Pub Date : 2022-01-25DOI: 10.1108/prt-08-2021-0093
S. N., N. B, B. G, P. R
Purpose This paper aims to investigate the resultant optimal ultimate tensile strength, elongation, flexural strength and modulus, compression strength and impact strength of fabricated alkali-treated Lagenaria siceraria fiber (LSF)-reinforced polymer matrix composite by optimizing input factors and microstructural characterization by influencing fiber length, fiber concentration and treatment condition of LSF. Design/methodology/approach The fabrication of LSF-reinforced composite specimens involved surface treatment followed by custom experimental design using a simple hand layup process. The wear analysis was performed by a multi-tribotester TR25 machine, and the developed model was validated by using statistical software Design Expert V.8 and analysis of variance (ANOVA). The surface morphology of the sample was also analyzed by field emission scanning electron microscopy. Findings The alkali treatment for LSFs had reduced the hemicellulose, and enhanced mechanical performance was observed for 30 wt.% concentration of L. siceraria in epoxy resin. Thermogravimetric analysis revealed thermal stability up to 245°C; microstructure revealed fiber entanglements in case of longer fiber length and compression strength reduction; and the surface-treated fiber composites exhibited reduced occurrences of defects and enhanced matrix–fiber bonding. Enhanced mechanical performances were observed, namely, ultimate tensile strength of 17.072 MPa, elongation of 1.847%, flexural strength of 50.4 MPa, flexural modulus of 3,376.31 GPa, compression strength of 52.154 MPa and impact strength of 0.53 joules. Originality/value The novel approach of optimizing and characterizing alkali surface-treated LSF-reinforced epoxy matrix composite was explored, varying fiber length and concentrations for specimens by empirical relations and experimental design to obtain optimal performance validated by ANOVA. Enhanced properties were obtained for: 7 mm fiber length and 30 wt.% concentration of fiber in the composite for alkali-treated fiber.
{"title":"Optimization and characterization of surface treated Lagenaria siceraria fiber and its reinforcement effect on epoxy composites","authors":"S. N., N. B, B. G, P. R","doi":"10.1108/prt-08-2021-0093","DOIUrl":"https://doi.org/10.1108/prt-08-2021-0093","url":null,"abstract":"\u0000Purpose\u0000This paper aims to investigate the resultant optimal ultimate tensile strength, elongation, flexural strength and modulus, compression strength and impact strength of fabricated alkali-treated Lagenaria siceraria fiber (LSF)-reinforced polymer matrix composite by optimizing input factors and microstructural characterization by influencing fiber length, fiber concentration and treatment condition of LSF.\u0000\u0000\u0000Design/methodology/approach\u0000The fabrication of LSF-reinforced composite specimens involved surface treatment followed by custom experimental design using a simple hand layup process. The wear analysis was performed by a multi-tribotester TR25 machine, and the developed model was validated by using statistical software Design Expert V.8 and analysis of variance (ANOVA). The surface morphology of the sample was also analyzed by field emission scanning electron microscopy.\u0000\u0000\u0000Findings\u0000The alkali treatment for LSFs had reduced the hemicellulose, and enhanced mechanical performance was observed for 30 wt.% concentration of L. siceraria in epoxy resin. Thermogravimetric analysis revealed thermal stability up to 245°C; microstructure revealed fiber entanglements in case of longer fiber length and compression strength reduction; and the surface-treated fiber composites exhibited reduced occurrences of defects and enhanced matrix–fiber bonding. Enhanced mechanical performances were observed, namely, ultimate tensile strength of 17.072 MPa, elongation of 1.847%, flexural strength of 50.4 MPa, flexural modulus of 3,376.31 GPa, compression strength of 52.154 MPa and impact strength of 0.53 joules.\u0000\u0000\u0000Originality/value\u0000The novel approach of optimizing and characterizing alkali surface-treated LSF-reinforced epoxy matrix composite was explored, varying fiber length and concentrations for specimens by empirical relations and experimental design to obtain optimal performance validated by ANOVA. Enhanced properties were obtained for: 7 mm fiber length and 30 wt.% concentration of fiber in the composite for alkali-treated fiber.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2022-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47164217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-24DOI: 10.1108/prt-06-2021-0062
A. Akar, Berrin Değirmenci, Nesrin Köken
Purpose The purpose of this paper is the production of fire retardant and smoke suppressant rigid polyurethane foam (RPUF) with lower toxicity by using several fire-retardant combinations. Design/methodology/approach Fire-retardant additives with cooling effect, barrier ash formation effect, gas-phase inhibition effect and smoke suppressant effect combined to produce an optimum outcome on RPUF. The additive amount and burning time correlation were studied to find out the minimum amount of fire-retardant to obtain fire-retardant polyurethane foam. Findings Zinc borate powder was coated with 1.5 wt % of stearic acid and hydroxy stearic acid. Polyammonium diborates (PABs) were synthesized and used as a fire-retardant and smoke suppressant for rigid PU foam. Fire-retardant rigid polyurethane foams (FR-RPUF) composites formed by using several combinations of zinc borate, aluminum trihydroxide, trischloroisopropyl phosphate (TCPP), PABs, zinc borate coated with stearic acid and hydroxy stearic acid. Produced FR-RPUF were horizontal burning grade, and burning time was in the range of 1–10 s. Research limitations/implications There were limitations during the mixing of fire-retardant powders with polyol due to the high viscosity of the mixture. Practical implications FR-RPUF foam with lower toxicity can be produced industrially with these fire-retardant combinations. Social implications FR-RPUF could be produced by using non-toxic additives. During a fire, these additives do not evolve toxic gases. The TCPP content of RPUF foam was reduced, and fire-retardant PU with lower toxicity was produced. Originality/value Coated zinc borate and the combinations of the fire-retardants were successful in producing non-toxic fire-retardant and smoke suppressant PU foam.
{"title":"Fire-retardant and smoke-suppressant rigid polyurethane foam composites","authors":"A. Akar, Berrin Değirmenci, Nesrin Köken","doi":"10.1108/prt-06-2021-0062","DOIUrl":"https://doi.org/10.1108/prt-06-2021-0062","url":null,"abstract":"\u0000Purpose\u0000The purpose of this paper is the production of fire retardant and smoke suppressant rigid polyurethane foam (RPUF) with lower toxicity by using several fire-retardant combinations.\u0000\u0000\u0000Design/methodology/approach\u0000Fire-retardant additives with cooling effect, barrier ash formation effect, gas-phase inhibition effect and smoke suppressant effect combined to produce an optimum outcome on RPUF. The additive amount and burning time correlation were studied to find out the minimum amount of fire-retardant to obtain fire-retardant polyurethane foam.\u0000\u0000\u0000Findings\u0000Zinc borate powder was coated with 1.5 wt % of stearic acid and hydroxy stearic acid. Polyammonium diborates (PABs) were synthesized and used as a fire-retardant and smoke suppressant for rigid PU foam. Fire-retardant rigid polyurethane foams (FR-RPUF) composites formed by using several combinations of zinc borate, aluminum trihydroxide, trischloroisopropyl phosphate (TCPP), PABs, zinc borate coated with stearic acid and hydroxy stearic acid. Produced FR-RPUF were horizontal burning grade, and burning time was in the range of 1–10 s.\u0000\u0000\u0000Research limitations/implications\u0000There were limitations during the mixing of fire-retardant powders with polyol due to the high viscosity of the mixture.\u0000\u0000\u0000Practical implications\u0000FR-RPUF foam with lower toxicity can be produced industrially with these fire-retardant combinations.\u0000\u0000\u0000Social implications\u0000FR-RPUF could be produced by using non-toxic additives. During a fire, these additives do not evolve toxic gases. The TCPP content of RPUF foam was reduced, and fire-retardant PU with lower toxicity was produced.\u0000\u0000\u0000Originality/value\u0000Coated zinc borate and the combinations of the fire-retardants were successful in producing non-toxic fire-retardant and smoke suppressant PU foam.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2022-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44775446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-20DOI: 10.1108/prt-09-2021-0116
Qingbin Cui, Fenjuan Shao
Purpose Both glazing and laminating play a certain role in finishing and protecting the surface of printed matter. This study makes a comparative analysis of the two through life cycle assessment (LCA) and theoretically explores the difference between them. Design/methodology/approach In this study, the life cycle of laminating and glazing processes was calculated through using Simapro software, and the results were compared and analyzed. Findings Twelve environmental categories were used to quantitatively analyze the environmental impact of the product. The results showed that the results of the 12 environmental categories involved in the analysis of glazing was less than that of laminating, indicating that the impact of the glazing on the environment was less than that of laminating on the environment. Research limitations/implications In order to simplify the study, we only calculated and analyzed the laminating and glazing. Practical implications Green packaging is the future, 3R1D, reduce, reuse, recycle and degradable. According to the calculation results, corresponding suggestions can be put forward from production, processing, use, waste and other aspects, and make corresponding contributions to the development of green packaging. Originality/value The contribution and impact of each stage to the product life cycle can be studied. In addition, different waste disposal methods have different impacts on the environment, and the higher the recovery ratio, the better the environmental benefits of the product. Recycling should then be promoted as proportionately as possible in practice in order to reduce the environmental impact .
{"title":"Comparison of life cycle assessment for laminating and glazing processes based on simapro","authors":"Qingbin Cui, Fenjuan Shao","doi":"10.1108/prt-09-2021-0116","DOIUrl":"https://doi.org/10.1108/prt-09-2021-0116","url":null,"abstract":"\u0000Purpose\u0000Both glazing and laminating play a certain role in finishing and protecting the surface of printed matter. This study makes a comparative analysis of the two through life cycle assessment (LCA) and theoretically explores the difference between them.\u0000\u0000\u0000Design/methodology/approach\u0000In this study, the life cycle of laminating and glazing processes was calculated through using Simapro software, and the results were compared and analyzed.\u0000\u0000\u0000Findings\u0000Twelve environmental categories were used to quantitatively analyze the environmental impact of the product. The results showed that the results of the 12 environmental categories involved in the analysis of glazing was less than that of laminating, indicating that the impact of the glazing on the environment was less than that of laminating on the environment.\u0000\u0000\u0000Research limitations/implications\u0000In order to simplify the study, we only calculated and analyzed the laminating and glazing.\u0000\u0000\u0000Practical implications\u0000Green packaging is the future, 3R1D, reduce, reuse, recycle and degradable. According to the calculation results, corresponding suggestions can be put forward from production, processing, use, waste and other aspects, and make corresponding contributions to the development of green packaging.\u0000\u0000\u0000Originality/value\u0000The contribution and impact of each stage to the product life cycle can be studied. In addition, different waste disposal methods have different impacts on the environment, and the higher the recovery ratio, the better the environmental benefits of the product. Recycling should then be promoted as proportionately as possible in practice in order to reduce the environmental impact .\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":"1 1","pages":""},"PeriodicalIF":1.4,"publicationDate":"2022-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41632394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-14DOI: 10.1108/prt-10-2021-0123
Amir A Abdelsalam, S. El-Sabbagh, Wael Sabry Mohamed, Jian Li, Lihua Wang, H. Ismail, Ahmed Abdelmoneim, Mohsen A. Khozami
Purpose This paper aims to study the effects of various compatibilisers (maleic anhydride (MAH), methyl methacrylate/butyl acrylate emulsion lattice, and adhesion system (HRH)) on properties of carbon black (CB) filled with natural rubber (NR)/styrene-butadiene rubber (SBR)/ nitrile butadiene rubber (NBR) blends). A series of NR/SBR/NBR blends at a 30/30/40 blend ratio reinforced with 45 phr of CB was prepared using the master-batch method. Design/methodology/approach The tensile properties such as the tensile strength, stress at 100, 200 and 300% elongations, and elongation at break (EB)% were studied. Additionally, the morphological properties of compatibilised and uncompatibilised composites were compared to determine the optimal compatibiliser content. Findings The influence of compatibilisers appeared on all the properties studied. The properties of the blends compatibilised with prepared emulsion are very distinct from those of blends compatibilised with MAH and adhesion systems. Research limitations/implications Interactions among the different components of blends at the interfaces have a high impact on the interfacial properties of the rubber blend. Practical implications Compatibilisers significantly improve the physicomechanical properties of the resulting composites with the loading of investigated compatibilisers because of the uniform dispersion of CB in the rubber matrix. Social implications Using blends in the rubber industry leads to high-efficiency production of low-cost products. Originality/value The rubber blending has a significant positive effect on a wide range of applications such as structural applications, aerospace, military, packaging, tires and biomedical. Hence, improving the compatibility of blends will make new materials suitable for new applications.
{"title":"Effect of compatibilisers on the cure characteristics and mechanical properties of ternary rubber blend composites","authors":"Amir A Abdelsalam, S. El-Sabbagh, Wael Sabry Mohamed, Jian Li, Lihua Wang, H. Ismail, Ahmed Abdelmoneim, Mohsen A. Khozami","doi":"10.1108/prt-10-2021-0123","DOIUrl":"https://doi.org/10.1108/prt-10-2021-0123","url":null,"abstract":"\u0000Purpose\u0000This paper aims to study the effects of various compatibilisers (maleic anhydride (MAH), methyl methacrylate/butyl acrylate emulsion lattice, and adhesion system (HRH)) on properties of carbon black (CB) filled with natural rubber (NR)/styrene-butadiene rubber (SBR)/ nitrile butadiene rubber (NBR) blends). A series of NR/SBR/NBR blends at a 30/30/40 blend ratio reinforced with 45 phr of CB was prepared using the master-batch method.\u0000\u0000\u0000Design/methodology/approach\u0000The tensile properties such as the tensile strength, stress at 100, 200 and 300% elongations, and elongation at break (EB)% were studied. Additionally, the morphological properties of compatibilised and uncompatibilised composites were compared to determine the optimal compatibiliser content.\u0000\u0000\u0000Findings\u0000The influence of compatibilisers appeared on all the properties studied. The properties of the blends compatibilised with prepared emulsion are very distinct from those of blends compatibilised with MAH and adhesion systems.\u0000\u0000\u0000Research limitations/implications\u0000Interactions among the different components of blends at the interfaces have a high impact on the interfacial properties of the rubber blend.\u0000\u0000\u0000Practical implications\u0000Compatibilisers significantly improve the physicomechanical properties of the resulting composites with the loading of investigated compatibilisers because of the uniform dispersion of CB in the rubber matrix.\u0000\u0000\u0000Social implications\u0000Using blends in the rubber industry leads to high-efficiency production of low-cost products.\u0000\u0000\u0000Originality/value\u0000The rubber blending has a significant positive effect on a wide range of applications such as structural applications, aerospace, military, packaging, tires and biomedical. Hence, improving the compatibility of blends will make new materials suitable for new applications.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2022-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43570590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-12DOI: 10.1108/prt-09-2021-0106
Ufuk Yilmaz
Purpose In this present study, electrophotographic printing is made on papers which are subjected to different recycling numbers, and this paper aims to examine the colour changes of this printing type. Design/methodology/approach Four-colour electrophotographic printing is carried out on adhering to the INGEDE 11p standard recycled papers four times under the same conditions. Colour measurements are made by means of electrophotographic printed colour scales printed on these recycled papers. Colour measurements are made with the X-Rite eXact spectrophotometer according to the ISO 13655:2017 standard. As a result of colour measurements, colour differences (ΔL′, ΔH′, ΔC′, ΔE00) of recycled papers are determined using some formulas. Findings According to the values obtained after four recycling, the highest ΔL′ value is found to be 4.80 yellow and the lowest 1.92 black. Again, according to the measurement results, it is determined that the highest ΔE00 is yellow colour with a value of 5.66, and lowest ΔE00 is black colour with a value of 1.98. In ΔH′, black colour is the highest value of 12.61, the lowest value with −2.05 is obtained in magenta colour. It was observed that the highest ΔC′ value is 2.98 in yellow, and the lowest value is −0.28 in black. Originality/value In the printing industry, sometimes customers want to monitor the colour differences in the printing by taking the L′a′b′ obtained values as a result of printing from the printing houses. If the colour differences exceed the tolerance values, then they can interfere with the printing. As a result of the calculations, colour changes in electrophotographic printing are observed with many parameters. This study can be a pioneer for the studies that can be done on this subject.
{"title":"Analysis of the color properties of papers subjected to different recycling numbers in electrophotographic (toner) printing","authors":"Ufuk Yilmaz","doi":"10.1108/prt-09-2021-0106","DOIUrl":"https://doi.org/10.1108/prt-09-2021-0106","url":null,"abstract":"\u0000Purpose\u0000In this present study, electrophotographic printing is made on papers which are subjected to different recycling numbers, and this paper aims to examine the colour changes of this printing type.\u0000\u0000\u0000Design/methodology/approach\u0000Four-colour electrophotographic printing is carried out on adhering to the INGEDE 11p standard recycled papers four times under the same conditions. Colour measurements are made by means of electrophotographic printed colour scales printed on these recycled papers. Colour measurements are made with the X-Rite eXact spectrophotometer according to the ISO 13655:2017 standard. As a result of colour measurements, colour differences (ΔL′, ΔH′, ΔC′, ΔE00) of recycled papers are determined using some formulas.\u0000\u0000\u0000Findings\u0000According to the values obtained after four recycling, the highest ΔL′ value is found to be 4.80 yellow and the lowest 1.92 black. Again, according to the measurement results, it is determined that the highest ΔE00 is yellow colour with a value of 5.66, and lowest ΔE00 is black colour with a value of 1.98. In ΔH′, black colour is the highest value of 12.61, the lowest value with −2.05 is obtained in magenta colour. It was observed that the highest ΔC′ value is 2.98 in yellow, and the lowest value is −0.28 in black.\u0000\u0000\u0000Originality/value\u0000In the printing industry, sometimes customers want to monitor the colour differences in the printing by taking the L′a′b′ obtained values as a result of printing from the printing houses. If the colour differences exceed the tolerance values, then they can interfere with the printing. As a result of the calculations, colour changes in electrophotographic printing are observed with many parameters. This study can be a pioneer for the studies that can be done on this subject.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2022-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48352597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-11DOI: 10.1108/prt-08-2021-0095
A. Shams Nateri, L. Asadi
Purpose The purpose of this study is evaluate the optical properties of polyacrylonitrile (PAN) nanofibers containing fluorescent agents such as fluorescent dye and carbon quantum dots (CQDs) by using image-processing technique of Fluorescence microscope image. Design/methodology/approach The fluorescence microscope image of the pure PAN, PAN/CQDs and PAN/fluorescent dye nanofibers composite was analyzed using several image-processing techniques such as color histogram, lookup table (LUT), Fourier transform, RGB profile and surface plot analysis. Findings The fluorescence microscope image indicates that the fluorescence emission of nanocomposites depends on the type of fluorescent agent. The fluorescence intensity of nanofiber containing CQDs is more than nanofiber containing fluorescent dye. Various image-processing methods provide similar results for optical property of nanocomposites. Analyzing the LUT, the blue value of CQDs/PAN nanocomposite image was significantly higher than other nanocomposites. This was confirmed by other methods such as Fourier transform, color histogram and 3D topography of the electrospun nanofibers. According to analysis of colorimetric parameters, higher negative value of b* indicates bluer color for CQDs/PAN nanofibers than other nanocomposites. The obtained results indicate that the image-processing technique can be used to evaluate the optical property of fluorescent nanocomposite. Originality/value This study evaluates the optical properties of fluorescent nanocomposites by using image-processing techniques such as Fourier transform, color histogram, RGB profiles, LUT, surface plot and histogram analysis.
{"title":"Evaluation of optical properties of fluorescent nanofiber using image-processing technique","authors":"A. Shams Nateri, L. Asadi","doi":"10.1108/prt-08-2021-0095","DOIUrl":"https://doi.org/10.1108/prt-08-2021-0095","url":null,"abstract":"\u0000Purpose\u0000The purpose of this study is evaluate the optical properties of polyacrylonitrile (PAN) nanofibers containing fluorescent agents such as fluorescent dye and carbon quantum dots (CQDs) by using image-processing technique of Fluorescence microscope image.\u0000\u0000\u0000Design/methodology/approach\u0000The fluorescence microscope image of the pure PAN, PAN/CQDs and PAN/fluorescent dye nanofibers composite was analyzed using several image-processing techniques such as color histogram, lookup table (LUT), Fourier transform, RGB profile and surface plot analysis.\u0000\u0000\u0000Findings\u0000The fluorescence microscope image indicates that the fluorescence emission of nanocomposites depends on the type of fluorescent agent. The fluorescence intensity of nanofiber containing CQDs is more than nanofiber containing fluorescent dye. Various image-processing methods provide similar results for optical property of nanocomposites. Analyzing the LUT, the blue value of CQDs/PAN nanocomposite image was significantly higher than other nanocomposites. This was confirmed by other methods such as Fourier transform, color histogram and 3D topography of the electrospun nanofibers. According to analysis of colorimetric parameters, higher negative value of b* indicates bluer color for CQDs/PAN nanofibers than other nanocomposites. The obtained results indicate that the image-processing technique can be used to evaluate the optical property of fluorescent nanocomposite.\u0000\u0000\u0000Originality/value\u0000This study evaluates the optical properties of fluorescent nanocomposites by using image-processing techniques such as Fourier transform, color histogram, RGB profiles, LUT, surface plot and histogram analysis.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2022-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44561500","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-12-28DOI: 10.1108/prt-06-2021-0067
P. S, U. P., P. R
Purpose This study aims to the optimization using three factors and three-level parameters (sliding speed [rpm], sliding distance [m/s] and load [N]) of design matrix were adapted to Box–Behnken design using design expert v8.0 software. Based on the parameters, to develop the linear regression equation and to find the significant considerable wear process parameters based on output responses like wear loss (WL) and coefficient of friction (COF) value of polymer matrix composites (PMC) specimen of Acrylonitrile-butadiene-styrene (ABS)/cellulose composite (80 wt% of ABS and 20 wt% of cellulose). Design/methodology/approach The fabrication of the ABS/cellulose composite sample was carried out by the simple hands-on stir process method. As per the American Society for Testing and Materials G99 standard, the sample was made by the molding process. The wear analysis was made by multi tribotester TR25 machine and validated the developed model by using statistical software design expert v.8.0 and numerical tools like analysis of variance. The surface morphology [field emission scanning electron microscopy (FESEM) analysis] of the sample was also observed using the Quanta FEG-250 FESEM instrument. Findings The parameters like sliding speed, sliding distance and load are independently affected the COF value and WL of the 80% of ABS matrix and 20% cellulose reinforced composite material. The regression equations were generated by the coefficient of friction value and WL, which predicted the minimum WL of 80% of ABS matrix and 20% of cellulose reinforced composite material. The worn surface analysis result exposes the worn path and equal distribution of reinforcement and matrix on the surface of composite material. Originality/value The literature survey revealed a small number of studies available regarding wear analysis of ABS matrix and cellulose reinforced composite materials. In the present work, to fabricate and evaluate the wear performance of PMC (80% of ABS and 20% of cellulose) depends on the WL and COF value. The maximum and minimum COF value (µ) of 80% of ABS and 20% of cellulose composite material is 4.71 and 0.28 with the optimized wear process parameter by 1,000 mm of sliding distance, 0.25 (m/s) of sliding speed and 9 N of load.
{"title":"Optimization and analysis of dry sliding wear process parameters on cellulose reinforced ABS polymer composite material","authors":"P. S, U. P., P. R","doi":"10.1108/prt-06-2021-0067","DOIUrl":"https://doi.org/10.1108/prt-06-2021-0067","url":null,"abstract":"\u0000Purpose\u0000This study aims to the optimization using three factors and three-level parameters (sliding speed [rpm], sliding distance [m/s] and load [N]) of design matrix were adapted to Box–Behnken design using design expert v8.0 software. Based on the parameters, to develop the linear regression equation and to find the significant considerable wear process parameters based on output responses like wear loss (WL) and coefficient of friction (COF) value of polymer matrix composites (PMC) specimen of Acrylonitrile-butadiene-styrene (ABS)/cellulose composite (80 wt% of ABS and 20 wt% of cellulose).\u0000\u0000\u0000Design/methodology/approach\u0000The fabrication of the ABS/cellulose composite sample was carried out by the simple hands-on stir process method. As per the American Society for Testing and Materials G99 standard, the sample was made by the molding process. The wear analysis was made by multi tribotester TR25 machine and validated the developed model by using statistical software design expert v.8.0 and numerical tools like analysis of variance. The surface morphology [field emission scanning electron microscopy (FESEM) analysis] of the sample was also observed using the Quanta FEG-250 FESEM instrument.\u0000\u0000\u0000Findings\u0000The parameters like sliding speed, sliding distance and load are independently affected the COF value and WL of the 80% of ABS matrix and 20% cellulose reinforced composite material. The regression equations were generated by the coefficient of friction value and WL, which predicted the minimum WL of 80% of ABS matrix and 20% of cellulose reinforced composite material. The worn surface analysis result exposes the worn path and equal distribution of reinforcement and matrix on the surface of composite material.\u0000\u0000\u0000Originality/value\u0000The literature survey revealed a small number of studies available regarding wear analysis of ABS matrix and cellulose reinforced composite materials. In the present work, to fabricate and evaluate the wear performance of PMC (80% of ABS and 20% of cellulose) depends on the WL and COF value. The maximum and minimum COF value (µ) of 80% of ABS and 20% of cellulose composite material is 4.71 and 0.28 with the optimized wear process parameter by 1,000 mm of sliding distance, 0.25 (m/s) of sliding speed and 9 N of load.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2021-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46986455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-12-17DOI: 10.1108/prt-09-2021-0110
Farhana Naeem, Fareha Asim, M. Tufail
Purpose Cellulosic fabric and plain weave are the most commonly used material in home textiles. The poor wrinkling, dimensional stability and pilling are some of the problems faced during usage. The textile industries apply resin finish to improve these characteristics. The purpose of this study is to improve pilling resistance, dimensional stability and smoothness appearance (SA) of rayon and rayon/cotton plain fabrics using different concentrations of dimethyloldihydroxyethylene urea (DMDHEU) and acrylic copolymer. The finish was fixed using two different fixation methods. Design/methodology/approach Three concentrations, 40, 100 and 150 g/l of Arkofix NF (DMDHE based) and Appretan N9211 (acrylic copolymer), were taken. The finish was applied at normal and shock cure. The effects of finish on pilling resistance, dimensional stability, smoothness, tear strength, light fastness, Berger whiteness and yellowness index of plain fabrics were investigated. Findings The changes in the characteristics of the finished fabrics were compared with unfinished fabrics. This study revealed that at 40 g/l of Arkofix NF and Appretan N9211 using a normal cure would improve the pilling resistance, dimensional stability and SA of the plain fabrics. Whereas, there was no adverse effect observed on tear strength, light fastness, Berger whiteness and yellowness index of plain fabrics at these conditions. Originality/value Unlike the previous studies, this paper proposed the single finish formulation where the functional characteristics of the plain rayon and rayon cotton fabrics meet the general requirement of a customer.
{"title":"Investigation into the effect of resin finish on the functional characteristics of plain fabrics using different curing methods","authors":"Farhana Naeem, Fareha Asim, M. Tufail","doi":"10.1108/prt-09-2021-0110","DOIUrl":"https://doi.org/10.1108/prt-09-2021-0110","url":null,"abstract":"\u0000Purpose\u0000Cellulosic fabric and plain weave are the most commonly used material in home textiles. The poor wrinkling, dimensional stability and pilling are some of the problems faced during usage. The textile industries apply resin finish to improve these characteristics. The purpose of this study is to improve pilling resistance, dimensional stability and smoothness appearance (SA) of rayon and rayon/cotton plain fabrics using different concentrations of dimethyloldihydroxyethylene urea (DMDHEU) and acrylic copolymer. The finish was fixed using two different fixation methods.\u0000\u0000\u0000Design/methodology/approach\u0000Three concentrations, 40, 100 and 150 g/l of Arkofix NF (DMDHE based) and Appretan N9211 (acrylic copolymer), were taken. The finish was applied at normal and shock cure. The effects of finish on pilling resistance, dimensional stability, smoothness, tear strength, light fastness, Berger whiteness and yellowness index of plain fabrics were investigated.\u0000\u0000\u0000Findings\u0000The changes in the characteristics of the finished fabrics were compared with unfinished fabrics. This study revealed that at 40 g/l of Arkofix NF and Appretan N9211 using a normal cure would improve the pilling resistance, dimensional stability and SA of the plain fabrics. Whereas, there was no adverse effect observed on tear strength, light fastness, Berger whiteness and yellowness index of plain fabrics at these conditions.\u0000\u0000\u0000Originality/value\u0000Unlike the previous studies, this paper proposed the single finish formulation where the functional characteristics of the plain rayon and rayon cotton fabrics meet the general requirement of a customer.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2021-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41713957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-12-16DOI: 10.1108/prt-09-2021-0104
N. Rozik, Emad S. Shafik, S. Abd-El-Messieh
Purpose This study aims to polymerize of 1-butyl-3-vinylimidazolium bromide (PIL). PIL was embedded into PVA with a different content ratio by casting method. This research also deals with the effect of adding PIL in different proportions to PVA on the electrical and mechanical properties properties in addition to the morphology of the prepared samples. Design/methodology/approach 1-Butyl-3-vinylimidazolium bromide was synthesized through quaternization and free radical polymerization. The resulting polymer was characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis and differential scanning calorimetry. In addition to the morphology of PVA, PVA/PIL was investigated by polarizing microscope. Also, the effect of PIL content on the electrical and mechanical properties was evaluated. Findings The findings of this study might lead to new applications for PVA and PILs in electrical and dielectrics. The mechanical results revealed that the tensile strength increased slightly with increasing polyionic liquid (PIL) content and decreased above 10% PIL. While the elongation at break increased significantly with increasing PIL content and begin to decrease above 10% PIL. Also, the electrical property of the poly(vinyl alcohol) (PVA)/PIL blends was improved because of the strong plasticizing effect of PIL. Also, the electrical conductivity of these polymer electrolytes is greatly increased. This indicates that the imidazolium-based PIL has an effective approach that leads to an increase in the conductivity of the polymer. The PILs/PVA design will not only enrich the chemical structure but also will contribute to green manufacturing techniques and a processing methodology that enables green membrane manufacture. Originality/value This study contributes to green manufacturing techniques and a processing methodology that enables “green” membrane manufacture.
{"title":"Physical and mechanical investigation for polyionic liquid/poly(vinyl alcohol) blends","authors":"N. Rozik, Emad S. Shafik, S. Abd-El-Messieh","doi":"10.1108/prt-09-2021-0104","DOIUrl":"https://doi.org/10.1108/prt-09-2021-0104","url":null,"abstract":"\u0000Purpose\u0000This study aims to polymerize of 1-butyl-3-vinylimidazolium bromide (PIL). PIL was embedded into PVA with a different content ratio by casting method. This research also deals with the effect of adding PIL in different proportions to PVA on the electrical and mechanical properties properties in addition to the morphology of the prepared samples.\u0000\u0000\u0000Design/methodology/approach\u00001-Butyl-3-vinylimidazolium bromide was synthesized through quaternization and free radical polymerization. The resulting polymer was characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis and differential scanning calorimetry. In addition to the morphology of PVA, PVA/PIL was investigated by polarizing microscope. Also, the effect of PIL content on the electrical and mechanical properties was evaluated.\u0000\u0000\u0000Findings\u0000The findings of this study might lead to new applications for PVA and PILs in electrical and dielectrics. The mechanical results revealed that the tensile strength increased slightly with increasing polyionic liquid (PIL) content and decreased above 10% PIL. While the elongation at break increased significantly with increasing PIL content and begin to decrease above 10% PIL. Also, the electrical property of the poly(vinyl alcohol) (PVA)/PIL blends was improved because of the strong plasticizing effect of PIL. Also, the electrical conductivity of these polymer electrolytes is greatly increased. This indicates that the imidazolium-based PIL has an effective approach that leads to an increase in the conductivity of the polymer. The PILs/PVA design will not only enrich the chemical structure but also will contribute to green manufacturing techniques and a processing methodology that enables green membrane manufacture.\u0000\u0000\u0000Originality/value\u0000This study contributes to green manufacturing techniques and a processing methodology that enables “green” membrane manufacture.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2021-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44082741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-12-15DOI: 10.1108/prt-12-2020-0126
N. M. Ahmed, E. Mossalam, B. El-Sabbagh, E. M. Souaya
Purpose This study aims to evaluate the effect of pH on the reinforced concrete steel protection for rebars coated with paint formulations containing talc and free from it. As the presence of talc in paints can offer high pH which cordially affects the protection behavior of the coated rebars. Additionally, this study includes evaluating the durability of concrete mixes in presence of some replacements of ordinary cement such as meta-kaolin (MK) and ground granulated blast furnace slag (GGBFS). Design/methodology/approach Two paint formulations were prepared containing the same ingredients except that (P1) is free from talc and (P2) contains talc. The anticorrosive behavior of painted steel in the blended concrete mixes containing MK and GGBFS was studied by using different electrochemical techniques in chloride solution. The concrete durability was evaluated by the means of compressive and bond strength beside chloride permeability. Different concrete mixes containing mineral groups or pozzolanic materials were prepared by replacing (10, and 30%) GGBFS and (5, 10 and 15%) MK as binary from cement CEM I with (w/b) 0.45 with superplasticizer ratio (SP) 2% of the binder Findings It was found that the presence of talc, in spite of its ability to offer high pH, has affected positively the corrosion behavior of reinforced concrete steel by forming a complex with concrete even if it is present in paint formulation and not free in the medium. Originality/value The results revealed that concrete blended with (30% GGBFS and 10% MK) with coated rebars with P2 containing talc showed the highest corrosion protection performance in addition to modified permeability and compression resistance.
{"title":"Evaluation of synergic methods for corrosion protection of reinforced steel","authors":"N. M. Ahmed, E. Mossalam, B. El-Sabbagh, E. M. Souaya","doi":"10.1108/prt-12-2020-0126","DOIUrl":"https://doi.org/10.1108/prt-12-2020-0126","url":null,"abstract":"\u0000Purpose\u0000This study aims to evaluate the effect of pH on the reinforced concrete steel protection for rebars coated with paint formulations containing talc and free from it. As the presence of talc in paints can offer high pH which cordially affects the protection behavior of the coated rebars. Additionally, this study includes evaluating the durability of concrete mixes in presence of some replacements of ordinary cement such as meta-kaolin (MK) and ground granulated blast furnace slag (GGBFS).\u0000\u0000\u0000Design/methodology/approach\u0000Two paint formulations were prepared containing the same ingredients except that (P1) is free from talc and (P2) contains talc. The anticorrosive behavior of painted steel in the blended concrete mixes containing MK and GGBFS was studied by using different electrochemical techniques in chloride solution. The concrete durability was evaluated by the means of compressive and bond strength beside chloride permeability. Different concrete mixes containing mineral groups or pozzolanic materials were prepared by replacing (10, and 30%) GGBFS and (5, 10 and 15%) MK as binary from cement CEM I with (w/b) 0.45 with superplasticizer ratio (SP) 2% of the binder\u0000\u0000\u0000Findings\u0000It was found that the presence of talc, in spite of its ability to offer high pH, has affected positively the corrosion behavior of reinforced concrete steel by forming a complex with concrete even if it is present in paint formulation and not free in the medium.\u0000\u0000\u0000Originality/value\u0000The results revealed that concrete blended with (30% GGBFS and 10% MK) with coated rebars with P2 containing talc showed the highest corrosion protection performance in addition to modified permeability and compression resistance.\u0000","PeriodicalId":20214,"journal":{"name":"Pigment & Resin Technology","volume":" ","pages":""},"PeriodicalIF":1.4,"publicationDate":"2021-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47356441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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