Enhanced Oil Recovery (EOR) of asphalt was obtained at injection concentration 4000 mg/L, and the best combination was “high–low–high” concentration slug mode. According to the results of numerical simulation, the best concentration, injection rate, radius of profile control and injection timing were 4000 mg/L, 0.15 PV/a (Pore Volume [PV], m3), 1/2 of well spacing and 96% water cut in single slug of asphalt injection system, when the injection condition was multiple slug, the “high–low–high” slug combination mode was the best injection mode. These results could provide effective development basis for asphalt profile control after polymer flooding in thick oil layers.
沥青调剖是进一步提高油藏聚合物驱采收率的有效方法,具有调剖强度高、密封地层效率高、成本低、无污染等优点,但其开发模式尚无完善的评价体系。采用数值模拟方法,在大庆油田实际典型井区研究了不同浓度、注入速度、调剖半径、调剖时机和分段组合方式对沥青调剖驱油效果的影响,并对沥青调剖的机理进行了详细研究。室内试验结果表明,在注入浓度为4000 mg/L时,沥青的提高采收率最大,最佳组合为“高-低-高”浓度段塞模式。数值模拟结果表明,沥青注入体系单段塞的最佳浓度、注入速率、调剖半径和注入时间分别为4000 mg/L、0.15 PV/a(孔隙体积[PV], m3)、1/2井距和96%含水率,当注入条件为多段塞时,“高-低-高”段塞组合方式为最佳注入方式。研究结果可为厚油层聚合物驱后沥青剖面控制提供有效的开发依据。
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引用次数: 1
Analysis of the impacts of relative permeability and mobility ratio on heterogeneity loss error during upscaling of geological models 地质模型升级过程中相对渗透率和流度比对非均质损失误差的影响分析
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020049
A. Darban, M. Ghaedi, J. Qajar
The detailed geological fine grids are upscaled to create reliably sized simulation coarse models to solve flow equations in a more efficient way. Any upscaling process results in a loss of accuracy, along with an increase of errors. Numerical dispersion, heterogeneity loss, and connectivity misrepresentation are responsible for the upscaling errors. Recognizing the source of each error, and the behavior of influential factors through upscaling process could provide an optimum level of upscaling and an evaluation of upscaling methods’ accuracy. Despite the importance of upscaling error, little attention has been paid to this subject. This paper represents a rigorous analysis of the heterogeneity loss behavior associated with the relative permeability contrast and the mobility ratio under a waterflooding process. For this purpose, heterogeneous fine grid models are constructed by the fractional Brownian motion process. The models are upscaled by three upscaling factors. The models achieved are implemented to eliminate the impact of numerical error among upscaling errors in order to focus strictly on heterogeneity loss. Water–oil displacement simulation is then performed on fine and corresponding refined upscaled models at three different ratios of relative permeabilities and mobility ratios. In the next stage, the relation between flow performance error and heterogeneity loss is investigated by the heterogeneity loss plot. The slope of this plot provides the reservoir engineer an insight to evaluate the performance of upscaling methods and the behavior of the influential factors on upscaling errors. Moreover, by using the heterogeneity loss plot for each ratio, a limit of coarsening is presented. Based on the results, the heterogeneity loss error is affected more by the mobility ratio contrast than the relative permeability difference. Also, it is demonstrated that water-wet reservoirs with light oil are more sensitive to the level of upscaling.
将详细的地质细网格进行放大,以创建可靠尺寸的模拟粗模型,从而更有效地求解流动方程。任何升级过程都会导致准确性的损失,以及错误的增加。数值色散、非均匀性损失和连通性错误表征是导致升尺度误差的原因。识别每个误差的来源和影响因素通过升级过程的行为,可以提供一个最优的升级水平和评估升级方法的准确性。尽管放大误差很重要,但很少有人注意到这一问题。本文严格分析了水驱过程中非均质损失与相对渗透率对比和流度比的关系。为此,利用分数布朗运动过程构建了非均匀精细网格模型。模型通过三个升级因素进行升级。所建立的模型是为了消除上尺度误差中数值误差的影响,从而严格关注非均匀性损失。在三种不同的相对渗透率和流度比下,对精细模型和相应的精细模型进行了水-油驱替模拟。下一阶段,通过非均质损失图研究流动性能误差与非均质损失之间的关系。该图的斜率为油藏工程师提供了评价上尺度方法的性能以及影响上尺度误差的因素的行为的洞察力。此外,利用各比值的非均质损失图,给出了粗化的极限。结果表明,非均质损失误差受迁移率对比的影响大于相对渗透率差异的影响。此外,研究还表明,含轻质油的水湿型油藏对升级程度更为敏感。
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引用次数: 2
A study in fractional diffusion: Fractured rocks produced through horizontal wells with multiple, hydraulic fractures 分数扩散的研究:水平井产生的裂缝岩石具有多个水力裂缝
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020062
R. Raghavan, Chih-Cheng Chen
The spatiotemporal evolution of transients in fractured rocks often displays unusual characteristics and is traced to multifaceted origins such as micro-discontinuity in rock properties, rock fragmentation, long-range connectivity and complex flow paths. A physics-based model that incorporates transient propagation wherein the mean square displacement of the diffusion front follows a nonlinear scaling with time is proposed. This model is based on fractional diffusion. The motivation for fractional flux laws follows from the existence of long-range connectivity that results in the mean square displacement of fronts moving faster than predicted by classical models; correspondingly, obstructions and discontinuities, local flow reversals, intercalations, etc. produce the opposite effect with fronts moving at a slower rate than classical predictions. The interplay of these two competing behaviors is quantified. We simulate transient production in a porous rock at the Theis scale as a result of production through a horizontal well consisting of multiple hydraulic fractures. Asymptotic solutions are derived and computations verified. The practical potential of this model is described through an example and the movement of fronts under the constraints of this model is demonstrated through the new expressions developed in this work. We demonstrate that this model offers a potential avenue to explain other behaviors noted in the literature. Though this work is developed in the context of applications to the earth sciences (production of hydrocarbons, extraction of geothermal resources, sequestration of radioactive waste and other fluids, groundwater flow), a minimal change in the Nomenclature permits application to other contexts. Ideas proposed here are particularly useful in the context of superdiffusion in bounded systems which until now, in many ways, has been considered to be an open problem.
断裂岩石瞬态的时空演化往往表现出不同寻常的特征,并可追溯到多方面的原因,如岩石性质的微不连续、岩石破碎、远距离连通性和复杂的流动路径。提出了一种包含瞬态传播的物理模型,其中扩散锋的均方位移随时间呈非线性缩放。这个模型是基于分数扩散的。分数通量定律的动机来自于长程连通性的存在,这种连通性导致锋面的均方位移比经典模型预测的要快;相应地,障碍物和不连续、局部气流逆转、夹层等会产生相反的效果,锋面的移动速度比经典预测的要慢。这两种竞争行为的相互作用是量化的。我们模拟了由多个水力裂缝组成的水平井在Theis规模下多孔岩石中的瞬态生产。导出了渐近解,并对计算结果进行了验证。通过一个实例说明了该模型的实际应用潜力,并通过本文开发的新表达式演示了该模型约束下锋面的运动。我们证明这个模型提供了一个潜在的途径来解释文献中提到的其他行为。虽然这项工作是在应用于地球科学(碳氢化合物的生产、地热资源的开采、放射性废物和其他流体的隔离、地下水流动)的背景下开展的,但对《命名法》的微小改动允许应用于其他情况。这里提出的思想在有界系统的超扩散中特别有用,到目前为止,在许多方面,超扩散一直被认为是一个开放的问题。
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引用次数: 3
Design of adsorption column for reclamation of methyldiethanolamine using homogeneous surface diffusion model 采用均匀表面扩散模型设计回收甲基二乙醇胺的吸附柱
IF 1.5 4区 工程技术 Q2 Energy Pub Date : 2020-01-01 DOI: 10.2516/ogst/2020073
P. Kannan, Priyabrata Pal, F. Banat
A predictive simulation model was applied to design a fixed-bed adsorber for studying the removal of Total Organic Acid (TOA) anions from lean Methyldiethanolamine (MDEA) solution using Calcium Alginate Bentonite (CAB) clay hybrid composite adsorbent. Unlike other conventional techniques typically used for packed bed design, the predictive Homogeneous Surface Diffusion Model (HSDM) does not require any test column breakthrough curves a priori. Mass transfer coefficients and isotherm model parameters are provided as input data to HSDM for simulating column breakthrough curves. Various isotherm models were fitted to batch equilibrium data for TOA adsorption on CAB composite adsorbent. Based on Akaike Information Criterion (AIC), Freundlich isotherm was selected and the model parameters were obtained by non-linear regression. Film transfer coefficients and surface diffusivities were determined using appropriate empirical correlations available in the literature. HSDM predictions were first validated using lab-scale column adsorption data generated at lower residence times. The effects of dimensionless numbers (Biot and Stanton) on breakthrough times were investigated using the dimensionless HSDM system and a suitable scale-up regime (Bi& ~& 1 and St& >& 10) was established wherein the sensitivity of mass transfer parameters would be minimal. Using similitude rules on key design parameters, a pilot-scale adsorption column was designed and breakthrough curves were generated using the validated HSDM. The appropriateness of the design technique was verified by comparing the estimated breakthrough data and column design parameters with conventional scale-up and kinetic approaches.
采用预测模拟模型设计固定床吸附装置,研究海藻酸钙膨润土(CAB)粘土杂化复合吸附剂对贫甲基二乙醇胺(MDEA)溶液中总有机酸(TOA)阴离子的去除效果。与填充床设计的其他常规技术不同,预测均匀表面扩散模型(HSDM)不需要任何先验的测试柱突破曲线。将传质系数和等温线模型参数作为HSDM模拟柱突曲线的输入数据。采用不同的等温线模型拟合了CAB复合吸附剂吸附TOA的批量平衡数据。基于赤池信息准则(Akaike Information Criterion, AIC),选择Freundlich等温线,通过非线性回归得到模型参数。薄膜转移系数和表面扩散系数是用文献中可用的适当的经验相关性来确定的。HSDM预测首先通过较低停留时间产生的实验室规模柱吸附数据进行验证。使用无量纲HSDM系统研究了无量纲数(Biot和Stanton)对突破时间的影响,并建立了一个合适的放大范围(Bi& ~& 1和St& >& 10),其中传质参数的灵敏度最小。利用关键设计参数的相似规则,设计了中试吸附柱,并利用验证后的HSDM生成了突破曲线。通过将估计的突破数据和柱设计参数与传统的放大和动力学方法进行比较,验证了设计技术的适用性。
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引用次数: 5
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Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles
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