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Capillarity and phase-mobility of a hydrocarbon gas–liquid system 烃类气液体系的毛细性和相迁移率
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/OGST/2021025
Ying Gao, A. Georgiadis, N. Brussee, A. Coorn, H. J. van der Linde, J. Dietderich, F. Alpak, Daniel Eriksen, M. M. MOOIJER‐van den HEUVEL, M. Appel, T. Sorop, O. B. Wilson, S. Berg
When oil fields fall during their lifetime below the bubble point gas comes out of solution. The key questions are at which saturation the gas becomes mobile (“critical gas saturation”) and what the gas mobility is, because mobile gas reduces the production of oil significantly. The traditional view is that the gas phase becomes mobile once gas bubbles grow or expand to a size where they connect and form a percolating path. For typical 3D porous media the saturation corresponding to this percolation limit is on the order of 20%. However, significant literature report on gas mobility below lower limits of percolation thresholds i.e. below 0.1%. A direct experimental insight for that is lacking because laboratory measurements are notoriously difficult since the formation of gas bubbles below the bubble point includes thermodynamic and kinetic aspects, and the pressure decline rates achievable in laboratory experiments are orders of magnitude higher than the decline rates in the field. Here we study the nucleation and transport of gas coming out of solution in-situ in 3D rock using X-ray computed micro tomography which allows direct visualization of the nucleation kinetics and connectivity of gas. We use either propane or a propane–decane mixture as model system and conduct pressure depletion in absence of flow finding that – consistent with the literature – observation of the bubble point in the porous medium is decreased and becomes pressure decline rate dependent because of the bubble nucleation kinetics. That occurs in single-component systems and in hydrocarbon mixtures. Pressure depletion in absence of flow results in critical gas saturations between 20 and 30% which is consistent with typical percolation thresholds in 3D porous structures. That does not explain experimentally observed critical gas saturations significantly below 20%. Also, the respective pore level fluid occupancy where pores are filled with either gas or liquid phase but not partially with both as in normal 2-phase immiscible systems rather diminishes connectivity of gas and liquid phases. This observation indicates that likely other mechanisms play a role in establishing gas mobility at saturations significantly below 20%. Experiments under flow conditions, where gas is injected near the bubble point suggest that diffusion may significantly contribute to the transport of gas and may even be the dominant transport mechanism at field relevant flow rates. The consequence of diffusive transport are compositional gradients where locally the composition is such gas nucleation may occur. That would lead to a disconnected but mobile gas distribution ahead of the convective front. Furthermore, diffusive exchange leads to ripening and anti-ripening effects which influences the distribution for which we see evidence in pressure depletion experiments but not so much at low rate gas injection. Respective relative permeability computed from the imaged fluid distributions using a lattice
当油田在其生命周期内低于气泡点时,气体就会从溶液中出来。关键问题是,在何种饱和度下,气体才会变得可流动(“临界气饱和度”),以及气体的流动性是多少,因为可流动气体会显著降低石油产量。传统的观点认为,一旦气泡生长或膨胀到一定的大小,它们就会连接并形成一个渗透路径,气相就会变得流动。对于典型的三维多孔介质,该渗流极限对应的饱和度约为20%。然而,大量文献报道了低于渗透阈值下限(即低于0.1%)的气体迁移率。由于气泡点以下的气泡形成包括热力学和动力学方面,因此实验室测量非常困难,因此缺乏直接的实验见解,并且实验室实验中可实现的压力下降率比现场的下降率高几个数量级。在这里,我们使用x射线计算机微层析成像技术研究了三维岩石中溶液中气体的成核和输运,该技术可以直接可视化气体的成核动力学和连通性。我们使用丙烷或丙烷-癸烷混合物作为模型系统,并在没有流动的情况下进行压力耗尽,发现-与文献一致-由于气泡成核动力学,多孔介质中气泡点的观测值降低并且变得依赖于压力下降率。这发生在单组分系统和碳氢化合物混合物中。在没有流动的情况下,压力耗尽导致临界气体饱和度在20%到30%之间,这与三维多孔结构中典型的渗透阈值一致。这并不能解释实验观察到的显著低于20%的临界气体饱和度。此外,当孔隙被气相或液相填充,而不是像正常的两相不混相体系那样部分被气相或液相填充时,相应的孔隙级流体占用会降低气相和液相的连通性。这一观察结果表明,在饱和度明显低于20%的情况下,可能还有其他机制在建立气体迁移率方面发挥作用。流动条件下,在气泡点附近注入气体的实验表明,扩散可能对气体的输运有显著贡献,甚至可能是在现场相关流速下的主要输运机制。扩散输运的结果是组成梯度,其中局部组成是这样的气体成核可能发生。这将导致对流锋面前方不相连但可移动的气体分布。此外,扩散交换导致成熟和反成熟效应,影响分布,我们在压力耗尽实验中看到证据,但在低速率注气中没有那么多。利用晶格玻尔兹曼方法从成像流体分布中计算出的相对渗透率在压力耗尽和流动条件下表现出明显不同的行为。这些发现表明,气液烃混合物中的毛细作用远比两相不混相体系复杂。毛细作用与快速时间尺度上的相行为热力学和动力学以及缓慢时间尺度上的成熟和反成熟效应等扩散主导机制相耦合。虽然目前的实验和现场建模方法的结果还不完全清楚,但这表明需要更多的研究来充分理解这些影响及其含义。
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引用次数: 7
Mechanical properties and X-ray diffraction analyses of clay/sand pellets for CO2 adsorption: the effects of sand content and humidity 吸附CO2的粘土/砂粒的力学性能和x射线衍射分析:含砂量和湿度的影响
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021030
Isaac Iglesias, Mayra Jiménez, A. M. Gallardo, Edward E. Ávila, V. Morera, A. Viloria, Marvin Ricaurte, J. Tafur
In this work, we report the mechanical properties of an alternative material based on a mixture of natural clay and ferruginous sand in pellet form for CO2 capture. These raw materials were collected from Ecuador, and they contain iron and titanium oxides from volcanic origin. To evaluate the effect of the sand content on the mechanical properties of pellets, the samples were manually prepared with 0 (control sample), 15, and 25 wt.% sand contents and analyzed using free-fall drop impact and uniaxial compression tests. The uniaxial compression test was carried out under three conditions: using sieved sand, using sand without sieving, and under wet conditions. The sand contents caused the drop number to decrease in the free-fall drop impact test. From the uniaxial compression test, the compressive strength, elastic modulus, and toughness were calculated. The elastic modulus showed a better performance for samples with lower porosity. The compressive strength demonstrated higher values for samples with 15 wt.% sand contents than for samples with the other sand contents. The toughness values did not significantly change. It was evidenced that the porosity, mineral composition, and humidity exerted an influence during the mechanical tests. The mineral phases were analyzed by X-ray diffraction, and quantitative analysis based on whole-powder-pattern fitting revealed that the iron and titanium oxide contents increased as the concentration of sand in the pellets increased.
在这项工作中,我们报告了一种基于天然粘土和含铁砂的颗粒状混合物的替代材料的机械性能,用于二氧化碳捕获。这些原料是从厄瓜多尔收集的,它们含有来自火山的铁和钛氧化物。为了评估含砂量对颗粒力学性能的影响,将含砂量分别为0(对照样品)、15和25 wt.%的样品手工制备,并通过自由落体冲击和单轴压缩试验进行分析。单轴压缩试验分别在筛砂、不筛砂和潮湿条件下进行。在自由落体冲击试验中,含砂量的增加导致了落体数量的减少。通过单轴压缩试验,计算了材料的抗压强度、弹性模量和韧性。孔隙率越低,材料的弹性模量越好。含砂量为15wt .%的样品的抗压强度高于其他含砂量的样品。韧性值没有明显变化。在力学试验中,孔隙度、矿物成分和湿度对其产生了影响。通过x射线衍射对矿相进行了分析,基于全粉模式拟合的定量分析表明,随着颗粒中砂浓度的增加,铁和氧化钛的含量也随之增加。
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引用次数: 2
Evaluation of 3D printed microfluidic networks to study fluid flow in rocks 研究岩石流体流动的3D打印微流体网络的评价
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021029
S. M. Mousavi, S. Sadeghnejad, M. Ostadhassan
Visualizing fluid flow in porous media can provide a better understanding of transport phenomena at the pore scale. In this regard, transparent micromodels are suitable tools to investigate fluid flow in porous media. However, using glass as the primary material makes them inappropriate for predicting the natural behavior of rocks. Moreover, constructing these micromodels is time-consuming via conventional methods. Thus, an alternative approach can be to employ 3D printing technology to fabricate representative porous media. This study investigates fluid flow processes through a transparent microfluidic device based on a complex porous geometry (natural rock) using digital-light processing printing technology. Unlike previous studies, this one has focused on manufacturing repeatability. This micromodel, like a custom-built transparent cell, is capable of modeling single and multiphase transport phenomena. First, the tomographic data of a carbonate rock sample is segmented and 3D printed by a digital-light processing printer. Two miscible and immiscible tracer injection experiments are performed on the printed microfluidic media, while the experiments are verified with the same boundary conditions using a CFD simulator. The comparison of the results is based on Structural Similarity Index Measure (SSIM), where in both miscible and immiscible experiments, more than 80% SSIM is achieved. This confirms the reliability of printing methodology for manufacturing reusable microfluidic models as a promising and reliable tool for visual investigation of fluid flow in porous media. Ultimately, this study presents a novel comprehensive framework for manufacturing 2.5D realistic microfluidic devices (micromodels) from pore-scale rock images that are validated through CFD simulations.
可视化流体在多孔介质中的流动可以更好地理解孔隙尺度上的输运现象。在这方面,透明微模型是研究多孔介质中流体流动的合适工具。然而,使用玻璃作为主要材料使得它们不适合预测岩石的自然行为。此外,通过传统方法构建这些微观模型非常耗时。因此,一种替代方法可以是采用3D打印技术来制造具有代表性的多孔介质。本研究利用数字光处理印刷技术研究了流体在基于复杂多孔几何结构(天然岩石)的透明微流体装置中的流动过程。与之前的研究不同,这次的研究重点是制造的可重复性。这种微模型就像一个定制的透明细胞,能够模拟单相和多相传输现象。首先,用数字光处理打印机对碳酸盐岩样品的层析数据进行分割和3D打印。在打印微流控介质上进行了混相和非混相示踪剂注射实验,并在相同的边界条件下利用CFD模拟器对实验进行了验证。结果的比较基于结构相似指数测量(SSIM),在混相和不混相实验中,SSIM达到80%以上。这证实了制造可重复使用的微流体模型的打印方法的可靠性,作为一种有前途和可靠的工具,用于可视化研究多孔介质中的流体流动。最后,本研究提出了一个全新的综合框架,用于从孔隙尺度岩石图像中制造2.5D逼真的微流体装置(微模型),并通过CFD模拟验证。
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引用次数: 4
Hierarchical simultaneous upscaling of porosity and permeability features using the bandwidth of kernel function and wavelet transformation in two dimensions: Application to the SPE-10 model 基于核函数带宽和小波变换的二维孔隙度和渗透率特征的分层同步上尺度化:在SPE-10模型中的应用
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/OGST/2021006
M. Azad, A. Kamkar-Rouhani, B. Tokhmechi, M. Arashi
In this paper, two methods of kernel bandwidth and wavelet transform are used for simultaneous upscaling of two features of hydrocarbon reservoir. In the bandwidth method, the criterion for upscaling is the cell variability, and by calculating the optimal bandwidth and determining the distance matrix, the upscaling process is performed in a completely non-uniform and unregularly manner. In areas with extreme variability, the bandwidth is considered small enough to maintain the fine scale characteristics of model. Conversely in homogenous areas, with the choice of large bandwidth, the maximum rate of upscaling will occur. The bandwidth upscaling algorithm is an iterative and hierarchical algorithm. The bandwidth method, unlike conventional scale-up methods, focuses on how to upgrid cells and, by determining the optimal averaging window, we will have the least loss information for the fine scale model. Upscaling is a pre-processing to building a simulator model with lower cell number, and thus, reducing volume and computational cost, while maintaining and retaining the basic information of the fine model. Due to the various variability of the reservoir features, the attribute upscaling pattern differs, and in order to show the variability of two features in the upscaling model simultaneously, it is suggested in this paper to upscale two features simultaneously. For simultaneous upscaling, we applied two different approaches; minimum and maximum bandwidth. Moreover, wavelet transformation is applied to upscaling the model. Then, as a result, the variance of the scale-up models based on wavelet is about one-third of the variance of the bandwidth method. Simulation results show that the bandwidth method is a good approach for upscaling the heterogeneous reservoirs.
本文采用核带宽和小波变换两种方法,对油气储层的两种特征进行同步上尺度变换。在带宽法中,升级的判据是单元的可变性,通过计算最优带宽和确定距离矩阵,使升级过程完全不均匀和不规则地进行。在极端变异性区域,认为带宽足够小以保持模型的精细尺度特征。相反,在均匀区域,随着带宽的选择,将出现最大的升级率。带宽升级算法是一种迭代的分层算法。与传统的按比例放大方法不同,带宽方法侧重于如何使网格单元升级,并通过确定最佳平均窗口,我们将获得最小的细比例模型损失信息。升级是在保持和保留精细模型基本信息的前提下,为构建具有较少单元数的仿真模型而进行的预处理,从而减少体积和计算成本。由于储层特征的变异性不同,属性上标模式也不同,为了在上标模型中同时显示两个特征的变异性,本文建议对两个特征同时进行上标。为了同时升级,我们采用了两种不同的方法;最小和最大带宽。在此基础上,利用小波变换对模型进行上尺度变换。结果表明,基于小波变换的放大模型的方差约为带宽放大模型方差的三分之一。仿真结果表明,带宽法是一种很好的非均质储层放大方法。
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引用次数: 2
Experimental and modeling studies of density and viscosity behavior of a live fluid due to CO2 injection at reservoir condition 油藏条件下注入CO2后活性流体密度和粘度变化的实验和模型研究
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021026
David C. Santos, Marina N. Lamim, D. S. Costa, A. Mehl, P. Couto, M. Paredes
In this study, highly accurate measurements of density and dynamic viscosities of a recombined live oil and its mixture with additional CO2 were performed. The experiments were carried out under pressure and temperature gradients found in Brazilian Pre-salt reservoirs, that is, in the pressure range from (27.6 to 68.9) MPa and at (333.15 and 353.15) K. The assumption of volume change on mixing is evaluated from the experimental results, and the influence of pressure and temperature on the volume change upon mixing is assessed. The densities of mixtures are calculated considering (i) the excess volume approach, and (ii) no volume change. The densities are better correlated using the excess volume approach with Average Absolute Deviations (AAD) of 0.03%. Thirteen mixing rules of viscosity are examined by comparing the predicted values with the experimental viscosity of the recombined live oil + CO2 mixture. The performance of some rules using compositional fractions (molar, volume and weight) is also evaluated. Thus, a total of 28 different ways to calculate the mixture viscosities were tested in this study. The worst result was obtained with Bingham’s method, leading to 148.6% AAD. The best result was obtained from Lederer’s method with 2% AAD and a maximum deviation of 5.8% using volume fractions and the fitting parameter α. In addition, deviations presented by the predictive methods of Chevron, Double log, and Kendall did not exceed 9% AAD, using weight fractions (Chevron and Double log) and molar fractions (Kendall and Monroe).
在这项研究中,对重新组合的活油及其与额外二氧化碳的混合物进行了高度精确的密度和动态粘度测量。实验是在巴西盐下储层的压力和温度梯度下进行的,即压力范围为(27.6 ~ 68.9)MPa,压力范围为(333.15 ~ 353.15)k。根据实验结果,评价了混合过程中体积变化的假设,并评价了压力和温度对混合过程中体积变化的影响。混合物密度的计算考虑了(i)过量体积法和(ii)无体积变化。过量体积法对密度的相关性较好,平均绝对偏差(AAD)为0.03%。通过将预测值与实验值进行对比,考察了13种粘度混合规律。使用组分分数(摩尔、体积和重量)的一些规则的性能也进行了评估。因此,本研究共测试了28种不同的混合粘度计算方法。Bingham法的结果最差,AAD为148.6%。采用体积分数和拟合参数α的Lederer法,在AAD为2%、最大偏差为5.8%的条件下得到最佳结果。此外,使用权重分数(Chevron和Double log)和摩尔分数(Kendall和Monroe)的Chevron、Double log和Kendall预测方法所呈现的偏差不超过9% AAD。
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引用次数: 6
Model-based production optimization under geological and economic uncertainties using multi-objective particle swarm method 地质经济不确定条件下基于模型的多目标粒子群方法生产优化
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021039
Mohammad Mahdi Moshir Farahi, Mohammad Ahmadi, B. Dabir
Optimization of the water-flooding process in the oilfields is inherently subject to several uncertainties arising from the imperfect reservoir subsurface model and inadequate data. On the other hand, the uncertainty of economic conditions due to oil price fluctuations puts the decision-making process at risk. It is essential to handle optimization problems under both geological and economic uncertainties. In this study, a Pareto-based Multi-Objective Particle Swarm Optimization (MOPSO) method has been utilized to maximize the short-term and long-term production goals, robust to uncertainties. Some modifications, including applying a variable in the procedure of leader determination, namely crowding distance, a corrected archive controller, and a changing boundary exploration, are performed on the MOPSO algorithm. These corrections led to a complete Pareto front with enough diversity on the investigated model, covering the entire solution space. Net Present Value (NPV) is considered the first goal that represents the long-term gains, while a highly discounted NPV (with a discount rate of 25%) has been considered short-term gains since economic uncertainty risk grows with time. The proposed optimization method has been used to optimize water flooding on the Egg benchmark model. Geological uncertainty is represented with ensembles, including 100 model realizations. The k-means clustering method is utilized to reduce the realizations to 10 to reduce the computing cost. The Pareto front is obtained from Robust Optimization (RO) by maximizing average NPV over the ensembles, as the conservative production plan. Results show that optimization over the ensemble of a reduced number of realizations by the k-means technique is consistent with all realizations’ ensembles results, comparing their cumulative density functions. Furthermore, 10 oil price functions have been considered to form the economic uncertainty space. When SNPV and LNPV are optimized, considering uncertainty in oil price scenarios, the Pareto front’s production scenarios are robust to oil price fluctuations. Using the robust Pareto front of LNPV versus SNPV in both cases, one can optimize production strategy conservatively and update it according to the current reservoir and economic conditions. This approach can help a decision-maker to handle unexpected situations in reservoir management.
由于油藏地下模型的不完善和数据的不充分,油田注水过程的优化本身就存在一些不确定性。另一方面,油价波动带来的经济状况的不确定性使决策过程面临风险。处理地质和经济不确定性条件下的优化问题是十分必要的。在本研究中,利用基于pareto的多目标粒子群优化(MOPSO)方法来最大化短期和长期生产目标,对不确定性具有鲁棒性。对MOPSO算法进行了一些改进,包括在leader确定过程中加入一个变量,即拥挤距离,修正归档控制器,以及改变边界探索。这些修正导致了一个完整的Pareto前沿,在被调查的模型上具有足够的多样性,覆盖了整个解决方案空间。净现值(NPV)被认为是代表长期收益的第一个目标,而高度贴现的NPV(贴现率为25%)被认为是短期收益,因为经济不确定性风险随着时间的推移而增加。本文提出的优化方法已用于Egg基准模型上的水驱优化。地质不确定性用集合表示,包括100个模型实现。采用k-means聚类方法将实现减少到10个,以降低计算成本。帕累托锋面作为保守生产计划,通过鲁棒优化(RO)方法,通过最大化组合上的平均NPV得到。结果表明,通过比较它们的累积密度函数,k-means技术在减少的实现数量的集合上的优化与所有实现的集合结果一致。此外,考虑了10个石油价格函数来形成经济不确定性空间。当SNPV和LNPV优化时,考虑到油价情景的不确定性,Pareto前沿的生产情景对油价波动具有鲁棒性。在这两种情况下,利用LNPV和SNPV的强大Pareto前沿,可以保守地优化生产策略,并根据当前的油藏和经济条件进行更新。这种方法可以帮助决策者处理油藏管理中的意外情况。
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引用次数: 2
A new model for predicting fluid loss in fracture-porosity reservoir 裂缝-孔隙型储层失液预测新模型
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/OGST/2021012
Liu Jinjiang, Fuxin Zhang, Peng Qian, Wenlin Wu
Drilling fluid loss always occurs in fracture-porosity reservoirs and it causes severe problems. To reduce and prevent lost circulation, it is important to get to know the cause and the characteristic of drilling fluid loss. According to the approach in the reservoir simulation and well test analysis, a new model for drilling fluid loss in fracture-porosity reservoir is presented. Multi fractures in the formation and drilling fluid seepage between fracture and rock matrix have been considered in the model. The governing equations are derived based on the principle of conservation of mass. The model is solved numerically using Newton-Raphson iterative method. The obtained results indicate that drilling fluid leak-off has great influence on the total leakage volume. It is necessary to consider the impact of the drilling fluid leak-off. In addition, influence of formation properties, such as fracture stiffness, rock matrix porosity, rock matrix permeability, and operation factors, such as pressure difference between wellbore and formation, are also analysed in detail in the paper which could help better understand the factors that influence the drilling fluid loss during drilling operation.
裂缝-孔隙型储层经常发生钻井液漏失,造成了严重的问题。为了减少和防止漏失,了解钻井液漏失的原因和特点是非常重要的。根据储层模拟和试井分析的方法,提出了一种新的裂缝-孔隙型储层钻井液漏失模型。该模型考虑了地层中的多道裂缝以及裂缝与岩石基质之间的钻井液渗流。控制方程是根据质量守恒原理导出的。采用牛顿-拉夫森迭代法对模型进行了数值求解。结果表明,钻井液漏出量对总泄漏量的影响较大。有必要考虑钻井液泄漏的影响。此外,本文还详细分析了裂缝刚度、岩石基质孔隙度、岩石基质渗透率等地层性质以及井筒与地层压差等作业因素的影响,有助于更好地了解钻井作业中影响钻井液漏失的因素。
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引用次数: 0
Editorial: Advanced modeling and simulation of flow in subsurface reservoirs with fractures and wells for a sustainable industry 社论:为了可持续发展的工业,先进的裂缝和井地下油藏流动建模和模拟
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/OGST/2021008
Shuyu Sun, M. Edwards, F. Frank, Jingfa Li, A. Salama, Bo Yu
Division of Physical Science and Engineering, King Abdullah University of Science and Technology, Mail box # 2077, Thuwal 23955-6900, Saudi Arabia Chair in Engineering, Swansea University, Singleton Park, Swansea, Wales SA2 8PP, UK Applied Mathematics (Modeling and Numerics), Friedrich-Alexander-University of Erlangen-Nürnberg, Cauerstraße 11, 91058 Erlangen, Germany 4 School of Mechanical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China 5 Faculty of Engineering, University of Regina, Regina, Saskatchewan, S4S 0A2, Canada 6 School of Mechanical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
阿卜杜拉国王科技大学物理科学与工程系,Thuwal 23955-6900邮箱2077号,沙特阿拉伯斯旺西大学工程教授,斯旺西Singleton Park,威尔士斯旺西SA2 8PP,英国应用数学(建模与数值),埃尔朗根- n伦贝格大学,德国埃尔朗根91058,德国cauerstrae 11;5里贾纳大学工程学院,萨斯喀彻温省里贾纳,S4S 0A2; 6北京石油化工学院机械工程学院,北京102617
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引用次数: 0
3D pore microstructures and computer simulation: Effective permeabilities and capillary pressure during drainage in Opalinus Clay 三维孔隙微观结构与计算机模拟:蛋白石粘土排水过程中的有效渗透率和毛细压力
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021027
L. Keller
The 3D reconstruction of the pore space in Opalinus Clay is faced with the difficulty that high-resolution imaging methods reach their limits at the nanometer-sized pores in this material. Until now it has not been possible to image the whole pore space with pore sizes that span two orders of magnitude. Therefore, it has not been possible to predict the transport properties of this material with the help computer simulations that require 3D pore structures as input. Following the concept of self-similarity, a digital pore microstructure was constructed from a real but incomplete pore microstructure. The constructed pore structure has the same pore size spectrum as measured in the laboratory. Computer simulations were used to predict capillary pressure curves during drainage, which also agree with laboratory data. It is predicted, that two-phase transport properties such as the evolution of effective permeability as well as capillary pressures during drainage depend both on transport directions, which should be considered for Opalinus Clay when assessing its suitability as host rock for nuclear waste. This directional dependence is controlled on the pore scale by a geometric anisotropy in the pore space.
蛋白石粘土孔隙空间的三维重建面临着高分辨率成像方法在纳米级孔隙中达到极限的难题。到目前为止,还不可能对孔隙大小跨越两个数量级的整个孔隙空间进行成像。因此,借助需要三维孔隙结构作为输入的计算机模拟来预测这种材料的输运性质是不可能的。根据自相似的概念,将真实但不完整的孔隙微观结构构建为数字孔隙微观结构。所构建的孔隙结构具有与实验室测得的相同的孔径谱。用计算机模拟方法预测了排水过程中的毛细管压力曲线,结果与实验数据吻合较好。预测两相输运特性,如有效渗透率的演化和排水过程中的毛管压力,都取决于输运方向,在评价蛋白石粘土作为核废料寄存岩的适宜性时,应考虑输运方向。这种方向依赖性在孔隙尺度上由孔隙空间的几何各向异性控制。
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引用次数: 1
Simulation and parametric analysis of natural gas sweetening process: a case study of Missan Oil Field in Iraq 天然气脱硫过程模拟与参数分析——以伊拉克米桑油田为例
IF 1.5 4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-01-01 DOI: 10.2516/ogst/2021033
Jassim Mohammed Khanjar, E. Amiri
Gas sweetening is one of the important purification processes which is employed to remove acidic contaminants from natural gases prior to meet transport requirements and sale gas specifications. In this work, simulation and parametric studies of the natural gas processing plant of Missan Oil Company/Buzurgan Oil Field of Natural Gas Processing Plant (in Iraq) were considered. After simulation and validation of this plant, the effect of feed temperature and flow rate and solvent concentration were considered. Results show with increasing the feed temperature and flow rate, the amount of H2S and CO2 in the sweet gas stream increases. Then, in the next step, the effect of mixture solvents was studied. Sulfolane–MDEA and MDEA–MEA were selected as a physical–chemical mixture solvent and chemical mixture solvent, respectively. The simulation results show that the solvent price and reboiler duty and cooling duty can be reduced by using a mixture solvent. However, the amount of H2S and CO2 in the sweet gas can be affected by these solvents. The system by a chemical mixture solvent can better performance than other solvents.
气体脱硫是一种重要的净化工艺,用于去除天然气中的酸性污染物,以满足运输要求和销售气体的规格。本文考虑了Missan石油公司天然气加工厂/Buzurgan油田天然气加工厂(伊拉克)的模拟和参数研究。通过对该装置的模拟和验证,考虑了进料温度、流速和溶剂浓度的影响。结果表明:随着进料温度的升高和进料流量的增大,含硫气流中H2S和CO2的含量增大;然后,在下一步,研究了混合溶剂的影响。选择亚砜- mdea和MDEA-MEA分别作为物理-化学混合溶剂和化学混合溶剂。模拟结果表明,使用混合溶剂可以降低溶剂价格、再沸器负荷和冷却负荷。然而,含硫气体中H2S和CO2的含量会受到溶剂的影响。该体系由化学溶剂混合而成,能比其他溶剂有更好的性能。
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引用次数: 6
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Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles
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