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Chemical characterization of PM10 in two small towns located in South Poland 波兰南部两个小镇PM10的化学特征
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2021-03-01 DOI: 10.2478/nuka-2021-0004
Anna Turek-Fijak, Joanna Brania, K. Styszko, D. Zięba, Z. Stęgowski, L. Samek
Abstract The purpose of this study is to analyse the elements and PM10 concentrations in air samples gathered in the winter of 2017/2018 in two small towns, namely Skala and Wadowice. The chemical elements were identified for each sample using the energy dispersive X-ray method. The spectrometer was equipped, among others, with an Mo-X-ray tube which was the source of the photons and the Si(Li) detector. The following chemical elements: Cl, K, Fe, Ca, Zn, Pb, Br, Ti, Cu, Mn, V, Co, Rb, Ni, Sr, and Cr were identified in the samples. In addition, As and Se were identified in Wadowice. First, the results were compared with each other and then with the results for the nearest city. It was observed that the PM10 concentrations were significantly higher than the UE limit value for PM10, which equals 50 μg·m−3 per 24 h. Moreover, the high concentrations of, among others, K, Pb, Cl or Zn, are likely to be linked with fossil fuels combustion and biomass burning. The levels of element concentrations in Wadowice and Skala resemble the levels observed several years earlier in Krakow.
摘要:本研究的目的是分析2017/2018年冬季在两个小镇Skala和Wadowice采集的空气样本中的元素和PM10浓度。利用能量色散x射线法对每个样品的化学元素进行了鉴定。光谱仪配备了mo - x射线管,这是光子的来源,还有Si(Li)探测器。在样品中鉴定出以下化学元素:Cl、K、Fe、Ca、Zn、Pb、Br、Ti、Cu、Mn、V、Co、Rb、Ni、Sr和Cr。此外,在Wadowice中还鉴定出As和Se。首先,将结果相互比较,然后与最近城市的结果进行比较。PM10浓度显著高于UE限定值(50 μg·m−3 / 24 h),且高浓度的K、Pb、Cl、Zn等可能与化石燃料燃烧和生物质燃烧有关。瓦多维采和斯卡拉的元素浓度水平与几年前在克拉科夫观察到的水平相似。
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引用次数: 2
Natural zeolite as a replacement for resin in the cation exchange process of cesium on post-irradiated nuclear fuel 天然沸石在辐照后核燃料铯阳离子交换过程中替代树脂的研究
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2021-03-01 DOI: 10.2478/nuka-2021-0002
Aslina Br. Ginting, A. Siti, Noviarty, Yanlinastuti, A. Nugroho, Boybul
Abstract Characterization of natural salts from Bayah, Lampung, and Tasikmalaya, Indonesia has been carried out as a substitute for synthetic resins. The characteristics include zeolite activation with NH4Cl, and heated at 200°C, the bond stability test of 137Cs-zeolite, chemical composition analysis, surface area, pore size, analysis of Cs cation exchange capacity (CEC), diffusion coefficient (Di), activation energy (Ea), and absorption of three zeolites. To do this, pipette 50 μl of a standard solution of 137Cs from the National Institute of Standards and Technology (NIST), put in, 2 ml of 0.1 N HCl, and then add 1 g of zeolite and stir each for 1, 2, 3, 4, 5, and 24 h. Based on this stirring time, the 137C isotope will exchange ions with NH4-zeolite to 137Cs-zeolite in the solid phase. The content of 137Cs in 137Cs-zeolites (solid phase) was analysed using a gamma spectrometer. The results of the chemical composition analysis showed that the character of zeolite from Lampung has a Si/Al ratio, with a CEC value of 1.448 mEq/g which is greater than Bayah and Tasikmalaya, while the Di and Ea values for the three select types were obtained almost the same. Moreover, the stability test of the Cs ion bond with zeolite showed no significant release of Cs ions from the zeolite structure. It can be concluded that the three soloists tested that the zeolite from Lampung has better characters. The results of 137Cs isotope separation in 150 μl of U3Si2/Al fuel solution post-irradiation using zeolite from Lampung and Dowex resins obtained almost the same recovery around 98–99%, so it can be concluded that zeolite from Lampung can be used as a substitute for synthetic resin in the cation exchange process for the 137Cs isotope in nuclear fuel post-irradiated.
摘要:表征天然盐从巴耶,楠榜,和Tasikmalaya,印度尼西亚已经进行了合成树脂的替代品。实验包括沸石与NH4Cl的活化,在200℃下加热,137cs -沸石的键稳定性测试,化学成分分析,表面积,孔径,Cs阳离子交换容量(CEC)分析,扩散系数(Di),活化能(Ea)分析,以及三种沸石的吸收率。取美国国家标准技术研究院(NIST) 137Cs标准溶液50 μl,加入2ml 0.1 HCl,再加入1g沸石,分别搅拌1、2、3、4、5、24 h。根据搅拌时间,137C同位素与nh4 -沸石在固相中交换离子至137Cs-沸石。用伽马能谱仪分析了137Cs-沸石(固相)中137Cs的含量。化学成分分析结果表明,楠榜沸石具有Si/Al比的特征,CEC值为1.448 mEq/g,高于巴雅沸石和塔西马拉沸石,而三种选择类型的Di和Ea值基本相同。此外,Cs离子键与沸石的稳定性测试表明,Cs离子没有从沸石结构中明显释放出来。通过对三种分子筛的测试,得出了楠榜沸石具有较好性能的结论。在辐照后的150 μl U3Si2/Al燃料溶液中,使用楠榜沸石和Dowex树脂分离137Cs同位素的结果几乎相同,回收率在98 ~ 99%之间,因此楠榜沸石可以作为合成树脂在辐照后核燃料中137Cs同位素的阳离子交换过程中的替代品。
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引用次数: 1
Comparison of dose distributions in target areas and organs at risk in conformal and VMAT techniques and dose verifications with the use of thermoluminescence dosimetry 适形和VMAT技术中靶区和危险器官的剂量分布比较以及使用热释光剂量测定法进行剂量验证
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2020-10-23 DOI: 10.2478/nuka-2020-0033
M. Paluch-Ferszt, B. Kozłowska, M. Dybek
Abstract The aim of the present study is to compare dose distributions and their verification in target areas and organs at risk (OAR) in conformal and volumetric modulated arc therapy (VMAT) techniques. Proper verification procedures allow the removal of the major sources of errors, such as incorrect application of a planning system, its insufficient or cursory commissioning, as well as an erroneous interpretation of the obtained results. Three target areas (head and neck, chest, and pelvic) were selected and the treatment was delivered based on plans made using collapsed cone convolution and Monte Carlo algorithms with 6-MV photon beams, adopting conformal and VMAT techniques, respectively. All the plans were prepared for the anthropomorphic phantom. Dose measurements were performed with TL detectors made of LiF phosphor doped with magnesium and titanium (LiF:Mg,Ti). This paper presents the results of TL measurements and calculated doses, as well as their deviations from the treatment planning system (TPS) in the three planned target areas. It was established that the algorithms subject to analysis differ, particularly in dose calculations for highly inhomogeneous regions (OAR). Aside from the need to achieve the dose intended for the tumour, the choice of irradiation technique in teleradiotherapy should be dictated by the degree of exposure to individual critical organs during irradiation. While nothing deviated beyond the bounds of what is acceptable by international regulatory bodies in plans from TPS, clinically one must be more cautious with the OAR areas.
摘要本研究的目的是比较适形和体积调制电弧治疗(VMAT)技术中靶区和危险器官(OAR)的剂量分布及其验证。适当的验证程序可以消除主要的错误来源,例如规划系统的应用不正确、调试不充分或草率,以及对所获得结果的错误解释。选择了三个目标区域(头颈部、胸部和骨盆),并根据分别采用保形和VMAT技术的塌陷锥卷积和6-MV光子束蒙特卡罗算法制定的计划进行治疗。所有的计划都是为拟人化的幻影准备的。使用由掺杂有镁和钛的LiF磷光体(LiF:Mg,Ti)制成的TL探测器进行剂量测量。本文介绍了TL测量和计算剂量的结果,以及它们与三个计划目标区域的治疗计划系统(TPS)的偏差。已经确定,进行分析的算法不同,特别是在高度不均匀区域(OAR)的剂量计算方面。除了需要达到肿瘤的预期剂量外,远程放射治疗中照射技术的选择还应取决于照射过程中暴露于单个关键器官的程度。虽然没有任何偏离国际监管机构在TPS计划中可接受的范围,但临床上必须对OAR领域更加谨慎。
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引用次数: 0
Efficient reading of thermoluminescent dosimeter signals using semiconductor detectors 利用半导体探测器有效读取热释光剂量计信号
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2020-10-23 DOI: 10.2478/nuka-2020-0034
P. Sobotka, Bartlomiej Klis, Z. Baranowska, K. Wołoszczuk, K. Rutkowska, T. Wolinski
Abstract The aim of this experimental work was to examine whether semiconductor photodetectors may be applied for the efficient reading of thermoluminescent dosimeter (TLD) signals. For this purpose, a series of experiments have been performed at the Department of Physics, Warsaw University of Technology, in cooperation with the Central Laboratory for Radiological Protection (CLOR). Specifically, the measurement system proposed here has been designed to detect a signal from TLDs that use a semiconductor detector operating in conditions analogous to those met when using commercial devices equipped with a classic photomultiplier. For the experimental tests, the TLDs were irradiated with a beam of 137Cs radiation in the accredited Laboratory for Calibration of Dosimetric and Radon Instruments. Eventually, a comparison of the results obtained with a semiconductor detector (ID120) and a commercial TLD reader with a photomultiplier tube (RADOS) were made.
摘要本实验的目的是研究半导体光电探测器是否可以应用于热释光剂量计(TLD)信号的有效读取。为此目的,在辐射防护中央实验室的合作下,在华沙理工大学物理系进行了一系列实验。具体来说,这里提出的测量系统被设计用于检测来自tld的信号,该信号使用半导体探测器在类似于使用配备经典光电倍增管的商用设备时遇到的条件下工作。在进行实验测试时,在认可的剂量学及氡仪器校正实验所,用一束137Cs辐射照射这些顶级区域。最后,比较了半导体探测器(ID120)和带有光电倍增管(RADOS)的商用TLD读取器的结果。
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引用次数: 0
Variation in rms charge radii of deuteron and helium nuclei with s sqrt s 氘核和氦核均方根电荷半径随s sqrt s的变化
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2020-10-23 DOI: 10.2478/nuka-2020-0032
S. Zahra, B. Shafaq, B. Kanwal, Nosheen Akbar
Abstract By considering energy-dependent form factors extracted from generalized Chou–Yang model, root mean square (rms) charge radii of deuteron and helium nuclei (alpha) are predicted at different values of center of mass energy which are in good agreement with theoretical predictions and experimental results. The rms radius is inversely proportional to mass of nuclei. Besides, the relationship between radii and energy are also derived.
摘要利用广义Chou-Yang模型中提取的能量相关形状因子,对氘核和氦核在不同质心能量值下的电荷半径进行了均方根预测,与理论预测和实验结果吻合较好。均方根半径与原子核质量成反比。此外,还推导了半径与能量的关系。
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引用次数: 0
Ablation of single-crystalline cesium iodide by extreme ultraviolet capillary-discharge laser 极紫外毛细管放电激光烧蚀单晶碘化铯
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2020-10-23 DOI: 10.2478/nuka-2020-0031
J. Wild, P. Pira, T. Burian, L. Vyšín, L. Juha, Z. Zelinger, S. Danis, V. Nehasil, Zdeněk Rafaj, V. Nevrlý, M. Dostal, P. Bitala, P. Kudrna, M. Tichý, J. Rocca
Abstract Extreme ultraviolet (XUV) capillary-discharge lasers (CDLs) are a suitable source for the efficient, clean ablation of ionic crystals, which are obviously difficult to ablate with conventional, long-wavelength lasers. In the present study, a single crystal of cesium iodide (CsI) was irradiated by multiple, focused 1.5-ns pulses of 46.9-nm radiation delivered from a compact XUV-CDL device operated at either 2-Hz or 3-Hz repetition rates. The ablation rates were determined from the depth of the craters produced by the accumulation of laser pulses. Langmuir probes were used to diagnose the plasma plume produced by the focused XUV-CDL beam. Both the electron density and electron temperature were sufficiently high to confirm that ablation was the key process in the observed CsI removal. Moreover, a CsI thin film on MgO substrate was prepared by XUV pulsed laser deposition; a fraction of the film was detected by X-ray photoelectron spectroscopy.
摘要极紫外(XUV)毛细管放电激光器(CDL)是一种有效、清洁烧蚀离子晶体的合适光源,而传统的长波长激光器显然难以烧蚀离子晶体。在本研究中,碘化铯(CsI)单晶受到以2Hz或3Hz重复频率运行的紧凑型XUV-CDL装置发出的46.9nm辐射的多个聚焦1.5-ns脉冲的照射。烧蚀速率由激光脉冲积累产生的凹坑深度确定。用Langmuir探针对聚焦XUV-CDL束产生的等离子体羽流进行了诊断。电子密度和电子温度都足够高,以证实烧蚀是观察到的CsI去除的关键过程。此外,采用XUV脉冲激光沉积方法在MgO衬底上制备了CsI薄膜;通过X射线光电子能谱检测膜的一部分。
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引用次数: 0
Development of X-ray scanning system Sowa Sowa X射线扫描系统的研制
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2020-10-23 DOI: 10.2478/nuka-2020-0035
Józef Bogowicz, M. Chabera, Wojciech Dziewiecki, Kacper Kaźmierczak, J. Klimaszewski, T. Kosiński, Andrzej Łubian, M. Matusiak, A. Wasilewski, M. Wojciechowski, S. Wronka, Tomasz Zakrzewski
Abstract The new vehicle scanning system Sowa has been developed in the National Centre for Nuclear Research. This innovative device is equipped with a 300 kV X-ray tube, U-shape imaging detector line, transport system, and fully shielded container. Sowa allows for a detailed inspection of the car and the detection of illegal transported items. This article presents the design, applied solutions, and achieved results of Sowa scanning system.
国家核研究中心研制了新型车辆扫描系统Sowa。这一创新设备配备了300千伏x射线管、u形成像探测器线路、传输系统和全屏蔽容器。Sowa允许对汽车进行详细检查,并发现非法运输的物品。本文介绍了索华扫描系统的设计、应用方案和取得的成果。
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引用次数: 0
Effect of electron beam irradiation on filtering facepiece respirators integrity and filtering efficiency 电子束辐照对过滤口罩完整性及过滤效率的影响
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2020-07-25 DOI: 10.22541/au.159569105.56056755
D. Chmielewska, Łukasz Werner, U. Gryczka, W. Migdał
Abstract The outbreak of the COVID-19 pandemic has shown that the demand for medical masks and respirators exceeds the current global stockpile of these items, and there is a dire need to increase the production capacity. Considering that ionizing radiation has been used for sterilization of medical products for many years and electron beam (EB) irradiation enables the treatment of huge quantities of disposable medical products in a short time this method should be tested for the mask’s decontamination. In this work, three different filtering facepiece respirators (FFRs) were irradiated with electron beams of 12 kGy and 25 kGy. The results confirmed that the decrease in filtration efficiency after irradiation of all respirators results from the elimination of the electric charge from the polypropylene (PP) fibers in the irradiation process. Moreover, the applied doses may affect the thermal stability of PP fabrics, while filtering materials structure and integrity have not changed after irradiation.
摘要新冠肺炎疫情的爆发表明,对医用口罩和呼吸器的需求超过了目前全球这些物品的库存,迫切需要提高生产能力。考虑到电离辐射已用于医疗产品的灭菌多年,而电子束(EB)辐射能够在短时间内处理大量一次性医疗产品,因此应测试这种方法对口罩的去污作用。在这项工作中,用12kGy和25kGy的电子束照射三种不同的过滤面罩呼吸器(FFR)。结果证实,所有呼吸器辐照后过滤效率的降低是由于在辐照过程中聚丙烯(PP)纤维的电荷被消除所致。此外,所施加的剂量可能会影响PP织物的热稳定性,而过滤材料的结构和完整性在辐照后没有改变。
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引用次数: 3
Long-term investigation of 137Cs and 134Cs in drinking water in the city of Zagreb, Croatia 克罗地亚萨格勒布市饮用水中137Cs和134Cs的长期调查
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2020-07-06 DOI: 10.2478/nuka-2020-0030
Z. Franić, Gina Branica, B. Petrinec, G. Marović
Abstract This paper presents the results of long-term investigations of 137Cs and 134Cs activity concentrations in drinking water in the city of Zagreb for the period 1987–2018. The highest activity concentrations of both radio-nuclides were measured in 1987, decreasing exponentially ever since, while 134Cs in several subsequent years fell under the detection limit. After the Fukushima Daiichi accident in 2011, the presence of 134Cs in drinking water was detected again. The environmental residence time for 137Cs was estimated to be 8.1 years in drinking water and 5.7 years in fallout. The correlation between 137Cs in fallout and in drinking water is very good, and this indicates that fallout is the main source of water contamination. The observed 134Cs/137Cs activity ratio in drinking water for the post-Chernobyl period was similar to the ratio found in other environmental samples. The estimation of annual effective doses received by the adult members of the Croatian population due to the intake of radiocaesium in drinking water showed quite small doses of 0.28 μSv in 1987 decreasing to 2.5 nSv in 2018, which indicated that drinking water was not a critical pathway for the transfer of radiocaesium to humans.
摘要:本文介绍了1987-2018年萨格勒布市饮用水中137Cs和134Cs活性浓度的长期调查结果。这两种放射性核素的最高活性浓度是在1987年测得的,此后呈指数下降,而134Cs在随后几年降至检测极限以下。2011年福岛第一核电站事故后,饮用水中再次检测到134Cs的存在。据估计,137Cs在饮用水中的环境停留时间为8.1年,在沉降物中的环境停留时间为5.7年。沉降物中的137Cs与饮用水中的137Cs具有很好的相关性,这表明沉降物是水污染的主要来源。观察到的切尔诺贝利后时期饮用水中134Cs/137Cs活度比与在其他环境样品中发现的比率相似。克罗地亚成年人因饮用水摄入放射性铯而获得的年有效剂量估计显示,1987年的剂量为0.28 μSv,到2018年减少到2.5 μSv,这表明饮用水不是放射性铯向人类转移的关键途径。
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引用次数: 2
Economical evaluation of radiation processing with high-intensity X-rays 高强度x射线辐射处理的经济评价
IF 0.7 4区 物理与天体物理 Q4 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2020-07-06 DOI: 10.2478/nuka-2020-0027
Z. Zimek
Abstract X-rays application for radiation processing was introduced to the industrial practice, and in some circumstances is found to be more economically competitive, and offer more flexibility than gamma sources. Recent progress in high-power accelerators development gives opportunity to construct and apply reliable high-power electron beam to X-rays converters for the industrial application. The efficiency of the conversion process depends mainly on electron energy and atomic number of the target material, as it was determined in theoretical predictions and confirmed experimentally. However, the lower price of low-energy direct accelerators and their higher electrical efficiency may also have certain influence on process economy. There are number of auxiliary parameters that can effectively change the economical results of the process. The most important ones are as follows: average beam power level, spare part cost, and optimal shape of electron beam and electron beam utilization efficiency. All these parameters and related expenses may affect the unit cost of radiation facility operation and have a significant influence on X-ray process economy. The optimization of X-rays converter construction is also important, but it does not depend on the type of accelerator. The article discusses the economy of radiation processing with high-intensity of X-rays stream emitted by conversion of electron beams accelerated in direct accelerator (electron energy 2.5 MeV) and resonant accelerators (electron energy 5 MeV and 7.5 MeV). The evaluation and comparison of the costs of alternative technical solutions were included to estimate the unit cost of X-rays facility operation for average beam power 100 kW.
摘要x射线在辐射处理中的应用被引入到工业实践中,并且在某些情况下被发现比伽马源更具经济竞争力,并且提供更大的灵活性。高功率加速器的最新进展为构建和应用可靠的高功率电子束用于工业应用的x射线转换器提供了机会。转换过程的效率主要取决于目标材料的电子能量和原子序数,这是理论预测和实验证实的。然而,低能量直接加速器的低价格和高电效率也可能对过程经济性产生一定的影响。有许多辅助参数可以有效地改变工艺的经济效果。其中最重要的是:平均束流功率水平、备件成本、电子束最佳形状和电子束利用效率。所有这些参数和相关费用都会影响到辐射设施运行的单位成本,并对x射线过程经济性产生重大影响。x射线转换器结构的优化也很重要,但这并不取决于加速器的类型。本文讨论了在直接加速器(电子能量2.5 MeV)和共振加速器(电子能量5 MeV和7.5 MeV)加速的电子束转换所发射的高强度x射线流辐射处理的经济性。通过对备选技术方案的成本进行评估和比较,估算出平均束流功率为100千瓦的x射线设施运行的单位成本。
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引用次数: 2
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Nukleonika
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