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Entropy production-based nonlinear optimal perturbation for subsonic flows around an airfoil 亚音速机翼周围流动的基于熵产生的非线性优化扰动
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-17 DOI: 10.1063/5.0220442
Nobutaka Taniguchi, Yuya Ohmichi, Kojiro Suzuki
The extraction and time evolution of optimal perturbation (OP) offers abundant physical insights in fluid dynamics. Nonlinear OP (NLOP) analysis provides an approach for obtaining the trajectory to induce the maximum changes in the flow field. In an extension into unsteady flow field, we tracked the changes of trajectory by an application of initial perturbation field in the compressible Navier–Stokes equation, and we focused on the entropy production (EP) to characterize the trajectory. We proposed entropy production-based NLOP (EP-NLOP) analysis for compressible flows and investigated the effect of evaluation function on the extracted Ops using the subsonic flow around an airfoil. Compared with the conventional disturbance energy (DE-) based NLOP (DE-NLOP) analysis, we demonstrated that the OPs with different spatial wavelength and concentration regions were successfully extracted due to the different spatial sensitivity of evaluation function. In the EP-NLOP analysis, the spatial distribution of OP extracted the larger energy dissipation upstream of the separation points for the short evaluation time. For the long evaluation time, EP-NLOP analysis extracted the transient-time evolution of interacting separation vortices, attributing the multiple wavelengths of OPs. These differences in the OPs offer promising insights into fluid dynamics.
最优扰动(OP)的提取和时间演化为流体动力学提供了丰富的物理启示。非线性最优扰动(NLOP)分析提供了一种获取轨迹的方法,以引起流场的最大变化。在向非稳态流场的扩展中,我们通过在可压缩 Navier-Stokes 方程中应用初始扰动场来跟踪轨迹的变化,并重点关注熵产生(EP)来表征轨迹。我们针对可压缩流提出了基于熵产生的 NLOP(EP-NLOP)分析,并以亚音速机翼周围流为例研究了评价函数对提取的 Ops 的影响。与传统的基于扰动能量(DE-)的 NLOP(DE-NLOP)分析相比,由于评价函数的空间敏感性不同,我们证明成功提取了不同空间波长和浓度区域的 OPs。在 EP-NLOP 分析中,在短评估时间内,OP 的空间分布提取了分离点上游较大的能量耗散。在较长的评估时间内,EP-NLOP 分析提取了相互作用的分离涡旋的瞬时演变,这归因于 OP 的多个波长。OPs 的这些差异为流体动力学提供了很好的启示。
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引用次数: 0
On the role of the Froude number on flow, turbulence, and hyporheic exchange in open-channel flow through boulder arrays 论弗劳德数对通过巨石阵的明渠水流中的流动、湍流和水汽交换的作用
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-17 DOI: 10.1063/5.0222673
Yan Liu, Zhengdao Tang, Lei Huang, Thorsten Stoesser, Hongwei Fang
In this paper, the results of numerical simulations of open-channel flow through boulder arrays at varying Froude numbers are reported. The simulations aim at clarifying the role of the Froude number on flow, turbulence, and hyporheic exchange. At low and intermediate Fr, the boulder top is above the water surface, and time-averaged streamwise flow velocity, Reynolds shear stresses, and the turbulent kinetic energy (TKE) are relatively low in the wake of boulders. Conversely, at high Fr values, the boulders are submerged, hence the flow separates at the boulder crest, creates vertical recirculation, and reattaches on the bed downstream, resulting in an area of elevated Reynolds shear stresses and TKE downstream of the boulders. Two dominant turbulence structures are observed: (i) flapping of boulder wakes with a characteristic length of 2.1 times the boulder diameter (D) at low and intermediate Fr and (ii) an upstream oriented hairpin vortex with a length scale of 1.0D at high Fr. These turbulence structures influence hyporheic exchange downstream of boulders within a limited region of x/D<2.0. In other locations, hyporheic flow is driven by downwelling flow immediately upstream of boulders with a wavelength larger than 2.9D. Finally, the normalized time-averaged hyporheic flux increases with increasing Fr, but it decreases at higher Fr values once the overtopping flow disrupts the formation of the boulder wake.
本文报告了在不同弗劳德数条件下明渠流经巨石阵列的数值模拟结果。模拟旨在阐明弗劳德数对水流、湍流和微流体交换的作用。在中低弗罗德数条件下,巨石顶部位于水面之上,巨石后的时间平均流向流速、雷诺切应力和湍流动能(TKE)相对较低。相反,在 Fr 值较高时,巨石被淹没,因此水流在巨石顶峰处分离,形成垂直再循环,并在下游河床上重新连接,导致巨石下游的雷诺切应力和 TKE 区域升高。观察到两种主要的湍流结构:(这些湍流结构在 x/D<2.0 的有限区域内影响着巨石下游的水汽交换。在其他位置,下沉流是由波长大于 2.9D 的巨石上游下沉流驱动的。最后,归一化的时间平均下垫面流量随 Fr 值的增加而增加,但在 Fr 值较高时,一旦溢流破坏了巨石尾流的形成,下垫面流量就会减少。
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引用次数: 0
Fuzzy uncertainty modeling of generalized Hirota–Satsuma coupled Korteweg–de Vries equation 广义 Hirota-Satsuma 耦合 Korteweg-de Vries 方程的模糊不确定性建模
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-17 DOI: 10.1063/5.0226445
Rambabu Vana, Perumandla Karunakar
This article explores the solitary wave solutions of a generalized Hirota–Satsuma Coupled Korteweg–de Vries (HSCKdV) equation. The HSCKdV equation is a mathematical model that describes certain types of long waves, particularly those found in shallow water. The generalized HSCKdV equation is solved exactly using the Homotopy Perturbation Transform Method (HPTM). By applying this technique, the authors obtain solutions in the form of a convergent power series. These solutions offer an understanding of the characteristics of solitary waves within the domain of shallow water waves. The HSCKdV equation has been solved using the adomian decomposition method, and the results have been compared with those obtained from the HPTM. This comparison demonstrates the effectiveness of the HPTM in solving such nonlinear equations. Further, the HSCKdV equation is extended to a fuzzy version considering the initial condition as a fuzzy parameter. Uncertainty in the initial condition is addressed by representing it using triangular and trapezoidal fuzzy numbers. The generalized fuzzy HSCKdV equation is subsequently tackled using the fuzzy HPTM (FHPTM) providing fuzzy bound solutions. Using the FHPTM, we explain the fuzzy results, highlighting how the solitary wave splits into two solitary waves and noting that the lower and upper bound solutions are interchanged due to negative fuzzy results.
本文探讨了广义广田-萨摩耦合科特韦格-德弗里斯方程(HSCKdV)的孤波解。HSCKdV 方程是一个数学模型,用于描述某些类型的长波,尤其是浅水中的长波。广义 HSCKdV 方程采用同调钝化变换法 (HPTM) 精确求解。通过应用这一技术,作者获得了收敛幂级数形式的解。这些解法有助于理解浅水波域内孤波的特征。HSCKdV 方程采用阿多米分解法求解,求解结果与 HPTM 得出的结果进行了比较。这一比较证明了 HPTM 在求解此类非线性方程时的有效性。此外,考虑到初始条件是一个模糊参数,HSCKdV 方程被扩展为模糊版本。初始条件的不确定性通过使用三角形和梯形模糊数来表示。随后,利用提供模糊约束解的模糊 HPTM(FHPTM)来处理广义模糊 HSCKdV 方程。利用 FHPTM,我们解释了模糊结果,强调了孤波如何分裂成两个孤波,并指出由于负模糊结果,下界解和上界解发生了互换。
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引用次数: 0
Soliton interaction in a two-temperature electron plasma with trapping and superthermality effects 具有捕获和超热效应的双温电子等离子体中的孤子相互作用
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-17 DOI: 10.1063/5.0223332
Usama H. Malik, S. Ali, R. Jahangir, Majid Khan
Head-on collision of the two small-amplitude electron-acoustic (EA) solitons is studied in an unmagnetized collisionless plasma in the presence of superthermal (hot) trapped electrons. For this purpose, using a well-known extended Poincare–Lighthill–Kuo (PLK) method, a pair of the trapped Korteweg–de Vries (tKdV) equations is derived to investigate the soliton trajectories and phase shifts. The latter are found dependent on amplitudes of the interacting solitons, effectively altering with hot-electron superthermality and plasma parameters. Typical parameters for the electron diffusion region (EDR) and day-side auroral zone have been selected to examine the impact of hot-electron superthermality, trapping parameter, hot-to-cold electron number density ratio, and cold-to-hot electron temperature ratio on the profiles of potential excitations and phase shifts of interacting solitons. It is found that phase speed of the EA waves becomes altered by varying the κ–parameter, strongly modifying the nonlinearity and dispersive coefficients in a superthermal trapped plasma. However, particle trapping phenomenon does not affect the linear phase speed but introduces a fractional nonlinearity in the tKdV equations of two interacting solitons. The impact of the adiabatic and isothermal pressures is also highlighted to show new modifications in the propagation characteristics of two interacting solitons.
研究了两个小振幅电子声(EA)孤子在存在超热(热)被困电子的无磁碰撞等离子体中的正面碰撞。为此,利用著名的扩展 Poincare-Lighthill-Kuo (PLK) 方法,推导出了一对被困 Korteweg-de Vries (tKdV) 方程,以研究孤子轨迹和相移。研究发现,后者取决于相互作用孤子的振幅,并随着热电子超热度和等离子体参数的变化而有效改变。我们选择了电子扩散区(EDR)和日侧极光区的典型参数,以研究热电子超热性、捕获参数、冷热电子数密度比和冷热电子温度比对相互作用孤子的势能激波剖面和相移的影响。研究发现,EA 波的相速会随着κ参数的变化而改变,从而强烈地改变了超热陷波等离子体中的非线性和色散系数。然而,粒子捕获现象并不影响线性相速,却在两个相互作用孤子的 tKdV 方程中引入了分数非线性。绝热和等温压力的影响也得到了强调,显示了两个相互作用孤子传播特性的新变化。
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引用次数: 0
Numerical investigation of wingtip aerodynamic interference of two flapping wings on opposite sides 两侧拍翼的翼尖气动干扰数值研究
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-17 DOI: 10.1063/5.0226399
Zengshuang Chen, Xiankai Li, Ming Ma, Yang Zhang, Xueguang Meng
Aerodynamic interference occurs at the wingtips when flying organisms fly in a V formation. In this paper, the wingtip aerodynamic interference of two flapping wings on opposite sides at low Reynolds numbers (Re) is numerically investigated. The effects of streamwise spacing (L1), spanwise spacing (L2), and phase angle (γ) on aerodynamic performance are considered. The results show that, compared to a single wing, a favorable combination of L1 and L2 can improve the overall thrust by 24% while keeping the overall lift essentially unchanged. In an unfavorable case, overall lift and thrust decrease by 18% and 20%, respectively. The overall aerodynamic forces are dominated by the rear wing. Analyzing the essential flow characteristics reveals the double-edged role of downwash and upwash in force generation. Moreover, it is found that the rear wing can realize the upwash/downwash exploitation by flap phasing, turning an unfavorable situation into a favorable one. The key flow physics behind this transformation lies in the relationship between the direction of wing motion and the direction of fluid velocity induced by vortices. These findings provide valuable insights into the understanding of biological phenomena and the design of new flapping wing vehicles.
当飞行生物以 V 形编队飞行时,翼尖会发生气动干扰。本文对低雷诺数(Re)条件下对侧两翼拍动时的翼尖气动干涉进行了数值研究。考虑了流向间距 (L1)、跨向间距 (L2) 和相位角 (γ) 对气动性能的影响。结果表明,与单翼相比,L1 和 L2 的有利组合可将整体推力提高 24%,同时保持整体升力基本不变。在不利的情况下,总升力和推力分别减少 18% 和 20%。整体气动力由尾翼主导。对基本流动特性的分析表明,下冲和上冲对力的产生具有双重作用。此外,研究还发现尾翼可以通过襟翼相位实现上冲/下冲的利用,将不利情况转化为有利情况。这种转变背后的关键流动物理学原理在于机翼运动方向与涡流诱导的流体速度方向之间的关系。这些发现为理解生物现象和设计新型拍翼飞行器提供了宝贵的见解。
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引用次数: 0
Modeling two-phase flows with complicated interface evolution using parallel physics-informed neural networks 利用并行物理信息神经网络模拟具有复杂界面演变的两相流动
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-17 DOI: 10.1063/5.0216609
Rundi Qiu, Haosen Dong, Jingzhu Wang, Chun Fan, Yiwei Wang
The physics-informed neural networks (PINNs) have shown great potential in solving a variety of high-dimensional partial differential equations (PDEs), but the complexity of a realistic problem still restricts the practical application of the PINNs for solving most complicated PDEs. In this paper, we propose a parallel framework for PINNs that is capable of modeling two-phase flows with complicated interface evolution. The proposed framework divides the problem into several simplified subproblems and solves them through training several PINNs on corresponding subdomains simultaneously. To enhance the accuracy of the parallel training framework in two-phase flow, the overlapping domain decomposition method is adopted. The optimal subnetwork sizes and partitioned method are systematically discussed, and a series of cases including a bubble rising, droplet splashing, and the Rayleigh–Taylor instability are applied for quantitative validation. The maximum relative error of quantitative values in these cases is 0.1319. Our results show that the proposed framework not only can accelerate the training procedure of PINNs, but also can capture the spatiotemporal evolution of the interface between various phases. This framework overcomes the difficulties of training PINNs to solve a forward problem in two-phase flow, and it is expected to model more realistic dynamic systems in nature.
物理信息神经网络(PINNs)在求解各种高维偏微分方程(PDEs)方面显示出巨大潜力,但现实问题的复杂性仍然限制了 PINNs 在求解大多数复杂 PDEs 方面的实际应用。在本文中,我们提出了一种 PINNs 并行框架,它能够模拟具有复杂界面演化的两相流。该框架将问题划分为多个简化子问题,并通过在相应子域上同时训练多个 PINNs 来解决这些问题。为了提高两相流并行训练框架的精度,采用了重叠域分解方法。系统地讨论了最佳子网络大小和划分方法,并应用气泡上升、液滴飞溅和瑞利-泰勒不稳定性等一系列案例进行定量验证。在这些情况下,定量值的最大相对误差为 0.1319。结果表明,所提出的框架不仅能加快 PINNs 的训练过程,还能捕捉各相之间界面的时空演变。该框架克服了训练 PINNs 解决两相流前向问题的困难,有望为自然界中更真实的动态系统建模。
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引用次数: 0
Recirculation through western boundary currents varies nonlinearly with the ocean basin's aspect ratio 西部边界流的再循环与海盆的纵横比呈非线性变化
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-17 DOI: 10.1063/5.0226883
Kaushal Gianchandani
Recirculation gyres adjacent to western boundary currents (WBCs) in the ocean enhance the poleward transport of these currents. While it is well-established that the WBC in a barotropic ocean strengthens with increase in basin's aspect ratio (the meridional-to-zonal extent ratio), how intensity of the recirculation through the western boundary layer varies with this parameter remains unexplored. I address this using the non-dimensional form of the nonlinear, wind-driven Stommel–Munk model of westward intensification that comprises three parameters—the aspect ratio (δ), the damping coefficient (ϵ), and the β-Rossby number (Rβ). Here, ϵ is set by the ratio of Rayleigh friction coefficient (or eddy viscosity) to the meridional gradient of the Coriolis frequency and the basin's zonal dimension, while Rβ is proportional to wind stress amplitude and quantifies the strength of nonlinearity. In the weak-to-moderate nonlinearity limit (Rβ<∼ϵ), perturbation analysis reveals that recirculation varies concavely with aspect ratio, suggesting existence of an optimal aspect ratio (δopt) for which the recirculation is maximum and for typical values of ϵ (10−3−10−2), δopt follows the power-law relation δopt=4.3ϵ. Numerical simulations further validate the existence of δopt. For large ϵ (>5×10−3), the power-law predicts δopt for the numerical solutions rather accurately, but does not hold for smaller ϵ (2×10−3) due to increased importance of nonlinear terms. Nevertheless, the nonlinear variation in recirculation through the western boundary layer with aspect ratio is observed for all ϵ values and may contribute to the heterogeneous increase in the WBC's transport across different ocean basins in a warming climate.
海洋中与西边界流(WBC)相邻的再循环涡旋会增强这些洋流的向极输送。尽管人们已经证实,随着海盆纵横比(经向与横向范围之比)的增加,各向同性海洋中的西边界流会增强,但通过西边界层的再循环强度如何随这一参数的变化而变化,仍有待探索。我使用非线性、风驱动的斯托梅尔-蒙克西向增强模型的非维形式来解决这个问题,该模型由三个参数组成--纵横比(δ)、阻尼系数(ϵ)和β-罗斯比数(Rβ)。其中,ϵ 由雷利摩阻系数(或涡粘度)与科里奥利频率子午梯度和海盆带状维度的比值决定,而 Rβ 与风应力振幅成正比,用于量化非线性的强度。在弱-中度非线性极限(Rβ<∼ϵ)下,扰动分析表明,再循环随长宽比呈凹形变化,表明存在一个最佳长宽比(δopt),在该长宽比下,再循环最大;在典型的ϵ值(10-3-10-2)下,δopt 遵循幂律关系 δopt=4.3ϵ。数值模拟进一步验证了 δopt 的存在。对于较大的 ϵ(>5×10-3),幂律对数值解的δopt 预测相当准确,但对于较小的 ϵ(2×10-3),由于非线性项的重要性增加,幂律并不成立。尽管如此,在所有ϵ 值上都可以观察到西部边界层的再循环随纵横比的非线性变化,这可能是气候变暖时西部边界层在不同海洋盆地的传输异质性增加的原因。
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引用次数: 0
Scaling of coherent structures in compressible wall-bounded turbulence 可压缩壁缘湍流中相干结构的缩放
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-17 DOI: 10.1063/5.0231296
Fuzhou Lyu, Chunxiao Xu
Semi-local scales have been widely used in compressible wall-bounded turbulence, but it is still unclear whether they are applicable to the scaling of coherent structures, especially under conditions of high Mach number and cold wall temperature. By scrutinizing the direct numerical simulation dataset at different Mach numbers and wall temperatures, this paper demonstrates that the coherent structures normalized by semi-local scales are universal in size. In addition to this, we find that the ratios of Kolmogorov scales to semi-local scales are independent of Mach number and wall temperature. Thus, Kolmogorov scales can achieve the same scaling effect as the semi-local scales. The velocity spectra are also compared to verify the current scaling method quantitatively. A method to determine the threshold for the vortex identification criterion is proposed, allowing the same threshold for different cases to obtain vortices of similar size. The scaling of other statistics including turbulent kinetic energy, streamwise Reynolds normal stress, and root mean square of fluctuating vorticity is also investigated. A new velocity scale is proposed based on the total-stress-based transformation for mean streamwise velocity, which can collapse the profiles of these statistics more accurately than the semi-local velocity scale. The present paper demonstrates that through appropriate normalization, the structures and statistics of compressible turbulence become universal, reaffirming the validity of Morkovin's hypothesis even for the present high Mach number and cold wall cases.
半局部尺度已被广泛应用于可压缩壁面湍流,但其是否适用于相干结构的缩放,尤其是在高马赫数和低壁温条件下,仍不清楚。通过仔细研究不同马赫数和壁温条件下的直接数值模拟数据集,本文证明了以半局部尺度归一化的相干结构在尺寸上具有普遍性。此外,我们还发现,柯尔莫哥洛夫尺度与半局部尺度的比率与马赫数和壁温无关。因此,柯尔莫哥洛夫尺度可以达到与半局部尺度相同的缩放效果。此外,还对速度谱进行了比较,以定量验证当前的缩放方法。提出了一种确定涡旋识别标准阈值的方法,允许在不同情况下使用相同的阈值来获得相似大小的涡旋。还研究了其他统计量的缩放,包括湍流动能、流向雷诺法向应力和波动涡度的均方根。根据基于总应力的平均流向速度变换,提出了一种新的速度尺度,它能比半局部速度尺度更精确地折叠这些统计量的剖面。本文证明,通过适当的归一化,可压缩湍流的结构和统计量变得通用,从而再次证实了莫尔科文假说的有效性,即使在目前的高马赫数和冷壁情况下也是如此。
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引用次数: 0
Electrokinetic flow and energy conversion induced by streaming potential in nanochannels with symmetric corrugated walls 具有对称波纹壁的纳米通道中由流势诱导的电动流和能量转换
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-11 DOI: 10.1063/5.0226494
Zhiyong Xie, Xingyu Chen, Fang Tan
A theoretical and numerical investigation of electrokinetic flow is performed in a nanochannel with the charged symmetric corrugated surfaces. The perturbation and numerical solutions of electrokinetic flow variables are given, and the effects of corrugation geometry, such as wave amplitude and wave number, on the electrokinetic flow characteristics are systematically examined. The results show that the electrokinetic flow recirculation may occur easily at wave crest due to the electroviscous effect. The velocity profile is strongly dependent on wave number, but the maximum or minimum velocity may be insusceptible to wave number. Furthermore, the distributions of streaming potential and energy conversion efficiency are also investigated. We find that, for some special geometry of corrugations, the streaming current and conversion efficiency obtained from the present corrugated nanochannel are higher than that from the smooth nanochannel. Specially, when the dimensionless wave number is 0.5/π, the magnitude of streaming potential is enhanced about 29% at δ = 0.5 and the peak value of conversion efficiency is enhanced about 2% at δ = 0.1. We believe that the optimal corrugation geometry parameters can be of benefit in designing a microfluidic device with higher streaming current and conversion efficiency.
对带电对称波纹表面纳米通道中的电动力流进行了理论和数值研究。给出了电动力流变量的扰动和数值解,并系统研究了波纹的几何形状(如波幅和波数)对电动力流特性的影响。结果表明,由于电粘性效应,电动力流在波峰处很容易发生再循环。速度剖面与波数密切相关,但最大或最小速度可能不受波数影响。此外,我们还研究了流势和能量转换效率的分布。我们发现,对于一些特殊的波纹几何形状,本波纹纳米通道获得的流势和能量转换效率均高于光滑纳米通道。特别是当无量纲波数为 0.5/π 时,δ = 0.5 时的流势大小提高了约 29%,δ = 0.1 时的转换效率峰值提高了约 2%。我们相信,最佳的波纹几何参数有助于设计出具有更高流电势和转换效率的微流体装置。
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引用次数: 0
Surface wettability and capillary flow of water in nanoslits of two-dimensional hexagonal-boron nitride 二维六方氮化硼纳米片中水的表面润湿性和毛细流动
IF 4.6 2区 工程技术 Q1 MECHANICS Pub Date : 2024-09-11 DOI: 10.1063/5.0224117
Ya-Wun Lu, Hsin-Yu Chang, Heng-Kwong Tsao, Yu-Jane Sheng
The wettability and imbibition dynamics of water within 2-dimensional hexagonal boron nitride (h-BN) nanochannels were investigated through nanoscale molecular dynamics simulations. Results from the sessile drop and liquid plug methods indicate that the contact angle on h-BN is notably lower than that on graphene, with single-layer h-BN exhibiting greater hydrophobicity compared to multilayer h-BN. The disjoining pressure in liquid nanoplug was calculated to validate the Young–Laplace equation. During the imbibition process, the penetration length follows l2 = Slt. Simultaneously, the decrease in internal energy (ΔE) follows ΔE = −SEt1/2. While the Lucas–Washburn expression (l2 ∼ wt) can capture such behavior, it does not account for the dependence on channel width (w), where w = Nb, with N denoting the number of h-BN sheets and b the thickness. In wide nanoslits (N > 4), the penetration velocity decreases as the channel width increases. The final ΔE converge to the same value, and SE2/Sl remains constant. In narrow nanoslits (N ≤ 4), the penetration velocity does not decrease consistently with channel width. The final ΔE does not converge to a consistent value for N = 1, 1.5, and 2, and SE exhibits distinct trends with Sl. Comparisons reveal that water in h-BN nanochannels exhibits a notably higher imbibition velocity than in graphene due to differences in the driving force.
通过纳米级分子动力学模拟研究了水在二维六方氮化硼(h-BN)纳米通道中的润湿性和浸润动力学。无柄液滴法和液塞法的结果表明,h-BN 上的接触角明显低于石墨烯上的接触角,与多层 h-BN 相比,单层 h-BN 表现出更大的疏水性。计算了液态纳米插头中的分离压力,以验证 Young-Laplace 方程。在浸泡过程中,渗透长度为 l2 = Slt。同时,内能(ΔE)的减少遵循ΔE = -SEt1/2。虽然卢卡斯-沃什伯恩表达式(l2 ∼ wt)可以捕捉到这种行为,但它没有考虑到与通道宽度(w)的关系,其中 w = Nb,N 表示 h-BN 薄片的数量,b 表示厚度。在宽纳米通道(N > 4)中,穿透速度随着通道宽度的增加而降低。最终的 ΔE 收敛到相同的值,SE2/Sl 保持不变。在窄纳米its(N ≤ 4)中,穿透速度不会随通道宽度的增加而持续降低。在 N = 1、1.5 和 2 时,最终的 ΔE 值并不趋于一致,SE 与 Sl 呈明显的变化趋势。比较结果表明,由于驱动力的不同,水在 h-BN 纳米通道中的浸润速度明显高于石墨烯。
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引用次数: 0
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