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A computational study of advanced hexagonal PCF (H-PCF) bio sensor for breast cancer identification 先进六边形PCF (H-PCF)生物传感器乳腺癌识别的计算研究
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-28 DOI: 10.1016/j.rio.2025.100908
A.Alice Linsie, K. Lalitha, G. Annapoorani
A novel hexagonal Photonic Crystal Fiber (PCF) with good sensitivity for the non-disruptive detection of breast cancer operating over terahertz (THz) regime has been reported in this study. The cladding region of this proposed H-PCF is made up of three layers of hexagonal air holes arranged in a triangular lattice structure. There is one hexagonal air hole in the middle that serves as a hollow core for studying the PCF during sensing operations. This core provides an index difference between the core, cladding, and background material, allowing efficient THz wave propagation and great sensitivity. Through simulation on COMSOL software, the compact arrangement of hexagonal air holes in this way facilitates a birefringence of 1.4 × 10−3, a minimum effective material loss (EML) of 1.22 × 10−3 cm−1, a maximum core power fraction of 91.2 %, a maximum sensitivity of 99.83 %, and a very narrow effective area of 0.0375 µm2 under a wide frequency band of 0.1–1.5 THz. The suggested H-PCF is a good alternative for PCF-based sensing devices because it of these unique features.
本文报道了一种新型的六角形光子晶体光纤(PCF),该光纤在太赫兹(THz)波段具有良好的灵敏度,可用于乳腺癌的无损检测。这种提出的H-PCF的包层区域由三层六边形空气孔组成,这些空气孔以三角形晶格结构排列。中间有一个六角形的空气孔,在传感过程中用作研究PCF的空心核心。该核心提供了核心,包层和背景材料之间的指数差异,允许有效的太赫兹波传播和高灵敏度。通过COMSOL软件仿真,在0.1 ~ 1.5 THz的宽频段内,以这种方式紧凑排列的六角形气孔的双折射率为1.4 × 10−3,有效材料损耗(EML)最小为1.22 × 10−3 cm−1,最大堆芯功率分数为91.2%,最大灵敏度为99.83%,有效面积为0.0375µm2。建议的H-PCF是基于pcf的传感器件的一个很好的替代方案,因为它具有这些独特的功能。
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引用次数: 0
Study of gold, silver-gold nanoparticles incorporated to carbon paint for electrodes application in thin-film solar cells 将金、银、金纳米颗粒掺入碳漆中用于薄膜太阳能电池电极的研究
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-28 DOI: 10.1016/j.rio.2025.100905
Patricia Horta-Fraijo, H.Moreno- García
The study investigated Au-Ag and Au nanoparticles (NPs) synthesized chemically and added to a commercial conductive carbon paint used as electrodes in Bi2S3/PbS thin-film solar cells. I-V measurements were used for device characterization. NPs were found on the carbon paint surface with sizes of 11.1 ± 0.09 nm to 29 ± 7.5 nm. FFT analysis showed a cubic crystal structure for all NPs. Optically, Au-Ag(1) exhibited broad absorption (363–600 nm), Au-Ag(2) peaked at 546 nm, and Au at 521 nm. Devices with NP-modified electrodes with sizes 29 ± 7.5 nm showed enhanced short-circuit current density (JSC), with Au-Ag(2) reaching 7.19 mA/cm2 and a PCE of 0.46 %, compared to the reference JSC of 3.02 mA/cm2 and PCE of 0.11 %. Series resistance dropped from 23 Ω·cm2 to 2 Ω·cm2 (Au-Ag) and 5 Ω·cm2 (Au).
该研究研究了化学合成的Au- ag和Au纳米颗粒(NPs),并将其添加到商用导电碳漆中,用作Bi2S3/PbS薄膜太阳能电池的电极。I-V测量用于器件表征。在碳漆表面发现了粒径为11.1±0.09 nm ~ 29±7.5 nm的纳米粒子。FFT分析显示所有NPs均为立方晶体结构。在光学上,Au- ag(1)表现出宽吸收(363 ~ 600 nm), Au- ag(2)在546 nm处达到峰值,Au在521 nm处达到峰值。采用尺寸为29±7.5 nm的np修饰电极的器件显示出更高的短路电流密度(JSC),其中Au-Ag(2)达到7.19 mA/cm2, PCE为0.46%,而参考电极的JSC为3.02 mA/cm2, PCE为0.11%。串联电阻从23 Ω·cm2下降到2 Ω·cm2 (Au- ag)和5 Ω·cm2 (Au)。
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引用次数: 0
Multi-band graphene-nested rings terahertz wave absorber with air gap for sensitive healthcare biosensing applications 多波段石墨烯嵌套环太赫兹波吸收器与气隙敏感的医疗保健生物传感应用
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-28 DOI: 10.1016/j.rio.2025.100911
Seyed Mahmoud Hoseini , Hadi Dehbovid , Seyed Mehdi Abedi Pahnehkolaei , Mehdi Radmehr
A highly sensitive multi-band terahertz wave absorber is proposed, featuring a three-layer structure with a central air gap for blood sample placement, sandwiched by stacked graphene-Kapton layers and backed by a fully reflecting metallic layer. The absorber is modeled using an equivalent impedance circuit and validated by full-wave numerical simulations. The device exhibits seven distinct absorption peaks across the 1 to 9.5 THz frequency range, with absorption levels exceeding 80% for each peak. Sensitivity analysis reveals robust absorption performance with minimal variation against geometrical parameter changes, while demonstrating high sensitivity to refractive index changes within the air gap. Specifically, the absorption spectrum shifts significantly for refractive index variations as small as 0.01, which is critical for non-invasive biosensing applications. These results underscore the absorber’s potential as an accurate, wearable, and reliable building block for healthcare monitoring systems.
提出了一种高灵敏度的多波段太赫兹波吸收器,其特点是三层结构,中间有一个用于放置血液样本的气隙,中间夹有堆叠的石墨烯-卡普顿层,后面有一个完全反射的金属层。利用等效阻抗电路对吸收器进行了建模,并通过全波数值模拟进行了验证。该器件在1 ~ 9.5太赫兹频率范围内显示出7个不同的吸收峰,每个峰的吸收水平超过80%。灵敏度分析揭示了对几何参数变化具有最小变化的稳健吸收性能,同时对气隙内折射率变化具有高灵敏度。具体来说,当折射率变化小至0.01时,吸收光谱就会发生显著变化,这对于非侵入性生物传感应用至关重要。这些结果强调了吸收器作为医疗监测系统中精确、可穿戴和可靠的构建块的潜力。
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引用次数: 0
Investigation of strain-induced modulation on electronic and optical properties of monolayer of BSb 应变诱导调制对BSb单层电子学和光学性质的影响
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-26 DOI: 10.1016/j.rio.2025.100900
Raad Chegel , Ahmad I. Ayesh
This work presents a comprehensive theoretical investigation of the electronic and optical responses of monolayer honeycomb boron antimony (h-BSb) and hexagonal boron phosphide (h-BP) under various biaxial strain conditions, employing a tight-binding approach validated through DFT calculations. Our findings reveal that monolayer h-BSb possesses a direct band gap that can be effectively modulated through mechanical strain: tensile strain raises the band gap, whereas compressive strain decreases it. This strain-induced tunability manifests directly in the optical spectra, where prominent optical peaks exhibit significant redshifts under compressive strain and blueshifts under tensile conditions. The refractive index n(ω) demonstrates clear strain-dependent modulations, with the zero-frequency value increasing under compressive strain and decreasing under tensile deformation. Additionally, the DC Kerr effect displays a distinctive double-peak structure that shows high sensitivity to mechanical strain. Comparative analysis demonstrates that monolayer h-BSb exhibits lower-energy optical transitions and enhanced sensitivity to strain-induced peak displacement compared to h-BP. This superior performance stems from h-BSb’s small band gap and narrow interband separations at the points of high-symmetry in the Brillouin zone. These characteristics position h-BSb as a highly promising material for strain-engineered optoelectronic applications, particularly in infrared photodetectors and sensors.
本文采用紧密结合的方法,通过DFT计算验证了单层蜂窝状硼锑(h-BSb)和六方磷化硼(h-BP)在各种双轴应变条件下的电子和光学响应的全面理论研究。我们的研究结果表明,单层h-BSb具有直接带隙,可以通过机械应变有效地调节:拉伸应变增大带隙,而压缩应变减小带隙。这种应变诱导的可调性直接表现在光谱中,其中突出的光学峰在压缩应变下表现出明显的红移,在拉伸条件下表现出明显的蓝移。折射率n(ω)表现出明显的应变相关调制,零频率值在压缩应变下增大,在拉伸变形下减小。此外,DC克尔效应表现出独特的双峰结构,对机械应变具有很高的灵敏度。对比分析表明,与h-BP相比,单层h-BSb具有较低能量的光学跃迁和对应变引起的峰值位移的敏感性增强。这种优异的性能源于h-BSb在布里渊区高对称性点处的小带隙和窄带间分离。这些特性使h-BSb成为应变工程光电应用中非常有前途的材料,特别是在红外光电探测器和传感器中。
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引用次数: 0
Low-power all-optical photonic crystal synapse using Ge2Sb2Te5 phase-change material 采用Ge2Sb2Te5相变材料制备的低功耗全光光子晶体突触
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-25 DOI: 10.1016/j.rio.2025.100901
Amir Hossein Abdollahi Nohoji, Parviz Keshavarzi, Mohammad Danaie
In this study, we propose an all-optical neuromorphic photonic crystal synapse structure equipped with a Ge2Sb2Te5 phase-change material (GST-PCM). By leveraging the unique properties of the GST-PCM material, this structure enables the control of the synaptic weight through targeted and focused laser irradiation. 3D simulations employing the finite-difference time-domain (FDTD) and finite element method (FEM) demonstrated optical transmission exceeding 99 % and reflection below −20 dB at a wavelength of 1504 nm within the proposed structure. These features, together with their compact dimensions and low power consumption, make our proposed structure an ideal candidate for optical processing applications and neuromorphic neural networks. Furthermore, we investigated the physical and thermal equations to determine the crystallization fraction of GST-PCM during the synapse weighting process. These equations showed excellent agreement with the simulation results and could accurately calculate the GST-PCM crystallization fraction as a function of time and laser power. Our proposed structure not only has the potential to be extended to neuromorphic systems and optical neural networks but also serves as an innovative platform for all-optical synapses because of its precise control of optical properties, high adaptability, and low power consumption.
在这项研究中,我们提出了一种配备Ge2Sb2Te5相变材料(GST-PCM)的全光神经形态光子晶体突触结构。通过利用GST-PCM材料的独特特性,这种结构可以通过靶向和聚焦激光照射来控制突触重量。采用时域有限差分法(FDTD)和有限元法(FEM)的三维仿真表明,在所提出的结构中,在波长1504 nm处,光透射率超过99%,反射率低于- 20 dB。这些特点,加上它们紧凑的尺寸和低功耗,使我们提出的结构成为光学处理应用和神经形态神经网络的理想候选者。此外,我们研究了物理和热方程,以确定突触称重过程中GST-PCM的结晶分数。这些方程与模拟结果吻合良好,能够准确地计算出GST-PCM结晶率随时间和激光功率的变化规律。我们提出的结构不仅具有扩展到神经形态系统和光神经网络的潜力,而且由于其精确控制光学特性,高适应性和低功耗,还可以作为全光突触的创新平台。
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引用次数: 0
Design and Theory of Characteristic Mode Analysis (TCMA) of 4 × 4 high isolation MIMO antenna for sub-6GHz 5G communications 用于sub-6GHz 5G通信的4 × 4高隔离MIMO天线的特性模态分析(TCMA)设计与理论
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-25 DOI: 10.1016/j.rio.2025.100903
Bhaskara Rao Perli , Tathababu Addepalli , Arashpreet K. Sohi , Sivasubramanyam Medasani , Manish Sharma , Imran Mohd Ibrahim , Ahmed J.A.Al–Gburi
This present work investigates a compact 4 × 4 cup-shaped Multi-Input Multi-Output (MIMO) antenna using Characteristic Mode Analysis (CMA). The systematic design procedure with six characteristic modes allows the antenna to operate at the working frequency of 3.5 GHz. Physical insight into one-element and four-element radiating structures is gained by analysing modal significance, modal fields, and surface currents. The 4 × 4 MIMO structure works in a narrow frequency band of 2.8 to 4.6 GHz. The total size of the MIMO model is 53 × 53 × 1.6 mm3 and is printed on an inexpensive flame-retardant substrate. The plus-shaped decoupling network and the orientation of the radiating patch provide a strong isolation of more than 20 dB across the operating band. The diversity MIMO performance the antenna provides good results with ECC < 0.000005, DG > 9.9999 dB, TARC <  − 10 dB, CCL < 0.02b/s/Hz, and MEG ≅  − 3.0 dB. These antenna features make the MIMO design suitable for sub-6 GHz 5G communications.
本研究利用特征模式分析(CMA)研究了一种紧凑的4 × 4杯形多输入多输出(MIMO)天线。六种特性模式的系统设计程序使天线工作在3.5 GHz的工作频率下。通过分析模态显著性、模态场和表面电流,获得了对单元和四元辐射结构的物理洞察。4 × 4 MIMO结构工作在2.8 ~ 4.6 GHz的窄带内。MIMO模型的总尺寸为53 × 53 × 1.6 mm3,印刷在廉价的阻燃基板上。加号形状的去耦网络和辐射贴片的方向在整个工作频段提供了超过20 dB的强隔离。在ECC = 0.000005、DG = 9.9999 dB、TARC = - 10 dB、CCL = 0.02b/s/Hz、MEG = - 3.0 dB时,天线的分集MIMO性能良好。这些天线特性使得MIMO设计适用于6 GHz以下的5G通信。
{"title":"Design and Theory of Characteristic Mode Analysis (TCMA) of 4 × 4 high isolation MIMO antenna for sub-6GHz 5G communications","authors":"Bhaskara Rao Perli ,&nbsp;Tathababu Addepalli ,&nbsp;Arashpreet K. Sohi ,&nbsp;Sivasubramanyam Medasani ,&nbsp;Manish Sharma ,&nbsp;Imran Mohd Ibrahim ,&nbsp;Ahmed J.A.Al–Gburi","doi":"10.1016/j.rio.2025.100903","DOIUrl":"10.1016/j.rio.2025.100903","url":null,"abstract":"<div><div>This present work investigates a compact 4 × 4 cup-shaped Multi-Input Multi-Output (MIMO) antenna using Characteristic Mode Analysis (CMA). The systematic design procedure with six characteristic modes allows the antenna to operate at the working frequency of 3.5 GHz. Physical insight into one-element and four-element radiating structures is gained by analysing modal significance, modal fields, and surface currents. The 4 × 4 MIMO structure works in a narrow frequency band of 2.8 to 4.6 GHz. The total size of the MIMO model is 53 × 53 × 1.6 mm3 and is printed on an inexpensive flame-retardant<!--> <!-->substrate<sub>.</sub> The plus-shaped decoupling network and the orientation of the radiating patch provide a strong isolation of more than 20 dB across the operating band. The diversity MIMO performance the antenna provides good results with ECC &lt; 0.000005, DG &gt; 9.9999 dB, TARC &lt;  − 10 dB, CCL &lt; 0.02b/s/Hz, and MEG ≅  − 3.0 dB. These antenna features make the MIMO design suitable for sub-6 GHz 5G communications.</div></div>","PeriodicalId":21151,"journal":{"name":"Results in Optics","volume":"21 ","pages":"Article 100903"},"PeriodicalIF":3.0,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145219345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dispersive near-infrared metalens integrated with linear polarization filtering functionality 具有线性偏振滤波功能的色散近红外超透镜
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-25 DOI: 10.1016/j.rio.2025.100902
Tae Young Kang , ByungSuk Lee , Seunghun Lee , Seonyong An , Robert A. Taylor , Kyoungchun Kwon , Kyujung Kim
The miniaturization and enhanced functionality of LiDAR systems present critical challenges in automotive sensing technologies, particularly in achieving efficient wide-angle beam scanning while maintaining compact form factors. We demonstrate a novel dual-wavelength polarization-selective concave metalens operating at 904 nm and 940 nm wavelengths, the standard operating wavelengths for LiDAR systems. By engineering rectangular TiO2 nanopillars on a quartz substrate, we achieved simultaneous polarization filtering and concave phase profile functionality within a single metasurface layer. The optimized 600 nm × 600 nm unit cell design with 1.7 μm height nanopillars enables full 2π phase coverage while maintaining high transmission efficiency for the desired polarization state. Our fabricated metalens exhibits remarkable polarization extinction ratios (ER) of 124:1 and 102:1 at 904 nm and 940 nm wavelengths, respectively. Angular-resolved measurements demonstrate wide beam divergence angles of 148° and 138° at the respective wavelengths, with 50 % of total power contained within ± 38° and ± 25°.
激光雷达系统的小型化和增强功能对汽车传感技术提出了严峻的挑战,特别是在保持紧凑外形的同时实现高效的广角波束扫描。我们展示了一种新型的双波长偏振选择性凹超透镜,工作波长为904 nm和940 nm,这是激光雷达系统的标准工作波长。通过在石英衬底上设计矩形TiO2纳米柱,我们在单个超表面层内实现了同时偏振滤波和凹相剖面功能。优化的600 nm × 600 nm单元电池设计具有1.7 μm高的纳米柱,可实现完全的2π相位覆盖,同时保持所需偏振态的高传输效率。我们制备的超构透镜在904 nm和940 nm波长处的偏振消光比分别为124:1和102:1。角分辨测量表明,在各自的波长下,光束发散角为148°和138°,总功率的50%包含在±38°和±25°范围内。
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引用次数: 0
Optical audio signal hiding algorithm based on fractional Fourier transform domain and Gerchberg Saxton phase recovery 基于分数阶傅里叶变换域和Gerchberg - Saxton相位恢复的光学音频信号隐藏算法
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-25 DOI: 10.1016/j.rio.2025.100898
Hang Chen , Zhenduo Ma , Ziyi Zhang , Zhengjun Liu
This article proposes an audio signal encryption method based on the Gerchberg-Saxton (G-S) phase recovery algorithm in the fractional Fourier transform domain. The algorithm first encodes the original audio signal into an image format and encrypts it. Subsequently, the G-S phase recovery algorithm is used in the fractional Fourier domain to extract the phase information of the audio signal. On this basis, the original audio phase is replaced with a reference phase representing the secret information to achieve information embedding. This technology can select two different types of keys according to encryption requirements, further increasing the difficulty of decryption and ensuring information security. Ultimately, the encrypted image can be decrypted and restored to the original audio signal. This scheme achieves effective embedding and extraction of secret information in audio signals through the replacement and recovery of phase information.
提出了一种基于分数阶傅里叶变换域Gerchberg-Saxton (G-S)相位恢复算法的音频信号加密方法。该算法首先将原始音频信号编码成图像格式并进行加密。随后,在分数阶傅里叶域中采用G-S相位恢复算法提取音频信号的相位信息。在此基础上,将原始音频相位替换为代表秘密信息的参考相位,实现信息嵌入。该技术可以根据加密需求选择两种不同类型的密钥,进一步提高了解密难度,保证了信息安全。最终,对加密后的图像进行解密,还原为原始音频信号。该方案通过相位信息的替换和恢复,实现了音频信号中秘密信息的有效嵌入和提取。
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引用次数: 0
Temperature distribution simulation and laser performance of Nd:YAG composite laser crystals Nd:YAG复合激光晶体的温度分布模拟及激光性能
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-24 DOI: 10.1016/j.rio.2025.100899
Zhao Chen , Fei Li , Wenpeng Liu , Yufa Zhang , Qingli Zhang
YAG/Nd:YAG and YAG/Nd:YAG/YAG composite laser crystals were fabricated through thermal bonding method. The temperature distribution and laser properties of Nd:YAG, YAG/Nd:YAG and YAG/Nd:YAG/YAG crystals under LD end-pumping conditions were studied. Laser outputs with wavelengths of 1064 nm and 946 nm have been achieved. Temperature simulation results revealed that at 20 W pump power, the YAG/Nd:YAG/YAG crystal exhibited 15 K lower temperature compared to Nd:YAG crystal, with a 33 K reduction in end-face temperature. Under 20 W pumping, the maximum continuous-wave output powers of YAG/Nd:YAG/YAG crystal reached 4.412 W at 1064 nm and 668 mW at 946 nm, corresponding to slope efficiencies of 34.66 % and 6.68 %, and optical-to-optical conversion efficiencies of 34.77 % and 5.99 %, respectively. These values represent 1.6-fold and 1.8-fold improvements in output power, 13.4 % and 4.33 % enhancements in slope efficiency, as well as 9.31 % and 3.92 % increases in conversion efficiency compared to Nd:YAG crystal. Moreover, the YAG/Nd:YAG/YAG crystal demonstrated superior beam quality with lower M2 factors than both Nd:YAG/YAG composite crystal and Nd:YAG crystal. It is shown that the composite YAG/Nd:YAG/YAG crystal has better cooling efficiency, which is beneficial to reduce the thermal lens effect and improve the laser efficiency.
采用热键合法制备了YAG/Nd:YAG和YAG/Nd:YAG/YAG复合激光晶体。研究了LD端泵浦条件下Nd:YAG、YAG/Nd:YAG和YAG/Nd:YAG/YAG晶体的温度分布和激光性能。实现了波长为1064 nm和946 nm的激光输出。温度模拟结果表明,在20 W泵浦功率下,YAG/Nd:YAG/YAG晶体比Nd:YAG晶体温度降低了15 K,端面温度降低了33 K。在20 W泵浦下,YAG/Nd:YAG/YAG晶体在1064 nm处的最大连续输出功率为4.412 W,在946 nm处的最大连续输出功率为668 mW,斜率效率分别为34.66%和6.68%,光-光转换效率分别为34.77%和5.99%。与Nd:YAG晶体相比,输出功率分别提高了1.6倍和1.8倍,斜率效率分别提高了13.4%和4.33%,转换效率分别提高了9.31%和3.92%。YAG/Nd:YAG/YAG晶体的光束质量优于Nd:YAG/YAG复合晶体和Nd:YAG晶体,且M2因子较低。结果表明,YAG/Nd:YAG/YAG复合晶体具有较好的冷却效率,有利于降低热透镜效应,提高激光效率。
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引用次数: 0
Temperature-dependent phase evolution of the Gd3+ doped strontium compounds: Structural and optical properties Gd3+掺杂锶化合物的温度依赖性相演化:结构和光学性质
IF 3 Q3 Physics and Astronomy Pub Date : 2025-09-22 DOI: 10.1016/j.rio.2025.100895
C. Dlamini , M.R. Mhlongo , V.M. Maphiri , T.D. Malevu , L.F. Koao , T.E. Motaung , T.T. Hlatshwayo , S.V. Motloung
Mixed-phases of the SrCO3/Sr3Al2O6/SrAl2O4/SrAl4O7/SrAl12O19 (hereafter called SSSSS) doped with Gd3+ (SSSSS: 0.05 % Gd3+) nanopowders were prepared using the citrate sol–gel method. The effect of annealing temperature (Ta) on the structure, morphology, and photoluminescence (PL) properties was investigated. The Ta was varied in a range of 600–1300 °C, while the dopant concentration was kept constant at 0.05 % Gd3+. X-ray diffraction (XRD) results revealed that the prepared nanopowders consist of a mixture of orthorhombic (SrCO3), cubic (Sr3Al2O6), monoclinic (SrAl2O4 and SrAl4O7), and hexagonal SrAl12O19 structures. It was noted that increasing the phase composition depends on the Ta. The Fourier-transform infrared spectroscopy (FTIR) shows several peaks at around 529, 874, 1181, 1442, 2947, and 3421 cm−1. The Energy dispersive spectroscopy (EDS) confirmed the elementary composition of the Sr, C, O, and Al. The scanning electron microscope (SEM) images showed that the phase composition highly depends on the Ta. Transmission electron microscope (TEM) showed that the particle sizes are in the nanoscale. The ultraviolet–visible (UV–vis) diffuse reflection spectroscopy results showed that the absorption peaks below 300 nm are influenced by the Ta. The PL results showed three emission peaks located around 431, 541, and 657 nm when excited at 272 nm. These emission peaks were attributed to SrCO3, SrAl2O4, and Sr3Al2O6 crystal lattice, respectively. The results showed that the luminescence intensity and lifetime of the prepared samples depends on the Ta. The chromaticiy coordinate showed that all samples emit in a blue region and the color purity was influenced by the Ta.
采用柠檬酸溶胶-凝胶法制备了掺杂Gd3+ (SSSSS: 0.05% Gd3+)纳米粉体的SrCO3/Sr3Al2O6/SrAl2O4/SrAl4O7/SrAl12O19(以下简称SSSSS)混合相。研究了退火温度(Ta)对材料结构、形貌和光致发光性能的影响。Ta在600 ~ 1300℃范围内变化,而掺杂剂浓度保持在0.05% Gd3+不变。x射线衍射(XRD)结果表明,制备的纳米粉体由正交(SrCO3)、立方(Sr3Al2O6)、单斜(SrAl2O4和SrAl4O7)和六方(SrAl12O19)结构组成。注意到相组成的增加取决于Ta。傅里叶变换红外光谱(FTIR)显示在529、874、1181、1442、2947和3421 cm−1附近有几个峰。能谱分析(EDS)证实了Sr、C、O和Al的基本组成,扫描电镜(SEM)图像表明,相组成高度依赖于Ta。透射电子显微镜(TEM)分析表明,所制备的颗粒尺寸为纳米级。紫外-可见(UV-vis)漫反射光谱结果表明,在300 nm以下的吸收峰受Ta的影响。当激发波长为272 nm时,发光峰分别位于431,541和657 nm附近。这些发射峰分别属于SrCO3、SrAl2O4和Sr3Al2O6晶格。结果表明,制备的样品的发光强度和寿命取决于Ta的含量。色度坐标显示所有样品都在蓝色区域发光,颜色纯度受Ta的影响。
{"title":"Temperature-dependent phase evolution of the Gd3+ doped strontium compounds: Structural and optical properties","authors":"C. Dlamini ,&nbsp;M.R. Mhlongo ,&nbsp;V.M. Maphiri ,&nbsp;T.D. Malevu ,&nbsp;L.F. Koao ,&nbsp;T.E. Motaung ,&nbsp;T.T. Hlatshwayo ,&nbsp;S.V. Motloung","doi":"10.1016/j.rio.2025.100895","DOIUrl":"10.1016/j.rio.2025.100895","url":null,"abstract":"<div><div>Mixed-phases of the SrCO<sub>3</sub>/Sr<sub>3</sub>Al<sub>2</sub>O<sub>6</sub>/SrAl<sub>2</sub>O<sub>4</sub>/SrAl<sub>4</sub>O<sub>7</sub>/SrAl<sub>12</sub>O<sub>19</sub> (hereafter called SSSSS) doped with Gd<sup>3+</sup> (SSSSS: 0.05 % Gd<sup>3+</sup>) nanopowders were prepared using the citrate sol–gel method. The effect of annealing temperature (T<sub>a</sub>) on the structure, morphology, and photoluminescence (PL) properties was investigated. The T<sub>a</sub> was varied in a range of 600–1300 °C, while the dopant concentration was kept constant at 0.05 % Gd<sup>3+</sup>. X-ray diffraction (XRD) results revealed that the prepared nanopowders consist of a mixture of orthorhombic (SrCO<sub>3</sub>), cubic (Sr<sub>3</sub>Al<sub>2</sub>O<sub>6</sub>), monoclinic (SrAl<sub>2</sub>O<sub>4</sub> and SrAl<sub>4</sub>O<sub>7</sub>), and hexagonal SrAl<sub>12</sub>O<sub>19</sub> structures. It was noted that increasing the phase composition depends on the T<sub>a</sub>. The Fourier-transform infrared spectroscopy (FTIR) shows several peaks at around 529, 874, 1181, 1442, 2947, and 3421 cm<sup>−1</sup>. The Energy dispersive spectroscopy (EDS) confirmed the elementary composition of the Sr, C, O, and Al. The scanning electron microscope (SEM) images showed that the phase composition highly depends on the T<sub>a</sub>. Transmission electron microscope (TEM) showed that the particle sizes are in the nanoscale. The ultraviolet–visible (UV–vis) diffuse reflection spectroscopy results showed that the absorption peaks below 300 nm are influenced by the T<sub>a</sub>. The PL results showed three emission peaks located around 431, 541, and 657 nm when excited at 272 nm. These emission peaks were attributed to SrCO<sub>3</sub>, SrAl<sub>2</sub>O<sub>4</sub>, and Sr<sub>3</sub>Al<sub>2</sub>O<sub>6</sub> crystal lattice, respectively. The results showed that the luminescence intensity and lifetime of the prepared samples depends on the T<sub>a</sub>. The chromaticiy coordinate showed that all samples emit in a blue region and the color purity was influenced by the T<sub>a</sub>.</div></div>","PeriodicalId":21151,"journal":{"name":"Results in Optics","volume":"21 ","pages":"Article 100895"},"PeriodicalIF":3.0,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145157219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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