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High-Performance Ti3C2Tx MXene-InP Side-Illuminated Schottky Photodetector: Theoretical design and performance enhancement beyond Graphene-Based devices 高性能Ti3C2Tx MXene-InP侧面照明肖特基光电探测器:超越石墨烯器件的理论设计和性能增强
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100964
Arash Vaghef-Koodehi
This comprehensive theoretical study investigates a novel MXene-based side-illuminated Schottky photodetector (SIMS-PD) integrated on an InP waveguide platform for telecommunication wavelengths. Building on our previous work with graphene-based devices achieving responsivities up to 1.76 A/W, we propose a Ti3C2Tx MXene double-layer structure that theoretically demonstrates superior performance metrics. Through electromagnetic modeling using Lumerical MODE and COMSOL Multiphysics, we predict a responsivity of 2.31 A/W at 1.55 μm—representing a 31% improvement over trilayer graphene devices. The MXene structure exhibits ultra-low dark current (5 × 101⁶ A), exceptional detectivity (2.1 × 1013 Jones), and 42 GHz bandwidth capability. These enhanced properties arise from MXene’s unique combination of metallic conductivity (8,500 S/cm), tunable work function (4.1–4.8 eV), and strong optical absorption coefficient (3.8 × 105 cm1). Comparative analysis reveals MXene’s advantages in terms of solution processability, environmental stability, and voltage tunability (Δμ = 0.8 eV) over graphene counterparts. The proposed device architecture features optimized field confinement at the MXene-InP interface with 85% modal overlap, achieving quantum efficiency of 0.69. This work establishes MXene as a promising alternative to graphene for next-generation integrated photodetectors, particularly for applications in optical communications, quantum technologies, and high-sensitivity sensing systems.
这项综合理论研究研究了一种新型的基于mxene的侧照明肖特基光电探测器(sim - pd),该探测器集成在InP波导平台上,用于电信波长。基于我们之前的工作,基于石墨烯的器件实现了高达1.76 A/W的响应,我们提出了一种理论上具有优越性能指标的Ti3C2Tx MXene双层结构。通过使用Lumerical MODE和COMSOL Multiphysics进行电磁建模,我们预测在1.55 μm时的响应率为2.31 a /W,比三层石墨烯器件提高了31%。MXene结构具有超低暗电流(5 × 10−1 26 A),出色的探测能力(2.1 × 1013 Jones)和42 GHz带宽能力。这些增强的性能源于MXene独特的金属电导率(8,500 S/cm),可调工作函数(4.1-4.8 eV)和强光吸收系数(3.8 × 105 cm−1)的组合。对比分析表明,MXene在溶液可加工性、环境稳定性和电压可调性(Δμ = 0.8 eV)方面优于石墨烯。所提出的器件结构在MXene-InP接口处具有优化的场约束,模态重叠率为85%,量子效率为0.69。这项工作确立了MXene作为下一代集成光电探测器的替代石墨烯的前景,特别是在光通信、量子技术和高灵敏度传感系统中的应用。
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引用次数: 0
Microscope-assisted scleral buckling with fiber-optic scleral depressor for retinal break localization —— A case series 显微镜辅助巩膜屈曲与光纤巩膜抑制剂用于视网膜断裂定位-一个病例系列
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100976
Xiaolong Chen , Yong Wang , Lingxi Wei , Yun Wang , Sibei Ren , Wahid Shah , Yu Liu
Rhegmatogenous retinal detachment (RRD) is an ophthalmic emergency characterized by the separation of the neurosensory retina from the retinal pigment epithelium due to retinal breaks. Scleral buckling is a conventional surgical treatment for this condition. This case series aims to illustrate the application of a novel surgical technique—illuminated scleral depressor-assisted scleral buckling for precise break localization—in clinical practice and to evaluate long-term postoperative outcomes in patients.
孔源性视网膜脱离(RRD)是一种眼科急症,其特征是由于视网膜破裂导致神经感觉视网膜与视网膜色素上皮分离。巩膜屈曲是治疗这种疾病的常规手术方法。本病例系列旨在说明一种新的外科技术的应用-照明巩膜抑制剂辅助巩膜屈曲精确骨折定位-在临床实践中,并评估患者的长期术后结果。
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引用次数: 0
Supervised RNN-PTS framework for PAPR reduction and performance optimization in optical OTSM-VLC systems 用于光学OTSM-VLC系统PAPR降低和性能优化的监督RNN-PTS框架
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100992
Arun Kumar , Nishant Gaur , Aziz Nanthaamornphong
This paper presents a supervised recurrent neural network–based partial transmit sequence (S–RNN–PTS) approach for reducing – the – peak-to-average power ratio (PAPR) in optical orthogonal time–sequence multiplexing (OTSM) visible-light communication (VLC) systems. A high PAPR in intensity–modulation/direct–detection (IM/DD) links introduces severe nonlinear distortion owing to LED nonlinearity, degrading power efficiency, and link reliability. The proposed framework integrates supervised learning with the PTS structure to enable search-free phase prediction at a fixed inference complexity, while preserving the conventional OTSM architecture. The performance was evaluated through Monte Carlo simulations using M−QAM−modulated OTSM waveforms over IM/DD VLC channels with nonlinear LED characteristics. The results demonstrate a PAPR reduction of up to 7  dB compared to conventional PTS schemes, and an SNR improvement of approximately 8  dB at a bit-error-rate (BER) of 10−3 for large subcarrier configurations. These gains enhance the spectral compactness and robustness against nonlinear distortion, making the S–RNN–PTS framework highly suitable for high-speed, energy-efficient OTSM–VLC systems.
提出了一种基于监督递归神经网络的部分传输序列(S-RNN-PTS)方法,用于降低光正交时序复用(OTSM)可见光通信(VLC)系统的峰均功率比(PAPR)。由于LED的非线性,高PAPR在强度调制/直接检测(IM/DD)链路中引入了严重的非线性失真,降低了功率效率和链路可靠性。该框架将监督学习与PTS结构相结合,在保留传统OTSM结构的同时,实现了固定推理复杂度下的无搜索相位预测。通过蒙特卡罗模拟,在具有非线性LED特性的IM/DD VLC通道上使用M - QAM调制的OTSM波形来评估性能。结果表明,与传统PTS方案相比,PAPR降低了7 dB,在误码率(BER)为10−3的大子载波配置下,信噪比提高了约8 dB。这些增益增强了频谱紧凑性和抗非线性失真的鲁棒性,使S-RNN-PTS框架非常适合高速,节能的OTSM-VLC系统。
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引用次数: 0
Biosensor based on photonic crystal fiber and surface plasmon resonance for glucose, HIV, and cancer cells detection 基于光子晶体光纤和表面等离子体共振的生物传感器,用于葡萄糖、HIV和癌细胞检测
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100980
Ruqayyah Raad Awad , Younis Mohamed Atiah Al-zahy
This paper presents a high-sensitivity biosensor based on a Surface Plasmon Resonance (SPR) Photonic Crystal Fiber (PCF). Light is confined in a single mode within the core by a lattice of air holes, while the fiber surface is coated with a circular gold thin film to excite plasmonic waves. The sensing performance was evaluated through numerical simulations using the Finite Element Method (FEM) in COMSOL Multiphysics 6.3. The design was optimized by refining structural parameters, including the air hole diameter (d), lattice pitch (ᴧ), and gold layer thickness (tg), to maximize light-matter interaction and minimize confinement loss. The optimized device demonstrates superior wavelength sensitivity (Sλ) and amplitude sensitivity (SA) across a diverse spectrum of biological analytes. For cervical cancer (HeLa) detection, the sensor achieves an Sλ of 7,333 nm/RIU and a high amplitude sensitivity of 1,942.79 RIU−1, representing a significant improvement over earlier reported value. Other malignancies are detected with high precision, including breast cancer (MDA-MB-231 and MCF-7) at 8,571 nm/RIU and 7,692 nm/RIU respectively, T-lymphocyte cancer (Jurkat) at 5,500 nm/RIU, and adrenal tumors (PC12) at 5,000 nm/RIU. Beyond cellular detection, the platform exhibits an outstanding sensitivity of 3,857 nm/RIU for HIV-infected blood and 4,000 nm/RIU for glucose solutions. Comprehensive numerical analysis across a refractive index range of 1.32 to 1.39 revealed a maximum sensitivity of 8,000 ± 452 nm/RIU and a peak Figure of Merit (FOM) of 291.7 ± 5.78 RIU−1. With a peak detection resolution of 2.5 × 10−6 RIU for biochemical sensing, this PCF-SPR platform offers a promising, cost-effective, and high-precision alternative to conventional diagnostic techniques such as surgical biopsies and chemical assays.
提出了一种基于表面等离子体共振光子晶体光纤的高灵敏度生物传感器。光在核心内被空气孔晶格限制在单模态,而光纤表面涂有一层圆形金薄膜来激发等离子体波。利用COMSOL Multiphysics 6.3软件中的有限元法(FEM)对传感性能进行数值模拟。通过优化结构参数,包括气孔直径(d)、晶格间距(ᴧ)和金层厚度(tg),优化设计,以最大化光-物质相互作用并最小化约束损失。优化后的器件在不同光谱的生物分析物中表现出优异的波长灵敏度(λ)和振幅灵敏度(SA)。对于宫颈癌(HeLa)检测,该传感器实现了7,333 nm/RIU的λ和1,942.79 RIU−1的高振幅灵敏度,比先前报道的值有了显着改善。其他恶性肿瘤的检测精度也很高,包括乳腺癌(MDA-MB-231和MCF-7)分别为8,571 nm/RIU和7,692 nm/RIU, t淋巴细胞癌(Jurkat)为5,500 nm/RIU,肾上腺肿瘤(PC12)为5,000 nm/RIU。除细胞检测外,该平台对hiv感染血液的灵敏度为3857 nm/RIU,对葡萄糖溶液的灵敏度为4000 nm/RIU。在1.32 ~ 1.39折射率范围内的综合数值分析显示,最大灵敏度为8,000±452 nm/RIU,峰值性能图(FOM)为291.7±5.78 RIU−1。该PCF-SPR平台具有2.5 × 10−6 RIU的峰值检测分辨率,用于生化传感,为传统诊断技术(如手术活检和化学分析)提供了一种有前途的,具有成本效益的和高精度的替代方案。
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引用次数: 0
Integrated 3D tensor and deep neural network approach for real-time toxic gas monitoring and device integrity assessment 集成三维张量和深度神经网络方法的有毒气体实时监测和设备完整性评估
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100972
Aymen A. Altae , Abdolvahab Ehsani Rad
This study presents an advanced multifunctional graphene-based sensing platform integrating deep neural networks (DNN), phase space reconstruction (PSR), and sophisticated feature engineering for real-time toxic gas monitoring and internal device integrity assessment. The sensor leverages a dual-sensor architecture composed of multilayer graphene and Kapton substrates, modeled through an equivalent circuit model (ECM) that captures subtle electrical impedance changes induced by gas adsorption and structural anomalies. Optical absorption spectra of CO2, NO2, and H2S in the terahertz frequency range reveal distinct molecular fingerprints, enabling precise gas discrimination and concentration quantification with response times as low as 5 s for CO2 detection. The PSR technique transforms time-series sensor data into multidimensional phase space representations fed into a 3D convolutional neural network, enhancing classification accuracy of both toxic gases and internal defects. Structural anomalies within the sensor, including internal gaps and delamination, are detected through characteristic shifts in absorption spectra, underscoring the platform’s dual capability for environmental monitoring and device fault diagnosis. Comparative analyses demonstrate enhanced capability in sensitivity, selectivity, and rapid response relative to existing sensor technologies. This integrated approach establishes a robust, scalable foundation for next-generation wearable, portable, and embedded sensing systems applicable to environmental safety, industrial emission control, and healthcare diagnostics.
该研究提出了一种先进的多功能石墨烯传感平台,集成了深度神经网络(DNN)、相空间重建(PSR)和复杂的特征工程,用于实时有毒气体监测和内部设备完整性评估。该传感器利用多层石墨烯和卡普顿衬底组成的双传感器架构,通过等效电路模型(ECM)建模,捕获由气体吸附和结构异常引起的细微电阻抗变化。在太赫兹频率范围内,CO2、NO2和H2S的光学吸收光谱显示出不同的分子指纹,从而实现精确的气体鉴别和浓度定量,CO2检测的响应时间低至5 s。PSR技术将时间序列传感器数据转换为多维相空间表示,并将其馈送到三维卷积神经网络中,从而提高有毒气体和内部缺陷的分类精度。传感器内部的结构异常,包括内部间隙和分层,可以通过吸收光谱的特征变化来检测,强调了该平台在环境监测和设备故障诊断方面的双重能力。对比分析表明,相对于现有的传感器技术,该技术在灵敏度、选择性和快速响应方面具有增强的能力。这种集成方法为适用于环境安全、工业排放控制和医疗保健诊断的下一代可穿戴、便携式和嵌入式传感系统建立了强大的可扩展基础。
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引用次数: 0
Development of a fiber-optic sensor for enhancing functional security of perimeter protection 一种增强周界防护功能安全性的光纤传感器的研制
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100986
Arash Kosari
This paper presents the design, implementation, and experimental evaluation of a compact macrobend-based fiber-optic sensor intended for perimeter intrusion detection with an additional capability for estimating the mass of an intruding object. The sensing principle relies on controlled macrobending of a single-mode optical fiber, which induces radiative power loss that is collected by a secondary fiber and converted into an electrical signal for analysis. Three standard commercial telecom fibers (G.652, G.655, and G.657) were experimentally characterized at four wavelengths (1310, 1490, 1550, and 1625 nm) in order to quantify macrobend sensitivity as a function of bend radius and arc length. The results demonstrate that G.655 exhibits the highest macrobend sensitivity, reaching up to 0.21 dB·mm−1 at 1625 nm, and provides a measurable and approximately linear response suitable for mass estimation. Within the identified linear operating range, the sensor achieves a mass sensitivity of approximately 1.4 dB·kg−1. A compact mechanical macrobend shaper, the complete optical and electronic measurement chain, and an analytical calibration framework linking applied load, induced displacement, bend geometry, and optical attenuation are presented. Repeatability experiments conducted over more than fifty measurement cycles show a coefficient of variation below 5% in the linear regime. The proposed approach offers a low-cost and mechanically simple solution for enhanced perimeter monitoring while highlighting practical trade-offs related to sensitivity, operating range, and calibration stability.
本文介绍了一种紧凑的基于大弯曲的光纤传感器的设计、实现和实验评估,该传感器用于周边入侵检测,具有估计入侵物体质量的附加功能。传感原理依赖于单模光纤的可控大弯曲,它引起辐射功率损失,由二次光纤收集并转换成电信号供分析。三种标准商用电信光纤(G.652、G.655和G.657)在四个波长(1310、1490、1550和1625 nm)下进行了实验表征,以量化弯曲半径和弧长对大弯曲灵敏度的影响。结果表明,G.655具有最高的大弯曲灵敏度,在1625 nm处可达0.21 dB·mm−1,并提供可测量的近似线性响应,适合于质量估计。在确定的线性工作范围内,传感器的质量灵敏度约为1.4 dB·kg−1。提出了一种紧凑的机械大弯曲成形器,完整的光学和电子测量链,以及连接施加载荷,诱导位移,弯曲几何形状和光学衰减的分析校准框架。在50多个测量周期中进行的重复性实验表明,在线性体系中,变异系数低于5%。所提出的方法提供了一种低成本和机械简单的解决方案,用于增强周界监测,同时突出了与灵敏度、工作范围和校准稳定性相关的实际权衡。
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引用次数: 0
Comprehensive analysis of thickness-dependent structural, morphological, and optical properties of TiO2 based thin films 二氧化钛基薄膜厚度相关结构、形态和光学性质的综合分析
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100993
B.D. Igamov , I.R. Bekpulatov , A.M. Normamatov , A.I. Kamardin , F.Sh. Kodirova , Gunel Imanova
In this study, three TiO2-based thin film samples were fabricated, and their thickness-dependent optical properties and crystal structures were systematically investigated. The films, with thicknesses of 72 nm, 125 nm, and 283 nm, were deposited onto Si(111) substrates using the DC magnetron sputtering technique. The structural, morphological, and optical properties of the TiO2 thin films were comprehensively characterized using a combination of analytical techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, and spectroscopic ellipsometry. XRD analysis confirmed that the films predominantly crystallized in the anatase phase with a high degree of crystallinity, while SEM images revealed smooth surface morphologies with a low density of structural defects.
Raman spectroscopic results demonstrated the strong influence of film thickness and substrate effects on the optical and structural characteristics of the films. In particular, the increased intensity and narrowing of anatase-related phonon modes with increasing thickness indicated a progressive enhancement of crystalline ordering. FTIR spectroscopy and spectroscopic ellipsometry were employed to determine the optical band gap (Eg) values for each film thickness.
For the 72 nm thick film, the optical band gap was estimated to be Eg ≈ 3.8–2.84 eV. At this low thickness, the substrate contribution remains significant, and the presence of mixed interfacial phases is evident. The 125 nm thick film exhibited an apparent band gap of Eg ≈ 4.13 eV. At this intermediate thickness, incomplete surface coverage and residual substrate influence result in an upward shift of the interband transition features. In contrast, the 283 nm thick film showed a band gap in the range of Eg ≈ 3.1–3.3 eV, which is consistent with the intrinsic optical properties of anatase TiO2. At this thickness, the film fully covers the substrate, effectively suppressing substrate-related optical contributions.
These results confirm that the TiO2 thin films produced in this study exhibit high structural and optical quality, making them promising candidates for applications in photocatalytic and optoelectronic devices. Overall, the findings highlight that precise control of film thickness and thermal treatment parameters is crucial for optimizing the optical and photocatalytic performance of TiO2-based thin films.
本研究制备了三种基于tio2的薄膜样品,系统地研究了其随厚度变化的光学性质和晶体结构。采用直流磁控溅射技术将厚度分别为72 nm、125 nm和283 nm的薄膜沉积在Si(111)衬底上。利用x射线衍射(XRD)、扫描电子显微镜(SEM)、拉曼光谱、傅里叶变换红外光谱(FTIR)和椭偏光谱等分析技术,对TiO2薄膜的结构、形态和光学性质进行了全面表征。XRD分析证实薄膜主要结晶为锐钛矿相,结晶度高,SEM图像显示表面形貌光滑,结构缺陷密度低。拉曼光谱结果表明,薄膜厚度和衬底效应对薄膜的光学和结构特性有很大影响。特别是随着厚度的增加,锐钛矿相关声子模式的强度增加和变窄表明晶体有序性逐渐增强。利用FTIR光谱和椭偏光谱法测定了各膜厚度下的光学带隙(Eg)值。对于72 nm厚的薄膜,估计光学带隙为Eg≈3.8 ~ 2.84 eV。在这种低厚度下,衬底的贡献仍然显著,并且混合界面相的存在是明显的。125 nm厚薄膜的带隙为Eg≈4.13 eV。在这个中间厚度,不完全的表面覆盖和残余衬底影响导致带间过渡特征向上移动。283 nm厚的薄膜带隙在Eg≈3.1 ~ 3.3 eV范围内,这与锐钛矿TiO2的固有光学性质一致。在这个厚度,薄膜完全覆盖衬底,有效地抑制与衬底相关的光学贡献。这些结果证实了本研究制备的TiO2薄膜具有较高的结构和光学质量,使其成为光催化和光电子器件应用的有希望的候选者。总的来说,研究结果强调了精确控制薄膜厚度和热处理参数对于优化tio2基薄膜的光学和光催化性能至关重要。
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引用次数: 0
Design and analysis of all-fiber mode filter based on multi-core fiber 基于多芯光纤的全光纤模滤波器设计与分析
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100991
Teng Wang , Yalong Wen , Haoyu Wang , Suxuan Cao , Jiancun Zuo
We propose an all-fiber mode filter based on multi-core fiber, which efficiently selects or filters out specific modes. Based on the mode coupling principle, we designed all-fiber mode filters using dual-core fiber (DCF) and three-core fiber (TCF) structures to achieve multifunctional mode filtering. In the DCF structure, any mode can be filtered out; taking 1550 nm as the working wavelength, the mode filter achieves remarkable efficiency exceeding 90% for LP01, LP11 and LP21 modes, achieving bandwidths of approximately 110 nm, 117 nm, and 117 nm, respectively. In the TCF structure, the beam containing LP11, LP21 and LP31 modes is transmitted, filtering out both the LP11 and LP21 modes while maintaining high transmission of the LP31 mode, and the transmission ratio can reach 90%. To the best of our knowledge, this is the first report on mode filter based on all-fiber structure. This method offers the promising solutions for advanced optical communication systems and photonic device integration.
我们提出了一种基于多芯光纤的全光纤模式滤波器,可以有效地选择或滤除特定的模式。基于模式耦合原理,采用双芯光纤(DCF)和三芯光纤(TCF)结构设计全光纤模式滤波器,实现多功能模式滤波。在DCF结构中,任何模式都可以被滤除;以1550 nm为工作波长,该模式滤波器在LP01、LP11和LP21模式下的效率均超过90%,带宽分别约为110 nm、117 nm和117 nm。在TCF结构中,传输包含LP11、LP21和LP31模式的波束,同时滤除LP11和LP21模式,同时保持LP31模式的高传输,传输比可达90%。据我们所知,这是基于全光纤结构的模式滤波器的第一篇报道。该方法为先进的光通信系统和光子器件集成提供了有前途的解决方案。
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引用次数: 0
Enhanced photocatalytic performance of TiO2-SiO2 composites: The role of structural defects and optimal composition TiO2-SiO2复合材料光催化性能的增强:结构缺陷和优化组成的作用
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100989
Senny Widyaningsih , Muhamad Diki Permana , D’ April Sabriantie Mulus , Kiki Maesaroh , Rudiawan Edwin , Joddy Arya Laksmono , Apang Djafar Shieddieque , Iman Rahayu , Diana Rakhmawaty Eddy
TiO2-SiO2 composites with varying molar ratios were synthesized and systematically evaluated for the photocatalytic degradation of methylene blue (MB) under UV irradiation. X-ray diffraction and spectroscopic analyses revealed that the incorporation of amorphous SiO2 reduced TiO2 crystallinity, suppressed rutile phase formation, and promoted the generation of structural defects, particularly non-bridging oxygen species. Among the investigated compositions, the TiO2-SiO2 1:1 composite exhibited the highest defect density and the smallest crystallite size, indicating enhanced interfacial interaction and surface reactivity. Photocatalytic experiments demonstrated that the TiO2-SiO2 1:1 composite achieved approximately 90% MB degradation within 160 min, significantly outperforming pure TiO2 and other TiO2-SiO2 ratios. The corresponding apparent kinetic rate constant reached 0.0134 min−1, which is nearly four times higher than that of pure TiO2 (0.0034 min−1), confirming the decisive role of defect-rich structures in accelerating photocatalytic reactions. The enhanced performance is attributed to the synergistic effects of optimized crystallinity, defect generation, and increased surface hydroxylation induced by SiO2 incorporation. These findings provide clear evidence that compositional control–driven defect engineering is a key strategy for improving the photocatalytic efficiency of TiO2-SiO2 composites for organic wastewater treatment.
合成了不同摩尔比的TiO2-SiO2复合材料,并对其紫外光催化降解亚甲基蓝(MB)的性能进行了系统评价。x射线衍射和光谱分析表明,无定形SiO2的掺入降低了TiO2的结晶度,抑制了金红石相的形成,促进了结构缺陷的产生,特别是非桥接氧的产生。在所研究的组合物中,TiO2-SiO2 1:1复合材料的缺陷密度最高,晶粒尺寸最小,表明界面相互作用和表面反应性增强。光催化实验表明,TiO2- sio2 1:1复合材料在160 min内降解MB达到90%左右,明显优于纯TiO2和其他TiO2- sio2比例。相应的表观动力学速率常数达到0.0134 min−1,是纯TiO2 (0.0034 min−1)的近4倍,证实了富缺陷结构在加速光催化反应中的决定性作用。这种性能的增强是由于二氧化硅掺入导致的结晶度优化、缺陷生成和表面羟基化的协同作用。这些研究结果清楚地表明,成分控制驱动的缺陷工程是提高TiO2-SiO2复合材料光催化处理有机废水效率的关键策略。
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引用次数: 0
Non-linear optical properties of excitonic complexes in prolate ellipsoidal quantum dot 长形椭球量子点中激子复合物的非线性光学性质
IF 3 Q3 Physics and Astronomy Pub Date : 2026-02-01 DOI: 10.1016/j.rio.2026.100982
Y.Y. Bleyan , M.Y. Vinnichenko , N. Zeiri , C.A. Duque , D.B. Hayrapetyan
This study presents a theoretical study of ground-state exciton and biexciton properties in strongly prolate ellipsoidal GaAs quantum dot. Using a variational approach with trial wave functions constructed from single-particle states, we examine the dependence of exciton and biexciton energies on the dot’s geometric parameters. The oscillator strengths of exciton–biexciton transitions are analyzed as functions of the major and minor semiaxes. We further investigate the third-order optical susceptibility near single- and two-photon resonances, elucidating the role of exciton–biexciton interactions. The results show that one-photon resonances dominate the nonlinear response, with contributions exceeding those of two-photon resonances by approximately four orders of magnitude. Absorption coefficients for exciton and biexciton transitions are evaluated for a fixed major semiaxis and varying minor semiaxis, along with the biexciton two-photon absorption coefficient. Finally, we analyze biexciton-induced nonlinear refractive index modulation, which exhibits a sign reversal across resonance and a pronounced peak–dip structure, indicating strong dispersive behavior and significant excitonic phase modulation.
本文从理论上研究了强长展椭球形GaAs量子点的基态激子和双激子性质。利用由单粒子态构造的试波函数的变分方法,我们研究了激子和双激子能量对点几何参数的依赖关系。分析了激子-双激子跃迁的振子强度随主半轴和小半轴的变化规律。我们进一步研究了单光子和双光子共振附近的三阶光磁化率,阐明了激子-双激子相互作用的作用。结果表明,单光子共振在非线性响应中占主导地位,其贡献比双光子共振的贡献高出约四个数量级。在固定的主半轴和变化的小半轴下,计算了激子和双激子跃迁的吸收系数,以及双激子双光子吸收系数。最后,我们分析了双激子诱导的非线性折射率调制,该调制在共振中表现出符号反转和明显的峰倾角结构,表明强色散行为和显著的激子相位调制。
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引用次数: 0
期刊
Results in Optics
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