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Experimental verification of molybdenum segregation for large-scale slab ingots of Ti–0.3Mo–0.8Ni alloy during electron-beam cold-hearth melting Ti–0.3Mo–0.8Ni合金大型扁锭电子束冷炉熔炼钼偏析的实验验证
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-07-21 DOI: 10.1080/09500839.2022.2100935
Zhenze Zhu, Zulai Li, Rongfeng Zhou, Hai-guang Huang, Wentao Xiong, Xiangming Li
ABSTRACT Ti–0.3Mo–0.8Ni alloy has excellent corrosion resistance and is widely used in making crystallizers, heaters and evaporators for salt production, as well as chemical reactors and heat exchangers. To study the distribution of Mo in the Ti–0.3Mo–0.8Ni alloy during electron beam cold hearth melting, the solidification process has been numerically modelled and the calculations compared with experimental data. A distribution law similar to the calculated results is obtained, which verifies the reliability of the numerical modelling and provides theoretical guidance for the industrial production of Ti–0.3Mo–0.8Ni alloy. In addition, the experimental data indicates that the deviation of the Mo content in each end face and cross-section is within ±0.05%.
摘要:Ti–0.3Mo–0.8Ni合金具有优异的耐腐蚀性,广泛用于制造盐生产的结晶器、加热器和蒸发器,以及化学反应器和热交换器。为了研究电子束冷炉熔炼Ti–0.3Mo–0.8Ni合金中Mo的分布,对凝固过程进行了数值模拟,并将计算结果与实验数据进行了比较。得到了与计算结果相似的分布规律,验证了数值模拟的可靠性,为Ti–0.3Mo–0.8Ni合金的工业化生产提供了理论指导。此外,实验数据表明,每个端面和横截面中Mo含量的偏差在±0.05%以内。
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引用次数: 1
Hidden symmetry in 1D localisation 一维局部化中的隐藏对称性
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-07-13 DOI: 10.1080/09500839.2022.2096267
I. M. Suslov

ABSTRACT

Resistance ρ of an one-dimensional disordered system of length L has the log-normal distribution in the limit of large L. Parameters of this distribution depend on the Fermi level position, but are independent on the boundary conditions. However, the boundary conditions essentially affect the distribution of phases entering the transfer matrix and generally change the parameters of the evolution equation for the distribution P(ρ). This visible contradiction is resolved by the existence of the hidden symmetry, whose nature is revealed by the derivation of the equation for the stationary phase distribution and by analysis of its transformation properties.

长度为L的一维无序系统的电阻ρ在大L的极限处呈对数正态分布,该分布的参数与费米能级位置有关,但与边界条件无关。然而,边界条件实质上影响了进入传递矩阵的相的分布,并且通常改变了P(ρ)分布演化方程的参数。这种可见的矛盾是由隐对称性的存在解决的,隐对称性的本质是通过对定相分布方程的推导和对其变换性质的分析来揭示的。
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引用次数: 0
Gibbsian interpretation of Langmuir, Freundlich and Temkin isotherms for adsorption in solution 溶液中吸附的Langmuir, Freundlich和Temkin等温线的gibbian解释
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-06-20 DOI: 10.1080/09500839.2022.2084571
Lei Lu, Chongzheng Na
ABSTRACT Adsorption is a physicochemical phenomenon important in both natural and engineering processes. In the research and practice of adsorption equilibrium, a long-standing challenge is how to reconcile the classical models proposed by Gibbs, Langmuir, Freundlich, and Temkin for interpreting experimentally obtained adsorption isotherms. Here, we show that the Langmuir, Freundlich, and Temkin isotherms can be derived from the Gibbs equation under different conditions for the change of surface energy (a.k.a. surface tension) by adsorption. When the change of surface energy is predominantly controlled by the change of chemical potential with negligible contribution from the change of internal energy and entropy, the Gibbs equation can be integrated to give the Langmuir isotherm. When changes of internal energy and entropy are no longer negligible, the integration of the Gibbs equation gives the Freundlich and Temkin equations, according to a change of surface energy either independent or linearly dependent on the adsorption capacity. These results indicate that the classical models share the common mechanism of phase equilibrium described by the Gibbsian thermodynamics, thereby providing novel insights for their application.
摘要吸附是一种在自然和工程过程中都很重要的物理化学现象。在吸附平衡的研究和实践中,一个长期存在的挑战是如何调和Gibbs、Langmuir、Freundlich和Temkin提出的用于解释实验获得的吸附等温线的经典模型。在这里,我们证明了Langmuir、Freundlich和Temkin等温线可以从吉布斯方程中导出,在不同条件下,吸附引起的表面能(也称为表面张力)的变化。当表面能的变化主要由化学势的变化控制,而内能和熵的变化贡献可以忽略不计时,吉布斯方程可以积分得到朗缪尔等温线。当内能和熵的变化不再可以忽略时,吉布斯方程的积分给出了Freundlich和Temkin方程,根据表面能的变化,独立于或线性依赖于吸附容量。这些结果表明,经典模型具有吉布斯热力学所描述的相平衡的共同机制,从而为其应用提供了新的见解。
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引用次数: 5
Physical constitutive relational model and structure evolution during dynamic recovery of 23Co14Ni12Cr3MoE (A-100) high-strength steel 23Co14Ni12Cr3MoE(A-100)高强度钢动态恢复过程中的物理本构关系模型及组织演变
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-06-20 DOI: 10.1080/09500839.2022.2084570
Jinke Han, Jianlin Li, Yifan Zhang, Haoyu Zhang, Ge Zhou, Lijia Chen
ABSTRACT The hot compression of A-100 steel at 850–1150°C and strain rate of 0.01–10 s−1 was tested on a Gleeble-3800 thermal simulation machine to determine the corresponding true stress–strain curve. Based on theoretical calculation, the dislocation density factor was introduced into the Avrami equation and thereby a dynamic recovery physical constitutive relational model based on dislocation density theory was established. Then the hot deformation behaviour of A-100 steel was predicted (correlation coefficient R = 0.9964 with an average absolute relative error AARE = 4.0923%). The structures after hot compression were observed by electron backscattered diffraction and found to be lath-shaped martensite and austenite. With an increase of temperature and deceleration of strain rate, the proportions of large-angle boundaries and substructures increased and the softening mechanism became dominated by dynamic recovery.
摘要A-100钢在850–1150°C和0.01–10应变速率下的热压缩 s−1在Gleeble-3800热模拟机上进行测试,以确定相应的真实应力-应变曲线。在理论计算的基础上,将位错密度因子引入Avrami方程,建立了基于位错密度理论的动态恢复物理本构关系模型。然后预测了A-100钢的热变形行为(相关系数R = 0.9964,平均绝对相对误差AARE = 4.0923%)。通过电子背散射衍射观察热压缩后的组织,发现其为板条状马氏体和奥氏体。随着温度的升高和应变速率的降低,大角度边界和亚结构的比例增加,软化机制以动态恢复为主。
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引用次数: 0
Nanoscale face-centered-cubic zirconium dispersed in omega zirconium 纳米级面心立方锆分散在欧米伽锆中
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-05-23 DOI: 10.1080/09500839.2022.2077999
Xinu Tan, R. Qiu, Yushun Liu, Fengxian Bi, Jinlong Zhang, Boran Tao, Qing Liu
ABSTRACT In contrast to lamella-like face-centered cubic zirconium (FCC-Zr) distributed inside an α-Zr matrix, as repeatedly reported previously, dispersed and nanoscale FCC-Zr with lattice parameter a = 0.520 nm has been found inside lamella-like and blocky ω-Zr by transmission electron microscopy (TEM). The orientation relationship between the FCC-Zr and the ω-Zr obeys [001]FCC//[1 02]ω, (100)FCC//(11 0)ω. A possible phase transformation mechanism between FCC-Zr, α-Zr and β-Zr is discussed. This finding introduces a new possibility in phase transformations during the fabrication of Zr alloys, potentially enlightening the design of new high-performance Zr alloys.
摘要与先前重复报道的分布在α-Zr基体内的片状面心立方锆(FCC Zr)不同,分散的纳米级FCC Zr具有晶格参数a = 0.520 透射电子显微镜(TEM)在ω-Zr片层状和块状内部发现了nm。FCC Zr与ω-Zr的取向关系服从[001]FCC//[1 02]ω,(100)FCC//(110)ω。讨论了FCC Zr、α-Zr和β-Zr之间可能的相变机制。这一发现为锆合金制造过程中的相变提供了一种新的可能性,可能对新型高性能锆合金的设计有所启发。
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引用次数: 1
Effect of secondary rolling on the interfacial bonding strength and mechanical properties of Al/Mg/Al clad plates 二次轧制对Al/Mg/Al复合板界面结合强度和力学性能的影响
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-04-22 DOI: 10.1080/09500839.2022.2065702
Xiang-Zhi Cao, Chunhua Xu, Yu Li, Xuecheng Cao, Ruizhi Peng, J. Fang
ABSTRACT The effects of secondary rolling on the microstructure evolution and mechanical properties of Al/Mg/Al clad sheets have been investigated. The results indicate that a double-layer intermetallic compound (Mg2Al3 and Mg17Al12) forms and sandwiches the MgO film during the first rolling and annealing, while the sandwich structure shows a low peel strength owing to the intrinsic brittleness of intermetallic. However, a secondary rolling leads to a shear-induced breakage of the sandwich structure, whereupon the peel strength significantly increases from 1.3 N/mm to 12.7 N/mm on account of an effective bonding of the Mg/Al interface. The secondary rolling not only eliminates the influence of MgO on the interface, but also improves the bonding strength of the interface. Furthermore, the clad sheet can obtain an excellent elongation (21%) and remain of high interfacial strength (∼12 N/mm) after the recovery annealing.
研究了二次轧制对Al/Mg/Al复合板组织演变和力学性能的影响。结果表明,在第一次轧制和退火过程中,双层金属间化合物(Mg2Al3和Mg17Al12)形成并夹住了MgO膜,而夹层结构由于金属间化合物的固有脆性而表现出较低的剥离强度。然而,二次轧制导致夹层结构的剪切引起的断裂,因此剥离强度从1.3显著增加 N/mm至12.7 N/mm,这是由于Mg/Al界面的有效结合。二次轧制不仅消除了MgO对界面的影响,而且提高了界面的结合强度。此外,包层片材可以获得优异的伸长率(21%),并保持较高的界面强度(~12 N/mm)。
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引用次数: 1
Dislocation multiplication and dynamics in an aluminium alloy 铝合金中的位错倍增和动力学
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-04-22 DOI: 10.1080/09500839.2022.2065701
Tiantian Huang, Fei Liu, Zhiyi Liu, Guangyu He, Yangcheng Hu
ABSTRACT A mechanism of dislocation multiplication is introduced. The surface of the Al20Cu2Mn3 phase in an Al alloy can act as a barrier to impede dislocation movement. When two dislocations with opposite Burgers vectors approach each other, dislocations can annihilate if the pair remains at a distance less than the critical distance for annihilation. A dislocation loop is then formed around the Al20Cu2Mn3 phase or dislocations interact with the loop forming a dislocation tangle, which can promote dislocation multiplication. The driving force for dislocation reproduction, the dislocation glide velocity and the rate of dislocation multiplication are discussed.
介绍了位错倍增的机理。Al20Cu2Mn3相的表面可以起到阻挡位错运动的屏障作用。当两个具有相反的Burgers向量的位错相互接近时,如果这对位错保持在小于湮灭的临界距离,则位错可以湮灭。在Al20Cu2Mn3相周围形成位错环或位错与位错环相互作用形成位错缠结,促进位错增殖。讨论了位错再生的驱动力、位错滑动速度和位错增殖速率。
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引用次数: 0
Deformation mechanisms in the directionally solidified nickel-based CM247LC at room temperature 室温定向凝固镍基CM247LC的变形机理
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-03-17 DOI: 10.1080/09500839.2022.2049908
Zhenhuan Gao, Peng Zhang, Q. Niu, Jiao Li, L. Nie, X. Gong, Xiaolong Song
ABSTRACT After solutionizing and aging at 980°C for various durations, the compressive deformation behaviour and mechanisms of the directionally solidified nickel-based superalloy CM247LC are investigated at room temperature. Experimental results show that the yield strength decreases gradually from 991 ± 1.2–672 ± 7.5 MPa with increasing the γ′ precipitate size from 145 ± 2–604 ± 19 nm. Transmission electron microscope observations on the slightly deformed specimens reveal that, in contrast to previous researches, plastic deformation of all the specimens is controlled by strongly coupled dislocations cutting through γ′ precipitates. Based on these experimental results, the relationship between the yield strength and precipitate size is discussed.
摘要研究了定向凝固镍基高温合金CM247LC在980°C不同时间的固溶和时效后的室温压缩变形行为和机理。实验结果表明,屈服强度从991开始逐渐降低 ± 1.2–672 ± 7.5 MPa,随着γ′沉淀尺寸从145增加 ± 2–604 ± 19 nm。对轻微变形试样的透射电镜观察表明,与以往的研究相比,所有试样的塑性变形都是由切割γ′析出相的强耦合位错控制的。基于这些实验结果,讨论了屈服强度与沉淀物尺寸之间的关系。
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引用次数: 1
Ex-situ study of diffusion in liquid Al–Cu melts under a transverse magnetic field using X-ray imaging X射线成像在横向磁场作用下Al–Cu液态熔体扩散的原位研究
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-03-09 DOI: 10.1080/09500839.2022.2048111
Ying Liu, Wen-Chih Lin, Bangfei Zhou, Xianghui Guo, Hao Cai, T. Zheng, B. Ding, Y. Zhong, Lei Zhang
ABSTRACT Al–Cu melts were used to study interdiffusion under a transverse magnetic field (TMF) using X-ray imaging. A novel gravity-assisted automatic docking device was used to create a long capillary of the diffusion couple. Compared with the results acquired using energy-dispersive spectroscopy, X-ray imaging is more convenient and accurate to determine concentration profiles along long capillaries using the numerous gray value intensities in the imaging. Because a TMF can inhibit melt convection, the interdiffusion coefficient (D AlCu) was reduced after applying a TMF of 2 T. Our results demonstrate that the application of X-ray imaging is an efficient way to study ex-situ diffusion in liquid melts.
摘要:采用x射线成像技术研究了Al-Cu熔体在横向磁场(TMF)作用下的相互扩散。采用一种新型的重力辅助自动对接装置,形成了扩散偶的长毛细管。与能量色散光谱的结果相比,x射线成像利用成像中的众多灰度值强度来确定长毛细血管的浓度分布更加方便和准确。由于TMF可以抑制熔体对流,施加2 T的TMF后,相互扩散系数(dalcu)降低。我们的结果表明,应用x射线成像是研究液体熔体中非原位扩散的有效方法。
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引用次数: 3
Modelling of cavity growth during the superplastic flow of a fine-grained Ti–6Al–4V titanium alloy processed by direct rolling 直轧细晶Ti-6Al-4V钛合金超塑性流动过程中空洞生长的模拟
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2022-02-23 DOI: 10.1080/09500839.2022.2036380
Xin Wang, Ge Zhou, Chao Liu, Siqian Zhang, Haoyu Zhang, Feng Li, Lijia Chen
ABSTRACT Ti–6Al–4V fine-grained plates were manufactured using a rolling method and then subjected to superplastic tensile tests at varying temperatures and strain rates on an AG 250KNE electronic tensile testing machine. The superplastic behaviours of the plates were also tested. A cavity-growth model was established and the changing laws of energy during cavity growth and microstructure evolution of superplastic deformation were predicted. The Ti–6Al–4V alloy possessed the maximum elongation rate of 886% at 840°C and a strain rate of 5 × 10−4 s−1. The strain-rate sensitivity index m for this alloy was 0.54. The mechanism of superplastic deformation was established to be strain-induced grain-boundary slip, and the mechanism of cavity growth to be plasticity-controlled cavity coalescence and growth.
摘要采用轧制方法制造了Ti–6Al–4V细晶板,然后在AG 250KNE电子拉伸试验机上进行了不同温度和应变速率下的超塑性拉伸试验。还测试了板材的超塑性行为。建立了空洞生长模型,预测了空洞生长过程中能量的变化规律和超塑性变形的微观组织演变。Ti–6Al–4V合金在840°C下的最大伸长率为886%,应变速率为5 × 10−4 s−1。该合金的应变速率敏感性指数m为0.54。建立了超塑变形机制为应变诱导晶界滑移,空穴生长机制为塑性控制的空穴聚结和生长。
{"title":"Modelling of cavity growth during the superplastic flow of a fine-grained Ti–6Al–4V titanium alloy processed by direct rolling","authors":"Xin Wang, Ge Zhou, Chao Liu, Siqian Zhang, Haoyu Zhang, Feng Li, Lijia Chen","doi":"10.1080/09500839.2022.2036380","DOIUrl":"https://doi.org/10.1080/09500839.2022.2036380","url":null,"abstract":"ABSTRACT Ti–6Al–4V fine-grained plates were manufactured using a rolling method and then subjected to superplastic tensile tests at varying temperatures and strain rates on an AG 250KNE electronic tensile testing machine. The superplastic behaviours of the plates were also tested. A cavity-growth model was established and the changing laws of energy during cavity growth and microstructure evolution of superplastic deformation were predicted. The Ti–6Al–4V alloy possessed the maximum elongation rate of 886% at 840°C and a strain rate of 5 × 10−4 s−1. The strain-rate sensitivity index m for this alloy was 0.54. The mechanism of superplastic deformation was established to be strain-induced grain-boundary slip, and the mechanism of cavity growth to be plasticity-controlled cavity coalescence and growth.","PeriodicalId":19860,"journal":{"name":"Philosophical Magazine Letters","volume":null,"pages":null},"PeriodicalIF":1.2,"publicationDate":"2022-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45635348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
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Philosophical Magazine Letters
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