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Review on Nanocellulose Polymer Nanocomposites 纳米纤维素聚合物纳米复合材料研究进展
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381253
S. Mondal
Recently, nanocellulosic materials have been received significant research interest as potential nanofiller for the reinforcements in the polymer matrices due to its renewable in nature, readily av...
近年来,纳米纤维素材料因其可再生、易降解、易降解等特性而成为聚合物基体增强材料的潜在纳米填料。
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引用次数: 79
Aniline-Modified Polypropylene as a Compatibilizer in Polypropylene Carbon Nanotube Composites 苯胺改性聚丙烯在聚丙烯碳纳米管复合材料中的增容剂作用
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381251
J. G. Martínez‐Colunga, S. Sánchez-Valdes, L. Ramos-deValle, O. Pérez‐Camacho, E. Ramírez‐Vargas, R. Benavides-Cantu, C. Ávila‐Orta, V. J. Cruz‐Delgado, J. M. Mata-Padilla, T. Lozano‐Ramírez, A. Espinoza-Martinez
ABSTRACTMaleic anhydride-grafted polypropylene (PP-g-MA) was reacted with aniline (NH2C6H5) to produce PP-g-NHC6H5 and used as a compatibilizer in polypropylene/carbon nanotube composites. Infrared spectroscopy (FTIR) and nuclear magnetic resonance confirmed the reaction between PP-g-MA and aniline. PP-g-NHC6H5 resulted a better compatibilizer than PP-g-MA, producing good dispersion and homogeneous distribution of the carbon nanotubes with less agglomerates, as observed by SEM analysis. Improved dispersion and distribution is assumed to be due to the π–π interactions between the –C6H5 ring in the prepared compatibilizer and the hexagonal carbon structure in the nanotubes. In addition, a higher degree of crystallinity (12%) was promoted, since it was favored by π–π interactions. This achieved higher crystallinity promoted an increase in tensile modulus, with only slight changes in tensile strength but with an adverse effect on elongation at break.
摘要以马来酸酐接枝聚丙烯(PP-g-MA)与苯胺(NH2C6H5)反应生成PP-g-NHC6H5,并将其用作聚丙烯/碳纳米管复合材料的增容剂。红外光谱(FTIR)和核磁共振证实了PP-g-MA与苯胺的反应。SEM分析发现,与PP-g-MA相比,PP-g-NHC6H5具有更好的增容剂作用,碳纳米管分散性好,分布均匀,团聚团块少。增容剂中的-C6H5环与纳米管中的六方碳结构之间的π -π相互作用改善了分散和分布。此外,由于π -π相互作用更有利于结晶度的提高(12%)。这样获得的较高结晶度促进了拉伸模量的增加,拉伸强度只有轻微的变化,但对断裂伸长率有不利影响。
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引用次数: 6
Ionic Conductivity and Power Conversion Efficiency Study of KI Incorporated Glucosyl Carboxonium Ion-based Biopolymer Crust Electrolyte KI掺入葡萄糖基羧基离子基生物聚合物结壳电解质的离子电导率和功率转换效率研究
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381245
E. Bementa, G. Okram, M. Rajan
The impedance of well-characterized KI-incorporated glucosyl carboxonium ion-based biopolymer crust electrolytes up to a maximum 2.7 wt% was measured using electrical impedance spectroscopy. Enhanced ionic conductivity of 2.3657 × 10−2 S cm−1 on the addition of 2.7 wt% of KI was observed in contrast to earlier reported value for pure GCI of 4.5278 × 10−4 S cm−1. This is attributed due to the increased concentration of KI in the system and is corroborated with increased ion density (n), mobility (µ), and diffusion coefficients (D). Dielectric and modulus study shows the capacitive nature of electrolyte. Fabricated dye-sensitized solar cell using pure glucosyl carboxonium ion crust and KI-incorporated glucosyl carboxonium ion crust shows the efficiency of 1.19% for pure and shows the efficiency of 2.14% for 2.6 wt% of KI in glucosyl carboxonium ion at 1 sun condition.
利用电阻抗谱法测量了表征良好的ki -葡萄糖基羧基离子基生物聚合物外壳电解质的阻抗,最大可达2.7 wt%。与之前报道的纯GCI的4.5278 × 10−4 S cm−1相比,在添加2.7 wt%的KI时,离子电导率提高了2.3657 × 10−2 S cm−1。这是由于系统中KI浓度的增加,离子密度(n)、迁移率(µ)和扩散系数(D)的增加也证实了这一点。介电和模量研究显示了电解质的电容性。在1个太阳条件下,用纯葡萄糖基碳鎓离子壳和KI掺杂的葡萄糖基碳鎓离子壳制备的染料敏化太阳能电池,纯葡萄糖基碳鎓离子壳的效率为1.19%,KI掺杂2.6 wt%葡萄糖基碳鎓离子壳的效率为2.14%。
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引用次数: 2
In Situ Synthesis of Ultrahigh Molecular Weight Polyethylene/Graphene Oxide Nanocomposite Using the Immobilized Single-site Catalyst 固定化单位点催化剂原位合成超高分子量聚乙烯/氧化石墨烯纳米复合材料
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381246
A. Heidari, S. Talebi, M. Rezaei, Hasan Keshavarz-Mirzamohamadi, Elchin Jafariyeh-Yazdi
ABSTRACTWe address the immobilization of single-site catalyst on the graphite oxide (GO) surface using methylaluminoxane. Ethylene polymerization was performed using the immobilized catalyst and the nanocomposite of ultrahigh molecular weight polyethylene (UHMWPE)/GO with less entanglement density was obtained. It was observed that the drawability, mechanical and thermal properties of the produced polymer significantly are affected by the anchoring of polymer chains to the GO nanosheets. The orientation and location of crystalline lamellae and nanosheets were verified by microscopic techniques. Besides, X-ray analysis demonstrated the dispersion of GO within the UHMWPE phase and crystallinity of UHMWPE/GO nanocomposites enhanced during drawing process.
摘要研究了甲基铝氧烷在氧化石墨(GO)表面固定单位点催化剂的方法。采用固定化催化剂进行乙烯聚合,得到了缠结密度小的超高分子量聚乙烯/氧化石墨烯纳米复合材料。观察到聚合物链锚定在氧化石墨烯纳米片上对聚合物的拉伸性、机械性能和热性能有显著影响。通过显微技术验证了晶片和纳米片的取向和位置。此外,x射线分析表明,在拉伸过程中,氧化石墨烯在UHMWPE相中分散,UHMWPE/GO纳米复合材料的结晶度增强。
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引用次数: 3
Expanded Polystyrene Foam Formed from Polystyrene Beads Coated with a Nanocrystalline SiO2 Film and the Analysis of Its Moisture Adsorption and Resistance to Mechanical Stress 聚苯乙烯微珠包覆纳米SiO2膜形成膨胀聚苯乙烯泡沫及其吸湿性和抗机械应力分析
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381244
S. Varnagiris, J. Donėlienė, S. Tučkutė, J. Cesniene, M. Lelis, D. Milčius
ABSTRACTConventional expanded polystyrene can absorb moisture, which significantly degrades its properties. In the present study, it was demonstrated that SiO2 can be deposited on polystyrene beads before pre-expansion and molding steps. Under the applied test conditions, expanded polystyrene with nanocrystalline SiO2 additives had approximately 10% lower moisture adsorption and an 8.4% better resistance to deformation. Expanded polystyrene analysis suggested that the observed improvements were caused by the hydrophobic nature of nanocrystalline SiO2 and, even more importantly, because SiO2 acted as an amalgamation catalyst and significantly increased adhesion between the expanded polystyrene beads during the expanded polystyrene molding process.
【摘要】传统的膨胀聚苯乙烯吸湿会显著降低其性能。在本研究中,证明了SiO2可以在预膨胀和成型步骤之前沉积在聚苯乙烯珠上。在应用的测试条件下,添加纳米晶SiO2的膨胀聚苯乙烯的吸湿性能降低了约10%,抗变形性能提高了8.4%。膨胀聚苯乙烯分析表明,观察到的改善是由纳米晶SiO2的疏水性引起的,更重要的是,在膨胀聚苯乙烯成型过程中,SiO2起到了汞化催化剂的作用,显著增加了膨胀聚苯乙烯珠之间的附着力。
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引用次数: 7
Preparation and Characterization of Microcapsules Containing Soybean Oil and Their Application in Self-Healing Anticorrosive Coatings 大豆油微胶囊的制备、表征及其在自愈防腐涂料中的应用
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381248
P. S. Shisode, C. Patil, P. Mahulikar
ABSTRACTSynthetic self-healing materials are a new prototype in polymeric coatings. In the present investigation, soybean oil along with drier was encapsulated in urea–formaldehyde (UF) microcapsul...
摘要合成自修复材料是高分子涂料中的一种新型材料。本研究将大豆油和干燥剂包封在脲醛(UF)微胶囊中。
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引用次数: 18
Facile Preparation of Cellulose/Polylactide Composite Materials with Tunable Mechanical Properties 机械性能可调的纤维素/聚乳酸复合材料的简易制备
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381243
T. Qiang, Jinwu Wang, M. Wolcott
ABSTRACTA solvent-free route was developed to fabricate 100% biobased, renewable, and degradable polylactide (PLA) composites reinforced with ball-milled celluloses. The results show that the original pulp cellulose fibers were modified to partial amorphization through 30-min ball milling. Filling the ball milled celluloses into PLA increased the tensile modulus for the resultant cellulose/PLA composite materials, while decreased their tensile strength and impact resistance. This method can be used to access the cost-efficient PLA-based composite materials with tunable mechanical properties. The variation analysis shows that filling content contributed more to the variations of their mechanical properties than that particle size did.
摘要:采用无溶剂路线制备100%生物基、可再生、可降解的球磨纤维素增强聚乳酸(PLA)复合材料。结果表明:经30min球磨后,原浆纤维素纤维被改性为部分非晶化;将球磨纤维素填充到PLA中增加了所得纤维素/PLA复合材料的拉伸模量,但降低了其拉伸强度和抗冲击性。该方法可用于获得具有可调力学性能的低成本pla基复合材料。变异分析表明,充填量对其力学性能的影响大于粒径。
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引用次数: 6
Influence of Solvent-Evaporation Effect on the Structure and Properties of PVDF-g-PNIPAAm Membranes 溶剂蒸发效应对PVDF-g-PNIPAAm膜结构和性能的影响
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381250
Zhaoguang Wang, Zhengyi Liu, Li Chen, Yiping Zhao, Xia Feng
Temperature-sensitive poly(vinylidene fluoride)-graft-poly(N-isopropylacrylamide)(PVDF-g-PNIPAAm) copolymer was synthesized and its flat membranes were prepared through phase inversion method with ...
合成了温度敏感型聚偏氟乙烯-接枝聚n -异丙基丙烯酰胺(PVDF-g-PNIPAAm)共聚物,并采用相转化法制备了其平板膜。
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引用次数: 3
Poly(Vinylpyrrolidone)-Embedded Bismuth Ferrite—Poly(Vinylidene Fluoride-co-Hexafluoropropylene) Composites with Enhanced Dielectric Properties 具有增强介电性能的聚(乙烯基吡咯烷酮)-嵌入铋铁氧体-聚(偏氟乙烯-共六氟丙烯)复合材料
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381249
S. Moharana, R. N. Mahaling
The dielectric properties of poly(vinylpyrrolidone) (PVP)-modified bismuth ferrite (BFO) particles in the poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP) matrix were prepared through solution casting techniques. The composites showed enhanced dielectric constant (90) and reduced dielectric loss (<0.5) at 40 wt% of PVP-modified BFO particles. The dielectric constant of the resultant composites with PVP-modified BFO was much higher as compared to that of unmodified BFO-P(VDF-HFP) composites. The maximum remnant polarization reached (2Pr ∼ 1.12 µC cm−2) in the PVP-modified BFO-P(VDF-HFP) composites. The demonstrated approach might provide a route for using PVP-modified BFO particles to enhance the dielectric and ferroelectric performance of the composites.
采用溶液铸造法制备了聚偏氟乙烯-共六氟丙烯(VDF-HFP)基体中聚乙烯吡啶烷酮(PVP)-改性铋铁氧体(BFO)颗粒的介电性能。当pvp改性BFO颗粒的质量分数为40%时,复合材料的介电常数提高(90),介电损耗降低(<0.5)。与未改性BFO- p (VDF-HFP)复合材料相比,pvp改性BFO- p复合材料的介电常数要高得多。pvp改性BFO-P(VDF-HFP)复合材料的最大残余极化达到(2Pr ~ 1.12µC cm−2)。该方法可能为使用pvp改性BFO颗粒来提高复合材料的介电和铁电性能提供了一条途径。
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引用次数: 1
Synthesis of Bio-Based Polyamide/Acid-Functionalized Multiwalled Carbon Nanotube Nanocomposites Using Vanillin 香兰素合成生物基聚酰胺/酸功能化多壁碳纳米管纳米复合材料
Q2 Materials Science Pub Date : 2018-09-02 DOI: 10.1080/03602559.2017.1381252
Z. Mirzakhanian, M. Hasani, K. Faghihi
Synthesis of bio-based polyamide/acid-functionalized multiwalled carbon nanotube nanocomposites (PA/FCNT NCs) is reported in this investigation. New aliphatic–aromatic bio-based polyamide (PA) was ...
本文报道了生物基聚酰胺/酸功能化多壁碳纳米管纳米复合材料(PA/FCNT NCs)的合成。研究了一种新型脂肪族芳香族生物基聚酰胺(PA)。
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引用次数: 1
期刊
Polymer-Plastics Technology and Engineering
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