Long-term assessment of near-surface air pollutants was done at the semi-arid region of Jaipur in the western part of India from 2018 to 2022. The annual mean mass concentrations of PM10, PM2.5, NOx, SO2, CO, and ozone were 121.37 ± 14.65 µg/m3, 54.37 ± 7.02 µg/m3, 43.65 ± 7.31 µg/m3, 12.36 ± 1.08 µg/m3, 0.94 ± 0.05 mg/m3, and 45.51 ± 3.35 µg/m3, respectively. The mass concentrations of PM2.5, PM10, and NOx exceeded ~ 36%, 62%, and 11% of days to their respective annual National Ambient Air Quality Standards (NAAQS), while SO2 and ozone remained within its permissible limits. A significant decline in pollutant concentrations was observed in 2020, attributed to the substantial reduction in various human-driven activities due to the nationwide lockdown amid COVID-19 pandemic. The sharp decline in anthropogenic emissions provided a rare glimpse into the environmental impact of human, industrial and economic operations. Seasonal variations indicated increased pollutant levels during the post-monsoon and winter seasons, attributed to a lower and stable boundary layer, constraining pollutant dispersion. Additionally, elevated pollutant concentrations coincided with high wind speed during the pre-monsoon, transporting large dust particles from the Thar Desert region to the west of Rajasthan. The potential source sectors and the transport pathways of pollutants at Jaipur were investigated with the air mass back-trajectory analysis. The enhanced pollutants over the region are found to be largely associated with the trajectories mainly from the west (~ 39%), west-southeast (~ 27%) and southwest (~ 15%) directions.
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