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Extraction and characterization of natural dye from leaves of Lannea coromandelica and application on cotton fabric 从 Lannea coromandelica 叶子中提取天然染料并将其应用于棉织物的研究
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-04-05 DOI: 10.1108/prt-08-2023-0074
K.G. Rumesh Samarawickrama, U.G. Samudrika Wijayapala, C.A. Nandana Fernando

Purpose

The purpose of this study is to extract and characterize a novel natural dye from the leaves of Lannea coromandelica and the extraction with finding ways of dyeing cotton fabric using three mordants.

Design/methodology/approach

The colouring agents were extracted from the leaves of Lannea coromandelica using an aqueous extraction method. The extract was characterized using analysis methods of pH, gas chromatography-mass spectrometry (GC-MS), Fourier transform infrared (FTIR), ultraviolet-visible (UV-vis) and cyclic voltammetry measurement. The extract was applied to cotton fabric samples using a non-mordant and three mordants under the two mordanting methods. The dyeing performance of the extracted colouring agent was evaluated using colour fastness properties, colour strength (K/S) and colour space (CIE Lab).

Findings

The aqueous dye extract showed reddish-brown colour, and its pH was 5.94. The GC-MS analysis revealed that the dye extract from the leaves of Lannea coromandelica contained active chemical compounds. The UV-vis and FTIR analyses found that groups influenced the reddish-brown colour of the dye extraction. The cyclic voltammetry measurements discovered the electrochemical properties of the dye extraction. The mordanted fabric samples showed better colour fastness properties than the non-mordanted fabric sample. The K/S and CIE Lab results indicate that the cotton fabric samples dyed with mordants showed more significant dye affinities than non-mordanted fabric samples.

Originality/value

Researchers have never discovered that the Lannea coromandelica leaf extract is a natural dye for cotton fabric dyeing. The findings of this study showed that natural dyes extracted from Lannea coromandelica leaf could be an efficient colouring agent for use in cotton fabric.

本研究的目的是从 Lannea coromandelica 的叶子中提取一种新型天然染料并对其进行表征,同时寻找使用三种媒染剂对棉织物进行染色的方法。采用 pH 值、气相色谱-质谱(GC-MS)、傅立叶变换红外(FTIR)、紫外-可见光(UV-VIS)和循环伏安法测量等分析方法对提取物进行表征。在两种媒染方法下,分别使用一种非媒染剂和三种媒染剂将提取物用于棉织物样品。使用色牢度、色强(K/S)和色空间(CIE Lab)对提取的染色剂的染色性能进行了评估。气相色谱-质谱分析表明,Lannea coromandelica 叶子的染料提取物含有活性化合物。紫外-可见光和傅立叶变换红外光谱分析发现,基团影响了染料提取物的红棕色。循环伏安法测量发现了染料提取物的电化学特性。与未添加媒染剂的织物样品相比,添加媒染剂的织物样品具有更好的色牢度特性。K/S 和 CIE 实验室结果表明,使用媒染剂染色的棉织物样品比未使用媒染剂的织物样品显示出更明显的染料亲和性。这项研究结果表明,从灯盏花叶中提取的天然染料可以作为一种有效的染色剂用于棉织物。
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引用次数: 0
Improving damping characteristics of epoxy by adding copper alloy wastes 通过添加铜合金废料改善环氧树脂的阻尼特性
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-03-26 DOI: 10.1108/prt-10-2023-0095
Payman Sahbah Ahmed, Ava A.K. Mohammed, Fakhir Aziz Rasul Rozhbiany

Purpose

The purpose of this study is to get benefits from manufacturing harmful wastes is by using them as a reinforcement with epoxy matrix composite materials to improve the damping characteristics in applications such as machine bases, rockets, satellites, missiles, navigation equipment and aircraft as large structures, and electronics as such small structures. Vibration causes damaging strains in these components.

Design/methodology/approach

By adding machining chips with weight percentages of 5, 10, 15 and 20 Wt.%, with three different chip lengths added for each percentage (0.6, 0.8 and 1.18 mm), the three-point bending and damping characteristics tests are utilized to examine how manufacturing waste impacts the mechanical properties. Following that, the optimal lengths and the chip-to-epoxy ratio are determined. The chip dispersion and homogeneity are assessed using a field emission scanning electron microscope.

Findings

Waste copper alloys can be used to enhance the vibration-dampening properties of epoxy resin. The interface and bonding between the resin and the chip are crucial for enhancing the damping capabilities of epoxy. Controlling the flexural modulus by altering the chip size and quantity can change the damping characteristics because the two variables are inversely related. The critical chip size is 0.8 mm, below which smaller chips cannot evenly transfer, and disperse the vibration force to the epoxy matrix and larger chips may shatter and fracture.

Originality/value

The main source of problems in machine tools, aircraft and vehicle manufacturing is vibrations generated in the structures. These components suffer harmful strains due to vibration. Damping can be added to these structures to get over these problems. The distribution of energy stored as a result of oscillatory mobility is known as damping. To optimize the serving lifetime of a dynamic suit, this is one of the most important design elements. The use of composites in construction is a modern method of improving a structure's damping capacity. Additionally, it has been demonstrated that composites offer better stiffness, strength, fatigue resistance and corrosion resistance. This research aims to reduce the vibration effect by using copper alloy wastes as dampers.

目的本研究的目的是从生产过程中产生的有害废料中获益,将其用作环氧基复合材料的增强材料,以提高其在机器底座、火箭、卫星、导弹、导航设备和飞机等大型结构以及电子设备等小型结构中的阻尼特性。设计/方法/途径通过添加重量百分比为 5、10、15 和 20 Wt.%、每种百分比添加三种不同长度(0.6、0.8 和 1.18 毫米)的加工芯片,利用三点弯曲和阻尼特性测试来检验制造废料对机械特性的影响。然后,确定最佳长度和切屑与环氧树脂的比例。研究结果废铜合金可用于增强环氧树脂的减震性能。树脂与芯片之间的界面和结合对于增强环氧树脂的减振能力至关重要。通过改变芯片尺寸和数量来控制弯曲模量可以改变阻尼特性,因为这两个变量成反比关系。临界芯片尺寸为 0.8 毫米,小于此尺寸的芯片无法将振动力均匀地传递和分散到环氧基体中,而较大的芯片可能会破碎和断裂。这些部件会因振动而产生有害应变。为了解决这些问题,可以在这些结构中加入阻尼。由于振荡移动而存储的能量分布被称为阻尼。为了优化动力服的使用寿命,阻尼是最重要的设计元素之一。在建筑中使用复合材料是提高结构阻尼能力的现代方法。此外,复合材料还具有更好的刚度、强度、抗疲劳性和耐腐蚀性。本研究旨在利用铜合金废料作为阻尼器来降低振动效应。
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引用次数: 0
Consolidation materials used with illuminated and non-illuminated paper manuscripts and historical leather bindings: a review 带照明和不带照明纸质手稿及历史性皮革装订使用的加固材料:综述
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-03-25 DOI: 10.1108/prt-10-2023-0093
Mostafa Abdel-Hamied, Ahmed A.M. Abdelhafez, Gomaa Abdel-Maksoud

Purpose

This study aims to focus on the main materials used in consolidation processes of illuminated paper manuscripts and leather binding.

Design/methodology/approach

For each material, chemical structure, chemical composition, molecular formula, solubility, advantages, disadvantages and its role in treatment process are presented.

Findings

This study concluded that carboxy methyl cellulose, hydroxy propyl cellulose, methyl cellulose, cellulose acetate, nanocrystalline cellulose, funori, sturgeon glue, poly vinyl alcohol, chitosan, chitosan nanoparticles (NPs), gelatin, aquazol, paraloid B72 and hydroxyapatite NPs were the most common and important materials used for the consolidation of illuminated paper manuscripts. For the leather bindings, hydroxy propyl cellulose, polyethylene glycol, oligomeric melamine-formaldehyde resin, acrylic wax SC6000, pliantex, paraloid B67 and B72, silicone oil and collagen NPs are the most consolidants used.

Originality/value

Illuminated paper manuscripts with leather binding are considered one of the most important objects in libraries, museums and storehouses. The uncontrolled conditions and other deterioration factors inside the libraries and storehouses lead to degradation of these artifacts. The brittleness, fragility and weakness are considered the most common deterioration aspects of illuminated paper manuscripts and leather binding. Therefore, the consolidation process became vital and important to solve this problem. This study presents the main materials used for consolidation process of illuminated paper manuscripts and leather bindings.

设计/方法/途径针对每种材料,介绍其化学结构、化学成分、分子式、溶解度、优缺点及其在处理过程中的作用。研究结果这项研究得出结论,羧甲基纤维素、羟丙基纤维素、甲基纤维素、醋酸纤维素、纳米结晶纤维素、Funori、鲟鱼胶、聚乙烯醇、壳聚糖、壳聚糖纳米颗粒 (NPs)、明胶、水杨酚、paraloid B72 和羟基磷灰石 NPs 是用于加固纸质手稿的最常见和最重要的材料。在皮革装订方面,羟丙基纤维素、聚乙二醇、低聚三聚氰胺甲醛树脂、丙烯酸蜡 SC6000、pliantex、paraloid B67 和 B72、硅油和胶原蛋白 NPs 是使用最多的固化剂。图书馆和仓库内的不可控条件和其他劣化因素导致了这些文物的退化。脆性、易碎性和薄弱性被认为是纸质手稿和皮革装订最常见的老化问题。因此,加固工艺对解决这一问题至关重要。本研究介绍了用于加固纸质手稿和皮革装订的主要材料。
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引用次数: 0
Sodium and potassium ferrocyanide derived Prussian blue pigment 铁氰化钠和铁氰化钾衍生普鲁士蓝颜料
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-03-20 DOI: 10.1108/prt-10-2023-0087
Malav R. Sanghvi, Karan W. Chugh, S.T. Mhaske

Purpose

This study aims to synthesize Prussian blue {FeIII4[FeII(CN)6]3} pigment by reacting ferric chloride with different ferrocyanides through the same procedure. The influence of the ferrocyanide used on resulting pigment properties is studied.

Design/methodology/approach

Prussian blue is commonly synthesized by direct or indirect methods, through iron salt and ferrocyanide/ferricyanide reactions. In this study, the direct, single-step process was pursued by dropwise addition of the ferrocyanide into ferric chloride (both as aqueous solutions). Two batches – (K-PB) and (Na-PB) – were prepared by using potassium ferrocyanide and sodium ferrocyanide, respectively. The development of pigment was confirmed by an identification test and characterized by spectroscopic techniques. Pigment properties were determined, and light fastness was observed for acrylic emulsion films incorporating dispersed pigment.

Findings

The two pigments differed mainly in elemental detection owing to the dissimilar ferrocyanide being used; IR spectroscopy where only (Na-PB) showed peaks indicating water molecules; and bleeding tendency where (K-PB) was water soluble whereas (Na-PB) was not. The pigment exhibited remarkable blue colour and good bleeding resistance in several solvents and showed no fading in 24 h of light exposure though oil absorption values were high.

Originality/value

This article is a comparative study of Prussian blue pigment properties obtained using different ferrocyanides. The dissimilarity in the extent of water solubility will influence potential applications as a colourant in paints and inks. K-PB would be advantageous in aqueous formulations to confer a blue colour without any dispersing aid but unfavourable in systems where other coats are water-based due to their bleeding tendency.

目的 本研究旨在通过相同的程序使氯化铁与不同的铁氰化物反应,合成普鲁士蓝{FeIII4[FeII(CN)6]3}颜料。普鲁士蓝通常通过铁盐和亚铁氰化物/铁氰化物反应以直接或间接方法合成。在本研究中,采用的是单步直接法,即将亚铁氰化物滴加到氯化铁中(两者均为水溶液)。分别使用亚铁氰化钾和亚铁氰化钠制备了两批产品--(K-PB) 和 (Na-PB)。颜料的形成通过鉴别试验进行确认,并通过光谱技术进行表征。研究结果这两种颜料主要在元素检测方面存在差异,原因是使用了不同的亚铁氰化钾;红外光谱方面,只有(Na-PB)出现了表示水分子的峰值;出血倾向方面,(K-PB)可溶于水,而(Na-PB)不溶于水。该颜料在几种溶剂中都呈现出明显的蓝色和良好的抗渗色性,虽然吸油值较高,但在光照 24 小时后仍未褪色。水溶性的差异将影响普鲁士蓝作为着色剂在涂料和油墨中的潜在应用。K-PB 在水性配方中无需任何分散助剂即可呈现蓝色,这一点非常有利,但在其他涂层为水性的体系中,由于其渗色倾向,这一点则非常不利。
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引用次数: 0
Harnessing of carboxy containing starch nanoparticles as an adsorbent for Cd (II) ions and methylene blue from waste water effluent: synthesis, metrological characterization and properties 利用含羧基的淀粉纳米颗粒作为废水中镉 (II) 离子和亚甲基蓝的吸附剂:合成、计量表征和特性
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-03-01 DOI: 10.1108/prt-12-2023-0113
Khaled Mostafa, Azza El-Sanabary

Purpose

The novelty addressed here is undertaken by using tailor-made and fully characterized starch nanoparticles (SNPs) having a particle size ranging from 80 to 100 nm with a larger surface area, biodegradability and high reactivity as a starting substrate for cadmium ions and basic dye removal from wastewater effluent. This was done via carboxylation of SNPs with citric acid via esterification reaction using the dry preparation technique, in which a simple, energy-safe and sustainable process concerning a small amount of water, energy and toxic chemicals was used. The obtained adsorbent is designated as cross-linked esterified starch nanoparticles (CESNPs).

Design/methodology/approach

The batch technique was used to determine the CESNPs adsorption capacity, whereas atomic adsorption spectrometry was used to determine the residual cadmium ions concentration in the filtrate before and after adsorption. Different factors affecting adsorption were examined concerning pH, contact time, adsorbent dose and degree of carboxylation. Besides, to validate the esterification reaction and existence of carboxylic groups in the adsorbent, CESNPs were characterized metrologically via analytical tools for carboxyl content estimation and instrumental tools using Fourier-transform infrared spectroscopy (FTIR) spectra and scanning electron microscopy (SEM) morphological analysis.

Findings

The overall adsorption potential of CESNPs was found to be 136 mg/g when a 0.1 g adsorbent dose having 190.8 meq/100 g sample carboxyl content at pH 5 for 60 min contact time was used. Besides, increasing the degree of carboxylation of the CESNPs expressed as carboxyl content would lead to the higher adsorption capacity of cadmium ions. FTIR spectroscopy analysis elucidates the esterification reaction with the appearance of a new intense peak C=O ester at 1,700 cm−1, whereas SEM observations reveal some atomic/molecules disorder after esterification.

Originality/value

The innovation addressed here is undertaken by studying the consequence of altering the extent of carboxylation reaction expressed as carboxyl contents on the prepared CESNPs via a simple dry technique with a small amount of water, energy and toxic chemicals that were used as a sustainable bio nano polymer for cadmium ions and basic dye removal from wastewater effluent in comparison with other counterparts published in the literature.

目的 本文的新颖之处在于使用了量身定制的、具有全面特征的淀粉纳米颗粒(SNPs),其粒径在 80 到 100 nm 之间,具有较大的比表面积、生物降解性和高反应活性,可作为去除废水中镉离子和碱性染料的起始底物。该方法采用干法制备技术,通过酯化反应使 SNP 与柠檬酸发生羧化反应,过程简单、能源安全且可持续,只需少量的水、能源和有毒化学品。设计/方法/步骤采用批次法测定 CESNPs 的吸附容量,并采用原子吸附光谱法测定吸附前后滤液中的残余镉离子浓度。研究了影响吸附的不同因素,包括 pH 值、接触时间、吸附剂剂量和羧化程度。此外,为了验证酯化反应和吸附剂中羧基的存在,还通过羧基含量估算分析工具和傅立叶变换红外光谱(FTIR)光谱及扫描电子显微镜(SEM)形态分析仪器对 CESNPs 进行了计量学表征。研究结果发现,在 pH 值为 5、接触时间为 60 分钟、吸附剂剂量为 0.1 g、羧基含量为 190.8 meq/100 g 样品的条件下,CESNPs 的总体吸附潜力为 136 mg/g。此外,以羧基含量表示的 CESNPs 羧基化程度越高,对镉离子的吸附容量就越大。傅立叶变换红外光谱分析阐明了酯化反应,在 1,700 cm-1 处出现了一个新的 C=O 酯强峰,而扫描电镜观察显示酯化后出现了一些原子/分子紊乱。与文献中发表的其他同类研究相比,本文的创新之处在于研究了改变羧化反应程度(以羧基含量表示)对通过简单干燥技术制备的 CESNPs 的影响,只需少量的水、能源和有毒化学品,即可将其用作可持续生物纳米聚合物,用于去除废水中的镉离子和碱性染料。
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引用次数: 0
Designing an optimised formulation for in situ emulsion polymerization: printing ink production by response surface methodology 通过响应面方法设计原位乳液聚合的优化配方:印刷油墨生产
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-02-21 DOI: 10.1108/prt-10-2023-0091
Bahareh Babaie, Mohsen Najafi, Maryam Ataeefard

Purpose

Toner is a crucial dry colorant composite used in printing based on the electrophotographic process. The quality of printed images is greatly influenced by the toner production method and material formulation. Chemically in situ polymerization methods are currently preferred. This paper aims to optimize the characteristics of a composite produced through emulsion polymerization using common raw materials for electrophotographic toner production.

Design/methodology/approach

Emulsion polymerization provides the possibility to optimize the physical and color properties of the final products. Response surface methodology (RSM) was used to optimize variables affecting particle size (PS), PS distribution (PSD), glass transition temperature (Tg°C), color properties (ΔE) and monomer conversion. Box–Behnken experimental design with three levels of styrene and butyl acrylate monomer ratios, carbon black pigment and sodium dodecyl sulfate surfactant was used for RSM optimization. Additionally, thermogravimetric analysis and surface morphology of composite particles were examined.

Findings

The results indicated that colorants with small PS, narrow PSDs, spherical shape morphology, acceptable thermal and color properties and a high percentage of conversion could be easily prepared by optimization of material parameters in this method. The anticipated outcome of the present inquiry holds promise as a guiding beacon toward the realization of electrographic toner of superior quality and exceptional efficacy, a vital factor for streamlined mass production.

Originality/value

To the best of the authors’ knowledge, for the first time, material parameters were evaluated to determine their impact on the characteristics of emulsion polymerized toner composites.

用途 墨粉是一种重要的干性复合着色剂,用于基于电子照相工艺的印刷。墨粉的生产方法和材料配方对印刷图像的质量影响很大。化学原位聚合方法是目前的首选。设计/方法/途径乳液聚合为优化最终产品的物理和颜色特性提供了可能。采用响应面方法(RSM)对影响粒度(PS)、PS 分布(PSD)、玻璃化温度(Tg°C)、颜色特性(ΔE)和单体转化率的变量进行了优化。在 RSM 优化中采用了箱式贝肯实验设计,将苯乙烯和丙烯酸丁酯单体比率、炭黑颜料和十二烷基硫酸钠表面活性剂分为三个等级。研究结果表明,通过优化该方法的材料参数,可以轻松制备出 PS 小、PSD 窄、形态为球形、热性能和颜色性能均可接受且转化率高的着色剂。据作者所知,这是首次对材料参数进行评估,以确定它们对乳液聚合墨粉复合材料特性的影响。
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引用次数: 0
Investigation of the effects of self-crosslinking acrylate with TiO2 nanoparticles on cotton denim fabrics 研究自交联丙烯酸酯与 TiO2 纳米粒子对纯棉牛仔面料的影响
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-02-19 DOI: 10.1108/prt-11-2023-0109
Sabiha Sezgin Bozok

Purpose

Titanium(IV) oxide nanoparticles (TiO2 NP) were deposited to cotton denim fabrics using a self-crosslinking acrylate – a polymer dispersion to extend the lifetime of the products. This study aims to determine the optimum conditions to increase abrasion resistance, to provide self-cleaning properties of denim fabrics and to examine the effects of these applications on other physical properties.

Design/methodology/approach

The denim samples were first treated with nonionic surfactant to increase their wettability. Three different amounts of the polymer dispersion and two different pH levels were selected for the experimental design. The finishing process was applied to the fabrics with pad-dry-cure method.

Findings

The presence of the coatings and the adhesion of TiO2 NPs to the surfaces were confirmed by scanning electron microscope and Fourier transform infrared spectroscopy analysis. It was ascertained that the most appropriate self-crosslinking acrylate amount and ambient pH level is 10 mL and “2”, respectively, for providing increased abrasion resistance (2,78%) and enhanced self-cleaning properties (363,4%) in the denim samples. The coating reduced the air permeability and softness of the denim samples. Differential scanning calorimetry and thermogravimetry analysis results showed that the treatments increased the crystallization temperatures and melting enthalpy values of the denim samples. Based on the thermal test results, it is clear that mass loss of the denim samples at 370°C decreased as the amount of self-crosslinking acrylate increased (at pH 3).

Originality/value

This study helped us to find out optimum amount of self-crosslinking acrylate and proper pH level for enhanced self-cleaning and abrasion strength on denim fabrics. With this finishing process, an environmentally friendly and long-life denim fabric was designed.

目的使用自交联丙烯酸酯-聚合物分散体将氧化钛(IV)纳米粒子(TiO2 NP)沉积到纯棉牛仔面料上,以延长产品的使用寿命。本研究旨在确定提高耐磨性的最佳条件,使牛仔布具有自清洁特性,并研究这些应用对其他物理性质的影响。设计/方法/途径首先用非离子表面活性剂处理牛仔布样品,以提高其润湿性。实验设计选择了三种不同量的聚合物分散体和两种不同的 pH 值。实验结果通过扫描电子显微镜和傅里叶变换红外光谱分析证实了涂层的存在以及 TiO2 NPs 在表面上的附着力。结果表明,最合适的自交联丙烯酸酯用量和环境 pH 值分别为 10 mL 和 "2",可提高牛仔布样品的耐磨性(2.78%)和自洁性(363.4%)。涂层降低了牛仔布样品的透气性和柔软度。差示扫描量热法和热重分析结果表明,涂层处理提高了牛仔布样品的结晶温度和熔焓值。根据热测试结果,很明显,随着自交联丙烯酸酯用量的增加(pH 值为 3 时),牛仔布样品在 370°C 时的质量损失减少了。通过这种整理工艺,我们设计出了一种环保型长寿命牛仔面料。
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引用次数: 0
Green encapsulation of textile dyes using lecithin to increase dyeing performance 利用卵磷脂对纺织染料进行绿色封装以提高染色性能
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-02-19 DOI: 10.1108/prt-10-2023-0094
Shimaa S.M. Elhadad, Hany Kafafy, Hamada Mashaly, Ahmed Ali El-Sayed

Purpose

The purpose of this study is to use liposome technology in the treatment of fabrics textiles because of its efficient energy saving, reducing time and temperature.

Design/methodology/approach

The newly prepared lecithin liposome was used to encapsulate dyes for the purpose of increasing dyeing affinity. Different ratios of commercially available lecithin liposomes (1%, 3%, 5% and 7%) were used simultaneously in the dyeing of cotton and wool fabrics. The treated fabrics (cotton and wool fabrics) were confirmed using different analytical procedures such as scanning electron microscope (SEM), Fourier-transition infrared spectroscopy, ultraviolet protection factor, colour strength (K|S) measurements and fastness measurements.

Findings

The results show that increasing liposome ratios in dyeing baths leads to increased dyeing affinity for cotton and wool fabrics compared with conventional dyeing without using liposomes. In addition to that, the colour strength values, infrared spectra, SEM and fastness properties of non-liposome-dyed fabrics and liposome-dyed fabrics were investigated.

Originality/value

The research paper provides broad spectrum of green encapsulation fabrics using liposome technology to perform the dye stability, dye strength and fastness.

设计/方法/途径采用新制备的卵磷脂脂质体包裹染料,以提高染色亲和力。将不同比例的市售卵磷脂脂质体(1%、3%、5% 和 7%)同时用于棉织物和羊毛织物的染色。研究结果表明,与不使用脂质体的传统染色相比,染色浴中增加脂质体的比例可提高棉和羊毛织物的染色亲和力。此外,还研究了非脂质体染色织物和脂质体染色织物的色强值、红外光谱、扫描电镜和牢度特性。
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引用次数: 0
Use of carboxymethyl cellulose, Klucel G, gum Arabic and zinc oxide nanoparticles nanocomposite as strength agents for inked papyrus 使用羧甲基纤维素、Klucel G、阿拉伯树胶和氧化锌纳米颗粒纳米复合材料作为着墨纸莎草纸的强度剂
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-02-12 DOI: 10.1108/prt-12-2023-0123
Bataa Sayed Mohamed Mazen, Badawi Mohamed Ismail, Rushdya Rabee Ali Hassan, Mahmoud Ali, Wael S. Mohamed

Purpose

The purpose of this study is to detect the effect of some natural cellulosic polymers in their nano forms with the addition of zinc oxide nanoparticles on restoring the lost mechanical strength of degraded papyrus without any harmful effects on the inks.

Design/methodology/approach

In the current study, the USB digital microscopy, scanning electron microscope, measurement of mechanical properties (tensile and elongation), pH measurement, color change and infrared spectroscopy were undertaken for the samples before and after treatment and aging.

Findings

In the current study, the USB digital microscopy, scanning electron microscope, measurement of mechanical properties (tensile and elongation), pH measurement, color change and infrared spectroscopy were undertaken for the samples before and after treatment and aging.

Originality/value

The effect of strengthening materials was studied on cellulose and carbon ink, which makes this study closer to reality as the manuscript is the consistent structure of cellulose and inks, whereas most of the literature stated the impact of consolidation materials on the strengthening the cellulosic supports without attention to their impact on inks.

本研究的目的是在不对油墨造成任何有害影响的情况下,检测添加了纳米氧化锌的纳米级天然纤维素聚合物对恢复退化纸莎草纸失去的机械强度的影响。在本研究中,对处理和老化前后的样品进行了 USB 数字显微镜、扫描电子显微镜、机械性能(拉伸和伸长)测量、pH 值测量、颜色变化和红外光谱分析。研究结果在本研究中,对处理和老化前后的样品进行了 USB 数字显微镜、扫描电子显微镜、机械性能(拉伸和伸长)测量、pH 值测量、颜色变化和红外光谱分析。原创性/价值研究了增强材料对纤维素和碳油墨的影响,这使得本研究更贴近现实,因为手稿中的纤维素和油墨结构是一致的,而大多数文献只阐述了增强材料对纤维素支撑物的影响,却没有关注它们对油墨的影响。
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引用次数: 0
New insights into the role of color extraction from (Aegle Marmelos leaf) using a non-traditional heating source 利用非传统加热源萃取(Aegle Marmelos 叶片)色素的作用新见解
IF 1.4 4区 材料科学 Q3 Materials Science Pub Date : 2024-02-07 DOI: 10.1108/prt-05-2023-0041
Nancy Sobh, Nagla Elshemy, Sahar Nassar, Mona Ali

Purpose

Due to herbs and plants’ therapeutic properties and simplicity of availability in nature, humans have used them to treat a variety of maladies and diseases since ancient times. Later, as technology advanced, these plants and herbs gained significant relevance in some industries due to their suitable chemical composition, abundant availability and ease of access. Aegle marmelos is a species of plant that may be found in nature. Yet, little or very little literature was located on the coloration behavior of this plant’s leaves. This study aims to focus on the effect of different parameters on the extraction of colorant from Aegle marmelos leaves.

Design/methodology/approach

Some factors that affected on the extraction processes were examined and found to have significant impacts on the textile dyeing such as the initial dye concentration, extracted temperature, extracted bath pH and extracted time were all changed to see how they affected color extraction. The authors report a direct comparison between three heating methods, namely, microwave irradiation (MWI), ultrasonic waves (USW) and conventional heating (CH). The two kinetic models have been designed (pseudo-first and pseudo-second orders) in the context of these experiments to investigate the mechanism of the dyeing processes for fabrics under study. Also, the experimental data were analyzed according to the Langmuir and Freundlich isotherms.

Findings

From the result, it was discovered these characteristics were found to have a substantial effect on extraction efficiency. Temperature 90°C and 80°C when using CH and USW, respectively, while at 90% watt when using MWI, period 120 min when using CH as well as USW waves, while 40 min when using MWI, and pH 4, 5 and 10 for polyamide, wool and cotton, respectively, were the optimal extraction conditions. Also, the authors can say that wool gives a higher absorption than the other fabric. Additionally, MWI provided the best color strength (K/S) value, and homogeneity, at low temperatures reducing the energy and time consumed. The coloring follows the order: MWI > USW > CH. The adsorption isotherm of wool could be well fitted by Freundlich isotherm when applying CH and USW as a heating source, while it is well fitted by the Langmuir equation in the case of MWI. In the study, it was observed that the pseudo-first-order kinetic model fits better the experimental results of CH with a constant rate K1 = −0.000171417 mg/g.min, while the pseudo-second-order kinetic model fits better the experimental results of absorption of both MWI (K2 = 38.14022572 mg/g.min) and USW (K2 = 12.45343554 mg/g.min).

Research limitations/implications

There is no research limitation for this work. Dye was extracted from Aegle marmelos leaves by applying three different heating sources (MWI, ultrasonic waves [U

目的由于草药和植物的治疗特性以及在自然界中的简单易得性,人类自古以来就用它们来治疗各种弊病和疾病。后来,随着科技的发展,这些植物和草药因其合适的化学成分、丰富的可获得性和易获取性,在一些行业中获得了重要的相关性。Aegle marmelos 是一种可以在自然界中找到的植物。然而,有关这种植物叶片着色行为的文献却很少。设计/方法/途径对影响萃取过程的一些因素进行了研究,发现这些因素对纺织品染色有重大影响,如初始染料浓度、萃取温度、萃取浴 pH 值和萃取时间都发生了变化,以了解它们对颜色萃取的影响。作者报告了微波辐照(MWI)、超声波(USW)和传统加热(CH)这三种加热方法之间的直接比较。根据这些实验设计了两个动力学模型(伪一阶和伪二阶),以研究织物染色过程的机理。此外,实验数据还根据 Langmuir 和 Freundlich 等温线进行了分析。使用 CH 波和 USW 波时,温度分别为 90°C 和 80°C,而使用 MWI 波时,温度为 90%瓦;使用 CH 波和 USW 波时,时间为 120 分钟,而使用 MWI 波时,时间为 40 分钟;聚酰胺、羊毛和棉花的 pH 值分别为 4、5 和 10,这些都是最佳萃取条件。作者还认为,羊毛的吸收率高于其他织物。此外,在低温条件下,MWI 提供了最佳的着色力(K/S)值和均匀性,减少了能源和时间的消耗。着色顺序如下MWI > USW > CH。当使用 CH 和 USW 作为加热源时,羊毛的吸附等温线可以用 Freundlich 等温线很好地拟合,而使用 MWI 时则可以用 Langmuir 方程很好地拟合。研究发现,伪一阶动力学模型能更好地拟合 CH 的实验结果,恒定速率 K1 = -0.000171417 mg/g.min,而伪二阶动力学模型能更好地拟合 MWI(K2 = 38.14022572 mg/g.min)和 USW(K2 = 12.45343554 mg/g.min)的吸收实验结果。通过使用三种不同的加热源(MWI、超声波 [USWW] 和 CH),从 Aegle marmelos 叶子中提取了染料。社会影响在社会方面,由于提取的染料不含任何致癌物质,因此对生态系统和全球社会具有良好的影响。原创性/价值这项工作具有原创性,为纺织业和其他相关领域提供了增值产品。
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Pigment & Resin Technology
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