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HaP/SBA-3 Nanostructured Composite to Remove Fluoride Effectively from Contaminated Water HaP/SBA-3纳米结构复合材料有效去除污染水中的氟化物
Pub Date : 2021-11-29 DOI: 10.31031/rdms.2021.16.000883
O. Anunziata
Nanostructured materials, based on silica (MCM, SBA [1,2]) and ordered mesoporous carbon (OMC), such as CMK-1, CMK-3 [3] and Multi-Walled Carbon Nanotubes (MWCN) [4], because of their large surface area, pore volume and possibility to vary the pore size, offer a great opportunity for their application in various fields, from industrial processes to biomedical engineering, air and water pollution decontamination and energy reservoirs. Recently, we have developed a technique of preparation of monocrystalline hydroxyapatite (HaP) , and by the same procedure, but in the presence of the respective hosts, forming in situ composites such as HaP/MCM-41 and HaP/SBA15 composites [5]. Numerous approaches for fluoride removal from contaminated water, such as precipitation-coagulation [6], membrane technology [7,8], ion exchange [9] and adsorption [10,11]. Among the above methods, fluoride adsorption on adsorbents is attracting increasing attention due to its advantages of convenient design and operation, and low cost [12]. Different types of adsorbents, such as metal adsorbents [13], carbon adsorbents [14], carbon materials [15], natural materials [16], and biosorbents [17], have been used to remove fluoride from water. MOFs have also been used as new adsorbents for fluoride adsorption due to their surface functional groups and ordered atomic arrangement [18]. Calcium phosphate apatites are compounds of the formula Ca5 (PO4)3X, where X can be an Fion (fluorapatite, FaP), OH(hydroxyapatite, HaP), or a Clion (chlorapatite). The ion is substituted by another ion of the same sign but of different charge. Neutrality is maintained by substitutions of ions with different charges or vacancies [19]. Studied the crystallization of HaP (hydroxyapatite) on polymers containing C-N groups, from supersaturated solutions of HaP has been reported [20]. The growth of hydroxyapatite on silica gels in the presence of organic additives was studied by Rivera-Muñoz et al. [21]. Laghzizil et al. [22] have correlated the results of HaP fluorination with the physicochemical properties of HaP. Recently, morphological modifications of hydroxyapatite using fatty acids as an organic modifier have been reported [23]. The goal of this work is the successful Crimson Publishers Wings to the Research Short Communication
基于二氧化硅(MCM, SBA[1,2])和有序介孔碳(OMC)的纳米结构材料,如CMK-1, CMK-3[3]和多壁碳纳米管(MWCN)[4],由于其大的表面积,孔体积和改变孔大小的可能性,为其在各个领域的应用提供了巨大的机会,从工业过程到生物医学工程,空气和水污染净化和能源储存。最近,我们开发了一种制备单晶羟基磷灰石(HaP)的技术,并通过相同的程序,但在各自的宿主存在下,形成原位复合材料,如HaP/MCM-41和HaP/SBA15复合材料[5]。除氟方法有沉淀-混凝法[6]、膜法[7,8]、离子交换法[9]和吸附法[10,11]等。在上述方法中,吸附剂吸附氟因其设计、操作方便、成本低等优点越来越受到人们的关注[12]。不同类型的吸附剂,如金属吸附剂[13]、碳吸附剂[14]、碳材料[15]、天然材料[16]和生物吸附剂[17],已被用于去除水中的氟化物。mof由于其表面官能团和有序的原子排列,也被用作新型的氟吸附剂[18]。磷酸钙磷灰石是分子式为Ca5 (PO4)3X的化合物,其中X可以是离子(氟磷灰石,FaP)、OH(羟基磷灰石,HaP)或cleon(氯磷灰石)。这个离子被另一个符号相同但带不同电荷的离子所取代。中性是通过不同电荷或空位的离子取代来维持的[19]。有报道研究了羟基磷灰石在含C-N基团的聚合物上从羟基磷灰石的过饱和溶液中结晶[20]。Rivera-Muñoz等[21]研究了有机添加剂存在下羟基磷灰石在硅胶上的生长。Laghzizil等[22]将羟基磷灰石氟化的结果与羟基磷灰石的理化性质联系起来。最近,利用脂肪酸作为有机改性剂对羟基磷灰石进行形态修饰的研究也有报道[23]。这项工作的目标是成功的深红出版社翼的研究短通信
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引用次数: 0
Challenges in Postprocessing of Hybrid Manufacturing of Magnet Polymer Composites to Enhance the Energy Product of NdFeB Bonded Magnets 提高钕铁硼粘结磁体能量积的磁体聚合物复合材料混合制造后处理挑战
Pub Date : 2021-11-22 DOI: 10.31031/rdms.2021.16.000882
T. Lamichhane
Bonded permanent magnets need to process magnetic filler particles and binder together which is a form of hybrid or composite manufacturing that needs to simultaneously process multimaterials. Polymer bonding of the permanent magnets decreases the energy product of the bonded magnets which varies with square of loading fraction of magnetic materials. However, due to high viscosity of bonding polymer prohibits loading higher than 80 volume % of magnetic materials in most efficient loading process such as compression molding. To further increase the loading of magnetic fraction in the bonded permanent magnets, it is expected to be beneficial to introduce a fraction of nonreacting thermally sacrificial polymer along with permanent bonding polymer in the least permissible of about 20 volume % of the polymer. This process of first adding the sacrificial polymer for higher processability for composites and later removing it via post processing such as heat treatment provides a simple example of inclusion of both the additive and the subtractive stages of hybrid manufacturing. These hybrid composite magnets can be heat treated to remove the sacrificial polymer to further increase the density and energy product which might require to implement hot isostatic pressing for compaction. Although the identification of such ideal polymer requires an extensive polymer chemistry research, we have compression molded several permanent bonding polymers such as nylon, polycarbonate (PC) and polyphenyl sulfide (PPS) and potential sacrificial polymer such as polyoxymethylene (POM), polystyrene (PS), and Acrylonitrile Butadiene Styrene (ABS) and heat treated to remove the sacrificial polymers. It is discovered that oxygen free low temperature pyrolizable polymers could be the potential candidates for increasing the magnet particles loading for achieving high energy products.
粘结永磁体需要将磁性填料颗粒和粘结剂加工在一起,这是一种需要同时加工多种材料的混合或复合制造形式。永磁体的聚合物键合降低了键合磁体的能量积,其能量积随磁性材料负载分数的平方而变化。然而,由于粘接聚合物的高粘度,在最有效的加载过程中,如压缩成型,禁止加载高于80%体积%的磁性材料。为了进一步增加粘接永磁体中磁性组分的负载,在聚合物的最小允许体积约为20%的情况下,在永久粘接聚合物中引入一部分不发生反应的热牺牲聚合物是有益的。首先添加牺牲聚合物以提高复合材料的可加工性,然后通过后处理(如热处理)将其去除,这一过程提供了混合制造中添加和减去阶段的简单示例。这些混合复合磁体可以经过热处理,去除牺牲聚合物,进一步增加密度和能量产物,这可能需要实施热等静压来进行压实。虽然这种理想聚合物的鉴定需要广泛的聚合物化学研究,但我们已经模压了几种永久键合聚合物,如尼龙、聚碳酸酯(PC)和聚苯硫醚(PPS),以及潜在的牺牲聚合物,如聚甲醛(POM)、聚苯乙烯(PS)和丙烯腈-丁二烯-苯乙烯(ABS),并对其进行热处理以去除牺牲聚合物。研究发现,无氧低温可热解聚合物可能是提高磁性粒子负载以获得高能产物的潜在候选材料。
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引用次数: 0
Experimental Simulation of Molten Corium and Sacrificial Material Interaction in a Scaled Down Core Catcher 缩小堆芯捕集器中熔融堆芯与牺牲材料相互作用的实验模拟
Pub Date : 2021-11-22 DOI: 10.31031/rdms.2021.16.000881
S. Munot
During the severe accident condition involving the core melt, stabilization and cooling the molten corium for long duration is the primary requirement. To address this challenge, core catcher systems are being installed inside the containment of the advanced nuclear reactors. Few ex-vessel core catcher designs incorporate special refractory sacrificial material, which on interaction with molten corium, ablate and reduce the enthalpy of the molten pool. During the interaction, the components of ablated sacrificial material and molten corium are stratified in different layers due to density difference between them, i.e., the low density oxidic components stratify in the top layer while higher density metallic components stratify in the bottom layers in the melt pool. This manuscript presents the material characterization of the stratified melt pool after cooling in an experiment involving interaction of approx. 550kg of molten simulant corium with approx. 150kg of sacrificial material in a scaled down V-shaped ex-vessel core catcher vessel. The cooling strategy in the experiment was similar to prototypic reactor conditions. After cooling and stratification of the melt pool, solid samples from different locations and different heights were collected for SEM-EDS analysis for characterizations. The phenomena of melt inversion were verified in the post-test analysis.
在涉及堆芯熔化的严重事故条件下,长时间稳定和冷却熔融堆芯是首要要求。为了应对这一挑战,在先进核反应堆的安全壳内安装了堆芯捕捉系统。采用特殊耐火牺牲材料的炉外堆芯捕集器设计很少,这种材料与熔化的堆芯相互作用,烧蚀并降低熔池的焓。在相互作用过程中,烧蚀牺牲材料和熔融堆芯的成分由于密度的差异而在不同的层中分层,即在熔池中,低密度的氧化成分在顶层分层,而高密度的金属成分在底层分层。本文介绍了在一项涉及近似相互作用的实验中,冷却后分层熔池的材料特性。550kg的熔融模拟堆芯,150kg的牺牲材料放在按比例缩小的v形舱外岩心捕集器中。实验中的冷却策略与原型反应堆条件相似。熔池冷却分层后,收集不同位置、不同高度的固体样品进行SEM-EDS分析表征。试验后分析证实了熔体反转现象。
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引用次数: 0
Properties in Fe-Doped ZnS Thin Films 掺铁ZnS薄膜的性能
Pub Date : 2021-11-16 DOI: 10.31031/rdms.2021.16.000879
Jafarli Rufat
Fe-doped ZnS single-phase thin films showing ferromagnetism have been successfully prepared by Chemical Bath deposition (CBD) on GaAs substrates. Field and temperature dependent magnetization curve indicate that the sample with a Curie temperature Tc as high as 270K. The X-ray diffraction and Atomic Force Microscopy (AFM) reveal that the thin films are well crystallized, Fe ions are substituted for Zn ions in the ZnS matrix and no trace of secondary phases or Fe clusters is detected. The experimental results are explained theoretically by spin-polarized density functional calculations within Generalized-Gradient Approximations (GGA), which indicates the observed high Tc could be mainly ascribed to the p-d exchange coupling between Fe ions and host elements.
采用化学浴沉积法(CBD)在砷化镓(GaAs)衬底上成功制备了铁掺杂ZnS单相铁磁性薄膜。随场和温度变化的磁化曲线表明,样品的居里温度Tc高达270K。x射线衍射和原子力显微镜(AFM)分析表明,薄膜结晶良好,Fe离子取代了ZnS基体中的Zn离子,未发现二次相和铁团簇的痕迹。用广义梯度近似(GGA)中的自旋极化密度泛函理论解释了实验结果,表明观察到的高Tc可能主要归因于Fe离子与宿主元素之间的p-d交换耦合。
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引用次数: 1
Recovery of Metallic Values in Smart Cards 回收智能卡的金属价值
Pub Date : 2021-11-09 DOI: 10.31031/rdms.2021.16.000878
F. Arslan
Today, smart cards which include a small microchip are very widely used in our daily lives. The chief among these is credit cards. In addition, gift shopping card, phone card, sim card, hotel room card involves great proportions. They generally include many precious metals in their body, including noble metals, and semi-noble metals; predominantly gold, silver, copper, etc. The aim of this experimental work is to recover the metals from the smart cards by hydrometallurgical processes namely acidic leaching (HNO 3 and Aqua Regia) followed by precipitation and cementation. Three different types of smart cards; credit cards supplied from different banks, telephone cards produced for Turk Telekom, and sim cards from three different mobile service providers, are used in the experimental work. As a result of this study, almost all copper, silver,
今天,包含一个小微芯片的智能卡在我们的日常生活中得到了广泛的应用。其中最主要的是信用卡。此外,礼品购物卡、电话卡、sim卡、酒店房卡涉及的比例也很大。它们体内一般含有许多贵金属,包括贵金属、半贵金属;主要是金、银、铜等。本实验工作的目的是通过湿法冶金工艺,即酸性浸出(hno3和王水),然后沉淀和胶结,从智能卡中回收金属。三种不同类型的智能卡;实验中使用了不同银行提供的信用卡、为土耳其电信生产的电话卡以及来自三家不同移动服务提供商的sim卡。这项研究的结果是,几乎所有的铜,银,
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引用次数: 0
Extending the Down Limit of Pore Size of Anodic TiO2 Nanotube Arrays 扩展阳极TiO2纳米管阵列孔径的下限
Pub Date : 2021-10-20 DOI: 10.31031/rdms.2021.15.000875
Hui Li
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引用次数: 0
Effective Sonodegradation of Methylene Blue (MB) Organic Dye by Mil-88(Fe)/NaY/MnFe2O4 Nanocomposite Sonocatalyst in Aqueous Solution Mil-88(Fe)/NaY/MnFe2O4纳米复合声催化剂在水溶液中对亚甲基蓝(MB)有机染料的有效声降解
Pub Date : 2021-10-20 DOI: 10.31031/rdms.2021.16.000876
M. Sadeghi
This research examined sonocatalytic degradation of Methylene Blue (MB) dye in the presence of MIL-88(Fe)/NaY/MnFe2O4 nanocomposite synthesized using the ultrasound assisted-hydrothermal route. Multiple identification techniques were utilized to investigate the MIL-88(Fe)/NaY/MnFe2O4 nanocomposite sonocatalyst involving FESEM, EDAX, FTIR, XRD and BET. The influences of various parameters like contact time, H2O2 concentration, initial MB concentration and sonocatalyst dosage were precisely studied. About 98.1% of MB dye degradation was achieved under the optimum parameter conditions i.e. at pH of 7, 25mg/L of initial MB concentration, H2O2 concentration of 4mM and 0.5g/L of MIL-88(Fe)/NaY/MnFe2O4 dosage within 60min. The enhancement of sonocatalytic activities can be related to the function of NaY zeolite as trap state for the electron. The scavenger tests outcomes demonstrated that the sono-generated hydroxyl radical (.OH) would play an important role in the MB degradation. Additionally, the MIL-88(Fe)/NaY/MnFe2O4 was quite stable since the efficiency of MB degradation gained in the four run was 93.7%.
研究了超声辅助水热法合成MIL-88(Fe)/NaY/MnFe2O4纳米复合材料对亚甲基蓝(MB)染料的声催化降解作用。采用FESEM、EDAX、FTIR、XRD、BET等多种鉴定技术对MIL-88(Fe)/NaY/MnFe2O4纳米复合声催化剂进行了表征。研究了接触时间、H2O2浓度、MB初始浓度、声催化剂用量等参数对反应的影响。在pH = 7、MB初始浓度为25mg/L、H2O2浓度为4mM、MIL-88(Fe)/NaY/MnFe2O4投加量为0.5g/L、投加60min的最佳参数条件下,MB染料降解率达到98.1%。其声催化活性的增强可能与NaY分子筛作为电子捕获态的功能有关。清除剂试验结果表明,超声波产生的羟基自由基(. oh)在MB的降解中起重要作用。此外,MIL-88(Fe)/NaY/MnFe2O4非常稳定,因为在四次运行中获得的MB降解效率为93.7%。
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引用次数: 0
Potential Sustainable Cement Free Limecrete Based on GGBS & Hydrated Lime as an Alternative for Standardised Prescribed Concrete Applications 基于GGBS和水合石灰的潜在可持续无水泥石灰作为标准化规定混凝土应用的替代方案
Pub Date : 2021-10-14 DOI: 10.31031/rdms.2021.15.000874
Ash Ahmed
A fundamental issue with the active ingredient of concrete, Portland cement, is its energy-intensive manufacturing process, which has led to the cement industry emitting up to 10% of global CO2 levels. To facilitate the reduction in the embodied CO 2 of concrete, the Portland Cement (PC) content has been entirely replaced volumetrically with Hydrated Lime (HL) and ground granulated blast furnace slag (GGBS or SL). GGBS was used to replace hydrated lime content in 10% increments up to 100% GGBS. Analysis of compressive and flexural strength and density testing was performed on samples to investigate the mechanical and physical properties at 7, 28 and 91-day curing ages, whilst flexural testing was conducted at 91 days curing age. Four standard mix ratios, 1:1:3, 1:2:3, 1:1:2 and 2:1 was made for comparison. Two curing conditions were tested at 91-day curing age, these being air-cured and water curing. Results have shown the optimum mix ratio to be 1:1:2 for all mixes. The optimum mix being HL 1:1:2 SL80%, water cured exceeding 25MPa. Throughout the different ratios, it can be concluded that the optimum replacement of GGBS lies between 80-90%; it can also be noted that 100% GGBS content sees a significant drop in compressive and flexural strength, indicating the presence of hydrated lime to be a catalyst for strength gain.
混凝土的活性成分波特兰水泥的一个根本问题是它的能源密集型制造过程,这导致水泥行业的二氧化碳排放量占全球二氧化碳排放量的10%。为了减少混凝土中二氧化碳的含量,硅酸盐水泥(PC)的含量已被水合石灰(HL)和磨碎的高炉矿渣(GGBS或SL)完全取代。GGBS以10%的增量代替水合石灰,直至100% GGBS。对试件进行抗压、抗弯强度和密度测试,研究试件在养护7、28和91天龄期的力学和物理性能,并进行养护91天龄期的抗弯试验。采用1:1:3、1:2:3、1:1:2、2:1四种标准配比进行比较。在91天养护龄期试验了两种养护条件,即空气养护和水养护。结果表明,所有混合料的最佳配比为1:1:2。最佳配比为HL: 1:1:2 SL80%,水固化大于25MPa。纵观不同的比例,可以得出GGBS的最佳替代率在80-90%之间;还可以注意到,当GGBS含量为100%时,抗压强度和抗折强度显著下降,这表明水合石灰的存在是强度增加的催化剂。
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引用次数: 1
Freckle Formation Affected by Geometry Features of Single Crystal Superalloy Castings 单晶高温合金铸件几何特征对雀斑形成的影响
Pub Date : 2021-10-11 DOI: 10.31031/rdms.2021.15.000873
D. Ma
In comparison to our conventional knowledge, some new features of freckle appearance have been observed, indicating new aspects of freckle formation in the Single Crystal (SC) turbine blades made of superalloys. The casting shape has more significant influence on the freckle formation than the local thermal condition. On the transverse sections of the components with curved contour, freckles were exclusively found on the outward curving surfaces having positive curvature, because the surface effect zones of the neighboring sides are overlapped, providing more favorable convection condition. In comparison, the surfaces with negative curvature remained freckle free, because the surface effect of the neighboring sides is divergent from each other. In the longitudinal direction, the freckle formation can be promoted by contracting contour and suppressed by expanding one, respectively.
与我们的传统认识相比,观察到一些雀斑外观的新特征,表明高温合金单晶涡轮叶片中雀斑形成的新方面。铸件形状对雀斑形成的影响比局部热条件更显著。在具有弯曲轮廓的构件的横截面上,雀斑只出现在正向曲率的向外曲面上,这是因为相邻侧面的表面效应区重叠,为对流提供了更有利的条件。相比之下,负曲率的表面仍然没有雀斑,因为相邻边的表面效应彼此发散。在纵向上,收缩轮廓可以促进雀斑的形成,扩大轮廓可以抑制雀斑的形成。
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引用次数: 0
Thermoplastic Composite Materials for the Aerospace Industry 航空航天工业用热塑性复合材料
Pub Date : 2021-09-29 DOI: 10.31031/rdms.2021.15.000872
F. Ozturk
Technology, which is one of the most basic needs of humanity, has continued to develop since the industrial revolution with its undeniable reality. Along with new inventions based on the efficient use of energy, automotive and aerospace industries have become the building blocks of technology. The rapidly developing metal industry has brought the serial manufacturing capability to the industry. On the other hand, high-strength light alloy steels developed in the aerospace industry could not show the desired performance in terms of energy, material life, and design flexibility. Aerospace components, also known as structural materials, should have high stiffness, enhanced toughness, and machinability capabilities [1].
技术作为人类最基本的需求之一,自工业革命以来不断发展,具有不可否认的现实性。随着基于有效利用能源的新发明,汽车和航空航天工业已成为技术的基石。快速发展的金属工业为该行业带来了系列化制造能力。另一方面,在航空航天工业中开发的高强度轻合金钢在能源、材料寿命和设计灵活性方面无法表现出理想的性能。航空航天部件,也称为结构材料,应具有高刚度,增强韧性和可加工性能力[1]。
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引用次数: 1
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Research & Development in Material Science
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