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Thermal lens investigation of the CdSe quantum dots using dual beam z-scan technique 利用双光束 Z 扫描技术对碲化镉量子点进行热透镜研究
Q3 Physics and Astronomy Pub Date : 2024-05-10 DOI: 10.1016/j.rio.2024.100692
M.D. Zidan , A. Allahham , A. Ghanem , N. Mousa , B. Abdallah , A. Al Salman

We highlighted on the thermal lens (TL) effect of Cadmium Selenide quantum dots (CdSe QDs) using dual beam z-scan technique. The thermal lens nonlinear optical properties of CdSe QDs were investigated by applying the two CW laser beams (λ = 532 nm and λ = 632.8 nm). The thermal lens parameters of the CdSe solutions, such as: the on-axis phase shift (θ), the thermal diffusivity (D), and thermal diffusion time (tc) were extracted using the theoretical thermal lens model. Our results give new insight into the CdSe QDs dissolved in toluene and are valuable for further development of semiconductor QDs optical devices.

我们利用双光束 Z 扫描技术重点研究了硒化镉量子点(CdSe QDs)的热透镜(TL)效应。我们使用两束连续波激光(λ = 532 nm 和 λ = 632.8 nm)研究了硒化镉量子点的热透镜非线性光学特性。利用热透镜理论模型提取了 CdSe 溶液的热透镜参数,如轴上相移 (θ)、热扩散率 (D) 和热扩散时间 (tc)。我们的研究结果使人们对溶解在甲苯中的 CdSe QDs 有了新的认识,对进一步开发半导体 QDs 光学器件具有重要价值。
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引用次数: 0
Graphene and ZnO NPs-enhanced photodetectors based on SiO NWs: Synthesis, characterization, and applications 基于 SiO NW 的石墨烯和 ZnO NPs 增强光电探测器:合成、表征和应用
Q3 Physics and Astronomy Pub Date : 2024-05-08 DOI: 10.1016/j.rio.2024.100690
Sumaya J. Abbas Alshareefi, Amer Al-Nafiey

In this study, we successfully synthesized and characterized silicon oxide nanowires/graphene/zinc oxide nanoparticles (SiO NWs/Graphene and ZnO NPs) hybrid nanostructures using pulsed laser deposition (PLD) technique. The characterization of the crystalline phase, morphology, and optical properties of the synthesized hybrid nanostructure systems revealed that the addition of graphene and ZnO NPs led to increased roughness values and changes in the surface topography of the films. The optical properties showed that the addition of graphene and zinc oxide enhanced the reflectivity in specific regions, including the UV and visible ranges, and improved the collection of charge carriers. The SiO NWs/Graphene and ZnO NPs was assessed as a photodetector and exhibited excellent performance, with high quantum efficiency, detectivity, and responsivity in the visible and near-infrared regions, making it a promising platform for the development of next-generation optoelectronic devices in various fields, including security, environmental monitoring, and medical diagnostics.

在这项研究中,我们利用脉冲激光沉积(PLD)技术成功合成了氧化硅纳米线/石墨烯/氧化锌纳米粒子(SiO NWs/Graphene and ZnO NPs)混合纳米结构,并对其进行了表征。对合成的杂化纳米结构体系的晶相、形貌和光学特性的表征表明,石墨烯和氧化锌纳米粒子的加入导致了薄膜粗糙度值的增加和表面形貌的变化。光学特性表明,石墨烯和氧化锌的添加增强了特定区域的反射率,包括紫外线和可见光范围,并改善了电荷载流子的收集。将 SiO NWs/Graphene 和 ZnO NPs 作为光电探测器进行了评估,结果表明其性能优异,在可见光和近红外区域具有较高的量子效率、探测性和响应性,是开发新一代光电器件的理想平台,可应用于安防、环境监测和医疗诊断等多个领域。
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引用次数: 0
High-efficiency anti-stokes Raman blue laser in CO2 enables high-luminance RGB laser-driven white light 二氧化碳中的高效反斯托克斯拉曼蓝激光器实现了高亮度 RGB 激光驱动白光
Q3 Physics and Astronomy Pub Date : 2024-05-07 DOI: 10.1016/j.rio.2024.100691
Jinglu Sun , Xianglong Cai , Ming Xu , Yuxi Jia , Feiyu Qian , Jingwei Guo

Stimulated Raman scattering (SRS) is an efficient nonlinear frequency conversion method, enabling simultaneous generation of red, green, and blue (RGB) lasers. In order to synthesize a white light source for laser display by SRS, a 532 nm laser was used as pump source, and high purity gaseous carbon dioxide (CO2) was used as the Raman active medium. First, by optimizing experimental parameters, with an f = 1.5 m focal lens, in 0.8 atm CO2 pumped at 304 mJ, a first-order anti-Stokes (AS1) 495 nm blue laser was achieved, with an energy of 31.9 mJ, peak power of 10.9 MW and conversion efficiency (CE) of 10.5 %. Then, Then, the second-order Stokes light (S2) at 624 nm, residual pump laser (S0) at 532 nm, and AS1 laser were utilized as RGB primary colors. By the variation of pressure below 1 atmosphere (atm), the laser-driven white light (LDWL) with adjustable correlated color temperature (CCT) below 4700 K were simulated. Finally, LDWL up to 2.6 × 1018cd/m2 of a CCT of 3300 K could be synthesized at an RGB power ratio of PR: PG: PB = 0.447:0.094:0.459, resulting in a white light power CE of 44.4 % and luminous efficacy of 113.7 lm/W. In addition, use of the 574 nm yellow Raman light is expected to realize a four-primary (RGBY) laser display scheme with higher Luminance and broader color gamut. Moreover, the feasibility of using a 515 nm Yb: YAG laser as pump source to widen the range of CCT and improve the brightness of LDWL was discussed.

受激拉曼散射(SRS)是一种高效的非线性频率转换方法,可同时产生红、绿、蓝(RGB)激光。为了利用 SRS 合成用于激光显示的白光光源,我们使用 532 nm 激光作为泵浦源,并使用高纯度气态二氧化碳(CO2)作为拉曼活性介质。首先,通过优化实验参数,在 0.8 atm CO2 泵浦 304 mJ 的条件下,使用 f = 1.5 m 焦距的透镜,实现了一阶反斯托克斯(AS1)495 nm 蓝色激光,能量为 31.9 mJ,峰值功率为 10.9 MW,转换效率(CE)为 10.5%。然后,利用波长为 624 nm 的二阶斯托克斯光(S2)、波长为 532 nm 的残余泵浦激光(S0)和 AS1 激光作为 RGB 三原色。通过改变低于 1 个大气压(atm)的压力,模拟了可调相关色温(CCT)低于 4700 K 的激光驱动白光(LDWL)。最后,在 RGB 功率比为 PR:PG: PB = 0.447:0.094:0.459,白光功率 CE 为 44.4 %,光效为 113.7 lm/W。此外,使用 574 nm 黄色拉曼光源有望实现具有更高亮度和更广色域的四基色(RGBY)激光显示方案。此外,使用 515 nm Yb:YAG 激光器作为泵浦源来拓宽 CCT 范围和提高 LDWL 亮度的可行性进行了讨论。
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引用次数: 0
χ(2) and χ(3) enhancement by arylamine substituents in aromatic conjugated polyenyne polymers 芳香族共轭聚烯炔聚合物中芳基胺取代基对χ(2)和χ(3)的增强作用
Q3 Physics and Astronomy Pub Date : 2024-04-21 DOI: 10.1016/j.rio.2024.100683
C.A. Guarin , L.G. Mendoza Luna , J.L. Hernández-Pozos , J.A. Díaz-Ponce

In this work, we have determined the χ(1), χ(2), and χ(3) NLO properties of NH2substituted aromatic polyenynes in ortho, meta, and para positions. It is worth noting that Mednis-Genkin’s approximation takes into account the intraband contribution with a derivate of the dipole valence-conduction band moment transition, unlike, for example, Ward’s summation-over-sates (SOS) methodology, which considers the difference of these states. Indeed, we have selected these polymers because of the high asymmetry in their molecular wavefunction. In this way, the calculated χ(3) values of the para-NH2 substituted aromatic polyenyne with a higher degree of polymerization are near 1 X 10−7 esu. For its part, the ortho polymer has higher values, of the order of 1 X 10−6 esu, due to its high transition dipole moment. We have also found that the energy band distribution in the para position of these polymers produces van Hove points, which have a negligible proportion of the NLO properties, compared with singularity regions 1 and 2, which have a contribution of 100 %. These regions are due to the wavefunction coefficients’ first and second-order derivatives. Besides, without considering border effects nor correlation effects, and only the variation of excitation energy, we have calculated that the quaternary monomeric oligomers of these polymers have almost similar values of χ(2) and χ(3). Then, it implies building a methodology to synthesize the polymers to avoid canceling the NLO-χ(2) and -χ(3) values.

在这项工作中,我们测定了正位、偏位和对位 NH2 取代芳香族多炔的 χ(1)、χ(2) 和 χ(3) NLO 特性。值得注意的是,Mednis-Genkin 的近似方法考虑了带内贡献与偶极价带-导带矩转换的衍生物,而不像 Ward 的态上求和(SOS)方法等考虑了这些态的差异。事实上,我们之所以选择这些聚合物,是因为它们的分子波函数具有高度不对称性。因此,聚合度较高的对位 NH2 取代芳香族聚烯烃的计算 χ(3) 值接近 1 X 10-7 esu。而正交聚合物由于具有较高的过渡偶极矩,其计算χ(3)值更高,约为 1 X 10-6 esu。我们还发现,这些聚合物的对位能带分布产生了范霍夫点,与奇异区 1 和奇异区 2 相比,范霍夫点在 NLO 特性中所占比例微乎其微,而奇异区 1 和奇异区 2 的贡献率则高达 100%。这些区域是由波函数系数的一阶和二阶导数造成的。此外,在不考虑边界效应和相关效应,只考虑激发能量变化的情况下,我们计算出这些聚合物的四元单体低聚物具有几乎相似的 χ(2) 和 χ(3) 值。这就意味着要建立一种合成聚合物的方法,以避免抵消 NLO-χ(2) 和 -χ(3) 值。
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引用次数: 0
Numerical analysis of microstructured optical fibers based on flint glass for ultra-high nonlinearity, low loss, and broadband dispersion compensation across telecom bands 对基于燧石玻璃的微结构光纤进行数值分析,以实现超高非线性、低损耗和跨电信波段的宽带色散补偿
Q3 Physics and Astronomy Pub Date : 2024-04-21 DOI: 10.1016/j.rio.2024.100687
Amit Halder , Yeasin Arafat , Md. Forkan , Ramamurthy Dinesh Kumar , Muhammad Ahsan , Imtiage Ahmed , Md. Shamim Anower

This research investigates the potential of flint glass as a foundational material for photonic crystal configurations designed to achieve high nonlinear coefficients across various communication wavelengths. We explore dispersion management within telecom bands using flint glass-based micro-structured optical fibers, employing numerical analysis via the finite element method to assess optical properties. In this study, three different basic MOF structures (hexagonal, square, and octagonal) were created using flint glass background material rather of the commonly utilized fused silica material, and the numerically was assessed in contrast to prior studies and designs. Among the configurations studied, the octagonal arrangement (FGO-MOF) excels in dispersion compensation, achieving −136.6 ps/(nm.km) at 1.55 µm. Conversely, the hexagonal air hole ring cladding design (FGH-MOF) displays higher nonlinearity (770.5 W−1.km−1), a smaller effective area (1.115 µm2), and a high numerical aperture (0.6378). In contrast, the square air hole ring cladding optical fiber (FGS-MOF) exhibits low confinement loss (6.309 × 10−7 dB/cm) at 1.55 µm but with comparatively less favorable optical properties. Our study demonstrates that the hexagonal microstructured optical fiber with flint glass (FGH-MOF) offers superior performance in dispersion compensation, nonlinearity, and low loss within telecom bands. This finding suggests promising applications in high-bit-rate communication systems, biomedical sensing, and supercontinuum generation, presenting exciting avenues for further research and practical implementation.

这项研究探讨了燧石玻璃作为光子晶体结构基础材料的潜力,旨在实现各种通信波长的高非线性系数。我们利用有限元法进行数值分析,评估光学特性,探索使用基于燧石玻璃的微结构光纤在电信波段内的色散管理。在这项研究中,我们使用燧石玻璃背景材料(而不是常用的熔融石英材料)制作了三种不同的基本 MOF 结构(六角形、方形和八角形),并与之前的研究和设计进行了对比,对其进行了数值评估。在所研究的配置中,八角形排列(FGO-MOF)在色散补偿方面表现出色,在 1.55 微米处达到 -136.6 ps/(nm.km)。相反,六边形气孔环包层设计(FGH-MOF)的非线性度更高(770.5 W-1.km-1),有效面积更小(1.115 µm2),数值孔径更大(0.6378)。相比之下,方形气孔环形包层光纤(FGS-MOF)在 1.55 µm 波长时的约束损耗较低(6.309 × 10-7 dB/cm),但光学特性相对较差。我们的研究表明,带火石玻璃的六角微结构光纤(FGH-MOF)在电信波段内的色散补偿、非线性和低损耗方面性能优越。这一发现表明,光纤在高比特率通信系统、生物医学传感和超连续产生等领域的应用前景广阔,为进一步研究和实际应用提供了令人兴奋的途径。
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引用次数: 0
Web-based application software for Judd-Ofelt analysis of Eu3+ ion luminescence 用于 Eu3+ 离子发光的 Judd-Ofelt 分析的网络应用软件
Q3 Physics and Astronomy Pub Date : 2024-04-18 DOI: 10.1016/j.rio.2024.100688
E.H.H. Hasabeldaim, H.C. Swart, R.E. Kroon

This article reports on the development of a new Web-based application software for calculating Judd-Ofelt intensity parameters and derived quantities from the emission spectra of Eu3+ doped compounds. The application was entirely developed in JavaScript, and it is compatible with all major browsers. The web application can be accessed via the following link https://sciapps.sci-sim.com/judd_ofelt_analysis_Eu.html. Test samples of ZnO doped with different amounts of Eu3+ were synthesized using the combustion method, and their radiative properties and the chemical environment in the Eu surroundings were thoroughly investigated by Judd-Ofelt intensity and the derived parameters using the online application. In contrast to the tediousness and time-consuming process of these types of calculations, by using this online software, all intensity parameters and the derived quantities can be obtained within a short time.

本文报告了一种新的基于网络的应用软件的开发情况,该软件用于计算掺杂 Eu3+ 的化合物发射光谱中的 Judd-Ofelt 强度参数和衍生量。该应用软件完全使用 JavaScript 开发,兼容所有主流浏览器。网络应用程序可通过以下链接访问:https://sciapps.sci-sim.com/judd_ofelt_analysis_Eu.html。利用燃烧法合成了掺杂不同数量 Eu3+ 的 ZnO 试验样品,并通过 Judd-Ofelt 强度和在线应用程序的推导参数对其辐射特性和 Eu 周围的化学环境进行了深入研究。与此类计算的繁琐和耗时相比,使用该在线软件可在短时间内获得所有强度参数和推导量。
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引用次数: 0
Implementation of forward error correction for improved performance of free space optical communication channel in adverse atmospheric conditions 实施前向纠错,提高自由空间光通信信道在不利大气条件下的性能
Q3 Physics and Astronomy Pub Date : 2024-04-17 DOI: 10.1016/j.rio.2024.100689
S.L. Sathiya Narayanan, B.C. Dhanush Devappa, Kalyani Pawar, Shreyas Jain, Appala Venkata Ramana Murthy

The tremendous speed and security that Free Space Optical Communication (FSOC) technology provides have led to its rapid expansion. This opens up a plethora of possibilities for terrestrial communication with small ranges of up to a few kilometers, such as multi-campus and building-to-building communication. However, the ever-varying nature of atmospheric channels poses a major challenge degrading the optical signal strength. Several constituents of atmospheric channels like fog, dust, smoke, rain, and wind turbulence will influence the performance of an FSOC channel. In this paper, we present a system model focusing on adverse atmospheric channels, primarily by replicating varying fog conditions. Additionally, we showcase the successful real-time implementation of diverse forward error correction (FEC) codes in adverse atmospheric conditions, specifically varying levels of fog, using a dedicated test bed. Our experiments demonstrate the capability to recover erroneous data up to 50% Bit Error Rates (BER). Furthermore, we delve into the selection of suitable FEC codes tailored to different fog conditions, aiming to optimize time efficiency with the encoded bitrate.

自由空间光通信(FSOC)技术提供的巨大速度和安全性使其迅速发展。这为小范围(最多几公里)地面通信提供了大量可能性,如多校园和楼宇间通信。然而,大气信道不断变化的性质对降低光信号强度构成了重大挑战。雾、尘、烟、雨和风湍流等大气信道的多种成分都会影响 FSOC 信道的性能。在本文中,我们主要通过复制不同的雾条件,提出了一个以不利大气信道为重点的系统模型。此外,我们还展示了在不利的大气条件下,特别是在不同程度的雾中,利用专用测试平台成功地实时实施了多种前向纠错(FEC)编码。我们的实验证明,我们有能力恢复误码率高达 50%的错误数据。此外,我们还深入研究了如何根据不同的雾气条件选择合适的 FEC 编码,以优化编码比特率的时间效率。
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引用次数: 0
A comprehensive review of blood component detection utilizing One-Dimensional, Two-Dimensional, and photonic crystal fiber biosensors 利用一维、二维和光子晶体光纤生物传感器检测血液成分的全面回顾
Q3 Physics and Astronomy Pub Date : 2024-04-16 DOI: 10.1016/j.rio.2024.100671
Fariborz Parandin , Zahra Rahimi , Abdolrasol Moloudi , Farsad Heidari , Mohamad Mehdi Parandin

This comprehensive review investigates the diverse landscape of blood component detection through the one-dimensional, two-dimensional, and photonic crystal fiber biosensors. Each biosensor, dedicated to specific blood components, is scrutinized in detail, with a focus on key parameters such as Quality Factor (Q) coefficient Loss, Figure of Merit (FOM), and Detection Limit (DL). The study discerns notable advancements in sensitivity and confinement loss within the realm of photonic crystal fiber sensors, attributing these improvements to recent structural modifications. The findings contribute valuable insights into the state-of-the-art techniques employed in blood component detection, paving the way for enhanced biosensor technologies in biomedical applications.

本综述通过一维、二维和光子晶体光纤生物传感器研究了血液成分检测的多样性。对每种专用于特定血液成分的生物传感器都进行了详细审查,重点关注质量因子 (Q) 系数损失、优越性图 (FOM) 和检测限 (DL) 等关键参数。研究发现,光子晶体光纤传感器在灵敏度和约束损耗方面取得了显著进步,这些进步归功于最近的结构调整。研究结果为血液成分检测中采用的最先进技术提供了宝贵的见解,为增强生物医学应用中的生物传感器技术铺平了道路。
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引用次数: 0
CuS-CuO nanoparticles for antennas collect light through their conductivity by absorbing a single photon located at the wavelength of 254 nm 用于天线的 CuS-CuO 纳米粒子通过其导电性吸收波长为 254 纳米的单光子来收集光线
Q3 Physics and Astronomy Pub Date : 2024-04-10 DOI: 10.1016/j.rio.2024.100674
N. Hafiene , B. Bouricha , R. Souissi , M. Abderrabba , C. Vázquez-Vázquez , M.A. López-Quintela , N. Bouguila , S. Alaya

CuS-CuO nanoparticles were prepared by air annealing as-made CuS nanoparticles deposited using spray pyrolysis. The optical, structural, and morphological properties of samples were investigated by UV–VIS Spectroscopy, X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Atomic Force Microscopy (AFM). The XRD analysis of as-prepared sample include two phases CuS and Cu2S, while annealed films are a mixture of CuS and CuO phases. The dimensions of the CuS crystallites were estimated by Williamson's method on the diffraction peaks (81 nm) while the dimensions of the CuO ones were statistically evaluated via the SEM image (95 nm) and corroborated by Williamson's method on the diffraction peaks (98 nm). SEM study of annealed samples reveals that nanoparticles are monocrystalline. Optical analysis shows more than 80 % transmittance through sample thickness 164 nm in the infrared region and two energy bandgaps of 1.92 and 2.50 eV in the visible region associated with CuO and CuS, respectively. In addition, we observe after several optical excitations that only the UV wavelength of 254 nm gives a tangible electrical response. We understand from the literature that this is only possible through one interpretation of the antenna effect. Optical antennas aim to freely change light rays into local energy. In fact, our sample presents nanoparticles with sizes around 80 nm that show clear absorption through the development of their reproducible resistance that increases with polarization toward saturation after 5 V. Therefore, we propose using prepared nanoparticles in a light-harvesting antenna for artificial photodetector and other optoelectronic applications.

CuS-CuO 纳米粒子是通过空气退火法制备的。通过紫外可见光谱、X 射线衍射(XRD)、扫描电子显微镜(SEM)和原子力显微镜(AFM)对样品的光学、结构和形态特性进行了研究。制备样品的 XRD 分析包括 CuS 和 Cu2S 两相,而退火薄膜则是 CuS 和 CuO 两相的混合物。CuS 结晶的尺寸是通过威廉姆森方法对衍射峰进行估算得出的(81 nm),而 CuO 结晶的尺寸则是通过扫描电镜图像进行统计评估得出的(95 nm),并通过威廉姆森方法对衍射峰进行证实(98 nm)。对退火样品的扫描电镜研究表明,纳米颗粒是单晶体。光学分析表明,在红外区域,样品厚度为 164 nm,透射率超过 80%;在可见光区域,与 CuO 和 CuS 相关的两个能带隙分别为 1.92 和 2.50 eV。此外,我们在多次光激发后观察到,只有波长为 254 纳米的紫外波段才会产生明显的电反应。我们从文献中了解到,这只能通过对天线效应的一种解释来实现。光学天线旨在自由地将光线转化为局部能量。事实上,我们的样品中的纳米颗粒大小约为 80 nm,通过发展其可重复的电阻显示出明显的吸收,这种电阻在 5 V 后随着极化的增加而达到饱和。因此,我们建议将制备的纳米粒子用于人工光电探测器和其他光电应用的光收集天线。
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引用次数: 0
Vanadium oxides nanostructures for adsorption of Methylene blue, vehicle exhaust and soot of ink as low carbon applications 吸附亚甲基蓝、汽车尾气和油墨烟尘的纳米氧化钒结构的低碳应用
Q3 Physics and Astronomy Pub Date : 2024-04-09 DOI: 10.1016/j.rio.2024.100673
E.M. El-Maghraby , Marwa H. Ashery , Mohamed Elnouby , E.M. Elsehly

In this study, V2O5 nanoparticles were synthesized via facile method by annealing ammonium meta vanadate at 450 °C for 1 h. The resulting nanoparticles were analyzed using X-ray diffractometer, scanning electron microscopy, and transmission electron microscopy to investigate their structural and morphological properties. The optical properties of the prepared samples were examined using UV–VIS spectrophotometry. The XRD measurements indicated an orthorhombic V2O5 structure with an average crystallite size of 21.34 nm as calculated using the Debye-Scherrer formula. The synthesized V2O5 nanoparticles showed a plate like rod structure with an average size around 55 nm through TEM and HRTEM analysis. The Urbach energy (Eu) of V2O5 was calculated to be 1.07ev. The V2O5 nano-adsorbents were tested for their effectiveness in the selective removal of MB from an aqueous medium, as well vehicle exhaust and soot of ink from non-aqueous media. During the adsorption process, the impact of several factors including time, adsorbent dose, and different initial concentrations were investigated. Equilibrium adsorption isotherms were evaluated using Langmuir and Freundlich equations. The Langmuir model was found to be a better fit for the adsorption equilibrium, with correlation coefficients of 0.915, 0.904, and 0.912 for MB, vehicle exhaust, and soot of ink, respectively. The experimental kinetic results of V2O5 were found to fit the pseudo-second-order model for both aqueous and non-aqueous media with a higher correlation factor indicating chemisorption during the adsorption process.

本研究采用简便的方法,将偏钒酸铵在 450 ℃ 下退火 1 小时,合成了 V2O5 纳米粒子,并使用 X 射线衍射仪、扫描电子显微镜和透射电子显微镜分析了所制备纳米粒子的结构和形态特性。使用紫外-可见分光光度法检测了制备样品的光学特性。XRD 测量结果表明,V2O5 为正交菱形结构,根据 Debye-Scherrer 公式计算得出的平均结晶尺寸为 21.34 nm。通过 TEM 和 HRTEM 分析,合成的 V2O5 纳米粒子呈板状棒状结构,平均尺寸约为 55 nm。经计算,V2O5 的厄巴赫能(Eu)为 1.07ev。测试了 V2O5 纳米吸附剂在选择性去除水介质中的甲基溴以及非水介质中的汽车尾气和油墨烟尘方面的有效性。在吸附过程中,研究了时间、吸附剂剂量和不同初始浓度等几个因素的影响。使用 Langmuir 和 Freundlich 方程评估了平衡吸附等温线。结果发现,Langmuir 模型更适合吸附平衡,对甲基溴、汽车尾气和油墨烟尘的相关系数分别为 0.915、0.904 和 0.912。在水介质和非水介质中,V2O5 的实验动力学结果均符合伪二阶模型,相关系数较高,表明吸附过程中存在化学吸附作用。
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Results in Optics
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