{"title":"The International Conference on Development and Applications of Nuclear Technologies, NUTECH-2020, Warsaw, Poland, 4–7 October 2020","authors":"Dagmara Chmielewska-Śmietanko, U. Gryczka","doi":"10.2478/nuka-2021-0016","DOIUrl":"https://doi.org/10.2478/nuka-2021-0016","url":null,"abstract":"","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"113 - 114"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45468022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B. P. Rurarz, Natalia Gibka, Małgorzata Bukowczyk, S. Kadłubowski, P. Ulański
Abstract Synthesis of polymer nanogels (NGs) for biomedical applications is considered to be a very promising application in radiation engineering. Under high-dose pulse irradiation of dilute aqueous polymer solution, reactive species generated by water radiolysis can create multiple radicals on each macromolecule and consequently induce intramolecular cross-linking of polymer chains, resulting in NG formation. The obtained products are free from harmful monomers, initiators, and cross-linking agents, which makes them potentially applicable for drug delivery applications. One of the biggest challenges in handling and use of nanoparticles, however, is the colloidal stability, when aqueous suspensions are stored for prolonged periods. Therefore, development of the best protocols for the particular nanocarrier storage is key. To address this need, we have performed the prospective study in which we systematically assessed the influence of various processing and storage scenarios feasible in our lab, on the colloidal stability of the radiation-synthesized poly(acrylic acid) (PAA) NG particles in suspension. This allowed us to choose the optimal way of handling the product after its synthesis. We confirmed that none of the strategies we used and tested are substantially detrimental to our product. Filtration with 0.2-μm filters was proven sufficient for sample purification and prolonged storage in aqueous suspension did not exert a negative effect on the colloidal stability of particles suspension. We have also demonstrated that lyoprotectant-free lyophilization was suitable for our polymer nanoparticles. This is an important fact for further application of particles as nanocarriers for biologically active compounds such as targeting ligands or therapeutic moieties.
{"title":"Radiation synthesis of poly(acrylic acid) nanogels for drug delivery applications – post-synthesis product colloidal stability","authors":"B. P. Rurarz, Natalia Gibka, Małgorzata Bukowczyk, S. Kadłubowski, P. Ulański","doi":"10.2478/nuka-2021-0026","DOIUrl":"https://doi.org/10.2478/nuka-2021-0026","url":null,"abstract":"Abstract Synthesis of polymer nanogels (NGs) for biomedical applications is considered to be a very promising application in radiation engineering. Under high-dose pulse irradiation of dilute aqueous polymer solution, reactive species generated by water radiolysis can create multiple radicals on each macromolecule and consequently induce intramolecular cross-linking of polymer chains, resulting in NG formation. The obtained products are free from harmful monomers, initiators, and cross-linking agents, which makes them potentially applicable for drug delivery applications. One of the biggest challenges in handling and use of nanoparticles, however, is the colloidal stability, when aqueous suspensions are stored for prolonged periods. Therefore, development of the best protocols for the particular nanocarrier storage is key. To address this need, we have performed the prospective study in which we systematically assessed the influence of various processing and storage scenarios feasible in our lab, on the colloidal stability of the radiation-synthesized poly(acrylic acid) (PAA) NG particles in suspension. This allowed us to choose the optimal way of handling the product after its synthesis. We confirmed that none of the strategies we used and tested are substantially detrimental to our product. Filtration with 0.2-μm filters was proven sufficient for sample purification and prolonged storage in aqueous suspension did not exert a negative effect on the colloidal stability of particles suspension. We have also demonstrated that lyoprotectant-free lyophilization was suitable for our polymer nanoparticles. This is an important fact for further application of particles as nanocarriers for biologically active compounds such as targeting ligands or therapeutic moieties.","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"179 - 186"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49414975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Patrycja Śliż-Szpytma, M. Lankosz, J. Dudała, D. Adamek, E. Radwańska, B. Kwinta, M. Jakšić, I. Božičević Mihalić, G. Provatas
Abstract Various types of neuromuscular diseases differ in symptoms, pathology, and clinical picture but one of their common elements is muscle weakness, which could lead to human motor activities impairment and in many cases to shortening of life span and even death due to respiratory failure. That is why it is very important to better understand the underlying causes of these diseases to be able to implement new methods of treatment more effectively. This paper presents the results of the elemental analysis of human muscular tissues affected by dystrophy and myopathy. For this purpose, the particle-induced X-ray emission method was used, which is perfectly suited for measuring light elements. The samples were analysed for differences in the elemental composition of Na, Mg, P, S, Cl, K, Fe, Zn, and Br. The results were presented in the form of elemental concentration maps and a thorough statistical analysis of the obtained data using the advanced statistical methods.
{"title":"Sub-cellular elemental imaging of human muscle tissues affected by neuromuscular diseases","authors":"Patrycja Śliż-Szpytma, M. Lankosz, J. Dudała, D. Adamek, E. Radwańska, B. Kwinta, M. Jakšić, I. Božičević Mihalić, G. Provatas","doi":"10.2478/nuka-2021-0024","DOIUrl":"https://doi.org/10.2478/nuka-2021-0024","url":null,"abstract":"Abstract Various types of neuromuscular diseases differ in symptoms, pathology, and clinical picture but one of their common elements is muscle weakness, which could lead to human motor activities impairment and in many cases to shortening of life span and even death due to respiratory failure. That is why it is very important to better understand the underlying causes of these diseases to be able to implement new methods of treatment more effectively. This paper presents the results of the elemental analysis of human muscular tissues affected by dystrophy and myopathy. For this purpose, the particle-induced X-ray emission method was used, which is perfectly suited for measuring light elements. The samples were analysed for differences in the elemental composition of Na, Mg, P, S, Cl, K, Fe, Zn, and Br. The results were presented in the form of elemental concentration maps and a thorough statistical analysis of the obtained data using the advanced statistical methods.","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"159 - 164"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45921003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract The sorption of 241Am3+, 85Sr2+ and 137Cs+ by calcium, strontium and barium alginates has been studied under different operation conditions. The most prominent adsorption was found in the pH range of 5–6 for all systems, even if the observed dependence on the acidity of the solution was small. The most favourable time for the adsorption process was found to be about 2 h for calcium alginate and 4 h for the other two sorbents.
{"title":"Sorption of selected radionuclides from liquid radioactive waste by sorbents of biological origin: The alkaline earth alginates","authors":"L. Fuks, Agata Oszczak-Nowińska","doi":"10.2478/nuka-2021-0023","DOIUrl":"https://doi.org/10.2478/nuka-2021-0023","url":null,"abstract":"Abstract The sorption of 241Am3+, 85Sr2+ and 137Cs+ by calcium, strontium and barium alginates has been studied under different operation conditions. The most prominent adsorption was found in the pH range of 5–6 for all systems, even if the observed dependence on the acidity of the solution was small. The most favourable time for the adsorption process was found to be about 2 h for calcium alginate and 4 h for the other two sorbents.","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"153 - 158"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43993462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Pawelec, A. Chmielewski, Yongxia Sun, S. Bułka, T. Torims, G. Pikurs, G. Mattausch
Abstract Operation of marine diesel engines causes significant emission of sulphur and nitrogen oxides. It was noticed worldwide and the regulations concerning harmful emissions were introduced. There were several solutions elaborated; however, emission control for both SOx and NOx requires two distinctive processes realized in separated devices, which is problematic due to limited space on ship board and high overall costs. Therefore, the electron beam flue gas treatment (EBFGT) process was adopted to ensure the abatement of the problem of marine diesel off-gases. This novel solution combines two main processes: first the flue gas is irradiated with electron beam where NO and SO2 are oxidized; the second stage is wet scrubbing to remove both pollutants with high efficiency. Laboratory tests showed that this process could be effectively applied to remove SO2 and NOx from diesel engine off-gases. Different compositions of absorbing solution with three different oxidants (NaClO, NaClO2 and NaClO3) were tested. The highest NOx removal efficiency (>96%) was obtained when seawater-NaClO2-NaOH was used as scrubber solution at 10.9 kGy dose. The process was further tested in real maritime conditions at Riga shipyard, Latvia. More than 45% NOx was removed at a 5.5 kGy dose, corresponding to 4800 Nm3/h off-gases arising from ship emission. The operation of the plant was the first case of examination of the hybrid electron beam technology in real conditions. Taking into account the experiment conditions, good agreement was obtained with laboratory tests. The results obtained in Riga shipyard provided valuable information for the application of this technology for control of large cargo ship emission.
{"title":"Plasma technology to remove NOx from off-gases","authors":"A. Pawelec, A. Chmielewski, Yongxia Sun, S. Bułka, T. Torims, G. Pikurs, G. Mattausch","doi":"10.2478/nuka-2021-0033","DOIUrl":"https://doi.org/10.2478/nuka-2021-0033","url":null,"abstract":"Abstract Operation of marine diesel engines causes significant emission of sulphur and nitrogen oxides. It was noticed worldwide and the regulations concerning harmful emissions were introduced. There were several solutions elaborated; however, emission control for both SOx and NOx requires two distinctive processes realized in separated devices, which is problematic due to limited space on ship board and high overall costs. Therefore, the electron beam flue gas treatment (EBFGT) process was adopted to ensure the abatement of the problem of marine diesel off-gases. This novel solution combines two main processes: first the flue gas is irradiated with electron beam where NO and SO2 are oxidized; the second stage is wet scrubbing to remove both pollutants with high efficiency. Laboratory tests showed that this process could be effectively applied to remove SO2 and NOx from diesel engine off-gases. Different compositions of absorbing solution with three different oxidants (NaClO, NaClO2 and NaClO3) were tested. The highest NOx removal efficiency (>96%) was obtained when seawater-NaClO2-NaOH was used as scrubber solution at 10.9 kGy dose. The process was further tested in real maritime conditions at Riga shipyard, Latvia. More than 45% NOx was removed at a 5.5 kGy dose, corresponding to 4800 Nm3/h off-gases arising from ship emission. The operation of the plant was the first case of examination of the hybrid electron beam technology in real conditions. Taking into account the experiment conditions, good agreement was obtained with laboratory tests. The results obtained in Riga shipyard provided valuable information for the application of this technology for control of large cargo ship emission.","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"227 - 231"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45401514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract The Irradiation System for High-Temperature Reactors (ISHTAR) thermostatic rig will be used to irradiate advanced core material samples in conditions corresponding to those prevailing in the high-temperature reactors (HTRs): these conditions include a stable temperature extending up to 1000°C in the helium atmosphere. Computational and experimental studies concerning the design have been conducted, proving the possibility of these conditions’ fulfillment inside the rig while maintaining the safety limits for MARIA research reactor. The outcome is the thermostatic rig design that will be implemented in the MARIA reactor. Appropriate irradiation temperature will be achieved by a combination of electric heating with the control system, gamma heating, and a helium insulation gap with precisely designed thickness. The ISHTAR rig will be placed inside the vertical irradiation channel, which is located in the reactor pool. The device is being developed from scratch at the Nuclear Facilities Operation Department of the National Centre for Nuclear Research as a part of the GOSPOSTRATEG programme.
{"title":"Preliminary computational and experimental design studies of the ISHTAR thermostatic rig for the high-temperature reactors materials irradiation","authors":"A. Talarowska, M. Lipka, G. Wojtania","doi":"10.2478/nuka-2021-0019","DOIUrl":"https://doi.org/10.2478/nuka-2021-0019","url":null,"abstract":"Abstract The Irradiation System for High-Temperature Reactors (ISHTAR) thermostatic rig will be used to irradiate advanced core material samples in conditions corresponding to those prevailing in the high-temperature reactors (HTRs): these conditions include a stable temperature extending up to 1000°C in the helium atmosphere. Computational and experimental studies concerning the design have been conducted, proving the possibility of these conditions’ fulfillment inside the rig while maintaining the safety limits for MARIA research reactor. The outcome is the thermostatic rig design that will be implemented in the MARIA reactor. Appropriate irradiation temperature will be achieved by a combination of electric heating with the control system, gamma heating, and a helium insulation gap with precisely designed thickness. The ISHTAR rig will be placed inside the vertical irradiation channel, which is located in the reactor pool. The device is being developed from scratch at the Nuclear Facilities Operation Department of the National Centre for Nuclear Research as a part of the GOSPOSTRATEG programme.","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"127 - 132"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47438110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Katarzyna Kiegiel, O. Roubinek, D. Gajda, P. Kalbarczyk, Grażyna Zakrzewska-Kołtuniewicz, A. Chmielewski
Abstract This work reports the possibility of uranium recovery from a post-mining uranium ore dump in Poland by a bioleaching method. The studies were conducted on the dump leaching model with the mass of 570 kg of uranium bearing mineral material from Radoniów pile and in the periodic bioreactor with a work volume of 80 dm3 and with mechanical mixing and aeration of the charge. The uranium concentration in the examined material was about 800 ppm. In this process, the consortium of microorganisms isolated from former mines was used. It was composed of the following microorganisms: Bacillius, Pseudomonas, Sphingomonas, Thiobacillus, Halothiobacillus, Thiomonas, and Geothrix. The efficiency of the uranium bioleaching process was 98% in the reactor, and a yield of 70% was obtained in the dump leaching model. The post-leaching solution contained significant amounts of uranium ions that were separated in two stages: (1) by ion chromatography and then (2) by a two-step precipitation method. The resulting solution was a source of ammonium diuranate, the precursor of yellowcake (uranium oxides).
{"title":"Studies on uranium recovery from a U-bearing Radoniów Dump","authors":"Katarzyna Kiegiel, O. Roubinek, D. Gajda, P. Kalbarczyk, Grażyna Zakrzewska-Kołtuniewicz, A. Chmielewski","doi":"10.2478/nuka-2021-0017","DOIUrl":"https://doi.org/10.2478/nuka-2021-0017","url":null,"abstract":"Abstract This work reports the possibility of uranium recovery from a post-mining uranium ore dump in Poland by a bioleaching method. The studies were conducted on the dump leaching model with the mass of 570 kg of uranium bearing mineral material from Radoniów pile and in the periodic bioreactor with a work volume of 80 dm3 and with mechanical mixing and aeration of the charge. The uranium concentration in the examined material was about 800 ppm. In this process, the consortium of microorganisms isolated from former mines was used. It was composed of the following microorganisms: Bacillius, Pseudomonas, Sphingomonas, Thiobacillus, Halothiobacillus, Thiomonas, and Geothrix. The efficiency of the uranium bioleaching process was 98% in the reactor, and a yield of 70% was obtained in the dump leaching model. The post-leaching solution contained significant amounts of uranium ions that were separated in two stages: (1) by ion chromatography and then (2) by a two-step precipitation method. The resulting solution was a source of ammonium diuranate, the precursor of yellowcake (uranium oxides).","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"115 - 119"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43691581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Lyophilization or freeze-drying is the technique of removing ice or other frozen solvents from a material through sublimation and the removal of bound water molecules through the process of desorption. Drying occurs in an absolute vacuum at temperatures from −40°C to −50°C. This technique is often used for the conservation of fruits, especially berries. During this process, the water changes from frozen to gaseous, with no thawing. Due to low temperatures and the high vacuum, most microorganisms are rendered inactive during the lyophilization process. However, if there is a necessity to destroy all microorganisms from treated food, subsequent irradiation with gamma rays is an appropriate method. This paper investigated the influence of different doses of gamma radiation on lyophilized berries’ microbiological characteristics. It was shown that the radiation dose of 7 kGy is sufficient to eliminate the total number of microorganisms (excluding molds) to the extent that the number falls below the permitted limit according t o the law on the microbiological safety of foodstuffs of the Republic of Serbia, and 5 kGy is enough for molds to be rendered inactive. It was also concluded that gamma irradiation does not affect the nutritional value of lyophilized berries.
{"title":"Effect of gamma irradiation on microbiological and nutritional properties of the freeze-dried berries","authors":"S. Mašić, Ivica Vujčić","doi":"10.2478/nuka-2021-0032","DOIUrl":"https://doi.org/10.2478/nuka-2021-0032","url":null,"abstract":"Abstract Lyophilization or freeze-drying is the technique of removing ice or other frozen solvents from a material through sublimation and the removal of bound water molecules through the process of desorption. Drying occurs in an absolute vacuum at temperatures from −40°C to −50°C. This technique is often used for the conservation of fruits, especially berries. During this process, the water changes from frozen to gaseous, with no thawing. Due to low temperatures and the high vacuum, most microorganisms are rendered inactive during the lyophilization process. However, if there is a necessity to destroy all microorganisms from treated food, subsequent irradiation with gamma rays is an appropriate method. This paper investigated the influence of different doses of gamma radiation on lyophilized berries’ microbiological characteristics. It was shown that the radiation dose of 7 kGy is sufficient to eliminate the total number of microorganisms (excluding molds) to the extent that the number falls below the permitted limit according t o the law on the microbiological safety of foodstuffs of the Republic of Serbia, and 5 kGy is enough for molds to be rendered inactive. It was also concluded that gamma irradiation does not affect the nutritional value of lyophilized berries.","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"221 - 225"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48098215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Fülöp, A. Šagátová, I. Benkovský, K. Prokeš, Ľubica Foltínová
Abstract An efficient method of burning polychlorinated biphenyls (PCBs) is often used to remove the environmental burden of PCBs. However, combustion produces toxic dioxins and furans (PCDD/F), so residents are increasingly rejecting this method. The heat treatment (HT) method does not burn PCBs but evaporates it from sediments. Even in this process, PCDD/Fs are formed to a lesser extent, which are destroyed by radiation processing (RP) following the HT. At the same time, the RP method degrades PCB congeners down to biphenyls, which decompose easily in the environment. A block assembly of a complex synergistic combination of equipment for methods of thermal (HT) and radiation (RP) destruction of PCBs in sediments is proposed. The efficacy of this complex was preliminarily determined at a level of 70-fold reduction in PCB concentration in sediments. To achieve a higher reduction factor in the concentration of PCBs, possible procedures for optimizing the settings of individual devices of this complex are presented.
{"title":"Combination of methods of thermal and radiation treatment of sediments associated with PCBs – the Delor type","authors":"M. Fülöp, A. Šagátová, I. Benkovský, K. Prokeš, Ľubica Foltínová","doi":"10.2478/nuka-2021-0030","DOIUrl":"https://doi.org/10.2478/nuka-2021-0030","url":null,"abstract":"Abstract An efficient method of burning polychlorinated biphenyls (PCBs) is often used to remove the environmental burden of PCBs. However, combustion produces toxic dioxins and furans (PCDD/F), so residents are increasingly rejecting this method. The heat treatment (HT) method does not burn PCBs but evaporates it from sediments. Even in this process, PCDD/Fs are formed to a lesser extent, which are destroyed by radiation processing (RP) following the HT. At the same time, the RP method degrades PCB congeners down to biphenyls, which decompose easily in the environment. A block assembly of a complex synergistic combination of equipment for methods of thermal (HT) and radiation (RP) destruction of PCBs in sediments is proposed. The efficacy of this complex was preliminarily determined at a level of 70-fold reduction in PCB concentration in sediments. To achieve a higher reduction factor in the concentration of PCBs, possible procedures for optimizing the settings of individual devices of this complex are presented.","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"207 - 211"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46490250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yongxia Sun, A. Chmielewski, A. Pawelec, G. Mattausch, T. Torims
Abstract The removal of organic pollutants from ship emission was studied using two processes namely electron beam (EB) and hybrid EB with wet scrubbing process. A mobile accelerator unit was used to treat 4915 Nm3/h of flue gas emitted from a tugboat in Riga Shipyard. A volume of 3 m3 seawater containing 36.8 mM of NaClO2 oxidant was used as a wet scrubber solution. Organic pollutants, mainly volatile organic pollutants (VOCs), were collected at three different sampling points, before and after irradiation vessels, and after wet-scrubber unit, respectively. They were collected with glass sampling bottles, tedlar bags, Coconut Shell Charcoal (CSC) sorbents and XAD-2 sorbents. CH3OH and CH3OH/CH2Cl2 (1:1) were used to extract VOCs from CSC and XAD-2 sorbents, respectively. Syringe filters were used to obtain the solid-free extraction solutions. They were concentrated using a micro-extractor under continuously blowing high-purity Ar. A gas chromatography–mass spectrometry (GC-MS) was used for analysis. The identified organic compounds were: aliphatic hydrocarbons (dodecane C12H26 to eicosane C20H42), aromatic hydrocarbon (toluene), esters (C3H7COOCH3, (C4H9OCO)2C6H4), nitro compounds (C3H5NO3, C4H7NO2) and acid (C7H15COOH). After 4.2 kGy EB irradiation, around 50–100% aliphatic hydrocarbons, 83% toluene and 7.5% (C4H9OCO)2C6H4 were removed from the off-gases, and after EB hybrid wet-scrubber process, most organic compounds including nitro compounds were removed. Only trace amount of toluene, hexadecane, octadecane and dibutyl phthalate were found to be present in the gas phase.
{"title":"Organic pollutant removal from marine diesel engine off-gases under electron beam and hybrid electron beam and wet scrubbing process","authors":"Yongxia Sun, A. Chmielewski, A. Pawelec, G. Mattausch, T. Torims","doi":"10.2478/nuka-2021-0028","DOIUrl":"https://doi.org/10.2478/nuka-2021-0028","url":null,"abstract":"Abstract The removal of organic pollutants from ship emission was studied using two processes namely electron beam (EB) and hybrid EB with wet scrubbing process. A mobile accelerator unit was used to treat 4915 Nm3/h of flue gas emitted from a tugboat in Riga Shipyard. A volume of 3 m3 seawater containing 36.8 mM of NaClO2 oxidant was used as a wet scrubber solution. Organic pollutants, mainly volatile organic pollutants (VOCs), were collected at three different sampling points, before and after irradiation vessels, and after wet-scrubber unit, respectively. They were collected with glass sampling bottles, tedlar bags, Coconut Shell Charcoal (CSC) sorbents and XAD-2 sorbents. CH3OH and CH3OH/CH2Cl2 (1:1) were used to extract VOCs from CSC and XAD-2 sorbents, respectively. Syringe filters were used to obtain the solid-free extraction solutions. They were concentrated using a micro-extractor under continuously blowing high-purity Ar. A gas chromatography–mass spectrometry (GC-MS) was used for analysis. The identified organic compounds were: aliphatic hydrocarbons (dodecane C12H26 to eicosane C20H42), aromatic hydrocarbon (toluene), esters (C3H7COOCH3, (C4H9OCO)2C6H4), nitro compounds (C3H5NO3, C4H7NO2) and acid (C7H15COOH). After 4.2 kGy EB irradiation, around 50–100% aliphatic hydrocarbons, 83% toluene and 7.5% (C4H9OCO)2C6H4 were removed from the off-gases, and after EB hybrid wet-scrubber process, most organic compounds including nitro compounds were removed. Only trace amount of toluene, hexadecane, octadecane and dibutyl phthalate were found to be present in the gas phase.","PeriodicalId":19467,"journal":{"name":"Nukleonika","volume":"66 1","pages":"193 - 199"},"PeriodicalIF":0.7,"publicationDate":"2021-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46346821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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