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Mechanisms of Raman scattering spectrum of light from pyridine molecule in the lower frequency range 低频范围内吡啶分子的拉曼散射光谱机制
Q3 Physics and Astronomy Pub Date : 2024-04-08 DOI: 10.1016/j.rio.2024.100685
Dilafruz Khudoyberdieva , Shavkat Otajonov , Bakhodir Eshchanov , Husan Eshquvatov , Nuraddin Abdullayev

The laws of interaction of electromagnetic wave radiation with pyridine molecules and atoms were studied using Raman light scattering spectra of light, and it was shown that the spectra appearing in the lower frequency range (0 ÷ 1031 cm−1) are related to the rotational-rocking movement of molecules. Based on quantum-chemical calculations, a structural model of the pyridine molecule was created. The possibility of determining the bond lengths and angles between the atoms in the pyridine molecule was suggested. Based on the obtained results, the frequency values of the Raman scattering spectra of light from the pyridine molecule were determined by theoretical calculations and compared with the experimental results. Based on the analysis of the results of the research, it was found that the intensity of the Raman scattering spectrum of the light generated by the rotational-rocking laws of the pyridine molecule is significantly smaller than the intensity of the spectra corresponding to other frequencies.

利用拉曼光散射光谱研究了电磁波辐射与吡啶分子和原子的相互作用规律,结果表明,出现在较低频率范围(0 ÷ 1031 cm-1)的光谱与分子的旋转摇摆运动有关。根据量子化学计算,建立了吡啶分子的结构模型。提出了确定吡啶分子中原子间的键长和角度的可能性。根据所获得的结果,通过理论计算确定了吡啶分子光的拉曼散射光谱的频率值,并与实验结果进行了比较。根据对研究结果的分析,发现由吡啶分子的旋转摇摆规律产生的光的拉曼散射光谱强度明显小于其他频率对应的光谱强度。
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引用次数: 0
Corrigendum to “Synthesis of Tio2 photocatalyst with tunable optical properties and exposed facet for textile wastewater treatment” [Res. Opt., Res. Opt. 13 (2023) 100545] 具有可调光学特性和暴露面的 Tio2 光催化剂的合成用于纺织废水处理》[Res. Opt.
Q3 Physics and Astronomy Pub Date : 2024-04-06 DOI: 10.1016/j.rio.2024.100666
Faridah Abu Bakar , Nur Syahidatul Insyirah Mohd Foad
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引用次数: 0
Editorial preface for special issue Recent Advances in Ultrafast Fiber Lasers 超快光纤激光器的最新进展》特刊编辑序言
Q3 Physics and Astronomy Pub Date : 2024-04-03 DOI: 10.1016/j.rio.2024.100668
Chengbo Mou , Zhichao Luo , Youjian Song
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引用次数: 0
A comprehensive DFT study on the structural, electronic, elastic, and optical behaviour of CsPbF3 under the effect of stress 应力作用下 CsPbF3 的结构、电子、弹性和光学行为的 DFT 综合研究
Q3 Physics and Astronomy Pub Date : 2024-04-02 DOI: 10.1016/j.rio.2024.100667
M. Ijaz Khan , Muhammad Tanveer , M. Sana Ullah Sahar , S.S.A. Gillani , S.M. Junaid Zaidi

Fluoro-perovskite compounds are important and auspicious materials according to their properties in photovoltaic anti-reflective coating and optoelectronics. In this study, the structural, mechanical, and optoelectronic properties of Cesium Lead Fluoride CsPbF3 were investigated using first principle calculations with generalized gradient approximations. The effect of stress on the crystal structure of CsPbF3 was examined at 0, 20, 40, and 59 GPa. It was found that the lattice constant is decreased with increasing stress, and the elastic, electronic, and optical properties of the material were significantly affected. The density of states and band gap of CsPbF3 were also calculated, and the band gap was found to be zero at 59 GPa. The cubical structure of CsPbF3 is distorted at 58 GPa. The various mechanical characteristics such as the bulk modulus, shear modulus, Young’s modulus, and Poisson ratio were derived and discussed. The results indicate that CsPbF3 exhibits ductile behaviour and anisotropic nature under stress, and the increase in refractive index, absorption, reflectivity, and conductivity at high stress make it a promising material for optoelectronic devices.

根据其在光伏抗反射涂层和光电子学方面的特性,氟闪石化合物是一种重要的吉祥材料。本研究采用广义梯度近似的第一性原理计算方法,研究了氟化铯铅 CsPbF3 的结构、力学和光电特性。研究了应力在 0、20、40 和 59 GPa 下对 CsPbF3 晶体结构的影响。结果发现,晶格常数随应力的增加而减小,材料的弹性、电子和光学特性受到显著影响。还计算了 CsPbF3 的态密度和带隙,发现 59 GPa 时带隙为零。CsPbF3 的立方体结构在 58 GPa 时发生扭曲。推导并讨论了各种力学特性,如体积模量、剪切模量、杨氏模量和泊松比。结果表明,CsPbF3 在应力作用下表现出延展性和各向异性,而且在高应力作用下折射率、吸收率、反射率和电导率都会增加,因此是一种很有前途的光电器件材料。
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引用次数: 0
Incoherent beam combination of higher-order Gaussian beam in atmospheric turbulence 大气湍流中高阶高斯光束的非相干光束组合
Q3 Physics and Astronomy Pub Date : 2024-03-30 DOI: 10.1016/j.rio.2024.100662
Mukesh Kumar , Azeemuddin Syed , Arpit Khandelwal , Jagannath Nayak

In this article, an incoherent beam combination of higher-order Gaussian beams through atmospheric turbulence is studied. An analytical expression of the combined intensity and spot size of higher-order Gaussian beams such as Hermite Gaussian (HG), Laguerre Gaussian (LG), and Bessel Gaussian (BG) are derived. The performance of these higher-order Gaussian beams is analyzed in various modes including the effect of beam wander, jitter, bore-sight error, Strehl ratio, and Visibility. A series of analytical simulations shows the intensity variation of 19 higher-order combined beams. Spot size, peak, and average intensity comparisons are made between various modes of higher-order Gaussian beam combinations. It is seen that the spot size of the combined beam increases rapidly in a higher mode of HG and LG beam. We evaluate the efficiency of combining beams at different distances, noting that it increases with higher mode orders and reaches its maximum with the HG22 mode. Additionally, we explore the performance of higher-order Gaussian beam combinations under varying ground turbulence conditions. We observe that higher modes such as HG22 and LG22 are more susceptible to strong turbulence compared to lower modes.

本文研究了穿过大气湍流的高阶高斯光束的非相干光束组合。推导出了高阶高斯光束(如赫米特高斯(HG)、拉盖尔高斯(LG)和贝塞尔高斯(BG))的组合强度和光斑大小的分析表达式。分析了这些高阶高斯光束在各种模式下的性能,包括光束漂移、抖动、孔视误差、Strehl 比和可见度的影响。一系列分析模拟显示了 19 个高阶组合光束的强度变化。对高阶高斯光束组合的各种模式的光斑大小、峰值和平均强度进行了比较。可以看出,在高阶高斯光束和低阶高斯光束的较高模式下,组合光束的光斑尺寸会迅速增大。我们评估了不同距离下的光束组合效率,注意到其随着模式阶数的增加而增加,并在 HG22 模式下达到最大值。此外,我们还探讨了高阶高斯波束组合在不同地面湍流条件下的性能。我们发现,HG22 和 LG22 等高阶模式与低阶模式相比,更容易受到强湍流的影响。
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引用次数: 0
Special issue on Group IV integrated optical sensors 第 IV 组集成光学传感器特刊
Q3 Physics and Astronomy Pub Date : 2024-03-27 DOI: 10.1016/j.rio.2024.100665
Vittorio M.N. Passaro, Martino De Carlo
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引用次数: 0
Optimizing the structural, optical and photovoltaic properties of Mn-doped perovskite solar cells 优化掺锰过氧化物太阳能电池的结构、光学和光伏特性
Q3 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.1016/j.rio.2024.100663
M.I. Khan , Saddam Hussain , M. Boota , Wajeehah Shahid , M. Atif , Ameena Nazneen

Perovskite solar cells (MAPbI2Br or CH3NH3I2Br) are the subject of this thorough examination of their optical, structural, and photovoltaic properties. These MAPbI2Br cells were prepared by the sol–gel spin-coating process to make films of both undoped and Mn2+-doped materials. In addition, the band gap energy (Eg) exhibited a steady downward trend as doping levels increased. The largest drop was observed at 4 % Mn2+ doping, when UV–Vis spectroscopy measured an Eg value of 1.88 eV. This decrease in band gap energy is essential to improving MAPbI2Br's functionality. Furthermore, when compared to cells that used pure MAPbI2Br perovskite solar cells, the efficiency of the manufactured MAPbI2Br cells shown a significant improvement. Analyzing the current–voltage (J-V) characteristics revealed that the MAPbI2Br produced with a 4 % Mn2+-doped MAPbI2Br film had dramatically improved properties. These cells showed an open-circuit voltage of 1.02, a fill factor of 0.74, a short-circuit current density of 8.10 mA/cm2, and an impressive power conversion efficiency of 6.14 %.

本研究对透镜太阳能电池(MAPbI2Br 或 CH3NH3I2Br)的光学、结构和光伏特性进行了深入研究。这些 MAPbI2Br 电池是通过溶胶-凝胶旋涂工艺制备的,制成了未掺杂和掺杂 Mn2+ 材料的薄膜。此外,随着掺杂水平的增加,带隙能(Eg)呈稳步下降趋势。在掺杂 4% Mn2+ 时,下降幅度最大,紫外可见光谱仪测得 Eg 值为 1.88 eV。带隙能的降低对提高 MAPbI2Br 的功能至关重要。此外,与使用纯 MAPbI2Br 的包晶体太阳能电池相比,制造的 MAPbI2Br 电池的效率有了显著提高。对电流-电压(J-V)特性的分析表明,使用掺杂了 4% Mn2+ 的 MAPbI2Br 薄膜生产的 MAPbI2Br 性能显著提高。这些电池的开路电压为 1.02,填充因子为 0.74,短路电流密度为 8.10 mA/cm2,功率转换效率高达 6.14%。
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引用次数: 0
PAPR analysis in OTFS using the centre phase sequence matrix based PTS method 使用基于中心相位序列矩阵的 PTS 方法分析 OTFS 中的 PAPR
Q3 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.1016/j.rio.2024.100664
Arun Kumar , Himanshu Sharma , Nishant Gaur , Aziz Nanthaamornphong

Orthogonal time–frequency space (OTFS) is a multicarrier modulation technique for high-speed data transfer in wireless communications. In an OTFS system, many subcarriers are used to send the modulated symbols. This makes OTFS signals have a high peak-to-average power ratio (PAPR). We suggest a partial transmit sequence (PTS) approach based on the Centre Phase Sequence Matrix (CPSM) to lower the high PAPR. Furthermore, the suggested method effectively searches for the best possible combination of phase rotation factors to reduce computing complexity. We examine the outcomes regarding bit error rate (BER), power spectral density (PSD), and PAPR to validate the competing transforms in the OTFS system. Along with non-orthogonal multiple access (NOMA), filter bank multi-carrier (FBMC), universal filter multi-carrier (UFMC), and orthogonal frequency division multiplexing (OFDM), the PAPR, BER, and PSD performance of OTFS were also compared. According to the data, the suggested PTS + CPSM reduces PAPR more effectively than the current PTS. It is also mentioned that by increasing the number of sub-blocks (s = 2 and 4), the suggested PTS + CPSM can achieve an even better PAPR rate. According to the experimental results, the suggested approach has dramatically decreased the PAPR while maintaining the BER and PSD performance with the least amount of computational complexity.

正交时频空间(OTFS)是一种多载波调制技术,用于无线通信中的高速数据传输。在 OTFS 系统中,许多子载波用于发送调制符号。这使得 OTFS 信号具有较高的峰均功率比(PAPR)。我们提出了一种基于中心相序矩阵(CPSM)的部分发送序列(PTS)方法,以降低高 PAPR。此外,建议的方法还能有效搜索相位旋转因子的最佳组合,从而降低计算复杂度。我们研究了误码率 (BER)、功率谱密度 (PSD) 和 PAPR 的结果,以验证 OTFS 系统中的竞争变换。与非正交多址接入(NOMA)、滤波器组多载波(FBMC)、通用滤波器组多载波(UFMC)和正交频分复用(OFDM)一起,我们还比较了 OTFS 的 PAPR、误码率和 PSD 性能。数据显示,建议的 PTS + CPSM 比当前的 PTS 更有效地降低了 PAPR。此外,通过增加子块的数量(s = 2 和 4),建议的 PTS + CPSM 可以获得更好的 PAPR 率。实验结果表明,建议的方法在保持误码率和 PSD 性能的同时,以最小的计算复杂度大幅降低了 PAPR。
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引用次数: 0
All reflective FROG using near 90° retro-reflecting mirror for single shot intensity and phase profile measurement of ultra-short laser pulse 使用近 90° 反射镜的全反射 FROG,用于超短激光脉冲的单发强度和相位轮廓测量
Q3 Physics and Astronomy Pub Date : 2024-03-23 DOI: 10.1016/j.rio.2024.100661
D. Daiya , R.K. Patidar , A. Moorti , M.P. Kamath , N.S. Benerji

In this paper, we propose a novel scheme for an all-reflective FROG device using a near-90° retro-reflecting mirror for the complete single-shot measurement of intensity and phase of ultra-short laser pulses. The proposed device has several advantages, such as (1) it is an all-reflective setup, hence no added material dispersion; (2) it is simple and free from alignment disturbances; and (3) the temporal resolution and temporal range of the device can be tuned as per requirement. The proposed device was set up to measure mode-locked ultra-short laser pulses generated from a Ti:Sapphire laser oscillator. Dispersion-broadened laser pulses, obtained by passing the oscillator pulses through a 30 cm long Nd:glass rod, were also characterized, and the group velocity dispersion parameter value of the glass rod was estimated.

在本文中,我们提出了一种全反射 FROG 设备的新方案,该设备使用近 90° 的逆反射镜,可对超短激光脉冲的强度和相位进行完整的单次测量。所提出的装置有几个优点,例如:(1) 它是一个全反射装置,因此没有额外的材料色散;(2) 它操作简单,不受校准干扰;(3) 装置的时间分辨率和时间范围可根据要求进行调整。所提议的装置用于测量由钛蓝宝石激光振荡器产生的锁模超短激光脉冲。此外,还对通过 30 厘米长的掺钕玻璃棒获得的色散展宽激光脉冲进行了表征,并估算了玻璃棒的群速度色散参数值。
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引用次数: 0
Impact of weak nonlocal nonlinearity on modulational instability and chirp-free soliton trains in parabolic law optical fiber 弱非局域非线性对抛物线定律光纤中调制不稳定性和无啁啾孤子束的影响
Q3 Physics and Astronomy Pub Date : 2024-03-22 DOI: 10.1016/j.rio.2024.100660
Nkeh Oma Nfor

This study considers the generation and evolution of chirp-free soliton trains in a focusing cubic-quintic nonlinear optical fiber media (by utilizing experimental parameters), under the influence of weak nonlocal nonlinearity. Analysis of modulational instability (MI) reveals that the MI gain exist only in the anomalous dispersion regime, with the quintic nonlinear term increasing the maximum gain and sideband frequencies. The nonlocal nonlinearity parameter generally suppresses the impact of MI, because the maximum gain is greatly reduced with increase in nonlocality. By using the subsidiary ordinary differential equation method, stationary periodic soliton trains are obtained; with the intensity of the optical beam greatly reduced and frequency increased as nonlocality is gradually stepped up. However, an increase in nonlocality instead reduces the frequency of the traveling optical signals; derived via an efficient transformation method. Our results strongly suggest that nonlocal nonlinearity has potential applications in the control of laser beams; as nonlinear periodic optical signals can be easily transformed to very weak quasi-plane waves.

本研究探讨了在弱非局部非线性影响下,聚焦立方-五次元非线性光纤介质(利用实验参数)中无啁啾孤子列车的产生和演化。对调制不稳定性(MI)的分析表明,调制不稳定性增益只存在于反常色散机制中,而五次方非线性项会增加最大增益和边带频率。非局部非线性参数通常会抑制 MI 的影响,因为随着非局部性的增加,最大增益会大大降低。通过使用附属常微分方程方法,可以得到静止的周期性孤子序列;随着非局部性的逐渐增加,光束强度会大大降低,频率会增加。然而,非局部性的增加反而降低了行进光信号的频率;这是通过一种有效的变换方法得出的。我们的研究结果有力地表明,非局部非线性在激光光束控制方面具有潜在的应用价值,因为非线性周期性光信号可以很容易地转换成非常微弱的准平面波。
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引用次数: 0
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Results in Optics
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