The research of copolymerization of ethylene with polar monomers catalyzed by group 4 metal complexes has gain substantial achievement, and the functional polyolefins, produced through the various structures of the catalysts and polar monomers, have already shown their unique applications in multiple fields. There are kinds of effective strategies to improve copolymerization activity and polar monomers incorporation: the structures of group 4 catalysts have been expanded from metallocenes to half-metallocenes and non-metallocenes; the new cocatalysts and catalytic systems have been developed; polar monomers are pretreated by masking agents; the functional groups of polar monomers have been largely enriched. In this review, the copolymerization of ethylene with polar monomers catalyzed by group 4 metal complexes are concluded and compared, and we are looking forward to summarizing the relationship between structure and reactivity of catalysts and providing advice for the design of catalysts. Moreover, the properties and potential applications of polar functionalized polyolefins are introduced.
{"title":"Copolymerization of Ethylene With Polar Monomers by Group 4 Catalysts","authors":"Qian Li, Zifang Guo, Xinwei Li, Jian Chen, Shuzhang Qu, Yiming Wei, Zhao Wen, Wei Wang","doi":"10.1080/15583724.2024.2444674","DOIUrl":"https://doi.org/10.1080/15583724.2024.2444674","url":null,"abstract":"The research of copolymerization of ethylene with polar monomers catalyzed by group 4 metal complexes has gain substantial achievement, and the functional polyolefins, produced through the various structures of the catalysts and polar monomers, have already shown their unique applications in multiple fields. There are kinds of effective strategies to improve copolymerization activity and polar monomers incorporation: the structures of group 4 catalysts have been expanded from metallocenes to half-metallocenes and non-metallocenes; the new cocatalysts and catalytic systems have been developed; polar monomers are pretreated by masking agents; the functional groups of polar monomers have been largely enriched. In this review, the copolymerization of ethylene with polar monomers catalyzed by group 4 metal complexes are concluded and compared, and we are looking forward to summarizing the relationship between structure and reactivity of catalysts and providing advice for the design of catalysts. Moreover, the properties and potential applications of polar functionalized polyolefins are introduced.","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"1 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142879781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-20DOI: 10.1080/15583724.2024.2406965
Jesús Molinar-Díaz, Andrew J. Parsons, Ifty Ahmed, Nicholas A. Warrior, Lee T. Harper
Polyetheretherketone (PEEK) is a lightweight, bioinert, high-performance thermoplastic that is beginning to see clinical use in orthopedic applications. PEEK outperforms conventional metallic counterparts in terms of reduced stress shielding and improved chemical resistance, making it highly suitable for implantable applications. However, despite its excellent mechanical properties, the elevated melting point (343 °C) presents significant challenges during manufacturing. Furthermore, PEEK requires surface modifications to enhance antibacterial, bioactive, and osseointegration properties suitable for in vivo applications. In this context, the present manuscript highlights current manufacturing challenges for implantable PEEK biomaterials and typical fiber reinforced PEEK composites. Emphasis is placed on reinforcements such as carbon fiber (CF), hydroxyapatite (HA) and titanium dioxide (TiO2), along with multi-material PEEK composites and their applications. Opportunities are identified to address these challenges, contributing toward the development of synergetic, multi-functional PEEK biomaterials suitable for long-term implantable applications.
{"title":"Poly-Ether-Ether-Ketone (PEEK) Biomaterials and Composites: Challenges, Progress, and Opportunities","authors":"Jesús Molinar-Díaz, Andrew J. Parsons, Ifty Ahmed, Nicholas A. Warrior, Lee T. Harper","doi":"10.1080/15583724.2024.2406965","DOIUrl":"https://doi.org/10.1080/15583724.2024.2406965","url":null,"abstract":"Polyetheretherketone (PEEK) is a lightweight, bioinert, high-performance thermoplastic that is beginning to see clinical use in orthopedic applications. PEEK outperforms conventional metallic counterparts in terms of reduced stress shielding and improved chemical resistance, making it highly suitable for implantable applications. However, despite its excellent mechanical properties, the elevated melting point (343 °C) presents significant challenges during manufacturing. Furthermore, PEEK requires surface modifications to enhance antibacterial, bioactive, and osseointegration properties suitable for <i>in vivo</i> applications. In this context, the present manuscript highlights current manufacturing challenges for implantable PEEK biomaterials and typical fiber reinforced PEEK composites. Emphasis is placed on reinforcements such as carbon fiber (CF), hydroxyapatite (HA) and titanium dioxide (TiO<sub>2</sub>), along with multi-material PEEK composites and their applications. Opportunities are identified to address these challenges, contributing toward the development of synergetic, multi-functional PEEK biomaterials suitable for long-term implantable applications.","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"22 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142329515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-19DOI: 10.1080/15583724.2024.2406973
Wenqi Wang, Shuang Guo, Fan Feng, Qianwen Li, Haojie Cai, Aline Rougier, Dongyun Ma, Jinmin Wang
Electrochromic devices (ECDs) have broad application prospects in smart windows, low-power displays, anti-glare rearview mirrors, and so on. The electrolyte layer is one of the crucial components of ECDs acting as an interface layer between two electrodes to provide ions transport. Conventional liquid electrolytes have disadvantages of easy leakage, low safety and complex encapsulation, while inorganic solid electrolytes (ISEs) have very poor room temperature conductivity. Polymer electrolytes are composites consisting of polymeric matrices, solvents, conductive salts and curing agents, including solid polymer electrolytes (SPEs), gel polymer electrolytes (GPEs) and composite polymer electrolytes (CPEs). They are widely used in ECDs because of their excellent ionic conductivity, superior electrochemical stability, high transparency and simplicity of processing. This review provides a detailed discussion of the types, mechanisms, characteristics and preparation methods of polymer electrolytes for ECDs. The latest research progresses in the design and application of CPEs based on poly(ethylene oxide) (PEO), poly(methyl methacrylate) (PMMA), poly(vinylidene fluoride) (PVDF) and poly(vinyl alcohol) (PVA) are highlighted, and the potential applications of polymer electrolytes in the field of electrochromism are reviewed. Furthermore, the future development of polymer electrolytes in ECDs with stability, significant coloration efficiency and high ionic conductivity is discussed.
{"title":"Research Progress in Polymer Electrolytes for Electrochromic Devices","authors":"Wenqi Wang, Shuang Guo, Fan Feng, Qianwen Li, Haojie Cai, Aline Rougier, Dongyun Ma, Jinmin Wang","doi":"10.1080/15583724.2024.2406973","DOIUrl":"https://doi.org/10.1080/15583724.2024.2406973","url":null,"abstract":"Electrochromic devices (ECDs) have broad application prospects in smart windows, low-power displays, anti-glare rearview mirrors, and so on. The electrolyte layer is one of the crucial components of ECDs acting as an interface layer between two electrodes to provide ions transport. Conventional liquid electrolytes have disadvantages of easy leakage, low safety and complex encapsulation, while inorganic solid electrolytes (ISEs) have very poor room temperature conductivity. Polymer electrolytes are composites consisting of polymeric matrices, solvents, conductive salts and curing agents, including solid polymer electrolytes (SPEs), gel polymer electrolytes (GPEs) and composite polymer electrolytes (CPEs). They are widely used in ECDs because of their excellent ionic conductivity, superior electrochemical stability, high transparency and simplicity of processing. This review provides a detailed discussion of the types, mechanisms, characteristics and preparation methods of polymer electrolytes for ECDs. The latest research progresses in the design and application of CPEs based on poly(ethylene oxide) (PEO), poly(methyl methacrylate) (PMMA), poly(vinylidene fluoride) (PVDF) and poly(vinyl alcohol) (PVA) are highlighted, and the potential applications of polymer electrolytes in the field of electrochromism are reviewed. Furthermore, the future development of polymer electrolytes in ECDs with stability, significant coloration efficiency and high ionic conductivity is discussed.","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"108 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142329511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-18DOI: 10.1080/15583724.2024.2400961
Abdelrahman Sakr, Abdallah Kamal, Liya Jacob, Rami Homsi, Haider Butt
Nanocomposite contact lenses (NCLs) have emerged as a promising advancement in the field of ophthalmic materials, combining the advantages of traditional contact lenses with the unique properties o...
{"title":"Comprehensive Review on the Synthesis, Properties and Applications of Nanocomposite Contact Lenses","authors":"Abdelrahman Sakr, Abdallah Kamal, Liya Jacob, Rami Homsi, Haider Butt","doi":"10.1080/15583724.2024.2400961","DOIUrl":"https://doi.org/10.1080/15583724.2024.2400961","url":null,"abstract":"Nanocomposite contact lenses (NCLs) have emerged as a promising advancement in the field of ophthalmic materials, combining the advantages of traditional contact lenses with the unique properties o...","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"35 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142245860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-10DOI: 10.1080/15583724.2024.2401992
Xiaoxiao Wang, Hui Li, Min Mu, Rui Ye, Lihua Zhou, Gang Guo
Oral diseases are a prevalent global issue, causing significant health and economic burdens that greatly diminish the quality of life for affected individuals. Tissue engineering strategies employi...
{"title":"Recent Development and Advances on Polysaccharide Composite Scaffolds for Dental and Dentoalveolar Tissue Regeneration","authors":"Xiaoxiao Wang, Hui Li, Min Mu, Rui Ye, Lihua Zhou, Gang Guo","doi":"10.1080/15583724.2024.2401992","DOIUrl":"https://doi.org/10.1080/15583724.2024.2401992","url":null,"abstract":"Oral diseases are a prevalent global issue, causing significant health and economic burdens that greatly diminish the quality of life for affected individuals. Tissue engineering strategies employi...","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"18 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-31DOI: 10.1080/15583724.2024.2387585
Yang Bai, Hao Yao, Xihua Li, Jingxia Wang, Wei Tian
Nonlinear supramolecular polymers (NLSPs) exhibit the merits of reversibility and tunability, along with a unique topological structure. These features contribute to the creation of novel supramole...
{"title":"Nonlinear Supramolecular Polymers: From Controlled Synthesis, Tunable Self-Assembly Toward Diverse Applications","authors":"Yang Bai, Hao Yao, Xihua Li, Jingxia Wang, Wei Tian","doi":"10.1080/15583724.2024.2387585","DOIUrl":"https://doi.org/10.1080/15583724.2024.2387585","url":null,"abstract":"Nonlinear supramolecular polymers (NLSPs) exhibit the merits of reversibility and tunability, along with a unique topological structure. These features contribute to the creation of novel supramole...","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"36 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-27DOI: 10.1080/15583724.2024.2396853
Milad Nouri, Ali Poorkhalil, Hasan Farrokhzad
The membrane, a core element in pervaporation technology, is of utmost importance for its advancement. Membrane modification is one of the most effective means of achieving an efficient membrane, w...
{"title":"Modification Methods Categorization of Polymeric Membranes for Pervaporation: A Review","authors":"Milad Nouri, Ali Poorkhalil, Hasan Farrokhzad","doi":"10.1080/15583724.2024.2396853","DOIUrl":"https://doi.org/10.1080/15583724.2024.2396853","url":null,"abstract":"The membrane, a core element in pervaporation technology, is of utmost importance for its advancement. Membrane modification is one of the most effective means of achieving an efficient membrane, w...","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"99 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-22DOI: 10.1080/15583724.2024.2392124
Mohammad Zibafar, Reza Eslami-Farsani
Self-healing materials have garnered significant attention for their potential to heal damage when it occurs. Elastomers, particularly natural rubber, have been a focal point of extensive research ...
自愈合材料因其在损伤发生时的愈合潜力而备受关注。弹性体，尤其是天然橡胶，一直是广泛研究的焦点...
{"title":"Reversible ionic bond mechanism in self-healing of natural rubber: A review","authors":"Mohammad Zibafar, Reza Eslami-Farsani","doi":"10.1080/15583724.2024.2392124","DOIUrl":"https://doi.org/10.1080/15583724.2024.2392124","url":null,"abstract":"Self-healing materials have garnered significant attention for their potential to heal damage when it occurs. Elastomers, particularly natural rubber, have been a focal point of extensive research ...","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"8 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-31DOI: 10.1080/15583724.2024.2382891
Hang Shen, Botuo Zheng, Huagui Zhang
Inverse vulcanization utilizes alkenyl monomers and elemental sulfur, an excessive by-product of oil and gas refineries, to synthesize dynamically crosslinked sulfur-rich polymers, therefore provid...
{"title":"A Decade Development of Inverse Vulcanization Towards Green and Sustainable Practices","authors":"Hang Shen, Botuo Zheng, Huagui Zhang","doi":"10.1080/15583724.2024.2382891","DOIUrl":"https://doi.org/10.1080/15583724.2024.2382891","url":null,"abstract":"Inverse vulcanization utilizes alkenyl monomers and elemental sulfur, an excessive by-product of oil and gas refineries, to synthesize dynamically crosslinked sulfur-rich polymers, therefore provid...","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"186 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Collagen has shown promising potential in biomedical fields due to its high biocompatibility, abundance of resources, ease of flexible modification, and potential for active targeting. The biomedic...
{"title":"Recent Advances on Collagen Biomaterial: From Extraction, Cross-Linking to Tissue Regeneration","authors":"Lian Zhu, Ze-Long Yu, Sheng Li, Cheng-Zhi Xu, Yuan-Jing Hou, Li-Xia Liao, Yu-Ling Xu, Jun-Tao Zhang, Ben-Mei Wei, Wei Wen, Hai-Bo Wang","doi":"10.1080/15583724.2024.2382128","DOIUrl":"https://doi.org/10.1080/15583724.2024.2382128","url":null,"abstract":"Collagen has shown promising potential in biomedical fields due to its high biocompatibility, abundance of resources, ease of flexible modification, and potential for active targeting. The biomedic...","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"30 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141939207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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