Pub Date : 2023-09-12DOI: 10.17807/orbital.v15i3.19319
Paulo Marcos Donate
Gil Valdo José da Silva, from Guaimbê, São Paulo, rose above the constraints of his small-town upbringing. He moved to São Paulo in 1970 and graduated from the Antárctica Technical School with a degree in Industrial Chemistry. Initially employed by General Motors do Brasil, his zeal for knowledge drove him to pass the entrance exam at the University of S. Paulo's Chemistry Institute (IQ-USP) in 1975. Balancing studies and work, he taught chemistry in schools and developed a passion for teaching. Gil Valdo graduated in 1980 and went on to undertake doctoral studies in organic synthesis of natural goods. He was interested in research, particularly chemical synthesis and Nuclear Magnetic Resonance (NMR) techniques. His accomplishments went beyond the classroom; he became a licensed pilot, a Dive Master, and a lover of languages, culinary arts, and winemaking. Gil Valdo retired in December 2021, after more than 30 years at FFCLRP-USP, to pursue his passions more freely. He died on July 21, 2023, as a result of a heart attack. He was survived by a loving family and a legacy of intellectual, scientific, and cultural achievements. Gil Valdo José da Silva will be remembered for his serenity, dedication, and the diverse interests that enriched his life and the lives of those who were lucky enough to know him.
{"title":"GIL VALDO JOSÉ DA SILVA (1954-2023)","authors":"Paulo Marcos Donate","doi":"10.17807/orbital.v15i3.19319","DOIUrl":"https://doi.org/10.17807/orbital.v15i3.19319","url":null,"abstract":"Gil Valdo José da Silva, from Guaimbê, São Paulo, rose above the constraints of his small-town upbringing. He moved to São Paulo in 1970 and graduated from the Antárctica Technical School with a degree in Industrial Chemistry. Initially employed by General Motors do Brasil, his zeal for knowledge drove him to pass the entrance exam at the University of S. Paulo's Chemistry Institute (IQ-USP) in 1975. Balancing studies and work, he taught chemistry in schools and developed a passion for teaching. Gil Valdo graduated in 1980 and went on to undertake doctoral studies in organic synthesis of natural goods. He was interested in research, particularly chemical synthesis and Nuclear Magnetic Resonance (NMR) techniques. His accomplishments went beyond the classroom; he became a licensed pilot, a Dive Master, and a lover of languages, culinary arts, and winemaking. Gil Valdo retired in December 2021, after more than 30 years at FFCLRP-USP, to pursue his passions more freely. He died on July 21, 2023, as a result of a heart attack. He was survived by a loving family and a legacy of intellectual, scientific, and cultural achievements. Gil Valdo José da Silva will be remembered for his serenity, dedication, and the diverse interests that enriched his life and the lives of those who were lucky enough to know him.","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":"132 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139340644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-15DOI: 10.17807/orbital.v15i2.17959
Dewi Lestarani, Arvinda C. Lalang, Ina Manggi
The articulate storyline 3 application is a multimedia authoring tool used to create interactive learning media with content from a combination of text, images, graphics, sound, animation, and video that is usable on various devices such as laptops, tablets, and smartphones. Teaching materials developed based on articulate storyline 3 can help independent learning. The development model used as a reference in this study is the Borg and Gall model which consists of 5 stages: preliminary studies, design and development, design validation and revision, product trial, and final product dissemination. The results of the assessment of material and media experts on the level of validity of digital teaching materials have a very valid category with a percentage of validity throughout the whole at 87.95% and 93.3%, respectively. The student response to the digital teaching material during the trial was very positive, with an average overall percentage of 95.71% in small-group trials and 95% in large-group trials. Thus, digital teaching materials based on Articulate Storyline 3 on the subject matter of atomic structure and periodic systems of these elements are suitable for use in chemistry learning activities as a source of independent learning and learning media.
{"title":"Development of Articulate Storyline 3-Based Digital Teaching Materials on the Subject of Atomic Structure and Periodic Elements System for SMA/MA Students in Class X","authors":"Dewi Lestarani, Arvinda C. Lalang, Ina Manggi","doi":"10.17807/orbital.v15i2.17959","DOIUrl":"https://doi.org/10.17807/orbital.v15i2.17959","url":null,"abstract":"The articulate storyline 3 application is a multimedia authoring tool used to create interactive learning media with content from a combination of text, images, graphics, sound, animation, and video that is usable on various devices such as laptops, tablets, and smartphones. Teaching materials developed based on articulate storyline 3 can help independent learning. The development model used as a reference in this study is the Borg and Gall model which consists of 5 stages: preliminary studies, design and development, design validation and revision, product trial, and final product dissemination. The results of the assessment of material and media experts on the level of validity of digital teaching materials have a very valid category with a percentage of validity throughout the whole at 87.95% and 93.3%, respectively. The student response to the digital teaching material during the trial was very positive, with an average overall percentage of 95.71% in small-group trials and 95% in large-group trials. Thus, digital teaching materials based on Articulate Storyline 3 on the subject matter of atomic structure and periodic systems of these elements are suitable for use in chemistry learning activities as a source of independent learning and learning media.","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43972507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-15DOI: 10.17807/orbital.v15i2.17939
G. Brasil, Romão Veloso, R. P. Assis, Juhan Augusto, Scardelato Pereira, Alexandre Carvalho, C. P. Soares, I. L. Brunetti, V. Isaac, Paulo Ricelli, G. Zocolo, M. Correa, André Gonzaga, dos Santos
Varronia curassavica Jacq. is a medicinal plant found in Brazil used as anti-inflammatory. Here, we investigated the in vitro antioxidant activity of 70 % ethanol extract of V. curassavica leaves on synthetic radicals (ABTS•+/DPPH•) and reactive oxygen species (O2•-, ROO•, HOCl/OCl-, H2O2), besides its in vitro cytotoxicity. The extract was characterized by UPLC-ESI-QToF-MSE and the annotated compounds were one hydroxybenzoic acid, five phenylpropanoids, and three glycosylated quercetin derivatives, being the main compound rosmarinic acid or its isomer. The antioxidant activity was very promising in all tests, highlighting on the capture of O2•-, which EC50 value was three times lower than Trolox. This activity may be due to the presence of the major compounds, all phenolic compounds. The extract also presented low cytotoxicity. Thus, the extract from V. curassavica leaves has great potential as an antioxidant.
{"title":"Scavenging Activity on Reactive Oxygen Species with Biological Relevance by Varronia curassavica","authors":"G. Brasil, Romão Veloso, R. P. Assis, Juhan Augusto, Scardelato Pereira, Alexandre Carvalho, C. P. Soares, I. L. Brunetti, V. Isaac, Paulo Ricelli, G. Zocolo, M. Correa, André Gonzaga, dos Santos","doi":"10.17807/orbital.v15i2.17939","DOIUrl":"https://doi.org/10.17807/orbital.v15i2.17939","url":null,"abstract":"Varronia curassavica Jacq. is a medicinal plant found in Brazil used as anti-inflammatory. Here, we investigated the in vitro antioxidant activity of 70 % ethanol extract of V. curassavica leaves on synthetic radicals (ABTS•+/DPPH•) and reactive oxygen species (O2•-, ROO•, HOCl/OCl-, H2O2), besides its in vitro cytotoxicity. The extract was characterized by UPLC-ESI-QToF-MSE and the annotated compounds were one hydroxybenzoic acid, five phenylpropanoids, and three glycosylated quercetin derivatives, being the main compound rosmarinic acid or its isomer. The antioxidant activity was very promising in all tests, highlighting on the capture of O2•-, which EC50 value was three times lower than Trolox. This activity may be due to the presence of the major compounds, all phenolic compounds. The extract also presented low cytotoxicity. Thus, the extract from V. curassavica leaves has great potential as an antioxidant.","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42201251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-14DOI: 10.17807/orbital.v15i2.18168
Érico Vinícius Rocha Sanches, Geovanna Vilalva Freire, Simone Reis Santos, Gláucia Braz Alcantra, João Batista Gomes de Souza
Soybean is the main oilseed cultivated in the Middle-west region of Brazil, once geoclimatic conditions favor its cultivation and underexplored species such as crambe, oilseed radish, and niger too. These species can be alternatives to eliminate the conflict between food and energy production, so the study aimed to evaluate and compare the fatty acids content of soybean, crambe, oilseed radish and niger oils by gas chromatography with flame ionization detector using two quantification methods, followed by multivariate statistical analysis to determine the similarity between the selected species and to provide safe information for the best selection and application of these oilseeds. The oil content in crambe, oilseed radish and niger seeds were 44.7% (m/m), 42.45% (m/m) and 28.19% (m/m), respectively. The major fatty acid in niger and soybean oils was linoleic acid (66.9% and 52.07% m/m, respectively), in crambe and oilseed radish was erucic acid (65.29% and 33.54% m/m, respectively). In addition, for saturated fatty acids, the presence is minor (<17%), except for niger seeds with 19.5% (m/m). Niger oil has greater similarity with soybean oil, whereas crambe and oilseed radish oils are more similar to each other. In this way, it was possible to discriminate the different fatty acids present in the oil samples by the proposed method contributing to the objective of the study and enabling better decision-making in the context like biofuels production.
{"title":"Comparative Study of Fatty Acid Composition in Crude Vegetable Oils from Species Cultivated in Mato Grosso do Sul, Brazil","authors":"Érico Vinícius Rocha Sanches, Geovanna Vilalva Freire, Simone Reis Santos, Gláucia Braz Alcantra, João Batista Gomes de Souza","doi":"10.17807/orbital.v15i2.18168","DOIUrl":"https://doi.org/10.17807/orbital.v15i2.18168","url":null,"abstract":"Soybean is the main oilseed cultivated in the Middle-west region of Brazil, once geoclimatic conditions favor its cultivation and underexplored species such as crambe, oilseed radish, and niger too. These species can be alternatives to eliminate the conflict between food and energy production, so the study aimed to evaluate and compare the fatty acids content of soybean, crambe, oilseed radish and niger oils by gas chromatography with flame ionization detector using two quantification methods, followed by multivariate statistical analysis to determine the similarity between the selected species and to provide safe information for the best selection and application of these oilseeds. The oil content in crambe, oilseed radish and niger seeds were 44.7% (m/m), 42.45% (m/m) and 28.19% (m/m), respectively. The major fatty acid in niger and soybean oils was linoleic acid (66.9% and 52.07% m/m, respectively), in crambe and oilseed radish was erucic acid (65.29% and 33.54% m/m, respectively). In addition, for saturated fatty acids, the presence is minor (<17%), except for niger seeds with 19.5% (m/m). Niger oil has greater similarity with soybean oil, whereas crambe and oilseed radish oils are more similar to each other. In this way, it was possible to discriminate the different fatty acids present in the oil samples by the proposed method contributing to the objective of the study and enabling better decision-making in the context like biofuels production.","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48819488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-14DOI: 10.17807/orbital.v15i2.17617
Ananta Ardyansyah, Sri Rahayu
The lack of knowledge integration about the learning environment is one of the causes of the low environmental awareness. The purpose of this study was to develop learning media for carbon compounds based on augmented reality and environmental literacy and to find out student learning outcomes after using media, students' perceptions of the media, and their environmental insight. This research is a research and development (R&D) research by following the ADDIE model. One group pre-test post-test research design was used to examine the effect of using the media. The research instruments were multiple choice test, questionnaires, and interviews which were developed independently and tested for validity & reliability. The analysis technique was the paired sample t-test and content analysis. The results of this study showed that the learning media was very eligible with a validation score reaching 88.1%. The result of the implementation of the final product of ChemiCa shows that there is an impact of using media on student learning outcomes (Sig. 0.000<0.05). Students' perception of the media are very good, learning media can increase their understanding of carbon compounds concepts, as well as their motivation to learn chemistry. This study implies that teachers can use augmented reality-based card game as a supplementary learning media to improve students’ understanding of others relevant chemistry concepts and their environment literacy.
{"title":"Development and Implementation of Augmented Reality-Based Card Game Learning Media with Environmental Literacy in Improving Students' Understanding of Carbon Compounds","authors":"Ananta Ardyansyah, Sri Rahayu","doi":"10.17807/orbital.v15i2.17617","DOIUrl":"https://doi.org/10.17807/orbital.v15i2.17617","url":null,"abstract":"The lack of knowledge integration about the learning environment is one of the causes of the low environmental awareness. The purpose of this study was to develop learning media for carbon compounds based on augmented reality and environmental literacy and to find out student learning outcomes after using media, students' perceptions of the media, and their environmental insight. This research is a research and development (R&D) research by following the ADDIE model. One group pre-test post-test research design was used to examine the effect of using the media. The research instruments were multiple choice test, questionnaires, and interviews which were developed independently and tested for validity & reliability. The analysis technique was the paired sample t-test and content analysis. The results of this study showed that the learning media was very eligible with a validation score reaching 88.1%. The result of the implementation of the final product of ChemiCa shows that there is an impact of using media on student learning outcomes (Sig. 0.000<0.05). Students' perception of the media are very good, learning media can increase their understanding of carbon compounds concepts, as well as their motivation to learn chemistry. This study implies that teachers can use augmented reality-based card game as a supplementary learning media to improve students’ understanding of others relevant chemistry concepts and their environment literacy.","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42164609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-14DOI: 10.17807/orbital.v15i2.18260
Ricardo Parra, C. Carvajal, J. G. Cuaspud
Carbon fly ash (CFA) is the principal industrial waste byproduct from the burning fossil fuel (coal combustion) for the thermal generation of electricity. CFA is a gray or black powdery solid that is constituted mostly metal oxides (Al, Si Fe and Ca), unburned carbon (UC) and other inorganic substance. The management of fly ash has thus been a matter of concern given the requirement of the large area of land for its disposal and potential of causing pollution of air, water, land and effects on human health. Physical and chemical characteristics of fly ash is important, as these characteristics influence its subsequent use and disposal. X-ray diffraction, and fluorescence, scanning microscopy with an energy dispersive spectroscopy, FTIR, BET was the common techniques employed to characterize FA. Characterization by XRD analysis identified the presence of quartz, mullite and sillimanite phases; while the FTIR results allowed the identification of vibrational bands, characteristic of Si-O-Si and Si-O bonds. The EDS analysis coupled to SEM allowed verifying that the composition of the samples is consistent with the results sought and that the morphological characteristics validate the proposed methodology. Surface area analyses (BET) showed that the fly ash possess an active area of 6.02 m2 · g-1.
{"title":"Structural, Morphological and Physical Characterization of Carbon Fly Ash","authors":"Ricardo Parra, C. Carvajal, J. G. Cuaspud","doi":"10.17807/orbital.v15i2.18260","DOIUrl":"https://doi.org/10.17807/orbital.v15i2.18260","url":null,"abstract":"Carbon fly ash (CFA) is the principal industrial waste byproduct from the burning fossil fuel (coal combustion) for the thermal generation of electricity. CFA is a gray or black powdery solid that is constituted mostly metal oxides (Al, Si Fe and Ca), unburned carbon (UC) and other inorganic substance. The management of fly ash has thus been a matter of concern given the requirement of the large area of land for its disposal and potential of causing pollution of air, water, land and effects on human health. Physical and chemical characteristics of fly ash is important, as these characteristics influence its subsequent use and disposal. X-ray diffraction, and fluorescence, scanning microscopy with an energy dispersive spectroscopy, FTIR, BET was the common techniques employed to characterize FA. Characterization by XRD analysis identified the presence of quartz, mullite and sillimanite phases; while the FTIR results allowed the identification of vibrational bands, characteristic of Si-O-Si and Si-O bonds. The EDS analysis coupled to SEM allowed verifying that the composition of the samples is consistent with the results sought and that the morphological characteristics validate the proposed methodology. Surface area analyses (BET) showed that the fly ash possess an active area of 6.02 m2 · g-1. \u0000 ","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43496683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-13DOI: 10.17807/orbital.v15i2.18152
Tasnim Rahman Anisa, M. Islam, M. Islam, M. Matin
Sugar-fatty acid esters (SFAEs, especially sucrose- and glucose-based ones) have dominated the chemical industries for more than 50 years. In comparison to other carbohydrate products, SFAEs serve essential roles in a variety of industries, including the food, pharmaceutical, and cosmetic industries. In this context, the 6-O-hexanoyl ester of 3-O-butyl-1,2-O-isopropylidene-α-D-glucofuranose was synthesized from commercially available D-glucose in a few steps. For a comparative biological study, the 5,6-di-O-benzyl ether of 3-O-butyl-1,2-O-isopropylidene-α-D-glucofuranose was also prepared and characterized. An in vitro antimicrobial test of all the ester and ether compounds indicated that these compounds are more susceptible to fungi than bacteria. Also, they have more potential for A. niger than A. flavus. According to Prediction of Spectra for Substances (PASS), the chemicals found in the current investigation have a variety of potential biological functions.
50多年来，糖脂肪酸酯(SFAEs，尤其是蔗糖和葡萄糖基脂肪酸酯)一直主导着化学工业。与其他碳水化合物产品相比，SFAEs在包括食品、制药和化妆品行业在内的各种行业中发挥着重要作用。在这种情况下，以市售的d -葡萄糖为原料，通过几个步骤合成了3- o -丁基-1,2- o -异丙基-α- d -葡萄糖葡萄糖的6- o -己醇酯。为了进行比较生物学研究，还制备了3- o -丁基-1,2- o -异丙基-α- d -葡聚糖的5,6-二- o -苄基醚并对其进行了表征。所有酯类和醚类化合物的体外抗菌试验表明，这些化合物对真菌比细菌更敏感。此外，它们比黑曲霉更有可能感染黄曲霉。根据物质光谱预测(PASS)，目前研究中发现的化学物质具有多种潜在的生物功能。
{"title":"1,2-O-Isopropylidene-3-O-butylglucofuranose-derived Ester, and Ether: Synthesis, Characterization, and Antimicrobial Study","authors":"Tasnim Rahman Anisa, M. Islam, M. Islam, M. Matin","doi":"10.17807/orbital.v15i2.18152","DOIUrl":"https://doi.org/10.17807/orbital.v15i2.18152","url":null,"abstract":"Sugar-fatty acid esters (SFAEs, especially sucrose- and glucose-based ones) have dominated the chemical industries for more than 50 years. In comparison to other carbohydrate products, SFAEs serve essential roles in a variety of industries, including the food, pharmaceutical, and cosmetic industries. In this context, the 6-O-hexanoyl ester of 3-O-butyl-1,2-O-isopropylidene-α-D-glucofuranose was synthesized from commercially available D-glucose in a few steps. For a comparative biological study, the 5,6-di-O-benzyl ether of 3-O-butyl-1,2-O-isopropylidene-α-D-glucofuranose was also prepared and characterized. An in vitro antimicrobial test of all the ester and ether compounds indicated that these compounds are more susceptible to fungi than bacteria. Also, they have more potential for A. niger than A. flavus. According to Prediction of Spectra for Substances (PASS), the chemicals found in the current investigation have a variety of potential biological functions.","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45492034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-12DOI: 10.17807/orbital.v15i2.17854
H. Jaafar, L. Magesvaran, N. Ameram, Arlina Ali
The production costs and energy conversion efficiency of dye-sensitized solar cells (DSSC) is strongly influenced by the types of dyes used to harvest photons. Natural dyes extracted from different pigments are emerged as a potential dye to enhance the efficiency of DSSC due to their merit properties such as low cost, biodegradable and less environmental concern. Natural pigments were derived from Eleiodoxa conferta (E. conferta) and Spinacia oleracea (S. oleracea) and formation of a mixture of these extracts in (1:1) volume ratio. The dihybrid extract displayed a diverse UV-vis absorption spectrum of 530–550 nm with maximum absorption at ~539 nm. The optical features of the harvested dyes and the photovoltaic productivity of the cells have been explored. The photovoltaic output of the dihybrid delivered the best findings with open-circuit voltage (VOC), short-circuit current density (JSC), fill factor (FF) and energy conversion efficiency values of 0.35 V, 5.83 mA/cm2, 0.63 and 1.29 % respectively.
{"title":"Studies on the Optical and Photoelectric Properties of Anthocyanin and Chlorophyll as Dihybrid Sensitizer in Dye Sensitized Solar Cell (DSSC)","authors":"H. Jaafar, L. Magesvaran, N. Ameram, Arlina Ali","doi":"10.17807/orbital.v15i2.17854","DOIUrl":"https://doi.org/10.17807/orbital.v15i2.17854","url":null,"abstract":"The production costs and energy conversion efficiency of dye-sensitized solar cells (DSSC) is strongly influenced by the types of dyes used to harvest photons. Natural dyes extracted from different pigments are emerged as a potential dye to enhance the efficiency of DSSC due to their merit properties such as low cost, biodegradable and less environmental concern. Natural pigments were derived from Eleiodoxa conferta (E. conferta) and Spinacia oleracea (S. oleracea) and formation of a mixture of these extracts in (1:1) volume ratio. The dihybrid extract displayed a diverse UV-vis absorption spectrum of 530–550 nm with maximum absorption at ~539 nm. The optical features of the harvested dyes and the photovoltaic productivity of the cells have been explored. The photovoltaic output of the dihybrid delivered the best findings with open-circuit voltage (VOC), short-circuit current density (JSC), fill factor (FF) and energy conversion efficiency values of 0.35 V, 5.83 mA/cm2, 0.63 and 1.29 % respectively.","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43915631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-11DOI: 10.17807/orbital.v15i2.17611
Satbir Singh, S. Raj, Sunil V Sharma, Sucheta, V. Yadav
The ring forming reaction of furfural imine (A) and substituted acetophenone (B) via a greener approach resulted in the synthesis of thiazole-imino derivatives (C1 – C5). The compound A was synthesized by green method using acetic acid in aqueous media where conc. Sulfuric acid was avoided. The final compounds (C1-C5) were again synthesized in aqueous media avoiding use of organic solvents. The resultant compounds were characterized and distinguished from their precursors by elemental analysis, 1H-NMR, 13C-NMR and IR spectral studies. The in-vitro activities of the final compounds (C1-C5) depicted that they are all appreciably active against bacterial strains S. aureus, B. subtilis and fungal strains C. albicans, C. glabrata. Ciprofloxacin and Itraconazole were used as the control drugs for anti-bacterial and for anti-fungal activities; respectively. As compared to the other analogues, compound C2 (R = NO2) and C4 (R = Cl) showed best activities against the bacterial and fungal strains; respectively.
{"title":"Green Synthesis and Anti-microbial Activities of Some Thiazole-imino Derivatives","authors":"Satbir Singh, S. Raj, Sunil V Sharma, Sucheta, V. Yadav","doi":"10.17807/orbital.v15i2.17611","DOIUrl":"https://doi.org/10.17807/orbital.v15i2.17611","url":null,"abstract":"The ring forming reaction of furfural imine (A) and substituted acetophenone (B) via a greener approach resulted in the synthesis of thiazole-imino derivatives (C1 – C5). The compound A was synthesized by green method using acetic acid in aqueous media where conc. Sulfuric acid was avoided. The final compounds (C1-C5) were again synthesized in aqueous media avoiding use of organic solvents. The resultant compounds were characterized and distinguished from their precursors by elemental analysis, 1H-NMR, 13C-NMR and IR spectral studies. The in-vitro activities of the final compounds (C1-C5) depicted that they are all appreciably active against bacterial strains S. aureus, B. subtilis and fungal strains C. albicans, C. glabrata. Ciprofloxacin and Itraconazole were used as the control drugs for anti-bacterial and for anti-fungal activities; respectively. As compared to the other analogues, compound C2 (R = NO2) and C4 (R = Cl) showed best activities against the bacterial and fungal strains; respectively.","PeriodicalId":19680,"journal":{"name":"Orbital: The Electronic Journal of Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41430551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-07-01DOI: 10.17807/orbital.v15i2.16800
Maryam Salehnassaj, M. Nikoorazm, A. Zabardasti, H. Goudarziafshar, B. G. Oliveira
Post-Hartree-Fock calculations performed at the MP2/aug-cc-pVDZ level of theory has been used to analyze the formation of intermolecular complexes between B5H11 and W = CO, NCH, NH3, H2O or HOCH3. The interactions on the structure of the arachno-pentaborane(11) are manifested by the terminal and bridge hydrogen atoms, whereby are formed the hydrogen bonds (H∙∙∙Y with Y = O, C or N) as well as dihydrogen bonds (H∙∙∙H). In this context, the B5H11 shows a host-guest capability for trapping molecules, of course depending on the strength of each aforementioned interactions. The topological descriptors of the Quantum Theory of Atoms in Molecules (QTAIM) were decisive for unveiling each one of the following structures B5H11∙∙∙CO, B5H11∙∙∙NCH, B5H11∙∙∙NH3, B5H11∙∙∙H2O and B5H11∙∙∙HOCH3, and ideally, all hydrogen bonding formed by them.
在MP2/aug-cc-pVDZ理论水平上进行的Post-Hartree-Fock计算被用于分析B5H11与W = CO, NCH, NH3, H2O或HOCH3之间的分子间配合物的形成。arachno-pentaborane(11)结构上的相互作用表现为末端氢原子和桥氢原子，由此形成氢键(H∙∙∙Y, Y = O、C或N)和二氢键(H∙∙∙H)。在这种情况下，B5H11显示出捕获分子的主客能力，当然这取决于上述每种相互作用的强度。分子原子量子理论(QTAIM)的拓扑描述符对于揭示以下结构中的每一个具有决定性作用:B5H11∙∙∙CO、B5H11∙∙NCH、B5H11∙∙NH3、B5H11∙∙H2O和B5H11∙∙HOCH3，以及理想情况下由它们形成的所有氢键。
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