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Continuous-wave and Fe2+:ZnSe passively Q-switched mid-infrared lasers based on 2at.% Er3+:CaF2 crystal 基于 2at.% Er3+:CaF2 晶体的连续波和 Fe2+:ZnSe 被动 Q 开关中红外激光器
Q3 Physics and Astronomy Pub Date : 2024-03-07 DOI: 10.1016/j.rio.2024.100650
Zhonghai Yang , Zhen Zhang , Zhenhua Cong , Peng Liu , Zhigang Zhao , Liangbi Su , Zhaojun Liu

A compact high-power 2.8-µm laser with a 2 at.%-doped Er3+:CaF2 crystal was demonstrated, which delivered a maximum output power of 2.848 W with a slope efficiency of 26.3 %. To the best of our knowledge, this is the highest output power among all the reported LD end-pumped Er3+-doped fluoride crystal lasers. Experimentally, the negative thermal lens effect was characterized and the thermal lens optical diopters for two axes were obtained as Mx = -0.21 m−1/W and My = -0.33 m−1/W. In addition, the visible fluorescence spectra of Er3+:CaF2 crystal with and without laser operation were measured and analyzed. With Fe2+:ZnSe as saturable absorber, a passively Q-switched 2.759-µm Er3+:CaF2 laser with an average output power of 75 mW, a peak power of 2.39 W, a single pulse energy of 1.81 µJ, and a pulse width of 755.3 ns was obtained at a repetition rate of 41.55 kHz.

我们展示了一种紧凑型高功率 2.8 微米激光器,该激光器采用掺杂 2%的 Er3+:CaF2 晶体,最大输出功率为 2.848 W,斜率效率为 26.3%。据我们所知,这是所有已报道的 LD 端泵掺杂 Er3+ 的氟化物晶体激光器中输出功率最高的。在实验中,对负热透镜效应进行了表征,得到了两个轴的热透镜光学斜率分别为 Mx = -0.21 m-1/W 和 My = -0.33 m-1/W。此外,还测量和分析了 Er3+:CaF2 晶体在有激光操作和无激光操作时的可见荧光光谱。以 Fe2+:ZnSe 作为可饱和吸收体,在 41.55 kHz 的重复频率下,获得了平均输出功率为 75 mW、峰值功率为 2.39 W、单脉冲能量为 1.81 µJ、脉宽为 755.3 ns 的被动 Q 开关 2.759µm Er3+:CaF2 激光。
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引用次数: 0
Surface relief structures for light coupling at air/liquid interface 用于空气/液体界面光耦合的表面浮雕结构
Q3 Physics and Astronomy Pub Date : 2024-03-01 DOI: 10.1016/j.rio.2024.100648
Lina Zang , Regis Barille , Sonia Zielinska , Aleksandra Korbut , Ewelina Ortyl

Relief patterns were photoinduced on the surface of a thin film floating on water. The structures have a length of several millimeters with a width of 33 μm. Both the intensity and the polarization of the irradiated light change the characteristics of the generated patterns. The light induced structuration is the result of simultaneously a reversible material transport originated by photoisomerization of azobenzene units and a process of self-organization of the molecules. The structures were used as waveguide or grating to couple light at the air/liquid interface on a short or long distance. The fabrication of waveguides can be extended to any liquid substrates.

浮在水面上的薄膜表面上出现了光诱导浮雕图案。这些结构的长度为几毫米,宽度为 33 微米。照射光的强度和偏振都会改变所生成图案的特征。光诱导结构化同时是偶氮苯单元光异构化产生的可逆物质传输和分子自组织过程的结果。这些结构可用作波导或光栅,在空气/液体界面上实现短距离或长距离的光耦合。波导的制造可扩展到任何液体基底。
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引用次数: 0
Device modelling and numerical analysis of high-efficiency double absorbers solar cells with diverse transport layer materials 采用不同传输层材料的高效双吸收太阳能电池的器件建模和数值分析
Q3 Physics and Astronomy Pub Date : 2024-02-24 DOI: 10.1016/j.rio.2024.100647
Sheikh Hasib Cheragee , Mohammad Jahangir Alam

Recently, a lot of focus has been placed on cesium lead iodide (CsPbI3) since it is considered a potentially useful inorganic halide perovskite with improved stability. Moreover, another potential absorber material is the mixed chalcogenide CZTSSe, which is abundant on Earth, cheap, environmentally acceptable, and has excellent photovoltaic performance. This research numerically simulated a novel double absorber solar cell structure employing CsPbI3 and CZTSSe absorbers in the active layer in SCAPS-1D. The current study analyses the effects of various electron and hole transport materials, back contact material's work functions, working temperatures, variations in defect concentration, and absorber thickness on the performance of photovoltaic devices. After researching a variety of distinct arrangements of double absorber solar cells, it was realized that the FTO/STO/CsPbI3/CZTSSe/NiO/W cell configuration exhibited the best overall performance with an open circuit voltage (Voc) at 1.0207 V, a short circuit current density (Jsc) at 41.815426 mA/cm2, Fill Factor (FF) at 87.50 %, and a Power Conversion Efficiency (PCE) at 37.35 %. The modeling of the device showed that a thickness of around 1.4 µm for the CZTSSe absorber is optimal. This simulation shows that when the working temperature in the cell and the defect concentration in the absorber increase, the efficiency of the device reduces uniformly, and the device is stable at 300 K temperature. In conclusion, if the material's work function is greater than 5.20 eV, then it is suitable for use as an anode.

最近,碘化铯铅(CsPbI3)受到了广泛关注,因为它被认为是一种具有潜在用途且稳定性更好的无机卤化物包晶。此外,另一种潜在的吸收材料是混合钙钛矿 CZTSSe,它在地球上资源丰富,价格低廉,环境可接受,而且具有优异的光伏性能。本研究在 SCAPS-1D 中对一种新型双吸收太阳能电池结构进行了数值模拟,在活性层中使用了 CsPbI3 和 CZTSSe 吸收剂。本研究分析了各种电子和空穴传输材料、背接触材料的功函数、工作温度、缺陷浓度变化以及吸收体厚度对光伏器件性能的影响。在对各种不同排列的双吸收器太阳能电池进行研究后,发现 FTO/STO/CsPbI3/CZTSSe/NiO/W 电池配置的整体性能最佳,其开路电压 (Voc) 为 1.0207 V,短路电流密度 (Jsc) 为 41.815426 mA/cm2,填充因子 (FF) 为 87.50 %,功率转换效率 (PCE) 为 37.35 %。设备建模显示,CZTSSe 吸收体的最佳厚度约为 1.4 µm。模拟结果表明,当电池的工作温度和吸收体中的缺陷浓度增加时,器件的效率会均匀降低,器件在 300 K 温度下保持稳定。总之,如果材料的功函数大于 5.20 eV,则适合用作阳极。
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引用次数: 0
Utilization of natural dyes extracted from mustard flower (Genus: Brassica, Species: Napus) as photosensitizer for DSSC: Experimental and computational studies 利用从芥菜花(属:芸苔属,种:Napus)中提取的天然染料作为 DSSC 的光敏剂:实验和计算研究
Q3 Physics and Astronomy Pub Date : 2024-02-23 DOI: 10.1016/j.rio.2024.100631
Abhilasha Tiwari, Nikhil Srivastav, Pankaj Srivastava

Dye-sensitized solar cells (DSSC) are considered as one of the most promising photovoltaic technologies, while exploring alternatives to traditional silicon-based solar cells. Dye sensitizer is a very important component of DSSC and the use of natural dyes in these cells is a promising development for this technology, as it has non-hazardous impact on the environment. This work reports the new natural dye extracted from Brassica Napus flower petals and used as sensitizer in TiO2 based DSSC. UV–Vis spectra showed the presence of carotenoid and flavonoid pigments along with broad absorption in dye loaded TiO2. FITR revealed functional groups in the Brassica Napus dye extract. Mass spectroscopy was used to find major constituents present in extract. With the natural Brassica Napus sensitizer and TiO2, photovoltaic performance results viz. conversion efficiency (ɳ%) 0.062, short circuit current density (Jsc) 0.45 mA/cm2, open circuit voltage (Voc) 0.260 V and fill factor (FF) 0.52 were observed. Further, HOMO-LUMO levels of constituents present in Brassica Napus have been measured via CV measurements and compared with relative energetic obtained by computational studies. The transport characteristics revealed from EIS studies were used to rationalize the observed photo-voltaic performance of the DSSC.

染料敏化太阳能电池(DSSC)被认为是最有前途的光伏技术之一,同时也在探索传统硅基太阳能电池的替代品。染料敏化剂是 DSSC 的一个非常重要的组成部分,在这些电池中使用天然染料对环境无有害影响,是这项技术的一个有前途的发展。这项研究报告了从芸薹属植物花瓣中提取的新型天然染料,并将其用作基于二氧化钛的 DSSC 的敏化剂。紫外-可见光谱显示,在负载染料的二氧化钛中存在类胡萝卜素和类黄酮色素以及宽吸收。FITR 揭示了芸苔素染料提取物中的官能团。质谱法用于发现提取物中存在的主要成分。利用天然芸苔素敏化剂和 TiO2,观察到光伏性能结果,即转换效率(ɳ%)为 0.062,短路电流密度(Jsc)为 0.45 mA/cm2,开路电压(Voc)为 0.260 V,填充因子(FF)为 0.52。此外,通过 CV 测量还测出了甘蓝中存在的成分的 HOMO-LUMO 水平,并与计算研究获得的相对能量进行了比较。EIS 研究揭示的传输特性被用来合理解释 DSSC 的光电性能。
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引用次数: 0
Porous core fiber with hybrid cladding for ultra-flattened dispersion and low loss propagation of terahertz waves 具有混合包层的多孔纤芯光纤,用于太赫兹波的超扁平色散和低损耗传播
Q3 Physics and Astronomy Pub Date : 2024-02-19 DOI: 10.1016/j.rio.2024.100646
Md Anwar Sadath , Jacob Kokinda , Dayang Lin , Md Sanwar Hossain , Qing Gu

This work proposes a design of a porous-core photonic crystal fiber (PC-PCF) made of a cyclic olefin copolymer, Zeonex, with a hybrid cladding for low-loss terahertz (THz) wave transmission. A combination of circular and elliptical air holes is employed, resulting in a very low material absorption loss of 0.045 cm-1 at Dcore = 450 µm and f = 1 THz. A flat dispersion of 0.73 ± 0.13 ps/THz/cm is obtained for a broad frequency range of 0.5–1.4 THz. Core diameter and frequency response of other key features such as normalized frequency (V-parameter), confinement loss, effective area, nonlinearity and the percentage of the power flow through different sections of the proposed PC-PCF are also analyzed. Comparing to state-of-the-art, our design is superior in terms of loss, dispersion and power fraction. Our proposed design can be manufactured using the established extrusion process and be used for long distance low-loss Terahertz (THz) communication.

本研究提出了一种多孔纤芯光子晶体光纤(PC-PCF)的设计方案,该光纤由环状烯烃共聚物 Zeonex 与混合包层制成,用于低损耗太赫兹(THz)波传输。由于采用了圆形和椭圆形气孔组合,因此在 Dcore = 450 µm 和 f = 1 THz 时,材料吸收损耗非常低,仅为 0.045 cm-1。在 0.5-1.4 THz 的宽频率范围内,可获得 0.73 ± 0.13 ps/THz/cm 的平坦色散。此外,还分析了磁芯直径和其他关键特性的频率响应,如归一化频率(V 参数)、约束损耗、有效面积、非线性以及通过拟议 PC-PCF 不同部分的功率流百分比。与最先进的设计相比,我们的设计在损耗、色散和功率分数方面更胜一筹。我们提出的设计可以使用成熟的挤压工艺制造,并可用于长距离低损耗太赫兹(THz)通信。
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引用次数: 0
Optimizing microlens arrays for incoherent HiLo microscopy 优化用于非相干 HiLo 显微镜的微透镜阵列
Q3 Physics and Astronomy Pub Date : 2024-02-16 DOI: 10.1016/j.rio.2024.100622
Ziao Jiao , Xi Chen , David Day Uei Li

HiLo microscopy is a powerful, low-cost, and easily configurable technique for acquiring high-contrast optically-sectioned images. However, traditional HiLo microscopes are based on coherent light sources with diffusive glass plates or incoherent light sources with digital mirror devices (DMD) and spatial light modulators (SLM), which are more expensive. Here, we propose a new low-cost HiLo microscopy technique using MLAs and incoherent LED light sources. We simulated structured illumination (SI) patterns and HiLo image generation. To observe how MLAs affect HiLo images, we used three common MLAs with specific microlens pitch and numerical aperture (NA) to generate periodic illumination patterns. Our simulations concluded that the MLA's NA does not significantly affect HiLo images, and a larger lens pitch can bring a higher image contrast. However, there is an optimized lens pitch. If the lens pitch is equal to or higher than 140 μm, artifacts are observed in HiLo images. Based on our simulations, employing the cross-type MLA with a 0.01NA and a period of 120 μm yields the optimal HiLo image (94.6 % contrast). In our quantitative analysis with the traditional HiLo, where SI patterns were set with the same period, we calculated the SSIM index between each HiLo-Ground Truth image pair. The cross-type MLA HiLo performed slightly better (SSIM = 0.9554) than the traditional HiLo (SSIM = 0.9396). However, when using the hexagon-type MLA, artifacts were evident in the final HiLo image (SSIM = 0.9054). The cylinder-type MLA HiLo result (SSIM = 0.9366) is similar to the traditional HiLo. To our knowledge, this is the first numerical study about MLA-based HiLo microscopy. This study can benefit researchers using MLAs and incoherent light sources to configure their low-cost HiLo microscopes.

HiLo 显微镜是一种功能强大、成本低廉且易于配置的技术,可用于获取高对比度的光学切片图像。然而,传统的 HiLo 显微镜基于带有扩散玻璃板的相干光源或带有数字镜像设备(DMD)和空间光调制器(SLM)的非相干光源,这些设备都比较昂贵。在这里,我们提出了一种使用工作重点和非相干 LED 光源的新型低成本 HiLo 显微镜技术。我们模拟了结构照明(SI)模式和 HiLo 图像生成。为了观察 MLA 对 HiLo 图像的影响,我们使用了三种具有特定微透镜间距和数值孔径 (NA) 的普通 MLA 来生成周期性照明模式。模拟结果表明,MLA 的 NA 对 HiLo 图像的影响不大,而较大的透镜间距可以带来更高的图像对比度。不过,镜头间距有一个最佳值。如果透镜间距等于或大于 140 μm,HiLo 图像中就会出现伪影。根据我们的模拟,采用 0.01NA 和周期为 120 μm 的十字型 MLA 可获得最佳 HiLo 图像(94.6% 对比度)。在对传统 HiLo 进行定量分析时,SI 图案的周期相同,我们计算了每对 HiLo-Ground Truth 图像之间的 SSIM 指数。十字型 MLA HiLo 的表现(SSIM = 0.9554)略好于传统 HiLo(SSIM = 0.9396)。然而,在使用六边形 MLA 时,最终 HiLo 图像中出现了明显的伪影(SSIM = 0.9054)。圆柱型 MLA HiLo 结果(SSIM = 0.9366)与传统 HiLo 相似。据我们所知,这是第一项关于基于 MLA 的 HiLo 显微镜的数值研究。这项研究可使使用 MLA 和非相干光源来配置低成本 HiLo 显微镜的研究人员受益匪浅。
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引用次数: 0
A gateway to synthesis of all-optical devices of desired functionalities 合成具有所需功能的全光器件的途径
Q3 Physics and Astronomy Pub Date : 2024-02-12 DOI: 10.1016/j.rio.2024.100644
Sarang Medhekar

I propose combining of all-optical devices to produce an all-optical device that exhibits a desired input–output (I/O) characteristic (i.e., a desired functionality). There could be infinite distinct combinations of same/different all-optical devices of same/different parameters resulting in possibility of infinite number of all-optical devices with distinct I/O characteristics, and hence, the proposal presented here opens-up a gateway to synthesis of all-optical devices of desired functionalities. To give a few of examples in support of the proposal, I show certain series and parallel combinations of nonlinear Mach-Zehnder interferometers (NMZIs) to synthesize an (i) ideal optical switch (with step like I/O characteristic), (ii) optical isolator/optical stabilizer (iii) optical pulse generator (iv) optical power filter and (v) optical limiter. The analytical findings are verified using BPM simulations in presence of losses also.

我建议将全光学器件组合起来,以生产出具有所需输入输出(I/O)特性(即所需功能)的全光学器件。相同/不同参数的全光器件可以有无限种不同的组合,从而可能产生无限种具有不同输入/输出特性的全光器件,因此,本文提出的建议为合成具有所需功能的全光器件开辟了一条途径。为支持这一提议,我列举了几个例子,说明非线性马赫-泽恩德干涉仪(NMZI)的某些串联和并联组合,以合成 (i) 理想光开关(具有类似阶跃的输入/输出特性)、(ii) 光隔离器/光稳定器、(iii) 光脉冲发生器、(iv) 光功率滤波器和 (v) 光限幅器。在存在损耗的情况下,还使用 BPM 仿真验证了分析结果。
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引用次数: 0
Optical properties study of a perovskite solar cell film stack by spectroscopic ellipsometry and spectrophotometry 通过分光椭偏仪和分光光度计研究过氧化物太阳能电池薄膜堆的光学特性
Q3 Physics and Astronomy Pub Date : 2024-02-12 DOI: 10.1016/j.rio.2024.100640
Maria Fernanda Villa-Bracamonte , Jose Raul Montes-Bojorquez , Arturo A. Ayon

Spectroscopic ellipsometry is a reproducible and non-invasive characterization technique that allows the evaluation of multilayered structures. However, it is an indirect technique and requires the use of well-calibrated models to correctly analyze the materials. In this work, we report a multilayer modeling approach to investigate the optical properties of the three layers of interest typically employed on an inverted perovskite solar cells structure, namely, indium-tin-oxide (ITO) as a transparent anode, poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) as a hole transport layer, and methylammonium lead iodide (MAPbI3) as the perovskite layer. The parameterized optical constants based on oscillator models were simultaneously fitted to ellipsometry and intensity-transmission data and validated with ultraviolet–visible (UV–Vis) spectroscopy and profilometry. We propose this multilayer modeling approach as a method to be employed throughout the different stages of the fabrication process to study the distinct mechanisms that impact the final performance of a photovoltaic device.

光谱椭偏仪是一种可重复的非侵入式表征技术,可对多层结构进行评估。然而,这是一种间接技术,需要使用校准良好的模型才能正确分析材料。在这项工作中,我们报告了一种多层建模方法,用于研究倒置包晶体太阳能电池结构中通常采用的三层相关材料的光学特性,即作为透明阳极的氧化铟锡(ITO)、作为空穴传输层的聚(3,4-亚乙二氧基噻吩):聚(苯乙烯磺酸)(PEDOT:PSS)和作为包晶体层的碘化甲铵铅(MAPbI3)。基于振荡器模型的参数化光学常数同时与椭偏仪和强度透射数据进行了拟合,并通过紫外可见(UV-Vis)光谱和轮廓仪进行了验证。我们建议将这种多层建模方法作为一种方法,在整个制造过程的不同阶段使用,以研究影响光伏设备最终性能的不同机制。
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引用次数: 0
One- and two-slit experiments using photons and electrons: A proper resolution 使用光子和电子的单缝和双缝实验:适当的分辨率
Q3 Physics and Astronomy Pub Date : 2024-02-10 DOI: 10.1016/j.rio.2024.100638
Andrew Das Arulsamy

We construct proper microscopic propositions to consistently capture and explain the interference patterns obtained for electrons and photons, detected individually or otherwise, in one- and two-slit experiments. We propose that for single-photon detections (after time integration), no interference pattern is obtained if one uses non-transparent slit material with slit holes (not diffraction slits). The non-transparent slit material does not permit photons to transmit, reflect internally nor refract. However, the same slit holes can produce the usual interference pattern with electromagnetic waves due to interfering in-phase and out-of-phase light waves. As for the electrons, detected individually or not, partial interference patterns can always be obtained from the two-slit experiment when one of the slits is closed (one at a time), which then can be manually overlapped to produce the complete interference pattern of a double-slit experiment. These new theoretically constructed experimental results for photons and electrons can be readily verified with our current technology using suitable optically non-transparent (for photons) and highly insulating (for electrons) slit materials.

我们构建了适当的微观命题,以一致地捕捉和解释在单缝和双缝实验中单独或以其他方式探测到的电子和光子的干涉图样。我们提出,对于单光子探测(时间积分后),如果使用带有狭缝孔(非衍射狭缝)的非透明狭缝材料,就不会获得干涉图样。非透明狭缝材料不允许光子传输、内部反射或折射。然而,由于同相和异相光波的干涉,同样的狭缝孔可以产生通常的电磁波干涉模式。至于电子,无论是否单独探测到,当其中一个狭缝关闭时(一次关闭一个),总能从双缝实验中得到部分干涉图样,然后可以手动重叠,产生双缝实验的完整干涉图样。这些新的理论构建的光子和电子实验结果可以很容易地通过我们现有的技术,使用合适的光学非透明(光子)和高绝缘(电子)狭缝材料进行验证。
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引用次数: 0
Influence of Ni2+ ions on the physical, structural, elastic, optical, and thermal aspects of oxy fluoro borate glasses mixed with sesquioxide ions (Al3+/Y3+/Sb3+) Ni2+ 离子对混合了倍半二氧化物离子(Al3+/Y3+/Sb3+)的氟硼酸氧玻璃的物理、结构、弹性、光学和热学方面的影响
Q3 Physics and Astronomy Pub Date : 2024-02-10 DOI: 10.1016/j.rio.2024.100632
B.K. Sudhakar , N. Rama Krishna Chand , T. Vennela , P.V.S. Sairam , G. Ravi Kumar , G. Srinivasa Rao , Ch. Srinivasa Rao

Oxy Fluoro Borate (OFB) Glasses mixed with Sesquioxide ions (Al3+/Y3+/Sb3+) were synthesized using the traditional melt quenching technique. The properties of the structure of the glasses prepared are investigated by SEM, EDS and XRD methods. Variations in properties like density in glasses allow Nickel/Aluminium/Antimony/Yttrium ions to go through the borate glass matrix with an increase in respective dopant mole fraction. The decrease in the values of different elastic constants with B-O-Ni/Al/Sb/Y bonds and alsoby the function of NiO/Al2O3/Sb2O3/Y2O3 as a modifier and converting a portion of BO3 tetrahedral units into BO4octahedral units indicates the depolymerization in the glass matrix. The I.R. spectra and FTIR spectra show an increment in the occupation of cations Ni2+, Y3+, Sb3+ and Al3+ ions in the octahedral positions of the glass matrix with an enhancement in their molefraction. Creation of NBOs owing to the transformation of BO3 to BO4 units is greater in Al3+ and the smallest in Y3+ with an increment in the sesquioxide concentration at a 1.00 mol% NiO concentration. The dominance of the nickel ions octahedral occupancy in the glasses prepared is revealed by the optical absorption spectra, which may be because of the ligand fields produced by various ions of sesquioxides present within the glass matrix creating NBO and many trapped electrons at the donor centers. Photoluminescence spectra of the prepared glasses show the octahedral occupation of the Ni2+ ions that is indicated by the transitions 3A2g(F) ↔ 3T1g(P) and 3T1g(P) → 3T2g(F). The synthesized glasses exhibit effective luminescence by Nickel ions, and the AlNi and NiAl glass series exhibit superior luminescence properties owing to their highest emission cross-sections compared with the other series of prepared glasses.

采用传统的熔融淬火技术合成了混合有二氧化硅离子(Al3+/Y3+/Sb3+)的氟硼酸氧玻璃(OFB)。通过 SEM、EDS 和 XRD 方法研究了所制备玻璃的结构特性。随着掺杂剂摩尔分数的增加,镍/铝/锑/钇离子可以穿过硼酸盐玻璃基体,从而使玻璃的密度等特性发生变化。不同弹性常数的值随 B-O-Ni/Al/Sb/Y 键的增加而降低,同时,NiO/Al2O3/Sb2O3/Y2O3 作为改性剂,将部分 BO3 四面体单元转化为 BO4 八面体单元,这表明玻璃基质中存在解聚现象。电离光谱和傅立叶变换红外光谱显示,Ni2+、Y3+、Sb3+ 和 Al3+ 等阳离子占据了玻璃基质的八面体位置,其摩尔比例也有所增加。在氧化镍浓度为 1.00 摩尔%时,随着倍半二氧化物浓度的增加,Al3+ 中因 BO3 向 BO4 单元转化而产生的 NBO 较多,而 Y3+ 中产生的 NBO 较少。光学吸收光谱显示,在制备的玻璃中,镍离子八面体占据主导地位,这可能是因为玻璃基体中存在的各种倍半氧化物离子产生了配体场,在供体中心形成了 NBO 和许多被截留的电子。所制备玻璃的光致发光光谱显示出 Ni2+ 离子的八面体占据,这可以通过跃迁 3A2g(F) ↔ 3T1g(P) 和 3T1g(P) → 3T2g(F) 来表示。合成的玻璃在镍离子的作用下表现出有效的发光特性,与其他制备的玻璃系列相比,AlNi 和 NiAl 玻璃系列因其最高的发射截面而表现出更优越的发光特性。
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