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Polyvinylpyrrolidone-resorcinol-formaldehyde hydrogel system reinforced with bio-synthesized zinc-oxide for water shut-off in heterogeneous reservoir: An experimental investigation 生物合成氧化锌增强聚乙烯吡咯烷酮-间苯二酚-甲醛水凝胶体系封堵非均质油藏的实验研究
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021043
Reena, Abhinav Kumar, V. Srivastava, V. Mahto, Abha Choubey
This work aims at evaluating advancement in water shut-off performance using nanocomposite hydrogel (PVP-ZnO:RF) prepared from PolyVinylPyrrolidone (PVP); used as polymer, Resorcinol-Formaldehyde (RF); used as a crosslinker and nano Zinc Oxide (ZnO); used as strength modifier and it was compared with conventional hydrogel (PVP:RF) i.e., hydrogel without ZnO nanofiller. The ZnO, used as a nanofiller in this work, was successfully bio-synthesized (i.e., green route synthesized) from plant extract (Moringa oleifera leaves) and the average size was found to be 10 nm. In this research work, the effect of ZnO nanofiller on gelation time, gel strength, thermal stability, rheological properties and water shut-off performance was systematically evaluated. On the incorporation of ZnO nanofiller, gelation time decreases but gel strength increases. The thermal stability of hydrogel was studied using a Differential Scanning Calorimeter (DSC) that depicts maximum tolerable temperature increases from 86 °C to 92 °C at 0.5 wt.% of ZnO concentration in nanocomposite hydrogel (PVP). The mechanical stability of the nanocomposite hydrogel (PVP-ZnO:RF) demonstrates that infusion of ZnO nanofiller has significantly enhanced the dynamic moduli (i.e., storage modulus (G′) and loss modulus (G″)). Moreover, the optimum results of storage modulus (G′) and loss modulus (G″) are found at 0.5 wt.% of ZnO nanofiller. The water shut-off performance in the high permeable streak, in terms of percentage reduction in permeability, was 97% and 92% for nanocomposite hydrogel (PVP-ZnO:RF) and conventional hydrogel (PVP:RF), respectively. Also, the residual resistance factor is found to be 31.31 and 12.71 for PVP-ZnO:RF and PVP:RF hydrogels. Thus, the developed nanocomposite hydrogel (PVP-ZnO:RF) may be a promising solution to excessive water production in mature oil fields.
本研究旨在评价聚乙烯吡咯烷酮(PVP)制备的纳米复合水凝胶(PVP- zno:RF)的阻水性能进展;间苯二酚-甲醛(RF)用作聚合物;用作交联剂和纳米氧化锌(ZnO);并与常规水凝胶(PVP:RF)即不添加ZnO纳米填料的水凝胶进行了比较。以植物提取物(辣木叶)为原料,成功地合成了氧化锌纳米填料(即绿色路线合成),其平均粒径为10 nm。本研究系统评价了ZnO纳米填料对胶凝时间、胶凝强度、热稳定性、流变性能和堵水性能的影响。ZnO纳米填料的掺入使胶凝时间缩短,但胶凝强度增加。利用差示扫描量热计(DSC)研究了水凝胶的热稳定性,描述了纳米复合水凝胶(PVP)中ZnO浓度为0.5 wt.%时的最大耐受温度从86°C增加到92°C。纳米复合水凝胶(PVP-ZnO:RF)的力学稳定性表明,ZnO纳米填料的注入显著提高了动态模量(即存储模量(G′)和损耗模量(G″))。此外,当ZnO纳米填料含量为0.5 wt.%时,储能模量(G′)和损耗模量(G″)达到最佳效果。在高渗透条纹中,纳米复合水凝胶(PVP- zno:RF)和常规水凝胶(PVP:RF)的阻水性能分别为97%和92%。PVP- zno:RF和PVP:RF水凝胶的剩余阻力因子分别为31.31和12.71。因此,所开发的纳米复合水凝胶(PVP-ZnO:RF)可能是解决成熟油田过度产水的一种有希望的解决方案。
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引用次数: 3
Statistical estimation of frictional coefficients of faults based on a structural dataset in the Tuy Hoa–Vung Tau Region, Viet Nam 基于越南Tuy Hoa-Vung Tau地区结构数据集的断层摩擦系数统计估计
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/OGST/2021016
Do Van Linh, Nguyen Loi Loc, Vu Trong Tan, N. X. Huy, Nguyen Thi Thu Trang, Pham Huu Tai, M. Abdurrahman, F. Hidayat
This study estimates the shear friction coefficient from shear friction angles for the prediction of slip tendencies in the Tuy Hoa–Vung Tau region of Southern Vietnam. A dataset consisting of measured data of 355 fractured planes, striations, and unconformities in coastal areas as well as 239 offshore faults was analyzed based on the principles of statistical probability. As a result, 138 friction angles for the onshore and offshore faults were calculated based on shear fracture conjugate pairs. The goodness-of-fit test was used to define the probability distribution of the friction angles, which had a normal distribution. The acceptable average of friction angles for the onshore region with a reliability of more than 95% were in the range of 25.8–31.5°, which corresponds to frictional coefficients of 0.48–0.61. The acceptable average friction angles for the offshore region were relatively low at 23–31°, which corresponds to a frictional coefficient of 0.42–0.60. Owing to the heterogeneity of the fault system, the median value (19.12°) should be used as the lowest threshold value for slipping faults at all conditions. The recommended applicable average friction angles are 28.65° and 27° for the onshore and offshore regions, respectively. The estimation of the frictional coefficients is highly reliable, and it can be applied to other subsurface resource exploitation projects within the study area.
本研究利用剪切摩擦角估算剪切摩擦系数,用于预测越南南部Tuy Hoa-Vung Tau地区的滑动趋势。基于统计概率原理,对沿海地区355条断裂面、裂缝条、不整合面和239条海上断裂实测数据进行了分析。基于剪切断裂共轭对,计算了陆上断裂和海上断裂的138个摩擦角。采用拟合优度检验定义摩擦角的概率分布,其具有正态分布。陆上区域可接受的摩擦角平均值在25.8-31.5°范围内,可靠性超过95%,对应的摩擦系数为0.48-0.61。近海区域可接受的平均摩擦角相对较低,为23-31°,对应的摩擦系数为0.42-0.60。由于断层系统的非均质性,在所有条件下均应采用中值(19.12°)作为滑动断层的最低阈值。对于陆上和海上区域,推荐的平均摩擦角分别为28.65°和27°。摩擦系数估算值具有较高的可靠性,可应用于研究区内其他地下资源开发项目。
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引用次数: 1
A new method to select demulsifiers and optimize dosage at wet crude oil separation facilities 提出了湿式原油分离装置中破乳剂选择及用量优化的新方法
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/OGST/2020096
Guillaume Raynel, Debora Salomon Marques, Sajjad Al-Khabaz, Mohammad Al-Thabet, L. Oshinowo
The current practice for crude oil demulsifier selection consists of pre-screening of the best performing demulsifiers followed by field trials to determine the optimum demulsifier dosage. The method of choice for demulsifier ranking is the bottle test. As there is no standard bottle test method, there are different methodologies reported in the literature. In this work, a new approach to bottle test and field trial was described which improved significantly the selection and dosage of the demulsifier. The bottle test was optimized by measuring an accurate mass of demulsifier. This method produces repeatable results. This bottle-test methodology was benchmarked against field trial results performed in oil processing plants. The field trials were also improved to avoid the accumulation effect of demulsifier, when optimizing their dosage. The field data for the optimization of demulsifier dosage was analyzed mathematically; and a graphical method to determine the optimum range is described.
目前原油破乳剂选择的做法是预先筛选性能最好的破乳剂,然后进行现场试验,以确定最佳的破乳剂用量。破乳剂排序的选择方法是瓶试法。由于没有标准的瓶子测试方法,文献中报道了不同的方法。本文介绍了一种新的破乳剂瓶试和现场试验的方法,大大提高了破乳剂的选择和用量。通过对破乳剂质量的精确测量,优化了瓶试法。这种方法产生可重复的结果。这种瓶试方法是根据在石油加工厂进行的现场试验结果进行基准测试的。在优化破乳剂用量的同时,还对现场试验进行了改进,以避免破乳剂的积累效应。对破乳剂用量优化的现场数据进行了数学分析;并描述了一种确定最佳范围的图解方法。
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引用次数: 6
Thermal conductivity model function of porosity: review and fitting using experimental data 孔隙率的导热模型函数:用实验数据回顾和拟合
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021047
C. Preux, I. Malinouskaya
Thermal conductivity of porous rocks depends on a large variety of proper to rock parameters as well as external influences. Thus, it can generate difficulties in determining accurate thermal behavior of the rock. The rock parameters which influence the thermal conductivity are principally the porosity, the microstructure [1] and the mineral composition. However, these parameters, in turn, can be impacted by external influences such as temperature and pressure. An accurate determining of the thermal conductivity is crucial in oil and gas engineering or in geothermal application. For example, during thermal EOR or geothermal application, the porosity and/or the microstructure of the sedimentary rocks can vary due to the increase of temperature and pressure, and this modification must be quantified to be accounted for the thermal behavior of rocks. Many efforts have been done to estimate the thermal conductivity of sedimentary rocks in parallel to the experimental methods for its determination. These estimations have always been the subject of intensive studies, and a lot of data [2, 3] are obtained as well as models and methodologies to characterize the thermal conductivity of rocks [4–7]. Moreover, this type of estimation is well-known by other research communities. Indeed, we find the same formal analogy between Fourier, Ohm’s law, Darcy’s laws and thermal conductivity. For example, considering Darcy’s laws, the same problem is well-known and termed “upscaling” [8, 9] and consists in computation of the effective permeability considering a heterogeneous rock. Classically, the upscaling process can be related to percolation theory [10], which describes connectivity of objects within for example, a porous structure. We can also determine effects of this connectivity on macroscale properties such as thermal conductivity [11]. In particular, the fundamental contributions of Torquato who proposed strategies via rigorous microstructure-property relations [1, 12]. Finally, many technics are based on a porosity dependence and a link between the conceptual thermal conductivity of the non-porous rock, kR, and the thermal conductivity of the fluid saturated the porous rock kf. These technics are simple to implement especially when there is no precise information about the microstructure. In order to predict accurately the thermal efficiency of the geothermal installation or the oil recovery of a thermal EOR process, such as, for example, Steam Assisted Gravity Drainage (SAGD), very often the engineers invoke numerical simulations. Numerous reservoir simulators [13–16] allow to estimate the thermal conductivity as function of porosity, but these solutions are often based on a mixing laws which are quite simplistic models. The purpose of this paper is to propose a better methodology to predict a thermal conductivity of reservoir rocks depending on the porosity for a reservoir simulator which satisfy the following conditions
多孔岩石的热导率受多种岩石固有参数和外界影响的影响。因此,它可以产生困难,以确定准确的热行为的岩石。影响导热系数的岩石参数主要是孔隙度、微观结构[1]和矿物组成。然而,这些参数反过来又会受到温度和压力等外部影响的影响。准确测定导热系数在油气工程或地热应用中是至关重要的。例如,在热采或地热应用过程中,沉积岩的孔隙度和/或微观结构会因温度和压力的增加而发生变化,这种变化必须被量化,以解释岩石的热行为。在测定沉积岩热导率的实验方法的同时,已经做了许多努力来估计沉积岩的热导率。这些估计一直是深入研究的主题,并且获得了大量数据[2,3]以及表征岩石导热系数的模型和方法[4-7]。此外,这种类型的估计是其他研究团体所熟知的。事实上,我们在傅里叶定律、欧姆定律、达西定律和导热率之间发现了同样的形式类比。例如,考虑达西定律,同样的问题是众所周知的,被称为“升级”[8,9],包括考虑非均质岩石的有效渗透率的计算。经典地,升级过程可能与渗透理论有关[10],该理论描述了例如多孔结构内部物体的连通性。我们还可以确定这种连通性对热导率等宏观性质的影响[11]。特别是,Torquato通过严格的微观结构-性质关系提出了策略[1,12]。最后,许多技术都是基于孔隙度依赖性和非多孔岩石的概念导热系数kR与多孔岩石饱和流体的导热系数kf之间的联系。这些工艺易于实现,特别是在没有精确的微观结构信息的情况下。为了准确预测地热装置的热效率或热采收率,例如蒸汽辅助重力泄油(SAGD),工程师们经常使用数值模拟。许多油藏模拟器[13-16]都可以估计导热系数作为孔隙度的函数,但这些解决方案通常基于混合定律,这是非常简单的模型。本文的目的是为满足以下条件的储层模拟器提出一种更好的根据孔隙度预测储层岩石导热系数的方法
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引用次数: 5
Research on kinematics analysis of spherical single-cone PDC compound bit and rock breaking simulation verification 球形单锥PDC复合钻头运动学分析及破岩仿真验证研究
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021034
Chunyan Kong, Rongjun Zhu, Derong Zhang, Shuangshuang Li
The single-cone bit has become the first choice for slim hole sidetracking and deep well drilling with its unique rock breaking method and high ROP (Rate Of Penetration), with its main failure mode being of early excessive wear of the cutting teeth. In order to improve the adaptability of single-cone bits to hard and highly abrasive formations, a spherical single-cone Polycrystalline Diamond Compact (PDC) compound bit is designed. According to the characteristics of the tooth profile, the way of tooth arrangement and the way of contact between the cutting teeth and the rock, the acceleration equation to the cutting teeth of the spherical single-cone PDC compound bit is established. The acceleration of the single-cone bit is verified by numerical simulation experiment of rock-breaking. The shaft inclination angle of the cone, the position and height of the PDC teeth, the radius of the PDC teeth, the lateral rotation angle and the front inclination angle on the acceleration are studied. The results show that as the shaft inclination angle increases, the bit transmission ratio gradually increases, and the harder the rock formation, the larger the transmission ratio of the single-cone bit; the shaft inclination angle and the position of the PDC tooth have a greater influence on the acceleration of the PDC tooth, and the radius, lateral rotation angle and front inclination angle of the PDC tooth have a small influence on the acceleration of the PDC tooth; rock properties have an impact on the acceleration of the cutting teeth, with the acceleration of the cutting teeth in hard rock formations being higher than that in soft rock formations; near the top of the cone, the absolute acceleration of the cutting teeth will fluctuate sharply and cause severe wear of the cutting teeth, so the tooth distribution in this area should be strengthened; on the premise that the bearing life of the single-cone bit is allowed, the value of the shaft inclination angle β can be approached to 70°. The relative error between the theoretical analysis results of the acceleration of the PDC cutter and the rock-breaking simulation experiment results is between −0.95% and −2.24%. This research lays a theoretical foundation for the dynamic research of spherical single-cone PDC compound bit.
单牙轮钻头以其独特的破岩方式和较高的机械钻速(ROP)成为小井侧钻和深井钻井的首选钻头,其主要失效模式是切削齿早期过度磨损。为了提高单牙轮钻头对坚硬、高磨蚀性地层的适应性,设计了一种球形单牙轮PDC复合钻头。根据齿形特点、排齿方式以及切削齿与岩石的接触方式,建立了球形单锥PDC复合钻头切削齿的加速度方程。通过破岩数值模拟实验验证了单牙轮钻头的加速度。研究了锥体轴倾角、PDC齿的位置和高度、PDC齿的半径、侧向旋转角度和前倾角对加速度的影响。结果表明:随着轴倾角的增大,钻头传动比逐渐增大,地层越硬,单牙轮钻头传动比越大;轴倾角和PDC齿的位置对PDC齿的加速度影响较大,而PDC齿的半径、横向旋转角度和前倾角对PDC齿的加速度影响较小;岩石性质对切削齿加速度有影响,硬岩层中切削齿加速度大于软岩层;在锥体顶部附近,切削齿的绝对加速度会剧烈波动,造成切削齿的严重磨损,因此应加强该区域的齿分布;在允许单牙轮钻头轴承寿命的前提下,轴倾角β值可接近70°。PDC切削齿加速度理论分析结果与破岩模拟实验结果的相对误差在−0.95% ~−2.24%之间。该研究为球面单锥PDC复合钻头的动力学研究奠定了理论基础。
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引用次数: 0
Mathematical modeling and optimization of semi-regenerative catalytic reforming of naphtha 石脑油半再生催化重整的数学建模与优化
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021041
E. Ivanchina, Ekaterina Chernyakova, Inna Pchelintseva, D. Poluboyartsev
Catalytic naphtha reforming is extensively applied in petroleum refineries and petrochemical industries to convert low-octane naphtha into high-octane gasoline. Besides, this process is an important source of hydrogen and aromatics obtained as side products. The bifunctional Pt-catalysts for reforming are deactivated by coke formation during an industrial operation. This results to a reduction in the yield and octane number. In this paper modeling and optimization of a semi-egenerative catalytic reforming of naphtha is carried out considering catalyst deactivation and a complex multicomponent composition of a hydrocarbon mixture. The mathematical model of semi-egenerative catalytic reforming considering coke formation process was proposed. The operating parameters (yield, octane number, activity) for different catalysts were predicted and optimized. It was found that a decrease in the pressure range from 1.5 to 1.2 MPa at the temperature 478–481 °C and feedstock space velocity equal to 1.4–1 h induces an increase in the yield for 1–2 wt.% due to an increase in the aromatization reactions rate and a decrease in the hydrocracking reactions rate depending on the feedstock composition and catalyst type. It is shown that the decrease in pressure is limited by the requirements for the catalyst stability due to the increase in the coke formation rate. The criterion of optimality is the yield, expressed in octanes per tons.
催化石脑油重整广泛应用于炼油厂和石化行业,将低辛烷值的石脑油转化为高辛烷值的汽油。此外,该工艺是氢气和芳烃副产品的重要来源。用于重整的双功能pt催化剂在工业操作过程中因焦炭的形成而失活。这导致了产率和辛烷值的降低。考虑催化剂失活和烃类混合物复杂的多组分组成,对石脑油半再生催化重整过程进行了建模和优化。提出了考虑焦炭形成过程的半再生催化重整数学模型。对不同催化剂的操作参数(产率、辛烷值、活度)进行了预测和优化。结果表明,在温度478 ~ 481℃,进料空速为1.4 ~ 1 h的条件下,压力在1.5 ~ 1.2 MPa范围内降低,由于芳香化反应速率提高,加氢裂化反应速率降低,收率提高1 ~ 2 wt.%。结果表明,由于焦炭生成速率的提高,对催化剂稳定性的要求限制了压力的降低。最优的标准是产量,以每吨辛烷值表示。
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引用次数: 5
Generalized Multi-Scale Stochastic Reservoir Opportunity Index for enhanced well placement optimization under uncertainty in green and brownfields 广义多尺度随机储层机会指数在不确定条件下增强绿棕地井位优化
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/OGST/2021014
F. Vaseghi, M. Ahmadi, M. Sharifi, M. Vanhoucke
Well placement planning is one of the challenging issues in any field development plan. Reservoir engineers always confront the problem that which point of the field should be drilled to achieve the highest recovery factor and/or maximum sweep efficiency. In this paper, we use Reservoir Opportunity Index (ROI) as a spatial measure of productivity potential for greenfields, which hybridizes the reservoir static properties, and for brownfields, ROI is replaced by Dynamic Measure (DM), which takes into account the current dynamic properties in addition to static properties. The purpose of using these criteria is to diminish the search region of optimization algorithms and as a consequence, reduce the computational time and cost of optimization, which are the main challenges in well placement optimization problems. However, considering the significant subsurface uncertainty, a probabilistic definition of ROI (SROI) or DM (SDM) is needed, since there exists an infinite number of possible distribution maps of static and/or dynamic properties. To build SROI or SDM maps, the k-means clustering technique is used to extract a limited number of characteristic realizations that can reasonably span the uncertainties. In addition, to determine the optimum number of clustered realizations, Higher-Order Singular Value Decomposition (HOSVD) method is applied which can also compress the data for large models in a lower-dimensional space. Additionally, we introduce the multiscale spatial density of ROI or DM (D2ROI and D2DM), which can distinguish between regions of high SROI (or SDM) in arbitrary neighborhood windows from the local SROI (or SDM) maxima with low values in the vicinity. Generally, we develop and implement a new systematic approach for well placement optimization for both green and brownfields on a synthetic reservoir model. This approach relies on the utilization of multi-scale maps of SROI and SDM to improve the initial guess for optimization algorithm. Narrowing down the search region for optimization algorithm can substantially speed up the convergence and hence the computational cost would be reduced by a factor of 4.
在任何油田开发计划中,井位规划都是具有挑战性的问题之一。油藏工程师总是面临这样的问题:应该在油田的哪一点进行钻井,以获得最高的采收率和/或最大的波及效率。本文采用储层机会指数(ROI)作为绿地生产力潜力的空间度量,它混合了储层静态属性;对于棕地,ROI被动态度量(DM)所取代,该度量在考虑静态属性的同时考虑了当前的动态属性。使用这些准则的目的是缩小优化算法的搜索范围,从而减少优化的计算时间和成本,这是排井优化问题的主要挑战。然而,考虑到显著的地下不确定性,需要对ROI (SROI)或DM (SDM)进行概率定义,因为存在无数可能的静态和/或动态属性分布图。为了构建SROI或SDM地图,使用k-means聚类技术提取有限数量的特征实现,这些特征实现可以合理地跨越不确定性。此外,为了确定聚类实现的最佳数量,采用了高阶奇异值分解(HOSVD)方法,该方法还可以在低维空间中压缩大型模型的数据。此外,我们还引入了ROI或DM的多尺度空间密度(D2ROI和D2DM),它可以区分任意邻域窗口内高SROI(或SDM)的区域和附近低值的局部SROI(或SDM)最大值。一般来说,我们开发并实施了一种新的系统方法,用于在合成油藏模型上对绿地和棕地进行井位优化。该方法依赖于利用SROI和SDM的多比例尺地图来改进优化算法的初始猜测。缩小优化算法的搜索区域可以大大加快收敛速度,从而使计算量减少1 / 4。
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引用次数: 6
Optimization of the pre-treatment of white sawdust (Triplochiton scleroxylon) by the organosolv process for the production of bioethanol 有机溶剂法预处理白木屑制备生物乙醇的优化研究
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/OGST/2021004
Thierry Tchamba Tchuidjang, Eric Noubissie, A. Ali
The exploitation of our forests generates waste, amongst which sawdust produces approximately cubic meter per year. The objective of this work is to contribute to the improvement of the recovery process of this waste through the optimization of the pre-treatment stage of sawdust from Ayous (Triplochiton scleroxylon) by the organosolv process in order to produce bioethanol. To achieve this objective, Ayous sawdust was sampled and then characterized, followed by the pre-treatment through organosolv process. During pre-treatment, a composite experimental design centred on three factors (temperature, time, ethanol concentration) was used to study their effects on extraction of pentoses, reducing sugars and phenolic compounds. Analysis shows that Ayous sawdust contains 45.33 ± 5.5% cellulose, 30.32 ± 1.95% lignin and 20.03 ± 3.5% hemicellulose. To release the maximum of pentoses, reducing sugars and the minimum of phenolic compounds, an organosolv pre-treatment of this substrate should be carried out at 209.08 °C for 47.60 min with an ethanol–water ratio of 24.02%. Temperature is the factor having the most positive influence on the pre-treatment process whereas, ethanol concentration is not an essential factor. Organosolv pre-treatment is an effective process for delignification of the lignocellulosic structure of Ayous sawdust.
我们对森林的开采产生了废物,其中木屑每年产生大约立方米。本研究的目的是通过优化有机溶剂法处理青玉木屑生产生物乙醇的预处理阶段,为改进该废弃物的回收工艺做出贡献。为了实现这一目标,我们对Ayous锯末进行了取样和表征,然后通过有机溶剂法进行预处理。在预处理过程中,采用以温度、时间、乙醇浓度为中心的复合实验设计,研究了三个因素对戊糖、还原糖和酚类化合物提取的影响。分析表明,Ayous木屑中纤维素含量为45.33±5.5%,木质素含量为30.32±1.95%,半纤维素含量为20.03±3.5%。为了释放最多的戊糖、还原糖和最少的酚类化合物,该底物应在209.08℃、47.60 min、乙醇-水比24.02%的条件下进行有机溶剂预处理。温度是对预处理过程影响最大的因素,而乙醇浓度不是重要因素。有机溶剂预处理是去除Ayous锯末木质纤维素结构的有效方法。
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引用次数: 5
Semi-clathrate hydrate phase stability conditions for methane + TetraButylAmmonium Bromide (TBAB)/TetraButylAmmonium Acetate (TBAA) + water system: Experimental measurements and thermodynamic modeling 甲烷+四丁基溴化铵(TBAB)/四丁基乙酸铵(TBAA) +水体系的半笼合物水合物相稳定性条件:实验测量和热力学建模
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021055
Hamid Irannezhad, J. Javanmardi, Ali Rasoolzadeh, K. Mehrabi, A. Mohammadi
One of the promising applications of clathrate/gas hydrates is the transport and storage of natural gas. Semi-clathrate hydrates have received more attention due to milder pressure/temperature stability conditions compared to ordinary clathrate hydrates. The most commonly reported semi-clathrate hydrates are formed from a combination of gas + water + quaternary ammonium salts. In this work, a total of 53 equilibrium data for semi-clathrate hydrates of methane + TetraButylAmmonium Bromide (TBAB)/TetraButylAmmonium Acetate (TBAA) aqueous solutions were experimentally measured. For TBAB, three concentrations including 0.0350, 0.0490, and 0.1500 mass fractions were used. For TBAA, a solution with a 0.0990 mass fraction was used. Additionally, the modified Chen–Guo model was applied to calculate the hydrate phase equilibrium conditions of methane + TBAB/TBAA aqueous solutions. The model can accurately calculate the aforementioned semi-clathrate hydrate phase equilibrium conditions with the Average Absolute Deviations ((AAD)T and (AAD)P) of 0.1 K and 0.08 MPa, respectively. The temperature increments for 0.0350, 0.0490, and 0.1500 mass fractions of TBAB are 7.7, 9.4, and 13.5 K, respectively. This value for 0.0990 mass fraction of TBAA is 6.2 K. Therefore, it is concluded that TBAB is a stronger hydrate promoter compared to TBAA.
包合物/天然气水合物的一个很有前途的应用是天然气的运输和储存。由于与普通包合物水合物相比,半包合物水合物具有更温和的压力/温度稳定性条件,因此受到了更多的关注。最常见的半笼状水合物是由气体+水+季铵盐的组合形成的。实验测量了甲烷+四丁基溴化铵(TBAB)/乙酸四丁基铵(TBAA)水溶液半笼形水合物的53个平衡数据。TBAB采用0.0350、0.0490和0.1500质量分数三种浓度。对于TBAA,采用质量分数为0.0990的溶液。此外,应用改进的Chen-Guo模型计算了甲烷+ TBAB/TBAA水溶液的水合物相平衡条件。该模型能准确地计算出上述半包合物水合物相平衡条件,平均绝对偏差(AAD)T和(AAD)P分别为0.1 K和0.08 MPa。0.0350、0.0490和0.1500质量分数的温度增量分别为7.7、9.4和13.5 K。0.0990 TBAA质量分数的值为6.2 K。因此,与TBAA相比,TBAB是一种更强的水合物促进剂。
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引用次数: 4
Effects of hydrogen blending on hydraulic and thermal characteristics of natural gas pipeline and pipe network 掺氢对天然气管道管网水力和热力特性的影响
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021052
Heng Zhang, Jingfa Li, Yue Su, Peng Wang, Bo Yu
Blending a fraction of hydrogen into the natural gas pipeline or urban pipe network is an efficient approach for hydrogen delivery. In this paper, the mathematical model of Hydrogen-Blended Natural Gas (HBNG) transportation is established, and the influences of hydrogen blending on hydraulic and thermal characteristics of natural gas pipeline and pipe network are numerically investigated. The impact of hydrogen blending ratio on the performance of centrifugal compressor and the operating point for joint operation of pipeline and compressor is discussed. Results illustrate that compared with natural gas without hydrogen, the hydrogen blending can reduce the pipeline friction resistance and increase the volume flow rate. However, due to the lower volumetric calorific value of HBNG, the energy flow rate actually decreases under the same transportation condition. Meanwhile, the temperature drop along the pipeline slows down due to the blended hydrogen. The performance degradation of centrifugal compressor occurs with the increasing hydrogen blending ratio, and the operating point for joint operation of pipeline and centrifugal compressor moves to the direction of higher volume flow rate and lower pressure. This study is expected to shed a light on the hydrogen delivery by natural gas pipelines and pipe networks.
将一部分氢气混合到天然气管道或城市管网中是一种有效的氢气输送方法。本文建立了混氢天然气(HBNG)输气的数学模型,数值研究了混氢对天然气管道管网水力和热力特性的影响。讨论了配氢比对离心压缩机性能的影响以及管道与压缩机联合运行的工作点。结果表明,与无氢天然气相比,掺氢天然气可以降低管道摩擦阻力,提高体积流量。然而,由于HBNG的体积热值较低,在相同的运输条件下,能量流率反而降低。同时,由于氢气的混合,管道沿线的温度下降速度减慢。随着配氢比的增大,离心式压缩机性能下降,管道与离心式压缩机联合运行的工作点向高容积流量、低压力方向移动。这项研究有望揭示通过天然气管道和管网输送氢气的问题。
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引用次数: 11
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Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles
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