首页 > 最新文献

Polymer Reviews最新文献

英文 中文
Melt-Based Additive Manufacturing of Polyolefins Using Material Extrusion and Powder Bed Fusion 采用材料挤压和粉末床熔合的熔融增材制造聚烯烃
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-06-12 DOI: 10.1080/15583724.2023.2220024
Arit Das, J. Bryant, C. Williams, M. Bortner
Abstract Polyolefin-based thermoplastics such as polyethylene and polypropylene constitute a major fraction of the polymers employed in commodity applications due to their ease of processability, durability, and economic viability. Additive manufacturing (AM) of polyolefins offers both a viable path toward functional prototyping of design concepts and direct manufacturing of end-use parts. Melt-based AM of polyolefins is more challenging than other semicrystalline polymers (polyamides) due to the relatively high levels of volumetric shrinkage encountered during crystallization of such polymers that lead to significant issues related to warpage and interlayer adhesion. The focus of this review is to evaluate the latest state-of-the-art for processing polyolefins by powder bed fusion (PBF) and material extrusion (MatEx) AM modalities. Recent progress in processing neat, filled, and blends of polyolefins using PBF and MatEx are discussed to highlight the importance of the rheological and morphological characteristics of the polymer melt on the printed parts performance. The existing challenges to AM of polyolefins are emphasized and strategies to address the limitations are recommended through a better understanding of the associated process-structure-property relationships. A holistic approach spanning synthetic modifications for feedstock development, improved system design, and physics-guided process parameter selection is required to broadly adopt melt-based AM of polyolefins.
基于聚烯烃的热塑性塑料,如聚乙烯和聚丙烯,由于其易于加工,耐用性和经济可行性,构成了商品应用中使用的聚合物的主要部分。聚烯烃的增材制造(AM)为设计概念的功能原型和最终用途部件的直接制造提供了可行的途径。基于熔融的聚烯烃AM比其他半结晶聚合物(聚酰胺)更具挑战性,因为在这种聚合物的结晶过程中会遇到相对较高的体积收缩水平,从而导致与翘曲和层间粘附相关的重大问题。本综述的重点是评估粉末床熔融(PBF)和材料挤压(MatEx)增材制造模式加工聚烯烃的最新技术。讨论了用PBF和MatEx加工纯聚烯烃、填充聚烯烃和共混聚烯烃的最新进展,强调了聚合物熔体的流变学和形态学特征对打印部件性能的重要性。强调了聚烯烃增材制造面临的挑战,并通过更好地理解相关的工艺-结构-性能关系,提出了解决这些限制的策略。为了广泛采用熔融聚烯烃增材制造,需要采用一种全面的方法,包括原料开发的合成改性、改进的系统设计和物理指导的工艺参数选择。
{"title":"Melt-Based Additive Manufacturing of Polyolefins Using Material Extrusion and Powder Bed Fusion","authors":"Arit Das, J. Bryant, C. Williams, M. Bortner","doi":"10.1080/15583724.2023.2220024","DOIUrl":"https://doi.org/10.1080/15583724.2023.2220024","url":null,"abstract":"Abstract Polyolefin-based thermoplastics such as polyethylene and polypropylene constitute a major fraction of the polymers employed in commodity applications due to their ease of processability, durability, and economic viability. Additive manufacturing (AM) of polyolefins offers both a viable path toward functional prototyping of design concepts and direct manufacturing of end-use parts. Melt-based AM of polyolefins is more challenging than other semicrystalline polymers (polyamides) due to the relatively high levels of volumetric shrinkage encountered during crystallization of such polymers that lead to significant issues related to warpage and interlayer adhesion. The focus of this review is to evaluate the latest state-of-the-art for processing polyolefins by powder bed fusion (PBF) and material extrusion (MatEx) AM modalities. Recent progress in processing neat, filled, and blends of polyolefins using PBF and MatEx are discussed to highlight the importance of the rheological and morphological characteristics of the polymer melt on the printed parts performance. The existing challenges to AM of polyolefins are emphasized and strategies to address the limitations are recommended through a better understanding of the associated process-structure-property relationships. A holistic approach spanning synthetic modifications for feedstock development, improved system design, and physics-guided process parameter selection is required to broadly adopt melt-based AM of polyolefins.","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"249 1","pages":"895 - 960"},"PeriodicalIF":13.1,"publicationDate":"2023-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76990113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Recent Progress in PEG-Based Composite Phase Change Materials 聚乙二醇基复合相变材料研究进展
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-06-07 DOI: 10.1080/15583724.2023.2220041
Andrew Kim, Nicole Alexandra Wert, E. B. Gowd, R. Patel
Abstract This review discusses advances in polyethylene glycol-based composite phase change materials (PCMs) for thermal energy storage (TES) and thermal regulation. PCMs utilize latent heat storage, absorbing and releasing energy during phase transitions within specific temperature ranges. Polyethylene glycol (PEG) is a promising organic PCM due to its easily tunable phase change temperatures, high melting/freezing enthalpies, and nontoxicity, among other advantages. However, PEG suffers from low thermal conductivity and requires encapsulation to contain the flow of liquified PEG. To address these issues, PEG has been composited with thermally conductive fillers and porous materials. Moreover, PEG has been modified to have enhanced photothermal conversion efficiency, decreased supercooling, and flame resistance. This review discusses exemplary developments in PEG-based composite PCMs, focusing on blending with different polymers, doping with various carbon materials (porous carbons, graphene, and carbon nanotubes), embedding into silica-based skeletons, and synergizing with other promising hosts and additives like layered doubled hydroxides, MXenes, and metal-organic frameworks. This work highlights key studies focused on implementing PEG-based PCMs in building, pavement, electronic, textile, solar, and waste heat recovery applications. The consequences of different synthesis parameters and their effects on the composite PCM’s thermal transition properties are emphasized among the other results. Graphical Abstract
摘要本文综述了聚乙二醇基复合相变材料(PCMs)在储热和热调节方面的研究进展。pcm利用潜热储存,在特定温度范围内的相变过程中吸收和释放能量。聚乙二醇(PEG)是一种很有前途的有机PCM,由于其易于调节的相变温度,高熔化/冷冻焓,以及无毒等优点。然而,聚乙二醇的导热性低,需要封装来控制液态聚乙二醇的流动。为了解决这些问题,聚乙二醇已与导热填料和多孔材料复合。此外,PEG已被改性,以提高光热转换效率,减少过冷性和阻燃性。本文讨论了聚乙二醇基复合pcm的典型进展,重点是与不同聚合物共混,掺杂各种碳材料(多孔碳、石墨烯和碳纳米管),嵌入硅基骨架,以及与其他有前途的宿主和添加剂(如层状双氢氧化物、MXenes和金属有机框架)协同作用。这项工作强调了在建筑、路面、电子、纺织、太阳能和废热回收应用中实施基于peg的pcm的关键研究。在其他结果中,重点讨论了不同的合成参数及其对复合PCM热转变性能的影响。图形抽象
{"title":"Recent Progress in PEG-Based Composite Phase Change Materials","authors":"Andrew Kim, Nicole Alexandra Wert, E. B. Gowd, R. Patel","doi":"10.1080/15583724.2023.2220041","DOIUrl":"https://doi.org/10.1080/15583724.2023.2220041","url":null,"abstract":"Abstract This review discusses advances in polyethylene glycol-based composite phase change materials (PCMs) for thermal energy storage (TES) and thermal regulation. PCMs utilize latent heat storage, absorbing and releasing energy during phase transitions within specific temperature ranges. Polyethylene glycol (PEG) is a promising organic PCM due to its easily tunable phase change temperatures, high melting/freezing enthalpies, and nontoxicity, among other advantages. However, PEG suffers from low thermal conductivity and requires encapsulation to contain the flow of liquified PEG. To address these issues, PEG has been composited with thermally conductive fillers and porous materials. Moreover, PEG has been modified to have enhanced photothermal conversion efficiency, decreased supercooling, and flame resistance. This review discusses exemplary developments in PEG-based composite PCMs, focusing on blending with different polymers, doping with various carbon materials (porous carbons, graphene, and carbon nanotubes), embedding into silica-based skeletons, and synergizing with other promising hosts and additives like layered doubled hydroxides, MXenes, and metal-organic frameworks. This work highlights key studies focused on implementing PEG-based PCMs in building, pavement, electronic, textile, solar, and waste heat recovery applications. The consequences of different synthesis parameters and their effects on the composite PCM’s thermal transition properties are emphasized among the other results. Graphical Abstract","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"9 1","pages":"1078 - 1129"},"PeriodicalIF":13.1,"publicationDate":"2023-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72939059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Material Design and Characterization of Conducting Polymer-Based Supercapacitors 导电聚合物基超级电容器的材料设计与表征
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-06-06 DOI: 10.1080/15583724.2023.2220131
Shofarul Wustoni, D. Ohayon, Angga Hermawan, A. Nuruddin, S. Inal, Y. S. Indartono, B. Yuliarto
{"title":"Material Design and Characterization of Conducting Polymer-Based Supercapacitors","authors":"Shofarul Wustoni, D. Ohayon, Angga Hermawan, A. Nuruddin, S. Inal, Y. S. Indartono, B. Yuliarto","doi":"10.1080/15583724.2023.2220131","DOIUrl":"https://doi.org/10.1080/15583724.2023.2220131","url":null,"abstract":"","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"34 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2023-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84412425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Conductive Polymer/Nanocellulose Composites as a Functional Platform for Electronic Devices: A Mini-Review 导电聚合物/纳米纤维素复合材料作为电子器件的功能平台:综述
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-06-05 DOI: 10.1080/15583724.2023.2220018
W. Gao, Qiyuan Tu, Ping Wang, J. Zeng, Jinpeng Li, Bin Wang, Junxin Xu, Ke-fu Chen, Zhen Zhang, N. Abidi, L. Lucia
{"title":"Conductive Polymer/Nanocellulose Composites as a Functional Platform for Electronic Devices: A Mini-Review","authors":"W. Gao, Qiyuan Tu, Ping Wang, J. Zeng, Jinpeng Li, Bin Wang, Junxin Xu, Ke-fu Chen, Zhen Zhang, N. Abidi, L. Lucia","doi":"10.1080/15583724.2023.2220018","DOIUrl":"https://doi.org/10.1080/15583724.2023.2220018","url":null,"abstract":"","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"4 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2023-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84797144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Progress on Controlled Polymerizations for Functional Metallopolymers 功能化金属聚合物控制聚合研究进展
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-05-09 DOI: 10.1080/15583724.2023.2209159
Xiong Liu, Fangfei Liu, Tursun Abdiryim, Ruxangul Jamal
{"title":"Recent Progress on Controlled Polymerizations for Functional Metallopolymers","authors":"Xiong Liu, Fangfei Liu, Tursun Abdiryim, Ruxangul Jamal","doi":"10.1080/15583724.2023.2209159","DOIUrl":"https://doi.org/10.1080/15583724.2023.2209159","url":null,"abstract":"","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"48 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2023-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84790668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Natural Terpenoid-Based Sustainable Thermoplastics, Cross-Linked Polymers, and Supramolecular Materials 天然萜类可持续热塑性塑料,交联聚合物和超分子材料
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-05-09 DOI: 10.1080/15583724.2023.2209165
Hao Zhang, Jianqiao Wu, Junbo Guo, Jun Hu
{"title":"Natural Terpenoid-Based Sustainable Thermoplastics, Cross-Linked Polymers, and Supramolecular Materials","authors":"Hao Zhang, Jianqiao Wu, Junbo Guo, Jun Hu","doi":"10.1080/15583724.2023.2209165","DOIUrl":"https://doi.org/10.1080/15583724.2023.2209165","url":null,"abstract":"","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"107 ","pages":""},"PeriodicalIF":13.1,"publicationDate":"2023-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72420207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Radical Polymerization of Methylene Heterocyclic Compounds: Functional Polymer Synthesis and Applications 亚甲基杂环化合物的自由基聚合:功能聚合物的合成及其应用
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-02-21 DOI: 10.1080/15583724.2023.2181819
Zhuoqun Wang, Antoine Debuigne
Abstract Synthetic polymers sustain a wide range of applications but the quest for further sophistication and functionalization of polymers remains topical to improve their scope and performance. In this respect, the radical polymerization of exo-methylene heterocyclic compounds (MHCs) is attractive. Compared to the classical acyclic vinyl monomers constrained to the vinyl-type polymerization process, MHCs can undergo different polymerization modes, namely the radical ring-retaining polymerization (rRRP) and the radical ring-opening polymerization (rROP). In rRRP, the cyclic group is preserved and inserted as side group of the polymer backbone offering a myriad of post-polymerization modifications whereas functional groups are incorporated within the backbone of linear polymers and confer them some degradability in rROP. Herein, recent advances in the radical polymerization of MHCs as well as the variety of macromolecular structures and applications it offers are highlighted. The reversible deactivation radical polymerization of MHCs leading to well-defined MHC-based macromolecular architectures, including multifunctional, stimuli-responsive and degradable polymers, is also discussed. The review emphasizes the current limitations of the radical polymerization of MHCs as well as future prospects including the development of innovative bio-based MHCs. Overall, the radical polymerization of MCHs represents a powerful macromolecular engineering tool and a broad field of exploration for polymer chemists. Graphical Abstract
合成聚合物有着广泛的应用,但对聚合物进一步复杂化和功能化的追求仍然是当前的热点,以提高它们的范围和性能。在这方面,外亚甲基杂环化合物(mhc)的自由基聚合是有吸引力的。与传统的无环乙烯基单体限制在乙烯基型聚合过程中相比,mhc可以进行不同的聚合模式,即自由基保环聚合(rRRP)和自由基开环聚合(rROP)。在rROP中,环基被保留并作为聚合物主链的侧基插入,提供了无数的聚合后修饰,而官能团被纳入线性聚合物的主链中,并赋予它们在rROP中一定的可降解性。本文重点介绍了mhc自由基聚合的最新进展,以及它所提供的各种大分子结构和应用。还讨论了mhc的可逆失活自由基聚合导致明确定义的mhc为基础的大分子结构,包括多功能,刺激响应和可降解的聚合物。综述了目前自由基聚合mhc的局限性以及未来的发展前景,包括创新的生物基mhc的发展。总之,高分子聚合物的自由基聚合是一种强大的大分子工程工具,也是高分子化学家探索的广阔领域。图形抽象
{"title":"Radical Polymerization of Methylene Heterocyclic Compounds: Functional Polymer Synthesis and Applications","authors":"Zhuoqun Wang, Antoine Debuigne","doi":"10.1080/15583724.2023.2181819","DOIUrl":"https://doi.org/10.1080/15583724.2023.2181819","url":null,"abstract":"Abstract Synthetic polymers sustain a wide range of applications but the quest for further sophistication and functionalization of polymers remains topical to improve their scope and performance. In this respect, the radical polymerization of exo-methylene heterocyclic compounds (MHCs) is attractive. Compared to the classical acyclic vinyl monomers constrained to the vinyl-type polymerization process, MHCs can undergo different polymerization modes, namely the radical ring-retaining polymerization (rRRP) and the radical ring-opening polymerization (rROP). In rRRP, the cyclic group is preserved and inserted as side group of the polymer backbone offering a myriad of post-polymerization modifications whereas functional groups are incorporated within the backbone of linear polymers and confer them some degradability in rROP. Herein, recent advances in the radical polymerization of MHCs as well as the variety of macromolecular structures and applications it offers are highlighted. The reversible deactivation radical polymerization of MHCs leading to well-defined MHC-based macromolecular architectures, including multifunctional, stimuli-responsive and degradable polymers, is also discussed. The review emphasizes the current limitations of the radical polymerization of MHCs as well as future prospects including the development of innovative bio-based MHCs. Overall, the radical polymerization of MCHs represents a powerful macromolecular engineering tool and a broad field of exploration for polymer chemists. Graphical Abstract","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"11 1","pages":"805 - 851"},"PeriodicalIF":13.1,"publicationDate":"2023-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78664708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Self-assembly of ABCBA Linear Pentablock Terpolymers ABCBA线性五嵌段三元共聚物的自组装
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-02-13 DOI: 10.1080/15583724.2023.2178008
Lei Guo, Junting Xu, B. Du
{"title":"Self-assembly of ABCBA Linear Pentablock Terpolymers","authors":"Lei Guo, Junting Xu, B. Du","doi":"10.1080/15583724.2023.2178008","DOIUrl":"https://doi.org/10.1080/15583724.2023.2178008","url":null,"abstract":"","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"38 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77783931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Revealing Structural and Physical Properties of Polylactide: What Simulation Can Do beyond the Experimental Methods 揭示聚乳酸的结构和物理性质:模拟在实验方法之外的作用
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-02-12 DOI: 10.1080/15583724.2023.2174136
D. Guseva, M. K. Glagolev, A. Lazutin, V. Vasilevskaya
{"title":"Revealing Structural and Physical Properties of Polylactide: What Simulation Can Do beyond the Experimental Methods","authors":"D. Guseva, M. K. Glagolev, A. Lazutin, V. Vasilevskaya","doi":"10.1080/15583724.2023.2174136","DOIUrl":"https://doi.org/10.1080/15583724.2023.2174136","url":null,"abstract":"","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"5 1","pages":""},"PeriodicalIF":13.1,"publicationDate":"2023-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80263720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eco-Friendly Room-Temperature Polymerization in Emulsions and Beyond 乳液及其他环境友好型室温聚合
IF 13.1 2区 化学 Q1 POLYMER SCIENCE Pub Date : 2023-02-10 DOI: 10.1080/15583724.2023.2176514
Tan Zhang, Gu Xu, F. Blum
Abstract This review highlights the effectiveness and robust nature of eco-friendly room-temperature polymerization initiated in emulsions, and some of its applications in polymer and materials science. The polymerization in emulsions initiated through a thermal or redox approach can be safely conducted under ambient conditions without using other hazardous chemicals. Thermal initiators decompose efficiently at the surfactant-stabilized oil–water interfaces at room temperature. The interface-induced initiation is found to be somewhat independent of surfactant type, insensitive to oxygen, and works for several thermal initiators. Redox initiators without transition metal compounds also effectively initiate room-temperature polymerization in emulsions. With the assistance of room temperature initiation, the polymers synthesized at room temperature are of high molecular mass. In addition, room-temperature polymerization allows temperature-sensitive molecules, for example, proteins and enzymes, to be incorporated with the polymers in situ. The applications of room-temperature polymerization in high internal phase emulsions and biomedicine are also discussed. The initiation of radicals from oil–water interfaces or transition metal-free redox systems is a promising eco-friendly method to promote radical reactions at room temperature. Graphic Abstract
摘要本文综述了乳液室温环境友好聚合的有效性和健壮性,以及它在聚合物和材料科学中的一些应用。通过热或氧化还原方法引发的乳液聚合可以在环境条件下安全进行,而不使用其他危险化学品。室温下,热引发剂在表面活性剂稳定的油水界面处分解效率高。发现界面诱导引发与表面活性剂类型无关,对氧不敏感,并且适用于几种热引发剂。不含过渡金属化合物的氧化还原引发剂也能有效地引发乳液中的室温聚合。在室温引发的辅助下,室温合成的聚合物具有较高的分子质量。此外,室温聚合允许对温度敏感的分子,例如蛋白质和酶,在原位与聚合物结合。讨论了室温聚合在高内相乳剂和生物医药中的应用。从油水界面或过渡金属氧化还原体系中引发自由基是一种在室温下促进自由基反应的有前途的环保方法。图形抽象
{"title":"Eco-Friendly Room-Temperature Polymerization in Emulsions and Beyond","authors":"Tan Zhang, Gu Xu, F. Blum","doi":"10.1080/15583724.2023.2176514","DOIUrl":"https://doi.org/10.1080/15583724.2023.2176514","url":null,"abstract":"Abstract This review highlights the effectiveness and robust nature of eco-friendly room-temperature polymerization initiated in emulsions, and some of its applications in polymer and materials science. The polymerization in emulsions initiated through a thermal or redox approach can be safely conducted under ambient conditions without using other hazardous chemicals. Thermal initiators decompose efficiently at the surfactant-stabilized oil–water interfaces at room temperature. The interface-induced initiation is found to be somewhat independent of surfactant type, insensitive to oxygen, and works for several thermal initiators. Redox initiators without transition metal compounds also effectively initiate room-temperature polymerization in emulsions. With the assistance of room temperature initiation, the polymers synthesized at room temperature are of high molecular mass. In addition, room-temperature polymerization allows temperature-sensitive molecules, for example, proteins and enzymes, to be incorporated with the polymers in situ. The applications of room-temperature polymerization in high internal phase emulsions and biomedicine are also discussed. The initiation of radicals from oil–water interfaces or transition metal-free redox systems is a promising eco-friendly method to promote radical reactions at room temperature. Graphic Abstract","PeriodicalId":20326,"journal":{"name":"Polymer Reviews","volume":"49 1","pages":"852 - 865"},"PeriodicalIF":13.1,"publicationDate":"2023-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86627209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
期刊
Polymer Reviews
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1