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Technical Development of Arsenic Reduction from Copper Resources by Kyushu University and Sumitomo Metal Mining Co. Ltd. 九州大学与住友金属矿业株式会社从铜资源中还原砷的技术开发。
Pub Date : 2022-01-01 DOI: 10.4144/rpsj.68.124
H. Miki, N. Okibe, G. Suyantara, Keishi Oyama, K. Sasaki, T. Hirajima, Takeshi Nakamura, Yuji Aoki, Yoshiyuki Tanaka, Takahiro Suwa
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引用次数: 0
Solvent Extraction of Rhodium and Ruthenium from Chloride Solutions added Tin(II) with Primary and Secondary Amines 从含伯胺和仲胺的氯化锡溶液中萃取铑和钌
Pub Date : 2022-01-01 DOI: 10.4144/rpsj.68.105
K. Fujii, Koudai Nagano, Tasuma Suzuki, Masakazu Niinae
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引用次数: 1
Study on the Applicability of Passive Treatment for Mine Drainage Treatment at Abandoned Mines in Japan 被动处理技术在日本废弃矿山污水处理中的适用性研究
Pub Date : 2022-01-01 DOI: 10.4144/rpsj.69.71
Takaya Hamai, Kengo Horiuchi, So Furukawa
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引用次数: 0
2D-3D Divergence in Liberation Analysis of Ore Particles 矿石颗粒解离分析中的2D-3D发散
Pub Date : 2022-01-01 DOI: 10.4144/rpsj.68.132
T. Ueda, T. Oki
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引用次数: 0
Distribution of Precious Metals in Two Liquids Phase Separation of the Fe-Cu-C, Fe-Pb-C, Fe-Ag-C and Ni-Ag-C Systems with Carbon Saturation 含碳饱和Fe-Cu-C、Fe-Pb-C、Fe-Ag-C和Ni-Ag-C体系两液相分离中贵金属的分布
Pub Date : 2022-01-01 DOI: 10.4144/rpsj.69.11
Takashi Murata, K. Yamaguchi,
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引用次数: 0
Impact of Biodegradable Plastics, Especially PHBH, on Mechanical Recycling 生物降解塑料,特别是PHBH对机械回收的影响
Pub Date : 2022-01-01 DOI: 10.4144/rpsj.68.143
C. Tokoro, Y. Takaya, Y. Ando, Tomoki Nakamura, Takeshi Chiba, N. Miyatake
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引用次数: 1
Study on Arsenic Methylation Properties of Cellulomonas sp. K31 纤维素单胞菌K31的砷甲基化特性研究
Pub Date : 2022-01-01 DOI: 10.4144/rpsj.68.117
M. Miyatake, J. Hirose, K. Shiomori, H. Yokoi
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引用次数: 0
Separation and Recovery of Cobalt and Nickel from Sulfuric Acid Leach Liquor of Zinc Smelting Residue with Acidic Extractants 用酸性萃取剂分离回收锌渣硫酸浸出液中的钴和镍
Pub Date : 2022-01-01 DOI: 10.4144/rpsj.69.5
Masashi Nakaso, Masakazu Niinae
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引用次数: 0
Runoff Characterization and Water Quality in the River Basin Near the Ningtyo-toge Mine, Okayama Prefecture 冈山县宁tyo -toge矿区附近河流流域的径流特征和水质
Pub Date : 2021-01-01 DOI: 10.4144/RPSJ.67.139
Shingo Tomiyama, Kana Odashiro, T. Igarashi, Ryota Kawano, Y. Ohara
To understand water mass balance and behavior of major elements in river basin is an important issue in advancing the management of abandoned and closed mines. This paper describes the response of river runoff due to rainfall, and the relationship between water mass balance and river water quality. In the river basin around the Ningyo-toge Mine, the runoff increased when it rained more than 50 mm d–1 and continued for several days after the rain, while in case of heavy rain over 500 mm, the effect of intermediate runoff extended to the next month. The river water quality was Na– Cl type in the upstream, while it was Na–HCO3 type or Ca–HCO3 type in the middle to downstream, and contained dissolved Si in the entire river basin. Based on the measured anions and cations, it is inferred HCO3 and Ca2+ results from the dissolution of carbonate minerals, and that Na+ and Cl– are derived from sea salt. Since a correlation between the concentration of Si and runoff was observed, the Si concentration may be regulated by both groundwater flow to the river and the dissolution rate of feldspar.
了解流域水质量平衡及其主要元素的变化规律,是推进废闭矿山治理的重要问题。本文阐述了降雨对河流径流的响应,以及水质量平衡与河流水质的关系。在宁窑托格矿区周边流域,降雨量大于50 mm d-1时,径流增加,并在雨后持续数天,大于500 mm暴雨时,中间径流的作用延续到下个月。河流水质上游为Na - Cl型,中下游为Na - hco3型或Ca-HCO3型,整个流域均含溶解Si。根据测定的阴离子和阳离子,推测HCO3和Ca2+来自碳酸盐矿物的溶解,Na+和Cl -来自海盐。由于Si浓度与径流之间存在相关性,因此Si浓度可能受到流入河流的地下水和长石溶解速率的调节。
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引用次数: 0
Surface Complexation Modeling of Cd on Mn(III) Oxyhydroxide (γ-MnOOH) for Neutralizing Model of Acid Mine Drainage 镉在Mn(III)羟基氧化锰(γ-MnOOH)上的表面络合模拟
Pub Date : 2021-01-01 DOI: 10.4144/RPSJ.67.117
S. Fuchida, Shota Tajima, C. Tokoro
Acid mine drainage (AMD) releasing from abandoned mines in Japan sometimes contains a high level of manganese (Mn) over the effluent standard (10 mg dm–3) with cadmium (Cd) and zinc. Cadmium is normally precipitate as hydroxides at pH 9–10, while it can be removed at a lower pH range of approximately 8–9 by surface complexation with metal hydroxides such as ferrihydrite and gibbsite. In this study, we examined the removal performance of Cd by manganite (γ-MnOOH) which is trivalent Mn oxide by an adsorption experiment, and found the Cd concentration decreased over pH 9.0 below the effluent standard (0.03 mg dm–3), which the surface complex equilibrium constant was Log K = –4.0. A neutralizing experiment of the AMD containing Mn (39 mg dm–3) and Cd (0.077 mg dm–3) from the X mine showed the Cd was removed at pH 8–10, and a chemical equilibrium calculation revealed the surface complexation on γ-MnOOH was the main removal mechanism. Our results therefore suggest the Mn oxidation and surface complexation with the product is the controlling factor Cd removability during the neutralization of AMD containing Mn.
在日本,废弃矿山排放的酸性矿山废水有时含有高水平的锰(Mn),超过了排放标准(10 mg dm-3),还含有镉(Cd)和锌。在pH值为9-10时,镉通常以氢氧化物的形式析出,而在较低的pH值范围(约为8-9)下,镉可以通过与金属氢氧化物(如水合铁和三水铝石)的表面络合去除。本研究通过吸附实验考察了三价氧化锰(γ-MnOOH)对Cd的去除效果,发现在pH为9.0时,Cd浓度低于出水标准(0.03 mg dm-3),其表面络合平衡常数为Log K = -4.0。对X矿含Mn (39 mg dm-3)和Cd (0.077 mg dm-3)的AMD进行了中和实验,结果表明Cd在pH 8 ~ 10范围内被去除,化学平衡计算表明γ-MnOOH表面络合是主要的去除机制。因此,我们的研究结果表明,在含锰的AMD中和过程中,Mn的氧化和与产物的表面络合是控制Cd去除率的因素。
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引用次数: 2
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Resources Processing
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