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Discussion on Measuring Method of Phytase Activity According to Term Enzyme Specificity 根据术语酶特异性测定植酸酶活性的方法探讨
Pub Date : 2020-05-14 DOI: 10.31031/rdms.2020.13.000814
Gan Zhao
According to the term enzyme specificity, a discussion on measuring method of phytase activity used now showed that the method could not show the order of inorganic phosphates released from sodium phytate to be helpful to classify or group the phytases studied now, but it is still be useful in production units at the grassroots level and preliminary researches of the phytase. The term enzyme specificity could be useful to interpreting accurately the results got by measuring enzyme activity and to judging the advantages and disadvantages of the method to measure enzyme activity. The discussion on the term enzyme specificity here could also be used as an example for students to study and apply the term they met or will meet.
根据酶特异性这一术语,对现有植酸酶活性测定方法的讨论表明,该方法不能显示植酸钠释放的无机磷酸盐的顺序,不利于对目前所研究的植酸酶进行分类或分组,但对基层生产单位和植酸酶的初步研究仍有一定的参考价值。“酶特异性”一词有助于准确解释测定酶活性所得结果,并判断测定酶活性方法的优缺点。这里关于术语酶特异性的讨论也可以作为一个例子,供学生学习和应用他们已经遇到或将要遇到的术语。
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引用次数: 0
Investigation on the Reducibility of Agbaja Iron Ore Lumps 阿格巴哈铁矿块的可还原性研究
Pub Date : 2020-05-11 DOI: 10.31031/rdms.2020.13.000811
C. Ocheri, Mbah Cn, R. E. Njoku, Urama Na
The investigation on the reducibility of Agbaja iron ore lumps were performed .The chemical compositions, morphology and structural analysis of the ore were examined. Various equipment such as Thermogravimetry (TG), Differential Thermal Analyzer (DTA), X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), Inverted Metallurgical Optical Microscopy and Scanning Electron Microscopy (SEM) with Energy Dispersive Spectroscopy (EDS). The reducibility experiments were performed where a muffle furnace was used as the heating device. The Agbaja iron ore lumps were taken inside six (6) stainless steel containers with diameter 60.75mm x 59.40mm inside diameter with mouths tightly closed by air tight covers having out let for exit gases. Metallurgical coking coal obtained from the Ajaokuta Steel Company Limited was used as the reducing agent. The experiments were performed where the ore lumps were crushed to some sizes and heated in the furnace ranging from 800 ͦC to 1000 ͦC for heating periods with interval temperature was 40 ͦC. The temperature interval rate was put at 40 ͦC. The corresponding heating period was from 20 minutes to 120 minutes with interval time of 20 minutes .The highest corresponding values for each temperature and heating period was put in the following order. The heating temperature of 800 ͦC for 120 minutes had corresponding values of 21.3% of reduction, at 840 ͦC for 120 minutes heating period gave a corresponding value of 25.0% of reduction. The result obtained when the ore lump was heated at 880 ͦC for 120 minutes gave a corresponding value of 26.7% of reduction, at 920 ͦC for 120 minutes , the corresponding value was 27,1% of reduction. The other corresponding values when the ore samples were heated to 960 ͦC and 1000 ͦC for both 120 minutes gave 31.0% and 33.0% degree of reduction respectively. The reduced Agbaja iron ore lumps were further analyzed using the Scanning Electron Microscopy (SEM) with Energy Dispersive Spectroscopy (EDS) and obtained the results as indicated in this orders. The values of Fe content for Agbaja iron ore lump at 800 ͦC for 120minutes was 40.7wt%, at 920 ͦC for 120 minutes, the Fe content value was 60.2wt% and at 1000 ͦC for 120 minutes, the Fe content was 56.2wt%..These results showed that the Agbaja iron ore reduced more at 800 ͦC for 120 minutes (40.7wt %) followed by 1000 ͦC for 120 minutes (56.2wt %) and the least reduced heating period and time was when the iron ore samples was heated at 920 ͦC for 120 minutes (60.2wt %).
对阿格巴哈铁矿块进行了还原性研究,对矿石进行了化学成分、形貌和结构分析。各种设备,如热重仪(TG),差热分析仪(DTA), x射线荧光(XRF), x射线衍射(XRD),倒置冶金光学显微镜和扫描电子显微镜(SEM)与能量色散光谱(EDS)。以马弗炉为加热装置,进行了还原性实验。阿格巴哈铁矿块被装入6个不锈钢容器中,容器内径为60.75mm x 59.40mm,容器口被密封的气密盖紧紧封闭,并有排气口。采用日本制铁公司生产的炼焦煤作为还原剂。实验将矿块破碎至一定大小,在800 ~ 1000ºC的加热炉中加热,间隔温度为40ºC。温度间隔率设置为40ºC。对应的加热时间为20 ~ 120分钟,间隔时间为20分钟,各温度和加热时间对应的最高值依次为:800ºC 120分钟的加热温度对应的减少值为21.3%,840ºC 120分钟的加热温度对应的减少值为25.0%。在880°C下加热120分钟的结果显示,矿块的还原率为26.7%;在920°C下加热120分钟的结果显示,矿块的还原率为27.1%。当矿样在960和1000度下加热120分钟时,其对应值分别为31.0%和33.0%。利用扫描电镜(SEM)和能谱仪(EDS)对还原后的Agbaja铁矿石块体进行了进一步分析,得到了如下顺序的结果。Agbaja铁矿石块体在800°C照射120分钟时的铁含量为40.7wt%,在920°C照射120分钟时的铁含量为60.2wt%,在1000°C照射120分钟时的铁含量为56.2wt%。结果表明,800ºC加热120 min时,Agbaja铁矿石的还原效果最大(40.7wt %),其次是1000ºC加热120 min时,还原效果最小(56.2wt %); 920ºC加热120 min时,还原效果最小(60.2wt %)。
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引用次数: 0
In-vitro Biodegradation of Micro-Arc Oxidation on AZ31 Hybridized with Dopamine Compared to Phytic Acid 与植酸相比,多巴胺杂化AZ31微弧氧化的体外生物降解
Pub Date : 2020-05-11 DOI: 10.31031/rdms.2020.13.000809
H. Soliman, Sun Mingyao, G. Wan
More and more attention has been paid to magnesium alloys as a new generation of medical implant materials [1]. Mg alloys present physical and mechanical properties compatible with those of human bone however, the major obstacle for their use is the undesirable high corrosion rate [1]. This problem encourages the search for a protective coating to expand the use of Mg alloys. Currently, surface modification such as plasma electrolytic process (PEO) [2] Crimson Publishers Wings to the Research Research Article
镁合金作为新一代医用植入材料越来越受到人们的关注[1]。镁合金具有与人骨相适应的物理和机械性能,但其使用的主要障碍是不受欢迎的高腐蚀速率[1]。这个问题促使人们寻找一种保护涂层来扩大镁合金的使用。目前,表面改性如等离子体电解工艺(PEO)[2]以Crimson出版社Wings Research Research文章为主
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引用次数: 0
Preparation of Porous SiO2-TiO2-NiO Synthesized by the Sol-Gel Process and its Characterization 溶胶-凝胶法制备多孔SiO2-TiO2-NiO及其表征
Pub Date : 2020-05-11 DOI: 10.31031/rdms.2020.13.000810
Chong-Santiago Aj, R. Mendoza-Serna, M. Caballero-Díaz, L. Valdez-Castro, J. Barrera-Cortés
An experimental strategy was developed to obtain Si-Ti-Ni transparent sols via the sol-gel process. The sol was prepared from Si(OEt) 4 , Ti(OBu) 4 and Nickel(II) acetylacetonate. The chelating agent (2,4 pentanedione, acacH) was employed to stabilize Ti precursor in order to control their chemical reactivity, avoiding precipitation. A prehydrolyzed tetraethyl orthosilicate (TEOS) sol was the Si source. The sol was characterized by UV-Vis and Fourier Transform Infrared Spectroscopy (FTIR) spectroscopies. The solids treated were characterized by FTIR. Assignments of the simultaneous formation of the Si-O-Ti and Si-O-Ni bonds were done. The sol was polymerized at room temperature (293 K) to obtain gels and these were dried and treated at 673, 773 and 873 K in air. The characterization techniques were, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), 29 Si Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR). The surface area of the solids was determined by N 2 adsorption/desorption isotherms. The corresponding average pore diameter was evaluated using the methods BJH, DA and HK. These models were used because all together cover the full range of the pore size. The purpose of producing porous polymeric system of SiO 2 -TiO 2 -NiO is to combine the properties of each of the oxides in a single material for use in catalytic reactions.
采用溶胶-凝胶法制备Si-Ti-Ni透明溶胶。溶胶由Si(OEt) 4、Ti(OBu) 4和镍(II)乙酰丙酮制备。采用螯合剂(2,4戊二酮,acacH)稳定Ti前驱体,控制其化学反应活性,避免沉淀。预水解正硅酸四乙酯(TEOS)溶胶为硅源。用紫外可见光谱和傅里叶变换红外光谱(FTIR)对溶胶进行了表征。用红外光谱对处理后的固体进行了表征。对同时形成的Si-O-Ti和Si-O-Ni键进行了赋值。溶胶在室温(293 K)下聚合得到凝胶,这些凝胶在673、773和873 K的空气中干燥和处理。表征技术有x射线衍射(XRD)、扫描电镜(SEM)、29硅魔角自旋核磁共振(MAS NMR)等。固体的表面积由n2吸附/解吸等温线测定。采用BJH、DA和HK法对相应的平均孔径进行了评价。使用这些模型是因为它们一起覆盖了孔隙大小的全部范围。制备sio2 - tio2 -NiO多孔聚合物体系的目的是将每种氧化物的性质结合在一种材料中,用于催化反应。
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引用次数: 0
Recycling Graphite for Vanadium Redox Flow Batteries: Options for Usage and Critical Integredients 钒氧化还原液流电池的回收石墨:使用和关键成分的选择
Pub Date : 2020-05-08 DOI: 10.31031/rdms.2020.13.000807
T. Hickmann
Already in 2010, a working group of the European Commission, analysed arround 41 materials and came to the conclusion about their criticality and the risk of supply safety and their ecomic importance. As a result, around 14 matrials were judged critically, and this included graphite as well [8]. For some industry areas, Graphite is estimated as a critical material [9]. For this reason, the importance of Recycling Graphite is growing and it is necessary to look for recycling material.
早在2010年,欧盟委员会的一个工作组就分析了大约41种材料,并得出了它们的临界性、供应安全风险及其经济重要性的结论。结果,大约有14种材料被严格评判,其中包括石墨和[8]。在某些工业领域,石墨被认为是一种关键材料。因此,回收石墨的重要性越来越大,有必要寻找可回收的材料。
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引用次数: 0
Crystallization Kinetics and Physical Properties of Al-3Fe-3Ni Alloy Due to the Order of the Introduction of the Alloying Elements 合金元素引入顺序对Al-3Fe-3Ni合金结晶动力学和物理性能的影响
Pub Date : 2020-04-03 DOI: 10.31031/rdms.2020.13.000804
M. Im, Khriplyviy Ao, Frieze Vv, Romanko Pm, Khokhlova Ja, Khokhlov Ma
The specific features of the crystallization kinetics of the ternary Al-Ni-Fe system due to the order of the introduction of the alloying elements are explained in terms of the cluster structure of the melts of binary metal systems Al-Ni and Al-Fe. It was established that the order of introduction of the alloying elements into the aluminum melt determines the formation of a different cluster structure, which is responsible for the mechanism of formation of crystallization nuclei and the formation of the phase composition of alloys. It is assumed that a substantial supersaturation of the solid solution with nickel atoms is associated with the introduction of Al3Ni-type clusters into the aluminum matrix of the Al-3Ni-3Fe alloy. This concept is confirmed by the presence of two exothermic peaks on the DSC curves in the region before the crystallization of the alloy and explains the abnormally high value of Young’s modulus and the high yield stress of the alloy.
用Al-Ni和Al-Fe二元金属体系熔体的团簇结构解释了三元Al-Ni- fe体系因合金元素引入顺序而产生的结晶动力学的具体特征。确定了合金元素引入铝熔体的顺序决定了不同团簇结构的形成,这是结晶核形成和合金相组成形成的机制。假设镍原子固溶体的大量过饱和与Al-3Ni-3Fe合金的铝基体中引入al3ni型簇有关。在合金结晶之前,DSC曲线上出现了两个放热峰,这证实了这一概念,并解释了合金的异常高杨氏模量和高屈服应力。
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引用次数: 1
Effect of Agricultural Waste Material on the Properties of Portland Cement Pastes 农业废弃物对硅酸盐水泥浆体性能的影响
Pub Date : 2020-03-02 DOI: 10.31031/rdms.2020.13.000802
Darweesh Hhm, Abo El Suoud Mr
The effect of wheat stalk ash (WSA) on the physical, chemical and mechanical properties as well as the hydration of the cement pastes containing it was evaluated, and so it can provide a necessary theoretical basis and a practical guiding significance for practical engineering. It is concluded that WSA could be partially added to cement without any adverse effect on its specific properties, particularly the compressive strength. The free lime content, Ca (OH) 2 is obviously decreased with WSA. The optimum WSA content was 20wt. %, and more than this amount, the specific properties of cement were declined. The polyprobyene admixture (PPP) is the mean reason responsible for the modification and improving most of physical, chemical, and mechanical properties of the hardened cement pastes. The pozzolanic reactions of WSA with Ca (OH) 2 played a vital role to form additional CSH gel-phases that support and enhance the specific properties of the cement.
评价了小麦秸秆灰(WSA)对含其水泥浆体物理、化学、力学性能及水化性能的影响,为实际工程提供了必要的理论依据和实践指导意义。结果表明,在水泥中部分添加WSA对水泥的性能,特别是抗压强度没有不利影响。游离石灰、Ca (OH) 2含量随WSA的增加而明显降低。WSA的最佳含量为20wt。%,超过此量,水泥的性能下降。聚丙烯外加剂(PPP)是对硬化水泥浆体的大部分物理、化学和力学性能进行改性和改善的主要原因。WSA与Ca (OH) 2的火山灰反应对形成额外的CSH凝胶相起着至关重要的作用,这些凝胶相支持并增强了水泥的特定性能。
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引用次数: 5
Study on Hydrodynamic Characteristics of Fluted Floating Garbage Collection Device 带槽浮式垃圾收集装置水动力特性研究
Pub Date : 2020-03-02 DOI: 10.31031/rdms.2020.13.000801
Z. Ting
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引用次数: 0
Room Temperature Photoluminescence and Optical Parameters of Micro Rods ZnO Thin Films Deposited on Silicon Substrates 硅基微棒ZnO薄膜的室温光致发光及光学参数
Pub Date : 2020-02-25 DOI: 10.31031/rdms.2020.12.000798
Hassan K. Juwhari
Micro structured zinc oxide (ZnO) is of potential use in solar cells, solid state gas sensors, and other optoelectronic devices. For the advancement of these technologies, a comprehensive understanding of these materials’ optical characteristics is considered essential. Using the spray pyrolysis (SP) method, thin films of ZnO micro rods are deposited from aqueous zinc chloride solution on silicon substrates held at 350±5 °C. The films have been studied using the data acquired from the X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy (EDS), reflectance and photoluminescence (PL) spectroscopy. Hence, the XRD and SEM confirmed the films’ hexagonal phase and revealed the tapered ends of the hexagonal rods. The optical parameters including the refractive index, extinction coefficient, absorption coefficient, real and imaginary dielectric constants, conductivity, and the energy loss are all deduced from the reflectance spectra. Finally, the photoluminescence spectra of the studied samples are measured at room temperature using two excitation wavelengths: 300 and 365nm. As such, the obtained results confirmed the quality of the prepared films and allowed proper determination of their respective optical characteristics.
微结构氧化锌(ZnO)在太阳能电池、固态气体传感器和其他光电器件中具有潜在的应用前景。为了这些技术的进步,全面了解这些材料的光学特性被认为是必不可少的。采用喷雾热解(SP)方法,在350±5℃的温度下,将氯化锌水溶液沉积在硅衬底上,制备出ZnO微棒薄膜。利用x射线衍射(XRD)、扫描电子显微镜(SEM)、x射线能谱(EDS)、反射率和光致发光(PL)光谱对薄膜进行了研究。因此,XRD和SEM证实了薄膜的六角形相,并揭示了六角形棒的锥形末端。从反射光谱中推导出折射率、消光系数、吸收系数、实介电常数和虚介电常数、电导率和能量损失等光学参数。最后,采用300和365nm两种激发波长,在室温下测量了所研究样品的光致发光光谱。因此,所获得的结果证实了所制备薄膜的质量,并允许适当地确定其各自的光学特性。
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引用次数: 0
Applications of Nanotechnology Towards Detection and Treatment of HIV/AIDs: A Review Article 纳米技术在HIV/AIDs检测和治疗中的应用综述
Pub Date : 2020-02-10 DOI: 10.31031/rdms.2020.12.000796
Mope Edwin Malefane
There are frequent grumbles of HIV investigations that appears to be getting whisker close to a minor but influential word cure. Toxicity, viral reservoirs, societal discrimination and drug resistance increases the challenges faced with HIV detection and treatment. Nanotechnological applications in drug development and delivery promises to combat and correct issues associated with HIV treatment through generation of drugs with pharmacological advantages that are pioneered by unique materials properties at nanoscale compared to bulk, atomic scale or molecular dimensions. This mini review explores the profound research findings on different manipulations of nanosized materials (nanocapsules, nanocarriers, nanocrystals, etc.) towards rapid detection and cure and/or prevention of HIV. Moreover, possibilities for future investigations are suggested based on attained literature investigations and opinions as a roadmap towards successful HIV free generation and numerous advances in nanomedicine.
人们经常抱怨艾滋病毒的研究似乎离“治愈”这个小而有影响力的词越来越近了。毒性、病毒库、社会歧视和耐药性增加了艾滋病毒检测和治疗面临的挑战。纳米技术在药物开发和输送中的应用有望通过产生具有药理优势的药物来对抗和纠正与艾滋病毒治疗相关的问题,这些药物是由纳米尺度上的独特材料特性开创的,与体积、原子尺度或分子尺度相比,纳米尺度上的材料具有独特的药理优势。这篇综述探讨了纳米材料(纳米胶囊、纳米载体、纳米晶体等)在快速检测、治疗和/或预防艾滋病毒方面的不同操作的深刻研究成果。此外,根据已获得的文献调查和意见,提出了未来研究的可能性,作为成功的无艾滋病毒生成和纳米医学的众多进展的路线图。
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引用次数: 1
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Research & Development in Material Science
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